[{"awards": "1745078 Brook, Edward", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ; Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation; Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "datasets": [{"dataset_uid": "601736", "doi": "10.15784/601736", "keywords": "Antarctica; Greenland; Methane; Paleoclimate; West Antarctic Ice Sheet", "people": "Martin, Kaden; Buizert, Christo; Rosen, Julia; Brook, Edward; Riddell-Young, Benjamin; M\u00fchl, Michaela; Edwards, Jon S.; Lee, James; Schmitt, Jochen; Fischer, Hubertus; Blunier, Thomas", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601736"}, {"dataset_uid": "601737", "doi": "10.15784/601737", "keywords": "Antarctica; Glaciers/Ice Sheet; Greenland; Ice Core Records; Methane; West Antarctic Ice Sheet", "people": "Edwards, Jon S.; Riddell-Young, Benjamin; Brook, Edward; Martin, Kaden; Rosen, Julia; Lee, James", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ", "url": "https://www.usap-dc.org/view/dataset/601737"}, {"dataset_uid": "601683", "doi": "10.15784/601683", "keywords": "Antarctica; Methane; West Antarctic Ice Sheet", "people": "Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601683"}], "date_created": "Mon, 01 May 2023 00:00:00 GMT", "description": "This project will develop methods to measure the ratios of carbon-13 to carbon-12, and heavy to light hydrogen in methane in air trapped in ice cores. The ratios of the different forms of carbon and hydrogen are \"fingerprints\" of different sources of this gas in the past--for example wetlands in the tropics versus methane frozen in the sea floor. Once the analysis method is developed, the measurements will be used to examine why methane changed abruptly in the past, both during the last ice age, and during previous warm periods. The data will be used to understand how methane sources like wildfires, methane hydrates, and wetlands respond to climate change. This information is needed to understand future risks of large changes in methane in the atmosphere as Earth warms. \u003cbr/\u003e\u003cbr/\u003eThe project involves two tasks. First, the investigators will build and test a gas extraction system for methane isotopic measurements using continuous flow methods, with the goal of equaling or bettering the precision attained by the few other laboratories that make these measurements. The system will be interfaced with existing mass spectrometers at Oregon State University. The system consists of a vacuum chamber and sequence of traps, purification columns, and furnaces that separate methane from other gases and convert it to carbon dioxide or hydrogen for mass spectrometry. Second, the team will measure the isotopic composition of methane across large changes in concentration associated with two past interglacial periods and during abrupt methane changes of the last ice age. These measurements will be used to understand if the main reason for these concentration changes is climate-driven changes in emissions from wetlands, or whether other sources are involved, for example methane hydrates or wildfires.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Antarctic Ice Sheet; TRACE GASES/TRACE SPECIES; METHANE", "locations": "Antarctic Ice Sheet", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Tracing Past Methane Variations with Stable Isotopes in Antarctic Ice Cores", "uid": "p0010416", "west": -180.0}, {"awards": "1543511 Stephens, Britton; 1543457 Munro, David", "bounds_geometry": "POLYGON((-73 -53,-71.2 -53,-69.4 -53,-67.6 -53,-65.8 -53,-64 -53,-62.2 -53,-60.4 -53,-58.6 -53,-56.8 -53,-55 -53,-55 -54.4,-55 -55.8,-55 -57.2,-55 -58.6,-55 -60,-55 -61.4,-55 -62.8,-55 -64.2,-55 -65.6,-55 -67,-56.8 -67,-58.6 -67,-60.4 -67,-62.2 -67,-64 -67,-65.8 -67,-67.6 -67,-69.4 -67,-71.2 -67,-73 -67,-73 -65.6,-73 -64.2,-73 -62.8,-73 -61.4,-73 -60,-73 -58.6,-73 -57.2,-73 -55.8,-73 -54.4,-73 -53))", "dataset_titles": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the Southern Ocean, Drake Passage and South Atlantic Ocean in 2018, processed by NOAA (NCEI Accession 0184338); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, Drake Passage, South Atlantic Ocean in 2022 (NCEI Accession 0276577); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Atlantic Ocean in 2021 (NCEI Accession 0246983); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean from 2019-02-16 to 2020-02-11 (NCEI Accession 0208838); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean in 2020 (NCEI Accession 0225445); Underway measurements of pCO2 in the Surface Waters and the Atmosphere During the ARSV Laurence M. Gould 2017 Expeditions processed by NOAA (NCEI Accession 0170337)", "datasets": [{"dataset_uid": "200351", "doi": "https://doi.org/10.25921/z0pk-pv81", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean in 2020 (NCEI Accession 0225445)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200350", "doi": "https://doi.org/10.25921/3ysc-pm11", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean from 2019-02-16 to 2020-02-11 (NCEI Accession 0208838)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200352", "doi": "https://doi.org/10.25921/f94g-zp40", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Atlantic Ocean in 2021 (NCEI Accession 0246983)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200348", "doi": "https://doi.org/10.7289/v5tq5zt1", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Underway measurements of pCO2 in the Surface Waters and the Atmosphere During the ARSV Laurence M. Gould 2017 Expeditions processed by NOAA (NCEI Accession 0170337)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200349", "doi": "https://doi.org/10.25921/b4jn-ef56", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the Southern Ocean, Drake Passage and South Atlantic Ocean in 2018, processed by NOAA (NCEI Accession 0184338)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200353", "doi": "https://doi.org/10.25921/fq0a-7y11", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, Drake Passage, South Atlantic Ocean in 2022 (NCEI Accession 0276577)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}], "date_created": "Wed, 22 Feb 2023 00:00:00 GMT", "description": "The Southern Ocean plays a key role in modulating the global carbon cycle, but the size and even the sign of the flux of carbon dioxide between the ocean and atmosphere in this region is still uncertain. This is in part due to the lack of measurements in this remote region of the world ocean. This project continues a multi-year time series of shipboard chemical measurements in the Drake Passage to detect changes in the ocean carbon cycle and to improve the understanding of mechanisms driving natural variability and long-term change in the Southern Ocean. More specifically, this project is a continuation of the collection of underway upper ocean measurements of the surface partial pressure of carbon dioxide during crossings of the Drake Passage by the Antarctic Research and Supply Vessel Laurence M. Gould. This project also includes collection and analysis of discrete samples relevant to ocean carbon cycle studies including macronutrient concentrations, total carbon dioxide concentrations, and the carbon isotopic composition of total carbon dioxide. The Drake Passage data are made readily available to the international science community and serve as both validation and constraints of remotely sensed observations and numerical coupled earth systems models.", "east": -55.0, "geometry": "POINT(-64 -60)", "instruments": null, "is_usap_dc": true, "keywords": "Drake Passage; NUTRIENTS; BIOGEOCHEMICAL CYCLES; DISSOLVED GASES; TRACE GASES/TRACE SPECIES", "locations": "Drake Passage", "north": -53.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Ocean and Atmospheric Sciences; Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Munro, David; Sweeney, Colm; Lovenduski, Nicole S; Stephens, Britton", "platforms": null, "repo": "NCEI", "repositories": "NCEI", "science_programs": null, "south": -67.0, "title": "Collaborative Research: Investigating Biogeochemical Fluxes and Linkages To Climate Change With Multi-Scale Observations In The Drake Passage", "uid": "p0010407", "west": -73.0}, {"awards": "1542723 Alexander, Becky", "bounds_geometry": "POINT(-112.05 -79.28)", "dataset_titles": "WAIS Divide ice core nitrate isotopes", "datasets": [{"dataset_uid": "601456", "doi": "10.15784/601456", "keywords": "Antarctica; Glaciers/Ice Sheet; Glaciology; Ice Core Chemistry; Ice Core Records; Nitrate; Nitrate Isotopes; WAIS Divide Ice Core; West Antarctic Ice Sheet", "people": "Alexander, Becky", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide ice core nitrate isotopes", "url": "https://www.usap-dc.org/view/dataset/601456"}], "date_created": "Mon, 13 Feb 2023 00:00:00 GMT", "description": "The Earth\u0027s atmosphere is a highly oxidizing medium. The abundance of oxidants such as ozone in the atmosphere strongly influences the concentrations of pollutants and greenhouse gases, with implications for human health and welfare. Because oxidants are not preserved in geological archives, knowledge of how oxidants have varied in the past under changing climate conditions is extremely limited. This award will measure a proxy for oxidant concentrations in a West Antarctic ice core over several major climate transitions over the past 50,000 years. These measurements will complement similar measurements from a Greenland ice core, which showed significant changes in atmospheric oxidants over major climate transitions covering this same time period. The addition of measurements from Antarctica will allow researchers to examine if the oxidant changes suggested by the Greenland ice core record are regional or global in scale. Knowledge of how oxidants vary naturally with climate will better inform predictions of the composition of the future atmosphere under a warming climate.\u003cbr/\u003e\u003cbr/\u003eThis award will support measurements of the isotopic composition of nitrate in a West Antarctic ice core as a proxy for oxidant concentrations in the past atmosphere. The nitrogen isotopes of nitrate provide information on the degree of preservation of nitrate in the ice core record, and thus aid in the interpretation of the observed variability in the observed nitrate concentrations and oxygen isotopes in ice core records. By providing information about the spatial scale of oxidant changes over abrupt climate change events during the last glacial period, this project may also improve our understanding of mechanisms driving these abrupt events. Insight from this project will prove valuable for forecasting the response of stratospheric circulation to climate change, which has large implications for climate feedbacks and tropospheric composition. In addition, the information gleaned from this project on the mechanisms and feedbacks during abrupt climate change events will help determine the likelihood of such rapid events occurring in the future, which would have dramatic impacts on humankind. This award will provide training for one graduate and one undergraduate student, and will support the development of a hands-on activity related to rapid climate change to be used at the annual Polar Science Weekend at the Pacific Science Center in Seattle, WA.", "east": -112.05, "geometry": "POINT(-112.05 -79.28)", "instruments": null, "is_usap_dc": true, "keywords": "Nitrate Isotopes; ICE CORE RECORDS; LABORATORY; WAIS divide", "locations": "WAIS divide", "north": -79.28, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Alexander, Becky", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -79.28, "title": "Measuring an Ice-core Proxy for Relative Oxidant Abundances over Glacial-interglacial and Rapid Climate changes in a West Antarctic Ice Core", "uid": "p0010403", "west": -112.05}, {"awards": "2135695 Emslie, Steven; 2135696 Polito, Michael", "bounds_geometry": "POLYGON((-180 -70,-180 -70,-180 -70,-180 -70,-180 -70,-180 -70,-180 -70,-180 -70,-180 -70,-180 -70,-180 -70,-180 -70.8,-180 -71.6,-180 -72.4,-180 -73.2,-180 -74,-180 -74.8,-180 -75.6,-180 -76.4,-180 -77.2,-180 -78,-180 -78,-180 -78,-180 -78,-180 -78,-180 -78,-180 -78,-180 -78,-180 -78,-180 -78,180 -78,178 -78,176 -78,174 -78,172 -78,170 -78,168 -78,166 -78,164 -78,162 -78,160 -78,160 -77.2,160 -76.4,160 -75.6,160 -74.8,160 -74,160 -73.2,160 -72.4,160 -71.6,160 -70.8,160 -70,162 -70,164 -70,166 -70,168 -70,170 -70,172 -70,174 -70,176 -70,178 -70,-180 -70))", "dataset_titles": null, "datasets": null, "date_created": "Fri, 28 Oct 2022 00:00:00 GMT", "description": "Stable isotope analyses of carbon and nitrogen (\u03b413C and \u03b415N) are commonly used to investigate animal migration, foraging locations and diet, especially in marine species that can travel over great distances. One other stable isotope, sulfur (\u03b434S), is not as commonly used but is increasingly being applied to refine and corroborate data obtained from carbon and nitrogen analyses. Collagen is one of the best tissues for these analyses as it is abundant in bone, preserves well, and can be easily extracted for analysis. In the Ross Sea region, the cold, dry environment has been conductive for the preservation of Ad\u00e9lie penguin (Pygoscelis adeliae) bones, feathers, eggshell and even mummified remains, at active and abandoned colonies that date from before the Last Glacial Maximum (\u003e45,000 yrs ago) through the Holocene. Most of these colonies are associated with one of three polynyas, or highly productive areas of open water surrounded by sea ice in the Ross Sea. Thus, this species is an excellent bioindicator for marine conditions, past and present, and its colonies have appeared and disappeared throughout this region with changing climate and sea ice regimes for millennia. Current warming trends are inducing relatively rapid ecological responses by this species and some of the largest colonies in the Ross Sea are likely to be abandoned in the next 50 years from rising sea level. The recently established Ross Sea Marine Protected Area aims to protect Ad\u00e9lie penguins and other species in this region from human impacts and knowledge on how this species responds to climate change, past and present, will support this goal. \r\n\r\nWe propose to investigate ecological responses in diet and foraging behavior of the Ad\u00e9lie penguin to known climatic events that occurred in the middle to late Holocene, specifically, before, during and after a warming period known as the penguin \u2018optimum\u2019 at 2000 - 4000 cal yr before present (BP). We will apply for the first time a suite of three stable isotope analyses (\u03b413C, \u03b415N, \u03b434S) on chick bones and feathers, as well as prey remains, from active and abandoned colonies in the Ross Sea. We will use existing tissue samples (~60-80 bones) collected by PI Emslie with NSF support since 2001 and supplement these with newly collected samples of bones and feathers in this project. We will conduct compound-specific isotope analyses of carbon on essential amino acids from collagen from a selected sample of 30-40 bones that span the past 5000 yrs to provide corroboratory information. We will apply three-dimensional Bayesian niche models and/or community metrics using R scripts in these analyses to identify isotopic \u2018signatures\u2019 of existing and past foraging grounds and polynyas used by Ad\u00e9lie penguins in the southern, central, and northern Ross Sea. This four-year study will the first of its kind to apply multiple stable isotope analyses to investigate a living species of seabird over millennia in a region where it still exists today. \r\n\r\nBroader Impacts:\r\nThe PIs are committed to public engagement and enhancement of K-12 education in the STEM sciences. Broader impacts of this research will include support and training for one Ph.D., two M.S., and eight undergraduate students in the Department of Biology and Marine Biology, and two M.A. students in the Watson School of Education at the University of North Carolina Wilmington (UNCW). The last two students will continue to expand on a detailed polar curriculum that was initiated in previous NSF grants for 2nd and 4th grade students, and most recently for 9-12th grade students now available on PI Emslie\u2019s website (www.uncw.edu/penguins). Additional curricula for K-12 students will be designed and tested in this project, which will include visitation to local K-12 schools. As in previous awards, we will focus on schools that serve historically under-represented groups in the sciences. We will work with the UNCW Center for Education in STEM Sciences to assess the efficacy of this new curricula. All curricula will be uploaded on the Educational Resource Commons website. Field work will include blogs and active question-answer sessions with students at these schools. We will continue to post project information and updates on PI Emslie\u2019s website and YouTube channel. Our partnership with tour ship companies will provide a platform for onboard lectures on the importance of scientific research as well as citizen science opportunities for another sector of the public. This proposal requires fieldwork in the Antarctic.\r\n", "east": -180.0, "geometry": "POINT(170 -74)", "instruments": null, "is_usap_dc": true, "keywords": "Climate Change; Adelie Penguin; Foraging Ecology; Ross Sea; PENGUINS; Holocene; Stable Isotopes", "locations": "Ross Sea", "north": -70.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Emslie, Steven; Lane, Chad S; Polito, Michael", "platforms": null, "repositories": null, "science_programs": null, "south": -78.0, "title": "Collaborative Research: Using Multiple Stable Isotopes to Investigate Middle to Late Holocene Ecological Responses by Adelie Penguins in the Ross Sea", "uid": "p0010388", "west": 160.0}, {"awards": "1644118 Dunbar, Robert", "bounds_geometry": "POLYGON((-108 -73,-107.3 -73,-106.6 -73,-105.9 -73,-105.2 -73,-104.5 -73,-103.8 -73,-103.1 -73,-102.4 -73,-101.7 -73,-101 -73,-101 -73.3,-101 -73.6,-101 -73.9,-101 -74.2,-101 -74.5,-101 -74.8,-101 -75.1,-101 -75.4,-101 -75.7,-101 -76,-101.7 -76,-102.4 -76,-103.1 -76,-103.8 -76,-104.5 -76,-105.2 -76,-105.9 -76,-106.6 -76,-107.3 -76,-108 -76,-108 -75.7,-108 -75.4,-108 -75.1,-108 -74.8,-108 -74.5,-108 -74.2,-108 -73.9,-108 -73.6,-108 -73.3,-108 -73))", "dataset_titles": "Antarctic Seawater d18O isotope data from SE Amundsen Sea: 2000, 2007, 2009, 2019, 2020", "datasets": [{"dataset_uid": "601611", "doi": "10.15784/601611", "keywords": "Amundsen Sea; Antarctica; Chemistry:Water; CTD; d18O; NBP0001; NBP0702; NBP0901; NBP1901; NBP2002; Oceans; Oxygen Isotope; R/V Nathaniel B. Palmer; seawater isotope; Southern Ocean", "people": "Hennig, Andrew", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Seawater d18O isotope data from SE Amundsen Sea: 2000, 2007, 2009, 2019, 2020", "url": "https://www.usap-dc.org/view/dataset/601611"}], "date_created": "Wed, 21 Sep 2022 00:00:00 GMT", "description": "Estimating Antarctic ice sheet growth or loss is important to predicting future sea level rise. Such estimates rely on field measurements or remotely sensed based observations of the ice sheet surface, ice margins, and or ice shelves. This work examines the introduction of freshwater into the ocean to surrounding Antarctica to track meltwater from continental ice. Polar ice is depleted in two stable isotopes, 18O and D, deuterium, relative to Southern Ocean seawater and precipitation. Measurements of seawater isotopic composition in conjunction with precise observations of seawater temperature and salinity, will permit discrimination of freshwater derived from melting glacial ice from that derived from regional precipitation or sea ice melt.\u003cbr/\u003e\u003cbr/\u003eThis research describes an accepted method for determining rates and locations of meltwater entering the oceans from polar ice sheets. As isotopic and salinity perturbations are cumulative in many Antarctic coastal seas, the method allows for the detection of any marked acceleration in meltwater introduction in specific regions, using samples collected and analyzed over a period of years to decades. Impact of the project derives from use of an independent method capable of constraining knowledge about current ice sheet melt rates, their stability and potential impact on sea level rise. The project allows for sample collection taken from foreign vessels of opportunity sailing in Antarctic waters, and subsequent sharing and interpretation of data. Research partners include the U.S., Korea, China, New Zealand, the United Kingdom, and Germany. Participating collaborators will collect seawater samples for isotopic and salinity analysis at Stanford University. USAP cruises will concentrate on sampling the Ross Sea, and the West Antarctic. The work plan includes interpretation of isotopic data using box model and mixing curve analyses as well as using isotope enabled ROMS (Regional Ocean Modeling System) models. The broader impacts of the research will include development of an educational module that illustrates the scientific method and how ocean observations help society understand how Earth is changing.", "east": -101.0, "geometry": "POINT(-104.5 -74.5)", "instruments": null, "is_usap_dc": true, "keywords": "Meltwater inventory; Stable Isotopes; WATER TEMPERATURE; SALINITY; Oxygen Isotope; Pine Island Bay; OCEAN CHEMISTRY", "locations": "Pine Island Bay", "north": -73.0, "nsf_funding_programs": "Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Dunbar, Robert", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -76.0, "title": "Estimation of Antarctic Ice Melt using Stable Isotopic Analyses of Seawater", "uid": "p0010380", "west": -108.0}, {"awards": "2123491 John, Seth; 2123354 Conway, Timothy; 2123333 Fitzsimmons, Jessica", "bounds_geometry": "POLYGON((-135 -66,-131.5 -66,-128 -66,-124.5 -66,-121 -66,-117.5 -66,-114 -66,-110.5 -66,-107 -66,-103.5 -66,-100 -66,-100 -67,-100 -68,-100 -69,-100 -70,-100 -71,-100 -72,-100 -73,-100 -74,-100 -75,-100 -76,-103.5 -76,-107 -76,-110.5 -76,-114 -76,-117.5 -76,-121 -76,-124.5 -76,-128 -76,-131.5 -76,-135 -76,-135 -75,-135 -74,-135 -73,-135 -72,-135 -71,-135 -70,-135 -69,-135 -68,-135 -67,-135 -66))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 08 Sep 2022 00:00:00 GMT", "description": "The goal of the international GEOTRACES program is to understand the distributions of trace chemical elements and their isotopes (TEIs) in the oceans. Many trace metals such as iron are essential for life and thus considered nutrients for phytoplankton growth, with trace metal cycling being especially important for influencing carbon cycling in the iron-limited Southern Ocean, where episodic supply of iron from a range of different external sources is important. The primary goal of this project is to measure the dissolved concentrations, size partitioning, and dissolved isotope signature of Fe on a transect of water-column stations throughout the Amundsen Sea and surrounding region of the Antarctic Margin, as part of the GP17-ANT Expedition. The secondary goal of this project is to analyze the concentrations and size partitioning of the trace metals manganese, zinc, copper, cadmium, nickel, and lead in all water-column samples, measure the isotope ratios of zinc, cadmium, nickel, and copper in a subset of water column samples, and measure the Fe isotopic signature of aerosols, porewaters, and particles. Observations from this project will be incorporated into regional and global biogeochemistry models to assess TEI cycling within the Amundsen Sea and implications for the wider Southern Ocean. This project spans three institutions, four graduate students, undergraduate students, and will provide ultrafiltered samples and data to other PIs as service.\r\n\r\nThe US GEOTRACES GP17 ANT expedition, planned for austral summer 2023/2024 aims to determine the distribution and cycling of trace elements and their isotopes in the Amundsen Sea Sector (100-135\u00b0W) of the Antarctic Margin. The cruise will follow the Amundsen Sea \u2018conveyor belt\u2019 by sampling waters coming from the Antarctic Circumpolar Current onto the continental shelf, including near the Dotson and Pine Island ice shelves, the productive Amundsen Sea Polynya (ASP), and outflowing waters. Episodic addition of dissolved Fe and other TEIs from dust, ice-shelves, melting ice, and sediments drive seasonal primary productivity and carbon export over the Antarctic shelf and offshore into Southern Ocean. Seasonal coastal polynyas such as the highly productive ASP thus act as key levers on global carbon cycling. However, field observations of TEIs in such regions remain scarce, and biogeochemical cycling processes are poorly captured in models of ocean biogeochemistry. The investigators will use their combined analytical toolbox, in collaboration with the diagnostic chemical tracers and regional models of other funded groups to address four main objectives: 1) What is the relative importance of different sources in supplying Fe and other TEIs to the ASP? 2) What is the physiochemical speciation of this Fe, and its potential for transport? 3) How do biological uptake, scavenging and regeneration in the ASP influence TEI distributions, stoichiometry, and nutrient limitation? 4) What is the flux and signature of TEIs transported offshore to the ACC and Southern Ocean?", "east": -100.0, "geometry": "POINT(-117.5 -71)", "instruments": null, "is_usap_dc": true, "keywords": "R/V NBP; Amundsen Sea; TRACE ELEMENTS; BIOGEOCHEMICAL CYCLES", "locations": "Amundsen Sea", "north": -66.0, "nsf_funding_programs": "Chemical Oceanography; Chemical Oceanography; Chemical Oceanography", "paleo_time": null, "persons": "Conway, Timothy; Fitzsimmons, Jessica; John, Seth", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repositories": null, "science_programs": null, "south": -76.0, "title": "Collaborative Research: US GEOTRACES GP17-ANT: Dissolved concentrations, isotopes, and colloids of the bioactive trace metals", "uid": "p0010374", "west": -135.0}, {"awards": "1903681 Brook, Edward", "bounds_geometry": null, "dataset_titles": "Preliminary nitrous oxide site preference isotopic data for last deglaciation from Taylor Glacier", "datasets": [{"dataset_uid": "601592", "doi": "10.15784/601592", "repository": "USAP-DC", "science_program": null, "title": "Preliminary nitrous oxide site preference isotopic data for last deglaciation from Taylor Glacier", "url": "http://www.usap-dc.org/view/dataset/601592"}], "date_created": "Tue, 02 Aug 2022 00:00:00 GMT", "description": null, "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "Antarctica; Nitrous Oxide; Taylor Glacier", "locations": "Taylor Glacier; Antarctica", "north": null, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Menking, Andy; Brook, Edward J.", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": null, "uid": null, "west": null}, {"awards": "1643664 Severinghaus, Jeffrey; 1643716 Buizert, Christo; 1643669 Petrenko, Vasilii", "bounds_geometry": "POLYGON((112 -66,112.2 -66,112.4 -66,112.6 -66,112.8 -66,113 -66,113.2 -66,113.4 -66,113.6 -66,113.8 -66,114 -66,114 -66.1,114 -66.2,114 -66.3,114 -66.4,114 -66.5,114 -66.6,114 -66.7,114 -66.8,114 -66.9,114 -67,113.8 -67,113.6 -67,113.4 -67,113.2 -67,113 -67,112.8 -67,112.6 -67,112.4 -67,112.2 -67,112 -67,112 -66.9,112 -66.8,112 -66.7,112 -66.6,112 -66.5,112 -66.4,112 -66.3,112 -66.2,112 -66.1,112 -66))", "dataset_titles": "Concentration and isotopic composition of atmospheric N2O over the last century; Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2; Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy", "datasets": [{"dataset_uid": "601693", "doi": "10.15784/601693", "keywords": "Antarctic; Antarctica; Anthropogenic Emission; Atmosphere; Greenhouse Gas; Greenland; Ice Core Data; Nitrification and Denitrification Processes; Nitrous Oxide; Site-specific 15N isotopomer; Styx Glacier", "people": "Etheridge, David; Yoshida, Naohiro ; Joong Kim, Seong; Ahn, Jinho ; Langenfelds, Ray L ; Buizert, Christo ; Toyoda, Sakae ; Ghosh, Sambit", "repository": "USAP-DC", "science_program": null, "title": "Concentration and isotopic composition of atmospheric N2O over the last century", "url": "https://www.usap-dc.org/view/dataset/601693"}, {"dataset_uid": "601597", "doi": "10.15784/601597", "keywords": "Antarctica; Ice Core; Law Dome; Noble Gas", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy", "url": "https://www.usap-dc.org/view/dataset/601597"}, {"dataset_uid": "601598", "doi": "10.15784/601598", "keywords": "Antarctica; Firn; Firn Density; Gravitational Settling; Inert Gases; Law Dome", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2", "url": "https://www.usap-dc.org/view/dataset/601598"}], "date_created": "Fri, 17 Jun 2022 00:00:00 GMT", "description": "Hydroxyl radicals are responsible for removal of most atmospheric trace gases, including pollutants and important greenhouse gases. They have been called the \"detergent of the atmosphere\". Changes in hydroxyl radical concentration in response to large changes in reactive trace gas emissions, which may happen in the future, are uncertain. This project aims to provide the first estimates of the variability of atmospheric hydroxyl radicals since about 1880 AD when anthropogenic emissions of reactive trace gases were minimal. This will improve understanding of their stability in response to large changes in emissions. The project will also investigate whether ice cores record past changes in Southern Hemisphere westerly winds. These winds are a key component of the global climate system, and have an important influence on ocean circulation and possibly on atmospheric carbon dioxide concentrations. The project team will include three early career scientists, a postdoctoral researcher, and graduate and undergraduate students, working in collaboration with senior scientists and Australian collaborators. \u003cbr/\u003e \u003cbr/\u003eFirn air and shallow ice to a depth of about 233 m will be sampled at the Law Dome high-accumulation coastal site in East Antarctica. Trapped air will be extracted from the ice cores on site immediately after drilling. Carbon-14 of carbon monoxide (14CO) will be analyzed in firn and ice-core air samples. Corrections will be made for the in situ cosmogenic 14CO component in the ice, allowing for the atmospheric 14CO history to be reconstructed. This 14CO history will be interpreted with the aid of a chemistry-transport model to place the first observational constraints on the variability of Southern Hemisphere hydroxyl radical concentration after about 1880 AD. An additional component of the project will analyze Krypton-86 in the firn-air and ice-core samples. These measurements will explore whether ice-core Krypton-86 acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere westerly winds.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 114.0, "geometry": "POINT(113 -66.5)", "instruments": null, "is_usap_dc": true, "keywords": "AMD; TRACE GASES/TRACE SPECIES; Law Dome; USAP-DC; LABORATORY; ICE CORE AIR BUBBLES; AMD/US; USA/NSF", "locations": "Law Dome", "north": -66.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Murray, Lee T; Buizert, Christo; Petrenko, Vasilii; Murray, Lee T", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -67.0, "title": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability", "uid": "p0010341", "west": 112.0}, {"awards": "2035580 Aarons, Sarah; 2035637 Tabor, Clay", "bounds_geometry": null, "dataset_titles": "Concentration and flux of ice core dust from ALHIC1903 drilled at the Allan Hills Blue Ice Area.; Oxygen and hydrogen isotope compositions of ice from ALHIC1903 drilled at the Allan Hills Blue Ice Area.; Rare earth elemental concentrations of leached ice core dust from ALHIC1903 drilled at the Allan Hills Blue Ice Area.; Strontium and neodymium isotope compositions of ice core dust from ALHIC1903 drilled at the Allan Hills Blue Ice Area.", "datasets": [{"dataset_uid": "601750", "doi": "10.15784/601750", "keywords": "ALHIC1903; Allan Hills; Antarctica; Blue Ice; Dust; Glaciology; Ice Core Records; Leach; Rare Earth Element; Snow/Ice", "people": "Carter, Austin", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Rare earth elemental concentrations of leached ice core dust from ALHIC1903 drilled at the Allan Hills Blue Ice Area.", "url": "https://www.usap-dc.org/view/dataset/601750"}, {"dataset_uid": "601748", "doi": "10.15784/601748", "keywords": "ALHIC1903; Allan Hills; Antarctica; Blue Ice; Concentration; Dust; Flux; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Snow/Ice", "people": "Carter, Austin", "repository": "USAP-DC", "science_program": null, "title": "Concentration and flux of ice core dust from ALHIC1903 drilled at the Allan Hills Blue Ice Area.", "url": "https://www.usap-dc.org/view/dataset/601748"}, {"dataset_uid": "601749", "doi": "10.15784/601749", "keywords": "ALHIC1903; Allan Hills; Antarctica; Dust; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Isotope; Nd; Neodymium; Snow/Ice; Sr; Strontium", "people": "Carter, Austin", "repository": "USAP-DC", "science_program": null, "title": "Strontium and neodymium isotope compositions of ice core dust from ALHIC1903 drilled at the Allan Hills Blue Ice Area.", "url": "https://www.usap-dc.org/view/dataset/601749"}, {"dataset_uid": "601751", "doi": "10.15784/601751", "keywords": "ALHIC1903; Allan Hills; Antarctica; Deuterium; Glaciology; Hydrogen; Ice; Ice Core Data; Ice Core Records; Isotope; Oxygen; Snow/Ice; Water", "people": "Carter, Austin", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Oxygen and hydrogen isotope compositions of ice from ALHIC1903 drilled at the Allan Hills Blue Ice Area.", "url": "https://www.usap-dc.org/view/dataset/601751"}], "date_created": "Wed, 06 Oct 2021 00:00:00 GMT", "description": "The spatial extent of the West Antarctic Ice Sheet during the last interglacial period (129,000 to 116,000 years ago) is currently unknown, yet this information is fundamental to projections of the future stability of the ice sheet in a warming climate. Paleoclimate records and proxy evidence such as dust can inform on past environmental conditions and ice-sheet coverage. This project will combine new, high-sensitivity geochemical measurements of dust from Antarctic ice collected at Allan Hills with existing water isotope records to document climate and environmental changes through the last interglacial period. These changes will then be compared with Earth-system model simulations of dust and water isotopes to determine past conditions and constrain the sensitivity of the West Antarctic Ice Sheet to warming. The project will test the hypothesis that the uncharacteristically volcanic dust composition observed at another peripheral ice core site at Taylor Glacier during the last interglacial period is related to changes in the spatial extent of the West Antarctic Ice Sheet.\r\n\r\nThis project aims to characterize mineral dust transport during the penultimate glacial-interglacial transition. The team will apply high-precision geochemical techniques to the high-volume, high-resolution ice core drilled at the Allan Hills site in combination with Earth system model simulations to: (1) determine if the volcanic dust signature found in interglacial ice from Taylor Glacier is also found at Allan Hills, (2) determine the likely dust source(s) to this site during the last interglacial, and (3) probe the atmospheric and environmental changes during the last interglacial with a diminished West Antarctic Ice Sheet. The team will develop a suite of measurements on previously drilled ice from Allan Hills, including isotopic compositions of Strontium and Neodymium, trace element concentrations, dust-size distribution, and imaging of ice-core dust to confirm the original signal observed and provide a broader spatial reconstruction of dust transport. In tandem, the team will conduct Earth system modeling with prognostic dust and water-isotope capability to test the sensitivity of dust transport under several plausible ice-sheet and freshwater-flux configurations. By comparing dust reconstruction and model simulations, the team aims to elucidate the driving mechanisms behind dust transport during the last interglacial period.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "MICROPARTICLE CONCENTRATION; FIELD SURVEYS; GEOCHEMISTRY; ICE EXTENT; USA/NSF; PALEOCLIMATE RECONSTRUCTIONS; AMD/US; AMD; Allan Hills; ICE CORE RECORDS; USAP-DC", "locations": "Allan Hills", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Aarons, Sarah; Tabor, Clay", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Peripheral East Antarctic ice as a unique recorder of climate variability during the Last Interglacial", "uid": "p0010270", "west": null}, {"awards": "2122248 Waters, Laura", "bounds_geometry": "POLYGON((-127.143608 -77.1380528,-127.1012394 -77.1380528,-127.0588708 -77.1380528,-127.0165022 -77.1380528,-126.9741336 -77.1380528,-126.931765 -77.1380528,-126.8893964 -77.1380528,-126.8470278 -77.1380528,-126.8046592 -77.1380528,-126.7622906 -77.1380528,-126.719922 -77.1380528,-126.719922 -77.14809141,-126.719922 -77.15813002,-126.719922 -77.16816863,-126.719922 -77.17820724,-126.719922 -77.18824585,-126.719922 -77.19828446,-126.719922 -77.20832307,-126.719922 -77.21836168,-126.719922 -77.22840029,-126.719922 -77.2384389,-126.7622906 -77.2384389,-126.8046592 -77.2384389,-126.8470278 -77.2384389,-126.8893964 -77.2384389,-126.931765 -77.2384389,-126.9741336 -77.2384389,-127.0165022 -77.2384389,-127.0588708 -77.2384389,-127.1012394 -77.2384389,-127.143608 -77.2384389,-127.143608 -77.22840029,-127.143608 -77.21836168,-127.143608 -77.20832307,-127.143608 -77.19828446,-127.143608 -77.18824585,-127.143608 -77.17820724,-127.143608 -77.16816863,-127.143608 -77.15813002,-127.143608 -77.14809141,-127.143608 -77.1380528))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 19 Aug 2021 00:00:00 GMT", "description": "Isotopic and sedimentary datasets reveal that volcanic activity typically increases during interglacial periods. However, the physical mechanisms through which changes in the surface loading affect volcanic magmatic plumbing systems remain unconstrained. Recently generated 40Ar/39Ar eruption ages indicate that 86% of the dated samples from Mt. Waesche, a late Quaternary volcano in Marie Byrd land, correlate with interglacial periods, suggesting this volcano uniquely responds to changes in the West Antarctic Ice Sheet. We propose to combine the petrology of Mount Waesche\u2019s volcanic record, constraints on changing ice loads through time, and geodynamic modelling to: (1) Determine how pre-eruptive storage conditions change during glacial and interglacial periods using whole rock and mineral compositions of volcanic rocks; (2) Conduct geodynamic modeling to elucidate the relationship between lithospheric structure, temporal variations in ice sheet thickness, and subsequent changes in crustal stresses and magmatic transport and, therefore, the mechanism(s) by which deglaciation impacts magmatic plumbing systems; (3) Use the outcomes of objectives (1) and (2) to provide new constraints on the changes in ice sheet thickness through time that could plausibly trigger future volcanic and magmatic activity in West Antarctica. This collaborative approach will provide a novel methodology to determine prior magnitudes and rates of ice load changes within the Marie Byrd Land region of Antarctica. Lastly, estimates of WAIS elevation changes from this study will be compared to ongoing studies at Mount Waesche focused on constraining last interglacial ice sheet draw down using cosmogenic exposure ages obtained from shallow drilling. The scope of work also includes a partnership with Mentoring Kids Works to develop several Polar and Earth Science Educational Modules aimed at improving reading skills in third grade students in New Mexico. The proposed Polar and Earth Science program consists of modules that include readings of books introducing students to Earth and Polar science themes, paired with Earth and Polar Science activities, followed by simple experiments, where students make predictions and collect data. Information required to implement our Polar and Earth Science curriculum will be made available online.", "east": -126.719922, "geometry": "POINT(-126.931765 -77.18824585)", "instruments": null, "is_usap_dc": true, "keywords": "Mt. Waesche; GEOCHEMISTRY; LITHOSPHERIC PLATE MOTION; STRESS; AMD/US; West Antarctica; Executive Committee Range; NOT APPLICABLE; USAP-DC; AMD; MAJOR ELEMENTS; USA/NSF; ROCKS/MINERALS/CRYSTALS", "locations": "West Antarctica; Mt. Waesche; Executive Committee Range", "north": -77.1380528, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Waters, Laura; Naliboff, John; Zimmerer, Matthew", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repositories": null, "science_programs": null, "south": -77.2384389, "title": "Integrating petrologic records and geodynamics: Quantifying the effects of glaciation on crustal stress and eruptive patterns at Mt. Waesche, Executive Committee Range, Antarctica", "uid": "p0010248", "west": -127.143608}, {"awards": "1644171 Blackburn, Terrence", "bounds_geometry": "POLYGON((162 -77.5,162.2 -77.5,162.4 -77.5,162.6 -77.5,162.8 -77.5,163 -77.5,163.2 -77.5,163.4 -77.5,163.6 -77.5,163.8 -77.5,164 -77.5,164 -77.525,164 -77.55,164 -77.575,164 -77.6,164 -77.625,164 -77.65,164 -77.675,164 -77.7,164 -77.725,164 -77.75,163.8 -77.75,163.6 -77.75,163.4 -77.75,163.2 -77.75,163 -77.75,162.8 -77.75,162.6 -77.75,162.4 -77.75,162.2 -77.75,162 -77.75,162 -77.725,162 -77.7,162 -77.675,162 -77.65,162 -77.625,162 -77.6,162 -77.575,162 -77.55,162 -77.525,162 -77.5))", "dataset_titles": "Isotopic ratios for subglacial precipitates from East Antarctica", "datasets": [{"dataset_uid": "200240", "doi": "10.26022/IEDA/111548 ", "keywords": null, "people": null, "repository": "EarthChem", "science_program": null, "title": "Isotopic ratios for subglacial precipitates from East Antarctica", "url": "https://doi.org/10.26022/IEDA/111548"}], "date_created": "Fri, 13 Aug 2021 00:00:00 GMT", "description": "The primary scientific goal of the proposed project is to test whether Taylor Valley, Antarctica has experienced glacial incision in the last ~1 million years in spite of cold climate conditions. One of the Dry Valleys of the Transantarctic Mountains, Taylor Valley exhibits over 2000 m of relief from sub sea-level troughs to high polar peaks. The Dry Valleys are characterized by low mean annual temperatures, paucity of precipitation and erosion that has allowed fragile glacial landforms, now subaerially exposed at high elevations, to be preserved for as long as 15 Ma. Two end member models can explain the timing of glacial incision and the observation that Quaternary advances of Taylor Glacier have left deposits at lower valley elevations with each advance. In the first scenario, all Valley relief is generated prior to 15 Ma when non-polar climates enabled warm-based glaciers to incise and widen fluvial channels more so than peaks. In this case, Quaternary drift deposits record advances of cold-based glaciers of decreasing ice volume. Limited glacial erosion and silt generation results in drift deposits composed primarily of recycled sediments. In the second scenario, selective erosion of the valley floor continues to deepen Taylor Valley over the last 2 Ma while high elevation peaks remain uneroded in polar conditions. The \u2018bathtub rings\u2019 of Quaternary drifts reaching a progressively lower elevation through time could be due to the lowering of the valley floor by subglacial erosion and with it, production of silt which is now incorporated into these drifts. While either scenario would result in the present day topography, they differ in the implied evolution of regional glacial ice volume over time and the timing of both valley relief production and generation of fine-grained particles. Here we propose to distinguish between these two models, by placing time constrains on fine particle production using U-series comminution dating. This new geochronologic tool exploits the loss of 234U due to alpha-recoil. The deficiency in 234U only becomes detectable in particles with a sufficiently high surface-area-to-volume ratio which can incur appreciable 234U loss (\u003c50 \uf0ecm). The timing of comminution and particle size controls the magnitude of 234U loss, up to 10% in silt-sized particles comminuted over 1.5 million years ago. And while this geochronologic tool is in its infancy, the scientific goal of this proposal can be achieved by resolving between ancient and recently comminuted fine particles, a binary question that our preliminary modeling and measured data show is readily resolved.", "east": 164.0, "geometry": "POINT(163 -77.625)", "instruments": null, "is_usap_dc": true, "keywords": "ICE SHEETS; Taylor Valley", "locations": "Taylor Valley", "north": -77.5, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Blackburn, Terrence; Tulaczyk, Slawek", "platforms": null, "repo": "EarthChem", "repositories": "EarthChem", "science_programs": null, "south": -77.75, "title": "U-Series Comminution Age Constraints on Taylor Valley Erosion", "uid": "p0010243", "west": 162.0}, {"awards": "1744871 Robinson, Rebecca", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Dissolved nutrients, cell counts, and nitrogen isotope measurements from Chaetoceros socialis culture experiments; ODP Site 1098 deglacial diatom assemblage; Sediment chemistry of ODP Site 1098", "datasets": [{"dataset_uid": "601720", "doi": "10.15784/601720", "keywords": "Antarctica; Antarctic Peninsula", "people": "Dove, Isabel", "repository": "USAP-DC", "science_program": null, "title": "Sediment chemistry of ODP Site 1098", "url": "https://www.usap-dc.org/view/dataset/601720"}, {"dataset_uid": "601727", "doi": "10.15784/601727", "keywords": "Antarctica", "people": "Dove, Isabel", "repository": "USAP-DC", "science_program": null, "title": "Dissolved nutrients, cell counts, and nitrogen isotope measurements from Chaetoceros socialis culture experiments", "url": "https://www.usap-dc.org/view/dataset/601727"}, {"dataset_uid": "601723", "doi": "10.15784/601723", "keywords": "Antarctica; Antarctic Peninsula; Glaciers/Ice Sheet", "people": "Dove, Isabel", "repository": "USAP-DC", "science_program": null, "title": "ODP Site 1098 deglacial diatom assemblage", "url": "https://www.usap-dc.org/view/dataset/601723"}], "date_created": "Wed, 28 Jul 2021 00:00:00 GMT", "description": "The chemical composition of diatom fossils in the Southern Ocean provides information about the environmental history of Antarctica, including sea ice extent, biological production, and ocean nutrient distribution. The sea ice zone is an important habitat for a group of diatoms, largely from the genus Chaetoceros, that have a unique life cycle stage under environmental stress, when they produce a structure called a resting spore. Resting spores are meant to reseed the surface ocean when conditions are more favorable. The production of these heavy resting spores tends to remove significant amounts of carbon and silicon, essential nutrients, out of the surface ocean. As a result, this group has the potential to remove carbon from the surface ocean and can impact the sedimentary record scientists use to reconstruct environmental change. \r\n\r\nThis project explores the role of resting spores and nutrients in the sedimentary record using the nitrogen isotopic signature of these fossils and how those measurements are used to estimate carbon cycle changes. Measurements of nitrogen stable isotopes of nitrate, biomass, and diatom-bound nitrogen and silicon-to-nitrogen ratios of individual species grown in the laboratory are used to quantify how resting spores record nutrient drawdown in the water column and to what degree their signature is biased toward low nutrient conditions. Laboratory incubations were conducted with surface sediment containing Chaetoceros spp.. The emergence of vegetative cells and subsequent formation of resting spores is manipulated with the addition of nutrients, primarily nitrate. The resulting samples, both of vegetative cells and resting spores were measured for diatom-bound d15N. Resting spore d15N values are consistently lower than the vegetative d15N \r\n from the same incubations. The incubation results will be used to quantify nutrient drawdown in sea ice environments during two contrasting intervals in earth history, the last ice age and the warm Pliocene. The project provided training and research opportunities for undergraduate and graduate students. Research efforts in Antarctic earth sciences are disseminated through an interactive display at the home institution and during university sponsored events.