In the past, Earth's climate underwent dramatic changes that influenced physical, chemical, geological, and biological processes on a global scale. Such changes left an imprint in Earth's atmosphere, as shown by the variability in abundances of trace gases like carbon dioxide and methane. In return, changes in the atmospheric trace gas composition affected Earth's climate. Studying compositional variations of the past atmosphere helps us understand the history of interactions between global biogeochemical cycles and Earth?s climate. The most reliable information on past atmospheric composition comes from analysis of air entrapped in polar ice cores. This project aims to generate ice-core records of relatively short-lived, very-low-abundance trace gases to determine the range of past variability in their atmospheric levels and investigate the changes in global biogeochemical cycles that caused this variability. This project measures three such gases: carbonyl sulfide, methyl chloride, and methyl bromide. Changes in carbonyl sulfide can indicate changes in primary productivity and photosynthetic update of carbon dioxide. Changes in methyl chloride and methyl bromide significantly impact natural variability in stratospheric ozone. In addition, the processes that control atmospheric levels of methyl chloride and methyl bromide are shared with those controlling levels of atmospheric methane. The measurements will be made in the new ice core from the South Pole, which is expected to provide a 40,000-year record.<br/><br/>The primary focus of this project is to develop high-quality trace gas records for the entire Holocene period (the past 11,000 years), with additional, more exploratory measurements from the last glacial period including the period from 29,000-36,000 years ago when there were large changes in atmospheric methane. Due to the cold temperatures of the South Pole ice, the proposed carbonyl sulfide measurements are expected to provide a direct measure of the past atmospheric variability of this gas without the large hydrolysis corrections that are necessary for interpretation of measurements from ice cores in warmer settings. Furthermore, we will test the expectation that contemporaneous measurements from the last glacial period in the deep West Antarctic Ice Sheet Divide ice core will not require hydrolysis loss corrections. With respect to methyl chloride, we aim to verify and improve the existing Holocene atmospheric history from the Taylor Dome ice core in Antarctica. The higher resolution of our measurements compared with those from Taylor Dome will allow us to derive a more statistically significant relationship between methyl chloride and methane. With respect to methyl bromide, we plan to extend the existing 2,000-year database to 11,000 years. Together, the methyl bromide and methyl chloride records will provide strong measurement-based constraints on the natural variability of stratospheric halogens during the Holocene period. In addition, the methyl bromide record will provide insight into the correlation between methyl chloride and methane during the Holocene period due to common sources and sinks.
The rise in atmospheric carbon dioxide concentrations and associated climate changes make understanding the role of the ocean in large scale carbon cycle a priority. Geologic samples allow exploration of potential mechanisms for carbon dioxide drawdown during glacial periods through the use of geochemical proxies. Nitrogen and silicon isotope signatures from fossil diatoms (microscopic plants) are used to investigate changes in the physical supply and biological demand for nutrients (like nitrogen and silicon and carbon) in the Southern Ocean. The project will evaluate the use the nitrogen and silicon isotope proxies through a series of laboratory experiments and Southern Ocean field sampling. The results will provide quantification of real relationships between nitrogen and silicon isotopes and nutrient usage in the Southern Ocean and allow exploration of the role of other factors, including biological diversity, ice cover, and mixing, in altering the chemical signatures recorded by diatoms. Seafloor sediment samples will be used to evaluate how well the signal created in the water column is recorded by fossil diatoms buried in the seafloor. Improving the nutrient isotope proxies will allow for a more quantitative understanding of the role of polar biology in regulating natural variation in atmospheric carbon dioxide. The project will also result in the training of a graduate student and development of outreach materials targeting a broad popular audience.
This project seeks to test the fidelity of the diatom nitrogen and silicon isotope proxies, two commonly used paleoceanographic tools for investigating the role of the Southern Ocean biological pump in regulating atmospheric CO2 concentrations on glacial-interglacial timescales. Existing ground-truthing data, including culture experiments, surface sediment data and downcore reconstructions, all suggest that nutrient utilization is the primary driver of isotopic variation in the Southern Ocean. However, strong contribution of interspecific variation is implied by recent culture results. Moreover, field and laboratory studies present some contradictory results in terms of the relative importance of interspecific variation and of inferred post-depositional alteration of the nutrient isotope signals. Here, a first order test of the N and Si diatom nutrient isotope paleo-proxies, involving water column dissolved and particulate sampling and laboratory culturing of field-isolates, is proposed. Southern Ocean water, biomass, live diatoms and fossil diatom sampling will be conducted to investigate species and assemblage related variability in diatom nitrogen and silicon isotopes and their relationship to surface nutrient fields and early diagenesis. Access to fresh materials produced in an analogous environmental context to the sediments of primary interest is critical for making robust paleoceanographic reconstructions. Field sampling will occur along 175°W, transecting the Antarctic Circumpolar Current from the subtropics to the marginal ice edge. Collection of water, sinking/suspended particles and multi-core samples from 13 stations and 3 shipboard incubation experiments will be used to test four proposed hypotheses that together evaluate the significance of existing culture results and seek to allow the best use of diatom nutrient isotope proxies in evaluating the biological pump.
The research seeks to further quantify the input of atmospheric Fe into the sparsely sampled Southern Ocean (SO), specifically in the vicinity of the West Antarctic Peninsula (WAP) and adjacent continental shelf waters in the Drake Passage. This is typically a high nutrient low chlorophyll region where surface trace metal and primary productivity data are suggestive of Fe limitation. The WAP is characterized by high productivity in the austral summer, and at this time may be in the path of northern dust (aeolian Fe) input or subject to melt influx of elevated Fe accumulated from glacial and present-day sea ice sources.<br/><br/>Primary scientific questions are: (1) to what extent does atmospheric Fe contribute to nutrient cycles and ecosystem dynamics in the SO? (2) How is warming climate occurring in the WAP affecting the aerosol composition of the maritime atmosphere. The primary productivity of the Southern Ocean is key to understanding oceanic uptake of anthropogenic greenhouse gases such as carbon dioxide.
ABSTRACT<br/>Intellectual Merit:<br/>The high concentration of the major nutrients nitrate and phosphate is a fundamental characteristic of the Antarctic Zone in the Southern Ocean and is central to its role in global ocean fertility and the global carbon cycle. The isotopic composition of diatom-bound organic nitrogen is one of the best hopes for reconstructing the nutrient status of polar surface waters over glacial cycles, which in turn may hold the explanation for the decline in atmospheric carbon dioxide during ice ages. The PIs propose to generate detailed diatom-bound nitrogen isotope (δ15Ndb) records from high sedimentation rate cores from the Kerguelen Plateau. Because the cores were collected at relatively shallow seafloor depths, they have adequate planktonic and benthic foraminifera to develop accurate age models. The resulting data could be compared with climate records from Antarctic ice cores and other archives to investigate climate-related changes, including the major steps into and out of ice ages and the millennial-scale events that occur during ice ages and at their ends. The records generated in this project will provide a critical test of hypotheses for the cause of lower ice age CO2.<br/><br/>Broader impacts:<br/>This study will contribute to the goal of understanding ice ages and past CO2 changes, which both have broad implications for future climate. Undergraduates will undertake summer internships, with the possibility of extending their work into junior year projects and senior theses. In addition, the PI will lead modules for two Princeton programs for middle school teachers and will host a teacher for a six-week summer research project.
The temperature of the earth is controlled, in part, by heat trapping gases that include carbon dioxide, methane, and nitrous oxide. Despite their importance to climate, direct measurements of these gases in the atmosphere are limited to the last 50 years at best. Air trapped in ice cores extends those data back hundreds of millennia, and measurements of greenhouse gases in ice cores underpin much of our understanding of global chemical cycles relevant to modern climate change. Existing records vary in quality and detail. The proposed work fills gaps in our knowledge of nitrous oxide and carbon dioxide over the last 10,000 years. New measurements from an ice core from the South Pole will be used to determine what role changes in ocean and land based processes played in controlling these gases, which decreased during the first 2,000 years of this time period, then gradually increased toward the present. The work will address a major controversy over whether early human activities could have impacted the atmosphere, and provide data to improve mathematical models of the land-ocean-atmosphere system that predict how future climate change will impact the composition of the atmosphere and climate. <br/><br/>For nitrous oxide the work will improve on existing concentration records It will also develop measurement of the isotopomers of nitrous oxide and explore their utility for understanding aspects of the Holocene nitrous oxide budget. The primary goal is to determine if marine and/or terrestrial emissions of nitrous oxide change in response to changes in Holocene climate. A new Holocene isotopic record for carbon dioxide (stable carbon and oxygen isotopes), will improve the precision of existing records by a factor 5 and increase the temporal resolution. These data will be used to evaluate controversial hypotheses about why carbon dioxide concentrations changed in the Holocene and provide insight into millennial scale processes in the carbon cycle, which are not resolved by current isotopic data. A graduate student and post doc will receive advanced training during and the student and principle investigator will conduct outreach efforts targeted at local middle school students. The proposed work will also contribute to teaching efforts by the PI and to public lectures on climate and climate change. The results will be disseminated through publications, data archive, and the OSU Ice Core Lab web site. New analytical methods of wide utility will also be developed and documented.
