USAP-DC

{"dp_type": "Project", "free_text": "Mass Spectrometry"}

[{"awards": "1745078 Brook, Edward", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "datasets": [{"dataset_uid": "601683", "doi": "10.15784/601683", "keywords": "Antarctica; Cryosphere; Methane; West Antarctic Ice Sheet", "people": "Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601683"}], "date_created": "Mon, 01 May 2023 00:00:00 GMT", "description": "This project will develop methods to measure the ratios of carbon-13 to carbon-12, and heavy to light hydrogen in methane in air trapped in ice cores. The ratios of the different forms of carbon and hydrogen are \"fingerprints\" of different sources of this gas in the past--for example wetlands in the tropics versus methane frozen in the sea floor. Once the analysis method is developed, the measurements will be used to examine why methane changed abruptly in the past, both during the last ice age, and during previous warm periods. The data will be used to understand how methane sources like wildfires, methane hydrates, and wetlands respond to climate change. This information is needed to understand future risks of large changes in methane in the atmosphere as Earth warms. \u003cbr/\u003e\u003cbr/\u003eThe project involves two tasks. First, the investigators will build and test a gas extraction system for methane isotopic measurements using continuous flow methods, with the goal of equaling or bettering the precision attained by the few other laboratories that make these measurements. The system will be interfaced with existing mass spectrometers at Oregon State University. The system consists of a vacuum chamber and sequence of traps, purification columns, and furnaces that separate methane from other gases and convert it to carbon dioxide or hydrogen for mass spectrometry. Second, the team will measure the isotopic composition of methane across large changes in concentration associated with two past interglacial periods and during abrupt methane changes of the last ice age. These measurements will be used to understand if the main reason for these concentration changes is climate-driven changes in emissions from wetlands, or whether other sources are involved, for example methane hydrates or wildfires.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Antarctic Ice Sheet; METHANE; TRACE GASES/TRACE SPECIES", "locations": "Antarctic Ice Sheet", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Tracing Past Methane Variations with Stable Isotopes in Antarctic Ice Cores", "uid": "p0010416", "west": -180.0}, {"awards": "1644234 Phillips, Fred", "bounds_geometry": "POLYGON((166.17 -77.3,166.32799999999997 -77.3,166.486 -77.3,166.644 -77.3,166.802 -77.3,166.95999999999998 -77.3,167.118 -77.3,167.276 -77.3,167.434 -77.3,167.59199999999998 -77.3,167.75 -77.3,167.75 -77.34,167.75 -77.38,167.75 -77.42,167.75 -77.46,167.75 -77.5,167.75 -77.54,167.75 -77.58,167.75 -77.62,167.75 -77.66,167.75 -77.7,167.59199999999998 -77.7,167.434 -77.7,167.276 -77.7,167.118 -77.7,166.95999999999998 -77.7,166.802 -77.7,166.644 -77.7,166.486 -77.7,166.32799999999997 -77.7,166.17 -77.7,166.17 -77.66,166.17 -77.62,166.17 -77.58,166.17 -77.54,166.17 -77.5,166.17 -77.46,166.17 -77.42,166.17 -77.38,166.17 -77.34,166.17 -77.3))", "dataset_titles": null, "datasets": null, "date_created": "Mon, 12 Dec 2022 00:00:00 GMT", "description": "Nontechnical Description: The age of rocks and soils at the surface of the Earth can help answer multiple questions that are important for human welfare, including: when did volcanoes erupt and are they likely to erupt again? when did glaciers advance and what do they tell us about climate? what is the frequency of hazards such as landslides, floods, and debris flows? how long does it take soils to form and is erosion of soils going to make farming unsustainable? One method that is used thousands of times every year to address these questions is called \u0027cosmogenic surface-exposure dating\u0027. This method takes advantage of cosmic rays, which are powerful protons and neutrons produced by supernova that constantly bombard the Earth\u0027s atmosphere. Some cosmic rays reach Earth\u0027s surface and produce nuclear reactions that result in rare isotopes. Measuring the quantity of the rare isotopes enables the length of time that the rock or soil has been exposed to the atmosphere to be calculated. The distribution of cosmic rays around the globe depends on Earth\u0027s magnetic field, and this distribution must be accurately known if useful exposure ages are to be obtained. Currently there are two remaining theories, narrowed down from many, of how to calculate this distribution. Measurements from a site that is at both high altitude and high latitude (close to the poles) are needed to test the two theories. This study involves both field and lab research and includes a Ph.D. student and an undergraduate student. The research team will collect rocks from lava flows on an active volcano in Antarctica named Mount Erebus and measure the amounts of two rare isotopes: 36Cl and 3He. The age of eruption of the samples will be determined using a highly accurate method that does not depend on cosmic rays, called 40Ar/39Ar dating. The two cosmic-ray theories will be used to calculate the ages of the samples using the 36Cl and 3He concentrations and will then be compared to the ages calculated from the 40Ar/39Ar dating. The accurate cosmic-ray theory will be the one that gives the same ages as the 40Ar/39Ar dating. Identification of the accurate theory will enable use of the cosmogenic surface dating methods anywhere on earth. \u003cbr/\u003eTechnical Description: Nuclides produced by cosmic rays in rocks at the surface of the earth are widely used for Quaternary geochronology and geomorphic studies and their use is increasing every year. The recently completed CRONUS-Earth Project (Cosmic-Ray Produced Nuclides on Earth) has systematically evaluated the production rates and theoretical underpinnings of cosmogenic nuclides. However, the CRONUS-Earth Project was not able to discriminate between the two leading theoretical approaches: the original Lal model (St) and the new Lifton-Sato-Dunai model (LSD). Mathematical models used to scale the production of the nuclides as a function of location on the earth, elevation, and magnetic field configuration are an essential component of this dating method. The inability to distinguish between the two models was because the predicted production rates did not differ sufficiently at the location of the calibration sites. \u003cbr/\u003e\u003cbr/\u003eThe cosmogenic-nuclide production rates that are predicted by the two models differ significantly from each other at Erebus volcano, Antarctica. Mount Erebus is therefore an excellent site for testing which production model best describes actual cosmogenic-nuclide production variations over the globe. The research team recently measured 3He and 36Cl in mineral separates extracted from Erebus lava flows. The exposure ages for each nuclide were reproducible within each flow (~2% standard deviation) and in very good agreement between the 3He and the 36Cl ages. However, the ages calculated by the St and LSD scaling methods differ by ~15-25% due to the sensitivity of the production rate to the scaling at this latitude and elevation. These results lend confidence that Erebus qualifies as a suitable high- latitude/high-elevation calibration site. The remaining component that is still lacking is accurate and reliable independent (i.e., non-cosmogenic) ages, however, published 40Ar/39Ar ages are too imprecise and typically biased to older ages due to excess argon contained in melt inclusions.\u003cbr/\u003eThe research team\u0027s new 40Ar/39Ar data show that previous problems with Erebus anorthoclase geochronology are now overcome with modern mass spectrometry and better sample preparation. This indicates a high likelihood of success for this proposal in defining an accurate global scaling model. Although encouraging, much remains to be accomplished. This project will sample lava flows over 3 km in elevation and determine their 40Ar/39Ar and exposure ages. These combined data will discriminate between the two scaling methods, resulting in a preferred scaling model for global cosmogenic geochronology. The LSD method contains two sub-methods, the \u0027plain\u0027 LSD scales all nuclides the same, whereas LSDn scales each nuclide individually. The project can discriminate between these models using 3He and 36Cl data from lava flows at different elevations, because the first model predicts that the production ratio for these two nuclides will be invariant with elevation and the second that there should be ~10% difference over the range of elevations to be sampled. Finally, the project will provide a local, finite-age calibration site for cosmogenic-nuclide investigations in Antarctica.", "east": 167.75, "geometry": "POINT(166.95999999999998 -77.5)", "instruments": null, "is_usap_dc": true, "keywords": "VOLCANO; AGE DETERMINATIONS; Mount Erebus", "locations": "Mount Erebus", "north": -77.3, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Phillips, Fred; Kyle, Philip; Heizler, Matthew T", "platforms": null, "repositories": null, "science_programs": null, "south": -77.7, "title": "A Test of Global and Antarctic Models for Cosmogenic-nuclide Production Rates using High-precision Dating of 40Ar/39Ar Lava Flows from Mount Erebus", "uid": "p0010397", "west": 166.17}, {"awards": "0944150 Hall, Brenda", "bounds_geometry": "POLYGON((163.6 -77.5,163.7 -77.5,163.8 -77.5,163.9 -77.5,164 -77.5,164.1 -77.5,164.2 -77.5,164.3 -77.5,164.4 -77.5,164.5 -77.5,164.6 -77.5,164.6 -77.57,164.6 -77.64,164.6 -77.71,164.6 -77.78,164.6 -77.85,164.6 -77.92,164.6 -77.99,164.6 -78.06,164.6 -78.13,164.6 -78.2,164.5 -78.2,164.4 -78.2,164.3 -78.2,164.2 -78.2,164.1 -78.2,164 -78.2,163.9 -78.2,163.8 -78.2,163.7 -78.2,163.6 -78.2,163.6 -78.13,163.6 -78.06,163.6 -77.99,163.6 -77.92,163.6 -77.85,163.6 -77.78,163.6 -77.71,163.6 -77.64,163.6 -77.57,163.6 -77.5))", "dataset_titles": "Marshall Valley Radiocarbon Data; Marshall Valley U-Series Data; Royal Society Range Headland Moraine Belt Radiocarbon Data; Salmon Valley Radiocarbon Data", "datasets": [{"dataset_uid": "601529", "doi": "10.15784/601529", "keywords": "Algae; Antarctica; Cryosphere; Glaciers/Ice Sheet; Marshall Valley; Radiocarbon; Ross Sea Drift; Royal Society Range", "people": "Hall, Brenda", "repository": "USAP-DC", "science_program": null, "title": "Marshall Valley Radiocarbon