\r\n\r\nThis work addresses uncertainties in how Chaetoceros resting spores record surface nutrient conditions in their nitrogen stable isotopic composition, the relative impact of their specific signal with respect to the full sedimentary assemblage, and their potential to bias or enhance environmental reconstructions in the sea ice zone. \r\n", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "USAP-DC; Antarctica; ISOTOPES; MARINE SEDIMENTS; LABORATORY; USA/NSF; AMD/US; NITROGEN; AMD", "locations": "Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Robinson, Rebecca", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "The nitrogen isotopic composition of diatom resting spores in Southern Ocean sediments: A source of bias and/or paleoenvironmental information?", "uid": "p0010234", "west": -180.0}, {"awards": "2042495 Blackburn, Terrence; 2045611 Rasbury, Emma", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": null, "datasets": null, "date_created": "Fri, 18 Jun 2021 00:00:00 GMT", "description": "Efforts to improve sea level forecasting on a warming planet have focused on determining the temperature, sea level and extent of polar ice sheets during Earth\u2019s past warm periods. Large uncertainties, however, in reconstructions of past and future sea levels, result from the poorly constrained climate sensitivity of the Antarctic Ice sheet (AIS). This research project aims to develop the use of subglacial precipitates as an archive the Antarctic ice sheet (AIS) past response to climate change. The subglacial precipitates from East Antarctica form in water bodies beneath Antarctic ice and in doing so provide an entirely new and unique measure of how the AIS responds to climate change. In preliminary examination of these precipitates, we identified multiple samples consisting of cyclic opal and calcite that spans hundreds of thousands of years in duration. Our preliminary geochemical characterization of these samples indicates that the observed mineralogic changes result from a cyclic change in subglacial water compositions between isotopically and chemically distinct waters. Opal-forming waters are reduced (Ce* \u003c1 and high Fe/Mn) and exhibit elevated 234U/238U compositions similar to the saline groundwater brines found at the periphery of the AIS. Calcite-forming waters, are rather, oxidized and exhibit \u03b418O compositions consistent with derivation from the depleted polar plateau (\u003c -50 \u2030). 234U-230Th dates permit construction of a robust timeseries describing these mineralogic and compositional changes through time. Comparisons of these time series with other Antarctic climate records (e.g., ice core records) reveal that calcite forming events align with millennial scale changes in local temperature or \u201cAntarctic isotopic maximums\u201d, which represent Southern Hemisphere warm periods during low Atlantic Meridional overturning circulation. Ultimately, this project seeks to develop a comprehensive model as to how changes in the thermohaline cycle induce a glaciologic response which in turn induces a change in the composition of subglacial waters and the mineralogic phase recorded within the precipitate archive. ", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "GLACIERS/ICE SHEETS; FIELD INVESTIGATION; AMD; USA/NSF; USAP-DC; East Antarctica; AMD/US", "locations": "East Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": null, "persons": "Blackburn, Terrence; Tulaczyk, Slawek; Hain, Mathis; Rasbury, Troy", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION", "repositories": null, "science_programs": null, "south": -90.0, "title": "Collaborative Research: Reconstructing East Antarctica\u2019s Past Response to Climate using Subglacial Precipitates", "uid": "p0010192", "west": -180.0}, {"awards": "1724670 Williams, Trevor", "bounds_geometry": "POLYGON((-70 -60,-65 -60,-60 -60,-55 -60,-50 -60,-45 -60,-40 -60,-35 -60,-30 -60,-25 -60,-20 -60,-20 -62.5,-20 -65,-20 -67.5,-20 -70,-20 -72.5,-20 -75,-20 -77.5,-20 -80,-20 -82.5,-20 -85,-25 -85,-30 -85,-35 -85,-40 -85,-45 -85,-50 -85,-55 -85,-60 -85,-65 -85,-70 -85,-70 -82.5,-70 -80,-70 -77.5,-70 -75,-70 -72.5,-70 -70,-70 -67.5,-70 -65,-70 -62.5,-70 -60))", "dataset_titles": "Argon thermochronological data on detrital mineral grains from the Weddell Sea embayment", "datasets": [{"dataset_uid": "601377", "doi": "10.15784/601377", "keywords": "40Ar/39Ar thermochronology; Antarctica; Argon; Chemistry:Sediment; Detrital Minerals; Glaciers/Ice Sheet; Marine Sediments; Mass Spectrometer; Provenance; R/V Polarstern; Sediment Core Data; Subglacial Till; Till; Weddell Sea", "people": "Williams, Trevor", "repository": "USAP-DC", "science_program": null, "title": "Argon thermochronological data on detrital mineral grains from the Weddell Sea embayment", "url": "https://www.usap-dc.org/view/dataset/601377"}, {"dataset_uid": "601378", "doi": "10.15784/601378", "keywords": "40Ar/39Ar thermochronology; Antarctica; Argon; Chemistry:Sediment; Detrital Minerals; Glaciers/Ice Sheet; Marine Sediments; Mass Spectrometer; Provenance; R/V Polarstern; Sediment Core Data; Subglacial Till; Till; Weddell Sea", "people": "Williams, Trevor", "repository": "USAP-DC", "science_program": null, "title": "Argon thermochronological data on detrital mineral grains from the Weddell Sea embayment", "url": "https://www.usap-dc.org/view/dataset/601378"}, {"dataset_uid": "601379", "doi": "10.15784/601379", "keywords": "40Ar/39Ar thermochronology; Antarctica; Argon; Chemistry:Sediment; Detrital Minerals; Glaciers/Ice Sheet; Marine Geoscience; Mass Spectrometer; Provenance; R/V Polarstern; Sediment Core Data; Subglacial Till; Till; Weddell Sea", "people": "Williams, Trevor", "repository": "USAP-DC", "science_program": null, "title": "Argon thermochronological data on detrital mineral grains from the Weddell Sea embayment", "url": "https://www.usap-dc.org/view/dataset/601379"}], "date_created": "Thu, 10 Sep 2020 00:00:00 GMT", "description": "Abstract for the general public:\u003cbr/\u003e\u003cbr/\u003eThe margins of the Antarctic ice sheet have advanced and retreated repeatedly over the past few million years. Melting ice from the last retreat, from 19,000 to 9,000 years ago, raised sea levels by 8 meters or more, but the extents of previous retreats are less well known. The main goal of this project is to understand how Antarctic ice retreats: fast or slow, stepped or steady, and which parts of the ice sheet are most prone to retreat. Antarctica loses ice by two main processes: melting of the underside of floating ice shelves and calving of icebergs. Icebergs themselves are ephemeral, but they carry mineral grains and rock fragments that have been scoured from Antarctic bedrock. As the icebergs drift and melt, this \u0027iceberg-rafted debris\u0027 falls to the sea-bed and is steadily buried in marine sediments to form a record of iceberg activity and ice sheet retreat. The investigators will read this record of iceberg-rafted debris to find when and where Antarctic ice destabilized in the past. This information can help to predict how Antarctic ice will behave in a warming climate. \u003cbr/\u003e\u003cbr/\u003eThe study area is the Weddell Sea embayment, in the Atlantic sector of Antarctica. Principal sources of icebergs are the nearby Antarctic Peninsula and Weddell Sea embayment, where ice streams drain about a quarter of Antarctic ice. The provenance of the iceberg-rafted debris (IRD), and the icebergs that carried it, will be found by matching the geochemical fingerprint (such as characteristic argon isotope ages) of individual mineral grains in the IRD to that of the corresponding source area. In more detail, the project will: \u003cbr/\u003e\u003cbr/\u003e1. Define the geochemical fingerprints of the source areas of the glacially-eroded material using samples from each major ice stream entering the Weddell Sea. Existing data indicates that the hinterland of the Weddell embayment is made up of geochemically distinguishable source areas, making it possible to apply geochemical provenance techniques to determine the origin of Antarctica icebergs. Few samples of onshore tills are available from this area, so this project includes fieldwork to collect till samples to characterize detritus supplied by the Recovery and Foundation ice streams. \u003cbr/\u003e\u003cbr/\u003e2. Document the stratigraphic changes in provenance of iceberg-rafted debris (IRD) and glacially-eroded material in two deep water sediment cores in the NW Weddell Sea. Icebergs calved from ice streams in the embayment are carried by the Weddell Gyre and deposit IRD as they pass over the core sites. The provenance information identifies which groups of ice streams were actively eroding and exporting detritus to the ocean (via iceberg rafting and bottom currents), and the stratigraphy of the cores shows the relative sequence of ice stream activity through time. A further dimension is added by determining the time lag between fine sediment erosion and deposition, using a new method of uranium-series isotope measurements in fine grained material. \u003cbr/\u003e\u003cbr/\u003eTechnical abstract:\u003cbr/\u003e\u003cbr/\u003e The behavior of the Antarctic ice sheets and ice streams is a critical topic for climate change and future sea level rise. The goal of this proposal is to constrain ice sheet response to changing climate in the Weddell Sea during the three most recent glacial terminations, as analogues for potential future warming. The project will also examine possible contributions to Meltwater Pulse 1A, and test the relative stability of the ice streams draining East and West Antarctica. Much of the West Antarctic ice may have melted during the Eemian (130 to 114 Ka), so it may be an analogue for predicting future ice drawdown over the coming centuries. \u003cbr/\u003e\u003cbr/\u003eGeochemical provenance fingerprinting of glacially eroded detritus provides a novel way to reconstruct the location and relative timing of glacial retreat during these terminations in the Weddell Sea embayment. The two major objectives of the project are to: \u003cbr/\u003e\u003cbr/\u003e1. Define the provenance source areas by characterizing Ar, U-Pb, and Nd isotopic signatures, and heavy mineral and Fe-Ti oxide compositions of detrital minerals from each major ice stream entering the Weddell Sea, using onshore tills and existing sediment cores from the Ronne and Filchner Ice Shelves. Pilot data demonstrate that detritus originating from the east and west sides of the Weddell Sea embayment can be clearly distinguished, and published data indicates that the hinterland of the embayment is made up of geochemically distinguishable source areas. Few samples of onshore tills are available from this area, so this project includes fieldwork to collect till to characterize detritus supplied by the Recovery and Foundation ice streams. \u003cbr/\u003e\u003cbr/\u003e2. Document the stratigraphic changes in provenance of iceberg-rafted debris (IRD) and glacially-eroded material in two deep water sediment cores in the NW Weddell Sea. Icebergs calved from ice streams in the embayment are carried by the Weddell Gyre and deposit IRD as they pass over the core sites. The provenance information will identify which ice streams were actively eroding and exporting detritus to the ocean (via iceberg rafting and bottom currents). The stratigraphy of the cores will show the relative sequence of ice stream activity through time. A further time dimension is added by determining the time lag between fine sediment erosion and deposition, using U-series comminution ages.", "east": -20.0, "geometry": "POINT(-45 -72.5)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e SEDIMENT CORERS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "TERRIGENOUS SEDIMENTS; AMD/US; Subglacial Till; USAP-DC; ICEBERGS; AMD; USA/NSF; ISOTOPES; AGE DETERMINATIONS; Argon; Provenance; Till; R/V POLARSTERN; FIELD INVESTIGATION; SEDIMENT CHEMISTRY; Weddell Sea; Antarctica; LABORATORY", "locations": "Weddell Sea; Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Williams, Trevor; Hemming, Sidney R.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY; WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V POLARSTERN", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -85.0, "title": "Collaborative Research: Deglacial Ice Dynamics in the Weddell Sea Embayment using Sediment Provenance", "uid": "p0010128", "west": -70.0}, {"awards": "1543537 Priscu, John; 1543396 Christner, Brent; 1543453 Lyons, W. Berry; 1543347 Rosenheim, Brad; 1543441 Fricker, Helen; 1543405 Leventer, Amy", "bounds_geometry": "POLYGON((-163.611 -84.33543,-162.200034 -84.33543,-160.789068 -84.33543,-159.378102 -84.33543,-157.967136 -84.33543,-156.55617 -84.33543,-155.145204 -84.33543,-153.734238 -84.33543,-152.323272 -84.33543,-150.912306 -84.33543,-149.50134 -84.33543,-149.50134 -84.3659157,-149.50134 -84.3964014,-149.50134 -84.4268871,-149.50134 -84.4573728,-149.50134 -84.4878585,-149.50134 -84.5183442,-149.50134 -84.5488299,-149.50134 -84.5793156,-149.50134 -84.6098013,-149.50134 -84.640287,-150.912306 -84.640287,-152.323272 -84.640287,-153.734238 -84.640287,-155.145204 -84.640287,-156.55617 -84.640287,-157.967136 -84.640287,-159.378102 -84.640287,-160.789068 -84.640287,-162.200034 -84.640287,-163.611 -84.640287,-163.611 -84.6098013,-163.611 -84.5793156,-163.611 -84.5488299,-163.611 -84.5183442,-163.611 -84.4878585,-163.611 -84.4573728,-163.611 -84.4268871,-163.611 -84.3964014,-163.611 -84.3659157,-163.611 -84.33543))", "dataset_titles": "Antarctica - PI Continuous - GZ01-WIS_GroundingZone_01 P.S. - GPS/GNSS Observations Dataset; Antarctica - PI Continuous - GZ13-WIS_GroundingZone_13 P.S. - GPS/GNSS Observations Dataset; Antarctica - PI Continuous - LA02-WIS_LAKES_02 P.S. - GPS/GNSS Observations Dataset; Antarctica - PI Continuous - LA06-WIS_LAKES_06 P.S. - GPS/GNSS Observations Dataset; Antarctica - PI Continuous - LA07-WIS_LAKES_07 P.S. - GPS/GNSS Observations Dataset; Antarctica - PI Continuous - LA09-WIS_LAKES_09 P.S. - GPS/GNSS Observations Dataset; Bistatic Radar Sounding of Whillans Ice Stream, Antarctica and Store Glacier, Greenland; CTD data from Mercer Subglacial Lake and access borehole; Discrete bulk sediment properties data from Mercer Subglacial Lake; Isotopic data from Whillans Ice Stream grounding zone, West Antarctica; Mercer Subglacial Lake radiocarbon and stable isotope data ; Mercer Subglacial Lake (SLM) microbial composition: 16S rRNA genes (Sequence Read Archive; BioProject: PRJNA790995); Mercer Subglacial Lake (SLM) noble gas and isotopic data; Mercer Subglacial Lake water column viral metagenomic sequencing; Salsa sediment cores; Sediment porewater properties data from Mercer Subglacial Lake; Water column biogeochemical data from Mercer Subglacial Lake", "datasets": [{"dataset_uid": "601672", "doi": "10.15784/601672", "keywords": "Antarctica; Isotope; Mercer Subglacial Lake; Radiocarbon; subglacial lake", "people": "Venturelli, Ryan; Rosenheim, Brad", "repository": "USAP-DC", "science_program": null, "title": "Mercer Subglacial Lake radiocarbon and stable isotope data ", "url": "https://www.usap-dc.org/view/dataset/601672"}, {"dataset_uid": "601360", "doi": "10.15784/601360", "keywords": "Antarctica; Radiocarbon; Sediment; Whillans Ice Stream", "people": "Venturelli, Ryan A", "repository": "USAP-DC", "science_program": "WISSARD", "title": "Isotopic data from Whillans Ice Stream grounding zone, West Antarctica", "url": "https://www.usap-dc.org/view/dataset/601360"}, {"dataset_uid": "200342", "doi": null, "keywords": null, "people": null, "repository": "GenBank", "science_program": null, "title": "Mercer Subglacial Lake water column viral metagenomic sequencing", "url": "https://www.ncbi.nlm.nih.gov/biosample/32811410"}, {"dataset_uid": "200282", "doi": "", "keywords": null, "people": null, "repository": "NCBI GenBank", "science_program": null, "title": "Mercer Subglacial Lake (SLM) microbial composition: 16S rRNA genes (Sequence Read Archive; BioProject: PRJNA790995)", "url": "https://www.ncbi.nlm.nih.gov/bioproject/?term=PRJNA790995"}, {"dataset_uid": "601472", "doi": "10.15784/601472", "keywords": "Antarctica; Bistatic Radar; Glaciers/Ice Sheet; Glaciology; GPS Data; Greenland; Lake Whillans; Radar; Store Glacier; Whillans Ice Stream; WISSARD", "people": "Bienert, Nicole; Christoffersen, Poul; Dawson, Eliza; MacKie, Emma; Peters, Sean; Siegfried, Matthew; Schroeder, Dustin", "repository": "USAP-DC", "science_program": "WISSARD", "title": "Bistatic Radar Sounding of Whillans Ice Stream, Antarctica and Store Glacier, Greenland", "url": "https://www.usap-dc.org/view/dataset/601472"}, {"dataset_uid": "200246", "doi": "", "keywords": null, "people": null, "repository": "OSU-MGR", "science_program": null, "title": "Salsa sediment cores", "url": "https://osu-mgr.org"}, {"dataset_uid": "200217", "doi": "10.7283/3JMY-Y504", "keywords": null, "people": null, "repository": "UNAVCO", "science_program": null, "title": "Antarctica - PI Continuous - LA09-WIS_LAKES_09 P.S. - GPS/GNSS Observations Dataset", "url": "https://www.unavco.org/data/doi/10.7283/3JMY-Y504"}, {"dataset_uid": "200216", "doi": "10.7283/F8NH-CV04", "keywords": null, "people": null, "repository": "UNAVCO", "science_program": null, "title": "Antarctica - PI Continuous - LA07-WIS_LAKES_07 P.S. - GPS/GNSS Observations Dataset", "url": "https://www.unavco.org/data/doi/10.7283/F8NH-CV04"}, {"dataset_uid": "200215", "doi": "10.7283/C503-KS23", "keywords": null, "people": null, "repository": "UNAVCO", "science_program": null, "title": "Antarctica - PI Continuous - LA06-WIS_LAKES_06 P.S. - GPS/GNSS Observations Dataset", "url": "https://www.unavco.org/data/doi/10.7283/C503-KS23"}, {"dataset_uid": "200214", "doi": "10.7283/YW8Z-TK03", "keywords": null, "people": null, "repository": "UNAVCO", "science_program": null, "title": "Antarctica - PI Continuous - LA02-WIS_LAKES_02 P.S. - GPS/GNSS Observations Dataset", "url": "https://www.unavco.org/data/doi/10.7283/YW8Z-TK03"}, {"dataset_uid": "200213", "doi": "10.7283/F7BB-JH05", "keywords": null, "people": null, "repository": "UNAVCO", "science_program": null, "title": "Antarctica - PI Continuous - GZ13-WIS_GroundingZone_13 P.S. - GPS/GNSS Observations Dataset", "url": "https://www.unavco.org/data/doi/10.7283/F7BB-JH05"}, {"dataset_uid": "200212", "doi": "10.7283/PT0Q-JB95", "keywords": null, "people": null, "repository": "UNAVCO", "science_program": null, "title": "Antarctica - PI Continuous - GZ01-WIS_GroundingZone_01 P.S. - GPS/GNSS Observations Dataset", "url": "https://www.unavco.org/data/doi/10.7283/PT0Q-JB95"}, {"dataset_uid": "601498", "doi": "10.15784/601498", "keywords": "Antarctica; Mercer Subglacial Lake; Noble Gas", "people": "Lyons, W. Berry; Gardner, Christopher B.", "repository": "USAP-DC", "science_program": null, "title": "Mercer Subglacial Lake (SLM) noble gas and isotopic data", "url": "https://www.usap-dc.org/view/dataset/601498"}, {"dataset_uid": "601664", "doi": "10.15784/601664", "keywords": "Antarctica; Gas; Geochemistry; Glacier; Glaciology; Mercer Subglacial Lake; Methane; SALSA; Sediment Core; West Antarctic Ice Sheet", "people": "Michaud, Alexander; Dore, John; Steigmeyer, August; Skidmore, Mark; Science Team, SALSA; Tranter, Martyn", "repository": "USAP-DC", "science_program": null, "title": "Sediment porewater properties data from Mercer Subglacial Lake", "url": "https://www.usap-dc.org/view/dataset/601664"}, {"dataset_uid": "601663", "doi": "10.15784/601663", "keywords": "Antarctica; Carbon; Cell Counts; Geochemistry; Glacier; Glaciers/Ice Sheet; Mercer Subglacial Lake; Microbes; Nutrients; SALSA; Stable Isotopes; Trace Elements; West Antarctic Ice Sheet", "people": "Hawkings, Jon; Tranter, Martyn; Barker, Joel; Skidmore, Mark; Li, Wei; Dore, John; Steigmeyer, August; Science Team, SALSA; Priscu, John", "repository": "USAP-DC", "science_program": null, "title": "Water column biogeochemical data from Mercer Subglacial Lake", "url": "https://www.usap-dc.org/view/dataset/601663"}, {"dataset_uid": "601661", "doi": "10.15784/601661", "keywords": "Antarctica; Carbon; Glacier; Glaciers/Ice Sheet; Iron; Mercer Subglacial Lake; Mineralogy; Particle Size; Physical Properties; SALSA; Sediment Core; sulfur; West Antarctic Ice Sheet", "people": "Hawkings, Jon; Science Team, SALSA; Venturelli, Ryan A; Tranter, Martyn; Skidmore, Mark; Michaud, Alexander; Campbell, Timothy; Dore, John", "repository": "USAP-DC", "science_program": null, "title": "Discrete bulk sediment properties data from Mercer Subglacial Lake", "url": "https://www.usap-dc.org/view/dataset/601661"}, {"dataset_uid": "601657", "doi": "10.15784/601657", "keywords": "Antarctica; Conductivity; CTD; Depth; Glaciers/Ice Sheet; Glaciology; Hot Water Drill; Mercer Subglacial Lake; Physical Properties; SALSA; subglacial lake; Temperature", "people": "Dore, John; Priscu, John; Leventer, Amy; Rosenheim, Brad", "repository": "USAP-DC", "science_program": null, "title": "CTD data from Mercer Subglacial Lake and access borehole", "url": "https://www.usap-dc.org/view/dataset/601657"}], "date_created": "Thu, 16 Jul 2020 00:00:00 GMT", "description": "The Antarctic subglacial environment remains one of the least explored regions on Earth. This project will examine the physical and biological characteristics of Subglacial Lake Mercer, a lake that lies 1200m beneath the West Antarctic Ice Sheet. This study will address key questions relating to the stability of the ice sheet, the subglacial hydrological system, and the deep-cold subglacial biosphere. The education and outreach component aims to widely disseminate results to the scientific community and to the general public through short films, a blog, and a website.\u003cbr/\u003e\u003cbr/\u003eSubglacial Lake Mercer is one of the larger hydrologically active lakes in the southern basin of the Whillans Ice Plain, West Antarctica. It receives about 25 percent of its water from East Antarctica with the remainder originating from West Antarctica, is influenced by drain/fill cycles in a lake immediately upstream (Subglacial Lake Conway), and lies about 100 km upstream of the present grounding line of the Ross Ice Shelf. This site will yield information on the history of the Whillans and Mercer Ice Streams, and on grounding line migration. The integrated study will include direct sampling of basal ice, water, and sediment from the lake in concert with surface geophysical surveys over a three-year period to define the hydrological connectivity among lakes on the Whillans Ice Plain and their flow paths to the sea. The geophysical surveys will furnish information on subglacial hydrology, aid the site selection for hot-water drilling, and provide spatial context for interpreting findings. The hot-water-drilled boreholes will be used to collect basal ice samples, provide access for direct measurement of subglacial physical, chemical, and biological conditions in the water column and sediments, and to explore the subglacial water cavities using a remotely operated vehicle equipped with sensors, cameras, and sampling equipment. Data collected from this study will address the overarching hypothesis \\\"Contemporary biodiversity and carbon cycling in hydrologically-active subglacial environments associated with the Mercer and Whillans ice streams are regulated by the mineralization and cycling of relict marine organic matter and through interactions among ice, rock, water, and sediments\\\". The project will be undertaken by a collaborative team of scientists, with expertise in microbiology, biogeochemistry, hydrology, geophysics, glaciology, marine geology, paleoceanography, and science communication.", "east": -149.50134, "geometry": "POINT(-156.55617 -84.4878585)", "instruments": null, "is_usap_dc": true, "keywords": "SEDIMENTS; Antarctica; ISOTOPES; USAP-DC; VIRUSES; PALEOCLIMATE RECONSTRUCTIONS; BACTERIA/ARCHAEA; LABORATORY; Radiocarbon; Whillans Ice Stream; AMD; SALSA; ECOSYSTEM FUNCTIONS; RADIOCARBON; FIELD INVESTIGATION; AMD/US; ICE MOTION; subglacial lake; Mercer Ice Stream; USA/NSF; GLACIERS/ICE SHEETS", "locations": "Antarctica; Mercer Ice Stream; Whillans Ice Stream", "north": -84.33543, "nsf_funding_programs": "Antarctic Integrated System Science; Antarctic Integrated System Science; Antarctic Integrated System Science; Antarctic Integrated System Science; Antarctic Glaciology; Antarctic Integrated System Science; Antarctic Glaciology; Antarctic Instrumentation and Support; Antarctic Integrated System Science; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Rosenheim, Brad; Fricker, Helen; Priscu, John; Leventer, Amy; Dore, John; Lyons, W. Berry; Christner, Brent", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "GenBank; NCBI GenBank; OSU-MGR; UNAVCO; USAP-DC", "science_programs": null, "south": -84.640287, "title": "Collaborative Research: Subglacial Antarctic Lakes Scientific Access (SALSA): Integrated Study of Carbon Cycling in Hydrologically-active Subglacial Environments", "uid": "p0010119", "west": -163.611}, {"awards": "1443482 Mak, John", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Carbon monoxide mixing ratios and stable isotopic values, SPICE", "datasets": [{"dataset_uid": "601356", "doi": "10.15784/601356", "keywords": "Antarctica; CO; Delta 13C; Delta 18O; South Pole; SPICEcore", "people": "Mak, John", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Carbon monoxide mixing ratios and stable isotopic values, SPICE", "url": "https://www.usap-dc.org/view/dataset/601356"}], "date_created": "Thu, 09 Jul 2020 00:00:00 GMT", "description": "The investigators plan to reconstruct historical variations in the sources of atmospheric carbon monoxide (CO) from measurements of the concentration and stable isotopic abundance of carbon monoxide ([CO], 13CO and C18O) in the South Pole Ice Core, which is being drilled in 2014-2016. The goal is to strategically sample and reconstruct the relative variations in CO source strengths over the past 20,000 years. These will be the first measurements to extend the CO record beyond 650 years before present, back to the last glacial maximum. Both atmospheric chemical processes and variations in CO sources can impact the CO budget, and variations in the CO budget are useful in identifying and quantifying chemistry-climate interactions.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "LABORATORY; TRACE GASES/TRACE SPECIES; FIELD INVESTIGATION; South Pole", "locations": "South Pole", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Mak, John", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Using Stable Isotopes to Constrain the Atmospheric Carbon Monoxide Budget over the Last 20,000 Years", "uid": "p0010117", "west": -180.0}, {"awards": "1246465 Brook, Edward", "bounds_geometry": "POINT(-112.1115 -79.481)", "dataset_titles": "WAIS Divide Ice Core Marine Isotope Stage 3 CO2 record", "datasets": [{"dataset_uid": "601337", "doi": "10.15784/601337", "keywords": "Antarctica; Carbon Cycle; CO2; Gas Chromatograph; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; WAIS divide", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Ice Core Marine Isotope Stage 3 CO2 record", "url": "https://www.usap-dc.org/view/dataset/601337"}], "date_created": "Mon, 22 Jun 2020 00:00:00 GMT", "description": "This award supports a project to measure the carbon dioxide (CO2) concentration in the WAIS Divide ice core covering the time period 25,000 to 60,000 years before present, and to analyze the isotopic composition of CO2 in selected time intervals. The research will improve understanding of how and why atmospheric CO2 varied during the last ice age, focusing particularly on abrupt transitions in the concentration record that are associated with abrupt climate change. These events represents large perturbations to the global climate system and better information about the CO2 response should inform our understanding of carbon cycle-climate feedbacks and radiative forcing of climate. The research will also improve analytical methods in support of these goals, including completing development of sublimation methods to replace laborious mechanical crushing of ice to release air for analysis. The intellectual merit of the proposed work is that it will increase knowledge about the magnitude and timing of atmospheric CO2 variations during the last ice age, and their relationship to regional climate in Antarctica, global climate history, and the history of abrupt climate change in the Northern Hemisphere. The temporal resolution of the proposed record will in most intervals be ~ 4 x higher than previous data sets for this time period, and for selected intervals up to 8-10 times higher. Broader impacts of the proposed work include a significant addition to the amount of data documenting the history of the most important long-lived greenhouse gas in the atmosphere and more information about carbon cycle-climate feedbacks - important parameters for predicting future climate change. The project will contribute to training a postdoctoral researcher, research experience for an undergraduate and a high school student, and outreach to local middle school and other students. It will also improve the analytical infrastructure at OSU, which will be available for future projects.", "east": -112.1115, "geometry": "POINT(-112.1115 -79.481)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Carbon Cycle; Ice Core Records; USAP-DC; CO2; FIELD INVESTIGATION; CARBON DIOXIDE; WAIS divide; LABORATORY", "locations": "WAIS divide", "north": -79.481, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.481, "title": "Completing the WAIS Divide Ice Core CO2 record", "uid": "p0010110", "west": -112.1115}, {"awards": "1341432 Brzezinski, Mark; 1341464 Robinson, Rebecca", "bounds_geometry": "POLYGON((-175 -54,-174 -54,-173 -54,-172 -54,-171 -54,-170 -54,-169 -54,-168 -54,-167 -54,-166 -54,-165 -54,-165 -55.3,-165 -56.6,-165 -57.9,-165 -59.2,-165 -60.5,-165 -61.8,-165 -63.1,-165 -64.4,-165 -65.7,-165 -67,-166 -67,-167 -67,-168 -67,-169 -67,-170 -67,-171 -67,-172 -67,-173 -67,-174 -67,-175 -67,-175 -65.7,-175 -64.4,-175 -63.1,-175 -61.8,-175 -60.5,-175 -59.2,-175 -57.9,-175 -56.6,-175 -55.3,-175 -54))", "dataset_titles": "Diatom assemblage counts from NBP17-02 shipboard carboy experiments; Dissolved nutrient profiles from along 170\u00b0W between 67 and 54\u00b0S; Expedition Data of NBP1702; Particle composition measurements from along 170\u00b0W between 67-54\u00b0S; Particulate silicon and nitrogen concentrations and isotopic composition measurements in McLane pump profiles from 67\u00b0S to 55\u00b0S latitude in the Pacific Sector of the Southern Ocean; Silicon concentration and isotopic composition measurements in pore waters and sediments from 67\u00b0S to 55\u00b0S latitude in the Pacific Sector of the Southern Ocean; Surface Southern Ocean community growouts to evaluate the diatom bound N isotope proxy", "datasets": [{"dataset_uid": "601576", "doi": "10.15784/601576", "keywords": "Antarctica; Biogenic Silica; Chemistry:Sediment; Diatom; Diatom Bound; Lithogenic Silica; Marine Geoscience; NBP1702; Nitrogen Isotopes; Silicon Cycle; Silicon Stable Isotope; Southern Ocean", "people": "Robinson, Rebecca; Jones, Janice L.; Brzezinski, Mark; Closset, Ivia", "repository": "USAP-DC", "science_program": null, "title": " Particulate silicon and nitrogen concentrations and isotopic composition measurements in McLane pump profiles from 67\u00b0S to 55\u00b0S latitude in the Pacific Sector of the Southern Ocean", "url": "https://www.usap-dc.org/view/dataset/601576"}, {"dataset_uid": "601276", "doi": "10.15784/601276", "keywords": "Antarctica; Biogenic Silica; Nitrogen Isotopes; Southern Ocean", "people": "Robinson, Rebecca; Brzezinski, Mark", "repository": "USAP-DC", "science_program": null, "title": "Particle composition measurements from along 170\u00b0W between 67-54\u00b0S", "url": "https://www.usap-dc.org/view/dataset/601276"}, {"dataset_uid": "601523", "doi": "10.15784/601523", "keywords": "Antarctica; Biota; Carboy Growouts; Diatom; Diatom Assemblage Data; NBP1702; Oceans; R/V Nathaniel B. Palmer; Southern Ocean; Southern Ocean Summer", "people": "Robinson, Rebecca; Riesselman, Christina; Robinson, Rebecca ; Jones, Colin", "repository": "USAP-DC", "science_program": null, "title": "Diatom assemblage counts from NBP17-02 shipboard carboy experiments", "url": "https://www.usap-dc.org/view/dataset/601523"}, {"dataset_uid": "601522", "doi": "10.15784/601522", "keywords": "Antarctica; Nitrogen Isotopes; Oceans; Paleoproxies; Southern Ocean", "people": "Kelly, Roger; Riesselman, Christina; Brzezinski, Mark; Closset, Ivia; Robinson, Rebecca; Jones, Colin; Robinson, Rebecca ", "repository": "USAP-DC", "science_program": null, "title": "Surface Southern Ocean community growouts to evaluate the diatom bound N isotope proxy", "url": "https://www.usap-dc.org/view/dataset/601522"}, {"dataset_uid": "601269", "doi": "10.15784/601269", "keywords": "Antarctica; Chlorophyll; Southern Ocean", "people": "Brzezinski, Mark; Robinson, Rebecca", "repository": "USAP-DC", "science_program": null, "title": "Dissolved nutrient profiles from along 170\u00b0W between 67 and 54\u00b0S", "url": "https://www.usap-dc.org/view/dataset/601269"}, {"dataset_uid": "200126", "doi": "10.7284/907211", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data of NBP1702", "url": "https://www.rvdata.us/search/cruise/NBP1702"}, {"dataset_uid": "601562", "doi": "10.15784/601562", "keywords": "Antarctica; Biogenic Silica; Chemistry:Sediment; Lithogenic Silica; Marine Geoscience; NBP1702; Pore Water Biogeochemistry; Sediment; Silicon Cycle; Silicon Stable Isotope; Southern Ocean", "people": "Brzezinski, Mark; Jones, Janice L.; Closset, Ivia", "repository": "USAP-DC", "science_program": null, "title": "Silicon concentration and isotopic composition measurements in pore waters and sediments from 67\u00b0S to 55\u00b0S latitude in the Pacific Sector of the Southern Ocean", "url": "https://www.usap-dc.org/view/dataset/601562"}], "date_created": "Wed, 26 Feb 2020 00:00:00 GMT", "description": "The rise in atmospheric carbon dioxide concentrations and associated climate changes make understanding the role of the ocean in large scale carbon cycle a priority. Geologic samples allow exploration of potential mechanisms for carbon dioxide drawdown during glacial periods through the use of geochemical proxies. Nitrogen and silicon isotope signatures from fossil diatoms (microscopic plants) are used to investigate changes in the physical supply and biological demand for nutrients (like nitrogen and silicon and carbon) in the Southern Ocean. The project will evaluate the use the nitrogen and silicon isotope proxies through a series of laboratory experiments and Southern Ocean field sampling. The results will provide quantification of real relationships between nitrogen and silicon isotopes and nutrient usage in the Southern Ocean and allow exploration of the role of other factors, including biological diversity, ice cover, and mixing, in altering the chemical signatures recorded by diatoms. Seafloor sediment samples will be used to evaluate how well the signal created in the water column is recorded by fossil diatoms buried in the seafloor. Improving the nutrient isotope proxies will allow for a more quantitative understanding of the role of polar biology in regulating natural variation in atmospheric carbon dioxide. The project will also result in the training of a graduate student and development of outreach materials targeting a broad popular audience.\r\n\r\nThis project seeks to test the fidelity of the diatom nitrogen and silicon isotope proxies, two commonly used paleoceanographic tools for investigating the role of the Southern Ocean biological pump in regulating atmospheric CO2 concentrations on glacial-interglacial timescales. Existing ground-truthing data, including culture experiments, surface sediment data and downcore reconstructions, all suggest that nutrient utilization is the primary driver of isotopic variation in the Southern Ocean. However, strong contribution of interspecific variation is implied by recent culture results. Moreover, field and laboratory studies present some contradictory results in terms of the relative importance of interspecific variation and of inferred post-depositional alteration of the nutrient isotope signals. Here, a first order test of the N and Si diatom nutrient isotope paleo-proxies, involving water column dissolved and particulate sampling and laboratory culturing of field-isolates, is proposed. Southern Ocean water, biomass, live diatoms and fossil diatom sampling will be conducted to investigate species and assemblage related variability in diatom nitrogen and silicon isotopes and their relationship to surface nutrient fields and early diagenesis. Access to fresh materials produced in an analogous environmental context to the sediments of primary interest is critical for making robust paleoceanographic reconstructions. Field sampling will occur along 175\u00b0W, transecting the Antarctic Circumpolar Current from the subtropics to the marginal ice edge. Collection of water, sinking/suspended particles and multi-core samples from 13 stations and 3 shipboard incubation experiments will be used to test four proposed hypotheses that together evaluate the significance of existing culture results and seek to allow the best use of diatom nutrient isotope proxies in evaluating the biological pump.", "east": -165.0, "geometry": "POINT(-170 -60.5)", "instruments": null, "is_usap_dc": true, "keywords": "Southern Ocean; AMD; NITROGEN ISOTOPES; R/V NBP; AMD/US; NSF/USA; NUTRIENTS; USAP-DC", "locations": "Southern Ocean", "north": -54.0, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": null, "persons": "Robinson, Rebecca; Brzezinski, Mark", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "USAP-DC", "repositories": "R2R; USAP-DC", "science_programs": null, "south": -67.0, "title": "Collaborative Proposal: A Field and Laboratory Examination of the Diatom N and Si Isotope Proxies: Implications for Assessing the Southern Ocean Biological Pump", "uid": "p0010083", "west": -175.0}, {"awards": "1443296 Cottle, John", "bounds_geometry": "POLYGON((-180 -76.85314,-179.4383642 -76.85314,-178.8767284 -76.85314,-178.3150926 -76.85314,-177.7534568 -76.85314,-177.191821 -76.85314,-176.6301852 -76.85314,-176.0685494 -76.85314,-175.5069136 -76.85314,-174.9452778 -76.85314,-174.383642 -76.85314,-174.383642 -77.658865,-174.383642 -78.46459,-174.383642 -79.270315,-174.383642 -80.07604,-174.383642 -80.881765,-174.383642 -81.68749,-174.383642 -82.493215,-174.383642 -83.29894,-174.383642 -84.104665,-174.383642 -84.91039,-174.9452778 -84.91039,-175.5069136 -84.91039,-176.0685494 -84.91039,-176.6301852 -84.91039,-177.191821 -84.91039,-177.7534568 -84.91039,-178.3150926 -84.91039,-178.8767284 -84.91039,-179.4383642 -84.91039,180 -84.91039,177.4459565 -84.91039,174.891913 -84.91039,172.3378695 -84.91039,169.783826 -84.91039,167.2297825 -84.91039,164.675739 -84.91039,162.1216955 -84.91039,159.567652 -84.91039,157.0136085 -84.91039,154.459565 -84.91039,154.459565 -84.104665,154.459565 -83.29894,154.459565 -82.493215,154.459565 -81.68749,154.459565 -80.881765,154.459565 -80.07604,154.459565 -79.270315,154.459565 -78.46459,154.459565 -77.658865,154.459565 -76.85314,157.0136085 -76.85314,159.567652 -76.85314,162.1216955 -76.85314,164.675739 -76.85314,167.2297825 -76.85314,169.783826 -76.85314,172.3378695 -76.85314,174.891913 -76.85314,177.4459565 -76.85314,-180 -76.85314))", "dataset_titles": null, "datasets": null, "date_created": "Mon, 02 Dec 2019 00:00:00 GMT", "description": "Subduction takes place at convergent plate boundaries and involves sinking of one tectonic plate underneath another. Although this process is a key aspect of plate tectonics that shapes the planet over geologic time, and is a primary cause of earthquakes, it is not known what causes subduction to cease, and what effect it has on the deepest portions of the crust and the upper part of the mantle. By studying the age and composition of igneous rocks emplaced at the very end of the subduction cycle, this project seeks to understand what causes subduction to cease, and how this changes the composition and structure of the crust and upper mantle. Because this process occurs deep within the earth, the project will focus on rocks in the root of an ancient subduction zone, now exposed in the Transantarctic Mountains of Antarctica. In addition, Antarctica remains relatively poorly understood, and this project will contribute directly to increasing our understanding of the geologic history of this region. The project will focus on training graduate and undergraduate students - incorporating hands-on experience with an array of state-of-the-art analytical instrumentation. Students will also gain a range of more general skills including Geographic Information Systems (GIS), written and oral communication, and data management - strengths that are highly relevant to careers both in the academic and Geosciences industry. Each summer, high school students will be incorporated into aspects of the laboratory-based research through the UCSB research mentorship program. The PI and graduate students will engage the general public through a purpose-built iPhone App and multimedia website. Activities will include live phone and video conversations from the field between elementary school students and members of the team in Antarctica. \u003cbr/\u003e\u003cbr/\u003eThe mechanisms by which the deep crustal delaminates or \"founders\" and is returned to the mantle remains a fundamental problem in earth science. Specifically, little is known about the temporal and spatial scales over which this process occurs or the mechanisms that trigger such catastrophic events. Igneous rocks highly enriched in potassium, called lamprophyres, are often emplaced during, and immediately after, termination of subduction and therefore potentially provide direct insight into foundering. These enigmatic rocks are important because they represent near-primary mantle melt compositions and therefore their age, geochemistry and petrologic evolution reveal key information on both the composition of the upper mantle and its thermal state. Of equal importance, they reveal how these key parameters vary through both space and time. By evaluating lamprophyres along a subduction zone margin it is possible to extract: 1) local-scale information, such as the timing and duration of melting and the role of igneous crystallization processes in generation of isotopic heterogeneities; 2) along-strike variations in mantle source composition, temperature, and depth of melting 3) the plate-scale forces that control foundering and termination of subduction. This project will study a suite of lamprophyres along the axis of the Transantarctic Mountains, emplaced during the latest stages of the Neoproterozoic - Ordovician Ross orogeny, Antarctica (roughly 505 to 470 million years before present). High-precision geochronology (age determinations) will be combined with geochemical measurements on the rocks and minerals to understand the mechanisms and timing of deep crustal foundering/delamination.", "east": -174.383642, "geometry": "POINT(170.0379615 -80.881765)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "AGE DETERMINATIONS; ISOTOPES; PLATE TECTONICS; Antarctica; USAP-DC; NOT APPLICABLE", "locations": "Antarctica", "north": -76.85314, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Cottle, John", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repositories": null, "science_programs": null, "south": -84.91039, "title": "Petrologic Constraints on Subduction Termination From Lamprophyres, Ross