Abstract<br/>During the Early Pliocene, 4.8 to 3.4 million years ago, warmer-than-present global temperatures resulted in a retreat of the Ross Ice Shelf and West Antarctic Ice Sheet. Understanding changes in ocean dynamics during times of reduced ice volume and increased temperatures in the geologic past will improve the predictive models for these conditions. The primary goal of the proposed research is to develop a new oxygen isotope record of Pliocene oceanographic conditions near the Antarctic continent. Oxygen isotope values from the carbonate tests of benthic foraminifera have become the global standard for paleo-oceanographic studies, but foraminifera are sparse in high-latitude sediment cores. This research will instead make use of oxygen isotope measurements from diatom silica preserved in a marine sediment core from the Ross Sea. The project is the first attempt at using this method and will advance understanding of global ocean dynamics and ice sheet-ocean interactions during the Pliocene. The project will foster the professional development of two early-career scientists and serve as training for graduate and undergraduate student researchers. The PIs will use this project to introduce High School students to polar/oceanographic research, as well as stable isotope geochemistry. Collaboration with teachers via NSTA and Polar Educators International will ensure the implementation of excellent STEM learning activities and curricula for younger students. <br/><br/>Technical Description<br/>This project will produce a high-resolution oxygen isotope record from well-dated diatom rich sediments that have been cross-correlated with global benthic foraminifera oxygen isotope records. Diatom silica frustules deposited during the Early Pliocene and recovered by the ANDRILL Project (AND-1B) provide ideal material for this objective. Diatomite unites in the AND-1B core are nearly pure, with little evidence of opal formation. A diatom oxygen isotope record from this core offers the potential to constrain lingering uncertainties about Ross Sea and Southern Ocean paleoceanography and Antarctic Ice Sheet history during a time of high atmospheric carbon dioxide concentrations. Specifically, oxygen isotope variations will be used to constrain changes in the water temperature and/or freshwater flux in the Pliocene Ross Sea. Diatom species data from the AND-1B core have been used to infer variations in the extent and duration of seasonal sea ice coverage, sea surface temperatures, and mid-water advection onto the continental shelf. However, the diatom oxygen isotope record will provide the first direct measure of water/oxygen isotope values at the Antarctic continental margin during the Pliocene.
The one place on Earth consistently showing increases in sea ice area, duration, and concentration is the Ross Sea in Antarctica. Satellite imagery shows about half of the Ross Sea increases are associated with changes in the austral fall, when the new sea ice is forming. The most pronounced changes are also located near polynyas, which are areas of open ocean surrounded by sea ice. To understand the processes driving the sea ice increase, and to determine if the increase in sea ice area is also accompanied by a change in ice thickness, this project will conduct an oceanographic cruise to the polynyas of the Ross Sea in April and May, 2017, which is the austral fall. The team will deploy state of the art research tools including unmanned airborne systems (UASs, commonly called drones), autonomous underwater vehicles (AUVs), and remotely operated underwater vehicles (ROVs). Using these tools and others, the team will study atmospheric, oceanic, and sea ice properties and processes concurrently. A change in sea ice production will necessarily change the ocean water below, which may have significant consequences for global ocean circulation patterns, a topic of international importance. All the involved institutions will be training students, and all share the goal of expanding climate literacy in the US, emphasizing the role high latitudes play in the Earth's dynamic climate.<br/><br/>The main goal of the project is to improve estimates of sea ice production and water mass transformation in the Ross Sea. The team will fully capture the spatial and temporal changes in air-ice-ocean interactions when they are initiated in the austral fall, and then track the changes into the winter and spring using ice buoys, and airborne mapping with the newly commissioned IcePod instrument system, which is deployed on the US Antarctic Program's LC-130 fleet. The oceanographic cruise will include stations in and outside of both the Terra Nova Bay and Ross Ice Shelf polynyas. Measurements to be made include air-sea boundary layer fluxes of heat, freshwater, and trace gases, radiation, and meteorology in the air; ice formation processes, ice thickness, snow depth, mass balance, and ice drift within the sea ice zone; and temperature, salinity, and momentum in the ocean below. Following collection of the field data, the team will improve both model parameterizations of air-sea-ice interactions and remote sensing algorithms. Model parameterizations are needed to determine if sea-ice production has increased in crucial areas, and if so, why (e.g., stronger winds or fresher oceans). The remote sensing validation will facilitate change detection over wider areas and verify model predictions over time. Accordingly this project will contribute to the international Southern Ocean Observing System (SOOS) goal of measuring essential climate variables continuously to monitor the state of the ocean and ice cover into the future.
Gases trapped in ice cores have revealed astonishing things about the greenhouse gas composition of the past atmosphere, including the fact that carbon dioxide concentrations never rose above 300 parts per million during the last 800,000 years. This places today's concentration of 400 parts per million in stark contrast. Furthermore, these gas records show that natural sources of greenhouse gas such as oceans and ecosystems act as amplifiers of climate change by increasing emissions of gases during warmer periods. Such amplification is expected to occur in the future, adding to the human-produced gas burden. The South Pole ice core will build upon these prior findings by expanding the suite of gases to include, for the first time, those potent trace gases that both trapped heat and depleted ozone during the past 40,000 years. The present project on inert gases and methane in the South Pole ice core will improve the dating of this crucial record, to unprecedented precision, so that the relative timing of events can be used to learn about the mechanism of trace gas production and destruction, and consequent climate change amplification. Ultimately, this information will inform predictions of future atmospheric chemical cleansing mechanisms and climate in the context of our rapidly changing atmosphere. This award also engages young people in the excitement of discovery and polar research, helping to entrain the next generations of scientists and educators. Education of graduate students, a young researcher (Buizert), and training of technicians, will add to the nation?s human resource base. <br/> <br/>This award funds the construction of the gas chronology for the South Pole 1500m ice core, using measured inert gases (d15N and d40Ar--Nitrogen and Argon isotope ratios, respectively) and methane in combination with a next-generation firn densification model that treats the stochastic nature of air trapping and the role of impurities on densification. The project addresses fundamental gaps in scientific understanding that limit the accuracy of gas chronologies, specifically a poor knowledge of the controls on ice-core d15N and the possible role of layering and impurities in firn densification. These gaps will be addressed by studying the gas enclosure process in modern firn at the deep core site. The work will comprise the first-ever firn air pumping experiment that has tightly co-located measurements of firn structural properties on the core taken from the same borehole.<br/><br/>The project will test the hypothesis that the lock-in horizon as defined by firn air d15N, CO2, and methane is structurally controlled by impermeable layers, which are in turn created by high-impurity content horizons in which densification is enhanced. Thermal signals will be sought using the inert gas measurements, which improve the temperature record with benefits to the firn densification modeling. Neon, argon, and oxygen will be measured in firn air and a limited number of deep core samples to test whether glacial period layering was enhanced, which could explain low observed d15N in the last glacial period. Drawing on separate volcanic and methane synchronization to well-dated ice cores to create independent ice and gas tie points, independent empirical estimates of the gas age-ice age difference will be made to check the validity of the firn densification model-inert gas approach to calculating the gas age-ice age difference. These points will also be used to test whether the anomalously low d15N seen during the last glacial period in east Antarctic ice cores is due to deep air convection in the firn, or a missing impurity dependence in the firn densification models. <br/><br/>The increased physical understanding gained from these studies, combined with new high-precision measurements, will lead to improved accuracy of the gas chronology of the South Pole ice core, which will enhance the overall science return from this gas-oriented core. This will lead to clarification of timing of atmospheric gas variations and temperature, and aid in efforts to understand the biogeochemical feedbacks among trace gases. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. Ozone-depleting substances will be measured in the South Pole ice core record, and a precise gas chronology will add value. Lastly, by seeking a better understanding of the physics of gas entrapment, the project aims to have an impact on ice-core science in general.
Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800,000 years. Previous field expeditions to the Allan Hills blue ice area, Antarctica, have recovered ice cores that date to one million years, the oldest ice cores yet recovered from Antarctica. These records have revealed that interglacial CO2 concentrations decreased by 800,000 years ago and that, in the warmer world 1 million years ago, CO2 and Antarctic temperature were linked as during the last 800,000 years. This project will return to the Allan Hills blue ice area to recover additional ice cores that date to 1 million years or older. The climate records developed from the drilled ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Our results will help answer questions about issues associated with anthropogenic change. These include the relationship between temperature change and the mass balance of Antarctic ice; precipitation and aridity variations associated with radiatively forced climate change; and the climate significance of sea ice extent. The project will entrain two graduate students and a postdoctoral scholar, and will conduct outreach including workshops to engage teachers in carbon science and ice cores.<br/><br/>Between about 2.8-0.9 million years ago, Earth's climate was characterized by 40,000-year cycles, driven or paced by changes in the tilt of Earth's spin axis. Much is known about the "40,000-year" world from studies of deep-sea sediments, but our understanding of climate change during this period is incomplete because we lack records of Antarctic climate and direct records of atmospheric greenhouse gas concentrations. We propose to address these issues by building on our recent studies of ancient ice from the Main Ice Field, Allan Hills, Antarctica. During previous field seasons we recovered ice extending, discontinuously, from 0.1-1.0 million years old. Ice was dated by measuring the 40Ar/38Ar (Argon) ratio of the trapped gases. Our discovery of million year-old ice demonstrates that there is gas-record-quality ice from the 40,000-year world in the Allan Hills Main Ice Field. We have identified two different sites, each overlying bedrock at ~ 200 m depth, that are attractive targets for coring ice dating to 1 million years and older. This project aims to core the ice at these two sites, re-occupy a previous site with million year-old ice and drill it down to the bedrock, and generate 10-20 short (~10-meter) cores in areas where our previous work and terrestrial meteorite ages suggest ancient surface ice. We plan to date the ice using the 40Ar/38Ar ages of trapped Argon. We also plan to characterize the continuity of our cores by measuring the deuterium and oxygen isotope ratios in the ice, methane, ratios of Oxygen and Argon to Nitrogen in trapped gas, the Nitrogen-15 isotope (d15N) of Nitrogen, and the Oxygen-18 isotope (d18O) of Oxygen. As the ice may be stratigraphically disturbed, these measurements will provide diagnostic properties for assessing the continuity of the ice-core records. Successful retrieval of ice older than one million years will provide the opportunity for follow-up work to measure the CO2 concentration and other properties within the ice to inform on the temperature history of the Allan Hills region, dust sources and source-area aridity, moisture sources, densification conditions, global average ocean temperature, and greenhouse gas concentrations. We will analyze the data in the context of leading hypotheses of the 40,000-year world and the Mid-Pleistocene Transition to the 100,000-year world. We expect to advance understanding of climate dynamics during these periods.