Data", "url": "https://www.usap-dc.org/view/dataset/601529"}, {"dataset_uid": "601528", "doi": "10.15784/601528", "keywords": "234U/230Th Dating; Antarctica; Cryosphere; Glaciers/Ice Sheet; Glaciology; Last Glacial Maximum; Marshall Drift; Marshall Valley; MIS 6; Royal Society Range", "people": "Hall, Brenda", "repository": "USAP-DC", "science_program": null, "title": "Marshall Valley U-Series Data", "url": "https://www.usap-dc.org/view/dataset/601528"}, {"dataset_uid": "601556", "doi": "10.15784/601556", "keywords": "Antarctica; Cryosphere; Last Glacial Maximum; McMurdo Sound; Radiocarbon Dates; Ross Sea Drift; Royal Society Range", "people": "Hall, Brenda", "repository": "USAP-DC", "science_program": null, "title": "Salmon Valley Radiocarbon Data", "url": "https://www.usap-dc.org/view/dataset/601556"}, {"dataset_uid": "601555", "doi": "10.15784/601555", "keywords": "Antarctica; Cryosphere; Last Glacial Maximum; McMurdo Sound; Radiocarbon Dates; Ross Sea Drift; Royal Society Range", "people": "Hall, Brenda", "repository": "USAP-DC", "science_program": null, "title": "Royal Society Range Headland Moraine Belt Radiocarbon Data", "url": "https://www.usap-dc.org/view/dataset/601555"}], "date_created": "Thu, 03 Mar 2022 00:00:00 GMT", "description": "This award supports a project to investigate the sensitivity of the Antarctic ice sheet (AIS) to global climate change over the last two Glacial/Interglacial cycles. The intellectual merit of the project is that despite its importance to Earth\u0027s climate system, we currently lack a full understanding of AIS sensitivity to global climate change. This project will reconstruct and precisely date the history of marine-based ice in the Ross Sea sector over the last two glacial/interglacial cycles, which will enable a better understanding of the potential driving mechanisms (i.e., sea-level rise, ice dynamics, ocean temperature variations) for ice fluctuations. This will also help to place present ice?]sheet behavior in a long-term context. During the last glacial maximum (LGM), the AIS is known to have filled the Ross Embayment and although much has been done both in the marine and terrestrial settings to constrain its extent, the chronology of the ice sheet, particularly the timing and duration of the maximum and the pattern of initial recession, remains uncertain. In addition, virtually nothing is known of the penultimate glaciation, other than it is presumed to have been generally similar to the LGM. These shortcomings greatly limit our ability to understand AIS evolution and the driving mechanisms behind ice sheet fluctuations. This project will develop a detailed record of ice extent and chronology in the western Ross Embayment for not only the LGM, but also for the penultimate glaciation (Stage 6), from well-dated glacial geologic data in the Royal Society Range. Chronology will come primarily from high-precision Accelerator Mass Spectrometry (AMS) Carbon-14 (14C) and multi-collector Inductively Coupled Plasma (ICP)-Mass Spectrometry (MS) 234Uranium/230Thorium dating of lake algae and carbonates known to be widespread in the proposed field area. ", "east": 164.6, "geometry": "POINT(164.1 -77.85)", "instruments": null, "is_usap_dc": true, "keywords": "USAP-DC; LABORATORY; AMD; AMD/US; USA/NSF; Royal Society Range; GLACIER ELEVATION/ICE SHEET ELEVATION; GLACIAL LANDFORMS", "locations": "Royal Society Range", "north": -77.5, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Hall, Brenda; Denton, George", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -78.2, "title": "Sensitivity of the Antarctic Ice Sheet to Climate Change over the Last Two Glacial/Interglacial Cycles", "uid": "p0010302", "west": 163.6}, {"awards": "1644128 Welten, Kees; 1644094 Caffee, Marc", "bounds_geometry": "POINT(-112.12 -79.48)", "dataset_titles": "WAIS Divide Core 10Be data, 2850-3240 m", "datasets": [{"dataset_uid": "601692", "doi": "10.15784/601692", "keywords": "10Be; Antarctica; Beryllium; Cosmogenic Radionuclides; Cryosphere; Ice Core Data; WAIS divide", "people": "Woodruff, Thomas; Caffee, Marc; Welten, Kees", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Core 10Be data, 2850-3240 m", "url": "https://www.usap-dc.org/view/dataset/601692"}], "date_created": "Mon, 15 Nov 2021 00:00:00 GMT", "description": "The award supports a project to use existing samples from the West Antarctic Ice Sheet (WAIS) Divide ice core to align its timescale with that of the Greenland ice cores using common chronological markers. The upper 2850 m of the WAIS Divide core, which was drilled to a depth of 3405 m, has been dated with high precision. The timescale of the remaining (bottom) 550 m of the core has larger uncertainties, limiting our understanding of the timing of abrupt climate events in Antarctica relative to those in Greenland during the last ice age. The intellectual merit of this project is to further constrain the relative timing of these abrupt climate events in Greenland and Antarctica to obtain crucial insight into the underlying mechanism. The main objective of this project is to improve the current timescale of the WAIS Divide core from 31,000 to 65,000 years ago by synchronizing this core with the Greenland ice cores using common signals in Beryllium-10, a radioactive isotope of Be that is produced in the atmosphere by cosmic rays and is deposited onto the snow within 1-2 years of its production. The 10Be flux is largely independent of climate signals since its production varies with solar activity and the geomagnetic field. This project will further strengthen collaborations between the PI\u2019s in Berkeley and Purdue with ice core researchers in the US and Europe, involve undergraduate students in many aspects of its research, and continue out-reach to under-represented students.\r\n\r\nThe direct ice-to-ice synchronization of the WAIS Divide ice core with the Greenland Ice Core Chronology (GICC05) using cosmogenic 10Be is expected to reduce the uncertainty in the relative timing of more than 20 abrupt climate events in Greenland and Antarctica to a few decades. To achieve this goal we will obtain a continuous high-resolution record of 10Be in the WAIS Divide core from 2850 to 3390 m depth, and compare the obtained 10Be record with existing 10Be records of the Greenland ice cores, including GISP2 and NGRIP. We will separate 10Be from ~1000 ice samples of the WAIS Divide core and measure the 10Be concentration in each sample using accelerator mass spectrometry (AMS). Broader impacts of the 10Be measurements are that they will also provide information on the Laschamp event, a ~2000 year long period of low geomagnetic field strength around 41,000 years ago, and improve the calibration of the 14C dating method for organic samples older than 30,000 years. The broader impacts of the project include (1) the involvement and training of undergraduate students in ice core research and accelerator mass spectrometry measurements, (2) the incorporation of ice core and climate research into ongoing outreach programs at Purdue University and Berkeley SSL, (3) better understanding of abrupt climate changes in the past will improve our ability to predict future climate change, (4) evaluating the possible threat of a future geomagnetic excursion in the next few hundred years. This award does not require support in Antarctica.\r\n", "east": -112.12, "geometry": "POINT(-112.12 -79.48)", "instruments": null, "is_usap_dc": true, "keywords": "WAIS divide; USA/NSF; AMD; USAP-DC; DEPTH AT SPECIFIC AGES; LABORATORY; AMD/US", "locations": "WAIS divide", "north": -79.48, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Welten, Kees; Caffee, Marc", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.48, "title": "Synchronizing the WAIS Divide and Greenland Ice Cores from 30-65 ka BP using high-resolution 10Be measurements", "uid": "p0010280", "west": -112.12}, {"awards": "1543328 Van Mooy, Benjamin", "bounds_geometry": null, "dataset_titles": "Lipidomics of Antarctic waters. (TBD)", "datasets": [{"dataset_uid": "200149", "doi": "TBD", "keywords": null, "people": null, "repository": "BCO-DMO", "science_program": null, "title": "Lipidomics of Antarctic waters. (TBD)", "url": "https://www.bco-dmo.org/data"}], "date_created": "Fri, 19 Jun 2020 00:00:00 GMT", "description": "The depletion of stratospheric ozone over Antarctica leads to abnormally high levels of ultraviolet radiation (UVR) from the sun reaching the surface of the ocean. This phenomenon is predicted to continue for the next half century, despite bans on ozone-destroying pollutants. Phytoplankton in the near surface ocean are subjected to variable amounts of UVR and contain a lot of lipids (fats). Because phytoplankton are at the base of the food chain their lipids makes their way into the Antarctic marine ecosystem\u0027s food web. The molecular structures of phytoplankton lipids are easily altered by UVR. When this happens, their lipids can be transformed from healthy molecules into potentially harmful molecules(oxylipins) known to be disruptive to reproductive and developmental processes. This project will use state-of-the-art molecular methods to answer questions about extent to which UVR damages lipid molecules in phytoplankton, and how these resultant molecules might effect the food chain in the ocean near Antarctica. \u003cbr/\u003e\u003cbr/\u003e\u003cbr/\u003eLipid peroxidation is often invoked as consequence of increased exposure of phytoplankton to UVR-produced reactive oxygen species (ROS), but the literature is practically silent on peroxidized lipids and their byproducts (i.e. oxylipins) in the ocean. In waters of the West Antarctic Peninsula (WAP), spring-time blooms of diatoms contribute significantly to overall marine primary production. Oxylipins from diatoms can be highly bioactive; their impact on zooplankton grazers, bacteria, and other phytoplankton has been the subject of intense study. However, almost all of this work has focused on the production of oxylipins via enzymatic pathways, not by pathways involving UVR and/or ROS. Furthermore, rigorous experimental work on the effects of oxylipins has been confined almost exclusively to pure cultures and artificial communities. Thus, the true potential of these molecules to disrupt carbon cycling is very poorly-constrained, and is entirely unknown in the waters of the WAP. Armed with new highly-sensitive, state-of-the-art analytical techniques based on high-mass-resolution mass spectrometry, the principal investigator and his research group have begun to uncover an exquisite diversity of oxylipins in natural WAP planktonic communities. These techniques will be applied to understand the connections between UVR, ROS, oxylipins, and carbon cycling. The project will answer the question of how UVR, via ROS, affects oxylipin production by diatoms in WAP surface waters in controlled experiments conducted at a field station. With the answer to this question in hand, the project will also seek to answer how this phenomenon impacts the flow of carbon, particularly the export of organic carbon from the system, during a research cruise. The level of UVR-induced stresses experienced by oxylipin-rich planktonic communities in the WAP is unique, making Antarctica the only location for answering these fundamental questions. Major activities will include laboratory experiments with artificial membranes and diatom cultures, as well field experiments with phytoplankton, zooplankton, and bacteria in WAP waters.