Orogen, Antarctica", "uid": "p0010071", "west": 154.459565}, {"awards": "1643684 Saito, Mak; 1644073 DiTullio, Giacomo", "bounds_geometry": "POLYGON((-180 -72,-173.6 -72,-167.2 -72,-160.8 -72,-154.4 -72,-148 -72,-141.6 -72,-135.2 -72,-128.8 -72,-122.4 -72,-116 -72,-116 -72.7,-116 -73.4,-116 -74.1,-116 -74.8,-116 -75.5,-116 -76.2,-116 -76.9,-116 -77.6,-116 -78.3,-116 -79,-122.4 -79,-128.8 -79,-135.2 -79,-141.6 -79,-148 -79,-154.4 -79,-160.8 -79,-167.2 -79,-173.6 -79,180 -79,178 -79,176 -79,174 -79,172 -79,170 -79,168 -79,166 -79,164 -79,162 -79,160 -79,160 -78.3,160 -77.6,160 -76.9,160 -76.2,160 -75.5,160 -74.8,160 -74.1,160 -73.4,160 -72.7,160 -72,162 -72,164 -72,166 -72,168 -72,170 -72,172 -72,174 -72,176 -72,178 -72,-180 -72))", "dataset_titles": "Algal pigment concentrations from the Ross Sea; Biogenic silica concentrations from the Ross Sea; NBP1801 Expedition data; Nutrients from NBP18-01 CICLOPS", "datasets": [{"dataset_uid": "601205", "doi": "10.15784/601205", "keywords": "Antarctica; Chemistry:Fluid; Chlorophyll; Chromatography; Liquid Chromatograph; Oceans; Ross Sea; R/V Nathaniel B. Palmer; Sea Water; seawater measurements; Southern Ocean; Water Measurements; Water Samples", "people": "Ditullio, Giacomo", "repository": "USAP-DC", "science_program": null, "title": "Algal pigment concentrations from the Ross Sea", "url": "https://www.usap-dc.org/view/dataset/601205"}, {"dataset_uid": "601225", "doi": "10.15784/601225", "keywords": "Antarctica; Biogenic Silica; Biogenic Silica Concentrations ; Chemistry:Water; Geochemistry; NBP1801; Oceans; Ross Sea; R/V Nathaniel B. Palmer; Sea Water; Southern Ocean; Spectroscopy; Water Measurements; Water Samples", "people": "Ditullio, Giacomo; Schanke, Nicole", "repository": "USAP-DC", "science_program": null, "title": "Biogenic silica concentrations from the Ross Sea", "url": "https://www.usap-dc.org/view/dataset/601225"}, {"dataset_uid": "601428", "doi": "10.15784/601428", "keywords": "Amundsen Sea; Antarctica; NBP1801; Nitrate; Nitrite; Nutrients; Phosphate; Ross Sea; R/V Nathaniel B. Palmer; Silicic Acid; Terra Nova Bay", "people": "Saito, Mak", "repository": "USAP-DC", "science_program": null, "title": "Nutrients from NBP18-01 CICLOPS", "url": "https://www.usap-dc.org/view/dataset/601428"}, {"dataset_uid": "200056", "doi": "10.7284/907753", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "NBP1801 Expedition data", "url": "https://www.rvdata.us/search/cruise/NBP1801"}], "date_created": "Thu, 08 Aug 2019 00:00:00 GMT", "description": "Phytoplankton blooms in the coastal waters of the Ross Sea, Antarctica are typically dominated by either diatoms or Phaeocystis Antarctica (a flagellated algae that often can form large colonies in a gelatinous matrix). The project seeks to determine if an association of bacterial populations with Phaeocystis antarctica colonies can directly supply Phaeocystis with Vitamin B12, which can be an important co-limiting micronutrient in the Ross Sea. The supply of an essential vitamin coupled with the ability to grow at lower iron concentrations may put Phaeocystis at a competitive advantage over diatoms. Because Phaeocystis cells can fix more carbon than diatoms and Phaeocystis are not grazed as efficiently as diatoms, the project will help in refining understanding of carbon dynamics in the region as well as the basis of the food web webs. Such understanding also has the potential to help refine predictive ecological models for the region. The project will conduct public outreach activities and will contribute to undergraduate and graduate research. Engagement of underrepresented students will occur during summer student internships. A collaboration with Italian Antarctic researchers, who have been studying the Terra Nova Bay ecosystem since the 1980s, aims to enhance the project and promote international scientific collaborations. \u003cbr/\u003e\u003cbr/\u003eThe study will test whether a mutualistic symbioses between attached bacteria and Phaeocystis provides colonial cells a mechanism for alleviating chronic Vitamin B12 co-limitation effects thereby conferring them with a competitive advantage over diatom communities. The use of drifters in a time series study will provide the opportunity to track in both space and time a developing algal bloom in Terra Nova Bay and to determine community structure and the physiological nutrient status of microbial populations. A combination of flow cytometry, proteomics, metatranscriptomics, radioisotopic and stable isotopic labeling experiments will determine carbon and nutrient uptake rates and the role of bacteria in mitigating potential vitamin B12 and iron limitation. Membrane inlet and proton transfer reaction mass spectrometry will also be used to estimate net community production and release of volatile organic carbon compounds that are climatically active. Understanding how environmental parameters can influence microbial community dynamics in Antarctic coastal waters will advance an understanding of how changes in ocean stratification and chemistry could impact the biogeochemistry and food web dynamics of Southern Ocean ecosystems.", "east": 160.0, "geometry": "POINT(-158 -75.5)", "instruments": null, "is_usap_dc": true, "keywords": "BIOGEOCHEMICAL CYCLES; NBP1801; USA/NSF; AMD/US; USAP-DC; NUTRIENTS; PIGMENTS; CHLOROPHYLL; R/V NBP; Ross Sea; AMD", "locations": "Ross Sea", "north": -72.0, "nsf_funding_programs": "Antarctic Integrated System Science; Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "DiTullio, Giacomo; Lee, Peter", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "USAP-DC", "repositories": "R2R; USAP-DC", "science_programs": null, "south": -79.0, "title": "Collaborative Research: Cobalamin and Iron Co-Limitation Of Phytoplankton Species in Terra Nova Bay", "uid": "p0010045", "west": -116.0}, {"awards": "1401489 Sigman, Daniel", "bounds_geometry": "POLYGON((-180 -45,-144 -45,-108 -45,-72 -45,-36 -45,0 -45,36 -45,72 -45,108 -45,144 -45,180 -45,180 -47.5,180 -50,180 -52.5,180 -55,180 -57.5,180 -60,180 -62.5,180 -65,180 -67.5,180 -70,144 -70,108 -70,72 -70,36 -70,0 -70,-36 -70,-72 -70,-108 -70,-144 -70,-180 -70,-180 -67.5,-180 -65,-180 -62.5,-180 -60,-180 -57.5,-180 -55,-180 -52.5,-180 -50,-180 -47.5,-180 -45))", "dataset_titles": "Deep-sea coral evidence for lower Southern Ocean surface nitrate concentrations during the last ice age; Diatom-bound N isotope records over the last two glacial cycles in sediment core PS75/072-4.; Diatom-bound nitrogen isotope and opal flux records over the Holocene period in Southern Ocean sediment cores MD12-3396, MD11-3353 and PS75/072-4.; GOSHIP section IO8S and P18S", "datasets": [{"dataset_uid": "200048", "doi": "doi.pangaea.de/10.1594/PANGAEA.891436.", "keywords": null, "people": null, "repository": "PANGAEA", "science_program": null, "title": "Diatom-bound nitrogen isotope and opal flux records over the Holocene period in Southern Ocean sediment cores MD12-3396, MD11-3353 and PS75/072-4.", "url": "https://doi.pangaea.de/10.1594/PANGAEA.891436"}, {"dataset_uid": "200050", "doi": "", "keywords": null, "people": null, "repository": "CLIVAR", "science_program": null, "title": "GOSHIP section IO8S and P18S", "url": "https://cchdo.ucsd.edu/"}, {"dataset_uid": "200051", "doi": "", "keywords": null, "people": null, "repository": "Publication", "science_program": null, "title": "Deep-sea coral evidence for lower Southern Ocean surface nitrate concentrations during the last ice age", "url": "https://www.pnas.org/content/suppl/2017/03/14/1615718114.DCSupplemental"}, {"dataset_uid": "200049", "doi": "doi.org/10.1594/PANGAEA.848271", "keywords": null, "people": null, "repository": "PANGAEA", "science_program": null, "title": "Diatom-bound N isotope records over the last two glacial cycles in sediment core PS75/072-4.", "url": "https://doi.org/10.1594/PANGAEA.848271"}], "date_created": "Thu, 08 Aug 2019 00:00:00 GMT", "description": "ABSTRACT\u003cbr/\u003eIntellectual Merit:\u003cbr/\u003eThe high concentration of the major nutrients nitrate and phosphate is a fundamental characteristic of the Antarctic Zone in the Southern Ocean and is central to its role in global ocean fertility and the global carbon cycle. The isotopic composition of diatom-bound organic nitrogen is one of the best hopes for reconstructing the nutrient status of polar surface waters over glacial cycles, which in turn may hold the explanation for the decline in atmospheric carbon dioxide during ice ages. The PIs propose to generate detailed diatom-bound nitrogen isotope (\u0026#948;15Ndb) records from high sedimentation rate cores from the Kerguelen Plateau. Because the cores were collected at relatively shallow seafloor depths, they have adequate planktonic and benthic foraminifera to develop accurate age models. The resulting data could be compared with climate records from Antarctic ice cores and other archives to investigate climate-related changes, including the major steps into and out of ice ages and the millennial-scale events that occur during ice ages and at their ends. The records generated in this project will provide a critical test of hypotheses for the cause of lower ice age CO2.\u003cbr/\u003e\u003cbr/\u003eBroader impacts:\u003cbr/\u003eThis study will contribute to the goal of understanding ice ages and past CO2 changes, which both have broad implications for future climate. Undergraduates will undertake summer internships, with the possibility of extending their work into junior year projects and senior theses. In addition, the PI will lead modules for two Princeton programs for middle school teachers and will host a teacher for a six-week summer research project.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "BIOGEOCHEMICAL CYCLES; South Pacific Ocean; USAP-DC; NOT APPLICABLE", "locations": "South Pacific Ocean", "north": -45.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Sigman, Daniel", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "PANGAEA", "repositories": "CLIVAR; PANGAEA; Publication", "science_programs": null, "south": -70.0, "title": "High-resolution, Assemblage-specific Records of Diatom-bound N Isotopes from the Indian Sector of the Antarctic Ocean", "uid": "p0010046", "west": -180.0}, {"awards": "1443550 Brook, Edward", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Polar Ice Cores 3,000 Year Nitrous Oxide d15N and d18O Data; SPICEcore Holocene CO2 and N2O data", "datasets": [{"dataset_uid": "601197", "doi": "10.15784/601197", "keywords": "Antarctica; Carbon Dioxide; Ice Core Gas Records; Nitrous Oxide; South Pole; SPICEcore", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPICEcore Holocene CO2 and N2O data", "url": "https://www.usap-dc.org/view/dataset/601197"}, {"dataset_uid": "200055", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Polar Ice Cores 3,000 Year Nitrous Oxide d15N and d18O Data", "url": "https://www.ncdc.noaa.gov/paleo-search/study/25530"}], "date_created": "Tue, 06 Aug 2019 00:00:00 GMT", "description": "The temperature of the earth is controlled, in part, by heat trapping gases that include carbon dioxide, methane, and nitrous oxide. Despite their importance to climate, direct measurements of these gases in the atmosphere are limited to the last 50 years at best. Air trapped in ice cores extends those data back hundreds of millennia, and measurements of greenhouse gases in ice cores underpin much of our understanding of global chemical cycles relevant to modern climate change. Existing records vary in quality and detail. The proposed work fills gaps in our knowledge of nitrous oxide and carbon dioxide over the last 10,000 years. New measurements from an ice core from the South Pole will be used to determine what role changes in ocean and land based processes played in controlling these gases, which decreased during the first 2,000 years of this time period, then gradually increased toward the present. The work will address a major controversy over whether early human activities could have impacted the atmosphere, and provide data to improve mathematical models of the land-ocean-atmosphere system that predict how future climate change will impact the composition of the atmosphere and climate. \u003cbr/\u003e\u003cbr/\u003eFor nitrous oxide the work will improve on existing concentration records It will also develop measurement of the isotopomers of nitrous oxide and explore their utility for understanding aspects of the Holocene nitrous oxide budget. The primary goal is to determine if marine and/or terrestrial emissions of nitrous oxide change in response to changes in Holocene climate. A new Holocene isotopic record for carbon dioxide (stable carbon and oxygen isotopes), will improve the precision of existing records by a factor 5 and increase the temporal resolution. These data will be used to evaluate controversial hypotheses about why carbon dioxide concentrations changed in the Holocene and provide insight into millennial scale processes in the carbon cycle, which are not resolved by current isotopic data. A graduate student and post doc will receive advanced training during and the student and principle investigator will conduct outreach efforts targeted at local middle school students. The proposed work will also contribute to teaching efforts by the PI and to public lectures on climate and climate change. The results will be disseminated through publications, data archive, and the OSU Ice Core Lab web site. New analytical methods of wide utility will also be developed and documented.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Antarctica; ICE CORE RECORDS; CARBON DIOXIDE; NOT APPLICABLE; USAP-DC; TRACE GASES/TRACE SPECIES; NITROUS OXIDE", "locations": "Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "NCEI; USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Controls on Variations in Atmospheric Carbon Dioxide and Nitrous Oxide During the Last 10,000 years", "uid": "p0010043", "west": -180.0}, {"awards": "1543229 Severinghaus, Jeffrey; 1543267 Brook, Edward", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Multi-site ice core Krypton stable isotope ratios; Noble Gas Data from recent ice in Antarctica for 86Kr problem", "datasets": [{"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.; Bereiter, Bernhard; Buizert, Christo; Mosley-Thompson, Ellen; Mulvaney, Robert; Etheridge, David; Shackleton, Sarah; Bertler, Nancy; Brook, Edward J.; Pyne, Rebecca L.; Baggenstos, Daniel", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601195", "doi": "10.15784/601195", "keywords": "Antarctica; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Krypton; Noble Gas; Xenon", "people": "Severinghaus, Jeffrey P.; Shackleton, Sarah", "repository": "USAP-DC", "science_program": null, "title": "Noble Gas Data from recent ice in Antarctica for 86Kr problem", "url": "https://www.usap-dc.org/view/dataset/601195"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS divide; WAIS Divide Ice Core", "people": "Buizert, Christo; Brook, Edward J.; Pyne, Rebecca L.; Baggenstos, Daniel; Shackleton, Sarah; Etheridge, David; Severinghaus, Jeffrey P.; Bereiter, Bernhard; Mulvaney, Robert; Mosley-Thompson, Ellen; Bertler, Nancy", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS divide; WAIS Divide Ice Core", "people": "Buizert, Christo; Mulvaney, Robert; Pyne, Rebecca L.; Brook, Edward J.; Bertler, Nancy; Shackleton, Sarah; Etheridge, David; Severinghaus, Jeffrey P.; Bereiter, Bernhard; Mosley-Thompson, Ellen; Baggenstos, Daniel", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}], "date_created": "Wed, 10 Jul 2019 00:00:00 GMT", "description": "Overview: The funded work investigated whether ice core 86Kr acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere (SH) westerly winds. Pressure variations drive macroscopic air movement in the firn column, which reduces the gravitational isotopic enrichment of slow-diffusing gases (such as Kr). The 86Kr deviation from gravitational equilibrium (denoted D86Kr) thus reflects the magnitude of pressure variations (among other things). Atmospheric reanalysis data suggest that pressure variability over Antarctica is linked to the Southern Annular Mode (SAM) index and the position of the SH westerly winds. Preliminary data from the WAIS Divide ice core show a large excursion in D86Kr during the last deglaciation (20-9 ka before present). In this project the investigators (1) performed high-precision 86Kr analysis on ice core and firn air samples to establish whether D86Kr is linked to pressure variability; (2) Refined the deglacial WAIS Divide record of Kr isotopes; (3) Investigated the role of pressure variability in firn air transport using firn air models with firn microtomography data and Lattice- Boltzmann modeling; and (4) Investigated how barometric pressure variability in Antarctica is linked to the SAM index and the position/strength of the SH westerlies in past and present climates using GCM and reanalysis data. A key finding was that D86Kr in recent ice samples (e.g. last 50 years) from a broad spatial array of sites in Antarctica and Greenland showed a significant correlation with directly measured barometric pressure variability at the ice core site. This strongly supports the hypothesis that 86Kr can be used as a paleo-proxy for storminess.\r\nIntellectual Merit: The SH westerlies are a key component of the global climate system; they are an important control on the global oceanic overturning circulation and possibly on atmospheric CO2 concentrations. Poleward movement of the SH westerlies during the last deglaciation has been hypothesized, yet evidence from proxy and modeling studies remains inconclusive. The funded work could provide valuable new constraints on deglacial movement of the SH westerlies. This record can be compared to high-resolution CO2 data from the same core, allowing us to test hypotheses that link CO2 to the SH westerlies. Climate proxies are at the heart of paleoclimate research. The funded work has apparently led to the discovery of a completely new proxy, opening up exciting new research possibilities and increasing the scientific value of existing ice cores. Once validated, the 86Kr proxy could be applied to other time periods as well, providing a long-term perspective on the movement of the SH westerlies. The funded work has furthermore provided valuable new insights into firn air transport. \r\n\r\nBroader impact: The Southern Ocean is presently an important sink of atmospheric CO2, thereby reducing the warming associated with anthropogenic CO2 emissions. Stratospheric ozone depletion and greenhouse warming have displaced the SH westerlies poleward, with potential consequences for the future magnitude of this oceanic carbon uptake. The funded work may provide a paleo-perspective on past movement of the SH westerlies and its link to atmospheric CO2, which could guide projections of future oceanic CO2 uptake, with strong societal benefits. The awarded funds supported and trained an early-career postdoctoral scholar at OSU, and fostered (international) collaboration. Data from the study will be available to the scientific community and the broad public through recognized data centers. During this project the PI and senior personnel have continued their commitment to public outreach through media interviews and speaking to schools and the public about their work. The PI provides services to the community by chairing the IPICS (International Partnership in Ice Core Sciences) working group and organizing annual PIRE (Partnerships in International Research and Education) workshops.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "AMD/US; USA/NSF; FIRN; ICE CORE RECORDS; USAP-DC; Greenland; Xenon; Noble Gas; Ice Core; Antarctica; AMD; LABORATORY; Krypton; ATMOSPHERIC PRESSURE", "locations": "Greenland; Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Collaborative research: Kr-86 as a proxy for barometric pressure variability and movement of the SH westerlies during the last\r\ndeglaciation", "uid": "p0010037", "west": -180.0}, {"awards": "1443306 Mayewski, Paul; 1443263 Higgins, John", "bounds_geometry": null, "dataset_titles": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores; Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores; Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores; Greenhouse gas composition in the Allan Hills S27 ice core; Methane concentration in Allan Hills ice cores; Stable isotope composition of the trapped air in the Allan Hills S27 ice core; Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "datasets": [{"dataset_uid": "601203", "doi": "10.15784/601203", "keywords": "Allan Hills; Allan Hills project; Antarctica; Chemistry:Ice; Gas Chromatography; Glaciers/Ice Sheet; Glaciology; Greenhouse Gas; Ice; Ice Core Data; Ice Core Gas Records; Methane; Snow/Ice", "people": "Yan, Yuzhen; Brook, Edward J.; Bender, Michael; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Methane concentration in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601203"}, {"dataset_uid": "601512", "doi": "10.15784/601512", "keywords": "Allan Hills; Antarctica; Blue Ice; Ice Core; Ice Core Gas Records; Isotope; Nitrogen; Oxygen", "people": "Bender, Michael; Higgins, John; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable isotope composition of the trapped air in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601512"}, {"dataset_uid": "601201", "doi": "10.15784/601201", "keywords": "Allan Hills; Allan Hills project; Antarctica; Argon; Chemistry:Ice; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Data; Ice Core Gas Records; Krypton; Mass Spectrometer; Noble Gas; Snow/Ice; Xenon", "people": "Bender, Michael; Yan, Yuzhen; Higgins, John; Ng, Jessica; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601201"}, {"dataset_uid": "601483", "doi": "10.15784/601483", "keywords": "Allan Hills; Antarctica; Argon; Ice; Ice Core Data; Ice Core Gas Records; Isotope; Mass Spectrometry; Nitrogen; Oxygen", "people": "Yan, Yuzhen; Higgins, John; Bender, Michael", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601483"}, {"dataset_uid": "601130", "doi": "10.15784/601130", "keywords": "Allan Hills; Allan Hills project; Antarctica; Blue Ice; Chemistry:Ice; Delta 18O; Delta Deuterium; Glaciers/Ice Sheet; Glaciology; Ice Core Gas Records; Ice Core Records; Oxygen; Snow/Ice; Stable water isotopes; Transantarctic Mountains", "people": "Kurbatov, Andrei V.; Mayewski, Paul A.; Introne, Douglas; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601130"}, {"dataset_uid": "601129", "doi": "10.15784/601129", "keywords": "Allan Hills; Allan Hills project; Antarctica; Blue Ice; Delta 18O; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; isotope data; Oxygen; Snow/Ice; Stable water isotopes; Transantarctic Mountains", "people": "Introne, Douglas; Yan, Yuzhen; Kurbatov, Andrei V.; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601129"}, {"dataset_uid": "601128", "doi": "10.15784/601128", "keywords": "Allan Hills; Antarctica; Blue Ice; Chemistry:Ice; Delta 18O; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope record; Mass Spectrometry; Stable water isotopes", "people": "Mayewski, Paul A.; Yan, Yuzhen; Kurbatov, Andrei V.; Introne, Douglas", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601128"}, {"dataset_uid": "601425", "doi": "10.15784/601425", "keywords": "Allan Hills; Antarctica; Blue Ice; Carbon Dioxide; Ice Core; Methane", "people": "Brook, Edward J.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Greenhouse gas composition in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601425"}, {"dataset_uid": "601202", "doi": "10.15784/601202", "keywords": "Allan Hills; Allan Hills project; Antarctica; Carbon Dioxide; Carbon Isotopes; Chemistry:Ice; CO2; Gas Chromatography; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Data; Ice Core Gas Records; Ice Core Records; Mass Spectrometer; Mass Spectrometry; Methane; Snow/Ice", "people": "Brook, Edward J.; Higgins, John; Yan, Yuzhen; Bender, Michael", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601202"}], "date_created": "Thu, 18 Oct 2018 00:00:00 GMT", "description": "Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800,000 years. Previous field expeditions to the Allan Hills blue ice area, Antarctica, have recovered ice cores that date to one million years, the oldest ice cores yet recovered from Antarctica. These records have revealed that interglacial CO2 concentrations decreased by 800,000 years ago and that, in the warmer world 1 million years ago, CO2 and Antarctic temperature were linked as during the last 800,000 years. This project will return to the Allan Hills blue ice area to recover additional ice cores that date to 1 million years or older. The climate records developed from the drilled ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Our results will help answer questions about issues associated with anthropogenic change. These include the relationship between temperature change and the mass balance of Antarctic ice; precipitation and aridity variations associated with radiatively forced climate change; and the climate significance of sea ice extent. The project will entrain two graduate students and a postdoctoral scholar, and will conduct outreach including workshops to engage teachers in carbon science and ice cores.\u003cbr/\u003e\u003cbr/\u003eBetween about 2.8-0.9 million years ago, Earth\u0027s climate was characterized by 40,000-year cycles, driven or paced by changes in the tilt of Earth\u0027s spin axis. Much is known about the \"40,000-year\" world from studies of deep-sea sediments, but our understanding of climate change during this period is incomplete because we lack records of Antarctic climate and direct records of atmospheric greenhouse gas concentrations. We propose to address these issues by building on our recent studies of ancient ice from the Main Ice Field, Allan Hills, Antarctica. During previous field seasons we recovered ice extending, discontinuously, from 0.1-1.0 million years old. Ice was dated by measuring the 40Ar/38Ar (Argon) ratio of the trapped gases. Our discovery of million year-old ice demonstrates that there is gas-record-quality ice from the 40,000-year world in the Allan Hills Main Ice Field. We have identified two different sites, each overlying bedrock at ~ 200 m depth, that are attractive targets for coring ice dating to 1 million years and older. This project aims to core the ice at these two sites, re-occupy a previous site with million year-old ice and drill it down to the bedrock, and generate 10-20 short (~10-meter) cores in areas where our previous work and terrestrial meteorite ages suggest ancient surface ice. We plan to date the ice using the 40Ar/38Ar ages of trapped Argon. We also plan to characterize the continuity of our cores by measuring the deuterium and oxygen isotope ratios in the ice, methane, ratios of Oxygen and Argon to Nitrogen in trapped gas, the Nitrogen-15 isotope (d15N) of Nitrogen, and the Oxygen-18 isotope (d18O) of Oxygen. As the ice may be stratigraphically disturbed, these measurements will provide diagnostic properties for assessing the continuity of the ice-core records. Successful retrieval of ice older than one million years will provide the opportunity for follow-up work to measure the CO2 concentration and other properties within the ice to inform on the temperature history of the Allan Hills region, dust sources and source-area aridity, moisture sources, densification conditions, global average ocean temperature, and greenhouse gas concentrations. We will analyze the data in the context of leading hypotheses of the 40,000-year world and the Mid-Pleistocene Transition to the 100,000-year world. We expect to advance understanding of climate dynamics during these periods.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "AMD; Allan Hills; AMD/US; USA/NSF; FIELD INVESTIGATION; USAP-DC; Ice Core; LABORATORY", "locations": "Allan Hills", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Mayewski, Paul A.; Kurbatov, Andrei V.; Higgins, John; Bender, Michael", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Allan Hills", "south": null, "title": "Collaborative Research: Window into the World with 40,000-year Glacial Cycles from Climate Records in Million Year-old Ice from the Allan Hills Blue Ice Area", "uid": "p0000760", "west": null}, {"awards": "1043471 Kaplan, Michael", "bounds_geometry": "POLYGON((-112.5 -79.468,-112.4586 -79.468,-112.4172 -79.468,-112.3758 -79.468,-112.3344 -79.468,-112.293 -79.468,-112.2516 -79.468,-112.2102 -79.468,-112.1688 -79.468,-112.1274 -79.468,-112.086 -79.468,-112.086 -79.4712,-112.086 -79.4744,-112.086 -79.4776,-112.086 -79.4808,-112.086 -79.484,-112.086 -79.4872,-112.086 -79.4904,-112.086 -79.4936,-112.086 -79.4968,-112.086 -79.5,-112.1274 -79.5,-112.1688 -79.5,-112.2102 -79.5,-112.2516 -79.5,-112.293 -79.5,-112.3344 -79.5,-112.3758 -79.5,-112.4172 -79.5,-112.4586 -79.5,-112.5 -79.5,-112.5 -79.4968,-112.5 -79.4936,-112.5 -79.4904,-112.5 -79.4872,-112.5 -79.484,-112.5 -79.4808,-112.5 -79.4776,-112.5 -79.4744,-112.5 -79.4712,-112.5 -79.468))", "dataset_titles": "List of samples of WAIS Divide and Byrd (deep) ice that were analyzed for radiogenic isotopes at LDEO", "datasets": [{"dataset_uid": "601065", "doi": "10.15784/601065", "keywords": "Antarctica; Dust; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Sample/Collection Description; WAIS divide; WAIS Divide Ice Core", "people": "Kaplan, Michael", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "List of samples of WAIS Divide and Byrd (deep) ice that were analyzed for radiogenic isotopes at LDEO", "url": "https://www.usap-dc.org/view/dataset/601065"}], "date_created": "Sun, 29 Oct 2017 00:00:00 GMT", "description": "This award supports a project to obtain the first set of isotopic-based provenance data from the WAIS divide ice core. A lack of data from the WAIS prevents even a basic knowledge of whether different sources of dust blew around the Pacific and Atlantic sectors of the southern latitudes. Precise isotopic measurements on dust in the new WAIS ice divide core are specifically warranted because the data will be synergistically integrated with other high frequency proxies, such as dust concentration and flux, and carbon dioxide, for example. Higher resolution proxies will bridge gaps between our observations on the same well-dated, well-preserved core. The intellectual merit of the project is that the proposed analyses will contribute to the WAIS Divide Project science themes. Whether an active driver or passive recorder, dust is one of the most important but least understood components of regional and global climate. Collaborative and expert discussion with dust-climate modelers will lead to an important progression in understanding of dust and past atmospheric circulation patterns and climate around the southern latitudes, and help to exclude unlikely air trajectories to the ice sheets. The project will provide data to help evaluate models that simulate the dust patterns and cycle and the relative importance of changes in the sources, air trajectories and transport processes, and deposition to the ice sheet under different climate states. The results will be of broad interest to a range of disciplines beyond those directly associated with the WAIS ice core project, including the paleoceanography and dust- paleoclimatology communities. The broader impacts of the project include infrastructure and professional development, as the proposed research will initiate collaborations between LDEO and other WAIS scientists and modelers with expertise in climate and dust. Most of the researchers are still in the early phase of their careers and hence the project will facilitate long-term relationships. This includes a graduate student from UMaine, an undergraduate student from Columbia University who will be involved in lab work, in addition to a LDEO Postdoctoral scientist, and possibly an additional student involved in the international project PIRE-ICETRICS. The proposed research will broaden the scientific outlooks of three PIs, who come to Antarctic ice core science from a variety of other terrestrial and marine geology perspectives. Outreach activities include interaction with the science writers of the Columbia\u0027s Earth Institute for news releases and associated blog websites, public speaking, and involvement in an arts/science initiative between New York City\u0027s arts and science communities to bridge the gap between scientific knowledge and public perception.", "east": -112.086, "geometry": "POINT(-112.293 -79.484)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -79.468, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Kaplan, Michael; Winckler, Gisela; Goldstein, Steven L.", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.5, "title": "A Study of Atmospheric Dust in the WAIS Divide Ice Core Based on Sr-Nd-Pb-He Isotopes", "uid": "p0000081", "west": -112.5}, {"awards": "1103428 Thurber, Andrew", "bounds_geometry": "POLYGON((165 -77,165.5 -77,166 -77,166.5 -77,167 -77,167.5 -77,168 -77,168.5 -77,169 -77,169.5 -77,170 -77,170 -77.1,170 -77.2,170 -77.3,170 -77.4,170 -77.5,170 -77.6,170 -77.7,170 -77.8,170 -77.9,170 -78,169.5 -78,169 -78,168.5 -78,168 -78,167.5 -78,167 -78,166.5 -78,166 -78,165.5 -78,165 -78,165 -77.9,165 -77.8,165 -77.7,165 -77.6,165 -77.5,165 -77.4,165 -77.3,165 -77.2,165 -77.1,165 -77))", "dataset_titles": "McMurdo Spiophanes beds 16s V4 region community composition from sediment cores at McMurdo Station, Antarctia on Sept 9th, 2012 (McMurdo Benthos project); Stable isotopic composition of McMurdo Benthos", "datasets": [{"dataset_uid": "000201", "doi": "", "keywords": null, "people": null, "repository": "BCO-DMO", "science_program": null, "title": "Stable isotopic composition of McMurdo Benthos", "url": "https://www.bco-dmo.org/dataset/716462"}, {"dataset_uid": "000202", "doi": "", "keywords": null, "people": null, "repository": "BCO-DMO", "science_program": null, "title": "McMurdo Spiophanes beds 16s V4 region community composition from sediment cores at McMurdo Station, Antarctia on Sept 9th, 2012 (McMurdo Benthos project)", "url": "https://www.bco-dmo.org/dataset/716443"}], "date_created": "Tue, 10 Oct 2017 00:00:00 GMT", "description": "The biota of the world\u0027s seafloor is fueled by bursts of seasonal primary production. For food-limited sediment communities to persist, a balance must exist between metazoan consumption of and competition with bacteria, a balance which likely changes through the seasons. Polar marine ecosystems are ideal places to study such complex interactions due to stark seasonal shifts between heterotrophic and autotrophic communities, and temperatures that may limit microbial processing of organic matter. The research will test the following hypotheses: 1) heterotrophic bacteria compete with macrofauna for food; 2) as phytoplankton populations decline macrofauna increasingly consume microbial biomass to sustain their populations; and 3) in the absence of seasonal photosynthetic inputs, macrofaunal biodiversity will decrease unless supplied with microbially derived nutrition. Observational and empirical studies will test these hypotheses at McMurdo Station, Antarctica, where a high-abundance macro-infaunal community is adapted to this boom-and-bust cycle of productivity. The investigator will mentor undergraduates from a predominantly minority-serving institution, in the fields of invertebrate taxonomy and biogeochemistry. The general public and young scientists will be engaged through lectures at local K-12 venues and launch of an interactive website. The results will better inform scientists and managers about the effects of climate change on polar ecosystems and the mechanisms of changing productivity patterns on global biodiversity.", "east": 170.0, "geometry": "POINT(167.5 -77.5)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -77.0, "nsf_funding_programs": null, "paleo_time": null, "persons": "Thurber, Andrew", "platforms": "Not provided", "repo": "BCO-DMO", "repositories": "BCO-DMO", "science_programs": null, "south": -78.0, "title": "PostDoctoral Research Fellowship", "uid": "p0000416", "west": 165.0}, {"awards": "1341284 Swanger, Kate", "bounds_geometry": "POLYGON((161 -77.5,161.2 -77.5,161.4 -77.5,161.6 -77.5,161.8 -77.5,162 -77.5,162.2 -77.5,162.4 -77.5,162.6 -77.5,162.8 -77.5,163 -77.5,163 -77.525,163 -77.55,163 -77.575,163 -77.6,163 -77.625,163 -77.65,163 -77.675,163 -77.7,163 -77.725,163 -77.75,162.8 -77.75,162.6 -77.75,162.4 -77.75,162.2 -77.75,162 -77.75,161.8 -77.75,161.6 -77.75,161.4 -77.75,161.2 -77.75,161 -77.75,161 -77.725,161 -77.7,161 -77.675,161 -77.65,161 -77.625,161 -77.6,161 -77.575,161 -77.55,161 -77.525,161 -77.5))", "dataset_titles": null, "datasets": null, "date_created": "Mon, 09 Oct 2017 00:00:00 GMT", "description": "Paragraph for Laypersons:\u003cbr/\u003eThis research focuses on the history of rock glaciers and buried glacial ice in the McMurdo Dry Valleys region of Antarctica. Rock glaciers are flowing mixtures of ice and sediments common throughout alpine and high-latitude regions on Earth and Mars. Despite similar appearances, rock glaciers can form under highly variable environmental and hydrological conditions. The main research questions addressed here are: 1) what environmental and climatological conditions foster long-term preservation of rock glaciers in Antarctica, 2) what role do rock glaciers play in Antarctic landscape evolution and the local water cycle, and 3) what can rock glaciers reveal about the extent and timing of previous glacial advances? The project will involve two Antarctic field seasons to image the interior of Antarctic rock glaciers using ground-penetrating radar, to gather ice cores for chemical analyses, and to gather surface sediments for dating. The Dry Valleys host the world?s southernmost terrestrial ecosystem (soil, stream and lake micro-organisms and mosses); rock glaciers and ground-ice are an important and poorly-studied source of meltwater and nutrients for these ecosystems. This research will shed light on the glacial and hydrological history of the Dry Valleys region and the general environmental conditions the foster rock glaciers, features that generally occur in warmer and/or wetter locations. The research will provide support for five graduate/undergraduate students, who will actively gather data in the field, followed by interpretation, dissemination and presentation of the data. Additionally, the researchers will participate in a range of educational activities including outreach with local K-12 in the Lowell, MA region, such as summer workshops and classroom visits with hands-on activities. A series of time-lapse images of hydrological processes, and videos of researchers in the field, will serve as a dramatic centerpiece in community and school presentations.\u003cbr/\u003e\u003cbr/\u003eParagraph for Scientific Community:\u003cbr/\u003eRock glaciers are common in the McMurdo Dry Valleys, but are concentrated in a few isolated regions: western Taylor Valley, western Wright Valley, Pearse Valley and Bull Pass. The investigators hypothesize that the origin and age of these features varies by region: that rock glaciers in Pearse and Taylor valley originated as buried glacier ice, whereas rock glaciers in Wright Valley formed through permafrost processes, such as mobilization of ice-rich talus. To address these hypotheses, the project will: 1) develop relative and absolute chronologies for the rock glaciers through field mapping and optically stimulated luminescence dating of overlying sediments, 2) assess the origin of clean-ice cores through stable isotopic analyses, and 3) determine if present-day soil-moisture and temperature conditions are conducive to rock glacier formation/preservation. The proposed research will provide insight into the spatial and temporal distribution of buried glacier ice and melt-water-derived ground ice in the McMurdo Dry Valleys, with implications for glacial history, as well as the potential role of rock glaciers in the regional hydrologic cycle (and the role of ground-ice as a source for moisture and nutrient for local ecosystems). The project will provide general constraints on the climatic and hydrologic conditions that foster permafrost rock glaciers, features that generally occur under warmer and wetter conditions than those found in the present-day McMurdo Dry Valleys. The application of OSL and cosmogenic exposure\u003cbr/\u003edating is novel to rock glaciers, geomorphic features that have proven difficult to date, despite their ubiquity in Antarctica and their potential scientific importance. The research will provide support for five graduate/undergraduate students, who will participate in the field work, followed by interpretation, dissemination and presentation of the data. The researchers will participate in a range of educational activities including outreach with local K-12 in the Lowell, MA region, such as summer workshops and classroom visits with hands-on activities.", "east": 163.0, "geometry": "POINT(162 -77.625)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -77.5, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Swanger, Kate", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -77.75, "title": "Origin and Climatic Significance of Rock Glaciers in the McMurdo Dry Valleys: Assessing Spatial and Temporal Variability", "uid": "p0000297", "west": 161.0}, {"awards": "1246223 Hastings, Meredith", "bounds_geometry": "POINT(-112.1115 -79.481)", "dataset_titles": "WAIS Divide WDC06A Nitrate Isotope Record", "datasets": [{"dataset_uid": "601022", "doi": "10.15784/601022", "keywords": "Antarctica; Chemistry:Ice; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Nitrate; WAIS divide; WAIS Divide Ice Core", "people": "Buffen, Aron; Hastings, Meredith", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide WDC06A Nitrate Isotope Record", "url": "https://www.usap-dc.org/view/dataset/601022"}], "date_created": "Tue, 02 May 2017 00:00:00 GMT", "description": "Hastings/1246223\u003cbr/\u003e\u003cbr/\u003eThis award supports a project with the aim of distinguishing the sources of nitrate deposition to the West Antarctic Ice Sheet (WAIS) using isotopic ratios snow in archive snow and ice samples. The isotopic composition of nitrate has been shown to contain information about the source of the nitrate (i.e. nitrogen oxides = NOx = NO+NO2) and the oxidation processes that convert NOx to nitrate in the atmosphere prior to deposition. A difficulty in interpreting records in the context of NOx sources is that nitrate can be post-depositionally processed in surface snow, such that the archived record does not reflect the composition of the atmosphere. This intellectual merit of this work specifically aims to investigate variability in the isotopic composition of nitrate in snow and ice from the WAIS in the context of accumulation rate, NOx source emissions, and atmospheric chemistry. These records will be interpreted in the context of our understanding of biospheric (biomass burning, microbial processes in soils), atmospheric (lightning, transport, chemistry), and climate (temperature, accumulation rate) changes over time. A graduate student will be supported as part of this project, and both graduate student and PI will be involved in communicating the utility and results of polar research to elementary school students in the Providence, RI area. The broader impacts of the project also include making efforts to attract more young, female scientists to polar research by establishing a connection between the Earth Science Women\u0027s Network (ESWN), an organization PI Hastings helped to establish, and the Association of Polar Early Career Scientists (APECS). Finally, results of all measurements will be presented at relevant conferences, made available publicly and published in peer-reviewed journals.", "east": -112.1115, "geometry": "POINT(-112.1115 -79.481)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -79.481, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Hastings, Meredith", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.481, "title": "Investigating Source, Chemistry and Climate changes using the Isotopic Composition of Nitrate in Antarctic Snow and Ice", "uid": "p0000399", "west": -112.1115}, {"awards": "1245283 Passchier, Sandra", "bounds_geometry": "POLYGON((66 -68,67.3 -68,68.6 -68,69.9 -68,71.2 -68,72.5 -68,73.8 -68,75.1 -68,76.4 -68,77.7 -68,79 -68,79 -68.2,79 -68.4,79 -68.6,79 -68.8,79 -69,79 -69.2,79 -69.4,79 -69.6,79 -69.8,79 -70,77.7 -70,76.4 -70,75.1 -70,73.8 -70,72.5 -70,71.2 -70,69.9 -70,68.6 -70,67.3 -70,66 -70,66 -69.8,66 -69.6,66 -69.4,66 -69.2,66 -69,66 -68.8,66 -68.6,66 -68.4,66 -68.2,66 -68))", "dataset_titles": "Antarctic Geochemistry Data and Mean Annual Temperature Reconstruction through the Eocene-Oligocene Transition; GSA Data Repository Item 2016298 - Passchier, S., Ciarletta, D.J., Miriagos, T.E., Bijl, P.K., and Bohaty, S.M., 2016, An Antarctic stratigraphic record of step-wise ice growth through the Eocene-Oligocene transition: GSA Bulletin, doi:10.1130/B31482.1.; Particle-size distributions of Eocene-Oligocene sediment from ODP Site 739, Prydz Bay; Particle-size distributions of Eocene-Oligocene sediment from ODP Site 742, Prydz Bay; Particle-size distributions of Eocene sediment from ODP Site 1166, Prydz Bay", "datasets": [{"dataset_uid": "601453", "doi": "10.15784/601453", "keywords": "Antarctica; Eocene; Marine Geoscience; ODP739; Oligocene; Particle Size; Prydz Bay; Sediment Core Data", "people": "Ciarletta, Daniel; Passchier, Sandra", "repository": "USAP-DC", "science_program": null, "title": "Particle-size distributions of Eocene-Oligocene sediment from ODP Site 739, Prydz Bay", "url": "https://www.usap-dc.org/view/dataset/601453"}, {"dataset_uid": "000192", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Antarctic Geochemistry Data and Mean Annual Temperature Reconstruction through the Eocene-Oligocene Transition", "url": "https://www.ncdc.noaa.gov/paleo-search/study/21770"}, {"dataset_uid": "601455", "doi": "10.15784/601455", "keywords": "Antarctica; Eocene; Marine Geoscience; ODP1166; Particle Size; Prydz Bay; Sediment Core Data", "people": "Passchier, Sandra; Ciarletta, Daniel", "repository": "USAP-DC", "science_program": null, "title": "Particle-size distributions of Eocene sediment from ODP Site 1166, Prydz Bay", "url": "https://www.usap-dc.org/view/dataset/601455"}, {"dataset_uid": "200200", "doi": "10.1130/2016298", "keywords": null, "people": null, "repository": "Publication", "science_program": null, "title": " GSA Data Repository Item 2016298 - Passchier, S., Ciarletta, D.J., Miriagos, T.E., Bijl, P.K., and Bohaty, S.M., 2016, An Antarctic stratigraphic record of step-wise ice growth through the Eocene-Oligocene transition: GSA Bulletin, doi:10.1130/B31482.1.", "url": "https://gsapubs.figshare.com/articles/journal_contribution/Supplemental_material_An_Antarctic_stratigraphic_record_of_step-wise_ice_growth_through_the_Eocene-Oligocene_transition/12534185"}, {"dataset_uid": "601454", "doi": "10.15784/601454", "keywords": "Antarctica; Eocene; Marine Geoscience; ODP742; Oligocene; Particle Size; Prydz Bay; Sediment Core Data", "people": "Passchier, Sandra; Ciarletta, Daniel", "repository": "USAP-DC", "science_program": null, "title": "Particle-size distributions of Eocene-Oligocene sediment from ODP Site 742, Prydz Bay", "url": "https://www.usap-dc.org/view/dataset/601454"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "Intellectual Merit: \u003cbr/\u003eThis project will investigate glacial advance and retreat of the East Antarctic Ice Sheet through the Eocene-Oligocene transition, a major episode of ice growth. In Prydz Bay, East Antarctica, a 130-170 m thick Eocene-Oligocene transition interval of glaciomarine sediments was cored in drillholes of the Ocean Drilling Program at Sites 739, 742 and 1166. Correlations between the Prydz Bay drillholes have recently been made through well-log and multichannel seismic interpretations. Recent drilling on the Wilkes Land margin of East Antarctica recovered earliest Oligocene sediments overlying a major regional unconformity in two drillholes. The PI will study the lithostratigraphy and weathering history of cores in the five drillholes, to establish a unique Eocene-Oligocene transition record within Antarctic continental margin sediments of glacial advance and retreat cycles, the onset of physical weathering, and glacio-isostasy and self-gravitation processes with implications for the margin architecture, sediment routing, and off-shore sediment dispersal. Cores from the five drillholes will be re-examined through detailed core description using an updated classification scheme, so that lithofacies can be compared between drillholes. Samples will be collected for detailed laser particle size and bulk major element geochemistry via ICP-AES to determine the degree of chemical alteration of the sediments. Phases of major ice growth will be recognized as marker beds of physically eroded sediment and will be correlated to isotopic records documenting Antarctic ice growth offshore in the Southern Ocean. \u003cbr/\u003e\u003cbr/\u003eBroader impacts: \u003cbr/\u003eThis project will benefit a large minority undergraduate student population through the availability of up to two paid laboratory internships, a classroom exercise, and the availability of research equipment supported by this award. The project also allows support and training of a graduate student.", "east": 79.0, "geometry": "POINT(72.5 -69)", "instruments": null, "is_usap_dc": true, "keywords": "ICE SHEETS; Not provided; Prydz Bay; SEDIMENTS", "locations": "Prydz Bay", "north": -68.