Climate change projections for this century suggest that the Southern Ocean will be the first region to be affected by seawater chemistry changes associated with enhanced carbon dioxide (CO2). Additionally, regions of the Southern Ocean are warming faster than any other locations on the planet. Ocean acidification and warming may act synergistically to impair the performance of different organisms by simultaneously increasing metabolic needs and reducing oxygen transport. However, no studies have measured krill acid-base regulation, metabolism, growth, or reproduction in the context of ocean acidification or synergistic 'greenhouse' conditions of elevated CO2 and temperature. In the present project, the investigators will conduct both short and prolonged exposure experiments at Palmer Station, Antarctica to determine the responses of Euphausia superba to elevated CO2 and temperature. The investigators will test hypotheses related to acid-base compensation and acclimation of various life stages of krill to elevated CO2 and temperature. Furthermore, they will determine these impacts on feeding, respiration, metabolism, growth, and reproduction.<br/><br/>The Antarctic krill, Euphausia superba, is a key component of Antarctic food webs as they are a primary food source for many of the top predators in the Southern Ocean including baleen whales, seals, penguins, and other sea birds. This project will determine the responses of Antarctic krill exposed to elevated CO2 and temperature and whether or not krill have the capacity to fully compensate under future ocean conditions. The proposed field effort will be complemented by an extensive broader impact effort focused on bringing marine science to both rural and urban high school students in the Midwest (Kansas). The core educational objectives of this proposal are to 1) instruct students about potential careers in marine science, 2) engage students and promote their interest in the scientific process, critical thinking, and applications of science, mathematics, and technology, and 3) and increase student and teacher awareness and understanding of the oceans and global climate change, with special focus on the Western Antarctic Peninsula region. Finally, this project will engage undergraduate and graduate students in the production, analysis, presentation and publication of datasets.
The waters of the Ross Sea continental shelf are among the most productive in the Southern Ocean, and likely comprise a significant oceanic sink for atmospheric carbon dioxide. In this region, primary production can be limited by the supply of dissolved iron to surface waters during the growing season.<br/>A range of biogeochemical measurements and activities are to be carried out in the late summer-autumnal- early winter time frame in the Ross Sea in order to better understand phytoplankton dynamics, along with carbon export. These biogeochemical parameters include elements such as Fe, C and S believed to be important to Antarctic ecosystems. As well as there being interest in the functioning of the Ross Sea ecosystem leading up to the impending polar night, there is also uncertainty as to what drives the biogeochemical redistribution undergone by micronutrient Fe species during the extensive sea-ice formation at this time of year.<br/><br/>The field setting and remote conditions that accompany the proposed study present several possibilities for STEM education and training at the K-12, undergraduate and graduate levels, as well as for public outreach. At the K-12 level, the project seeks to support the development of educational outreach materials targeting elementary and middle school students,<br/>pre-service science teachers, and in-service science teachers.
This project focuses on an important group of photosynthetic algae in the Southern Ocean (SO), diatoms, and the roles associated bacterial communities play in modulating their growth. Diatom growth fuels the SO food web and balances atmospheric carbon dioxide by sequestering the carbon used for growth to the deep ocean on long time scales as cells sink below the surface. The diatom growth is limited by the available iron in the seawater, most of which is not freely available to the diatoms but instead is tightly bound to other compounds. The nature of these compounds and how phytoplankton acquire iron from them is critical to understanding productivity in this region and globally. The investigators will conduct experiments to characterize the relationship between diatoms, their associated bacteria, and iron in open ocean and inshore waters. Experiments will involve supplying nutrients at varying nutrient ratios to natural phytoplankton assemblages to determine how diatoms and their associated bacteria respond to different conditions. This will provide valuable data that can be used by climate and food web modelers and it will help us better understand the relationship between iron, a key nutrient in the ocean, and the organisms at the base of the food web that use iron for photosynthetic growth and carbon uptake. The project will also further the NSF goals of training new generations of scientists and of making scientific discoveries available to the general public. The project supports early career senior investigators and the training of graduate and undergraduate students as well as outreach activities with middle school Girl Scouts in Rhode Island, inner city middle and high school age girls in Virginia, and middle school girls in Florida.<br/><br/>The project combines trace metal biogeochemistry, phytoplankton cultivation, and molecular biology to address questions regarding the production of iron-binding compounds and the role of diatom-bacterial interactions in this iron-limited region. Iron is an essential micronutrient for marine phytoplankton. Phytoplankton growth in the SO is limited by a lack of sufficient iron, with important consequences for carbon cycling and climate in this high latitude regime. Some of the major outstanding questions in iron biogeochemistry relate to the organic compounds that bind >99.9% of dissolved iron in surface oceans. The investigators' prior research in this region suggests that production of strong iron-binding compounds in the SO is linked to diatom blooms in waters with high nitrate to iron ratios. The sources of these compounds are unknown but the investigators hypothesize that they may be from bacteria, which are known to produce such compounds for their own use. The project will test three hypotheses concerning the production of these iron-binding compounds, limitations on the biological availability of iron even if present in high concentrations, and the roles of diatom-associated bacteria in these processes. Results from this project will provide fundamental information about the biogeochemical trigger, and biological sources and function, of natural strong iron-binding compound production in the SO, where iron plays a critical role in phytoplankton productivity, carbon cycling, and climate regulation.
Interest in the reduced alkalinity of high latitude waters under conditions of enhanced CO2 uptake from the atmosphere have been the impetus of numerous recent studies of bio-stressors in the polar marine environment. The project seeks to improve our understanding of the variance of coastal Southern Ocean carbonate species (CO2 system), its diurnal and inter-annual variability, by acquiring autonomous, high frequency observations from an Antarctic coastal mooring(s). <br/><br/>A moored observing system co-located within the existing Palmer LTER array will measure pH, CO2 partial pressure, temperature, salinity and dissolved oxygen with 3-hour frequency in this region of the West Antarctic Peninsula continental shelf. Such observations will help estimate the dominant physical and biological controls on the seasonal variations in the CO2 system in coastal Antarctic waters, including the sign, seasonality and the flux of the net annual air-sea exchange of carbon dioxide. The Palmer LTER site is experiencing rapid ecological change in the West Antarctic Peninsula, a region that is warming at rates faster than any other region of coastal Antarctica.
This award supports a project to obtain the first set of isotopic-based provenance data from the WAIS divide ice core. A lack of data from the WAIS prevents even a basic knowledge of whether different sources of dust blew around the Pacific and Atlantic sectors of the southern latitudes. Precise isotopic measurements on dust in the new WAIS ice divide core are specifically warranted because the data will be synergistically integrated with other high frequency proxies, such as dust concentration and flux, and carbon dioxide, for example. Higher resolution proxies will bridge gaps between our observations on the same well-dated, well-preserved core. The intellectual merit of the project is that the proposed analyses will contribute to the WAIS Divide Project science themes. Whether an active driver or passive recorder, dust is one of the most important but least understood components of regional and global climate. Collaborative and expert discussion with dust-climate modelers will lead to an important progression in understanding of dust and past atmospheric circulation patterns and climate around the southern latitudes, and help to exclude unlikely air trajectories to the ice sheets. The project will provide data to help evaluate models that simulate the dust patterns and cycle and the relative importance of changes in the sources, air trajectories and transport processes, and deposition to the ice sheet under different climate states. The results will be of broad interest to a range of disciplines beyond those directly associated with the WAIS ice core project, including the paleoceanography and dust- paleoclimatology communities. The broader impacts of the project include infrastructure and professional development, as the proposed research will initiate collaborations between LDEO and other WAIS scientists and modelers with expertise in climate and dust. Most of the researchers are still in the early phase of their careers and hence the project will facilitate long-term relationships. This includes a graduate student from UMaine, an undergraduate student from Columbia University who will be involved in lab work, in addition to a LDEO Postdoctoral scientist, and possibly an additional student involved in the international project PIRE-ICETRICS. The proposed research will broaden the scientific outlooks of three PIs, who come to Antarctic ice core science from a variety of other terrestrial and marine geology perspectives. Outreach activities include interaction with the science writers of the Columbia's Earth Institute for news releases and associated blog websites, public speaking, and involvement in an arts/science initiative between New York City's arts and science communities to bridge the gap between scientific knowledge and public perception.
Taylor/0944348<br/><br/>This award supports renewal of funding of the WAIS Divide Science Coordination Office (SCO). The Science Coordination Office (SCO) was established to represent the research community and facilitates the project by working with support organizations responsible for logistics, drilling, and core curation. During the last five years, 26 projects have been individually funded to work on this effort and 1,511 m of the total 3,470 m of ice at the site has been collected. This proposal seeks funding to continue the SCO and related field operations needed to complete the WAIS Divide ice core project. Tasks for the SCO during the second five years include planning and oversight of logistics, drilling, and core curation; coordinating research activities in the field; assisting in curation of the core in the field; allocating samples to individual projects; coordinating the sampling effort; collecting, archiving, and distributing data and other information about the project; hosting an annual science meeting; and facilitating collaborative efforts among the research groups. The intellectual merit of the WAIS Divide project is to better predict how human-caused increases in greenhouse gases will alter climate requires an improved understanding of how previous natural changes in greenhouse gases influenced climate in the past. Information on previous climate changes is used to validate the physics and results of climate models that are used to predict future climate. Antarctic ice cores are the only source of samples of the paleo-atmosphere that can be used to determine previous concentrations of carbon dioxide. Ice cores also contain records of other components of the climate system such as the paleo air and ocean temperature, atmospheric loading of aerosols, and indicators of atmospheric transport. The WAIS Divide ice core project has been designed to obtain the best possible record of greenhouse gases during the last glacial cycle (last ~100,000 years). The site was selected because it has the best balance of high annual snowfall (23 cm of ice equivalent/year), low dust Antarctic ice that does not compromise the carbon dioxide record, and favorable glaciology. The main science objectives of the project are to investigate climate forcing by greenhouse gases, initiation of climate changes, stability of the West Antarctic Ice Sheet, and cryobiology in the ice core. The project has numerous broader impacts. An established provider of educational material (Teachers? Domain) will develop and distribute web-based resources related to the project and climate change for use in K?12 classrooms. These resources will consist of video and interactive graphics that explain how and why ice cores are collected, and what they tell us about future climate change. Members of the national media will be included in the field team and the SCO will assist in presenting information to the general public. Video of the project will be collected and made available for general use. Finally, an opportunity will be created for cryosphere students and early career scientists to participate in field activities and core analysis. An ice core archive will be available for future projects and scientific discoveries from the project can be used by policy makers to make informed decisions.