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "Oxylipins; USAP-DC; Palmer Station; West Antarctic Shelf; NOT APPLICABLE; AQUATIC SCIENCES; Phytoplankton ; UV Radiation", "locations": "West Antarctic Shelf; Palmer Station", "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Van Mooy, Benjamin", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "BCO-DMO", "repositories": "BCO-DMO", "science_programs": null, "south": null, "title": "Production and Fate of Oxylipins in Waters of the Western Antarctic Peninsula: Linkages Between UV Radiation, Lipid Peroxidation, and Carbon Cycling", "uid": "p0010109", "west": null}, {"awards": "1644013 Gaetani, Glenn; 1644027 Wallace, Paul; 1644020 Sims, Kenneth W.", "bounds_geometry": "POLYGON((164.1 -77.1,164.65 -77.1,165.2 -77.1,165.75 -77.1,166.3 -77.1,166.85 -77.1,167.4 -77.1,167.95 -77.1,168.5 -77.1,169.05 -77.1,169.6 -77.1,169.6 -77.235,169.6 -77.37,169.6 -77.505,169.6 -77.64,169.6 -77.775,169.6 -77.91,169.6 -78.045,169.6 -78.18,169.6 -78.315,169.6 -78.45,169.05 -78.45,168.5 -78.45,167.95 -78.45,167.4 -78.45,166.85 -78.45,166.3 -78.45,165.75 -78.45,165.2 -78.45,164.65 -78.45,164.1 -78.45,164.1 -78.315,164.1 -78.18,164.1 -78.045,164.1 -77.91,164.1 -77.775,164.1 -77.64,164.1 -77.505,164.1 -77.37,164.1 -77.235,164.1 -77.1))", "dataset_titles": "G170 Electron Microprobe Analyses of Melt Inclusions and Host Olivines; G170 Raman Spectroscopy \u0026 Tomography Volumes of Melt Inclusions and Vapor Bubbles; G170 Sample Locations Ross Island \u0026 Discovery Province; G170 Secondary Ion Mass Spectrometry Analses of Melt Inclusion Volatiles; G170 Secondary Ion Mass Spectrometry Analyses of Melt Inclusion Hydrogen Isotopes; Location and Description of Tephra Samples from the Erebus and Discovery Sub-provinces", "datasets": [{"dataset_uid": "601250", "doi": "10.15784/601250", "keywords": "Antarctica; Hut Point Peninsula; Mt. Bird; Mt. Morning; Mt. Terror; Ross Island; Turks Head; Turtle Rock", "people": "Gaetani, Glenn; Pamukcu, Ayla", "repository": "USAP-DC", "science_program": null, "title": "Location and Description of Tephra Samples from the Erebus and Discovery Sub-provinces", "url": "https://www.usap-dc.org/view/dataset/601250"}, {"dataset_uid": "601504", "doi": "10.15784/601504", "keywords": "Antarctica; Cryosphere; Ross Island; Sample/Collection Description; Sample Location", "people": "Gaetani, Glenn", "repository": "USAP-DC", "science_program": null, "title": "G170 Sample Locations Ross Island \u0026 Discovery Province", "url": "https://www.usap-dc.org/view/dataset/601504"}, {"dataset_uid": "601505", "doi": "10.15784/601505", "keywords": "Antarctica; Chemistry:Rock; Cryosphere; Electron Microprobe Analyses; Olivine; Petrography; Ross Island", "people": "Gaetani, Glenn", "repository": "USAP-DC", "science_program": null, "title": "G170 Electron Microprobe Analyses of Melt Inclusions and Host Olivines", "url": "https://www.usap-dc.org/view/dataset/601505"}, {"dataset_uid": "601506", "doi": "10.15784/601506", "keywords": "Antarctica; Cryosphere; Ion Mass Spectrometry; Ross Island; Volatiles", "people": "Gaetani, Glenn", "repository": "USAP-DC", "science_program": null, "title": "G170 Secondary Ion Mass Spectrometry Analses of Melt Inclusion Volatiles", "url": "https://www.usap-dc.org/view/dataset/601506"}, {"dataset_uid": "601507", "doi": "10.15784/601507", "keywords": "Antarctica; Chemistry:Rock; Cryosphere; Geochemistry; Hydrogen; Ion Mass Spectrometry; Ross Island", "people": "Gaetani, Glenn", "repository": "USAP-DC", "science_program": null, "title": "G170 Secondary Ion Mass Spectrometry Analyses of Melt Inclusion Hydrogen Isotopes", "url": "https://www.usap-dc.org/view/dataset/601507"}, {"dataset_uid": "601508", "doi": "10.15784/601508", "keywords": "Antarctica; Chemistry:Rock; Cryosphere; Geochemistry; Melt Inclusions; Raman Spectroscopy; Ross Island; Vapor Bubbles; Volcanic", "people": "Gaetani, Glenn", "repository": "USAP-DC", "science_program": null, "title": "G170 Raman Spectroscopy \u0026 Tomography Volumes of Melt Inclusions and Vapor Bubbles", "url": "https://www.usap-dc.org/view/dataset/601508"}], "date_created": "Sat, 08 Feb 2020 00:00:00 GMT", "description": "The depths at which magmas are stored, their pre-eruptive volatile contents, and the rates at which they ascend to the Earth\u0027s surface are important controls on the dynamics of volcanic eruptions. Basaltic magmas are likely to be vapor undersaturated as they begin their ascent from the mantle through the crust, but volatile solubility drops with decreasing pressure. Once vapor saturation is achieved and the magma begins to degas, its pre-eruptive volatile content is determined largely by the depth at which it resides within the crust. Magma stored in deeper reservoirs tend to experience less pre-eruptive degassing and to be richer in volatiles than magma shallower reservoirs. Eruptive style is influenced by the rate at which a magma ascends from the reservoir to the surface through its effect on the efficiency of vapor bubble nucleation, growth, and coalescence. The proposed work will advance our understanding of pre-eruptive storage conditions and syn-eruptive ascent rates through a combined field and analytical research program. Volatile measurements from olivine-hosted melt inclusions will be used to systematically investigate magma storage depths and ascent rates associated with alkaline volcanism in the Erebus volcanic province. A central goal of the project is to provide a spatial and temporal framework for interpreting results from studies of present-day volcanic processes at Mt Erebus volcano. The Erebus volcanic province of Antarctica is especially well suited to this type of investigation because: (1) there are many exposed mafic scoria cones, fissure vents, and hyaloclastites (exposed in sea cliffs) that produced rapidly quenched, olivine-rich tephra; (2) existing volatile data for Ross Island MIs show that magma storage was relatively deep compared to many mafic volcanic systems; (3) some of the eruptive centers ejected mantle xenoliths, allowing for comparison of ascent rates for xenolith-bearing and xenolith-free eruptions, and comparison of ascent rates for those bearing xenoliths with times estimated from settling velocities; and (4) the cold, dry conditions in Antarctica result in excellent tephra preservation compared to tropical and even many temperate localities. The project provides new tools for assessing volcanic hazards, facilitates collaboration involving researchers from three different institutions (WHOI, U Wyoming, and U Oregon), supports the researchers\u0027 involvement in teaching, advising, and outreach, and provides an educational opportunity for a promising young postdoctoral researcher. Understanding the interrelationships among magma volatile contents, reservoir depths, and ascent rates is vital for assessing volcanic hazards associated with alkaline volcanism across the globe.\r\n\r\n", "east": 169.6, "geometry": "POINT(166.85 -77.775)", "instruments": null, "is_usap_dc": true, "keywords": "Tephra; Turtle Rock; AMD/US; USA/NSF; AMD; Ross Island; LABORATORY; Turks Head; Hut Point Peninsula; LAVA SPEED/FLOW; USAP-DC; Mt. Morning; Mt. Terror; ROCKS/MINERALS/CRYSTALS; Mt. Bird; FIELD INVESTIGATION", "locations": "Ross Island; Mt. Morning; Mt. Bird; Mt. Terror; Hut Point Peninsula; Turtle Rock; Turks Head", "north": -77.1, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": null, "persons": "Gaetani, Glenn; Le Roux, Veronique; Sims, Kenneth; Wallace, Paul", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -78.45, "title": "Collaborative Research: Determining Magma Storage Depths and Ascent Rates for the Erebus Volcanic Province, Antarctica Using Diffusive Water Loss from Olivine-hosted Melt Inclusion", "uid": "p0010081", "west": 164.1}, {"awards": "1644073 DiTullio, Giacomo; 1643684 Saito, Mak", "bounds_geometry": "POLYGON((-180 -72,-173.6 -72,-167.2 -72,-160.8 -72,-154.4 -72,-148 -72,-141.6 -72,-135.2 -72,-128.8 -72,-122.4 -72,-116 -72,-116 -72.7,-116 -73.4,-116 -74.1,-116 -74.8,-116 -75.5,-116 -76.2,-116 -76.9,-116 -77.6,-116 -78.3,-116 -79,-122.4 -79,-128.8 -79,-135.2 -79,-141.6 -79,-148 -79,-154.4 -79,-160.8 -79,-167.2 -79,-173.6 -79,180 -79,178 -79,176 -79,174 -79,172 -79,170 -79,168 -79,166 -79,164 -79,162 -79,160 -79,160 -78.3,160 -77.6,160 -76.9,160 -76.2,160 -75.5,160 -74.8,160 -74.1,160 -73.4,160 -72.7,160 -72,162 -72,164 -72,166 -72,168 -72,170 -72,172 -72,174 -72,176 -72,178 -72,-180 -72))", "dataset_titles": "Algal pigment concentrations from the Ross Sea; Biogenic silica concentrations from the Ross Sea; NBP1801 Expedition data; Nutrients from NBP18-01 CICLOPS", "datasets": [{"dataset_uid": "200056", "doi": "10.7284/907753", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "NBP1801 Expedition data", "url": "https://www.rvdata.us/search/cruise/NBP1801"}, {"dataset_uid": "601205", "doi": "10.15784/601205", "keywords": "Antarctica; Chemistry:Fluid; Chlorophyll; Chromatography; Cryosphere; Liquid Chromatograph; Oceans; Ross Sea; R/V Nathaniel B. Palmer; Sea Water; seawater measurements; Southern Ocean; Water Measurements; Water Samples", "people": "Ditullio, Giacomo", "repository": "USAP-DC", "science_program": null, "title": "Algal pigment concentrations from the Ross Sea", "url": "https://www.usap-dc.org/view/dataset/601205"}, {"dataset_uid": "601225", "doi": "10.15784/601225", "keywords": "Antarctica; Biogenic Silica; Biogenic Silica Concentrations ; Chemistry:Water; Cryosphere; Geochemistry; NBP1801; Oceans; Ross Sea; R/V Nathaniel B. Palmer; Sea Water; Southern Ocean; Spectroscopy; Water Measurements; Water