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Passchier, Sandra", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "NCEI; Publication; USAP-DC", "science_programs": null, "south": -70.0, "title": "The Stratigraphic Expression of the Onset of Glaciation in Eocene-Oligocene Successions on the Antarctic Continental Margin", "uid": "p0000309", "west": 66.0}, {"awards": "0944653 Forster, Richard", "bounds_geometry": "POLYGON((-119.4 -78.1,-118.46000000000001 -78.1,-117.52000000000001 -78.1,-116.58 -78.1,-115.64 -78.1,-114.7 -78.1,-113.76 -78.1,-112.82000000000001 -78.1,-111.88 -78.1,-110.94 -78.1,-110 -78.1,-110 -78.28999999999999,-110 -78.47999999999999,-110 -78.67,-110 -78.86,-110 -79.05,-110 -79.24,-110 -79.42999999999999,-110 -79.62,-110 -79.81,-110 -80,-110.94 -80,-111.88 -80,-112.82000000000001 -80,-113.76 -80,-114.7 -80,-115.64 -80,-116.58 -80,-117.52000000000001 -80,-118.46000000000001 -80,-119.4 -80,-119.4 -79.81,-119.4 -79.62,-119.4 -79.42999999999999,-119.4 -79.24,-119.4 -79.05,-119.4 -78.86,-119.4 -78.67,-119.4 -78.47999999999999,-119.4 -78.28999999999999,-119.4 -78.1))", "dataset_titles": "Annual Satellite Era Accumulation Patterns Over WAIS Divide: A Study Using Shallow Ice Cores, Near-Surface Radars and Satellites", "datasets": [{"dataset_uid": "600146", "doi": "10.15784/600146", "keywords": "Airborne Radar; Antarctica; Geology/Geophysics - Other; Glaciers/Ice Sheet; Glaciology; Radar; WAIS divide; WAIS Divide Ice Core", "people": "Forster, Richard", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Annual Satellite Era Accumulation Patterns Over WAIS Divide: A Study Using Shallow Ice Cores, Near-Surface Radars and Satellites", "url": "https://www.usap-dc.org/view/dataset/600146"}], "date_created": "Fri, 20 Nov 2015 00:00:00 GMT", "description": "This award supports a project to broaden the knowledge of annual accumulation patterns over the West Antarctic Ice Sheet by processing existing near-surface radar data taken on the US ITASE traverse in 2000 and by gathering and validating new ultra/super-high-frequency (UHF) radar images of near surface layers (to depths of ~15 m), expanding abilities to monitor recent annual accumulation patterns from point source ice cores to radar lines. Shallow (15 m) ice cores will be collected in conjunction with UHF radar images to confirm that radar echoed returns correspond with annual layers, and/or sub-annual density changes in the near-surface snow, as determined from ice core stable isotopes. This project will additionally improve accumulation monitoring from space-borne instruments by comparing the spatial-radar-derived-annual accumulation time series to the passive microwave time series dating back over 3 decades and covering most of Antarctica. The intellectual merit of this project is that mapping the spatial and temporal variations in accumulation rates over the Antarctic ice sheet is essential for understanding ice sheet responses to climate forcing. Antarctic precipitation rate is projected to increase up to 20% in the coming century from the predicted warming. Accumulation is a key component for determining ice sheet mass balance and, hence, sea level rise, yet our ability to measure annual accumulation variability over the past 5 decades (satellite era) is mostly limited to point-source ice cores. Developing a radar and ice core derived annual accumulation dataset will provide validation data for space-born remote sensing algorithms, climate models and, additionally, establish accumulation trends. The broader impacts of the project are that it will advance discovery and understanding within the climatology, glaciology and remote sensing communities by verifying the use of UHF radars to monitor annual layers as determined by visual, chemical and isotopic analysis from corresponding shallow ice cores and will provide a dataset of annual to near-annual accumulation measurements over the past ~5 decades across WAIS divide from existing radar data and proposed radar data. By determining if temporal changes in the passive microwave signal are correlated with temporal changes in accumulation will help assess the utility of passive microwave remote sensing to monitor accumulation rates over ice sheets for future decades. The project will promote teaching, training and learning, and increase representation of underrepresented groups by becoming involved in the NASA History of Winter project and Thermochron Mission and by providing K-12 teachers with training to monitor snow accumulation and temperature here in the US, linking polar research to the student?s backyard. The project will train both undergraduate and graduate students in polar research and will encouraging young investigators to become involved in careers in science. In particular, two REU students will participate in original research projects as part of this larger project, from development of a hypothesis to presentation and publication of the results. The support of a new, young woman scientist will help to increase gender diversity in polar research.", "east": -110.0, "geometry": "POINT(-114.7 -79.05)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -78.1, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Forster, Richard", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -80.0, "title": "Collaborative Research: Annual satellite era accumulation patterns over WAIS Divide: A study using shallow ice cores, near-surface radars and satellites", "uid": "p0000079", "west": -119.4}, {"awards": "1142156 Marschall, Horst", "bounds_geometry": "POLYGON((-6.44 -71.93,-5.378 -71.93,-4.316 -71.93,-3.254 -71.93,-2.192 -71.93,-1.13 -71.93,-0.068 -71.93,0.994 -71.93,2.056 -71.93,3.118 -71.93,4.18 -71.93,4.18 -71.998,4.18 -72.066,4.18 -72.134,4.18 -72.202,4.18 -72.27,4.18 -72.338,4.18 -72.406,4.18 -72.474,4.18 -72.542,4.18 -72.61,3.118 -72.61,2.056 -72.61,0.994 -72.61,-0.068 -72.61,-1.13 -72.61,-2.192 -72.61,-3.254 -72.61,-4.316 -72.61,-5.378 -72.61,-6.44 -72.61,-6.44 -72.542,-6.44 -72.474,-6.44 -72.406,-6.44 -72.338,-6.44 -72.27,-6.44 -72.202,-6.44 -72.134,-6.44 -72.066,-6.44 -71.998,-6.44 -71.93))", "dataset_titles": "Zircon Hf Isotopes and the Continental Evolution of Dronning Maud Land, East Antarctica", "datasets": [{"dataset_uid": "600135", "doi": "10.15784/600135", "keywords": "Antarctica; Chemistry:Rock; Dronning Maud Land; Geochemistry; Geochronology; Solid Earth", "people": "Marschall, Horst", "repository": "USAP-DC", "science_program": null, "title": "Zircon Hf Isotopes and the Continental Evolution of Dronning Maud Land, East Antarctica", "url": "https://www.usap-dc.org/view/dataset/600135"}], "date_created": "Fri, 23 Oct 2015 00:00:00 GMT", "description": "Geochemical studies of single mineral grains in rocks can be probed to reconstruct the history of our planet. The mineral zircon (ZrSiO4) is of unique importance in that respect because of its reliability as a geologic clock due to its strong persistence against weathering, transport and changes in temperature and pressure. Uranium-Lead (U-Pb) dating of zircon grains is, perhaps, the most frequently employed method of extracting time information on geologic processes that shaped the continental crust, and has been used to constrain the evolution of continents and mountain belts through time. In addition, the isotopic composition of the element Hafnium (Hf) in zircon is used to date when the continental crust was generated by extraction of magma from the underlying mantle. Melting of rocks in the mantle and deep in the continental crust are key processes in the evolution of the continents, and they are recorded in the Hf isotopic signatures of zircon. Although the analytical procedures for U-Pb dating and Hf isotope analyses of zircon are robust now, our understanding of zircon growth and its exchange of elements and isotopes with its surrounding rock or magma are still underdeveloped. The focus of the proposed study, therefore, is to unravel the evolution of zircon Hf isotopes in rocks that were formed deep in the Earth?s crust, and more specifically, to apply these isotopic methods to rocks collected in Dronning Maud Land (DML), East Antarctica.\u003cbr/\u003e\u003cbr/\u003eDronning Maud Land (DML) occupied a central location during the formation of supercontinents ? large landmasses made up of all the continents that exist today - more than 500 million years ago. It is currently thought that supercontinents were formed and dismembered five or six times throughout Earth?s history. The area of DML is key for understanding the formation history of the last two supercontinents. The boundaries of continents that were merged to form those supercontinents are most likely hidden in DML. In this study, the isotopic composition of zircon grains recovered from DML rocks will be employed to identify these boundaries across an extensive section through the area. The rock samples were collected by the investigator during a two-month expedition to Antarctica in the austral summer of 2007?2008. The results of dating and isotope analyses of zircon of the different DML crustal domains will deliver significant insight into the regional geology of East Antarctica and its previous northern extension into Africa. This has significance for the reconstruction of the supercontinents and defining the continental boundaries in DML.", "east": 4.18, "geometry": "POINT(-1.13 -72.27)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -71.93, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Marschall, Horst", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -72.61, "title": "Zircon Hf Isotopes and the Continental Evolution of Dronning Maud Land, East Antacrtica", "uid": "p0000448", "west": -6.44}, {"awards": "1043421 Severinghaus, Jeffrey; 1043522 Brook, Edward", "bounds_geometry": "POINT(-112.09 -79.47)", "dataset_titles": "WAIS Divide Replicate Core Methane Isotopic Data Set", "datasets": [{"dataset_uid": "601059", "doi": "10.15784/601059", "keywords": "Antarctica; Chemistry:Fluid; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS divide; WAIS Divide Ice Core", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Replicate Core Methane Isotopic Data Set", "url": "https://www.usap-dc.org/view/dataset/601059"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "1043421/Severinghaus\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to obtain samples of ice in selected intervals for replication and verification of the validity and spatial representativeness of key results in the WAIS Divide ice core, and to obtain additional ice samples in areas of intense scientific interest where demand is high. The US Ice Core Working Group recommended in 2003 that NSF pursue the means to take replicate samples, termed \"replicate coring\". This recommendation was part of an agreement to reduce the diameter of the (then) new drilling system (the DISC drill) core to 12.2 cm to lighten logistics burdens, and the science community accepted the reduction in ice sample with the understanding that replicate coring would be able to provide extra sample volume in key intervals. The WAIS Divide effort would particularly benefit from replicate coring, because of the unique quality of the expected gas record and the large samples needed for gases and gas isotopes; thus this proposal to employ replicate coring at WAIS Divide. In addition, scientific demand for ice samples has been, and will continue to be, very unevenly distributed, with the ice core archive being completely depleted in depth intervals of high scientific interest (abrupt climate changes, volcanic sulfate horizons, meteor impact horizons, for example). The broader impacts of the proposed research may include identification of leads and lags between Greenland, tropical, and Antarctic climate change, enabling critical tests of hypotheses for the mechanism of abrupt climate change. Improved understanding of volcanic impacts on atmospheric chemistry and climate may also emerge. This understanding may ultimately help improve climate models and prediction of the Earth System feedback response to ongoing human perturbation in coming centuries. Outreach and public education about climate change are integral components of the PIs\u0027 activities and the proposed work will enhance these efforts. Broader impacts also include education and training of 2 postdoctoral scholars and 1 graduate student, and invaluable field experience for the graduate and undergraduate students who will likely make up the core processing team at WAIS Divide.", "east": -112.09, "geometry": "POINT(-112.09 -79.47)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": false, "keywords": "Ice Core Gas Records; Firn Air Isotopes; LABORATORY; FIELD SURVEYS; Mass Spectrometry; Not provided; WAIS divide; FIELD INVESTIGATION; Ice Core", "locations": "WAIS divide", "north": -79.47, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -79.47, "title": "Collaborative Research: Replicate Coring at WAIS Divide to Obtain Additional Samples at Events of High Scientific Interest", "uid": "p0000751", "west": -112.09}, {"awards": "0944645 Goodge, John", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Wed, 11 Feb 2015 00:00:00 GMT", "description": "Intellectual Merit: \u003cbr/\u003eBecause of extensive ice cover and sparse remote-sensing data, the geology of the Precambrian East Antarctic Shield (EAS) remains largely unexplored with information limited to coastal outcrops from the African, Indian and Australian sectors. The East Antarctic lithosphere is globally important: as one of the largest coherent Precambrian shields, including rocks as old as ~3.8 Ga, it played an important role in global crustal growth; it is a key piece in assembly of the Rodinia and Gondwana supercontinents; it is the substrate to Earth?s major ice cap, including numerous sub-glacial lakes, and influences its thermal state and mechanical stability; and its geotectonic association with formerly adjacent continental blocks in South Africa, India and Australia suggest that it might harbor important mineral resources. This project will increase understanding of the age and composition of the western EAS lithosphere underlying and adjacent to the Transantarctic Mountains (TAM) using U-Pb ages, and Hf- and O-isotope analysis of zircon in early Paleozoic granitoids and Pleistocene glacial tills. TAM granites of the early Paleozoic Ross Orogen represent an areally extensive continental-margin arc suite that can provide direct information about the EAS crust from which it melted and/or through which it passed. Large rock clasts of igneous and metamorphic lithologies entrained in glacial tills at the head of major outlet glaciers traversing the TAM provide eroded samples of the proximal EAS basement. Zircons in these materials will provide data about age and inheritance (U-Pb), crustal vs. mantle origin (O isotopes), and crustal sources and evolution (Hf isotopes). Integrated along a significant part of the TAM, these data will help define broader crustal provinces that can be correlated with geophysical data and used to test models of crustal assembly. \u003cbr/\u003e\u003cbr/\u003eBroader impacts: \u003cbr/\u003eThis project will provide a research opportunity for undergraduate and graduate students. Undergraduates will be involved as Research Assistants in sample preparation, imaging, and analytical procedures, and conducting their own independent research. The two main elements of this project will form the basis of MS thesis projects for two graduate students at UMD. Through this project they will gain a good understanding of petrology, isotope geochemistry, and analytical methods. The broader scientific impacts of this work are that it will help develop a better understanding of the origin and evolution of East Antarctic lithosphere underlying and adjacent to the TAM, which will be of value to the broader earth science and glaciological community. Furthermore, knowledge of East Antarctic geology is of continuing interest to the general public because of strong curiosity about past supercontinents, what?s under the ice, and the impact of global warming on ice-sheet stability.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": false, "keywords": "Transantarctic Mountains; Not provided", "locations": "Transantarctic Mountains", "north": null, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Goodge, John", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": null, "title": "Age and Composition of the East Antarctic Shield by Isotopic Analysis of Granite and Glacial Till", "uid": "p0000258", "west": null}, {"awards": "1241460 Barbeau, David; 1241574 Hemming, Sidney", "bounds_geometry": "POLYGON((-67 -63.2,-65.97 -63.2,-64.94 -63.2,-63.91 -63.2,-62.88 -63.2,-61.85 -63.2,-60.82 -63.2,-59.79 -63.2,-58.76 -63.2,-57.73 -63.2,-56.7 -63.2,-56.7 -63.54,-56.7 -63.88,-56.7 -64.22,-56.7 -64.56,-56.7 -64.9,-56.7 -65.24,-56.7 -65.58,-56.7 -65.92,-56.7 -66.26,-56.7 -66.6,-57.73 -66.6,-58.76 -66.6,-59.79 -66.6,-60.82 -66.6,-61.85 -66.6,-62.88 -66.6,-63.91 -66.6,-64.94 -66.6,-65.97 -66.6,-67 -66.6,-67 -66.26,-67 -65.92,-67 -65.58,-67 -65.24,-67 -64.9,-67 -64.56,-67 -64.22,-67 -63.88,-67 -63.54,-67 -63.2))", "dataset_titles": null, "datasets": null, "date_created": "Wed, 03 Dec 2014 00:00:00 GMT", "description": "Intellectual Merit: \u003cbr/\u003eRecent geochemical, sequence stratigraphic, and integrated investigations of marine strata from several continental margins and ocean basins suggest that ephemeral ice sheets may have existed on Antarctica during parts of the Cretaceous and early Paleogene. However, atmospheric carbon dioxide estimates for this time are as much as four times modern levels. With such greenhouse conditions, the presence of Antarctic ice sheets would imply that our current understanding of Earth?s climate system, and specifically the interpreted thresholds of Antarctic glaciation and deglaciation should be reconsidered. The proposed research will compare the quantity and provenance of Cretaceous sediments in the Larsen basin of the eastern Antarctic Peninsula with the exhumation chronology and composition of potential sediment source terranes on the peninsula and in adjacent regions. New outcrop stratigraphic analyses with improvements in the age models from radioisotopic approaches will be integrated to determine the amount of detrital sediment fluxed to the Larsen basin between key chronostratigraphic surfaces. Microtextural analysis of quartz sand and silt grains will help determine whether the Larsen basin detrital sediment originated from glacial weathering. These preliminary results will test the viability of the proposed approach to assess the controversial Cretaceous Antarctic glaciation hypothesis.\u003cbr/\u003e\u003cbr/\u003eBroader impacts: \u003cbr/\u003eThe proposed work will partially support a PhD, a MSc, and three undergraduate students at the University of South Carolina. The PIs will publicize this work through volunteer speaking engagements and the development of videos and podcasts. They also commit to prompt publication of the results and timely submission of data to archives. The development/improvement of the Larsen basin age model will benefit ongoing research in paleobiology, paleoclimate and biogeography. Development of the glauconite K-Ar and Rb-Sr chronometers could be an important outcome beyond the direct scope of the proposed research.", "east": -56.7, "geometry": "POINT(-61.85 -64.9)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ELECTRON MICROPROBES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e LA-ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MC-ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e IRMS", "is_usap_dc": true, "keywords": "Not provided; Noble-Gas Mass Spectrometer; Antarctic Peninsula", "locations": "Antarctic Peninsula", "north": -63.2, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": "PROTEROZOIC; PHANEROZOIC \u003e PALEOZOIC; PHANEROZOIC \u003e MESOZOIC; PHANEROZOIC \u003e CENOZOIC; PHANEROZOIC \u003e MESOZOIC \u003e CRETACEOUS; PHANEROZOIC \u003e CENOZOIC \u003e PALEOGENE", "persons": "Barbeau, David; Hemming, Sidney R.; Barbeau, David Jr", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -66.6, "title": "Collaborative Research: EAGER: Evaluating the Larsen basin\u0027s suitability for testing the Cretaceous Glaciation Hypothesis", "uid": "p0000369", "west": -67.0}, {"awards": "0944489 Williams, Trevor", "bounds_geometry": "POLYGON((-55 -58,-33.2 -58,-11.4 -58,10.4 -58,32.2 -58,54 -58,75.8 -58,97.6 -58,119.4 -58,141.2 -58,163 -58,163 -60,163 -62,163 -64,163 -66,163 -68,163 -70,163 -72,163 -74,163 -76,163 -78,141.2 -78,119.4 -78,97.6 -78,75.8 -78,54 -78,32.2 -78,10.4 -78,-11.4 -78,-33.2 -78,-55 -78,-55 -76,-55 -74,-55 -72,-55 -70,-55 -68,-55 -66,-55 -64,-55 -62,-55 -60,-55 -58))", "dataset_titles": "History of the East Antarctic Ice Sheet since the mid-Miocene: New Evidence from Provenance of Ice-rafted Debris", "datasets": [{"dataset_uid": "600116", "doi": "10.15784/600116", "keywords": "Geochronology; George V Land; IODP U1356; IODP U1361; Marine Sediments; ODP1165; Prydz Bay; Solid Earth; Southern Ocean; Wilkes Land", "people": "Hemming, Sidney R.; Williams, Trevor", "repository": "USAP-DC", "science_program": null, "title": "History of the East Antarctic Ice Sheet since the mid-Miocene: New Evidence from Provenance of Ice-rafted Debris", "url": "https://www.usap-dc.org/view/dataset/600116"}], "date_created": "Wed, 13 Aug 2014 00:00:00 GMT", "description": "Intellectual Merit: \u003cbr/\u003eThe PIs propose to study the stability and dynamics of the East Antarctic ice sheet during the Pliocene in the area of the Wilkes and Aurora subglacial basins. Models indicate the ice sheet is most sensitive to warming in these low-lying areas. This study is important as there is very little direct evidence about which parts of the East Antarctic ice sheet became unstable under warm conditions. In a pilot study the PIs have shown that the isotopic geochemical signature of downcore ice-rafted debris (IRD) can be linked to continental source areas indicating which parts of the ice sheet reached the coast and calved IRD-bearing icebergs. Their initial results suggest rapid iceberg discharge from the Wilkes Land and Ad\u00e9lie Land coastal areas at times in the late Miocene and early Pliocene. In this study the PIs will analyze IRD from IODP sediment cores collected on the continental rise off East Antarctica. By analyzing 40Ar/39Ar ages of hornblende IRD grains, U-Pb ages of zircons, and Sm-Nd isotopes of the fine fraction of several IRD-rich layers for each core, they will be able to fingerprint continental source areas that will indicated ice extent and dynamics on East Antarctica. The PIs will also carry out detailed studies across a few of these layers to characterize the anatomy of the ice-rafting event and better understand the mechanism of ice destabilization.\u003cbr/\u003e\u003cbr/\u003eBroader impacts: \u003cbr/\u003eThe data collected will be important for scientists in a broad variety of fields. The project will involve one undergraduate student and one summer intern at LDEO, and a graduate student at Imperial College London. The project will expose to cutting edge methodologies as well as an international research team. Data from the project will be deposited in the online databases (SedDB) and all results and methods will be made available to the scientific community through publications in peer-reviewed journals and attendance at international conferences.", "east": 163.0, "geometry": "POINT(54 -68)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -58.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Williams, Trevor; Hemming, Sidney R.", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -78.0, "title": "History of the East Antarctic Ice Sheet since the mid-Miocene: New Evidence from Provenance of Ice-rafted Debris", "uid": "p0000353", "west": -55.0}, {"awards": "0439906 Koch, Paul", "bounds_geometry": "POLYGON((162 -72,162.6 -72,163.2 -72,163.8 -72,164.4 -72,165 -72,165.6 -72,166.2 -72,166.8 -72,167.4 -72,168 -72,168 -72.6,168 -73.2,168 -73.8,168 -74.4,168 -75,168 -75.6,168 -76.2,168 -76.8,168 -77.4,168 -78,167.4 -78,166.8 -78,166.2 -78,165.6 -78,165 -78,164.4 -78,163.8 -78,163.2 -78,162.6 -78,162 -78,162 -77.4,162 -76.8,162 -76.2,162 -75.6,162 -75,162 -74.4,162 -73.8,162 -73.2,162 -72.6,162 -72))", "dataset_titles": "Abandoned Elephant Seal Colonies in Antarctica: Integration of Genetic, Isotopic, and Geologic Approaches toward Understanding Holocene Environmental Change", "datasets": [{"dataset_uid": "600041", "doi": "10.15784/600041", "keywords": "Biota; Isotope; Penguin; Ross Sea; Seals; Southern Ocean", "people": "Koch, Paul", "repository": "USAP-DC", "science_program": null, "title": "Abandoned Elephant Seal Colonies in Antarctica: Integration of Genetic, Isotopic, and Geologic Approaches toward Understanding Holocene Environmental Change", "url": "https://www.usap-dc.org/view/dataset/600041"}], "date_created": "Sat, 30 Oct 2010 00:00:00 GMT", "description": "During previous NSF-sponsored research, the PI\u0027s discovered that southern elephant seal colonies once existed along the Victoria Land coast (VLC) of Antarctica, a region where they are no longer observed. Molted seal skin and hair occur along 300 km of coastline, more than 1000 km from any extant colony. The last record of a seal at a former colony site is at ~A.D. 1600. Because abandonment occurred prior to subantarctic sealing, disappearance of the VLC colony probably was due to environmental factors, possibly cooling and encroachment of land-fast, perennial sea ice that made access to haul-out sites difficult. The record of seal inhabitation along the VLC, therefore, has potential as a proxy for climate change. Elephant seals are a predominantly subantarctic species with circumpolar distribution. Genetic studies have revealed significant differentiation among populations, particularly with regard to that at Macquarie I., which is the extant population nearest to the abandoned VLC colony. Not only is the Macquarie population unique genetically, but it is has undergone unexplained decline of 2%/yr over the last 50 years3. In a pilot study, genetic analyses showed a close relationship between the VLC seals and those at Macquarie I. An understanding of the relationship between the two populations, as well as of the environmental pressures that led to the demise of the VLC colonies, will provide a better understanding of present-day population genetic structure, the effect of environmental change on seal populations, and possibly the reasons underlying the modern decline at Macquarie Island.\u003cbr/\u003eThis project addresses several key research problems: (1) Why did elephant seals colonize and then abandon the VLC? (2) What does the elephant seal record reveal about Holocene climate change and sea-ice conditions? (3) What were the foraging strategies of the seals and did these strategies change over time as climate varied? (4) How does the genetic structure of the VLC seals relate to extant populations? (5) How did genetic diversity change over time and with colony decline? (6) Using ancient samples to estimate mtDNA mutation rates, what can be learned about VLC population dynamics over time? (7) What was the ecological relationship between elephant seals and Adelie penguins that occupied the same sites, but apparently at different times? The proposed work includes the professional training of young researchers and incorporation of data into graduate and undergraduate courses.", "east": 168.0, "geometry": "POINT(165 -75)", "instruments": null, "is_usap_dc": true, "keywords": "FIELD SURVEYS", "locations": null, "north": -72.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Earth Sciences", "paleo_time": null, "persons": "Koch, Paul", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -78.0, "title": "Collaborative Research: Abandoned Elephant Seal Colonies in Antarctica: Integration of Genetic, Isotopic, and Geologic Approaches toward Understanding Holocene Environmental Change", "uid": "p0000533", "west": 162.0}, {"awards": "0538657 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Borehole Temperature Measurement in WDC05A in January 2008 and January 2009; d15N and d18O of air in the WAIS Divide ice core; Low-res d15N and d18O of O2 in the WAIS Divide 06A Deep Core; Ultra-High Resolution LA-ICP-MS Results: DO-21 Rapid Warming Event; WAIS Divide d18Oatm and Siple Dome/WAIS Divide composite and individual delta epsilon LAND", "datasets": [{"dataset_uid": "609637", "doi": "10.7265/N5B27S7S", "keywords": "Antarctica; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.; Orsi, Anais J.", "repository": "USAP-DC", "science_program": null, "title": "Borehole Temperature Measurement in WDC05A in January 2008 and January 2009", "url": "https://www.usap-dc.org/view/dataset/609637"}, {"dataset_uid": "601747", "doi": "10.15784/601747", "keywords": "Antarctica; Delta 15N; Delta 18O; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Gas Records; Ice Core Records; Isotope; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/Ice; WAIS; WAIS divide", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "d15N and d18O of air in the WAIS Divide ice core", "url": "https://www.usap-dc.org/view/dataset/601747"}, {"dataset_uid": "609660", "doi": "10.7265/N5S46PWD", "keywords": "Antarctica; Chemistry:Fluid; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Low-res d15N and d18O of O2 in the WAIS Divide 06A Deep Core", "url": "https://www.usap-dc.org/view/dataset/609660"}, {"dataset_uid": "601041", "doi": "10.15784/601041", "keywords": "Antarctica; Chemistry:Ice; Gas; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; WAIS Divide Ice Core", "people": "Seltzer, Alan; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide d18Oatm and Siple Dome/WAIS Divide composite and individual delta epsilon LAND", "url": "https://www.usap-dc.org/view/dataset/601041"}, {"dataset_uid": "609635", "doi": "10.7265/N51J97PS", "keywords": "Arctic; Geochemistry; GISP; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate", "people": "Mayewski, Paul A.; Kurbatov, Andrei V.; Haines, Skylar", "repository": "USAP-DC", "science_program": null, "title": "Ultra-High Resolution LA-ICP-MS Results: DO-21 Rapid Warming Event", "url": "https://www.usap-dc.org/view/dataset/609635"}], "date_created": "Thu, 08 Jul 2010 00:00:00 GMT", "description": "0538657\u003cbr/\u003eSeveringhaus\u003cbr/\u003eThis award supports a project to develop high-resolution (20-yr) nitrogen and oxygen isotope records on trapped gases in the WAIS Divide ice core (Antarctica), with a comparison record for chronological purposes in the GISP2 (Greenland) ice core. The main scientific objective is to provide an independent temperature-change record for the past 100,000 years in West Antarctica that is not subject to the uncertainty inherent in ice isotopes (18O and deuterium), the classical paleothermometer. Nitrogen isotopes (Delta 15N) in air bubbles in glacial ice record rapid surface temperature change because of thermal fractionation of air in the porous firn layer, and this isotopic anomaly is recorded in bubbles as the firn becomes ice. Using this gas-based temperature-change record, in combination with methane data as interpolar stratigraphic markers, the proposed work will define the precise relative timing of abrupt warming in Greenland and abrupt cooling at the WAIS Divide site during the millennial-scale climatic oscillations of Marine Isotopic Stage 3 (30-70 kyr BP) and the last glacial termination. The nitrogen isotope record also provides constraints on past firn thickness, which inform temperature and accumulation rate histories from the ice core. A search for possible solar-related cycles will be conducted with the WAIS Divide Holocene (Delta 15N.) Oxygen isotopes of O2 (Delta 18Oatm) are obtained as a byproduct of the (Delta 15N) measurement. The gas-isotopic records will enhance the value of other atmospheric gas measurements in WAIS Divide, which are expected to be of unprecedented quality. The high-resolution (Delta 18Oatm) records will provide chronological control for use by the international ice coring community and for surface glacier ice dating. Education of a graduate student, and training of a staff member in the laboratory, will contribute to the nation\u0027s human resource base. Outreach activities in the context of the International Polar Year will be enhanced. International collaboration is planned with the laboratory of LSCE, University of Paris.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e LA-ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Borehole Temperature; LABORATORY; WAIS Divide-project; Depth; Not provided; GROUND-BASED OBSERVATIONS; WAIS divide; Ice Core", "locations": "WAIS divide", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Haines, Skylar; Mayewski, Paul A.; Orsi, Anais J.; Kurbatov, Andrei V.; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Nitrogen and Oxygen Gas Isotopes in the WAIS Divide Ice Core as Constraints on Chronology, Temperature, and Accumulation Rate", "uid": "p0000036", "west": null}, {"awards": "0003956 Burns, Jennifer", "bounds_geometry": "POLYGON((-76.5119 -52.3523,-74.93335 -52.3523,-73.3548 -52.3523,-71.77625 -52.3523,-70.1977 -52.3523,-68.61915 -52.3523,-67.0406 -52.3523,-65.46205 -52.3523,-63.8835 -52.3523,-62.30495 -52.3523,-60.7264 -52.3523,-60.7264 -53.99299,-60.7264 -55.63368,-60.7264 -57.27437,-60.7264 -58.91506,-60.7264 -60.55575,-60.7264 -62.19644,-60.7264 -63.83713,-60.7264 -65.47782,-60.7264 -67.11851,-60.7264 -68.7592,-62.30495 -68.7592,-63.8835 -68.7592,-65.46205 -68.7592,-67.0406 -68.7592,-68.61915 -68.7592,-70.1977 -68.7592,-71.77625 -68.7592,-73.3548 -68.7592,-74.93335 -68.7592,-76.5119 -68.7592,-76.5119 -67.11851,-76.5119 -65.47782,-76.5119 -63.83713,-76.5119 -62.19644,-76.5119 -60.55575,-76.5119 -58.91506,-76.5119 -57.27437,-76.5119 -55.63368,-76.5119 -53.99299,-76.5119 -52.3523))", "dataset_titles": "Expedition Data", "datasets": [{"dataset_uid": "001757", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/LMG0205"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "The U.S. Global Ocean Ecosystems Dynamics (U.S. GLOBEC) program has the goal of understanding and ultimately predicting how populations of marine animal species respond to natural and anthropogenic changes in climate. Research in the Southern Ocean (SO) indicates strong coupling between climatic processes and ecosystem dynamics via the annual formation and destruction of sea ice. The Southern Ocean GLOBEC Program (SO GLOBEC) will investigate the dynamic relationship between physical processes and ecosystem responses through identification of critical parameters that affect the distribution, abundance and population dynamics of target species. The overall goals of the SO GLOBEC program are to elucidate shelf circulation processes and their effect on sea ice formation and krill distribution, and to examine the factors which govern krill survivorship and availability to higher trophic levels, including penguins, seals and whales. The focus of the U.S. contribution to the international SO GLOBEC program will be on winter processes. This component will focus on the distribution and foraging behavior of adult female crabeater seals, using a combination of satellite-linked tracking, specialized diver recorders, and stable isotopic tracers. This research will be coordinated with components focused on prey (krill) distribution and the physical environment. The results will be analyzed using an optimality model. The result of the integrated SO GLOBEC program will be to improve the predictability of living marine resources, especially with respect to local and global climatic shifts.", "east": -60.7264, "geometry": "POINT(-68.61915 -60.55575)", "instruments": null, "is_usap_dc": false, "keywords": "R/V LMG", "locations": null, "north": -52.3523, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Costa, Daniel", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V LMG", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": -68.7592, "title": "Foraging Ecology of Crabeater Seals (Lobodon Carcinophagus)", "uid": "p0000599", "west": -76.5119}, {"awards": "9981683 Costa, Daniel", "bounds_geometry": null, "dataset_titles": "Expedition Data; Expedition data of LMG0106; Expedition data of LMG0203; Expedition data of LMG0205", "datasets": [{"dataset_uid": "002701", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of LMG0205", "url": "https://www.rvdata.us/search/cruise/LMG0205"}, {"dataset_uid": "002698", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of LMG0106", "url": "https://www.rvdata.us/search/cruise/LMG0106"}, {"dataset_uid": "001757", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/LMG0205"}, {"dataset_uid": "002695", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of LMG0106", "url": "https://www.rvdata.us/search/cruise/LMG0106"}, {"dataset_uid": "002700", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of LMG0203", "url": "https://www.rvdata.us/search/cruise/LMG0203"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "The U.S. Global Ocean Ecosystems Dynamics (U.S. GLOBEC) program has the goal of understanding and ultimately predicting how populations of marine animal species respond to natural and anthropogenic changes in climate. Research in the Southern Ocean (SO) indicates strong coupling between climatic processes and ecosystem dynamics via the annual formation and destruction of sea ice. The Southern Ocean GLOBEC Program (SO GLOBEC) will investigate the dynamic relationship between physical processes and ecosystem responses through identification of critical parameters that affect the distribution, abundance and population dynamics of target species. The overall goals of the SO GLOBEC program are to elucidate shelf circulation processes and their effect on sea ice formation and krill distribution, and to examine the factors which govern krill survivorship and availability to higher trophic levels, including penguins, seals and whales. The focus of the U.S. contribution to the international SO GLOBEC program will be on winter processes. This component will focus on the distribution and foraging behavior of adult female crabeater seals, using a combination of satellite-linked tracking, specialized diver recorders, and stable isotopic tracers. This research will be coordinated with components focused on prey (krill) distribution and the physical environment. The results will be analyzed using an optimality model. The result of the integrated SO GLOBEC program will be to improve the predictability of living marine resources, especially with respect to local and global climatic shifts.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": false, "keywords": "R/V LMG", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Costa, Daniel", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V LMG", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "Foraging Ecology of Crabeater Seals (Lobodon Carcinophagus)", "uid": "p0000866", "west": null}, {"awards": "0338008 Wemple, Beverley", "bounds_geometry": null, "dataset_titles": "Laboratory Studies of Isotopic Exchange in Snow; Snow Accumulation and Snow Melt in a Mixed Northern Hardwood-Conifer Forest", "datasets": [{"dataset_uid": "609441", "doi": "10.7265/N54X55R2", "keywords": "Snow/Ice", "people": "Wemple, Beverley C.", "repository": "USAP-DC", "science_program": null, "title": "Snow Accumulation and Snow Melt in a Mixed Northern Hardwood-Conifer Forest", "url": "https://www.usap-dc.org/view/dataset/609441"}, {"dataset_uid": "609445", "doi": "10.7265/N51834DX", "keywords": "Atmosphere; Chemistry:Ice; Snow/Ice; Snow Sublimation Rate", "people": "Neumann, Thomas A.", "repository": "USAP-DC", "science_program": null, "title": "Laboratory Studies of Isotopic Exchange in Snow", "url": "https://www.usap-dc.org/view/dataset/609445"}], "date_created": "Fri, 01 Jan 2010 00:00:00 GMT", "description": "This award supports a project to develop a quantitative understanding of the processes active in isotopic exchange between snow/firn and water vapor, which is of paramount importance to ice core interpretation. Carefully controlled laboratory studies will be conducted at a variety of temperatures to empirically measure the mass transfer coefficient (the rate at which water moves from the solid to the vapor phase) for sublimating snow and to determine the time scale for isotopic equilibration between water vapor and ice. In addition the isotopic fractionation coefficient for vapor derived from sublimating ice will be determined and the results will be used to update existing models of mass transfer and isotopic evolution in firn. It is well known that water vapor moves through firn due to diffusion, free convection and forced convection. Although vapor movement through variably-saturated firn due to these processes has been modeled, because of a lack of laboratory data the mass transfer coefficient had to be estimated. Field studies have documented the magnitudes of post-depositional changes, but field studies do not permit rigorous analysis of the relative importance of the many processes which are likely to act in natural snow packs. The results of these laboratory investigations will be broadly applicable to a number of studies and will allow for improvement of existing physically-based models of post-depositional isotopic change, isotopic diffusion in firn, and vapor motion in firn. A major component of this project will be the design and fabrication of the necessary, novel experimental apparatus, which will be facilitated by existing technical expertise, cold room facilities, and laboratory equipment at CRREL. This project is a necessary step toward a quantitative understanding of the isotopic effects of water vapor movement in firn. The proposed work has broader impacts in several different areas. The modeling results will be applicable to a wide range of studies of water in the polar environment, including studies of wind-blown or drifting snow. The proposed collaborative study will partially support a Dartmouth graduate student for three years. This project will also provide support for a young first-time NSF investigator at the University of Vermont. Undergraduate students from Dartmouth will be involved in the research through the Women in Science Project and undergraduate students at the University of Vermont will be supported through the Research Experiences for Undergraduates program. The principal investigators and graduate student will continue their tradition of k-12 school outreach by giving science lessons and talks in local schools each year. Research results will be disseminated through scientific conferences, journal publications, and institutional seminars.