Severinghaus/0839031 <br/><br/>This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).<br/><br/>This award supports a project to develop a precise gas-based chronology for an archive of large-volume samples of the ancient atmosphere, which would enable ultra-trace gas measurements that are currently precluded by sample size limitations of ice cores. The intellectual merit of the proposed work is that it will provide a critical test of the "clathrate hypothesis" that methane clathrates contributed to the two abrupt atmospheric methane concentration increases during the last deglaciation 15 and 11 kyr ago. This approach employs large volumes of ice (>1 ton) to measure carbon-14 on past atmospheric methane across the abrupt events. Carbon-14 is an ideal discriminator of fossil sources of methane to the atmosphere, because most methane sources (e.g., wetlands, termites, biomass burning) are rich in carbon-14, whereas clathrates and other fossil sources are devoid of carbon-14. The proposed work is a logical extension to Taylor Glacier, Antarctica, of an approach pioneered at the margin of the Greenland ice sheet over the past 7 years. The Greenland work found higher-than-expected carbon-14 values, likely due in part to contaminants stemming from the high impurity content of Greenland ice and the interaction of the ice with sediments from the glacier bed. The data also pointed to the possibility of a previously unknown process, in-situ cosmogenic production of carbon-14 methane (radiomethane) in the ice matrix. Antarctic ice in Taylor Glacier is orders of magnitude cleaner than the ice at the Greenland site, and is much colder and less stratigraphically disturbed, offering the potential for a clear resolution of this puzzle and a definitive test of the cosmogenic radiomethane hypothesis. Even if cosmogenic radiomethane in ice is found, it still may be possible to reconstruct atmospheric radiomethane with a correction enabled by a detailed understanding of the process, which will be sought by co-measuring carbon-14 in carbon monoxide and carbon dioxide. The broader impacts of the proposed work are that the clathrate test may shed light on the stability of the clathrate reservoir and its potential for climate feedbacks under human-induced warming. Development of Taylor Glacier as a "horizontal ice core" would provide a community resource for other researchers. Education of one postdoc, one graduate student, and one undergraduate, would add to human resources. This award has field work in Antarctica.
The continental shelf region west of the Antarctic Peninsula has recently undergone dramatic changes and ecosystem shifts, and the community of organisms that live in, or feed off, the sea floor sediments is being impacted by species invasions from the north. Previous studies of these sediments indicate that this community may consume much more of the regional productivity than previously estimated, suggesting that sediments are a rich and important component of this ecosystem and one that may be ripe for dramatic change. Furthermore, under richer sediment conditions, iron is mobilized and released back to the water column. Since productivity in this ecosystem is thought to be limited by the availability of iron, increased rates of iron release from these sediments could stimulate productivity and promote greater overall ecosystem change. In this research, a variety of sites across the shelf region will be sampled to accurately evaluate the role of sediments in consuming ecosystem productivity and to estimate the current level of iron release from the sediments. This project will provide a baseline set of sediment results that will present a more complete picture of the west Antarctic shelf ecosystem, will allow for comparison with water column measurements and for evaluation of the fundamental workings of this important ecosystem. This is particularly important since high latitude systems may be vulnerable to the effects of climate fluctuations. Both graduate and undergraduate students will be trained. Presentations will be made at scientific meetings, at other universities, and at outreach events. A project web site will present key results to the public and explain how this new information improves understanding of Antarctic ecosystems. <br/><br/><br/>Technical Description of Project: <br/>In order to determine the role of sediments within the west Antarctic shelf ecosystem, this project will determine the rates of sediment organic matter oxidation at a variety of sites across the Palmer Long Term Ecosystem Research (LTER) study region. To estimate the rates of release of iron and manganese from the sediments, these same sites will be sampled for detailed vertical distributions of the concentrations of these metals both in the porewaters and in important mineral phases. Since sediment sampling will be done at LTER sites, the sediment data can be correlated with the rich productivity data set from the LTER. In detail, the project: a) will determine the rates of oxygen consumption, organic carbon oxidation, nutrient release, and iron mobilization by shelf sediments west of the Antarctic Peninsula; b) will investigate the vertical distribution of diagenetic reactions within the sediments; and c) will assess the regional importance of these sediment rates. Sediment cores will be used to determine sediment-water fluxes of dissolved oxygen, total carbon dioxide, nutrients, and the vertical distributions of these dissolved compounds, as well as iron and manganese in the pore waters. Bulk sediment properties of porosity, organic carbon and nitrogen content, carbonate content, biogenic silica content, and multiple species of solid-phase iron, manganese, and sulfur species will also be determined. These measurements will allow determination of total organic carbon oxidation and denitrification rates, and the proportion of aerobic versus anaerobic respiration at each site. Sediment diagenetic modeling will link the processes of organic matter oxidation to metal mobilization. Pore water and solid phase iron and manganese distributions will be used to model iron diagenesis in these sediments and to estimate the iron flux from the sediments to the overlying waters. Finally, the overall regional average and distribution of the sediment processes will be compared with the distributions of seasonally averaged chlorophyll biomass and productivity.
Aydin/1043780<br/>This award supports the analysis of the trace gas carbonyl sulfide (COS) in a deep ice core from West Antarctic Ice Sheet Divide (WAIS-D), Antarctica. COS is the most abundant sulfur gas in the troposphere and a precursor of stratospheric sulfate. It has a large terrestrial COS sink that is tightly coupled to the photosynthetic uptake of atmospheric carbon dioxide (CO2). The primary goal of this project is to develop high a resolution Holocene record of COS from the WAIS-D 06A ice core. The main objectives are 1) to assess the natural variability of COS and the extent to which its atmospheric variability was influenced by climate variability, and 2) to examine the relationship between changes in atmospheric COS and CO2. This project also includes low-resolution sampling and analysis of COS from 10,000-30,000 yrs BP, covering the transition from the Last Glacial Maximum into the early Holocene. The goal of this work is to assess the stability of COS in ice core air over long time scales and to establish the COS levels during the last glacial maximum and the magnitude of the change between glacial and interglacial conditions. The results of this work will be disseminated via peer-review publications and will contribute to environmental assessments such as the WMO Stratospheric Ozone Assessment and IPCC Climate Assessment. This project will support a PhD student and undergraduate researcher in the Department of Earth System Science at the University of California, Irvine, and will create summer research opportunities for undergraduates from non-research active Universities.
This award supports a project to use the Taylor Glacier, Antarctica, ablation zone to collect ice samples for a range of paleoenvironmental studies. A record of carbon-14 of atmospheric methane (14CH4) will be obtained for the last deglaciation and the Early Holocene, together with a supporting record of CH4 stable isotopes. In-situ cosmogenic 14C content and partitioning of 14C between different species (14CH4, C-14 carbon monoxide (14CO) and C-14 carbon dioxide (14CO2)) will be determined with unprecedented precision in ice from the surface down to ~67 m. Further age-mapping of the ablating ice stratigraphy will take place using a combination of CH4, CO2, δ18O of oxygen gas and H2O stable isotopes. High precision, high-resolution records of CO2, δ13C of CO2, nitrous oxide (N2O) and N2O isotopes will be obtained for the last deglaciation and intervals during the last glacial period. The potential of 14CO2 and Krypton-81 (81Kr) as absolute dating tools for glacial ice will be investigated. The intellectual merit of proposed work includes the fact that the response of natural methane sources to continuing global warming is uncertain, and available evidence is insufficient to rule out the possibility of catastrophic releases from large 14C-depleted reservoirs such as CH4 clathrates and permafrost. The proposed paleoatmospheric 14CH4 record will improve our understanding of the possible magnitude and timing of CH4 release from these reservoirs during a large climatic warming. A thorough understanding of in-situ cosmogenic 14C in glacial ice (production rates by different mechanisms and partitioning between species) is currently lacking. Such an understanding will likely enable the use of in-situ 14CO in ice at accumulation sites as a reliable, uncomplicated tracer of the past cosmic ray flux and possibly past solar activity, as well as the use of 14CO2 at both ice accumulation and ice ablation sites as an absolute dating tool. Significant gaps remain in our understanding of the natural carbon cycle, as well as in its responses to global climate change. The proposed high-resolution, high-precision records of δ13C of CO2 would provide new information on carbon cycle changes both during times of rising CO2 in a warming climate and falling CO2 in a cooling climate. N2O is an important greenhouse gas that increased by ~30% during the last deglaciation. The causes of this increase are still largely uncertain, and the proposed high-precision record of N2O concentration and isotopes would provide further insights into N2O source changes in a warming world. The broader impacts of proposed work include an improvement in our understanding of the response of these greenhouse gas budgets to global warming and inform societally important model projections of future climate change. The continued age-mapping of Taylor Glacier ablation ice will add value to this high-quality, easily accessible archive of natural environmental variability. Establishing 14CO as a robust new tracer for past cosmic ray flux would inform paleoclimate studies and constitute a valuable contribution to the study of the societally important issue of climate change. The proposed work will contribute to the development of new laboratory and field analytical systems. The data from the study will be made available to the scientific community and the broad public through the NSIDC and NOAA Paleoclimatology data centers. 1 graduate student each will be trained at UR, OSU and SIO, and the work will contribute to the training of a postdoc at OSU. 3 UR undergraduates will be involved in fieldwork and research. The work will support a new, junior UR faculty member, Petrenko. All PIs have a strong history of and commitment to scientific outreach in the forms of media interviews, participation in filming of field projects, as well as speaking to schools and the public about their research, and will continue these activities as part of the proposed work. This award has field work in Antarctica.