Samples", "people": "Ditullio, Giacomo; Schanke, Nicole", "repository": "USAP-DC", "science_program": null, "title": "Biogenic silica concentrations from the Ross Sea", "url": "https://www.usap-dc.org/view/dataset/601225"}, {"dataset_uid": "601428", "doi": "10.15784/601428", "keywords": "Amundsen Sea; Antarctica; Cryosphere; NBP1801; Nitrate; Nitrite; Nutrients; Phosphate; Ross Sea; R/V Nathaniel B. Palmer; Silicic Acid; Terra Nova Bay", "people": "Saito, Mak", "repository": "USAP-DC", "science_program": null, "title": "Nutrients from NBP18-01 CICLOPS", "url": "https://www.usap-dc.org/view/dataset/601428"}], "date_created": "Thu, 08 Aug 2019 00:00:00 GMT", "description": "Phytoplankton blooms in the coastal waters of the Ross Sea, Antarctica are typically dominated by either diatoms or Phaeocystis Antarctica (a flagellated algae that often can form large colonies in a gelatinous matrix). The project seeks to determine if an association of bacterial populations with Phaeocystis antarctica colonies can directly supply Phaeocystis with Vitamin B12, which can be an important co-limiting micronutrient in the Ross Sea. The supply of an essential vitamin coupled with the ability to grow at lower iron concentrations may put Phaeocystis at a competitive advantage over diatoms. Because Phaeocystis cells can fix more carbon than diatoms and Phaeocystis are not grazed as efficiently as diatoms, the project will help in refining understanding of carbon dynamics in the region as well as the basis of the food web webs. Such understanding also has the potential to help refine predictive ecological models for the region. The project will conduct public outreach activities and will contribute to undergraduate and graduate research. Engagement of underrepresented students will occur during summer student internships. A collaboration with Italian Antarctic researchers, who have been studying the Terra Nova Bay ecosystem since the 1980s, aims to enhance the project and promote international scientific collaborations. \u003cbr/\u003e\u003cbr/\u003eThe study will test whether a mutualistic symbioses between attached bacteria and Phaeocystis provides colonial cells a mechanism for alleviating chronic Vitamin B12 co-limitation effects thereby conferring them with a competitive advantage over diatom communities. The use of drifters in a time series study will provide the opportunity to track in both space and time a developing algal bloom in Terra Nova Bay and to determine community structure and the physiological nutrient status of microbial populations. A combination of flow cytometry, proteomics, metatranscriptomics, radioisotopic and stable isotopic labeling experiments will determine carbon and nutrient uptake rates and the role of bacteria in mitigating potential vitamin B12 and iron limitation. Membrane inlet and proton transfer reaction mass spectrometry will also be used to estimate net community production and release of volatile organic carbon compounds that are climatically active. Understanding how environmental parameters can influence microbial community dynamics in Antarctic coastal waters will advance an understanding of how changes in ocean stratification and chemistry could impact the biogeochemistry and food web dynamics of Southern Ocean ecosystems.", "east": 160.0, "geometry": "POINT(-158 -75.5)", "instruments": null, "is_usap_dc": true, "keywords": "BIOGEOCHEMICAL CYCLES; NBP1801; USA/NSF; CHLOROPHYLL; AMD/US; R/V NBP; USAP-DC; Ross Sea; AMD; NUTRIENTS; PIGMENTS", "locations": "Ross Sea", "north": -72.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems; Antarctic Integrated System Science", "paleo_time": null, "persons": "DiTullio, Giacomo; Lee, Peter", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "Other; USAP-DC", "science_programs": null, "south": -79.0, "title": "Collaborative Research: Cobalamin and Iron Co-Limitation Of Phytoplankton Species in Terra Nova Bay", "uid": "p0010045", "west": -116.0}, {"awards": "1543031 Ivany, Linda", "bounds_geometry": null, "dataset_titles": "NetCDF outputs from middle Eocene climate simulation using the GENESIS global circulation model ; Organic carbon isotope data from serially sampled Eocene driftwood from the La Meseta Fm., Seymour ; Oxygen isotope data from serially sampled Eocene bivalves from the La Meseta Fm., Seymour Island, Antarctica ", "datasets": [{"dataset_uid": "601173", "doi": "10.15784/601173 ", "keywords": "Antarctica; Carbon Isotopes; Cryosphere; Driftwood; Eocene; Geochemistry; Geochronology; isotope data; La Meseta Formation; Mass Spectrometer; Mass Spectrometry; Organic Carbon Isotopes; Seasonality; Seymour Island; Wood", "people": "Judd, Emily", "repository": "USAP-DC", "science_program": null, "title": "Organic carbon isotope data from serially sampled Eocene driftwood from the La Meseta Fm., Seymour ", "url": "https://www.usap-dc.org/view/dataset/601173"}, {"dataset_uid": "601175", "doi": "10.15784/601175 ", "keywords": "Antarctica; Atmosphere; Climate Model; Climate Model; Computer Model; Cryosphere; Eocene; Genesis; Global Circulation Model; Modeling; Model Output; Seasonality; Temperature", "people": "Judd, Emily", "repository": "USAP-DC", "science_program": null, "title": "NetCDF outputs from middle Eocene climate simulation using the GENESIS global circulation model ", "url": "https://www.usap-dc.org/view/dataset/601175"}, {"dataset_uid": "601174", "doi": "10.15784/601174", "keywords": "Antarctica; Biology; Biosphere; Bivalves; Cryosphere; Cucullaea; Eocene; Glaciers/Ice Sheet; isotope data; La Meseta Formation; Mass Spectrometer; Mass Spectrometry; Oxygen Isotopes; Paleotemperature; Paleotemperature; Retrotapes; Seasonality; Seymour Island", "people": "Judd, Emily", "repository": "USAP-DC", "science_program": null, "title": "Oxygen isotope data from serially sampled Eocene bivalves from the La Meseta Fm., Seymour Island, Antarctica ", "url": "https://www.usap-dc.org/view/dataset/601174"}], "date_created": "Tue, 23 Apr 2019 00:00:00 GMT", "description": "In order to understand what environmental conditions might look like for future generations, we need to turn to archives of past times when the world was indeed warmer, before anyone was around to commit them to collective memory. The geologic record of Earth\u0027s past offers a glimpse of what could be in store for the future. Research by Ivany and her team looks to Antarctica during a time of past global warmth to see how seasonality of temperature and rainfall in coastal settings are likely to change in the future. They will use the chemistry of fossils (a natural archive of these variables) to test a provocative hypothesis about near-monsoonal conditions in the high latitudes when the oceans are warm. If true, we can expect high-latitude shipping lanes to become more hazardous and fragile marine ecosystems adapted to constant cold temperatures to suffer. With growing information about how human activities are likely to affect the planet in the future, we will be able to make more informed decisions about policies today. This research involves an international team of scholars, including several women scientists, training of graduate students, and a public museum exhibit to educate children about how we study Earth\u0027s ancient climate and what we can learn from it.\u003cbr/\u003e\u003cbr/\u003eAntarctica is key to an understanding how Earth?s climate system works under conditions of elevated CO2. The poles are the most sensitive regions on the planet to climate change, and the equator-to-pole temperature gradient and the degree to which high-latitude warming is amplified are important components for climate models to capture. Accurate proxy data with good age control are therefore critical for testing numerical models and establishing global patterns. The La Meseta Formation on Seymour Island is the only documented marine section from the globally warm Eocene Epoch exposed in outcrop on the continent; hence its climate record is integral to studies of warming. Early data suggest the potential for strongly seasonal precipitation and runoff in coastal settings. This collaboration among paleontologists, geochemists, and climate modelers will test this using seasonally resolved del-18O data from fossil shallow marine bivalves to track the evolution of seasonality through the section, in combination with independent proxies for the composition of summer precipitation (leaf wax del-D) and local seawater (clumped isotopes). The impact of the anticipated salinity stratification on regional climate will be evaluated in the context of numerical climate model simulations. In addition to providing greater clarity on high-latitude conditions during this time of high CO2, the combination of proxy and model results will provide insights about how Eocene warmth may have been maintained and how subsequent cooling came about. As well, a new approach to the analysis of shell carbonates for 87Sr/86Sr will allow refinements in age control so as to allow correlation of this important section with other regions to clarify global climate gradients. The project outlined here will develop new and detailed paleoclimate records from existing samples using well-tuned as well as newer proxies applied here in novel ways. Seasonal extremes are climate parameters generally inaccessible to most studies but critical to an understanding of climate change; these are possible to resolve in this well-preserved, accretionary-macrofossil-bearing section. This is an integrated study that links marine and terrestrial climate records for a key region of the planet across the most significant climate transition in the Cenozoic.", "east": -56.0, "geometry": "POINT(-56.5 -64.25)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "PALEOCLIMATE RECONSTRUCTIONS; NOT APPLICABLE; USAP-DC; ISOTOPES; MACROFOSSILS; Antarctica", "locations": "Antarctica", "north": -64.