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e CAMERAS \u003e CAMERAS; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e SNOW TUBE; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e HYGROMETERS \u003e HYGROMETERS", "is_usap_dc": true, "keywords": "Snow Accumulation; Snow Chemistry; Snow Melt; Snowfall; Snow Water Equivalent; LABORATORY; Seasonal Snow Cover; Not provided; Snow; Sublimation Rate; FIELD SURVEYS; FIELD INVESTIGATION", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Neumann, Thomas A.; Wemple, Beverley C.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Laboratory Studies of Isotopic Exchange in Snow and Firn", "uid": "p0000132", "west": null}, {"awards": "0440975 Severinghaus, Jeffrey", "bounds_geometry": "POINT(-119.533333 -80.016667)", "dataset_titles": "Nitrogen and Oxygen Gas Isotopes in the Siple Dome and Byrd Ice Cores, Antarctica", "datasets": [{"dataset_uid": "609407", "doi": "10.7265/N55X26V0", "keywords": "Antarctica; Arctic; Atmosphere; Byrd Glacier; Byrd Ice Core; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/Ice Sheet; Ice Core Records; Isotope; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Nitrogen and Oxygen Gas Isotopes in the Siple Dome and Byrd Ice Cores, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609407"}], "date_created": "Fri, 17 Jul 2009 00:00:00 GMT", "description": "The award supports the development of high-resolution nitrogen and oxygen isotope records on trapped gases in the Byrd and Siple Dome ice cores, and the Holocene part of the GISP2 ice core. The primary scientific goals of this work are to understand the enigmatic d15N anomalies seen thus far in the Siple Dome record at 15.3 ka and 35 ka, and to find other events that may occur in both cores. At these events, d15N of trapped air approaches zero, implying little or no gravitational fractionation of gases in the firn layer at the time of formation of the ice. These events may represent times of low accumulation rate and arid meteorological conditions, and thus may contain valuable information about the climatic history of West Antarctica. Alternatively, they may stem from crevassing and thus may reveal ice-dynamical processes. Finding the events in the Byrd core, which is located 500 km from Siple Dome, would place powerful constraints on their origin and significance. A second major goal is to explore the puzzling absence of the abrupt warming event at 22 ka (seen at Siple Dome) in the nearby Byrd 18O/16O record in the ice (d18Oice), and search for a possible correlative signal in Byrd d15N. A third goal takes advantage of the fact that precise measurements of the oxygen isotopic composition of atmospheric O2 (d18Oatm) are obtained as a byproduct of the d15N measurement. The proposed gas-isotopic measurements will underpin an integrated suite of West Antarctic climate and atmospheric gas records, which will ultimately include the WAIS Divide core. These records will help separate regional from global climate signals, and may place constraints on the cause of abrupt climate change. Education of two graduate students, and training of two staff members in the laboratory, contribute to the nation\u0027s human resource base. Education and outreach will be an important component of the project.", "east": -119.533333, "geometry": "POINT(-119.533333 -80.016667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Firn Air Isotopes; Not provided; Nitrogen Isotopes; LABORATORY; Firn Isotopes; Paleoclimate; FIELD SURVEYS; Ice Core; Oxygen Isotope; FIELD INVESTIGATION; Siple Dome", "locations": "Antarctica; Siple Dome", "north": -80.016667, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -80.016667, "title": "Nitrogen and oxygen gas isotopes in the Siple Dome and Byrd ice cores", "uid": "p0000450", "west": -119.533333}, {"awards": "0536526 Le Masurier, Wesley", "bounds_geometry": "POLYGON((-136 -73,-133.4 -73,-130.8 -73,-128.2 -73,-125.6 -73,-123 -73,-120.4 -73,-117.8 -73,-115.2 -73,-112.6 -73,-110 -73,-110 -73.425,-110 -73.85,-110 -74.275,-110 -74.7,-110 -75.125,-110 -75.55,-110 -75.975,-110 -76.4,-110 -76.825,-110 -77.25,-112.6 -77.25,-115.2 -77.25,-117.8 -77.25,-120.4 -77.25,-123 -77.25,-125.6 -77.25,-128.2 -77.25,-130.8 -77.25,-133.4 -77.25,-136 -77.25,-136 -76.825,-136 -76.4,-136 -75.975,-136 -75.55,-136 -75.125,-136 -74.7,-136 -74.275,-136 -73.85,-136 -73.425,-136 -73))", "dataset_titles": "Geochemistry and Petrologic Evolution of Felsic Volcanoes in Western Marie Byrd Land, Antarctica", "datasets": [{"dataset_uid": "600051", "doi": "10.15784/600051", "keywords": "Antarctica; Chemistry:Rock; Geochemistry; IntraContinental Magmatism; Marie Byrd Land; Solid Earth", "people": "Le Masurier, Wesley", "repository": "USAP-DC", "science_program": null, "title": "Geochemistry and Petrologic Evolution of Felsic Volcanoes in Western Marie Byrd Land, Antarctica", "url": "https://www.usap-dc.org/view/dataset/600051"}], "date_created": "Wed, 24 Jun 2009 00:00:00 GMT", "description": "This project uses geochemical studies to determine the origin of volcanic rocks from Marie Byrd Land (MBL), Antarctica. Surprisingly, adjacent volcanoes in the MBL have dramatically different compositions, ranging from phonolite to trachyte to rhyolite. This diversity offers an opportunity to constrain the processes responsible for generating silica oversaturated and undersaturated magmas in a single geologic setting. Previous work suggests that the most obvious and simplest explanation--crustal contamination--is not a significant factor, and that polybaric fractional crystallization is the major cause. This study evaluates these factors through analyses and interpretation of trace and rare earth element abundances, as well as Sr and Nd isotopic ratios. \u003cbr/\u003e\u003cbr/\u003eThe broader impacts include outreach programs to the Girl Scouts of America, and dissemination of results through publications and meetings.", "east": -110.0, "geometry": "POINT(-123 -75.125)", "instruments": null, "is_usap_dc": true, "keywords": "FIELD SURVEYS", "locations": null, "north": -73.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Le Masurier, Wesley", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.25, "title": "Geochemistry and Petrologic Evolution of Felsic Volcanoes in Western Marie Byrd Land, Antarctica", "uid": "p0000534", "west": -136.0}, {"awards": "0453680 Sigman, Daniel", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Robinson et al. 2004 Southern Ocean Diatom-bound Nitrogen and d15N Data", "datasets": [{"dataset_uid": "000119", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Robinson et al. 2004 Southern Ocean Diatom-bound Nitrogen and d15N Data", "url": "https://www.ncdc.noaa.gov/paleo-search/study/8751"}], "date_created": "Wed, 20 May 2009 00:00:00 GMT", "description": "The Southern Ocean may play a central role in causing ice ages and general global climate change. This work will reveal key characteristics of the glacial ocean, and may explain the cause of glacial/interglacial cycles by measuring the abundances of certain isotopes of nitrogen found in fossil diatoms from Antarctic marine sediments. Diatom-bound N is a potentially important recorder of nutrient utilization. The Southern Ocean\u0027s nutrient status, productivity and circulation may be central to setting global atmospheric CO2 contents and other aspects of climate. Previous attempts to make these measurements have yielded ambiguous results. This project includes both technique development and analyses, including measurements on diatoms from both sediment traps and culture experiments. With regard to broader impacts, this grant is focused around the education and academic development of a graduate student, by coupling their research with mentorship of an undergraduate researcher", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -60.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Sigman, Daniel", "platforms": "Not provided", "repo": "NCEI", "repositories": "NCEI", "science_programs": null, "south": -90.0, "title": "Application of a New Method for Isotopic Analysis of Diatom Microfossil-bound Nitrogen", "uid": "p0000550", "west": -180.0}, {"awards": "0440498 White, James; 0440509 Battle, Mark; 0440759 Sowers, Todd; 0440602 Saltzman, Eric; 0440615 Brook, Edward; 0440701 Severinghaus, Jeffrey", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane Isotopes from the WAIS Divide Ice Core; Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A; WAIS ice core Methane Data, Carbon Dioxide Data", "datasets": [{"dataset_uid": "609638", "doi": "10.7265/N56971HF", "keywords": "Antarctica; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.; Orsi, Anais J.", "repository": "USAP-DC", "science_program": null, "title": "Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A", "url": "https://www.usap-dc.org/view/dataset/609638"}, {"dataset_uid": "609412", "doi": "10.7265/N5251G40", "keywords": "Antarctica; Atmosphere; Chemistry:Fluid; Geochemistry; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/Ice; WAIS divide; WAIS Divide Ice Core", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609412"}, {"dataset_uid": "609435", "doi": "10.7265/N5J67DW0", "keywords": "Antarctica; Chemistry:Fluid; Geochemistry; Glaciers/Ice Sheet; Ice Core Records; Isotope; Methane; Paleoclimate; WAIS divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Methane Isotopes from the WAIS Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609435"}, {"dataset_uid": "609493", "doi": "10.7265/N5319SV3", "keywords": "Antarctica; Chemistry:Fluid; Geochemistry; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS divide; WAIS Divide Ice Core", "people": "Taylor, Kendrick C.; Sowers, Todd A.; Mitchell, Logan E; Brook, Edward J.; McConnell, Joseph", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS ice core Methane Data, Carbon Dioxide Data", "url": "https://www.usap-dc.org/view/dataset/609493"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; gas measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}], "date_created": "Tue, 03 Feb 2009 00:00:00 GMT", "description": "This award supports a project to measure the elemental and isotopic composition of firn air and occluded air in shallow boreholes and ice cores from the WAIS Divide site, the location of a deep ice-coring program planned for 2006-07 and subsequent seasons. The three primary objectives are: 1) to establish the nature of firn air movement and trapping at the site to aid interpretations of gas data from the deep core; 2) to expand the suite of atmospheric trace gas species that can be measured in ice and replicate existing records of other species; and 3) to inter-calibrate all collaborating labs to insure that compositional and isotopic data sets are inter-comparable. The program will be initiated with a shallow drilling program during the 05/06 field season which will recover two 300+m cores and firn air samples. The ice core and firn air will provide more than 700 years of atmospheric history that will be used to address a number of important questions related to atmospheric change over this time period. The research team consists of six US laboratories that also plan to participate in the deep core program. This collaborative research program has a number of advantages. First, the scientists will be able to coordinate sample allocation a priori to maximize the resolution and overlap of records of interrelated species. Second, sample registration will be exact, allowing direct comparison of all records. Third, a coherent data set will be produced at the same time and all PI.s will participate in interpreting and publishing the results. This will insure that the best possible understanding of gas records at the WAIS Divide site will be achieved, and that all work necessary to interpret the deep core is conducted in a timely fashion. The collaborative structure created by the proposal will encourage sharing of techniques, equipment, and ideas between the laboratories. The research will identify impacts of various industrial/agricultural activities and help to distinguish them from natural variations, and will include species for which there are no long records of anthropogenic impact. The work will also help to predict future atmospheric loadings. The project will contribute to training scientists at several levels, including seven undergraduates, two graduate students and one post doctoral fellow.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e SPECTROMETERS/RADIOMETERS \u003e SPECTROMETERS \u003e SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; Firn; LABORATORY; Ice Core; Firn Air Isotope Measurements; Shallow Firn Air; FIELD INVESTIGATION; Ice Core Gas Records; GROUND-BASED OBSERVATIONS; Firn Isotopes; gas data; Polar Firn Air; Not provided; Trapped Gases; West Antarctic Ice Sheet; Ice Sheet; Gas; deep core; Firn Air Isotopes; WAIS Divide-project; FIELD SURVEYS; Atmospheric Gases; Isotope; trace gas species; Atmosphere; Ice Core Data; Surface Temperatures; Firn Air; air samples; cores; Borehole; WAIS divide; Antarctica", "locations": "West Antarctic Ice Sheet; Antarctica; WAIS divide", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Battle, Mark; Mischler, John; Saltzman, Eric; Aydin, Murat; White, James; Brook, Edward J.; Orsi, Anais J.; Severinghaus, Jeffrey P.; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "uid": "p0000368", "west": -112.085}, {"awards": "0230268 Anderson, Robert", "bounds_geometry": "POLYGON((-180 -50,-169 -50,-158 -50,-147 -50,-136 -50,-125 -50,-114 -50,-103 -50,-92 -50,-81 -50,-70 -50,-70 -51.5,-70 -53,-70 -54.5,-70 -56,-70 -57.5,-70 -59,-70 -60.5,-70 -62,-70 -63.5,-70 -65,-81 -65,-92 -65,-103 -65,-114 -65,-125 -65,-136 -65,-147 -65,-158 -65,-169 -65,180 -65,177 -65,174 -65,171 -65,168 -65,165 -65,162 -65,159 -65,156 -65,153 -65,150 -65,150 -63.5,150 -62,150 -60.5,150 -59,150 -57.5,150 -56,150 -54.5,150 -53,150 -51.5,150 -50,153 -50,156 -50,159 -50,162 -50,165 -50,168 -50,171 -50,174 -50,177 -50,-180 -50))", "dataset_titles": "Southern Ocean Deglacial Opal, Radionuclide, and Diatom Upwelling Data", "datasets": [{"dataset_uid": "000199", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Southern Ocean Deglacial Opal, Radionuclide, and Diatom Upwelling Data", "url": "https://www.ncdc.noaa.gov/paleo/study/8439"}], "date_created": "Mon, 12 Jan 2009 00:00:00 GMT", "description": "This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a project to investigate the \"Silicic Acid Leakage Hypothesis\" as it relates to global carbon dioxide fluctuations during glacial-interglacial cycles.\u003cbr/\u003e\u003cbr/\u003eIntellectual Merit\u003cbr/\u003eThis project will evaluate the burial rate of biogenic opal in the Pacific sector of the Southern Ocean, both during the Last Glacial Maximum (LGM) and during the Holocene, as a critical test of the \"Silicic Acid Leakage Hypothesis\". \u003cbr/\u003e\u003cbr/\u003eThe \"Silicic Acid Leakage Hypothesis\" has been proposed recently to explain the glacial reduction in the carbon dioxide content of the atmosphere that has been reconstructed from Antarctic ice cores. Vast amounts of dissolved Si (silicic acid) are supplied to surface waters of the Southern Ocean by wind-driven upwelling of deep waters. Today, that dissolved Si is consumed almost quantitatively by diatoms who form skeletal structures composed of biogenic opal (a mineral form of silicon). According to the \"Silicic Acid Leakage Hypothesis\", environmental conditions in the Southern Ocean during glacial periods were unfavorable for diatom growth, leading to reduced (compared to interglacials) efficiency of dissolved Si utilization. Dissolved Si that was not consumed biologically in the glacial Southern ocean was then exported to the tropics in waters that sink in winter to depths of a few hundred meters along the northern fringes of the Antarctic Circumpolar Current, and return some decades later to the sunlit surface in tropical regions of wind-driven upwelling. \u003cbr/\u003e\u003cbr/\u003eAn increase in the amount of dissolved Si that \"leaks\" out of the Southern Ocean and later upwells at low latitudes could shift the global average composition of phytoplankton toward a greater abundance of diatoms and fewer CaCO3-secreting taxa (especially coccolithophorids). Consequences of such a taxonomic shift in the ocean\u0027s phytoplankton assemblage include:\u003cbr/\u003e a) an increase in the global average organic carbon/calcium carbonate ratio of particulate biogenic material sinking into the deep sea;\u003cbr/\u003e b) a reduction in the preservation and burial of calcium carbonate in marine sediments;\u003cbr/\u003e c) an increase in ocean alkalinity as a consequence of the first two changes mentioned above, and;\u003cbr/\u003e d) a lowering of atmospheric CO2 concentrations in response to increased alkalinity of ocean waters. \u003cbr/\u003e\u003cbr/\u003eA complete assessment of the Silicic acid leakage hypothesis will require an evaluation of: (1) Si utilization efficiencies using newly-developed stable isotopic techniques; (2) opal burial rates in low-latitude upwelling regions; and (3) opal burial rates in the Southern Ocean. This project addresses the last of these topics. \u003cbr/\u003e\u003cbr/\u003ePrevious work has shown that there was little change in opal burial rate between the LGM and the Holocene in the Atlantic and Indian sectors of the Southern Ocean. Preliminary results (summarized in this proposal) suggest that the Pacific may have been different, however, in that opal burial rates in the Pacific sector seem to have been lower during the LGM than during the Holocene, allowing for the possibility of \"Si leakage\" from this region. However, available results are too sparse to make any quantitative conclusions at this time. For that reason, we propose to make a comprehensive evaluation of opal burial rates in the Pacific sector of the Southern Ocean. \u003cbr/\u003e\u003cbr/\u003eSignificance and Broader Impacts\u003cbr/\u003eDetermining the mechanism(s) by which the ocean has regulated climate-related changes in the CO2 content of the atmosphere has been the focus of a substantial effort by paleoceanographers over the past two decades. The Silicic Acid Leakage Hypothesis is a viable new candidate mechanism that warrants further exploration and testing. Completion of the proposed work will contribute significantly to that effort. \u003cbr/\u003e\u003cbr/\u003eDuring the course of this work, several undergraduates will be exposed to paleoclimate research through their involvement in this project. Burckle and Anderson are both dedicated to the education and training of young scientists, and to the recruitment of women and under-represented minorities. To illustrate, two summer students (undergraduates) worked in Burckle\u0027s lab during the summer of 2002. One was a woman and the other (male) was a member of an under-represented minority. Anderson and Burckle will continue with similar recruitment efforts during the course of the proposed study. A minority student who has expressed an interest in working on this research during the summer of 2003 has already been identified.", "east": -70.0, "geometry": "POINT(-140 -57.5)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -50.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Anderson, Robert; Burckle, Lloyd", "platforms": "Not provided", "repo": "NCEI", "repositories": "NCEI", "science_programs": null, "south": -65.0, "title": "Opal Burial in the Pacific Sector of the Southern Ocean: A Test of the \"Silicic Acid Leakage Hypothesis.\"", "uid": "p0000457", "west": 150.0}, {"awards": "0337891 Brook, Edward", "bounds_geometry": "POINT(158 -77.666667)", "dataset_titles": "Atmospheric CO2 and Climate: Byrd Ice Core, Antarctica; Atmospheric CO2 and Climate: Taylor Dome Ice Core, Antarctica", "datasets": [{"dataset_uid": "609315", "doi": "10.7265/N5542KJK", "keywords": "Antarctica; Atmosphere; Chemistry:Ice; Geochemistry; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Taylor Dome; Taylor Dome Ice Core", "people": "Ahn, Jinho; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Atmospheric CO2 and Climate: Taylor Dome Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609315"}, {"dataset_uid": "609314", "doi": "10.7265/N58W3B80", "keywords": "Antarctica; Atmosphere; Byrd Glacier; Byrd Ice Core; Chemistry:Ice; Geochemistry; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate", "people": "Ahn, Jinho; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Byrd Ice Core", "title": "Atmospheric CO2 and Climate: Byrd Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609314"}], "date_created": "Mon, 05 Nov 2007 00:00:00 GMT", "description": "This award supports the development of a new laboratory capability in the U.S. to measure CO2 in ice cores and investigate millennial-scale changes in CO2 during the last glacial period using samples from the Byrd and Siple Dome ice cores. Both cores have precise relative chronologies based on correlation of methane and the isotopic composition of atmospheric oxygen with counterpart records from Greenland ice cores. The proposed work will therefore allow comparison of the timing of CO2 change, Antarctic temperature change, and Greenland temperature change on common time scales. Such comparisons are vital for evaluating models that explain changes in atmospheric CO2. The techniques being developed will also be available for future projects, specifically the proposed Inland WAIS ice core, for which a highly detailed CO2 record is a major objective, and studies greenhouse and other atmospheric gases and their isotopic composition for which dry extraction is necessary (stable isotopes in CO2, for example). There are many broad impacts of the proposed work. Ice core greenhouse gas records are central contributions of paleoclimatology to research and policy-making concerning global change. The proposed work will enhance those contributions by improving our understanding of the natural cycling of the most important greenhouse gas. It will contribute to the training of a postdoctoral researcher, who will be an integral part of an established research group and benefit from the diverse paleoclimate and geochemistry community at OSU. The PI teaches major and non-major undergraduate and graduate courses on climate and global change. The proposed work will enrich those courses and the courses will provide an opportunity for the postdoctoral researcher to participate in teaching by giving guest lectures. The PI also participates in a summer climate workshop for high school teachers at Washington State University and the proposed work will enrich that contribution. The extraction device that is built and the expertise gained in using it will be resources for the ice core community and available for future projects. Data will be made available through established national data center and the equipment designs will also be made available to other researchers.", "east": 158.0, "geometry": "POINT(158 -77.666667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core; Climate Change; CO2; Atmospheric Chemistry; Atmospheric CO2; LABORATORY; Not provided; Ice Core Data; Climate; Ice Core Chemistry; Atmospheric Gases; Ice Core Gas Records; GROUND STATIONS; Climate Research", "locations": null, "north": -77.666667, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Ahn, Jinho; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.666667, "title": "Developing Dry Extraction of Ice Core Gases and Application to Millennial-Scale Variability in Atmospheric CO2", "uid": "p0000268", "west": 158.0}, {"awards": "0603729 Mukasa, Samuel", "bounds_geometry": "POLYGON((161.2 -77.5029,161.26 -77.5029,161.32 -77.5029,161.38 -77.5029,161.44 -77.5029,161.5 -77.5029,161.56 -77.5029,161.62 -77.5029,161.68 -77.5029,161.74 -77.5029,161.8 -77.5029,161.8 -77.52511,161.8 -77.54732,161.8 -77.56953,161.8 -77.59174,161.8 -77.61395,161.8 -77.63616,161.8 -77.65837,161.8 -77.68058,161.8 -77.70279,161.8 -77.725,161.74 -77.725,161.68 -77.725,161.62 -77.725,161.56 -77.725,161.5 -77.725,161.44 -77.725,161.38 -77.725,161.32 -77.725,161.26 -77.725,161.2 -77.725,161.2 -77.70279,161.2 -77.68058,161.2 -77.65837,161.2 -77.63616,161.2 -77.61395,161.2 -77.59174,161.2 -77.56953,161.2 -77.54732,161.2 -77.52511,161.2 -77.5029))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 02 Aug 2007 00:00:00 GMT", "description": "This Small Grant for Exploratory Research supports measurement of PGE abundances and Hf, Nd, Sr and Pb isotopic ratios of the Basement Sill and Dais Intrusion lobe of the Ferrar Magmatic Province, Antarctica. This province played a key role in the breakup of Gondwanaland. Models to be tested are magma production by plume activity versus decompression melting in a fossil subduction zone. The PGE data will also be used to evaluate the behavior of volatiles during magma crystallization, which other evidence indicates may have reached saturation. The samples to be studied were collected during the NSF-sponsored, Magmatic Field Laboratory Workshop held in Antarctica in 2005. This study\u0027s results will be compliled with complementary data from other attendees to develop a new multidisciplinary model of Ferrar magmatism.\u003cbr/\u003e\u003cbr/\u003eThe broader impacts fo this work include international collaboration and informal science education through public outreach to K12 students.", "east": 161.8, "geometry": "POINT(161.5 -77.61395)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS", "is_usap_dc": false, "keywords": "Ferrar magmatism; Ferrar Magmatic Province; Basement Sill; Antarctic; HELICOPTER; Dais Intrusion lobe; magma crystallization; Antarctica", "locations": "Antarctica; Antarctic", "north": -77.5029, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Mukasa, Samuel", "platforms": "AIR-BASED PLATFORMS \u003e ROTORCRAFT/HELICOPTER \u003e HELICOPTER", "repositories": null, "science_programs": null, "south": -77.725, "title": "SGER: Basement Sill, Antarctica: Constraints from its PGE Abundance Patterns and Isotopic Compositions on Magma Source Characteristics and Crystallization Processes", "uid": "p0000278", "west": 161.2}, {"awards": "9526556 Sowers, Todd", "bounds_geometry": "POINT(-148.3023 -81.403)", "dataset_titles": "Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica", "datasets": [{"dataset_uid": "609310", "doi": "10.7265/N5ST7MR2", "keywords": "Antarctica; Atmosphere; Chemistry:Fluid; Geochemistry; Siple Dome; Snow/Ice; South Pole", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609310"}], "date_created": "Mon, 09 Jul 2007 00:00:00 GMT", "description": "This award is for support for a program to reconstruct records of the isotopic composition of paleoatmospheric methane and nitrous oxide covering the last 200,000 years. High resolution measurements of the carbon-13 isotopic composition of methane from shallow ice cores will help to determine the relative contributions of biogenic (wetlands, rice fields and ruminants) and abiogenic (biomass burning and natural gas) methane emissions which have caused the concentrations of this gas to increase at an exponential rate during the anthropogenic period. Isotopic data on methane and nitrous oxide over glacial/interglacial timescales will help determine the underlying cause of the large concentration variations that are known to occur. This project will make use of a new generation mass spectrometer which is capable of generating precise isotopic information on nanomolar quantities of methane and nitrous oxide, which means that samples can be 1000 times smaller than those needed for a standard isotope ratio instrument. The primary objective of the work is to further our understanding of the biogeochemical cycles of these two greenhouse gases throughout the anthropogenic period as well as over glacial interglacial timescales.", "east": -148.3023, "geometry": "POINT(-148.3023 -81.403)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core; Firn Air Isotope Measurements; Ice Core Chemistry; Firn Isotopes; Stable Isotopes; Methane; Carbon; Paleoclimate; LABORATORY; Siple Dome; Antarctica; Ice Core Data; Firn Air Isotopes; Antarctic Ice Sheet", "locations": "Antarctica; Antarctic Ice Sheet; Siple Dome", "north": -81.403, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Sowers, Todd A.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.403, "title": "Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide", "uid": "p0000611", "west": -148.3023}, {"awards": "0229917 Becker, Luann", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Wed, 24 Jan 2007 00:00:00 GMT", "description": "This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports an interdisciplinary study of fluvial sediments in Antarctica for evidence of what caused the greatest of all mass extinctions in the history of life at the Permian-Triassic boundary. This boundary was, until recently, difficult to locate and thought to be unequivocally disconformable in Antarctica. New studies, particularly of carbon isotopic chemostratigraphy and of paleosols and root traces as paleoecosystem indicators, together with improved fossil plant, reptile and pollen biostratigraphy, now suggest that the precise location of the boundary might be identified and have led to local discovery of iridium anomalies, shocked quartz, and fullerenes with extraterrestrial noble gases. These anomalies are associated with a distinctive claystone breccia bed, similar to strata known in South Africa and Australia, and taken as evidence of deforestation. There is already much evidence from Antarctica and elsewhere that the mass extinction on land was abrupt and synchronous with extinction in the ocean. The problem now is what led to such death and destruction. Carbon isotopic values are so low in these and other Permian-Triassic boundary sections that there was likely to have been some role for catastrophic destabilization of methane clathrates. Getting the modeled amount of methane out of likely reservoirs would require such catastrophic events as bolide impact, flood-basalt eruption or continental-shelf collapse, which have all independently been implicated in the mass extinction and for which there is independent evidence. Teasing apart these various hypotheses requires careful re-examination of beds that appear to represent the Permian-Triassic boundary, and search for more informative sequences, as was the case for the Cretaceous-Tertiary boundary. This collaborative research on geochemistry and petrography of boundary beds and paleosols (by Retallack), on carbon isotopic variation through the boundary interval (by Jahren), and on fullerenes, iridium and helium (by Becker) is designed to test these ideas about the Permian-Triassic boundary in Antarctica and to shed light on processes which contributed to this largest of mass extinctions on Earth. Fieldwork for this research will be conducted in the central Transantarctic Mountains and in Southern Victoria Land with an initial objective of examining the stratigraphic sequences for continuity across the boundary. Stratigraphic continuity is a critical element that must exist for the work to be successful. If fieldwork indicates sufficiently continuous sections, the full analytical program will follow fieldwork.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e PROBES; SOLAR/SPACE OBSERVING INSTRUMENTS \u003e PARTICLE DETECTORS \u003e SEM", "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Becker, Luann", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": null, "title": "Collaborative Research: Permian-Triassic Mass Extinction in Antarctica", "uid": "p0000718", "west": null}, {"awards": "0338363 Thiemens, Mark; 0337933 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Major Ion Concentrations in 2004 South Pole Ice Core", "datasets": [{"dataset_uid": "609542", "doi": "10.7265/N5HX19N8", "keywords": "Antarctica; Chemistry:Ice; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Major Ion Concentrations in 2004 South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609542"}], "date_created": "Fri, 11 Aug 2006 00:00:00 GMT", "description": "This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Not provided; Ion Chromatograph; Ions; LABORATORY; GROUND-BASED OBSERVATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Investigating Atmospheric Chemistry and Dynamics through Oxygen and Sulfur Isotopes in Volcanic Sulfate from South Pole Ice Cores", "uid": "p0000031", "west": null}, {"awards": "0230316 White, James; 0230348 Dunbar, Nelia; 0230021 Sowers, Todd", "bounds_geometry": "POINT(135.1333 -76.05)", "dataset_titles": "Mount Moulton Isotopes and Other Ice Core Data", "datasets": [{"dataset_uid": "609640", "doi": "10.7265/N5FT8J0N", "keywords": "Antarctica; Chemistry:Ice; EPICA Dome C; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Lake Vostok; Mount Moulton; Paleoclimate; Talos Dome; Taylor Dome", "people": "Steig, Eric J.; Popp, Trevor; White, James", "repository": "USAP-DC", "science_program": null, "title": "Mount Moulton Isotopes and Other Ice Core Data", "url": "https://www.usap-dc.org/view/dataset/609640"}], "date_created": "Tue, 01 Aug 2006 00:00:00 GMT", "description": "The summit crater of Mt. Moulton, in West Antarctica, contains a 600-m thick horizontally-exposed section of ice with intercalated tephra layers from nearby Mt Berlin. Argon-40/Argon-39 dating of the thick, near-source tephra indicates that the age of the horizontal ice section ranges between 15,000 and 492,000 years. Thus, the Mt Moulton site offers an unparalleled repository of ancient West Antarctic snow and trapped air that can be used to investigate West Antarctic climate over much of the past 500,000 years. The planar nature and consistent dips of the tephra layers suggests that, although the ice section has thinned, it is otherwise undeformed. The Mt. Moulton site was visited during the 1999/2000 field season, at which time a horizontal ice core representing approximately 400 meters of ice was collected, ranging in age from 15,000 to older than 480,000 years. In addition to this horizontal core, samples of ice at a range of depths were collected in order to test the quality of the climate record in the ice. Forty tephra layers intercalated in the ice were also collected in order to provide chronology for the ice section. The results of this first effort are extremely encouraging. Based on the d?18 O of ice, for example, there is clearly a useable record of past climate at Mt. Moulton extending back beyond 140,000 years. There is work to do, however, to realize the full potential of this horizontal ice core. The elemental and isotopic composition of trapped gases suggest some contamination with modern air, for example. As gas cross-dating of ice cores is the current standard by which climate records are intercompared, we need to understand why and how the gas record is compromised before adding Moulton to our arsenal of ice core paleoclimate records. This award supports a collaborative effort between three institutions with following objectives: 1) to evaluate more thoroughly the integrity of the climatic record through shallow drilling of the blue ice area, as well as the snow field upslope from the blue ice; 2) to improve the radioisotopic dating of specific tephra layers; 3) to obtain baseline information about modern snowfall deposition, mean annual temperature, and wind pumping around the summit of Mt. Moulton; and 4) to study how firn densification differs when surface accumulation changes from net accumulation to net ablation.", "east": 135.1333, "geometry": "POINT(135.1333 -76.05)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ELECTRON MICROPROBES", "is_usap_dc": true, "keywords": "chronology; LABORATORY; Climate; Argon-40; 40Ar; Argon-39; FIELD SURVEYS; Ice Core Gas Age; Ice Core; FIELD INVESTIGATION; Tephra; gas record; Mount Moulton; Not provided; 39Ar; Stratigraphy; Ice Core Depth; caldera ", "locations": "Mount Moulton", "north": -76.05, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "White, James; Popp, Trevor; Dunbar, Nelia; Sowers, Todd A.; Steig, Eric J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -76.05, "title": "Collaborative Research: Refining a 500-kry Climate Record From the Moulton Blue Ice Field in West Antarctica", "uid": "p0000755", "west": 135.1333}, {"awards": "0125761 Thiemens, Mark", "bounds_geometry": null, "dataset_titles": "Atmospheric Nitrate Isotopic Analysis at Amundsen-Scott South Pole Station, A Twenty-Five Year Record", "datasets": [{"dataset_uid": "609281", "doi": "10.7265/N5TT4NWF", "keywords": "Aerosol; Antarctica; Atmosphere; Chemistry:Fluid; Geochemistry; NBP1502; Snow/Ice; South Pole Station", "people": "Thiemens, Mark H.; Savarino, Joel", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric Nitrate Isotopic Analysis at Amundsen-Scott South Pole Station, A Twenty-Five Year Record", "url": "https://www.usap-dc.org/view/dataset/609281"}], "date_created": "Tue, 27 Dec 2005 00:00:00 GMT", "description": "This award supports a detailed laboratory analysis of the mass-independent isotopic composition of processes associated with atmospheric nitrate trapped in the snow pack at the South Pole. The project will specifically test if the oxygen isotopes 16O, 17O, 18O of nitrate can be used to probe the denitrification of the Antarctic stratosphere. Despite decades of research, there are several important issues in Antarctic atmospheric science, which are presently inadequately resolved. This includes quantification over time of the sources of nitrate aerosols. Today, little is known about the past denitrification of the stratosphere in high latitude regions. This lack of knowledge significantly limits our ability to understand the chemical state of ancient atmospheres and therefore evaluate present and past-coupled climate/atmosphere models. The role of nitrogen in environmental degradation is well known. This issue will also be addressed in this proposal. Atmospheric aerosols have now been shown to possess a mass-independent oxygen isotopic content. The proposed research will investigate the stable oxygen isotope ratios of nitrate in Antarctica both collected in real time and from the snow. Two periods of time will be covered. Full year nitrate aerosol collections, with week resolution time horizons, will be performed at the South Pole. Weekly aerosol collections will help us to identify any seasonal trend of the oxygen-17 excess anomaly, and eventually link this anomaly to the denitrification of the Antarctic stratosphere. This data set will also be used to test our assumption that the oxygen isotopic anomaly of nitrate is mainly formed in the stratosphere and is well preserved in the snow pack. If true, we will for the first time resolve an atmospheric signal extracted from a nitrate profile. The snow pit will allow us to see any trend in the data on a multiple decade timescale.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Snow; GROUND STATIONS; Ion Chemistry; South Pole; Not provided; Aerosol; Oxygen Isotope; GROUND-BASED OBSERVATIONS; Snow Pit; Antarctica; Admundsen-Scott Station", "locations": "Antarctica; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Savarino, Joel; Thiemens, Mark H.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "South Pole Atmospheric Nitrate Isotopic Analysis (SPANIA)", "uid": "p0000242", "west": null}, {"awards": "0125981 Sowers, Todd", "bounds_geometry": "POLYGON((-180 -62.83,-144 -62.83,-108 -62.83,-72 -62.83,-36 -62.83,0 -62.83,36 -62.83,72 -62.83,108 -62.83,144 -62.83,180 -62.83,180 -65.547,180 -68.264,180 -70.981,180 -73.698,180 -76.415,180 -79.132,180 -81.849,180 -84.566,180 -87.283,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.283,-180 -84.566,-180 -81.849,-180 -79.132,-180 -76.415,-180 -73.698,-180 -70.981,-180 -68.264,-180 -65.547,-180 -62.83))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 05 May 2005 00:00:00 GMT", "description": "0125981\u003cbr/\u003eSowers\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to construct an isotopic record of atmospheric methane and nitrous oxide over the last century from South Pole firn air. Over the last 150 years, atmospheric methane and nitrous oxide concentrations have risen in response to increased emissions from various anthropogenic activities. As this trend is liable to continue in the foreseeable future, it is important to understand the biogeochemical processes that contribute to the emissions of these two greenhouse gases. In this context, records of the variations in the atmospheric loading of trace gases found in ice cores and interstitial spaces in the snow near the surface of the ice sheet (firn air) provide fundamental boundary conditions for reconstructing historical emission records. One way to improve our understanding of the cycling of bioactive trace gases and their emission records is to use stable isotope tracers, which have been recorded in the ice cores and firn air. This project will develop records of carbon-13 and deuterium isotope ratios of methane, as well as the nitrogen-15, oxygen-18 and the isotopomer composition of nitrous oxide trapped in firn air samples collected in January 2001 at the South Pole. These measurements will allow isotopic records of these atmospheric gases to be reconstructed throughout the 20th century. Such records will help to establish the relative contribution of individual sources with a higher degree of confidence than is currently available.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": -62.83, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Sowers, Todd A.", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -90.0, "title": "Generating an Isotopic Record of Atmospheric Methane and Nitrous Oxide Over the Last Century from South Pole Firn Air", "uid": "p0000086", "west": -180.0}, {"awards": "0088054 Goldstein, Steven", "bounds_geometry": "POLYGON((-180 -39.57,-144 -39.57,-108 -39.57,-72 -39.57,-36 -39.57,0 -39.57,36 -39.57,72 -39.57,108 -39.57,144 -39.57,180 -39.57,180 -42.967,180 -46.364,180 -49.761,180 -53.158,180 -56.555,180 -59.952,180 -63.349,180 -66.746,180 -70.143,180 -73.54,144 -73.54,108 -73.54,72 -73.54,36 -73.54,0 -73.54,-36 -73.54,-72 -73.54,-108 -73.54,-144 -73.54,-180 -73.54,-180 -70.143,-180 -66.746,-180 -63.349,-180 -59.952,-180 -56.555,-180 -53.158,-180 -49.761,-180 -46.364,-180 -42.967,-180 -39.57))", "dataset_titles": null, "datasets": null, "date_created": "Tue, 26 Apr 2005 00:00:00 GMT", "description": "This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a project to investigate the sediment core from the Southern Ocean for paleoenvironmental research. The polar regions are susceptible to the largest changes in climate and are among the least accessible places on Earth. Current concern about the instability of the West Antarctic Ice Sheet has heightened awareness of the vulnerability of polar regions. This proposal seeks to gain a basic understanding of the isotopic characteristics of terrigenous sediment sources derived from Antarctica in the Holocene and Last Glacial Maximum, and their dispersal into the Southern Ocean. Terrigenous clastic sediments are brought to the ocean from continental sources via rivers, ice and wind, and distributed within the ocean by surface and deep currents. At present there are virtually no isotopic data on circumpolar detritus, save a few strontium (Sr) isotopic ratios in the Atlantic sector. This project will fill part of this gap. From the large range in geological ages of crustal provinces of Antarctica, we would predict that there are large isotopic differences in detritus around the continent. The main objectives are to (1) characterize the strontium-neodymium-lead-argon (Sr-Nd-Pb-Ar) isotope compositions of sediment sources derived from Antarctica, (2) to identify the composition and source ages of major ice rafted detritus (IRD) contributions by analyzing individual grains of hornblende and feldspar in conjunction with bulk isotopic analysis, and (3) track sediment dispersal into the Antarctic Circumpolar Current (ACC) during the Holocene and Last Glacial Maximum.\u003cbr/\u003e\u003cbr/\u003eBecause of the paucity of circumpolar data, this research necessarily has a large exploratory component. Consequently, it will provide a basic database for future studies. Nevertheless there are important hypothesis-driven questions that will be addressed in this primary pass. Can lessons learned in North Atlantic IRD studies be applied toward understanding the history of Antarctic ice sheets? Can the large geological variability around the Antarctic margin be treated as a series of natural tracer injections into the ACC, and thus characterize its trajectory, speed, and interaction with other current systems today and in the past? The proposed study is motivated by an exciting set of results from the South Atlantic, showing that detrital Sr isotope ratios are a sensitive current tracer in that region. This research should serve a basic need across many Earth Science disciplines if the use of long-lived radiogenic isotopes (Sr-Nd-Pb-Ar) as tracers of marine sediment sources is successful in elucidating processes related to changing climatic conditions. The results of this study will fill a basic gap in our knowledge of an important region of the Earth. At the same time, it will provide an essential basis for attempting reconstruction of the ACC during the LGM, as well as for future studies of Antarctic geology, ice sheet history, and the Southern Ocean circulation.