Hemming, Sidney R.; Barbeau, David; Barbeau, David Jr
No dataset link provided
Intellectual Merit: <br/>Recent geochemical, sequence stratigraphic, and integrated investigations of marine strata from several continental margins and ocean basins suggest that ephemeral ice sheets may have existed on Antarctica during parts of the Cretaceous and early Paleogene. However, atmospheric carbon dioxide estimates for this time are as much as four times modern levels. With such greenhouse conditions, the presence of Antarctic ice sheets would imply that our current understanding of Earth?s climate system, and specifically the interpreted thresholds of Antarctic glaciation and deglaciation should be reconsidered. The proposed research will compare the quantity and provenance of Cretaceous sediments in the Larsen basin of the eastern Antarctic Peninsula with the exhumation chronology and composition of potential sediment source terranes on the peninsula and in adjacent regions. New outcrop stratigraphic analyses with improvements in the age models from radioisotopic approaches will be integrated to determine the amount of detrital sediment fluxed to the Larsen basin between key chronostratigraphic surfaces. Microtextural analysis of quartz sand and silt grains will help determine whether the Larsen basin detrital sediment originated from glacial weathering. These preliminary results will test the viability of the proposed approach to assess the controversial Cretaceous Antarctic glaciation hypothesis.<br/><br/>Broader impacts: <br/>The proposed work will partially support a PhD, a MSc, and three undergraduate students at the University of South Carolina. The PIs will publicize this work through volunteer speaking engagements and the development of videos and podcasts. They also commit to prompt publication of the results and timely submission of data to archives. The development/improvement of the Larsen basin age model will benefit ongoing research in paleobiology, paleoclimate and biogeography. Development of the glauconite K-Ar and Rb-Sr chronometers could be an important outcome beyond the direct scope of the proposed research.
Severinghaus/0944343<br/><br/>This award supports a project to develop both a record of past local temperature change at the WAIS Divide site, and past mean ocean temperature using solubility effects on atmospheric krypton and xenon. The two sets of products share some of the same measurements, because the local temperature is necessary to make corrections to krypton and xenon, and thus synergistically support each other. Further scientific synergy is obtained by the fact that the mean ocean temperature is constrained to vary rather slowly, on a 1000-yr timescale, due to the mixing time of the deep ocean. Thus rapid changes are not expected, and can be used to flag methodological problems if they appear in the krypton and xenon records. The mean ocean temperature record produced will have a temporal resolution of 500 years, and will cover the entire 3400 m length of the core. This record will be used to test hypotheses regarding the cause of atmospheric carbon dioxide (CO2) variations, including the notion that deep ocean stratification via a cold salty stagnant layer caused atmospheric CO2 drawdown during the last glacial period. The local surface temperature record that results will synergistically combine with independent borehole thermometry and water isotope records to produce a uniquely precise and accurate temperature history for Antarctica, on a par with the Greenland temperature histories. This history will be used to test hypotheses that the ?bipolar seesaw? is forced from the North Atlantic Ocean, which makes a specific prediction that the timing of Antarctic cooling should slightly lag abrupt Greenland warming. The WAIS Divide ice core is expected to be the premier atmospheric gas record of the past 100,000 years for the foreseeable future, and as such, making this set of high precision noble gas measurements adds value to the other gas records because they all share a common timescale and affect each other in terms of physical processes such as gravitational fractionation. Broader impact of the proposed work: The clarification of timing of atmospheric CO2 and Antarctic surface temperature, along with deep ocean temperature, will aid in efforts to understand the feedbacks among CO2, temperature, and ocean circulation. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. A deeper understanding of the mechanism of deglaciation, and the role of atmospheric CO2, will go a long way towards clarifying a topic that has become quite confused in the public mind in the public debate over climate change. Elucidating the role of the bipolar seesaw in ending glaciations and triggering CO2 increases may also provide an important warning that this represents a potential positive feedback, not currently considered by IPCC. Education of one graduate student, and training of one technician, will add to the nation?s human resource base. Outreach activities will be enhanced and will to continue to entrain young people in discovery, and excitement will enhance the training of the next generation of scientists and educators.
Intellectual Merit: The Diapycnal and Isopycnal Mixing Experiment in the Southern Ocean (DIMES) is a study of ocean mixing in the Antarctic Circumpolar Current (ACC) which runs west to east all around the continent of Antarctica, south of the other continents. This current system is somewhat of a barrier to transport of heat, carbon dioxide and other important ocean constituents between the far south and the rest of the ocean, and mixing processes play an important role in those transports. DIMES is a multi-investigator cooperative project, led by physical oceanographers in the U.S. and in the U.K. A passive tracer and an array of sub-surface floats were deployed early in 2009 more than 2000 km west of Drake Passage on a surface of constant density about 1500 m deep between the Sub Antarctic Front and the Polar Front of the ACC. In early 2010 a U.S. led research cruise sampled the tracer, turbulence levels, and the velocity and density profiles that govern the generation of that turbulence, and additional U.K. led research cruises in 2011 and 2012 continue this sampling as the tracer has made its way through Drake Passage, into the Scotia Sea, and over the North Scotia Ridge, a track of more than 3000 km. The initial results show that diapycnal, i.e., vertical, mixing west of Drake Passage where the bottom is relatively smooth is no larger than in most other regions of the open ocean. In contrast, there are strong velocity shears and intense turbulence levels over the rough topography in Drake Passage and diapycnal diffusivity of the tracer more than 10 times larger in Drake Passage and to the east than west of Drake Passage.<br/><br/>The DIMES field program continues with the U.S. team collecting new velocity and turbulence data in the Scotia Sea. It is anticipated that the tracer will continue passing through the Scotia Sea until at least early 2014. The U.K. partners have scheduled sampling of the tracer on cruises at the North Scotia Ridge and in the eastern and central Scotia Sea in early 2013 and early 2014. The current project will continue the time series of the tracer at Drake Passage on two more U.S. led cruises, in late 2012 and late 2013. Trajectories through the Scotia Sea estimated from the tracer observations, from neutrally buoyant floats, and from numerical models will be used to accurately estimate mixing rates of the tracer and to locate where the mixing is concentrated. During the 2013 cruise the velocity and turbulence fields along high-resolution transects along the ACC and across the ridges of Drake Passage will be measured to see how far downstream of the ridges the mixing is enhanced, and to test the hypothesis that mixing is enhanced by breaking lee waves generated by flow over the rough topography.<br/><br/>Broader Impacts: DIMES (see web site at http://dimes.ucsd.edu) involves many graduate students and post-doctoral researchers. Two graduate students, who would become expert in ocean turbulence and the processes generating it, will continue be trained on this project. The work in DIMES is ultimately motivated by the need to understand the overturning circulation of the global ocean. This circulation governs the transport and storage of heat and carbon dioxide within the huge oceanic reservoir, and thus plays a major role in regulating the earth?s climate. Understanding the circulation and how it changes in reaction to external forces is necessary to the understanding of past climate change and of how climate might change in the future, and is therefore of great importance to human well-being. The data collected and analyzed by the DIMES project will be assembled and made publicly available at the end of the project.<br/><br/>The DIMES project is a process experiment sponsored by the U.S. CLIVAR (Climate variability and predictability) program.
This award supports a project to create new, unprecedented high-resolution atmospheric carbon dioxide (CO2) records spanning intervals of abrupt climate changes during the last glacial period and the early Holocene. The proposed work will utilize high-precision methods on existing ice cores from high accumulation sites such as Siple Dome and Byrd Station, Antarctica and will improve our understanding of how fast CO2 can change naturally, how its variations are linked with climate, and, combined with a coupled climate-carbon cycle model, will clarify the role of terrestrial and oceanic processes during past abrupt changes of climate and CO2. The intellectual merit of this work is that CO2 is the most important anthropogenic greenhouse gas and understanding its past variations, its sources and sinks, and how they are linked to climate change is a major goal of the climate research community. This project will produce high quality data on centennial to multi-decadal time scales. Such high-resolution work has not been conducted before because of insufficient analytical precision, slow experimental procedures in previous studies, or lack of available samples. The proposed research will complement future high-resolution studies from WAIS Divide ice cores and will provide ice core CO2 records for the target age intervals, which are in the zone of clathrate formation in the WAIS ice cores. Clathrate hydrate is a phase composed of air and ice. CO2 analyses have historically been less precise in clathrate ice than in ?bubbly ice? such as the Siple Dome ice core that will be analyzed in the proposed project. High quality, high-resolution results from specific intervals in Siple Dome that we propose to analyze will provide important data for verifying the WAIS Divide record. The broader impacts of the work are that current models show a large uncertainty of future climate-carbon cycle interactions. The results of this proposed work will be used for testing coupled carbon cycle-climate models and may contribute to reducing this uncertainty. The project will contribute to the training of several undergraduate students and a full-time technician. Both will learn analytical techniques and the basic science involved. Minorities and female students will be highly encouraged to participate in this project. Outreach efforts will include participation in news media interviews, at a local festival celebrating art, science and technology, and giving seminar presentations in the US and foreign countries. The OSU ice core laboratory has begun a collaboration with a regional science museum and is developing ideas to build an exhibition booth to make public be aware of climate change and ice core research. All data will be archived at the National Snow and Ice Data Center and at other similar archives per the OPP data policy.