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Ivany, Linda; Lu, Zunli; Junium, Christopher; Samson, Scott", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -64.5, "title": "Seasonality, Summer Cooling, and Calibrating the Approach of the Icehouse in Late Eocene Antarctica", "uid": "p0010025", "west": -57.0}, {"awards": "1543313 VanTongeren, Jill", "bounds_geometry": null, "dataset_titles": "U-Pb ages and mineral compositions from Dufek Intrusion", "datasets": [{"dataset_uid": "601132", "doi": "10.15784/601132", "keywords": "Antarctica; Chemical Composition; Chemistry:Rock; Cryosphere; Crystallization; Dufek Complex; Geochemistry; magma chamber procesess; Mass Spectrometry; Rocks; Snow/Ice; Solid Earth; TIMS; volcanic deposits", "people": "VanTongeren, Jill", "repository": "USAP-DC", "science_program": null, "title": "U-Pb ages and mineral compositions from Dufek Intrusion", "url": "https://www.usap-dc.org/view/dataset/601132"}], "date_created": "Mon, 29 Oct 2018 00:00:00 GMT", "description": "The solidified remnants of large magma bodies within the continental crust hold the key to understanding the chemical and physical evolution of volcanic provinces through time. These deposits also commonly contain some of the world\u0027s most important ore deposits. Exposed deposits in South Africa, Greenland, USA, Canada, and Antarctica have led researchers to propose that the bigger the magma body, the faster it will crystallize. While this might seem counter-intuitive (typically it is thought that more magma = hotter = harder to cool), the comparison of these exposures show that bigger magma chambers maintain a molten top that is always in contact with the colder crust; whereas smaller magma chambers insulate themselves by crystallizing at the margins. The process is similar to the difference between a large cup of coffee with no lid, and a smaller cup of coffee held in a thermos. The large unprotected cup of coffee will cool down much faster than that held in the thermos. This research project of VanTongeren and Schoene will use previously collected rocks from the large (~8-9 km thick) Dufek Intrusion in Antarctica to precisely quantify how fast the magma chamber crystallized, and compare that rate to the much smaller magma chamber exposed in the Skaergaard Intrusion of E. Greenland. The work is an important step towards improving our understanding of time-scales associated with the thermal and chemical evolution of nearly all magma chambers on Earth, which will ultimately lead to better predictions of volcanic hazards globally. The work will also yield important insights into the timescales and conditions necessary for developing vast magmatic ore deposits, which is essential to the platinum and steel industries in the USA and abroad.\u003cbr/\u003e\u003cbr/\u003eBased on observations of solidification fronts in six of the world\u0027s most completely exposed layered mafic intrusions, it was recently proposed that bigger magma chambers must crystallize faster than small magma chambers. While this is initially counter-intuitive, the hypothesis falls out of simple heat balance equations and the observation that the thickness of cumulates at the roofs of such intrusions is negatively proportional to the size of the intrusion. In this study, VanTongeren and Schoene will directly test the hypothesis that bigger magma chambers crystallize faster by applying high precision U-Pb zircon geochronology on 5-10 samples throughout the large Dufek Intrusion of Antarctica. Due to uncertainties in even the highest-precision ID-TIMS analyses, the Dufek Intrusion of Antarctica is the only large layered mafic intrusion on Earth where this research can be accomplished. VanTongeren and Schoene will place the geochronological measurements of the Dufek Intrusion into a comprehensive petrologic framework by linking zircon crystallization to other liquidus phases using mineral geochemistry, zircon saturation models, and petrologic models for intrusion crystallization. The research has the potential to radically change the way that we understand the formation and differentiation of large magma bodies within the shallow crust. Layered intrusions are typically thought to cool and crystallize over very long timescales allowing for significant differentiation of the magmas and reorganization of the cumulate rocks. If the \u0027bigger magma chambers crystallize faster hypothesis\u0027 holds this could reduce the calculated solidification time scales of the early earth and lunar magma oceans and have important implications for magma chamber dynamics of active intraplate volcanism and long-lived continental arcs. Furthermore, while the Dufek Intrusion is one of only two large layered intrusions exposed on Earth, very little is known about its petrologic evolution. The detailed geochemical and petrologic work of VanTongeren and Schoene based on analyses of previously collected samples will provide important observations with which to compare the Dufek and other large magma chambers.", "east": null, "geometry": null, "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "NOT APPLICABLE; USAP-DC", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "VanTongeren, Jill", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Testing the Hypothesis that Bigger Magma Chambers Crystallize Faster", "uid": "p0000135", "west": null}, {"awards": "1443306 Mayewski, Paul; 1443263 Higgins, John", "bounds_geometry": null, "dataset_titles": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores; Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores; Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores; Greenhouse gas composition in the Allan Hills S27 ice core; Methane concentration in Allan Hills ice cores; Stable isotope composition of the trapped air in the Allan Hills S27 ice core; Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "datasets": [{"dataset_uid": "601202", "doi": "10.15784/601202", "keywords": "Allan Hills; Allan Hills project; Antarctica; Carbon Dioxide; Carbon Isotopes; Chemistry:Ice; CO2; Cryosphere; Gas Chromatography; Glaciers/Ice Sheet; Glaciology; Greenhouse Gases; Ice; Ice Core Data; Ice Core Gas Records; Ice Core Records; Mass Spectrometer; Mass Spectrometry; Methane; Snow/Ice", "people": "Brook, Edward J.; Bender, Michael; Higgins, John; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601202"}, {"dataset_uid": "601203", "doi": "10.15784/601203", "keywords": "Allan Hills; Allan Hills project; Antarctica; Chemistry:Ice; Cryosphere; Gas Chromatography; Glaciers/Ice Sheet; Glaciology; Greenhouse Gases; Ice; Ice Core Data; Ice Core Gas Records; Methane; Snow/Ice", "people": "Brook, Edward J.; Yan, Yuzhen; Bender, Michael; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Methane concentration in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601203"}, {"dataset_uid": "601512", "doi": "10.15784/601512", "keywords": "Allan Hills; Antarctica; Blue Ice; Cryosphere; Ice Core; Ice Core Gas Records; Isotope; Nitrogen; Oxygen", "people": "Bender, Michael; Higgins, John; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable isotope composition of the trapped air in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601512"}, {"dataset_uid": "601483", "doi": "10.15784/601483", "keywords": "AGDC-project; Allan Hills; Antarctica; Argon; Cryosphere; Ice; Ice Core Data; Ice Core Gas Records; Isotope; Mass Spectrometry; Nitrogen; Oxygen", "people": "Yan, Yuzhen; Higgins, John; Bender, Michael", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601483"}, {"dataset_uid": "601128", "doi": "10.15784/601128", "keywords": "Allan Hills; Antarctica; Blue Ice Area; Chemistry:Ice; Cryosphere; Delta 18O; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope record; Mass Spectrometry; Stable water isotopes", "people": "Introne, Douglas; Yan, Yuzhen; Mayewski, Paul A.; Kurbatov, Andrei V.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601128"}, {"dataset_uid": "601129", "doi": "10.15784/601129", "keywords": "Allan Hills; Allan Hills project; Antarctica; Blue Ice Area; Cryosphere; Delta 18O; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; isotope data; Oxygen; Snow/Ice; Stable water isotopes; Transantarctic Mountains", "people": "Kurbatov, Andrei V.; Introne, Douglas; Yan, Yuzhen; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601129"}, {"dataset_uid": "601130", "doi": "10.15784/601130", "keywords": "Allan Hills; Allan Hills project; Antarctica; Blue Ice Area; Chemistry:Ice; Cryosphere; Delta 18O; Delta Deuterium; Glaciers/Ice Sheet; Glaciology; Ice Core Gas Records; Ice Core Records; Oxygen; Snow/Ice; Stable water isotopes; Transantarctic Mountains", "people": "Introne, Douglas; Yan, Yuzhen; Kurbatov, Andrei V.; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601130"}, {"dataset_uid": "601201", "doi": "10.15784/601201", "keywords": "Allan Hills; Allan Hills project; Antarctica; Argon; Chemistry:Ice; Cryosphere; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Data; Ice Core Gas Records; Krypton; Mass Spectrometer; Noble Gas; Snow/Ice; Xenon", "people": "Yan, Yuzhen; Ng, Jessica; Higgins, John; Bender, Michael; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601201"}, {"dataset_uid": "601425", "doi": "10.15784/601425", "keywords": "Allan Hills; Antarctica; Blue Ice; Carbon Dioxide; Cryosphere; Ice Core; Methane", "people": "Yan, Yuzhen; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Greenhouse gas composition in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601425"}], "date_created": "Thu, 18 Oct 2018 00:00:00 GMT", "description": "Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800,000 years. Previous field expeditions to the Allan Hills blue ice area, Antarctica, have recovered ice cores that date to one million years, the oldest ice cores yet recovered from Antarctica. These records have revealed that interglacial CO2 concentrations decreased by 800,000 years ago and that, in the warmer world 1 million years ago, CO2 and Antarctic temperature were linked as during the last 800,000 years. This project will return to the Allan Hills blue ice area to recover additional ice cores that date to 1 million years or older. The climate records developed from the drilled ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Our results will help answer questions about issues associated with anthropogenic change. These include the relationship between temperature change and the mass balance of Antarctic ice; precipitation and aridity variations associated with radiatively forced climate change; and the climate significance of sea ice extent. The project will entrain two graduate students and a postdoctoral scholar, and will conduct outreach including workshops to engage teachers in carbon science and ice cores.