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": -39.57, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Roy, Martin; Hemming, Sidney R.; Goldstein, Steven L.; Van De Flierdt, Christina-Maria", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -73.54, "title": "Establishing the Pattern of Holocene-LGM Changes in Sediment Contributions from Antarctica to the Southern Ocean", "uid": "p0000724", "west": -180.0}, {"awards": "9714687 Brook, Edward", "bounds_geometry": null, "dataset_titles": "Byrd Ice Core Microparticle and Chemistry Data", "datasets": [{"dataset_uid": "609247", "doi": "", "keywords": "Antarctica; Byrd; Byrd Ice Core; Chemistry:Ice; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate", "people": "Thompson, Lonnie G.; Brook, Edward J.; Blunier, Thomas; Fluckiger, Jacqueline", "repository": "USAP-DC", "science_program": "Byrd Ice Core", "title": "Byrd Ice Core Microparticle and Chemistry Data", "url": "https://www.usap-dc.org/view/dataset/609247"}], "date_created": "Thu, 26 Aug 2004 00:00:00 GMT", "description": "This award is for support for a program to make high resolution studies of variations in the concentration of methane, the oxygenisotope composition of paleoatmospheric oxygen, and the total gas content of deep Antarctic ice cores. Studies of the concentration and isotopic composition of air in the firn of the Antarctic ice sheet will also be continued. One objective of this work is to use the methane concentration and oxygen-isotope composition of oxygen of air in ice as time-stratigraphic markers for the precise intercorrelation of Greenland and Antarctic ice cores as well as the correlation of ice cores to other climatic records. A second objective is to use variations in the concentration and interhemispheric gradient of methane measured in Greenland and Antarctic ice cores to deduce changes in continental climates and biogeochemistry on which the atmospheric methane distribution depends. A third objective is to use data on the variability of total gas content in the Siple Dome ice core to reconstruct aspects of the glacial history of West Antarctica during the last glacial maximum. The fourth objective is to participate in collaborative studies of firn air chemistry at Vostok, Siple Dome, and South Pole which will yield much new information about gas trapping in ice as well as the concentration history and isotopic composition of greenhouse gases, oxygen, trace biogenic gases and trace anthropogenic gases during the last 100 years.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "GROUND STATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Blunier, Thomas; Fluckiger, Jacqueline; Thompson, Lonnie G.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Studies of Trapped Gases in Firn and Ice from Antarctic Deep Ice Cores", "uid": "p0000168", "west": null}, {"awards": "0087380 Alley, Richard", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 01 Jul 2004 00:00:00 GMT", "description": "0087380\u003cbr/\u003eAlley\u003cbr/\u003e\u003cbr/\u003eThis award provides three years of support to use a broad, adaptable, multi-parameter approach, using a range of techniques including artificial neural networks to seek the relations between meteorological conditions and the snow pit and ice core records they produce. Multi-parameter, high resolution, ice core data already in hand or now being collected reflect snow accumulation, atmospheric chemistry, isotopic fractionation, and other processes, often with subannual resolution. The West Antarctic sites from which such data are available will be used as starting points for back-trajectory analyses in reanalysis data products to determine the meteorological conditions feeding the data stream. The artificial neural nets will then be used to look for optimal relations between these meteorological conditions and their products. Previous work has demonstrated the value of reanalysis products in determining snow accumulation, of back trajectory analyses in understanding glaciochemistry, and of artificial neural nets in linking meteorological conditions and their products. Preliminary work shows that neural nets are successful in downscaling from reanalysis products to automatic weather station data in West Antarctica, enabling interpolation of site-specific data to improve understanding of recent changes in West Antarctic climate.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": false, "keywords": "Climate; FF-ANNs; feed-forward artificial neural networks; Not provided", "locations": null, "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Reusch, David", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -90.0, "title": "Relating West Antarctic Ice Cores to Climate with Artificial Neural Networks", "uid": "p0000747", "west": -180.0}, {"awards": "0126286 McConnell, Joseph", "bounds_geometry": "POLYGON((-180 -62.83,-144 -62.83,-108 -62.83,-72 -62.83,-36 -62.83,0 -62.83,36 -62.83,72 -62.83,108 -62.83,144 -62.83,180 -62.83,180 -65.547,180 -68.264,180 -70.981,180 -73.698,180 -76.415,180 -79.132,180 -81.849,180 -84.566,180 -87.283,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.283,-180 -84.566,-180 -81.849,-180 -79.132,-180 -76.415,-180 -73.698,-180 -70.981,-180 -68.264,-180 -65.547,-180 -62.83))", "dataset_titles": "Siple Shallow Core Density Data", "datasets": [{"dataset_uid": "609129", "doi": "10.7265/N52F7KCD", "keywords": "Antarctica; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Physical Properties; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Lamorey, Gregg W.", "repository": "USAP-DC", "science_program": null, "title": "Siple Shallow Core Density Data", "url": "https://www.usap-dc.org/view/dataset/609129"}], "date_created": "Mon, 19 Apr 2004 00:00:00 GMT", "description": "This award provides one year of support to use newly developed technology in which an ice-core melter is coupled with both an Inductively Coupled Plasma - Mass Spectrometer (ICP-MS) and a traditional Continuous Flow Analysis (CFA) system, to measure a continuous time series of chemical and trace element deposition on the Siple Dome ice core from West Antarctica. A coupled ice-core melter, ICP-MS, and CFA system will be used to measure concentrations of a number of elements, isotopes and chemical species at very high depth resolution (~2-cm) in the top 54 m of the Siple Dome A-core. Pilot data from analyses of ~6 m from the nearby but much lower accumulation J-core site at Siple Dome, together with more extensive results from Summit, Greenland, indicate that it will be possible to obtain exactly co-registered, high-quality records of at least 12 seasonally varying elements (sodium, magnesium, aluminum, potassium, calcium, iron, manganese, rubidium, strontium, zirconium, barium, lead) and three other chemical species and ions (ammonium, nitrate, calcium ion) with this system. Under this proposed research, we will also add continuous measurements of sulfate to our system. Because more than sufficient core from Siple Dome for these depths is archived at the National Ice Core Laboratory, the proposed research will require no fieldwork. The continuous, very high-resolution, ~350-y record of these elemental tracers will enhance the value of previous chemical and isotopic measurements that have been made on the Siple Dome core and will be particularly valuable for comparisons between ice-core proxies and modern instrumental data related to El Nino-Southern Oscillation (ENSO) as well as for validation of model simulations of atmospheric circulation. These data, and the expertise gained through this research, will be invaluable when this novel chemical analysis technology is eventually applied to deep ice-core records for the study of rapid climate-change events.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "WAISCORES; shallow core; Siple Coast; Glaciology; Not provided; GROUND-BASED OBSERVATIONS; Ice Core; Siple; Antarctica; Density; Snow; Ice Sheet; Siple Dome; GROUND STATIONS; Stratigraphy", "locations": "Antarctica; Siple Coast; Siple Dome", "north": -62.83, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Lamorey, Gregg W.; McConnell, Joseph", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -90.0, "title": "Continuous High Resolution Ice-Core Chemistry using ICP-MS at Siple Dome", "uid": "p0000159", "west": -180.0}, {"awards": "9977306 Ryan, Jeffrey", "bounds_geometry": "POINT(167.16 -77.5)", "dataset_titles": "B-Be-Li Abundance and Isotope Data: Mt. Erebus-McMurdo Volcanics", "datasets": [{"dataset_uid": "600020", "doi": "", "keywords": null, "people": "Ryan, Jeffrey", "repository": "USAP-DC", "science_program": null, "title": "B-Be-Li Abundance and Isotope Data: Mt. Erebus-McMurdo Volcanics", "url": "https://www.usap-dc.org/view/dataset/600020"}], "date_created": "Thu, 19 Jun 2003 00:00:00 GMT", "description": "Subduction zones are the one place on Earth where materials from the surface (water, sediments and crustal rocks) can be carried into our planet\u0027s deep interior. To quantify this process of subduction-zone recycling, we need to understand both the input of sediments and crust to trenches, and all geochemical outputs related to the subduction process. While the chemical outputs represented by magmatism at volcanic arcs and in back-arc settings have been widely studied, little is known about possible subduction-related outfluxes through the shallow forearc, between the arc and the trench. We are attempting to characterize the \"forearc flux\" by examining serpentinites which are rising diapirically through the forearc mantle and crust in the Mariana arc-trench system. Our work will complete efforts begun (with NSF support) several years ago, and will characterize these samples (and the slab-derived fluids which helped to create them) for radiogenic isotopes, lithium and oxygen isotopes, and the \"fluid-mobile\" elements Cs, Rb, U, As, Pb, and Sb. Our work will allow us to characterize both the chemical inventories of species that are released from subducting slabs beneath forearcs, and the magnitude of this flux, for comparison with results for trench inputs (being collected as part of ODP Leg 125), and existing data for arc volcanic outputs in the Mariana system.", "east": 167.16, "geometry": "POINT(167.16 -77.5)", "instruments": null, "is_usap_dc": false, "keywords": "Mount Erebus; McMurdo Volcanic Group; Not provided; Crary Mountains", "locations": "Mount Erebus", "north": -77.5, "nsf_funding_programs": "Marine Geology and Geophysics", "paleo_time": null, "persons": "Ryan, Jeffrey", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.5, "title": "The Role of the Forearc in Subduction Zone Chemical Cycles: Elemental and Isotopic Signatures of Forearc Serpentinites, ODP Leg 125", "uid": "p0000244", "west": 167.16}, {"awards": "9526979 White, James", "bounds_geometry": null, "dataset_titles": "Siple Dome Core Date from Measurement of the d18O of Paleoatmospheric Oxygen", "datasets": [{"dataset_uid": "609123", "doi": "10.7265/N5TX3C95", "keywords": "Antarctica; Chemistry:Ice; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "White, James; Bender, Michael", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Siple Dome Core Date from Measurement of the d18O of Paleoatmospheric Oxygen", "url": "https://www.usap-dc.org/view/dataset/609123"}], "date_created": "Mon, 16 Jun 2003 00:00:00 GMT", "description": "This award is for support for a program to measure the stable isotope (deuterium to hydrogen and oxygen-18 to oxygen-16) concentrations of ice cores retrieved from Siple Dome as part of the West Antarctic ice sheet program. In addition, the deuterium excess of samples from the Taylor Dome ice core will be determined. This project will approach the question of rapid climate change using ice cores to determine the history of temperature changes, moisture source changes, and elevational changes in the West Antarctic ice sheet. Results from ice cores taken to date in the interior of Antarctica (East and West) are surprisingly lacking in indications of abrupt climate changes, such as those that have been observed in the GISP2 ice core from Summit, Greenland. This work will address the question of whether rapid climate changes, which are known to have occurred in other parts of the southern hemi-sphere, may have also occurred in the coastal regions of West Antarctica. There is some indication from existing records of isotopes in ice cores that the West Antarctic ice sheet may have flushed ice in the past (as evidenced by large changes in elevation of the ice sheet).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Antarctica; LABORATORY; WAISCORES; GROUND STATIONS; Siple Coast; Glaciology; Snow; d18O; Isotope; thermometry; Ice Sheet; Siple; Accumulation; Ice Core; Siple Dome; Stratigraphy; Densification; GROUND-BASED OBSERVATIONS; Not provided", "locations": "Antarctica; Siple Coast; Siple Dome", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "White, James; Bender, Michael", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Isotopic Measurements on the WAIS/Siple Dome Ice Cores", "uid": "p0000063", "west": null}, {"awards": "9615292 Wahlen, Martin", "bounds_geometry": null, "dataset_titles": "Carbon-Isotopic Composition of Atmospheric CO2 since the Last Glacial Maximum; Taylor Dome Ice Core Chemistry, Ion, and Isotope Data", "datasets": [{"dataset_uid": "609108", "doi": "10.7265/N54F1NN5", "keywords": "Antarctica; Atmosphere; Chemistry:Fluid; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Taylor Dome; Taylor Dome Ice Core", "people": "Wahlen, Martin", "repository": "USAP-DC", "science_program": null, "title": "Carbon-Isotopic Composition of Atmospheric CO2 since the Last Glacial Maximum", "url": "https://www.usap-dc.org/view/dataset/609108"}, {"dataset_uid": "609246", "doi": "", "keywords": "Antarctica; Chemistry:Ice; Geochemistry; Glaciers/Ice Sheet; Ice Core Records; Isotope; Paleoclimate; Taylor Dome; Taylor Dome Ice Core", "people": "Sowers, Todd A.; Brook, Edward J.; Steig, Eric J.; Smith, Jesse; Mayewski, Paul A.; Indermuhle, A.", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Taylor Dome Ice Core Chemistry, Ion, and Isotope Data", "url": "https://www.usap-dc.org/view/dataset/609246"}], "date_created": "Tue, 01 Jan 2002 00:00:00 GMT", "description": "This award is for support of a program to reconstruct the record of atmospheric carbon dioxide (and the carbon-13 isotopes of carbon dioxide) over several intervals, including the Last Glacial Maximum-Holocene transition, interstadial episodes, the mid-Holocene, the last 1000 years and the penultimate glacial period, using ice from the Taylor Dome and Vostok ice cores. The major objective of this study is to investigate the phase relationship between variations of the greenhouse gases occluded in the ice cores and temperature changes (indicated by oxygen and deuterium isotopes) during the last deglaciation. In addition, the concentration of atmospheric carbon dioxide over the past 1000 years and during the mid-Holocene will be determined in these cores.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "USAP-DC; Ice Core; GROUND-BASED OBSERVATIONS; Carbon; Trapped Gases; Glaciology; GROUND STATIONS; Taylor Dome; Carbon Dioxide; Isotope; Antarctica; Nitrogen", "locations": "Antarctica; Taylor Dome", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Steig, Eric J.; Wahlen, Martin; Smith, Jesse; Brook, Edward J.; Indermuhle, A.; Mayewski, Paul A.; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": null, "title": "Carbon Dioxide and Carbon Isotopes in the Taylor Dome and Vostok Ice Cores", "uid": "p0000153", "west": null}, {"awards": "9222121 Dalziel, Ian", "bounds_geometry": null, "dataset_titles": "Concentration and Isotopic Composition of O2 and N2 in Trapped Gases of the Vostok Ice Core", "datasets": [{"dataset_uid": "609107", "doi": "10.7265/N5862DCW", "keywords": "Antarctica; Chemistry:Fluid; Geochemistry; Glaciology; Ice Core Records; Lake Vostok; Paleoclimate; UPLC-Q-TOF; Vostok Ice Core", "people": "Bender, Michael", "repository": "USAP-DC", "science_program": null, "title": "Concentration and Isotopic Composition of O2 and N2 in Trapped Gases of the Vostok Ice Core", "url": "https://www.usap-dc.org/view/dataset/609107"}], "date_created": "Tue, 01 Jan 2002 00:00:00 GMT", "description": "This award supports an in situ and short traverse seismic reflection/refraction and magnetotelluric experiment in West Antarctica. This collaborative experiment involves four awards at four institutions. The four-fold purpose is 1) to investigate part of the Byrd Subglacial Basin, 2) to test techniques for this work that could be done in a long traverse, 3) to determine the viability of the magnetotelluric method on a thick (electrically resistive) ice sheet, and 4) to evaluate the relative merits of refraction with wide reflection versus reflection with narrow refraction seismic studies in imaging the lithosphere. The geophysical techniques that will be employed are capable of imaging the ice sheet, the continental lithosphere, and the upper mantle, as well as determining physical properties of parts of the lithosphere and mantle. Investigations of outcrop geology over the last thirty years in West Antarctica and the Transantarctic Mountains have lead to recent interpretations that the crust is made up of many different lithospheric blocks. Seismic reflection work is the only way to image the crust in detail and the refraction work is the only way to determine physical properties of the layers and blocks defined by the reflection work. The magnetotelluric work is scientifically risky because it may not yield useful information when used over the electrically resistive ice sheet; however, if it works it has the potential to image molten rock in the crust and upper mantle. In a continental rift region such as West Antarctica, the presence of melt in the lithosphere is likely and, if documented, has very important ramifications to ice sheet dynamics. Research work supported by this award is expected to provide constraints to models of a range of crustal processes from models of ice sheet dynamics to tectonic and kinematic models of lithospheric thinning and rifting.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Isotope; Vostok; USAP-DC; Antarctica; Trapped Gases; Ice Core; Glaciology; Nitrogen; GROUND STATIONS", "locations": "Antarctica; Vostok", "north": null, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Bender, Michael; Dalziel, Ian W.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Seismic Traverse of the Byrd Subglacial Basin-Field Test", "uid": "p0000150", "west": null}, {"awards": "9725305 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "datasets": [{"dataset_uid": "609098", "doi": "10.7265/N51N7Z2P", "keywords": "Antarctica; Atmosphere; Chemistry:Ice; Geochemistry; Glaciology; Isotope; Paleoclimate; Siple Dome; Snow/Ice; South Pole; Temperature", "people": "Battle, Mark; Severinghaus, Jeffrey P.; Grachev, Alexi", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "url": "https://www.usap-dc.org/view/dataset/609098"}], "date_created": "Mon, 01 Jan 2001 00:00:00 GMT", "description": "9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Isotopic History; GROUND STATIONS; Thermal Diffusion; Firn Temperature Measurements; Not provided; Oxygen Isotope; Trapped Air Bubbles; Shallow Firn Air; Firn Air Isotope Measurements; Seasonal Temperature Gradients; Mass Spectrometry; GROUND-BASED OBSERVATIONS; Thermal Fractionation; Polar Firn Air; Isotopic Anomalies; Xenon; Atmospheric Gases; Argon Isotopes; Siple Dome; Krypton; Nitrogen Isotopes; Seasonal Temperature Changes; Antarctica; Ice Core Gas Records; Firn Air Isotopes; Mass Spectrometer; South Pole; Firn Isotopes; Borehole", "locations": "Antarctica; Siple Dome; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change", "uid": "p0000160", "west": null}]
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This project will develop methods to measure the ratios of carbon-13 to carbon-12, and heavy to light hydrogen in methane in air trapped in ice cores. The ratios of the different forms of carbon and hydrogen are "fingerprints" of different sources of this gas in the past--for example wetlands in the tropics versus methane frozen in the sea floor. Once the analysis method is developed, the measurements will be used to examine why methane changed abruptly in the past, both during the last ice age, and during previous warm periods. The data will be used to understand how methane sources like wildfires, methane hydrates, and wetlands respond to climate change. This information is needed to understand future risks of large changes in methane in the atmosphere as Earth warms. <br/><br/>The project involves two tasks. First, the investigators will build and test a gas extraction system for methane isotopic measurements using continuous flow methods, with the goal of equaling or bettering the precision attained by the few other laboratories that make these measurements. The system will be interfaced with existing mass spectrometers at Oregon State University. The system consists of a vacuum chamber and sequence of traps, purification columns, and furnaces that separate methane from other gases and convert it to carbon dioxide or hydrogen for mass spectrometry. Second, the team will measure the isotopic composition of methane across large changes in concentration associated with two past interglacial periods and during abrupt methane changes of the last ice age. These measurements will be used to understand if the main reason for these concentration changes is climate-driven changes in emissions from wetlands, or whether other sources are involved, for example methane hydrates or wildfires.<br/><br/>This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
The Southern Ocean plays a key role in modulating the global carbon cycle, but the size and even the sign of the flux of carbon dioxide between the ocean and atmosphere in this region is still uncertain. This is in part due to the lack of measurements in this remote region of the world ocean. This project continues a multi-year time series of shipboard chemical measurements in the Drake Passage to detect changes in the ocean carbon cycle and to improve the understanding of mechanisms driving natural variability and long-term change in the Southern Ocean. More specifically, this project is a continuation of the collection of underway upper ocean measurements of the surface partial pressure of carbon dioxide during crossings of the Drake Passage by the Antarctic Research and Supply Vessel Laurence M. Gould. This project also includes collection and analysis of discrete samples relevant to ocean carbon cycle studies including macronutrient concentrations, total carbon dioxide concentrations, and the carbon isotopic composition of total carbon dioxide. The Drake Passage data are made readily available to the international science community and serve as both validation and constraints of remotely sensed observations and numerical coupled earth systems models.
The Earth's atmosphere is a highly oxidizing medium. The abundance of oxidants such as ozone in the atmosphere strongly influences the concentrations of pollutants and greenhouse gases, with implications for human health and welfare. Because oxidants are not preserved in geological archives, knowledge of how oxidants have varied in the past under changing climate conditions is extremely limited. This award will measure a proxy for oxidant concentrations in a West Antarctic ice core over several major climate transitions over the past 50,000 years. These measurements will complement similar measurements from a Greenland ice core, which showed significant changes in atmospheric oxidants over major climate transitions covering this same time period. The addition of measurements from Antarctica will allow researchers to examine if the oxidant changes suggested by the Greenland ice core record are regional or global in scale. Knowledge of how oxidants vary naturally with climate will better inform predictions of the composition of the future atmosphere under a warming climate.<br/><br/>This award will support measurements of the isotopic composition of nitrate in a West Antarctic ice core as a proxy for oxidant concentrations in the past atmosphere. The nitrogen isotopes of nitrate provide information on the degree of preservation of nitrate in the ice core record, and thus aid in the interpretation of the observed variability in the observed nitrate concentrations and oxygen isotopes in ice core records. By providing information about the spatial scale of oxidant changes over abrupt climate change events during the last glacial period, this project may also improve our understanding of mechanisms driving these abrupt events. Insight from this project will prove valuable for forecasting the response of stratospheric circulation to climate change, which has large implications for climate feedbacks and tropospheric composition. In addition, the information gleaned from this project on the mechanisms and feedbacks during abrupt climate change events will help determine the likelihood of such rapid events occurring in the future, which would have dramatic impacts on humankind. This award will provide training for one graduate and one undergraduate student, and will support the development of a hands-on activity related to rapid climate change to be used at the annual Polar Science Weekend at the Pacific Science Center in Seattle, WA.
Stable isotope analyses of carbon and nitrogen (δ13C and δ15N) are commonly used to investigate animal migration, foraging locations and diet, especially in marine species that can travel over great distances. One other stable isotope, sulfur (δ34S), is not as commonly used but is increasingly being applied to refine and corroborate data obtained from carbon and nitrogen analyses. Collagen is one of the best tissues for these analyses as it is abundant in bone, preserves well, and can be easily extracted for analysis. In the Ross Sea region, the cold, dry environment has been conductive for the preservation of Adélie penguin (Pygoscelis adeliae) bones, feathers, eggshell and even mummified remains, at active and abandoned colonies that date from before the Last Glacial Maximum (>45,000 yrs ago) through the Holocene. Most of these colonies are associated with one of three polynyas, or highly productive areas of open water surrounded by sea ice in the Ross Sea. Thus, this species is an excellent bioindicator for marine conditions, past and present, and its colonies have appeared and disappeared throughout this region with changing climate and sea ice regimes for millennia. Current warming trends are inducing relatively rapid ecological responses by this species and some of the largest colonies in the Ross Sea are likely to be abandoned in the next 50 years from rising sea level. The recently established Ross Sea Marine Protected Area aims to protect Adélie penguins and other species in this region from human impacts and knowledge on how this species responds to climate change, past and present, will support this goal.
We propose to investigate ecological responses in diet and foraging behavior of the Adélie penguin to known climatic events that occurred in the middle to late Holocene, specifically, before, during and after a warming period known as the penguin ‘optimum’ at 2000 - 4000 cal yr before present (BP). We will apply for the first time a suite of three stable isotope analyses (δ13C, δ15N, δ34S) on chick bones and feathers, as well as prey remains, from active and abandoned colonies in the Ross Sea. We will use existing tissue samples (~60-80 bones) collected by PI Emslie with NSF support since 2001 and supplement these with newly collected samples of bones and feathers in this project. We will conduct compound-specific isotope analyses of carbon on essential amino acids from collagen from a selected sample of 30-40 bones that span the past 5000 yrs to provide corroboratory information. We will apply three-dimensional Bayesian niche models and/or community metrics using R scripts in these analyses to identify isotopic ‘signatures’ of existing and past foraging grounds and polynyas used by Adélie penguins in the southern, central, and northern Ross Sea. This four-year study will the first of its kind to apply multiple stable isotope analyses to investigate a living species of seabird over millennia in a region where it still exists today.
Broader Impacts:
The PIs are committed to public engagement and enhancement of K-12 education in the STEM sciences. Broader impacts of this research will include support and training for one Ph.D., two M.S., and eight undergraduate students in the Department of Biology and Marine Biology, and two M.A. students in the Watson School of Education at the University of North Carolina Wilmington (UNCW). The last two students will continue to expand on a detailed polar curriculum that was initiated in previous NSF grants for 2nd and 4th grade students, and most recently for 9-12th grade students now available on PI Emslie’s website (www.uncw.edu/penguins). Additional curricula for K-12 students will be designed and tested in this project, which will include visitation to local K-12 schools. As in previous awards, we will focus on schools that serve historically under-represented groups in the sciences. We will work with the UNCW Center for Education in STEM Sciences to assess the efficacy of this new curricula. All curricula will be uploaded on the Educational Resource Commons website. Field work will include blogs and active question-answer sessions with students at these schools. We will continue to post project information and updates on PI Emslie’s website and YouTube channel. Our partnership with tour ship companies will provide a platform for onboard lectures on the importance of scientific research as well as citizen science opportunities for another sector of the public. This proposal requires fieldwork in the Antarctic.
Estimating Antarctic ice sheet growth or loss is important to predicting future sea level rise. Such estimates rely on field measurements or remotely sensed based observations of the ice sheet surface, ice margins, and or ice shelves. This work examines the introduction of freshwater into the ocean to surrounding Antarctica to track meltwater from continental ice. Polar ice is depleted in two stable isotopes, 18O and D, deuterium, relative to Southern Ocean seawater and precipitation. Measurements of seawater isotopic composition in conjunction with precise observations of seawater temperature and salinity, will permit discrimination of freshwater derived from melting glacial ice from that derived from regional precipitation or sea ice melt.<br/><br/>This research describes an accepted method for determining rates and locations of meltwater entering the oceans from polar ice sheets. As isotopic and salinity perturbations are cumulative in many Antarctic coastal seas, the method allows for the detection of any marked acceleration in meltwater introduction in specific regions, using samples collected and analyzed over a period of years to decades. Impact of the project derives from use of an independent method capable of constraining knowledge about current ice sheet melt rates, their stability and potential impact on sea level rise. The project allows for sample collection taken from foreign vessels of opportunity sailing in Antarctic waters, and subsequent sharing and interpretation of data. Research partners include the U.S., Korea, China, New Zealand, the United Kingdom, and Germany. Participating collaborators will collect seawater samples for isotopic and salinity analysis at Stanford University. USAP cruises will concentrate on sampling the Ross Sea, and the West Antarctic. The work plan includes interpretation of isotopic data using box model and mixing curve analyses as well as using isotope enabled ROMS (Regional Ocean Modeling System) models. The broader impacts of the research will include development of an educational module that illustrates the scientific method and how ocean observations help society understand how Earth is changing.
The goal of the international GEOTRACES program is to understand the distributions of trace chemical elements and their isotopes (TEIs) in the oceans. Many trace metals such as iron are essential for life and thus considered nutrients for phytoplankton growth, with trace metal cycling being especially important for influencing carbon cycling in the iron-limited Southern Ocean, where episodic supply of iron from a range of different external sources is important. The primary goal of this project is to measure the dissolved concentrations, size partitioning, and dissolved isotope signature of Fe on a transect of water-column stations throughout the Amundsen Sea and surrounding region of the Antarctic Margin, as part of the GP17-ANT Expedition. The secondary goal of this project is to analyze the concentrations and size partitioning of the trace metals manganese, zinc, copper, cadmium, nickel, and lead in all water-column samples, measure the isotope ratios of zinc, cadmium, nickel, and copper in a subset of water column samples, and measure the Fe isotopic signature of aerosols, porewaters, and particles. Observations from this project will be incorporated into regional and global biogeochemistry models to assess TEI cycling within the Amundsen Sea and implications for the wider Southern Ocean. This project spans three institutions, four graduate students, undergraduate students, and will provide ultrafiltered samples and data to other PIs as service.
The US GEOTRACES GP17 ANT expedition, planned for austral summer 2023/2024 aims to determine the distribution and cycling of trace elements and their isotopes in the Amundsen Sea Sector (100-135°W) of the Antarctic Margin. The cruise will follow the Amundsen Sea ‘conveyor belt’ by sampling waters coming from the Antarctic Circumpolar Current onto the continental shelf, including near the Dotson and Pine Island ice shelves, the productive Amundsen Sea Polynya (ASP), and outflowing waters. Episodic addition of dissolved Fe and other TEIs from dust, ice-shelves, melting ice, and sediments drive seasonal primary productivity and carbon export over the Antarctic shelf and offshore into Southern Ocean. Seasonal coastal polynyas such as the highly productive ASP thus act as key levers on global carbon cycling. However, field observations of TEIs in such regions remain scarce, and biogeochemical cycling processes are poorly captured in models of ocean biogeochemistry. The investigators will use their combined analytical toolbox, in collaboration with the diagnostic chemical tracers and regional models of other funded groups to address four main objectives: 1) What is the relative importance of different sources in supplying Fe and other TEIs to the ASP? 2) What is the physiochemical speciation of this Fe, and its potential for transport? 3) How do biological uptake, scavenging and regeneration in the ASP influence TEI distributions, stoichiometry, and nutrient limitation? 4) What is the flux and signature of TEIs transported offshore to the ACC and Southern Ocean?
Hydroxyl radicals are responsible for removal of most atmospheric trace gases, including pollutants and important greenhouse gases. They have been called the "detergent of the atmosphere". Changes in hydroxyl radical concentration in response to large changes in reactive trace gas emissions, which may happen in the future, are uncertain. This project aims to provide the first estimates of the variability of atmospheric hydroxyl radicals since about 1880 AD when anthropogenic emissions of reactive trace gases were minimal. This will improve understanding of their stability in response to large changes in emissions. The project will also investigate whether ice cores record past changes in Southern Hemisphere westerly winds. These winds are a key component of the global climate system, and have an important influence on ocean circulation and possibly on atmospheric carbon dioxide concentrations. The project team will include three early career scientists, a postdoctoral researcher, and graduate and undergraduate students, working in collaboration with senior scientists and Australian collaborators. <br/> <br/>Firn air and shallow ice to a depth of about 233 m will be sampled at the Law Dome high-accumulation coastal site in East Antarctica. Trapped air will be extracted from the ice cores on site immediately after drilling. Carbon-14 of carbon monoxide (14CO) will be analyzed in firn and ice-core air samples. Corrections will be made for the in situ cosmogenic 14CO component in the ice, allowing for the atmospheric 14CO history to be reconstructed. This 14CO history will be interpreted with the aid of a chemistry-transport model to place the first observational constraints on the variability of Southern Hemisphere hydroxyl radical concentration after about 1880 AD. An additional component of the project will analyze Krypton-86 in the firn-air and ice-core samples. These measurements will explore whether ice-core Krypton-86 acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere westerly winds.<br/><br/>This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
The spatial extent of the West Antarctic Ice Sheet during the last interglacial period (129,000 to 116,000 years ago) is currently unknown, yet this information is fundamental to projections of the future stability of the ice sheet in a warming climate. Paleoclimate records and proxy evidence such as dust can inform on past environmental conditions and ice-sheet coverage. This project will combine new, high-sensitivity geochemical measurements of dust from Antarctic ice collected at Allan Hills with existing water isotope records to document climate and environmental changes through the last interglacial period. These changes will then be compared with Earth-system model simulations of dust and water isotopes to determine past conditions and constrain the sensitivity of the West Antarctic Ice Sheet to warming. The project will test the hypothesis that the uncharacteristically volcanic dust composition observed at another peripheral ice core site at Taylor Glacier during the last interglacial period is related to changes in the spatial extent of the West Antarctic Ice Sheet.
This project aims to characterize mineral dust transport during the penultimate glacial-interglacial transition. The team will apply high-precision geochemical techniques to the high-volume, high-resolution ice core drilled at the Allan Hills site in combination with Earth system model simulations to: (1) determine if the volcanic dust signature found in interglacial ice from Taylor Glacier is also found at Allan Hills, (2) determine the likely dust source(s) to this site during the last interglacial, and (3) probe the atmospheric and environmental changes during the last interglacial with a diminished West Antarctic Ice Sheet. The team will develop a suite of measurements on previously drilled ice from Allan Hills, including isotopic compositions of Strontium and Neodymium, trace element concentrations, dust-size distribution, and imaging of ice-core dust to confirm the original signal observed and provide a broader spatial reconstruction of dust transport. In tandem, the team will conduct Earth system modeling with prognostic dust and water-isotope capability to test the sensitivity of dust transport under several plausible ice-sheet and freshwater-flux configurations. By comparing dust reconstruction and model simulations, the team aims to elucidate the driving mechanisms behind dust transport during the last interglacial period.
Isotopic and sedimentary datasets reveal that volcanic activity typically increases during interglacial periods. However, the physical mechanisms through which changes in the surface loading affect volcanic magmatic plumbing systems remain unconstrained. Recently generated 40Ar/39Ar eruption ages indicate that 86% of the dated samples from Mt. Waesche, a late Quaternary volcano in Marie Byrd land, correlate with interglacial periods, suggesting this volcano uniquely responds to changes in the West Antarctic Ice Sheet. We propose to combine the petrology of Mount Waesche’s volcanic record, constraints on changing ice loads through time, and geodynamic modelling to: (1) Determine how pre-eruptive storage conditions change during glacial and interglacial periods using whole rock and mineral compositions of volcanic rocks; (2) Conduct geodynamic modeling to elucidate the relationship between lithospheric structure, temporal variations in ice sheet thickness, and subsequent changes in crustal stresses and magmatic transport and, therefore, the mechanism(s) by which deglaciation impacts magmatic plumbing systems; (3) Use the outcomes of objectives (1) and (2) to provide new constraints on the changes in ice sheet thickness through time that could plausibly trigger future volcanic and magmatic activity in West Antarctica. This collaborative approach will provide a novel methodology to determine prior magnitudes and rates of ice load changes within the Marie Byrd Land region of Antarctica. Lastly, estimates of WAIS elevation changes from this study will be compared to ongoing studies at Mount Waesche focused on constraining last interglacial ice sheet draw down using cosmogenic exposure ages obtained from shallow drilling. The scope of work also includes a partnership with Mentoring Kids Works to develop several Polar and Earth Science Educational Modules aimed at improving reading skills in third grade students in New Mexico. The proposed Polar and Earth Science program consists of modules that include readings of books introducing students to Earth and Polar science themes, paired with Earth and Polar Science activities, followed by simple experiments, where students make predictions and collect data. Information required to implement our Polar and Earth Science curriculum will be made available online.
The primary scientific goal of the proposed project is to test whether Taylor Valley, Antarctica has experienced glacial incision in the last ~1 million years in spite of cold climate conditions. One of the Dry Valleys of the Transantarctic Mountains, Taylor Valley exhibits over 2000 m of relief from sub sea-level troughs to high polar peaks. The Dry Valleys are characterized by low mean annual temperatures, paucity of precipitation and erosion that has allowed fragile glacial landforms, now subaerially exposed at high elevations, to be preserved for as long as 15 Ma. Two end member models can explain the timing of glacial incision and the observation that Quaternary advances of Taylor Glacier have left deposits at lower valley elevations with each advance. In the first scenario, all Valley relief is generated prior to 15 Ma when non-polar climates enabled warm-based glaciers to incise and widen fluvial channels more so than peaks. In this case, Quaternary drift deposits record advances of cold-based glaciers of decreasing ice volume. Limited glacial erosion and silt generation results in drift deposits composed primarily of recycled sediments. In the second scenario, selective erosion of the valley floor continues to deepen Taylor Valley over the last 2 Ma while high elevation peaks remain uneroded in polar conditions. The ‘bathtub rings’ of Quaternary drifts reaching a progressively lower elevation through time could be due to the lowering of the valley floor by subglacial erosion and with it, production of silt which is now incorporated into these drifts. While either scenario would result in the present day topography, they differ in the implied evolution of regional glacial ice volume over time and the timing of both valley relief production and generation of fine-grained particles. Here we propose to distinguish between these two models, by placing time constrains on fine particle production using U-series comminution dating. This new geochronologic tool exploits the loss of 234U due to alpha-recoil. The deficiency in 234U only becomes detectable in particles with a sufficiently high surface-area-to-volume ratio which can incur appreciable 234U loss (<50 m). The timing of comminution and particle size controls the magnitude of 234U loss, up to 10% in silt-sized particles comminuted over 1.5 million years ago. And while this geochronologic tool is in its infancy, the scientific goal of this proposal can be achieved by resolving between ancient and recently comminuted fine particles, a binary question that our preliminary modeling and measured data show is readily resolved.
The chemical composition of diatom fossils in the Southern Ocean provides information about the environmental history of Antarctica, including sea ice extent, biological production, and ocean nutrient distribution. The sea ice zone is an important habitat for a group of diatoms, largely from the genus Chaetoceros, that have a unique life cycle stage under environmental stress, when they produce a structure called a resting spore. Resting spores are meant to reseed the surface ocean when conditions are more favorable. The production of these heavy resting spores tends to remove significant amounts of carbon and silicon, essential nutrients, out of the surface ocean. As a result, this group has the potential to remove carbon from the surface ocean and can impact the sedimentary record scientists use to reconstruct environmental change.
This project explores the role of resting spores and nutrients in the sedimentary record using the nitrogen isotopic signature of these fossils and how those measurements are used to estimate carbon cycle changes. Measurements of nitrogen stable isotopes of nitrate, biomass, and diatom-bound nitrogen and silicon-to-nitrogen ratios of individual species grown in the laboratory are used to quantify how resting spores record nutrient drawdown in the water column and to what degree their signature is biased toward low nutrient conditions. Laboratory incubations were conducted with surface sediment containing Chaetoceros spp.. The emergence of vegetative cells and subsequent formation of resting spores is manipulated with the addition of nutrients, primarily nitrate. The resulting samples, both of vegetative cells and resting spores were measured for diatom-bound d15N. Resting spore d15N values are consistently lower than the vegetative d15N
from the same incubations. The incubation results will be used to quantify nutrient drawdown in sea ice environments during two contrasting intervals in earth history, the last ice age and the warm Pliocene. The project provided training and research opportunities for undergraduate and graduate students. Research efforts in Antarctic earth sciences are disseminated through an interactive display at the home institution and during university sponsored events.