Brook 0739766<br/><br/>This award supports a project to create a 25,000-year high-resolution record of atmospheric CO2 from the WAIS Divide ice core. The site has high ice accumulation rate, relatively cold temperatures, and annual layering that should be preserved back to 40,000 years, all prerequisite for preserving a high quality, well-dated CO2 record. The new record will be used to examine relationships between Antarctic climate, Northern Hemisphere climate, and atmospheric CO2 on glacial-interglacial to centennial time scales, at unprecedented temporal resolution. The intellectual merit of the proposed work is simply that CO2 is the most important greenhouse gas that humans directly impact, and understanding the sources, sinks, and controls of atmospheric CO2 is a major goal for the global scientific community. Accurate chronology and detailed records are primary requirements for developing and testing models that explain and predict CO2 variability. The proposed work has several broader impacts. It contributes to the training of a post-doctoral researcher, who will transfer to a research faculty position during the award period and who will participate in graduate teaching and guest lecture in undergraduate courses. An undergraduate researcher will gain valuable lab training and conduct independent research. Bringing the results of<br/>the proposed work to the classroom will enrich courses taught by the PI. Outreach efforts will expose pre-college students to ice core research. The proposed work will enhance the laboratory facilities for ice core research at OSU, insuring that the capability for CO2 measurements exists for future projects. All data will be archived at the National Snow and Ice Data Center and other similar archives, per OPP policy. Highly significant results will be disseminated to the news media through OSU?s very effective News and Communications group. Carbon dioxide is the most important greenhouse gas that humans are directly changing. Understanding how CO2 and climate are linked on all time scales is necessary for predicting the future behavior of the carbon cycle and climate system, primarily to insure that the appropriate processes are represented in carbon cycle/climate models. Part of the proposed work emphasizes the relationship of CO2 and abrupt climate change. Understanding how future abrupt change might impact the carbon cycle is an important issue for society.
Convincing evidence now confirms that polar regions are changing rapidly in response to human activities. Changes in sea ice extent and thickness will have profound implications for productivity, food webs and carbon fluxes at high latitudes, since sea ice biota are a significant source of biogenic matter for the ecosystem. While sea ice is often thought to be a barrier to gas exchange between the ocean and the atmosphere, it more likely functions as a source or sink for climate-active gases such as carbon dioxide and ozone-depleting organohalogens, due in part to activities of microbes embedded in the sea ice matrix. This project brings together experienced US and Swedish investigators to examine the controls by sea-ice biota on the production and degradation of key climate-active gases in the Pacific sector of the Southern Ocean. We hypothesize that 1) the physical properties of the sea-ice environment will determine the community structure and activities of the sea ice biota; 2) the productivity, biomass, physiological state and species composition of ice algae will determine the production of specific classes of organic carbon, including organohalogens; 3) heterotrophic co-metabolism within the ice will break down these compounds to some extent, depending on the microbial community structure and productivity, and 4) the sea ice to atmosphere fluxes of CO2 and organohalogens will be inversely related. This project will build close scientific collaborations between US and Swedish researchers and also train young scientists, including members of underrepresented groups. Dissemination of results will include the scientific literature, and public outreach venues including interactions with a PolarTrec teacher.
Rising atmospheric carbon dioxide concentrations have resulted in greater oceanic uptake of anthropogenic carbon dioxide. Elevated partial pressure of carbon dioxide can impact marine organisms both via decreased carbonate saturation that affects calcification rates and via disturbance to acid-base (metabolic) physiology. Pteropod molluscs (Thecosomata) form shells made of aragonite, a type of calcium carbonate that is highly soluble, suggesting that these organisms may be particularly sensitive to increasing carbon dioxide and reduced carbonate ion concentration. Thecosome pteropods, which dominate the calcium carbonate export south of the Antarctic Polar Front, will be the first major group of marine calcifying organisms to experience carbonate undersaturation within parts of their present-day geographical ranges as a result of anthropogenic carbon dioxide. An unusual, co-evolved relationship between thecosomes and their specialized gymnosome predators provides a unique backdrop against which to assess the physiological and ecological importance of elevated partial pressure of carbon dioxide. Pteropods are functionally important components of the Antarctic ecosystem with potential to influence phytoplankton stocks, carbon export, and dimethyl sulfide levels that, in turn, influence global climate through ocean-atmosphere feedback loops. The research will quantify the impact of elevated carbon dioxide on a dominant aragonitic pteropod, Limacina helicina, and its specialist predator, the gymnosome Clione antarctica, in the Ross Sea through laboratory experimentation. Results will be disseminated broadly to enhance scientific understanding in this field. The project involves collaboration between researchers at a predominantly undergraduate institution with a significant enrollment of students that are typically underrepresented in the research environment (California State University San Marcos - CSUSM) and at a Ph.D.-granting institution (University of Rhode Island - URI). The program will promote education and learning through the joint education of undergraduate students and graduate students at CSUSM and URI as part of a research team, as well as through the teaching activities of the principal investigators. Dr. Keating, CSUSM professor of science education, will participate in the McMurdo fieldwork and lead the outreach opportunities for the project.
The proposed project will expand the suite of observations and lengthen the existing time series of underway surface dissolved carbon dioxide (pCO2) measurements transects across the Drake Passage on the R/VIB L.M. Gould. The additional observations include oxygen, nutrients and total CO2 (TCO2) concentrations, and the 13C to 12C ratio of TCO2. The continued and expanded time series will contribute towards two main scientific goals: the quantification of the spatial and temporal variability and the trends of surface carbon dioxide species in four major water mass regimes in the Drake Passage, and the understanding of the dominant processes and changes in those processes that contribute to the variability in surface pCO2 and the resulting air-sea flux of CO2 in the Drake Passage. The expanded program will also include the analysis of the 14C/12C of TCO2 and the specific study of the observations on one short wintertime cruise, with the objective of testing the hypothesis that the dissolved carbon dioxide in surface waters of the Drake Passage is determined by the degree of winter mixing. This is of special significance in light of two scenarios that may be affecting the ventilation of Southern Ocean deep water now and in the future: a decrease in water column stratification with the observations of higher zonal winds, or an increase in stratification due to higher precipitation and warming from climate change. If winter mixing determines the mean annual pCO2 in the Drake Passage, the increasing trend in atmospheric pCO2 should have little effect on sea surface pCO2.
The objectives of this proposal are to investigate the controls on the large-scale distribution and production of the two major bloom-forming phytoplankton taxa in the Southern Ocean, diatoms and Phaeocystis Antarctica. These two groups, through their involvement in the biogeochemical cycles of carbon, sulfur and nutrient elements, may have played important roles in the climate variations of the late Quaternary, and they also may be key players in future environmental change. A current paradigm is that irradiance and iron availability drive phytoplankton dynamics in the Southern Ocean. Recent work, however, suggests that carbon dioxide (CO2) concentrations may also be important in structuring algal assemblages, due to species-specific differences in the physiology. This proposal examines the interactive effects of iron, light and CO2 on the physiology, ecology and relative dominance of Phaeocystis and diatoms in the Southern Ocean. The Ross Sea is an ideal system in which to investigate the environmental factors that regulate the distribution and production of these two algal groups, since it is characterized by seasonal blooms of both P. Antarctica and diatoms that are typically separated in both space and time. This study will take the form of an interdisciplinary investigation that includes a field survey and statistical analysis of algal assemblage composition, iron, mixed layer depth, and CO2 levels in the southern Ross Sea, coupled with shipboard experiments to examine the response of diatom and P. Antarctica assemblages to high and low levels of iron, light and CO2 during spring and summer. <br/>This project will provide information on some of the major factors controlling the production and distribution of the two major bloom forming phytoplankton in the Southern Ocean and the related biogeochemical cycling of carbon, sulfur and nutrient elements. The results may ultimately advance the ability to predict how the Southern Ocean will be affected by and possibly modulate future climate change. This project will also make significant educational contributions at several levels, including the planned research involvement of graduate and undergraduate students, postdoctoral associates, a student teacher, and community outreach and educational activities. A number of activities are planned to interface the project with K-12 education. Presentations will be made at local schools to discuss the research and events of the research cruise. During the cruise there will be daily interactive email contact with elementary classrooms. Established websites will be used to allow students to learn about the ongoing research, and to allow researchers to communicate with students through text and downloaded images.
This proposal is for the continuation and expansion of an underway program on the R/V Laurence M. Gould to measure dissolved carbon dioxide gas (pCO2) along with occasional total carbon dioxide (TCO2) in surface waters on transects of Drake Passage. The added observations include dissolved oxygen, as well as nutrient and carbon-13. The proposed work is similar to the underway measurement program made aboard R/V Nathaniel B. Palmer, and complements similar surface temperature and current data.<br/>The Southern Ocean is an important component of the global carbon budget. Low surface temperatures with consequently low vertical stability, ice formation, and high winds produce a very active environment for the exchange of gaseous carbon dioxide between the atmospheric and oceanic reservoirs. The Drake Passage is the narrowest point through which the Antarctic Circumpolar Current and its associated fronts must pass, and is the most efficient location for the measurement of latitudinal gradients of gas exchange. The generated time series will contribute towards two scientific goals: the quantification of the spatial and temporal variability and trends of surface carbon dioxide, oxygen, nutrients and C-13, and an understanding of the dominant processes that contribute to the observed variability.