\u003cbr/\u003e\u003cbr/\u003eBetween about 2.8-0.9 million years ago, Earth\u0027s climate was characterized by 40,000-year cycles, driven or paced by changes in the tilt of Earth\u0027s spin axis. Much is known about the \"40,000-year\" world from studies of deep-sea sediments, but our understanding of climate change during this period is incomplete because we lack records of Antarctic climate and direct records of atmospheric greenhouse gas concentrations. We propose to address these issues by building on our recent studies of ancient ice from the Main Ice Field, Allan Hills, Antarctica. During previous field seasons we recovered ice extending, discontinuously, from 0.1-1.0 million years old. Ice was dated by measuring the 40Ar/38Ar (Argon) ratio of the trapped gases. Our discovery of million year-old ice demonstrates that there is gas-record-quality ice from the 40,000-year world in the Allan Hills Main Ice Field. We have identified two different sites, each overlying bedrock at ~ 200 m depth, that are attractive targets for coring ice dating to 1 million years and older. This project aims to core the ice at these two sites, re-occupy a previous site with million year-old ice and drill it down to the bedrock, and generate 10-20 short (~10-meter) cores in areas where our previous work and terrestrial meteorite ages suggest ancient surface ice. We plan to date the ice using the 40Ar/38Ar ages of trapped Argon. We also plan to characterize the continuity of our cores by measuring the deuterium and oxygen isotope ratios in the ice, methane, ratios of Oxygen and Argon to Nitrogen in trapped gas, the Nitrogen-15 isotope (d15N) of Nitrogen, and the Oxygen-18 isotope (d18O) of Oxygen. As the ice may be stratigraphically disturbed, these measurements will provide diagnostic properties for assessing the continuity of the ice-core records. Successful retrieval of ice older than one million years will provide the opportunity for follow-up work to measure the CO2 concentration and other properties within the ice to inform on the temperature history of the Allan Hills region, dust sources and source-area aridity, moisture sources, densification conditions, global average ocean temperature, and greenhouse gas concentrations. We will analyze the data in the context of leading hypotheses of the 40,000-year world and the Mid-Pleistocene Transition to the 100,000-year world. We expect to advance understanding of climate dynamics during these periods.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "AMD/US; USA/NSF; FIELD INVESTIGATION; AMD; USAP-DC; Allan Hills; ice cores; LABORATORY", "locations": "Allan Hills", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Mayewski, Paul A.; Kurbatov, Andrei V.; Higgins, John; Bender, Michael", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Allan Hills", "south": null, "title": "Collaborative Research: Window into the World with 40,000-year Glacial Cycles from Climate Records in Million Year-old Ice from the Allan Hills Blue Ice Area", "uid": "p0000760", "west": null}, {"awards": "1246378 Shevenell, Amelia", "bounds_geometry": "POLYGON((-65.32 -64.15,-65.309 -64.15,-65.298 -64.15,-65.287 -64.15,-65.276 -64.15,-65.265 -64.15,-65.254 -64.15,-65.243 -64.15,-65.232 -64.15,-65.221 -64.15,-65.21 -64.15,-65.21 -64.186,-65.21 -64.222,-65.21 -64.258,-65.21 -64.294,-65.21 -64.33,-65.21 -64.366,-65.21 -64.402,-65.21 -64.438,-65.21 -64.474,-65.21 -64.51,-65.221 -64.51,-65.232 -64.51,-65.243 -64.51,-65.254 -64.51,-65.265 -64.51,-65.276 -64.51,-65.287 -64.51,-65.298 -64.51,-65.309 -64.51,-65.32 -64.51,-65.32 -64.474,-65.32 -64.438,-65.32 -64.402,-65.32 -64.366,-65.32 -64.33,-65.32 -64.294,-65.32 -64.258,-65.32 -64.222,-65.32 -64.186,-65.32 -64.15))", "dataset_titles": "Anvers Trough Foraminifer Stable Isotope data; Geochemical and sedimentologic data from NBP01-01 JPC-34", "datasets": [{"dataset_uid": "601064", "doi": "10.15784/601064", "keywords": "Antarctica; Antarctic Peninsula; Anvers Trough; Chemistry:Sediment; Cryosphere; Foraminifera; Geochemistry; Isotope; LMG1211; LMG1311; Marine Sediments; Oceans; Paleoclimate; Sample/Collection Description; Southern Ocean", "people": "Shevenell, Amelia", "repository": "USAP-DC", "science_program": null, "title": "Anvers Trough Foraminifer Stable Isotope data", "url": "https://www.usap-dc.org/view/dataset/601064"}, {"dataset_uid": "601180", "doi": "10.15784/601180", "keywords": "Antarctica; Be-10; Cryosphere; Glaciers/Ice Sheet; Grain Size; Late Quaternary; Magnetic Susceptibility; Mass Spectrometry; NBP0101; Paleoenvironments; Prydz Bay; Radiocarbon; R/V Nathaniel B. Palmer; Sediment; Sediment Core; Sediment Core Data", "people": "Shevenell, Amelia", "repository": "USAP-DC", "science_program": null, "title": "Geochemical and sedimentologic data from NBP01-01 JPC-34", "url": "https://www.usap-dc.org/view/dataset/601180"}], "date_created": "Fri, 27 Oct 2017 00:00:00 GMT", "description": "Intellectual Merit: \u003cbr/\u003eSouthern Ocean processes play an important role in Late Quaternary glacial-interglacial climate change. However, the direct influence of newly upwelled warm nutrient-rich Circumpolar Deep Water on the Antarctic cryosphere remains speculative. The PI proposes to test the hypothesis that Circumpolar Deep Water-derived ocean heat negatively impacts the mass-balance of Antarctica?s ice sheets during deglaciations using precisely dated late Quaternary paleoceanographic studies of Antarctic margin sediments and a suite of geochemical proxies measured on three existing glacial marine sediment cores from the Prydz Channel, Antarctica. Specifically, the PI will use these data to reconstruct the Late Quaternary history of the Lambert Glacier/Amery Ice Shelf system; evaluate the timing, speed, and style of retreat of the Lambert Glacier/Amery Ice Shelf system during the last deglaciation, and to assess the impact of Circumpolar Deep Water intrusions on the Lambert Glacier/Amery Ice Shelf system in the Late Quaternary. Diatom bound radiocarbon and optically stimulated luminescence techniques will be used to obtain precise stratigraphic age control for the Prydz Channel siliceous muddy ooze intervals. In addition, the PI will measure sedimentary 10Be concentrations to determine the origin of the siliceous muddy ooze units and to track past changes in the position of the ice shelf front.\u003cbr/\u003e\u003cbr/\u003eBroader impacts: \u003cbr/\u003eThis proposal will support an early career female scientist and will provide professional development and research experiences for women/minority graduate and undergraduate students. The PI will take advantage of USF?s Oceanography Camp for Girls.", "east": -65.21, "geometry": "POINT(-65.265 -64.33)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e SEDIMENT CORERS", "is_usap_dc": true, "keywords": "R/V NBP; AMD/US; USAP-DC", "locations": null, "north": -64.15, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Shevenell, Amelia", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -64.51, "title": "Late Quaternary Evolution of the Lambert Glacier/Amery Ice Shelf System, Prydz Bay, Antarctica", "uid": "p0000381", "west": -65.32}, {"awards": "1246378 Shevenell, Amelia", "bounds_geometry": "POLYGON((70 -68,70.5 -68,71 -68,71.5 -68,72 -68,72.5 -68,73 -68,73.5 -68,74 -68,74.5 -68,75 -68,75 -68.2,75 -68.4,75 -68.6,75 -68.8,75 -69,75 -69.2,75 -69.4,75 -69.6,75 -69.8,75 -70,74.5 -70,74 -70,73.5 -70,73 -70,72.5 -70,72 -70,71.5 -70,71 -70,70.5 -70,70 -70,70 -69.8,70 -69.6,70 -69.4,70 -69.2,70 -69,70 -68.8,70 -68.6,70 -68.4,70 -68.2,70 -68))", "dataset_titles": "Anvers Trough Foraminifer Stable Isotope data; Geochemical and sedimentologic data from NBP01-01 JPC-34", "datasets": [{"dataset_uid": "601064", "doi": "10.15784/601064", "keywords": "Antarctica; Antarctic Peninsula; Anvers Trough; Chemistry:Sediment; Cryosphere; Foraminifera; Geochemistry; Isotope; LMG1211; LMG1311; Marine Sediments; Oceans; Paleoclimate; Sample/Collection Description; Southern Ocean", "people": "Shevenell, Amelia", "repository": "USAP-DC", "science_program": null, "title": "Anvers Trough Foraminifer Stable Isotope data", "url": "https://www.usap-dc.org/view/dataset/601064"}, {"dataset_uid": "601180", "doi": "10.15784/601180", "keywords": "Antarctica; Be-10; Cryosphere; Glaciers/Ice Sheet; Grain Size; Late Quaternary; Magnetic Susceptibility; Mass Spectrometry; NBP0101; Paleoenvironments; Prydz Bay; Radiocarbon; R/V Nathaniel B. Palmer; Sediment; Sediment Core; Sediment Core Data", "people": "Shevenell, Amelia", "repository": "USAP-DC", "science_program": null, "title": "Geochemical and sedimentologic data from NBP01-01 JPC-34", "url": "https://www.usap-dc.org/view/dataset/601180"}], "date_created": "Fri, 27 Oct 2017 00:00:00 GMT", "description": "Intellectual Merit: \u003cbr/\u003eSouthern Ocean processes play an important role in Late Quaternary glacial-interglacial climate change. However, the direct influence of newly upwelled warm nutrient-rich Circumpolar Deep Water on the Antarctic cryosphere remains speculative. The PI proposes to test the hypothesis that Circumpolar Deep Water-derived ocean heat negatively impacts the mass-balance of Antarctica?s ice sheets during deglaciations using precisely dated late Quaternary paleoceanographic studies of Antarctic margin sediments and a suite of geochemical proxies measured on three existing glacial marine sediment cores from the Prydz Channel, Antarctica. Specifically, the PI will use these data to reconstruct the Late Quaternary history of the Lambert Glacier/Amery Ice Shelf system; evaluate the timing, speed, and style of retreat of the Lambert Glacier/Amery Ice Shelf system during the last deglaciation, and to assess the impact of Circumpolar Deep Water intrusions on the Lambert Glacier/Amery Ice Shelf system in the Late Quaternary. Diatom bound radiocarbon and optically stimulated luminescence techniques will be used to obtain precise stratigraphic age control for the Prydz Channel siliceous muddy ooze intervals. In addition, the PI will measure sedimentary 10Be concentrations to determine the origin of the siliceous muddy ooze units and to track past changes in the position of the ice shelf front.\u003cbr/\u003e\u003cbr/\u003eBroader impacts: \u003cbr/\u003eThis proposal will support an early career female scientist and will provide professional development and research experiences for women/minority graduate and undergraduate students. The PI will take advantage of USF?s Oceanography Camp for Girls.", "east": 75.0, "geometry": "POINT(72.5 -69)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e SEDIMENT CORERS", "is_usap_dc": true, "keywords": "R/V NBP; AMD/US; USAP-DC", "locations": null, "north": -68.