This work addresses uncertainties in how Chaetoceros resting spores record surface nutrient conditions in their nitrogen stable isotopic composition, the relative impact of their specific signal with respect to the full sedimentary assemblage, and their potential to bias or enhance environmental reconstructions in the sea ice zone.
Efforts to improve sea level forecasting on a warming planet have focused on determining the temperature, sea level and extent of polar ice sheets during Earth’s past warm periods. Large uncertainties, however, in reconstructions of past and future sea levels, result from the poorly constrained climate sensitivity of the Antarctic Ice sheet (AIS). This research project aims to develop the use of subglacial precipitates as an archive the Antarctic ice sheet (AIS) past response to climate change. The subglacial precipitates from East Antarctica form in water bodies beneath Antarctic ice and in doing so provide an entirely new and unique measure of how the AIS responds to climate change. In preliminary examination of these precipitates, we identified multiple samples consisting of cyclic opal and calcite that spans hundreds of thousands of years in duration. Our preliminary geochemical characterization of these samples indicates that the observed mineralogic changes result from a cyclic change in subglacial water compositions between isotopically and chemically distinct waters. Opal-forming waters are reduced (Ce* <1 and high Fe/Mn) and exhibit elevated 234U/238U compositions similar to the saline groundwater brines found at the periphery of the AIS. Calcite-forming waters, are rather, oxidized and exhibit δ18O compositions consistent with derivation from the depleted polar plateau (< -50 ‰). 234U-230Th dates permit construction of a robust timeseries describing these mineralogic and compositional changes through time. Comparisons of these time series with other Antarctic climate records (e.g., ice core records) reveal that calcite forming events align with millennial scale changes in local temperature or “Antarctic isotopic maximums”, which represent Southern Hemisphere warm periods during low Atlantic Meridional overturning circulation. Ultimately, this project seeks to develop a comprehensive model as to how changes in the thermohaline cycle induce a glaciologic response which in turn induces a change in the composition of subglacial waters and the mineralogic phase recorded within the precipitate archive.
Abstract for the general public:<br/><br/>The margins of the Antarctic ice sheet have advanced and retreated repeatedly over the past few million years. Melting ice from the last retreat, from 19,000 to 9,000 years ago, raised sea levels by 8 meters or more, but the extents of previous retreats are less well known. The main goal of this project is to understand how Antarctic ice retreats: fast or slow, stepped or steady, and which parts of the ice sheet are most prone to retreat. Antarctica loses ice by two main processes: melting of the underside of floating ice shelves and calving of icebergs. Icebergs themselves are ephemeral, but they carry mineral grains and rock fragments that have been scoured from Antarctic bedrock. As the icebergs drift and melt, this 'iceberg-rafted debris' falls to the sea-bed and is steadily buried in marine sediments to form a record of iceberg activity and ice sheet retreat. The investigators will read this record of iceberg-rafted debris to find when and where Antarctic ice destabilized in the past. This information can help to predict how Antarctic ice will behave in a warming climate. <br/><br/>The study area is the Weddell Sea embayment, in the Atlantic sector of Antarctica. Principal sources of icebergs are the nearby Antarctic Peninsula and Weddell Sea embayment, where ice streams drain about a quarter of Antarctic ice. The provenance of the iceberg-rafted debris (IRD), and the icebergs that carried it, will be found by matching the geochemical fingerprint (such as characteristic argon isotope ages) of individual mineral grains in the IRD to that of the corresponding source area. In more detail, the project will: <br/><br/>1. Define the geochemical fingerprints of the source areas of the glacially-eroded material using samples from each major ice stream entering the Weddell Sea. Existing data indicates that the hinterland of the Weddell embayment is made up of geochemically distinguishable source areas, making it possible to apply geochemical provenance techniques to determine the origin of Antarctica icebergs. Few samples of onshore tills are available from this area, so this project includes fieldwork to collect till samples to characterize detritus supplied by the Recovery and Foundation ice streams. <br/><br/>2. Document the stratigraphic changes in provenance of iceberg-rafted debris (IRD) and glacially-eroded material in two deep water sediment cores in the NW Weddell Sea. Icebergs calved from ice streams in the embayment are carried by the Weddell Gyre and deposit IRD as they pass over the core sites. The provenance information identifies which groups of ice streams were actively eroding and exporting detritus to the ocean (via iceberg rafting and bottom currents), and the stratigraphy of the cores shows the relative sequence of ice stream activity through time. A further dimension is added by determining the time lag between fine sediment erosion and deposition, using a new method of uranium-series isotope measurements in fine grained material. <br/><br/>Technical abstract:<br/><br/> The behavior of the Antarctic ice sheets and ice streams is a critical topic for climate change and future sea level rise. The goal of this proposal is to constrain ice sheet response to changing climate in the Weddell Sea during the three most recent glacial terminations, as analogues for potential future warming. The project will also examine possible contributions to Meltwater Pulse 1A, and test the relative stability of the ice streams draining East and West Antarctica. Much of the West Antarctic ice may have melted during the Eemian (130 to 114 Ka), so it may be an analogue for predicting future ice drawdown over the coming centuries. <br/><br/>Geochemical provenance fingerprinting of glacially eroded detritus provides a novel way to reconstruct the location and relative timing of glacial retreat during these terminations in the Weddell Sea embayment. The two major objectives of the project are to: <br/><br/>1. Define the provenance source areas by characterizing Ar, U-Pb, and Nd isotopic signatures, and heavy mineral and Fe-Ti oxide compositions of detrital minerals from each major ice stream entering the Weddell Sea, using onshore tills and existing sediment cores from the Ronne and Filchner Ice Shelves. Pilot data demonstrate that detritus originating from the east and west sides of the Weddell Sea embayment can be clearly distinguished, and published data indicates that the hinterland of the embayment is made up of geochemically distinguishable source areas. Few samples of onshore tills are available from this area, so this project includes fieldwork to collect till to characterize detritus supplied by the Recovery and Foundation ice streams. <br/><br/>2. Document the stratigraphic changes in provenance of iceberg-rafted debris (IRD) and glacially-eroded material in two deep water sediment cores in the NW Weddell Sea. Icebergs calved from ice streams in the embayment are carried by the Weddell Gyre and deposit IRD as they pass over the core sites. The provenance information will identify which ice streams were actively eroding and exporting detritus to the ocean (via iceberg rafting and bottom currents). The stratigraphy of the cores will show the relative sequence of ice stream activity through time. A further time dimension is added by determining the time lag between fine sediment erosion and deposition, using U-series comminution ages.
The Antarctic subglacial environment remains one of the least explored regions on Earth. This project will examine the physical and biological characteristics of Subglacial Lake Mercer, a lake that lies 1200m beneath the West Antarctic Ice Sheet. This study will address key questions relating to the stability of the ice sheet, the subglacial hydrological system, and the deep-cold subglacial biosphere. The education and outreach component aims to widely disseminate results to the scientific community and to the general public through short films, a blog, and a website.<br/><br/>Subglacial Lake Mercer is one of the larger hydrologically active lakes in the southern basin of the Whillans Ice Plain, West Antarctica. It receives about 25 percent of its water from East Antarctica with the remainder originating from West Antarctica, is influenced by drain/fill cycles in a lake immediately upstream (Subglacial Lake Conway), and lies about 100 km upstream of the present grounding line of the Ross Ice Shelf. This site will yield information on the history of the Whillans and Mercer Ice Streams, and on grounding line migration. The integrated study will include direct sampling of basal ice, water, and sediment from the lake in concert with surface geophysical surveys over a three-year period to define the hydrological connectivity among lakes on the Whillans Ice Plain and their flow paths to the sea. The geophysical surveys will furnish information on subglacial hydrology, aid the site selection for hot-water drilling, and provide spatial context for interpreting findings. The hot-water-drilled boreholes will be used to collect basal ice samples, provide access for direct measurement of subglacial physical, chemical, and biological conditions in the water column and sediments, and to explore the subglacial water cavities using a remotely operated vehicle equipped with sensors, cameras, and sampling equipment. Data collected from this study will address the overarching hypothesis \"Contemporary biodiversity and carbon cycling in hydrologically-active subglacial environments associated with the Mercer and Whillans ice streams are regulated by the mineralization and cycling of relict marine organic matter and through interactions among ice, rock, water, and sediments\". The project will be undertaken by a collaborative team of scientists, with expertise in microbiology, biogeochemistry, hydrology, geophysics, glaciology, marine geology, paleoceanography, and science communication.
The investigators plan to reconstruct historical variations in the sources of atmospheric carbon monoxide (CO) from measurements of the concentration and stable isotopic abundance of carbon monoxide ([CO], 13CO and C18O) in the South Pole Ice Core, which is being drilled in 2014-2016. The goal is to strategically sample and reconstruct the relative variations in CO source strengths over the past 20,000 years. These will be the first measurements to extend the CO record beyond 650 years before present, back to the last glacial maximum. Both atmospheric chemical processes and variations in CO sources can impact the CO budget, and variations in the CO budget are useful in identifying and quantifying chemistry-climate interactions.
This award supports a project to measure the carbon dioxide (CO2) concentration in the WAIS Divide ice core covering the time period 25,000 to 60,000 years before present, and to analyze the isotopic composition of CO2 in selected time intervals. The research will improve understanding of how and why atmospheric CO2 varied during the last ice age, focusing particularly on abrupt transitions in the concentration record that are associated with abrupt climate change. These events represents large perturbations to the global climate system and better information about the CO2 response should inform our understanding of carbon cycle-climate feedbacks and radiative forcing of climate. The research will also improve analytical methods in support of these goals, including completing development of sublimation methods to replace laborious mechanical crushing of ice to release air for analysis. The intellectual merit of the proposed work is that it will increase knowledge about the magnitude and timing of atmospheric CO2 variations during the last ice age, and their relationship to regional climate in Antarctica, global climate history, and the history of abrupt climate change in the Northern Hemisphere. The temporal resolution of the proposed record will in most intervals be ~ 4 x higher than previous data sets for this time period, and for selected intervals up to 8-10 times higher. Broader impacts of the proposed work include a significant addition to the amount of data documenting the history of the most important long-lived greenhouse gas in the atmosphere and more information about carbon cycle-climate feedbacks - important parameters for predicting future climate change. The project will contribute to training a postdoctoral researcher, research experience for an undergraduate and a high school student, and outreach to local middle school and other students. It will also improve the analytical infrastructure at OSU, which will be available for future projects.
The rise in atmospheric carbon dioxide concentrations and associated climate changes make understanding the role of the ocean in large scale carbon cycle a priority. Geologic samples allow exploration of potential mechanisms for carbon dioxide drawdown during glacial periods through the use of geochemical proxies. Nitrogen and silicon isotope signatures from fossil diatoms (microscopic plants) are used to investigate changes in the physical supply and biological demand for nutrients (like nitrogen and silicon and carbon) in the Southern Ocean. The project will evaluate the use the nitrogen and silicon isotope proxies through a series of laboratory experiments and Southern Ocean field sampling. The results will provide quantification of real relationships between nitrogen and silicon isotopes and nutrient usage in the Southern Ocean and allow exploration of the role of other factors, including biological diversity, ice cover, and mixing, in altering the chemical signatures recorded by diatoms. Seafloor sediment samples will be used to evaluate how well the signal created in the water column is recorded by fossil diatoms buried in the seafloor. Improving the nutrient isotope proxies will allow for a more quantitative understanding of the role of polar biology in regulating natural variation in atmospheric carbon dioxide. The project will also result in the training of a graduate student and development of outreach materials targeting a broad popular audience.
This project seeks to test the fidelity of the diatom nitrogen and silicon isotope proxies, two commonly used paleoceanographic tools for investigating the role of the Southern Ocean biological pump in regulating atmospheric CO2 concentrations on glacial-interglacial timescales. Existing ground-truthing data, including culture experiments, surface sediment data and downcore reconstructions, all suggest that nutrient utilization is the primary driver of isotopic variation in the Southern Ocean. However, strong contribution of interspecific variation is implied by recent culture results. Moreover, field and laboratory studies present some contradictory results in terms of the relative importance of interspecific variation and of inferred post-depositional alteration of the nutrient isotope signals. Here, a first order test of the N and Si diatom nutrient isotope paleo-proxies, involving water column dissolved and particulate sampling and laboratory culturing of field-isolates, is proposed. Southern Ocean water, biomass, live diatoms and fossil diatom sampling will be conducted to investigate species and assemblage related variability in diatom nitrogen and silicon isotopes and their relationship to surface nutrient fields and early diagenesis. Access to fresh materials produced in an analogous environmental context to the sediments of primary interest is critical for making robust paleoceanographic reconstructions. Field sampling will occur along 175°W, transecting the Antarctic Circumpolar Current from the subtropics to the marginal ice edge. Collection of water, sinking/suspended particles and multi-core samples from 13 stations and 3 shipboard incubation experiments will be used to test four proposed hypotheses that together evaluate the significance of existing culture results and seek to allow the best use of diatom nutrient isotope proxies in evaluating the biological pump.
Subduction takes place at convergent plate boundaries and involves sinking of one tectonic plate underneath another. Although this process is a key aspect of plate tectonics that shapes the planet over geologic time, and is a primary cause of earthquakes, it is not known what causes subduction to cease, and what effect it has on the deepest portions of the crust and the upper part of the mantle. By studying the age and composition of igneous rocks emplaced at the very end of the subduction cycle, this project seeks to understand what causes subduction to cease, and how this changes the composition and structure of the crust and upper mantle. Because this process occurs deep within the earth, the project will focus on rocks in the root of an ancient subduction zone, now exposed in the Transantarctic Mountains of Antarctica. In addition, Antarctica remains relatively poorly understood, and this project will contribute directly to increasing our understanding of the geologic history of this region. The project will focus on training graduate and undergraduate students - incorporating hands-on experience with an array of state-of-the-art analytical instrumentation. Students will also gain a range of more general skills including Geographic Information Systems (GIS), written and oral communication, and data management - strengths that are highly relevant to careers both in the academic and Geosciences industry. Each summer, high school students will be incorporated into aspects of the laboratory-based research through the UCSB research mentorship program. The PI and graduate students will engage the general public through a purpose-built iPhone App and multimedia website. Activities will include live phone and video conversations from the field between elementary school students and members of the team in Antarctica. <br/><br/>The mechanisms by which the deep crustal delaminates or "founders" and is returned to the mantle remains a fundamental problem in earth science. Specifically, little is known about the temporal and spatial scales over which this process occurs or the mechanisms that trigger such catastrophic events. Igneous rocks highly enriched in potassium, called lamprophyres, are often emplaced during, and immediately after, termination of subduction and therefore potentially provide direct insight into foundering. These enigmatic rocks are important because they represent near-primary mantle melt compositions and therefore their age, geochemistry and petrologic evolution reveal key information on both the composition of the upper mantle and its thermal state. Of equal importance, they reveal how these key parameters vary through both space and time. By evaluating lamprophyres along a subduction zone margin it is possible to extract: 1) local-scale information, such as the timing and duration of melting and the role of igneous crystallization processes in generation of isotopic heterogeneities; 2) along-strike variations in mantle source composition, temperature, and depth of melting 3) the plate-scale forces that control foundering and termination of subduction. This project will study a suite of lamprophyres along the axis of the Transantarctic Mountains, emplaced during the latest stages of the Neoproterozoic - Ordovician Ross orogeny, Antarctica (roughly 505 to 470 million years before present). High-precision geochronology (age determinations) will be combined with geochemical measurements on the rocks and minerals to understand the mechanisms and timing of deep crustal foundering/delamination.
Phytoplankton blooms in the coastal waters of the Ross Sea, Antarctica are typically dominated by either diatoms or Phaeocystis Antarctica (a flagellated algae that often can form large colonies in a gelatinous matrix). The project seeks to determine if an association of bacterial populations with Phaeocystis antarctica colonies can directly supply Phaeocystis with Vitamin B12, which can be an important co-limiting micronutrient in the Ross Sea. The supply of an essential vitamin coupled with the ability to grow at lower iron concentrations may put Phaeocystis at a competitive advantage over diatoms. Because Phaeocystis cells can fix more carbon than diatoms and Phaeocystis are not grazed as efficiently as diatoms, the project will help in refining understanding of carbon dynamics in the region as well as the basis of the food web webs. Such understanding also has the potential to help refine predictive ecological models for the region. The project will conduct public outreach activities and will contribute to undergraduate and graduate research. Engagement of underrepresented students will occur during summer student internships. A collaboration with Italian Antarctic researchers, who have been studying the Terra Nova Bay ecosystem since the 1980s, aims to enhance the project and promote international scientific collaborations. <br/><br/>The study will test whether a mutualistic symbioses between attached bacteria and Phaeocystis provides colonial cells a mechanism for alleviating chronic Vitamin B12 co-limitation effects thereby conferring them with a competitive advantage over diatom communities. The use of drifters in a time series study will provide the opportunity to track in both space and time a developing algal bloom in Terra Nova Bay and to determine community structure and the physiological nutrient status of microbial populations. A combination of flow cytometry, proteomics, metatranscriptomics, radioisotopic and stable isotopic labeling experiments will determine carbon and nutrient uptake rates and the role of bacteria in mitigating potential vitamin B12 and iron limitation. Membrane inlet and proton transfer reaction mass spectrometry will also be used to estimate net community production and release of volatile organic carbon compounds that are climatically active. Understanding how environmental parameters can influence microbial community dynamics in Antarctic coastal waters will advance an understanding of how changes in ocean stratification and chemistry could impact the biogeochemistry and food web dynamics of Southern Ocean ecosystems.
ABSTRACT<br/>Intellectual Merit:<br/>The high concentration of the major nutrients nitrate and phosphate is a fundamental characteristic of the Antarctic Zone in the Southern Ocean and is central to its role in global ocean fertility and the global carbon cycle. The isotopic composition of diatom-bound organic nitrogen is one of the best hopes for reconstructing the nutrient status of polar surface waters over glacial cycles, which in turn may hold the explanation for the decline in atmospheric carbon dioxide during ice ages. The PIs propose to generate detailed diatom-bound nitrogen isotope (δ15Ndb) records from high sedimentation rate cores from the Kerguelen Plateau. Because the cores were collected at relatively shallow seafloor depths, they have adequate planktonic and benthic foraminifera to develop accurate age models. The resulting data could be compared with climate records from Antarctic ice cores and other archives to investigate climate-related changes, including the major steps into and out of ice ages and the millennial-scale events that occur during ice ages and at their ends. The records generated in this project will provide a critical test of hypotheses for the cause of lower ice age CO2.<br/><br/>Broader impacts:<br/>This study will contribute to the goal of understanding ice ages and past CO2 changes, which both have broad implications for future climate. Undergraduates will undertake summer internships, with the possibility of extending their work into junior year projects and senior theses. In addition, the PI will lead modules for two Princeton programs for middle school teachers and will host a teacher for a six-week summer research project.
The temperature of the earth is controlled, in part, by heat trapping gases that include carbon dioxide, methane, and nitrous oxide. Despite their importance to climate, direct measurements of these gases in the atmosphere are limited to the last 50 years at best. Air trapped in ice cores extends those data back hundreds of millennia, and measurements of greenhouse gases in ice cores underpin much of our understanding of global chemical cycles relevant to modern climate change. Existing records vary in quality and detail. The proposed work fills gaps in our knowledge of nitrous oxide and carbon dioxide over the last 10,000 years. New measurements from an ice core from the South Pole will be used to determine what role changes in ocean and land based processes played in controlling these gases, which decreased during the first 2,000 years of this time period, then gradually increased toward the present. The work will address a major controversy over whether early human activities could have impacted the atmosphere, and provide data to improve mathematical models of the land-ocean-atmosphere system that predict how future climate change will impact the composition of the atmosphere and climate. <br/><br/>For nitrous oxide the work will improve on existing concentration records It will also develop measurement of the isotopomers of nitrous oxide and explore their utility for understanding aspects of the Holocene nitrous oxide budget. The primary goal is to determine if marine and/or terrestrial emissions of nitrous oxide change in response to changes in Holocene climate. A new Holocene isotopic record for carbon dioxide (stable carbon and oxygen isotopes), will improve the precision of existing records by a factor 5 and increase the temporal resolution. These data will be used to evaluate controversial hypotheses about why carbon dioxide concentrations changed in the Holocene and provide insight into millennial scale processes in the carbon cycle, which are not resolved by current isotopic data. A graduate student and post doc will receive advanced training during and the student and principle investigator will conduct outreach efforts targeted at local middle school students. The proposed work will also contribute to teaching efforts by the PI and to public lectures on climate and climate change. The results will be disseminated through publications, data archive, and the OSU Ice Core Lab web site. New analytical methods of wide utility will also be developed and documented.
Overview: The funded work investigated whether ice core 86Kr acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere (SH) westerly winds. Pressure variations drive macroscopic air movement in the firn column, which reduces the gravitational isotopic enrichment of slow-diffusing gases (such as Kr). The 86Kr deviation from gravitational equilibrium (denoted D86Kr) thus reflects the magnitude of pressure variations (among other things). Atmospheric reanalysis data suggest that pressure variability over Antarctica is linked to the Southern Annular Mode (SAM) index and the position of the SH westerly winds. Preliminary data from the WAIS Divide ice core show a large excursion in D86Kr during the last deglaciation (20-9 ka before present). In this project the investigators (1) performed high-precision 86Kr analysis on ice core and firn air samples to establish whether D86Kr is linked to pressure variability; (2) Refined the deglacial WAIS Divide record of Kr isotopes; (3) Investigated the role of pressure variability in firn air transport using firn air models with firn microtomography data and Lattice- Boltzmann modeling; and (4) Investigated how barometric pressure variability in Antarctica is linked to the SAM index and the position/strength of the SH westerlies in past and present climates using GCM and reanalysis data. A key finding was that D86Kr in recent ice samples (e.g. last 50 years) from a broad spatial array of sites in Antarctica and Greenland showed a significant correlation with directly measured barometric pressure variability at the ice core site. This strongly supports the hypothesis that 86Kr can be used as a paleo-proxy for storminess.
Intellectual Merit: The SH westerlies are a key component of the global climate system; they are an important control on the global oceanic overturning circulation and possibly on atmospheric CO2 concentrations. Poleward movement of the SH westerlies during the last deglaciation has been hypothesized, yet evidence from proxy and modeling studies remains inconclusive. The funded work could provide valuable new constraints on deglacial movement of the SH westerlies. This record can be compared to high-resolution CO2 data from the same core, allowing us to test hypotheses that link CO2 to the SH westerlies. Climate proxies are at the heart of paleoclimate research. The funded work has apparently led to the discovery of a completely new proxy, opening up exciting new research possibilities and increasing the scientific value of existing ice cores. Once validated, the 86Kr proxy could be applied to other time periods as well, providing a long-term perspective on the movement of the SH westerlies. The funded work has furthermore provided valuable new insights into firn air transport.
Broader impact: The Southern Ocean is presently an important sink of atmospheric CO2, thereby reducing the warming associated with anthropogenic CO2 emissions. Stratospheric ozone depletion and greenhouse warming have displaced the SH westerlies poleward, with potential consequences for the future magnitude of this oceanic carbon uptake. The funded work may provide a paleo-perspective on past movement of the SH westerlies and its link to atmospheric CO2, which could guide projections of future oceanic CO2 uptake, with strong societal benefits. The awarded funds supported and trained an early-career postdoctoral scholar at OSU, and fostered (international) collaboration. Data from the study will be available to the scientific community and the broad public through recognized data centers. During this project the PI and senior personnel have continued their commitment to public outreach through media interviews and speaking to schools and the public about their work. The PI provides services to the community by chairing the IPICS (International Partnership in Ice Core Sciences) working group and organizing annual PIRE (Partnerships in International Research and Education) workshops.
Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800,000 years. Previous field expeditions to the Allan Hills blue ice area, Antarctica, have recovered ice cores that date to one million years, the oldest ice cores yet recovered from Antarctica. These records have revealed that interglacial CO2 concentrations decreased by 800,000 years ago and that, in the warmer world 1 million years ago, CO2 and Antarctic temperature were linked as during the last 800,000 years. This project will return to the Allan Hills blue ice area to recover additional ice cores that date to 1 million years or older. The climate records developed from the drilled ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Our results will help answer questions about issues associated with anthropogenic change. These include the relationship between temperature change and the mass balance of Antarctic ice; precipitation and aridity variations associated with radiatively forced climate change; and the climate significance of sea ice extent. The project will entrain two graduate students and a postdoctoral scholar, and will conduct outreach including workshops to engage teachers in carbon science and ice cores.<br/><br/>Between about 2.8-0.9 million years ago, Earth's climate was characterized by 40,000-year cycles, driven or paced by changes in the tilt of Earth's spin axis. Much is known about the "40,000-year" world from studies of deep-sea sediments, but our understanding of climate change during this period is incomplete because we lack records of Antarctic climate and direct records of atmospheric greenhouse gas concentrations. We propose to address these issues by building on our recent studies of ancient ice from the Main Ice Field, Allan Hills, Antarctica. During previous field seasons we recovered ice extending, discontinuously, from 0.1-1.0 million years old. Ice was dated by measuring the 40Ar/38Ar (Argon) ratio of the trapped gases. Our discovery of million year-old ice demonstrates that there is gas-record-quality ice from the 40,000-year world in the Allan Hills Main Ice Field. We have identified two different sites, each overlying bedrock at ~ 200 m depth, that are attractive targets for coring ice dating to 1 million years and older. This project aims to core the ice at these two sites, re-occupy a previous site with million year-old ice and drill it down to the bedrock, and generate 10-20 short (~10-meter) cores in areas where our previous work and terrestrial meteorite ages suggest ancient surface ice. We plan to date the ice using the 40Ar/38Ar ages of trapped Argon. We also plan to characterize the continuity of our cores by measuring the deuterium and oxygen isotope ratios in the ice, methane, ratios of Oxygen and Argon to Nitrogen in trapped gas, the Nitrogen-15 isotope (d15N) of Nitrogen, and the Oxygen-18 isotope (d18O) of Oxygen. As the ice may be stratigraphically disturbed, these measurements will provide diagnostic properties for assessing the continuity of the ice-core records. Successful retrieval of ice older than one million years will provide the opportunity for follow-up work to measure the CO2 concentration and other properties within the ice to inform on the temperature history of the Allan Hills region, dust sources and source-area aridity, moisture sources, densification conditions, global average ocean temperature, and greenhouse gas concentrations. We will analyze the data in the context of leading hypotheses of the 40,000-year world and the Mid-Pleistocene Transition to the 100,000-year world. We expect to advance understanding of climate dynamics during these periods.
This award supports a project to obtain the first set of isotopic-based provenance data from the WAIS divide ice core. A lack of data from the WAIS prevents even a basic knowledge of whether different sources of dust blew around the Pacific and Atlantic sectors of the southern latitudes. Precise isotopic measurements on dust in the new WAIS ice divide core are specifically warranted because the data will be synergistically integrated with other high frequency proxies, such as dust concentration and flux, and carbon dioxide, for example. Higher resolution proxies will bridge gaps between our observations on the same well-dated, well-preserved core. The intellectual merit of the project is that the proposed analyses will contribute to the WAIS Divide Project science themes. Whether an active driver or passive recorder, dust is one of the most important but least understood components of regional and global climate. Collaborative and expert discussion with dust-climate modelers will lead to an important progression in understanding of dust and past atmospheric circulation patterns and climate around the southern latitudes, and help to exclude unlikely air trajectories to the ice sheets. The project will provide data to help evaluate models that simulate the dust patterns and cycle and the relative importance of changes in the sources, air trajectories and transport processes, and deposition to the ice sheet under different climate states. The results will be of broad interest to a range of disciplines beyond those directly associated with the WAIS ice core project, including the paleoceanography and dust- paleoclimatology communities. The broader impacts of the project include infrastructure and professional development, as the proposed research will initiate collaborations between LDEO and other WAIS scientists and modelers with expertise in climate and dust. Most of the researchers are still in the early phase of their careers and hence the project will facilitate long-term relationships. This includes a graduate student from UMaine, an undergraduate student from Columbia University who will be involved in lab work, in addition to a LDEO Postdoctoral scientist, and possibly an additional student involved in the international project PIRE-ICETRICS. The proposed research will broaden the scientific outlooks of three PIs, who come to Antarctic ice core science from a variety of other terrestrial and marine geology perspectives. Outreach activities include interaction with the science writers of the Columbia's Earth Institute for news releases and associated blog websites, public speaking, and involvement in an arts/science initiative between New York City's arts and science communities to bridge the gap between scientific knowledge and public perception.
The biota of the world's seafloor is fueled by bursts of seasonal primary production. For food-limited sediment communities to persist, a balance must exist between metazoan consumption of and competition with bacteria, a balance which likely changes through the seasons. Polar marine ecosystems are ideal places to study such complex interactions due to stark seasonal shifts between heterotrophic and autotrophic communities, and temperatures that may limit microbial processing of organic matter. The research will test the following hypotheses: 1) heterotrophic bacteria compete with macrofauna for food; 2) as phytoplankton populations decline macrofauna increasingly consume microbial biomass to sustain their populations; and 3) in the absence of seasonal photosynthetic inputs, macrofaunal biodiversity will decrease unless supplied with microbially derived nutrition. Observational and empirical studies will test these hypotheses at McMurdo Station, Antarctica, where a high-abundance macro-infaunal community is adapted to this boom-and-bust cycle of productivity. The investigator will mentor undergraduates from a predominantly minority-serving institution, in the fields of invertebrate taxonomy and biogeochemistry. The general public and young scientists will be engaged through lectures at local K-12 venues and launch of an interactive website. The results will better inform scientists and managers about the effects of climate change on polar ecosystems and the mechanisms of changing productivity patterns on global biodiversity.
Paragraph for Laypersons:<br/>This research focuses on the history of rock glaciers and buried glacial ice in the McMurdo Dry Valleys region of Antarctica. Rock glaciers are flowing mixtures of ice and sediments common throughout alpine and high-latitude regions on Earth and Mars. Despite similar appearances, rock glaciers can form under highly variable environmental and hydrological conditions. The main research questions addressed here are: 1) what environmental and climatological conditions foster long-term preservation of rock glaciers in Antarctica, 2) what role do rock glaciers play in Antarctic landscape evolution and the local water cycle, and 3) what can rock glaciers reveal about the extent and timing of previous glacial advances? The project will involve two Antarctic field seasons to image the interior of Antarctic rock glaciers using ground-penetrating radar, to gather ice cores for chemical analyses, and to gather surface sediments for dating. The Dry Valleys host the world?s southernmost terrestrial ecosystem (soil, stream and lake micro-organisms and mosses); rock glaciers and ground-ice are an important and poorly-studied source of meltwater and nutrients for these ecosystems. This research will shed light on the glacial and hydrological history of the Dry Valleys region and the general environmental conditions the foster rock glaciers, features that generally occur in warmer and/or wetter locations. The research will provide support for five graduate/undergraduate students, who will actively gather data in the field, followed by interpretation, dissemination and presentation of the data. Additionally, the researchers will participate in a range of educational activities including outreach with local K-12 in the Lowell, MA region, such as summer workshops and classroom visits with hands-on activities. A series of time-lapse images of hydrological processes, and videos of researchers in the field, will serve as a dramatic centerpiece in community and school presentations.<br/><br/>Paragraph for Scientific Community:<br/>Rock glaciers are common in the McMurdo Dry Valleys, but are concentrated in a few isolated regions: western Taylor Valley, western Wright Valley, Pearse Valley and Bull Pass. The investigators hypothesize that the origin and age of these features varies by region: that rock glaciers in Pearse and Taylor valley originated as buried glacier ice, whereas rock glaciers in Wright Valley formed through permafrost processes, such as mobilization of ice-rich talus. To address these hypotheses, the project will: 1) develop relative and absolute chronologies for the rock glaciers through field mapping and optically stimulated luminescence dating of overlying sediments, 2) assess the origin of clean-ice cores through stable isotopic analyses, and 3) determine if present-day soil-moisture and temperature conditions are conducive to rock glacier formation/preservation. The proposed research will provide insight into the spatial and temporal distribution of buried glacier ice and melt-water-derived ground ice in the McMurdo Dry Valleys, with implications for glacial history, as well as the potential role of rock glaciers in the regional hydrologic cycle (and the role of ground-ice as a source for moisture and nutrient for local ecosystems). The project will provide general constraints on the climatic and hydrologic conditions that foster permafrost rock glaciers, features that generally occur under warmer and wetter conditions than those found in the present-day McMurdo Dry Valleys. The application of OSL and cosmogenic exposure<br/>dating is novel to rock glaciers, geomorphic features that have proven difficult to date, despite their ubiquity in Antarctica and their potential scientific importance. The research will provide support for five graduate/undergraduate students, who will participate in the field work, followed by interpretation, dissemination and presentation of the data. The researchers will participate in a range of educational activities including outreach with local K-12 in the Lowell, MA region, such as summer workshops and classroom visits with hands-on activities.
Hastings/1246223<br/><br/>This award supports a project with the aim of distinguishing the sources of nitrate deposition to the West Antarctic Ice Sheet (WAIS) using isotopic ratios snow in archive snow and ice samples. The isotopic composition of nitrate has been shown to contain information about the source of the nitrate (i.e. nitrogen oxides = NOx = NO+NO2) and the oxidation processes that convert NOx to nitrate in the atmosphere prior to deposition. A difficulty in interpreting records in the context of NOx sources is that nitrate can be post-depositionally processed in surface snow, such that the archived record does not reflect the composition of the atmosphere. This intellectual merit of this work specifically aims to investigate variability in the isotopic composition of nitrate in snow and ice from the WAIS in the context of accumulation rate, NOx source emissions, and atmospheric chemistry. These records will be interpreted in the context of our understanding of biospheric (biomass burning, microbial processes in soils), atmospheric (lightning, transport, chemistry), and climate (temperature, accumulation rate) changes over time. A graduate student will be supported as part of this project, and both graduate student and PI will be involved in communicating the utility and results of polar research to elementary school students in the Providence, RI area. The broader impacts of the project also include making efforts to attract more young, female scientists to polar research by establishing a connection between the Earth Science Women's Network (ESWN), an organization PI Hastings helped to establish, and the Association of Polar Early Career Scientists (APECS). Finally, results of all measurements will be presented at relevant conferences, made available publicly and published in peer-reviewed journals.
Intellectual Merit: <br/>This project will investigate glacial advance and retreat of the East Antarctic Ice Sheet through the Eocene-Oligocene transition, a major episode of ice growth. In Prydz Bay, East Antarctica, a 130-170 m thick Eocene-Oligocene transition interval of glaciomarine sediments was cored in drillholes of the Ocean Drilling Program at Sites 739, 742 and 1166. Correlations between the Prydz Bay drillholes have recently been made through well-log and multichannel seismic interpretations. Recent drilling on the Wilkes Land margin of East Antarctica recovered earliest Oligocene sediments overlying a major regional unconformity in two drillholes. The PI will study the lithostratigraphy and weathering history of cores in the five drillholes, to establish a unique Eocene-Oligocene transition record within Antarctic continental margin sediments of glacial advance and retreat cycles, the onset of physical weathering, and glacio-isostasy and self-gravitation processes with implications for the margin architecture, sediment routing, and off-shore sediment dispersal. Cores from the five drillholes will be re-examined through detailed core description using an updated classification scheme, so that lithofacies can be compared between drillholes. Samples will be collected for detailed laser particle size and bulk major element geochemistry via ICP-AES to determine the degree of chemical alteration of the sediments. Phases of major ice growth will be recognized as marker beds of physically eroded sediment and will be correlated to isotopic records documenting Antarctic ice growth offshore in the Southern Ocean. <br/><br/>Broader impacts: <br/>This project will benefit a large minority undergraduate student population through the availability of up to two paid laboratory internships, a classroom exercise, and the availability of research equipment supported by this award. The project also allows support and training of a graduate student.
This award supports a project to broaden the knowledge of annual accumulation patterns over the West Antarctic Ice Sheet by processing existing near-surface radar data taken on the US ITASE traverse in 2000 and by gathering and validating new ultra/super-high-frequency (UHF) radar images of near surface layers (to depths of ~15 m), expanding abilities to monitor recent annual accumulation patterns from point source ice cores to radar lines. Shallow (15 m) ice cores will be collected in conjunction with UHF radar images to confirm that radar echoed returns correspond with annual layers, and/or sub-annual density changes in the near-surface snow, as determined from ice core stable isotopes. This project will additionally improve accumulation monitoring from space-borne instruments by comparing the spatial-radar-derived-annual accumulation time series to the passive microwave time series dating back over 3 decades and covering most of Antarctica. The intellectual merit of this project is that mapping the spatial and temporal variations in accumulation rates over the Antarctic ice sheet is essential for understanding ice sheet responses to climate forcing. Antarctic precipitation rate is projected to increase up to 20% in the coming century from the predicted warming. Accumulation is a key component for determining ice sheet mass balance and, hence, sea level rise, yet our ability to measure annual accumulation variability over the past 5 decades (satellite era) is mostly limited to point-source ice cores. Developing a radar and ice core derived annual accumulation dataset will provide validation data for space-born remote sensing algorithms, climate models and, additionally, establish accumulation trends. The broader impacts of the project are that it will advance discovery and understanding within the climatology, glaciology and remote sensing communities by verifying the use of UHF radars to monitor annual layers as determined by visual, chemical and isotopic analysis from corresponding shallow ice cores and will provide a dataset of annual to near-annual accumulation measurements over the past ~5 decades across WAIS divide from existing radar data and proposed radar data. By determining if temporal changes in the passive microwave signal are correlated with temporal changes in accumulation will help assess the utility of passive microwave remote sensing to monitor accumulation rates over ice sheets for future decades. The project will promote teaching, training and learning, and increase representation of underrepresented groups by becoming involved in the NASA History of Winter project and Thermochron Mission and by providing K-12 teachers with training to monitor snow accumulation and temperature here in the US, linking polar research to the student?s backyard. The project will train both undergraduate and graduate students in polar research and will encouraging young investigators to become involved in careers in science. In particular, two REU students will participate in original research projects as part of this larger project, from development of a hypothesis to presentation and publication of the results. The support of a new, young woman scientist will help to increase gender diversity in polar research.
Geochemical studies of single mineral grains in rocks can be probed to reconstruct the history of our planet. The mineral zircon (ZrSiO4) is of unique importance in that respect because of its reliability as a geologic clock due to its strong persistence against weathering, transport and changes in temperature and pressure. Uranium-Lead (U-Pb) dating of zircon grains is, perhaps, the most frequently employed method of extracting time information on geologic processes that shaped the continental crust, and has been used to constrain the evolution of continents and mountain belts through time. In addition, the isotopic composition of the element Hafnium (Hf) in zircon is used to date when the continental crust was generated by extraction of magma from the underlying mantle. Melting of rocks in the mantle and deep in the continental crust are key processes in the evolution of the continents, and they are recorded in the Hf isotopic signatures of zircon. Although the analytical procedures for U-Pb dating and Hf isotope analyses of zircon are robust now, our understanding of zircon growth and its exchange of elements and isotopes with its surrounding rock or magma are still underdeveloped. The focus of the proposed study, therefore, is to unravel the evolution of zircon Hf isotopes in rocks that were formed deep in the Earth?s crust, and more specifically, to apply these isotopic methods to rocks collected in Dronning Maud Land (DML), East Antarctica.<br/><br/>Dronning Maud Land (DML) occupied a central location during the formation of supercontinents ? large landmasses made up of all the continents that exist today - more than 500 million years ago. It is currently thought that supercontinents were formed and dismembered five or six times throughout Earth?s history. The area of DML is key for understanding the formation history of the last two supercontinents. The boundaries of continents that were merged to form those supercontinents are most likely hidden in DML. In this study, the isotopic composition of zircon grains recovered from DML rocks will be employed to identify these boundaries across an extensive section through the area. The rock samples were collected by the investigator during a two-month expedition to Antarctica in the austral summer of 2007?2008. The results of dating and isotope analyses of zircon of the different DML crustal domains will deliver significant insight into the regional geology of East Antarctica and its previous northern extension into Africa. This has significance for the reconstruction of the supercontinents and defining the continental boundaries in DML.
1043421/Severinghaus<br/><br/>This award supports a project to obtain samples of ice in selected intervals for replication and verification of the validity and spatial representativeness of key results in the WAIS Divide ice core, and to obtain additional ice samples in areas of intense scientific interest where demand is high. The US Ice Core Working Group recommended in 2003 that NSF pursue the means to take replicate samples, termed "replicate coring". This recommendation was part of an agreement to reduce the diameter of the (then) new drilling system (the DISC drill) core to 12.2 cm to lighten logistics burdens, and the science community accepted the reduction in ice sample with the understanding that replicate coring would be able to provide extra sample volume in key intervals. The WAIS Divide effort would particularly benefit from replicate coring, because of the unique quality of the expected gas record and the large samples needed for gases and gas isotopes; thus this proposal to employ replicate coring at WAIS Divide. In addition, scientific demand for ice samples has been, and will continue to be, very unevenly distributed, with the ice core archive being completely depleted in depth intervals of high scientific interest (abrupt climate changes, volcanic sulfate horizons, meteor impact horizons, for example). The broader impacts of the proposed research may include identification of leads and lags between Greenland, tropical, and Antarctic climate change, enabling critical tests of hypotheses for the mechanism of abrupt climate change. Improved understanding of volcanic impacts on atmospheric chemistry and climate may also emerge. This understanding may ultimately help improve climate models and prediction of the Earth System feedback response to ongoing human perturbation in coming centuries. Outreach and public education about climate change are integral components of the PIs' activities and the proposed work will enhance these efforts. Broader impacts also include education and training of 2 postdoctoral scholars and 1 graduate student, and invaluable field experience for the graduate and undergraduate students who will likely make up the core processing team at WAIS Divide.