9528807 Gordon The proposed project is part of a multi-institutional integrated study of the outflow of newly formed bottom water from the Weddell Sea and its dispersion into the South Atlantic Ocean. It builds upon earlier successful studies of the inflow of intermediate water masses into the Eastern Weddell Sea, their modification within the Weddell Gyre, and their interaction with bottom water formation processes in the western Weddell Sea. The study is called Deep Ocean Ventilation Through Antarctic Intermediate Layers (DOVETAIL) and includes six components involving hydrographic measurements, natural tracer experiments, and modeling studies. The study will be centered east of the Drake Passage where water masses from the Weddell Sea and the Scotia Sea come together in the Weddell-Scotia Confluence, and will be carried out in cooperation with the national antarctic programs of Germany and Spain. This particular component concerns observations of the temperature and salinity structure, as well as the chemical nature of the water column in the confluence region. The study has four related objectives. The first is to assess the quantity and the physical and chemical characteristics of Weddell Sea source waters for the confluence. The second is to describe the dominant processes associated with spreading and sinking of dense antarctic waters within the Weddell-Scotia Confluence. The third is to estimate the ventilation rate of the world ocean, and the fourth is to estimate seasonal fluctuations in the regional ocean transport and hydrographic structure and to assess the likely influence of seasonal to interannual variability on rates of ventilation by Weddell Sea waters. Ventilation of the deep ocean -- the rising of sub-surface water masses to the surface to be recharged with atmospheric gases and to give up heat to the atmosphere -- is a uniquely antarctic phenomenon that has significant consequences for global change by affecting the g lobal reservoir of carbon dioxide, and by modulating the amount and extent of seasonal sea ice in the southern hemisphere. This component will make systematic observations of the temperature salinity structure of the water and undertake an extensive sampling program for other chemical studies. The purpose is to identify the individual water masses and to relate their temperature and salinity characteristics to the modification processes within the Weddell Sea. ***
9317379 Foster This project is study of the deep and bottom water formation processes of the antarctic continental shelf off Wilkes Land between 145 deg E longitude and 160 deg E longitude. The project is to be carried out jointly with an Australian oceanographic project. Preliminary work in 1985 has shown that hydrographic sections in this area are quite similar to those of known deep water formation regions in the southern Weddell Sea. This project will include the year-long deployment of six current meter moorings, and tracer studies (oxygen, carbon dioxide, chlorofluorocarbons, stable isotopes, and nutrients) to test whether shelf waves and tides are the principal mechanism for mixing shelf water with the off-shore intermediate water. Two oceanographic cruises are planned for this work: a cruise of the RVIB Nathaniel B. Palmer in February 1995, and a cruise of the Australian ship R/V Aurora Australis in February 1996. ***
The growing season for phytoplankton in polar oceans is short, but intense. There is an increasing body of evidence that in many Antarctic habitats, the most active period may be very early in the season, a period that has not been emphasized in previous investigations. This project is part of an interdisciplinary program that focuses on the dynamics of the spring phytoplankton bloom in a highly productive subsystem of the Antarctic, the Ross Sea. The overall program will test hypotheses related to the initiation of the phytoplankton bloom shortly after the onset of ice melt, the mechanisms controlling phytoplankton growth and productivity in spring, the implications and short-term fate of high productivity in spring, and the transition from spring to midsummer conditions. This component will conduct a set of process-oriented experiments designed to elucidate the controls of phytoplankton productivity, growth and accumulation as well as the mechanisms which control bacterial abundance and productivity in Antarctic waters. Specifically, the relative photosynthetic and nutrient (nitrate, ammonium) characteristics of diatom- vs. Phaeocystis- dominated assemblages will be examined to test if Phaeocystis simply grows faster under spring conditions in the Ross Sea. Phytoplankton and bacterial biomass, productivity and their interactions will be measured to elucidate the complex physical-chemical-biological interactions which occur. Substantial understanding of the mechanisms controlling phytoplankton growth and productivity in spring, the implications and short-term fate of high productivity in spring, and the transition from spring to midsummer conditions will result from this research. Finally, because the Antarctic is the ocean's largest high-nutrient, low biomass system, and hence has the greatest potential for sequestering carbon dioxide, knowledge of the dynamics of the Ross Sea phytoplankton will also increase our understanding of the carbo n cycle of the Southern Ocean.
The objectives of this proposal are to investigate the controls on the large-scale distribution and production of the two major bloom-forming phytoplankton taxa in the Southern Ocean, diatoms and Phaeocystis Antarctica. These two groups, through their involvement in the biogeochemical cycles of carbon, sulfur and nutrient elements, may have played important roles in the climate variations of the late Quaternary, and they also may be key players in future environmental change. A current paradigm is that irradiance and iron availability drive phytoplankton dynamics in the Southern Ocean. Recent work, however, suggests that carbon dioxide (CO2) concentrations may also be important in structuring algal assemblages, due to species-specific differences in the physiology. This proposal examines the interactive effects of iron, light and CO2 on the physiology, ecology and relative dominance of Phaeocystis and diatoms in the Southern Ocean. The Ross Sea is an ideal system in which to investigate the environmental factors that regulate the distribution and production of these two algal groups, since it is characterized by seasonal blooms of both P. Antarctica and diatoms that are typically separated in both space and time. This study will take the form of an interdisciplinary investigation that includes a field survey and statistical analysis of algal assemblage composition, iron, mixed layer depth, and CO2 levels in the southern Ross Sea, coupled with shipboard experiments to examine the response of diatom and P. Antarctica assemblages to high and low levels of iron, light and CO2 during spring and summer. <br/>This project will provide information on some of the major factors controlling the production and distribution of the two major bloom forming phytoplankton in the Southern Ocean and the related biogeochemical cycling of carbon, sulfur and nutrient elements. The results may ultimately advance the ability to predict how the Southern Ocean will be affected by and possibly modulate future climate change. This project will also make significant educational contributions at several levels, including the planned research involvement of graduate and undergraduate students, postdoctoral associates, a student teacher, and community outreach and educational activities. A number of activities are planned to interface the project with K-12 education. Presentations will be made at local schools to discuss the research and events of the research cruise. During the cruise there will be daily interactive email contact with elementary classrooms. Established websites will be used to allow students to learn about the ongoing research, and to allow researchers to communicate with students through text and downloaded images.
The research will examine the relative importance of the physical and chemical controls on phytoplankton dynamics and carbon flux in continental margin regions of the Southern Ocean, and elucidate mechanisms by which plankton populations and carbon export might be altered by climate change. We specifically will address (1) how the phytoplankton on the continental margins of the southern Ocean respond to spatial and temporal changes in temperature, light, iron supply, and carbon dioxide levels, (2) how these factors initiate changes in phytoplankton assemblage structure, and (3) how carbon export and the efficiency of the biological pump are impacted by the biomass and composition of the phytoplankton. Two regions of study (the Amundsen and Ross Seas) will be investigated, one well studied (Ross Sea) and one poorly described (Amundsen Sea). It is hypothesized that each region will have markedly different physical forcing, giving rise to distinct chemical conditions and therefore biological responses. As such, the comparison of the two may give us insights into the mechanisms of how Antarctic continental margins will respond under changing environmental conditions. Broader impacts include participation by an international graduate student from Brazil, outreach via seminars to the general public, collaboration with the teachers-in-residence on the cruise, development of a cruise web site and interactive email exchanges with local middle school students while at sea
Abstract<br/><br/>The research will continue and extend the study in the Southern Ocean that was initiated during the Oden Southern Ocean 2006 expedition in collaboration with Swedish scientist Mellissa Chierici. We will quantify carbon flux through the food web in the marginal ice zone (MIZ) by measuring size fractionated primary and secondary production, grazing and carbon flux through nanoplankton (2-20 um), microplankton (20-200um), and mesoplankton (200-2000 um). Community structure, species abundance and size specific grazing rates will be quantified using a variety of techniques both underway and at ice stations along the MIZ. The proposed cruise track extends across the Drake Passage to the Western Antarctic Peninsula (WAP) with three station transects along a gradient from the open ocean through the marginal ice zone (MIZ) in the Bellinghausen and Amundsen Seas and into the Ross Sea Polynya. Ice stations along each transect will provide material to characterize production associated with annual ice. Underway measurements of primary and secondary production (chlorophyll, CDOM, microplankton, and mesoplankton) and hydrography (temperature, salinity, pH, DO, turbidity) will establish a baseline for future cruises and as support for other projects such as biogeochemical studies on carbon dioxide drawdown and trace metal work on primary production. The outcome of these measurements will be a description of nano to mesoplankton standing stocks, community structure, and carbon flux along the MIZ in the Bellinghausen and Amundsen Seas and the Ross Sea Polynya.
Abstract<br/><br/>The research objective is (1) to determine the distributions and dynamics of a full suite of bioactive trace metals in dissolved and suspended particulate forms, along sampling transects of the Amundsen and Ross Seas. And (2) to test the sensitivity of overall cellular metal stoichiometry (metal/carbon ratios) to natural gradients in species assemblage and Fe availability. Our earlier findings from a single Ross Sea station and from a Drake Passage crossing suggest that Fe-limited phytoplankton cells are unusually enriched in Zn, Cu and Cd relative to biomass carbon, with strong implications for the biogeochemical cycling of these elements relative to carbon fluxes in the Southern Ocean. In collaboration with other researchers on the cruise, we will also measure metal stoichiometry of cells exposed to predicted 2010 temperature and carbon dioxide levels in shipboard incubation studies, as a window into possible effects of climate change on metals biogeochemistry in these regions. This proposal will support close international collaborations and lasting infrastructure development as US and Swedish scientists, and more importantly, their students, work toward shared the shared goal of understanding a region that is experiencing one of the fastest rates of climate change on the globe. Trace metal micro-nutrients are a key control on the productivity of Antarctic marine ecosystems. Our results will be made widely available through research publications and internet-available databases, and public outreach through COSEE at Rutgers University.
This award supports a project to measure the elemental and isotopic composition of firn air and occluded air in shallow boreholes and ice cores from the WAIS Divide site, the location of a deep ice-coring program planned for 2006-07 and subsequent seasons. The three primary objectives are: 1) to establish the nature of firn air movement and trapping at the site to aid interpretations of gas data from the deep core; 2) to expand the suite of atmospheric trace gas species that can be measured in ice and replicate existing records of other species; and 3) to inter-calibrate all collaborating labs to insure that compositional and isotopic data sets are inter-comparable. The program will be initiated with a shallow drilling program during the 05/06 field season which will recover two 300+m cores and firn air samples. The ice core and firn air will provide more than 700 years of atmospheric history that will be used to address a number of important questions related to atmospheric change over this time period. The research team consists of six US laboratories that also plan to participate in the deep core program. This collaborative research program has a number of advantages. First, the scientists will be able to coordinate sample allocation a priori to maximize the resolution and overlap of records of interrelated species. Second, sample registration will be exact, allowing direct comparison of all records. Third, a coherent data set will be produced at the same time and all PI.s will participate in interpreting and publishing the results. This will insure that the best possible understanding of gas records at the WAIS Divide site will be achieved, and that all work necessary to interpret the deep core is conducted in a timely fashion. The collaborative structure created by the proposal will encourage sharing of techniques, equipment, and ideas between the laboratories. The research will identify impacts of various industrial/agricultural activities and help to distinguish them from natural variations, and will include species for which there are no long records of anthropogenic impact. The work will also help to predict future atmospheric loadings. The project will contribute to training scientists at several levels, including seven undergraduates, two graduate students and one post doctoral fellow.