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Shevenell, Amelia", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -70.0, "title": "Late Quaternary Evolution of the Lambert Glacier/Amery Ice Shelf System, Prydz Bay, Antarctica", "uid": "p0000381", "west": 70.0}, {"awards": "1341360 Steig, Eric", "bounds_geometry": "POINT(106 -77.5)", "dataset_titles": "Seasonal 17O Isotope Data from Lake Vostok and WAIS Divide Snow Pits", "datasets": [{"dataset_uid": "601031", "doi": "10.15784/601031", "keywords": "Antarctica; Chemistry:Ice; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Lake Vostok; Snow Pit; WAIS Divide Ice Core", "people": "Schoenemann, Spruce; Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Seasonal 17O Isotope Data from Lake Vostok and WAIS Divide Snow Pits", "url": "https://www.usap-dc.org/view/dataset/601031"}], "date_created": "Tue, 06 Jun 2017 00:00:00 GMT", "description": "Steig/1341360\u003cbr/\u003e\u003cbr/\u003eThis award supports a two-year project to develop a method for rapid and precise measurements of the difference in 18O/16O and 17O/16O isotope ratios in water, referred to as the 17O-excess. Measurement of 17O-excess is a recent innovation in geochemistry, complementing traditional measurements of the ratios of hydrogen (D/H) and oxygen (18O/16O). Conventional measurements of 17O/16O are limited in number because of the time-consuming and laborious nature of the analyses, which involves the conversion of water to oxygen via fluorination, followed by high-precision mass spectrometry. This project will use a novel cavity ring-down spectroscopy (CRDS) system developed by a joint effort of the University of Washington and Picarro, Inc. (Santa Clara, CA), along with the Centre for Ice and Climate (Neils Bohr Institute, Copenhagen). The primary intellectual merit of the research is the improvement of the CRDS method for measurements of 17Oexcess of discrete samples of water, to obtain precision and accuracy competitive with conventional methods using mass spectrometry. This will be achieved by quantification of the effects of water vapor concentration variability and instrument memory, precise calibration of the instrument against standard waters, and improvements to the spectroscopic analyses. The CRDS system will also be coupled to continuous-flow systems for ice core analysis, in collaboration with the University of Colorado, Boulder. The goal is to have an operational system available for ice core processing associated with the next major U.S.-led ice core project at South Pole, in 2015-2017. The broader impacts of the research include the ability to measure 17O-excess in ambient atmospheric water vapor, which can be used to improve understanding of convection, moisture transport, and condensation. The instrument development work proposed here is relevant to research supported by several NSF-GEO programs, including Hydrology, Climate and Large Scale Dynamics, Paleoclimate, Atmosphere Chemistry, and both the Arctic and Antarctic Programs. This proposal will support a postdoctoral researcher.", "east": 106.0, "geometry": "POINT(106 -77.5)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -77.5, "nsf_funding_programs": "Antarctic Instrumentation and Support; Antarctic Glaciology", "paleo_time": null, "persons": "Steig, Eric J.", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -77.5, "title": "Development of a Laser Spectroscopy System for Analysis of 17Oexcess on Ice Cores", "uid": "p0000316", "west": 106.0}, {"awards": "1141978 Foreman, Christine", "bounds_geometry": "POLYGON((160 -76,160.1 -76,160.2 -76,160.3 -76,160.4 -76,160.5 -76,160.6 -76,160.7 -76,160.8 -76,160.9 -76,161 -76,161 -76.1,161 -76.2,161 -76.3,161 -76.4,161 -76.5,161 -76.6,161 -76.7,161 -76.8,161 -76.9,161 -77,160.9 -77,160.8 -77,160.7 -77,160.6 -77,160.5 -77,160.4 -77,160.3 -77,160.2 -77,160.1 -77,160 -77,160 -76.9,160 -76.8,160 -76.7,160 -76.6,160 -76.5,160 -76.4,160 -76.3,160 -76.2,160 -76.1,160 -76))", "dataset_titles": "FT-ICR MS Metadata; Respiration Metadata; UPLC-Q-TOF data of Cotton Glacier exometabolites", "datasets": [{"dataset_uid": "601089", "doi": "10.15784/601089", "keywords": "Antarctica; Biology; Biosphere; Exometabolites; Mass Spectrometry; Microbes; Microbiology", "people": "Foreman, Christine; Tigges, Michelle; Bothner, Brian", "repository": "USAP-DC", "science_program": null, "title": "UPLC-Q-TOF data of Cotton Glacier exometabolites", "url": "https://www.usap-dc.org/view/dataset/601089"}, {"dataset_uid": "601077", "doi": "10.15784/601077", "keywords": "Antarctica; Biology; Biosphere; Chemistry:Fluid; Cryosphere; Fluorescence spectroscopy; Mass Spectrometry", "people": "Foreman, Christine; D\u0027Andrilli, Juliana", "repository": "USAP-DC", "science_program": null, "title": "FT-ICR MS Metadata", "url": "https://www.usap-dc.org/view/dataset/601077"}, {"dataset_uid": "601076", "doi": "10.15784/601076", "keywords": "Antarctica; Biology; Biosphere; Chemistry:Fluid; Cryosphere; Fluorescence spectroscopy; Mass Spectrometry", "people": "Foreman, Christine; Smith, Heidi", "repository": "USAP-DC", "science_program": null, "title": "Respiration Metadata", "url": "https://www.usap-dc.org/view/dataset/601076"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "Uncovering the dynamics of dissolved organic matter (DOM) is central to an understanding of the global carbon cycle, as organic material from lakes, streams, oceans and soils passes through this pool. DOM acts as a key energy source for microbes in many ecosystems and therefore can affect regional nutrient cycling patterns. For example, preliminary results suggest that organisms isolated from a supraglacial stream on Cotton Glacier, Antarctica, may be important in DOM cycling in this relatively simple, low temperature system. However, little is known about the functional attributes of the microbes that interact with DOM in the environment. This project will use state-of-the-art genomics, proteomics and metabolomics approaches to understand the mechanisms by which two microbial isolates, CG3 and CG9_1, affect DOM cycling. Liquid chromatography-mass spectrometry will also be used to better characterize the microbially-derived DOM from this ecosystem. This project will support the research and training of one undergraduate and two graduate students. Results will be widely disseminated through publications as well as through presentations at national and international meetings. In addition, raw data will be made available through open-access databases. Understanding the relationship between cold-adapted microbial metabolisms and DOM pools is important as more than 90% of the Earth?s oceans are below 5 degrees Celsius.", "east": 161.0, "geometry": "POINT(160.5 -76.5)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -76.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Foreman, Christine; Bothner, Brian", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.0, "title": "Multidimensional \"omics\" characterization of microbial metabolism and dissolved organic matter in Antarctica", "uid": "p0000408", "west": 160.0}, {"awards": "1043092 Steig, Eric; 1043167 White, James", "bounds_geometry": "POINT(-112.08 -79.47)", "dataset_titles": "Resampling of Deep Polar Ice Cores using Information Theory; Seasonal temperatures in West Antarctica during the Holocene ; Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "datasets": [{"dataset_uid": "601365", "doi": "10.15784/601365", "keywords": "Antarctica; Cryosphere; Delta 18O; Isotope; WAIS divide; WAIS Divide Ice Core; West Antarctic Ice Sheet", "people": "White, James; Vaughn, Bruce; Morris, Valerie; Jones, Tyler R.; Garland, Joshua", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Resampling of Deep Polar Ice Cores using Information Theory", "url": "https://www.usap-dc.org/view/dataset/601365"}, {"dataset_uid": "601274", "doi": "10.15784/601274", "keywords": "Antarctica; Cryosphere; Delta 18O; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Snow/Ice; WAIS divide; WAIS Divide Ice Core; West Antarctic Ice Sheet", "people": "Vaughn, Bruce; Morris, Valerie; Jones, Tyler R.; Garland, Joshua; Bradley, Elizabeth; Price, Michael; White, James", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "url": "https://www.usap-dc.org/view/dataset/601274"}, {"dataset_uid": "600169", "doi": "10.15784/600169", "keywords": "Antarctica; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Paleoclimate; Snow Accumulation; WAIS divide; WAIS Divide Ice Core", "people": "Vaughn, Bruce; Morris, Valerie; Jones, Tyler R.; White, James", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "url": "https://www.usap-dc.org/view/dataset/600169"}, {"dataset_uid": "601603", "doi": "10.15784/601603", "keywords": "Antarctica; Cryosphere; Glaciers/Ice Sheet; Glaciology; Ice Core Records; ice cores; Seasonality; Seasonal Temperatures; Temperature; Water Isotopes; West Antarctic Ice Sheet", "people": "Jones, Tyler R.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Seasonal temperatures in West Antarctica during the Holocene ", "url": "https://www.usap-dc.org/view/dataset/601603"}], "date_created": "Thu, 15 Sep 2016 00:00:00 GMT", "description": "Steig/1043092\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to contribute one of the cornerstone analyses, stable isotopes of ice (Delta-D, Delta-O18) to the ongoing West Antarctic Ice Sheet Divide (WAIS) deep ice core. The WAIS Divide drilling project, a multi-institution project to obtain a continuous high resolution ice core record from central West Antarctica, reached a depth of 2560 m in early 2010; it is expected to take one or two more field seasons to reach the ice sheet bed (~3300 m), plus an additional four seasons for borehole logging and other activities including proposed replicate coring. The current proposal requests support to complete analyses on the WAIS Divide core to the base, where the age will be ~100,000 years or more. These analyses will form the basis for the investigation of a number of outstanding questions in climate and glaciology during the last glacial period, focused on the dynamics of the West Antarctic Ice Sheet and the relationship of West Antarctic climate to that of the Northern polar regions, the tropical Pacific, and the rest of the globe, on time scales ranging from years to tens of thousands of years. One new aspect of this work is the growing expertise at the University of Washington in climate modeling with isotope-tracer-enabled general circulation models, which will aid in the interpretation of the data. Another major new aspect is the completion and use of a high-resolution, semi-automated sampling system at the University of Colorado, which will permit the continuous analysis of isotope ratios via laser spectroscopy, at an effective resolution of ~2 cm or less, providing inter-annual time resolution for most of the core. Because continuous flow analyses of stable ice isotopes is a relatively new measurement, we will complement them with parallel measurements, every ~10-20 m, using traditional discrete sampling and analysis by mass spectrometry at the University of Washington. The intellectual merit and the overarching goal of the work are to see Inland WAIS become the reference ice isotope record for West Antarctica. The broader impacts of the work are that the data generated in this project pertain directly to policy-relevant and immediate questions of the stability of the West Antarctic ice sheet, and thus past and future changes in sea level, as well as the nature of climate change in the high southern latitudes. The project will also contribute to the development of modern isotope analysis techniques using laser spectroscopy, with applications well beyond ice cores. The project will involve a graduate student and postdoc who will work with both P.I.s, and spend time at both institutions. Data will be made available rapidly through the Antarctic Glaciological Data Center, for use by other researchers and the public.", "east": -112.08, "geometry": "POINT(-112.08 -79.47)", "instruments": null, "is_usap_dc": true, "keywords": "LABORATORY", "locations": null, "north": -79.47, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Glaciology; Antarctic Glaciology; Antarctic Earth Sciences", "paleo_time": null, "persons": "White, James; Vaughn, Bruce; Jones, Tyler R.