Intellectual Merit: <br/>Because of extensive ice cover and sparse remote-sensing data, the geology of the Precambrian East Antarctic Shield (EAS) remains largely unexplored with information limited to coastal outcrops from the African, Indian and Australian sectors. The East Antarctic lithosphere is globally important: as one of the largest coherent Precambrian shields, including rocks as old as ~3.8 Ga, it played an important role in global crustal growth; it is a key piece in assembly of the Rodinia and Gondwana supercontinents; it is the substrate to Earth?s major ice cap, including numerous sub-glacial lakes, and influences its thermal state and mechanical stability; and its geotectonic association with formerly adjacent continental blocks in South Africa, India and Australia suggest that it might harbor important mineral resources. This project will increase understanding of the age and composition of the western EAS lithosphere underlying and adjacent to the Transantarctic Mountains (TAM) using U-Pb ages, and Hf- and O-isotope analysis of zircon in early Paleozoic granitoids and Pleistocene glacial tills. TAM granites of the early Paleozoic Ross Orogen represent an areally extensive continental-margin arc suite that can provide direct information about the EAS crust from which it melted and/or through which it passed. Large rock clasts of igneous and metamorphic lithologies entrained in glacial tills at the head of major outlet glaciers traversing the TAM provide eroded samples of the proximal EAS basement. Zircons in these materials will provide data about age and inheritance (U-Pb), crustal vs. mantle origin (O isotopes), and crustal sources and evolution (Hf isotopes). Integrated along a significant part of the TAM, these data will help define broader crustal provinces that can be correlated with geophysical data and used to test models of crustal assembly. <br/><br/>Broader impacts: <br/>This project will provide a research opportunity for undergraduate and graduate students. Undergraduates will be involved as Research Assistants in sample preparation, imaging, and analytical procedures, and conducting their own independent research. The two main elements of this project will form the basis of MS thesis projects for two graduate students at UMD. Through this project they will gain a good understanding of petrology, isotope geochemistry, and analytical methods. The broader scientific impacts of this work are that it will help develop a better understanding of the origin and evolution of East Antarctic lithosphere underlying and adjacent to the TAM, which will be of value to the broader earth science and glaciological community. Furthermore, knowledge of East Antarctic geology is of continuing interest to the general public because of strong curiosity about past supercontinents, what?s under the ice, and the impact of global warming on ice-sheet stability.
Barbeau, David; Hemming, Sidney R.; Barbeau, David Jr
No dataset link provided
Intellectual Merit: <br/>Recent geochemical, sequence stratigraphic, and integrated investigations of marine strata from several continental margins and ocean basins suggest that ephemeral ice sheets may have existed on Antarctica during parts of the Cretaceous and early Paleogene. However, atmospheric carbon dioxide estimates for this time are as much as four times modern levels. With such greenhouse conditions, the presence of Antarctic ice sheets would imply that our current understanding of Earth?s climate system, and specifically the interpreted thresholds of Antarctic glaciation and deglaciation should be reconsidered. The proposed research will compare the quantity and provenance of Cretaceous sediments in the Larsen basin of the eastern Antarctic Peninsula with the exhumation chronology and composition of potential sediment source terranes on the peninsula and in adjacent regions. New outcrop stratigraphic analyses with improvements in the age models from radioisotopic approaches will be integrated to determine the amount of detrital sediment fluxed to the Larsen basin between key chronostratigraphic surfaces. Microtextural analysis of quartz sand and silt grains will help determine whether the Larsen basin detrital sediment originated from glacial weathering. These preliminary results will test the viability of the proposed approach to assess the controversial Cretaceous Antarctic glaciation hypothesis.<br/><br/>Broader impacts: <br/>The proposed work will partially support a PhD, a MSc, and three undergraduate students at the University of South Carolina. The PIs will publicize this work through volunteer speaking engagements and the development of videos and podcasts. They also commit to prompt publication of the results and timely submission of data to archives. The development/improvement of the Larsen basin age model will benefit ongoing research in paleobiology, paleoclimate and biogeography. Development of the glauconite K-Ar and Rb-Sr chronometers could be an important outcome beyond the direct scope of the proposed research.
Intellectual Merit: <br/>The PIs propose to study the stability and dynamics of the East Antarctic ice sheet during the Pliocene in the area of the Wilkes and Aurora subglacial basins. Models indicate the ice sheet is most sensitive to warming in these low-lying areas. This study is important as there is very little direct evidence about which parts of the East Antarctic ice sheet became unstable under warm conditions. In a pilot study the PIs have shown that the isotopic geochemical signature of downcore ice-rafted debris (IRD) can be linked to continental source areas indicating which parts of the ice sheet reached the coast and calved IRD-bearing icebergs. Their initial results suggest rapid iceberg discharge from the Wilkes Land and Adélie Land coastal areas at times in the late Miocene and early Pliocene. In this study the PIs will analyze IRD from IODP sediment cores collected on the continental rise off East Antarctica. By analyzing 40Ar/39Ar ages of hornblende IRD grains, U-Pb ages of zircons, and Sm-Nd isotopes of the fine fraction of several IRD-rich layers for each core, they will be able to fingerprint continental source areas that will indicated ice extent and dynamics on East Antarctica. The PIs will also carry out detailed studies across a few of these layers to characterize the anatomy of the ice-rafting event and better understand the mechanism of ice destabilization.<br/><br/>Broader impacts: <br/>The data collected will be important for scientists in a broad variety of fields. The project will involve one undergraduate student and one summer intern at LDEO, and a graduate student at Imperial College London. The project will expose to cutting edge methodologies as well as an international research team. Data from the project will be deposited in the online databases (SedDB) and all results and methods will be made available to the scientific community through publications in peer-reviewed journals and attendance at international conferences.
During previous NSF-sponsored research, the PI's discovered that southern elephant seal colonies once existed along the Victoria Land coast (VLC) of Antarctica, a region where they are no longer observed. Molted seal skin and hair occur along 300 km of coastline, more than 1000 km from any extant colony. The last record of a seal at a former colony site is at ~A.D. 1600. Because abandonment occurred prior to subantarctic sealing, disappearance of the VLC colony probably was due to environmental factors, possibly cooling and encroachment of land-fast, perennial sea ice that made access to haul-out sites difficult. The record of seal inhabitation along the VLC, therefore, has potential as a proxy for climate change. Elephant seals are a predominantly subantarctic species with circumpolar distribution. Genetic studies have revealed significant differentiation among populations, particularly with regard to that at Macquarie I., which is the extant population nearest to the abandoned VLC colony. Not only is the Macquarie population unique genetically, but it is has undergone unexplained decline of 2%/yr over the last 50 years3. In a pilot study, genetic analyses showed a close relationship between the VLC seals and those at Macquarie I. An understanding of the relationship between the two populations, as well as of the environmental pressures that led to the demise of the VLC colonies, will provide a better understanding of present-day population genetic structure, the effect of environmental change on seal populations, and possibly the reasons underlying the modern decline at Macquarie Island.<br/>This project addresses several key research problems: (1) Why did elephant seals colonize and then abandon the VLC? (2) What does the elephant seal record reveal about Holocene climate change and sea-ice conditions? (3) What were the foraging strategies of the seals and did these strategies change over time as climate varied? (4) How does the genetic structure of the VLC seals relate to extant populations? (5) How did genetic diversity change over time and with colony decline? (6) Using ancient samples to estimate mtDNA mutation rates, what can be learned about VLC population dynamics over time? (7) What was the ecological relationship between elephant seals and Adelie penguins that occupied the same sites, but apparently at different times? The proposed work includes the professional training of young researchers and incorporation of data into graduate and undergraduate courses.
0538657<br/>Severinghaus<br/>This award supports a project to develop high-resolution (20-yr) nitrogen and oxygen isotope records on trapped gases in the WAIS Divide ice core (Antarctica), with a comparison record for chronological purposes in the GISP2 (Greenland) ice core. The main scientific objective is to provide an independent temperature-change record for the past 100,000 years in West Antarctica that is not subject to the uncertainty inherent in ice isotopes (18O and deuterium), the classical paleothermometer. Nitrogen isotopes (Delta 15N) in air bubbles in glacial ice record rapid surface temperature change because of thermal fractionation of air in the porous firn layer, and this isotopic anomaly is recorded in bubbles as the firn becomes ice. Using this gas-based temperature-change record, in combination with methane data as interpolar stratigraphic markers, the proposed work will define the precise relative timing of abrupt warming in Greenland and abrupt cooling at the WAIS Divide site during the millennial-scale climatic oscillations of Marine Isotopic Stage 3 (30-70 kyr BP) and the last glacial termination. The nitrogen isotope record also provides constraints on past firn thickness, which inform temperature and accumulation rate histories from the ice core. A search for possible solar-related cycles will be conducted with the WAIS Divide Holocene (Delta 15N.) Oxygen isotopes of O2 (Delta 18Oatm) are obtained as a byproduct of the (Delta 15N) measurement. The gas-isotopic records will enhance the value of other atmospheric gas measurements in WAIS Divide, which are expected to be of unprecedented quality. The high-resolution (Delta 18Oatm) records will provide chronological control for use by the international ice coring community and for surface glacier ice dating. Education of a graduate student, and training of a staff member in the laboratory, will contribute to the nation's human resource base. Outreach activities in the context of the International Polar Year will be enhanced. International collaboration is planned with the laboratory of LSCE, University of Paris.
The U.S. Global Ocean Ecosystems Dynamics (U.S. GLOBEC) program has the goal of understanding and ultimately predicting how populations of marine animal species respond to natural and anthropogenic changes in climate. Research in the Southern Ocean (SO) indicates strong coupling between climatic processes and ecosystem dynamics via the annual formation and destruction of sea ice. The Southern Ocean GLOBEC Program (SO GLOBEC) will investigate the dynamic relationship between physical processes and ecosystem responses through identification of critical parameters that affect the distribution, abundance and population dynamics of target species. The overall goals of the SO GLOBEC program are to elucidate shelf circulation processes and their effect on sea ice formation and krill distribution, and to examine the factors which govern krill survivorship and availability to higher trophic levels, including penguins, seals and whales. The focus of the U.S. contribution to the international SO GLOBEC program will be on winter processes. This component will focus on the distribution and foraging behavior of adult female crabeater seals, using a combination of satellite-linked tracking, specialized diver recorders, and stable isotopic tracers. This research will be coordinated with components focused on prey (krill) distribution and the physical environment. The results will be analyzed using an optimality model. The result of the integrated SO GLOBEC program will be to improve the predictability of living marine resources, especially with respect to local and global climatic shifts.
The U.S. Global Ocean Ecosystems Dynamics (U.S. GLOBEC) program has the goal of understanding and ultimately predicting how populations of marine animal species respond to natural and anthropogenic changes in climate. Research in the Southern Ocean (SO) indicates strong coupling between climatic processes and ecosystem dynamics via the annual formation and destruction of sea ice. The Southern Ocean GLOBEC Program (SO GLOBEC) will investigate the dynamic relationship between physical processes and ecosystem responses through identification of critical parameters that affect the distribution, abundance and population dynamics of target species. The overall goals of the SO GLOBEC program are to elucidate shelf circulation processes and their effect on sea ice formation and krill distribution, and to examine the factors which govern krill survivorship and availability to higher trophic levels, including penguins, seals and whales. The focus of the U.S. contribution to the international SO GLOBEC program will be on winter processes. This component will focus on the distribution and foraging behavior of adult female crabeater seals, using a combination of satellite-linked tracking, specialized diver recorders, and stable isotopic tracers. This research will be coordinated with components focused on prey (krill) distribution and the physical environment. The results will be analyzed using an optimality model. The result of the integrated SO GLOBEC program will be to improve the predictability of living marine resources, especially with respect to local and global climatic shifts.
This award supports a project to develop a quantitative understanding of the processes active in isotopic exchange between snow/firn and water vapor, which is of paramount importance to ice core interpretation. Carefully controlled laboratory studies will be conducted at a variety of temperatures to empirically measure the mass transfer coefficient (the rate at which water moves from the solid to the vapor phase) for sublimating snow and to determine the time scale for isotopic equilibration between water vapor and ice. In addition the isotopic fractionation coefficient for vapor derived from sublimating ice will be determined and the results will be used to update existing models of mass transfer and isotopic evolution in firn. It is well known that water vapor moves through firn due to diffusion, free convection and forced convection. Although vapor movement through variably-saturated firn due to these processes has been modeled, because of a lack of laboratory data the mass transfer coefficient had to be estimated. Field studies have documented the magnitudes of post-depositional changes, but field studies do not permit rigorous analysis of the relative importance of the many processes which are likely to act in natural snow packs. The results of these laboratory investigations will be broadly applicable to a number of studies and will allow for improvement of existing physically-based models of post-depositional isotopic change, isotopic diffusion in firn, and vapor motion in firn. A major component of this project will be the design and fabrication of the necessary, novel experimental apparatus, which will be facilitated by existing technical expertise, cold room facilities, and laboratory equipment at CRREL. This project is a necessary step toward a quantitative understanding of the isotopic effects of water vapor movement in firn. The proposed work has broader impacts in several different areas. The modeling results will be applicable to a wide range of studies of water in the polar environment, including studies of wind-blown or drifting snow. The proposed collaborative study will partially support a Dartmouth graduate student for three years. This project will also provide support for a young first-time NSF investigator at the University of Vermont. Undergraduate students from Dartmouth will be involved in the research through the Women in Science Project and undergraduate students at the University of Vermont will be supported through the Research Experiences for Undergraduates program. The principal investigators and graduate student will continue their tradition of k-12 school outreach by giving science lessons and talks in local schools each year. Research results will be disseminated through scientific conferences, journal publications, and institutional seminars.
The award supports the development of high-resolution nitrogen and oxygen isotope records on trapped gases in the Byrd and Siple Dome ice cores, and the Holocene part of the GISP2 ice core. The primary scientific goals of this work are to understand the enigmatic d15N anomalies seen thus far in the Siple Dome record at 15.3 ka and 35 ka, and to find other events that may occur in both cores. At these events, d15N of trapped air approaches zero, implying little or no gravitational fractionation of gases in the firn layer at the time of formation of the ice. These events may represent times of low accumulation rate and arid meteorological conditions, and thus may contain valuable information about the climatic history of West Antarctica. Alternatively, they may stem from crevassing and thus may reveal ice-dynamical processes. Finding the events in the Byrd core, which is located 500 km from Siple Dome, would place powerful constraints on their origin and significance. A second major goal is to explore the puzzling absence of the abrupt warming event at 22 ka (seen at Siple Dome) in the nearby Byrd 18O/16O record in the ice (d18Oice), and search for a possible correlative signal in Byrd d15N. A third goal takes advantage of the fact that precise measurements of the oxygen isotopic composition of atmospheric O2 (d18Oatm) are obtained as a byproduct of the d15N measurement. The proposed gas-isotopic measurements will underpin an integrated suite of West Antarctic climate and atmospheric gas records, which will ultimately include the WAIS Divide core. These records will help separate regional from global climate signals, and may place constraints on the cause of abrupt climate change. Education of two graduate students, and training of two staff members in the laboratory, contribute to the nation's human resource base. Education and outreach will be an important component of the project.
This project uses geochemical studies to determine the origin of volcanic rocks from Marie Byrd Land (MBL), Antarctica. Surprisingly, adjacent volcanoes in the MBL have dramatically different compositions, ranging from phonolite to trachyte to rhyolite. This diversity offers an opportunity to constrain the processes responsible for generating silica oversaturated and undersaturated magmas in a single geologic setting. Previous work suggests that the most obvious and simplest explanation--crustal contamination--is not a significant factor, and that polybaric fractional crystallization is the major cause. This study evaluates these factors through analyses and interpretation of trace and rare earth element abundances, as well as Sr and Nd isotopic ratios. <br/><br/>The broader impacts include outreach programs to the Girl Scouts of America, and dissemination of results through publications and meetings.
The Southern Ocean may play a central role in causing ice ages and general global climate change. This work will reveal key characteristics of the glacial ocean, and may explain the cause of glacial/interglacial cycles by measuring the abundances of certain isotopes of nitrogen found in fossil diatoms from Antarctic marine sediments. Diatom-bound N is a potentially important recorder of nutrient utilization. The Southern Ocean's nutrient status, productivity and circulation may be central to setting global atmospheric CO2 contents and other aspects of climate. Previous attempts to make these measurements have yielded ambiguous results. This project includes both technique development and analyses, including measurements on diatoms from both sediment traps and culture experiments. With regard to broader impacts, this grant is focused around the education and academic development of a graduate student, by coupling their research with mentorship of an undergraduate researcher
This award supports a project to measure the elemental and isotopic composition of firn air and occluded air in shallow boreholes and ice cores from the WAIS Divide site, the location of a deep ice-coring program planned for 2006-07 and subsequent seasons. The three primary objectives are: 1) to establish the nature of firn air movement and trapping at the site to aid interpretations of gas data from the deep core; 2) to expand the suite of atmospheric trace gas species that can be measured in ice and replicate existing records of other species; and 3) to inter-calibrate all collaborating labs to insure that compositional and isotopic data sets are inter-comparable. The program will be initiated with a shallow drilling program during the 05/06 field season which will recover two 300+m cores and firn air samples. The ice core and firn air will provide more than 700 years of atmospheric history that will be used to address a number of important questions related to atmospheric change over this time period. The research team consists of six US laboratories that also plan to participate in the deep core program. This collaborative research program has a number of advantages. First, the scientists will be able to coordinate sample allocation a priori to maximize the resolution and overlap of records of interrelated species. Second, sample registration will be exact, allowing direct comparison of all records. Third, a coherent data set will be produced at the same time and all PI.s will participate in interpreting and publishing the results. This will insure that the best possible understanding of gas records at the WAIS Divide site will be achieved, and that all work necessary to interpret the deep core is conducted in a timely fashion. The collaborative structure created by the proposal will encourage sharing of techniques, equipment, and ideas between the laboratories. The research will identify impacts of various industrial/agricultural activities and help to distinguish them from natural variations, and will include species for which there are no long records of anthropogenic impact. The work will also help to predict future atmospheric loadings. The project will contribute to training scientists at several levels, including seven undergraduates, two graduate students and one post doctoral fellow.
This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a project to investigate the "Silicic Acid Leakage Hypothesis" as it relates to global carbon dioxide fluctuations during glacial-interglacial cycles.<br/><br/>Intellectual Merit<br/>This project will evaluate the burial rate of biogenic opal in the Pacific sector of the Southern Ocean, both during the Last Glacial Maximum (LGM) and during the Holocene, as a critical test of the "Silicic Acid Leakage Hypothesis". <br/><br/>The "Silicic Acid Leakage Hypothesis" has been proposed recently to explain the glacial reduction in the carbon dioxide content of the atmosphere that has been reconstructed from Antarctic ice cores. Vast amounts of dissolved Si (silicic acid) are supplied to surface waters of the Southern Ocean by wind-driven upwelling of deep waters. Today, that dissolved Si is consumed almost quantitatively by diatoms who form skeletal structures composed of biogenic opal (a mineral form of silicon). According to the "Silicic Acid Leakage Hypothesis", environmental conditions in the Southern Ocean during glacial periods were unfavorable for diatom growth, leading to reduced (compared to interglacials) efficiency of dissolved Si utilization. Dissolved Si that was not consumed biologically in the glacial Southern ocean was then exported to the tropics in waters that sink in winter to depths of a few hundred meters along the northern fringes of the Antarctic Circumpolar Current, and return some decades later to the sunlit surface in tropical regions of wind-driven upwelling. <br/><br/>An increase in the amount of dissolved Si that "leaks" out of the Southern Ocean and later upwells at low latitudes could shift the global average composition of phytoplankton toward a greater abundance of diatoms and fewer CaCO3-secreting taxa (especially coccolithophorids). Consequences of such a taxonomic shift in the ocean's phytoplankton assemblage include:<br/> a) an increase in the global average organic carbon/calcium carbonate ratio of particulate biogenic material sinking into the deep sea;<br/> b) a reduction in the preservation and burial of calcium carbonate in marine sediments;<br/> c) an increase in ocean alkalinity as a consequence of the first two changes mentioned above, and;<br/> d) a lowering of atmospheric CO2 concentrations in response to increased alkalinity of ocean waters. <br/><br/>A complete assessment of the Silicic acid leakage hypothesis will require an evaluation of: (1) Si utilization efficiencies using newly-developed stable isotopic techniques; (2) opal burial rates in low-latitude upwelling regions; and (3) opal burial rates in the Southern Ocean. This project addresses the last of these topics. <br/><br/>Previous work has shown that there was little change in opal burial rate between the LGM and the Holocene in the Atlantic and Indian sectors of the Southern Ocean. Preliminary results (summarized in this proposal) suggest that the Pacific may have been different, however, in that opal burial rates in the Pacific sector seem to have been lower during the LGM than during the Holocene, allowing for the possibility of "Si leakage" from this region. However, available results are too sparse to make any quantitative conclusions at this time. For that reason, we propose to make a comprehensive evaluation of opal burial rates in the Pacific sector of the Southern Ocean. <br/><br/>Significance and Broader Impacts<br/>Determining the mechanism(s) by which the ocean has regulated climate-related changes in the CO2 content of the atmosphere has been the focus of a substantial effort by paleoceanographers over the past two decades. The Silicic Acid Leakage Hypothesis is a viable new candidate mechanism that warrants further exploration and testing. Completion of the proposed work will contribute significantly to that effort. <br/><br/>During the course of this work, several undergraduates will be exposed to paleoclimate research through their involvement in this project. Burckle and Anderson are both dedicated to the education and training of young scientists, and to the recruitment of women and under-represented minorities. To illustrate, two summer students (undergraduates) worked in Burckle's lab during the summer of 2002. One was a woman and the other (male) was a member of an under-represented minority. Anderson and Burckle will continue with similar recruitment efforts during the course of the proposed study. A minority student who has expressed an interest in working on this research during the summer of 2003 has already been identified.
This award supports the development of a new laboratory capability in the U.S. to measure CO2 in ice cores and investigate millennial-scale changes in CO2 during the last glacial period using samples from the Byrd and Siple Dome ice cores. Both cores have precise relative chronologies based on correlation of methane and the isotopic composition of atmospheric oxygen with counterpart records from Greenland ice cores. The proposed work will therefore allow comparison of the timing of CO2 change, Antarctic temperature change, and Greenland temperature change on common time scales. Such comparisons are vital for evaluating models that explain changes in atmospheric CO2. The techniques being developed will also be available for future projects, specifically the proposed Inland WAIS ice core, for which a highly detailed CO2 record is a major objective, and studies greenhouse and other atmospheric gases and their isotopic composition for which dry extraction is necessary (stable isotopes in CO2, for example). There are many broad impacts of the proposed work. Ice core greenhouse gas records are central contributions of paleoclimatology to research and policy-making concerning global change. The proposed work will enhance those contributions by improving our understanding of the natural cycling of the most important greenhouse gas. It will contribute to the training of a postdoctoral researcher, who will be an integral part of an established research group and benefit from the diverse paleoclimate and geochemistry community at OSU. The PI teaches major and non-major undergraduate and graduate courses on climate and global change. The proposed work will enrich those courses and the courses will provide an opportunity for the postdoctoral researcher to participate in teaching by giving guest lectures. The PI also participates in a summer climate workshop for high school teachers at Washington State University and the proposed work will enrich that contribution. The extraction device that is built and the expertise gained in using it will be resources for the ice core community and available for future projects. Data will be made available through established national data center and the equipment designs will also be made available to other researchers.
This Small Grant for Exploratory Research supports measurement of PGE abundances and Hf, Nd, Sr and Pb isotopic ratios of the Basement Sill and Dais Intrusion lobe of the Ferrar Magmatic Province, Antarctica. This province played a key role in the breakup of Gondwanaland. Models to be tested are magma production by plume activity versus decompression melting in a fossil subduction zone. The PGE data will also be used to evaluate the behavior of volatiles during magma crystallization, which other evidence indicates may have reached saturation. The samples to be studied were collected during the NSF-sponsored, Magmatic Field Laboratory Workshop held in Antarctica in 2005. This study's results will be compliled with complementary data from other attendees to develop a new multidisciplinary model of Ferrar magmatism.<br/><br/>The broader impacts fo this work include international collaboration and informal science education through public outreach to K12 students.
This award is for support for a program to reconstruct records of the isotopic composition of paleoatmospheric methane and nitrous oxide covering the last 200,000 years. High resolution measurements of the carbon-13 isotopic composition of methane from shallow ice cores will help to determine the relative contributions of biogenic (wetlands, rice fields and ruminants) and abiogenic (biomass burning and natural gas) methane emissions which have caused the concentrations of this gas to increase at an exponential rate during the anthropogenic period. Isotopic data on methane and nitrous oxide over glacial/interglacial timescales will help determine the underlying cause of the large concentration variations that are known to occur. This project will make use of a new generation mass spectrometer which is capable of generating precise isotopic information on nanomolar quantities of methane and nitrous oxide, which means that samples can be 1000 times smaller than those needed for a standard isotope ratio instrument. The primary objective of the work is to further our understanding of the biogeochemical cycles of these two greenhouse gases throughout the anthropogenic period as well as over glacial interglacial timescales.
This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports an interdisciplinary study of fluvial sediments in Antarctica for evidence of what caused the greatest of all mass extinctions in the history of life at the Permian-Triassic boundary. This boundary was, until recently, difficult to locate and thought to be unequivocally disconformable in Antarctica. New studies, particularly of carbon isotopic chemostratigraphy and of paleosols and root traces as paleoecosystem indicators, together with improved fossil plant, reptile and pollen biostratigraphy, now suggest that the precise location of the boundary might be identified and have led to local discovery of iridium anomalies, shocked quartz, and fullerenes with extraterrestrial noble gases. These anomalies are associated with a distinctive claystone breccia bed, similar to strata known in South Africa and Australia, and taken as evidence of deforestation. There is already much evidence from Antarctica and elsewhere that the mass extinction on land was abrupt and synchronous with extinction in the ocean. The problem now is what led to such death and destruction. Carbon isotopic values are so low in these and other Permian-Triassic boundary sections that there was likely to have been some role for catastrophic destabilization of methane clathrates. Getting the modeled amount of methane out of likely reservoirs would require such catastrophic events as bolide impact, flood-basalt eruption or continental-shelf collapse, which have all independently been implicated in the mass extinction and for which there is independent evidence. Teasing apart these various hypotheses requires careful re-examination of beds that appear to represent the Permian-Triassic boundary, and search for more informative sequences, as was the case for the Cretaceous-Tertiary boundary. This collaborative research on geochemistry and petrography of boundary beds and paleosols (by Retallack), on carbon isotopic variation through the boundary interval (by Jahren), and on fullerenes, iridium and helium (by Becker) is designed to test these ideas about the Permian-Triassic boundary in Antarctica and to shed light on processes which contributed to this largest of mass extinctions on Earth. Fieldwork for this research will be conducted in the central Transantarctic Mountains and in Southern Victoria Land with an initial objective of examining the stratigraphic sequences for continuity across the boundary. Stratigraphic continuity is a critical element that must exist for the work to be successful. If fieldwork indicates sufficiently continuous sections, the full analytical program will follow fieldwork.
This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.
The summit crater of Mt. Moulton, in West Antarctica, contains a 600-m thick horizontally-exposed section of ice with intercalated tephra layers from nearby Mt Berlin. Argon-40/Argon-39 dating of the thick, near-source tephra indicates that the age of the horizontal ice section ranges between 15,000 and 492,000 years. Thus, the Mt Moulton site offers an unparalleled repository of ancient West Antarctic snow and trapped air that can be used to investigate West Antarctic climate over much of the past 500,000 years. The planar nature and consistent dips of the tephra layers suggests that, although the ice section has thinned, it is otherwise undeformed. The Mt. Moulton site was visited during the 1999/2000 field season, at which time a horizontal ice core representing approximately 400 meters of ice was collected, ranging in age from 15,000 to older than 480,000 years. In addition to this horizontal core, samples of ice at a range of depths were collected in order to test the quality of the climate record in the ice. Forty tephra layers intercalated in the ice were also collected in order to provide chronology for the ice section. The results of this first effort are extremely encouraging. Based on the d?18 O of ice, for example, there is clearly a useable record of past climate at Mt. Moulton extending back beyond 140,000 years. There is work to do, however, to realize the full potential of this horizontal ice core. The elemental and isotopic composition of trapped gases suggest some contamination with modern air, for example. As gas cross-dating of ice cores is the current standard by which climate records are intercompared, we need to understand why and how the gas record is compromised before adding Moulton to our arsenal of ice core paleoclimate records. This award supports a collaborative effort between three institutions with following objectives: 1) to evaluate more thoroughly the integrity of the climatic record through shallow drilling of the blue ice area, as well as the snow field upslope from the blue ice; 2) to improve the radioisotopic dating of specific tephra layers; 3) to obtain baseline information about modern snowfall deposition, mean annual temperature, and wind pumping around the summit of Mt. Moulton; and 4) to study how firn densification differs when surface accumulation changes from net accumulation to net ablation.
This award supports a detailed laboratory analysis of the mass-independent isotopic composition of processes associated with atmospheric nitrate trapped in the snow pack at the South Pole. The project will specifically test if the oxygen isotopes 16O, 17O, 18O of nitrate can be used to probe the denitrification of the Antarctic stratosphere. Despite decades of research, there are several important issues in Antarctic atmospheric science, which are presently inadequately resolved. This includes quantification over time of the sources of nitrate aerosols. Today, little is known about the past denitrification of the stratosphere in high latitude regions. This lack of knowledge significantly limits our ability to understand the chemical state of ancient atmospheres and therefore evaluate present and past-coupled climate/atmosphere models. The role of nitrogen in environmental degradation is well known. This issue will also be addressed in this proposal. Atmospheric aerosols have now been shown to possess a mass-independent oxygen isotopic content. The proposed research will investigate the stable oxygen isotope ratios of nitrate in Antarctica both collected in real time and from the snow. Two periods of time will be covered. Full year nitrate aerosol collections, with week resolution time horizons, will be performed at the South Pole. Weekly aerosol collections will help us to identify any seasonal trend of the oxygen-17 excess anomaly, and eventually link this anomaly to the denitrification of the Antarctic stratosphere. This data set will also be used to test our assumption that the oxygen isotopic anomaly of nitrate is mainly formed in the stratosphere and is well preserved in the snow pack. If true, we will for the first time resolve an atmospheric signal extracted from a nitrate profile. The snow pit will allow us to see any trend in the data on a multiple decade timescale.
0125981<br/>Sowers<br/><br/>This award supports a project to construct an isotopic record of atmospheric methane and nitrous oxide over the last century from South Pole firn air. Over the last 150 years, atmospheric methane and nitrous oxide concentrations have risen in response to increased emissions from various anthropogenic activities. As this trend is liable to continue in the foreseeable future, it is important to understand the biogeochemical processes that contribute to the emissions of these two greenhouse gases. In this context, records of the variations in the atmospheric loading of trace gases found in ice cores and interstitial spaces in the snow near the surface of the ice sheet (firn air) provide fundamental boundary conditions for reconstructing historical emission records. One way to improve our understanding of the cycling of bioactive trace gases and their emission records is to use stable isotope tracers, which have been recorded in the ice cores and firn air. This project will develop records of carbon-13 and deuterium isotope ratios of methane, as well as the nitrogen-15, oxygen-18 and the isotopomer composition of nitrous oxide trapped in firn air samples collected in January 2001 at the South Pole. These measurements will allow isotopic records of these atmospheric gases to be reconstructed throughout the 20th century. Such records will help to establish the relative contribution of individual sources with a higher degree of confidence than is currently available.
Roy, Martin; Hemming, Sidney R.; Goldstein, Steven L.; Van De Flierdt, Christina-Maria
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This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a project to investigate the sediment core from the Southern Ocean for paleoenvironmental research. The polar regions are susceptible to the largest changes in climate and are among the least accessible places on Earth. Current concern about the instability of the West Antarctic Ice Sheet has heightened awareness of the vulnerability of polar regions. This proposal seeks to gain a basic understanding of the isotopic characteristics of terrigenous sediment sources derived from Antarctica in the Holocene and Last Glacial Maximum, and their dispersal into the Southern Ocean. Terrigenous clastic sediments are brought to the ocean from continental sources via rivers, ice and wind, and distributed within the ocean by surface and deep currents. At present there are virtually no isotopic data on circumpolar detritus, save a few strontium (Sr) isotopic ratios in the Atlantic sector. This project will fill part of this gap. From the large range in geological ages of crustal provinces of Antarctica, we would predict that there are large isotopic differences in detritus around the continent. The main objectives are to (1) characterize the strontium-neodymium-lead-argon (Sr-Nd-Pb-Ar) isotope compositions of sediment sources derived from Antarctica, (2) to identify the composition and source ages of major ice rafted detritus (IRD) contributions by analyzing individual grains of hornblende and feldspar in conjunction with bulk isotopic analysis, and (3) track sediment dispersal into the Antarctic Circumpolar Current (ACC) during the Holocene and Last Glacial Maximum.<br/><br/>Because of the paucity of circumpolar data, this research necessarily has a large exploratory component. Consequently, it will provide a basic database for future studies. Nevertheless there are important hypothesis-driven questions that will be addressed in this primary pass. Can lessons learned in North Atlantic IRD studies be applied toward understanding the history of Antarctic ice sheets? Can the large geological variability around the Antarctic margin be treated as a series of natural tracer injections into the ACC, and thus characterize its trajectory, speed, and interaction with other current systems today and in the past? The proposed study is motivated by an exciting set of results from the South Atlantic, showing that detrital Sr isotope ratios are a sensitive current tracer in that region. This research should serve a basic need across many Earth Science disciplines if the use of long-lived radiogenic isotopes (Sr-Nd-Pb-Ar) as tracers of marine sediment sources is successful in elucidating processes related to changing climatic conditions. The results of this study will fill a basic gap in our knowledge of an important region of the Earth. At the same time, it will provide an essential basis for attempting reconstruction of the ACC during the LGM, as well as for future studies of Antarctic geology, ice sheet history, and the Southern Ocean circulation.
This award is for support for a program to make high resolution studies of variations in the concentration of methane, the oxygenisotope composition of paleoatmospheric oxygen, and the total gas content of deep Antarctic ice cores. Studies of the concentration and isotopic composition of air in the firn of the Antarctic ice sheet will also be continued. One objective of this work is to use the methane concentration and oxygen-isotope composition of oxygen of air in ice as time-stratigraphic markers for the precise intercorrelation of Greenland and Antarctic ice cores as well as the correlation of ice cores to other climatic records. A second objective is to use variations in the concentration and interhemispheric gradient of methane measured in Greenland and Antarctic ice cores to deduce changes in continental climates and biogeochemistry on which the atmospheric methane distribution depends. A third objective is to use data on the variability of total gas content in the Siple Dome ice core to reconstruct aspects of the glacial history of West Antarctica during the last glacial maximum. The fourth objective is to participate in collaborative studies of firn air chemistry at Vostok, Siple Dome, and South Pole which will yield much new information about gas trapping in ice as well as the concentration history and isotopic composition of greenhouse gases, oxygen, trace biogenic gases and trace anthropogenic gases during the last 100 years.
0087380<br/>Alley<br/><br/>This award provides three years of support to use a broad, adaptable, multi-parameter approach, using a range of techniques including artificial neural networks to seek the relations between meteorological conditions and the snow pit and ice core records they produce. Multi-parameter, high resolution, ice core data already in hand or now being collected reflect snow accumulation, atmospheric chemistry, isotopic fractionation, and other processes, often with subannual resolution. The West Antarctic sites from which such data are available will be used as starting points for back-trajectory analyses in reanalysis data products to determine the meteorological conditions feeding the data stream. The artificial neural nets will then be used to look for optimal relations between these meteorological conditions and their products. Previous work has demonstrated the value of reanalysis products in determining snow accumulation, of back trajectory analyses in understanding glaciochemistry, and of artificial neural nets in linking meteorological conditions and their products. Preliminary work shows that neural nets are successful in downscaling from reanalysis products to automatic weather station data in West Antarctica, enabling interpolation of site-specific data to improve understanding of recent changes in West Antarctic climate.
This award provides one year of support to use newly developed technology in which an ice-core melter is coupled with both an Inductively Coupled Plasma - Mass Spectrometer (ICP-MS) and a traditional Continuous Flow Analysis (CFA) system, to measure a continuous time series of chemical and trace element deposition on the Siple Dome ice core from West Antarctica. A coupled ice-core melter, ICP-MS, and CFA system will be used to measure concentrations of a number of elements, isotopes and chemical species at very high depth resolution (~2-cm) in the top 54 m of the Siple Dome A-core. Pilot data from analyses of ~6 m from the nearby but much lower accumulation J-core site at Siple Dome, together with more extensive results from Summit, Greenland, indicate that it will be possible to obtain exactly co-registered, high-quality records of at least 12 seasonally varying elements (sodium, magnesium, aluminum, potassium, calcium, iron, manganese, rubidium, strontium, zirconium, barium, lead) and three other chemical species and ions (ammonium, nitrate, calcium ion) with this system. Under this proposed research, we will also add continuous measurements of sulfate to our system. Because more than sufficient core from Siple Dome for these depths is archived at the National Ice Core Laboratory, the proposed research will require no fieldwork. The continuous, very high-resolution, ~350-y record of these elemental tracers will enhance the value of previous chemical and isotopic measurements that have been made on the Siple Dome core and will be particularly valuable for comparisons between ice-core proxies and modern instrumental data related to El Nino-Southern Oscillation (ENSO) as well as for validation of model simulations of atmospheric circulation. These data, and the expertise gained through this research, will be invaluable when this novel chemical analysis technology is eventually applied to deep ice-core records for the study of rapid climate-change events.
Subduction zones are the one place on Earth where materials from the surface (water, sediments and crustal rocks) can be carried into our planet's deep interior. To quantify this process of subduction-zone recycling, we need to understand both the input of sediments and crust to trenches, and all geochemical outputs related to the subduction process. While the chemical outputs represented by magmatism at volcanic arcs and in back-arc settings have been widely studied, little is known about possible subduction-related outfluxes through the shallow forearc, between the arc and the trench. We are attempting to characterize the "forearc flux" by examining serpentinites which are rising diapirically through the forearc mantle and crust in the Mariana arc-trench system. Our work will complete efforts begun (with NSF support) several years ago, and will characterize these samples (and the slab-derived fluids which helped to create them) for radiogenic isotopes, lithium and oxygen isotopes, and the "fluid-mobile" elements Cs, Rb, U, As, Pb, and Sb. Our work will allow us to characterize both the chemical inventories of species that are released from subducting slabs beneath forearcs, and the magnitude of this flux, for comparison with results for trench inputs (being collected as part of ODP Leg 125), and existing data for arc volcanic outputs in the Mariana system.
This award is for support for a program to measure the stable isotope (deuterium to hydrogen and oxygen-18 to oxygen-16) concentrations of ice cores retrieved from Siple Dome as part of the West Antarctic ice sheet program. In addition, the deuterium excess of samples from the Taylor Dome ice core will be determined. This project will approach the question of rapid climate change using ice cores to determine the history of temperature changes, moisture source changes, and elevational changes in the West Antarctic ice sheet. Results from ice cores taken to date in the interior of Antarctica (East and West) are surprisingly lacking in indications of abrupt climate changes, such as those that have been observed in the GISP2 ice core from Summit, Greenland. This work will address the question of whether rapid climate changes, which are known to have occurred in other parts of the southern hemi-sphere, may have also occurred in the coastal regions of West Antarctica. There is some indication from existing records of isotopes in ice cores that the West Antarctic ice sheet may have flushed ice in the past (as evidenced by large changes in elevation of the ice sheet).
This award is for support of a program to reconstruct the record of atmospheric carbon dioxide (and the carbon-13 isotopes of carbon dioxide) over several intervals, including the Last Glacial Maximum-Holocene transition, interstadial episodes, the mid-Holocene, the last 1000 years and the penultimate glacial period, using ice from the Taylor Dome and Vostok ice cores. The major objective of this study is to investigate the phase relationship between variations of the greenhouse gases occluded in the ice cores and temperature changes (indicated by oxygen and deuterium isotopes) during the last deglaciation. In addition, the concentration of atmospheric carbon dioxide over the past 1000 years and during the mid-Holocene will be determined in these cores.
This award supports an in situ and short traverse seismic reflection/refraction and magnetotelluric experiment in West Antarctica. This collaborative experiment involves four awards at four institutions. The four-fold purpose is 1) to investigate part of the Byrd Subglacial Basin, 2) to test techniques for this work that could be done in a long traverse, 3) to determine the viability of the magnetotelluric method on a thick (electrically resistive) ice sheet, and 4) to evaluate the relative merits of refraction with wide reflection versus reflection with narrow refraction seismic studies in imaging the lithosphere. The geophysical techniques that will be employed are capable of imaging the ice sheet, the continental lithosphere, and the upper mantle, as well as determining physical properties of parts of the lithosphere and mantle. Investigations of outcrop geology over the last thirty years in West Antarctica and the Transantarctic Mountains have lead to recent interpretations that the crust is made up of many different lithospheric blocks. Seismic reflection work is the only way to image the crust in detail and the refraction work is the only way to determine physical properties of the layers and blocks defined by the reflection work. The magnetotelluric work is scientifically risky because it may not yield useful information when used over the electrically resistive ice sheet; however, if it works it has the potential to image molten rock in the crust and upper mantle. In a continental rift region such as West Antarctica, the presence of melt in the lithosphere is likely and, if documented, has very important ramifications to ice sheet dynamics. Research work supported by this award is expected to provide constraints to models of a range of crustal processes from models of ice sheet dynamics to tectonic and kinematic models of lithospheric thinning and rifting.
9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period).