This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a project to investigate the "Silicic Acid Leakage Hypothesis" as it relates to global carbon dioxide fluctuations during glacial-interglacial cycles.<br/><br/>Intellectual Merit<br/>This project will evaluate the burial rate of biogenic opal in the Pacific sector of the Southern Ocean, both during the Last Glacial Maximum (LGM) and during the Holocene, as a critical test of the "Silicic Acid Leakage Hypothesis". <br/><br/>The "Silicic Acid Leakage Hypothesis" has been proposed recently to explain the glacial reduction in the carbon dioxide content of the atmosphere that has been reconstructed from Antarctic ice cores. Vast amounts of dissolved Si (silicic acid) are supplied to surface waters of the Southern Ocean by wind-driven upwelling of deep waters. Today, that dissolved Si is consumed almost quantitatively by diatoms who form skeletal structures composed of biogenic opal (a mineral form of silicon). According to the "Silicic Acid Leakage Hypothesis", environmental conditions in the Southern Ocean during glacial periods were unfavorable for diatom growth, leading to reduced (compared to interglacials) efficiency of dissolved Si utilization. Dissolved Si that was not consumed biologically in the glacial Southern ocean was then exported to the tropics in waters that sink in winter to depths of a few hundred meters along the northern fringes of the Antarctic Circumpolar Current, and return some decades later to the sunlit surface in tropical regions of wind-driven upwelling. <br/><br/>An increase in the amount of dissolved Si that "leaks" out of the Southern Ocean and later upwells at low latitudes could shift the global average composition of phytoplankton toward a greater abundance of diatoms and fewer CaCO3-secreting taxa (especially coccolithophorids). Consequences of such a taxonomic shift in the ocean's phytoplankton assemblage include:<br/> a) an increase in the global average organic carbon/calcium carbonate ratio of particulate biogenic material sinking into the deep sea;<br/> b) a reduction in the preservation and burial of calcium carbonate in marine sediments;<br/> c) an increase in ocean alkalinity as a consequence of the first two changes mentioned above, and;<br/> d) a lowering of atmospheric CO2 concentrations in response to increased alkalinity of ocean waters. <br/><br/>A complete assessment of the Silicic acid leakage hypothesis will require an evaluation of: (1) Si utilization efficiencies using newly-developed stable isotopic techniques; (2) opal burial rates in low-latitude upwelling regions; and (3) opal burial rates in the Southern Ocean. This project addresses the last of these topics. <br/><br/>Previous work has shown that there was little change in opal burial rate between the LGM and the Holocene in the Atlantic and Indian sectors of the Southern Ocean. Preliminary results (summarized in this proposal) suggest that the Pacific may have been different, however, in that opal burial rates in the Pacific sector seem to have been lower during the LGM than during the Holocene, allowing for the possibility of "Si leakage" from this region. However, available results are too sparse to make any quantitative conclusions at this time. For that reason, we propose to make a comprehensive evaluation of opal burial rates in the Pacific sector of the Southern Ocean. <br/><br/>Significance and Broader Impacts<br/>Determining the mechanism(s) by which the ocean has regulated climate-related changes in the CO2 content of the atmosphere has been the focus of a substantial effort by paleoceanographers over the past two decades. The Silicic Acid Leakage Hypothesis is a viable new candidate mechanism that warrants further exploration and testing. Completion of the proposed work will contribute significantly to that effort. <br/><br/>During the course of this work, several undergraduates will be exposed to paleoclimate research through their involvement in this project. Burckle and Anderson are both dedicated to the education and training of young scientists, and to the recruitment of women and under-represented minorities. To illustrate, two summer students (undergraduates) worked in Burckle's lab during the summer of 2002. One was a woman and the other (male) was a member of an under-represented minority. Anderson and Burckle will continue with similar recruitment efforts during the course of the proposed study. A minority student who has expressed an interest in working on this research during the summer of 2003 has already been identified.
Abstract<br/><br/>This Small Grants for Exploratory Research (SGER) proposal describes global change-related experimental research designed to take full advantage of a unique science opportunity on short notice, the leasing of the Oden to conduct ice-breaking operations in McMurdo Sound. <br/><br/>Our emphasis will be on using this opportunistic research platform to ask two questions about present day and future controls on Antarctic margin phytoplankton communities. These are: 1. How will expected alterations in pCO2, pH, and Fe availability in the Southern Ocean, due to future anthropogenic climate change affect phytoplankton species assemblages, carbon and nutrient biogeochemistry, and remineralization processes? 2. What is the current role of organic co-factors (vitamins) in limiting or co-limiting (along with iron ) phytoplankton growth and production in the Antarctic margin? The research approach includes experimental incubations with variation in iron enrichment, carbon dioxide concentration, and temperature. A second suite of experiments will examine co-limitation effects between vitamin B12 and Fe and B12 uptake kinetics. Changes in phytoplankton community structure, and carbon and nutrient cycling will be determined, in collaboration with many of the participating U.S. and Swedish investigators. Together, these two main objectives should allow us to obtain novel insights into the current and future controls on Antarctic margin phytoplankton growth, productivity, and carbon and nutrient biogeochemistry. In particular, the experiments in the Amundsen Sea represent a one-of-a-kind opportunity to understand algal dynamics and potential future responses to climate change in this little-studied ecosystem, and compare these results to those from the better-known Ross Sea. An important result of this study will be to build strong international collaborations with the Swedish marine science community. Additional broader impacts include participatin of an Hispanic Ph.D. student in cruise work and post-cruise analyses, and integration of results into graduate courses at the USC Catalina Lab facility. Public outreach will include presentations on global change impacts on the ocean targeted at audiences ranging from legislators and policymakers to the general public.
This award supports a two-year project to continue work developing the techniques to make carbon monoxide (CO) measurements in ice core samples. Carbon monoxide is an important atmospheric chemical constituent as it is a primary sink for hydroxyl radical (OH) (and therefore influences the oxidizing capacity of the atmosphere) and because the concentrations of three major greenhouses gases , carbon dioxide (CO2), methane (CH4) and ozone (O3) are directly tied to the concentration of CO. In light of recent anthropogenic increases in the emissions of CO, CO2, CH4 and NOx, it is desirable to understand this complex chemical system and the changes in the greenhouse forcing resulting from perturbation. Because it is difficult to test the accuracy of models for past and future conditions for which no direct atmospheric measurements of trace gas concentrations are available these measurements must be obtained in other ways. Polar ice cores provide a means to make these measurements. Further work is necessary to refine the analytical technique and additional measurements are necessary to investigate the accuracy of these results and to establish the nature of temporal trends in CO. It is anticipated that the CO record, combined with existing or new data for CO2, CH4 , N2O and other paleoclimate variables, will provide further constraints on model studies of the effect of changing atmospheric chemistry on greenhouse forcing.
This award supports the continued measurements of gas isotopes in the Vostok ice core, from Antarctica. One objective is to identify the phasing of carbon dioxide variations and temperature variations, which may place constraints on hypothesized cause and effect relationships. Identification of phasing has in the past been hampered by the large and uncertain age difference between the gases trapped in air bubbles and the surrounding ice. This work will circumvent this issue by employing an indicator of temperature in the gas phase. It is argued that 40Ar/39Ar behaves as a qualitative indicator of temperature, via an indirect relationship between temperature, accumulation rate, firn thickness, and gravitational fractionation of the gas isotopes. The proposed research will make nitrogen and argon isotope measurements on ~ 200 samples of ice covering Termination II (130,000 yr B.P.) and Termination IV (340,000 yr BP). The broader impacts may include a better understanding of the role of atmospheric carbon dioxide concentrations in climate change.
9980691<br/>Wahlen<br/><br/>This award is for support for three years of funding to reconstruct the atmospheric carbon dioxide (CO2) and carbon-13 isotope (d13C) concentration in ice cores from Antarctica over several climatic periods. Samples from the Holocene, the Last Glacial Maximum (LGM)-Holocene transition and glacial stadial/interstadial episodes will be examined. Samples from the Siple Dome ice core drilled in 1998/99 will be made, in addition to measurements from the Taylor Dome and Vostok ice cores. The major objectives are to investigate the phase relationships between variations in the concentration of atmospheric CO2, its carbon isotope composition, and temperature changes (indicated by 18dO and dD of the ice) during deglaciations as well as across rapid climate change events (e.g. Dansgaard-Oeschger events). This will help to determine systematic changes in the global carbon cycle during and between different climatic periods, and to ascertain if the widely spread northern hemisphere temperature stadial/interstadial events produced a global atmospheric carbon dioxide signal. Proven experimental techniques will be used.
This award is for support of a program to reconstruct the record of atmospheric carbon dioxide (and the carbon-13 isotopes of carbon dioxide) over several intervals, including the Last Glacial Maximum-Holocene transition, interstadial episodes, the mid-Holocene, the last 1000 years and the penultimate glacial period, using ice from the Taylor Dome and Vostok ice cores. The major objective of this study is to investigate the phase relationship between variations of the greenhouse gases occluded in the ice cores and temperature changes (indicated by oxygen and deuterium isotopes) during the last deglaciation. In addition, the concentration of atmospheric carbon dioxide over the past 1000 years and during the mid-Holocene will be determined in these cores.