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.47, "title": "Collaborative Research: Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "uid": "p0000078", "west": -112.08}, {"awards": "1141936 Foreman, Christine", "bounds_geometry": "POINT(112.085 -79.467)", "dataset_titles": "Molecular Level Characterization of Dissolved Organic Carbon and Microbial Diversity in the WAIS Divide Replicate Core", "datasets": [{"dataset_uid": "600133", "doi": "10.15784/600133", "keywords": "Antarctica; Biology; Biosphere; Cryosphere; Genetic Sequences; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS divide; WAIS Divide Ice Core", "people": "Foreman, Christine", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Molecular Level Characterization of Dissolved Organic Carbon and Microbial Diversity in the WAIS Divide Replicate Core", "url": "https://www.usap-dc.org/view/dataset/600133"}], "date_created": "Thu, 05 Nov 2015 00:00:00 GMT", "description": "This award supports a detailed, molecular level characterization of dissolved organic carbon and microbes in Antarctic ice cores. Using the most modern biological (genomic), geochemical techniques, and advanced chemical instrumentation researchers will 1) optimize protocols for collecting, extracting and amplifying DNA from deep ice cores suitable for use in next generation pyrosequencing; 2) determine the microbial diversity within the ice core; and 3) obtain and analyze detailed molecular characterizations of the carbon in the ice by ultrahigh resolution Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR-MS). With this pilot study investigators will be able to quantify the amount of material (microbial biomass and carbon) required to perform these characterizations, which is needed to inform future ice coring projects. The ultimate goal will be to develop protocols that maximize the yield, while minimizing the amount of ice required. The broader impacts include education and outreach at both the local and national levels. As a faculty mentor with the American Indian Research Opportunities and BRIDGES programs at Montana State University, Foreman will serve as a mentor to a Native American student in the lab during the summer months. Susan Kelly is an Education and Outreach Coordinator with a MS degree in Geology and over 10 years of experience in science outreach. She will coordinate efforts for comprehensive educational collaboration with the Hardin School District on the Crow Indian Reservation in South-central Montana.", "east": 112.085, "geometry": "POINT(112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ADS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "LABORATORY; Dissolved Organic Carbon; WAIS divide; FIELD SURVEYS; Microbes; Ice Core; Not provided; molecular; Antarctic; FIELD INVESTIGATION; Microbial Diversity; pyrosequencing; DNA", "locations": "Antarctic; WAIS divide", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Foreman, Christine", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Molecular Level Characterization of Dissolved Organic Carbon and Microbial Diversity in the WAIS Divide Replicate Core", "uid": "p0000342", "west": 112.085}, {"awards": "1245821 Brook, Edward; 1245659 Petrenko, Vasilii; 1246148 Severinghaus, Jeffrey", "bounds_geometry": "POINT(162.167 -77.733)", "dataset_titles": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores; Last Interglacial Mean Ocean Temperature; Mean Ocean Temperature in Marine Isotope Stage 4; Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation; N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica; Taylor Glacier CO2 Isotope Data 74-59 kyr; Taylor Glacier Noble Gases - Younger Dryas; The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "datasets": [{"dataset_uid": "600163", "doi": "10.15784/600163", "keywords": "Antarctica; Atmosphere; Cryosphere; Geochemistry; Ice Core Records; Isotope; Paleoclimate; Taylor Glacier; Transantarctic Mountains", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "url": "https://www.usap-dc.org/view/dataset/600163"}, {"dataset_uid": "601198", "doi": "10.15784/601198", "keywords": "Antarctica; Blue Ice Area; Chemistry:Ice; CO2; Cryosphere; Dust; Gas; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Mass Spectrometer; Methane; Nitrogen Isotopes; Oxygen Isotopes; Paleoclimate; Snow/Ice; Taylor Dome; Taylor Dome Ice Core", "people": "Dyonisius, Michael; Baggenstos, Daniel; Bauska, Thomas; Rhodes, Rachel; McConnell, Joseph; Petrenko, Vasilii; Severinghaus, Jeffrey P.; Shackleton, Sarah; Barker, Stephen; Marcott, Shaun; Brook, Edward J.; Menking, James", "repository": "USAP-DC", "science_program": null, "title": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/601198"}, {"dataset_uid": "601176", "doi": "10.15784/601176", "keywords": "Antarctica; CO2; Cryosphere; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; Noble Gas; Noble Gas Isotopes; Snow/Ice; Taylor Glacier; Younger Dryas", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Taylor Glacier Noble Gases - Younger Dryas", "url": "https://www.usap-dc.org/view/dataset/601176"}, {"dataset_uid": "601415", "doi": "10.15784/601415", "keywords": "Antarctica; Cryosphere; Glaciology; Ice Core Data; Ice Core Records; Paleoclimate; Paleotemperature; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": null, "title": "Mean Ocean Temperature in Marine Isotope Stage 4", "url": "https://www.usap-dc.org/view/dataset/601415"}, {"dataset_uid": "601260", "doi": "10.15784/601260", "keywords": "Antarctica; Carbon-14; Cosmogenic; Cryosphere; Ice Core; Methane", "people": "Dyonisius, Michael; Petrenko, Vasilii", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601260"}, {"dataset_uid": "601600", "doi": "10.15784/601600", "keywords": "Antarctica; Cryosphere; Taylor Glacier", "people": "Petrenko, Vasilii; Dyonisius, Michael; Severinghaus, Jeffrey P.; Barker, Stephen; Brook, Edward J.; Buffen, Aron; Bauska, Thomas; Shackleton, Sarah; Menking, James; Menking, Andy", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier CO2 Isotope Data 74-59 kyr", "url": "https://www.usap-dc.org/view/dataset/601600"}, {"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:Ice; CO2; Cryosphere; Dome C Ice Core; EPICA; EPICA Dome C; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; isotope data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotopes; Paleotemperature; Pleistocene; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:Ice; CO2; Cryosphere; Dome C Ice Core; EPICA; EPICA Dome C; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; isotope data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotopes; Paleotemperature; Pleistocene; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "601398", "doi": "10.15784/601398", "keywords": "Antarctica; Cryosphere; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Gas Records; Ice Core Records; Marine Isotope Stage 4; MIS 4; Nitrous Oxide; Pleistocene; Taylor Dome Ice Core; Taylor Glacier", "people": "Dyonisius, Michael; Menking, James; Brook, Edward J.; Schilt, Adrian; Shackleton, Sarah; Severinghaus, Jeffrey P.; Petrenko, Vasilii", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601398"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "This award supports a project to use the Taylor Glacier, Antarctica, ablation zone to collect ice samples for a range of paleoenvironmental studies. A record of carbon-14 of atmospheric methane (14CH4) will be obtained for the last deglaciation and the Early Holocene, together with a supporting record of CH4 stable isotopes. In-situ cosmogenic 14C content and partitioning of 14C between different species (14CH4, C-14 carbon monoxide (14CO) and C-14 carbon dioxide (14CO2)) will be determined with unprecedented precision in ice from the surface down to ~67 m. Further age-mapping of the ablating ice stratigraphy will take place using a combination of CH4, CO2, \u0026#948;18O of oxygen gas and H2O stable isotopes. High precision, high-resolution records of CO2, \u0026#948;13C of CO2, nitrous oxide (N2O) and N2O isotopes will be obtained for the last deglaciation and intervals during the last glacial period. The potential of 14CO2 and Krypton-81 (81Kr) as absolute dating tools for glacial ice will be investigated. The intellectual merit of proposed work includes the fact that the response of natural methane sources to continuing global warming is uncertain, and available evidence is insufficient to rule out the possibility of catastrophic releases from large 14C-depleted reservoirs such as CH4 clathrates and permafrost. The proposed paleoatmospheric 14CH4 record will improve our understanding of the possible magnitude and timing of CH4 release from these reservoirs during a large climatic warming. A thorough understanding of in-situ cosmogenic 14C in glacial ice (production rates by different mechanisms and partitioning between species) is currently lacking. Such an understanding will likely enable the use of in-situ 14CO in ice at accumulation sites as a reliable, uncomplicated tracer of the past cosmic ray flux and possibly past solar activity, as well as the use of 14CO2 at both ice accumulation and ice ablation sites as an absolute dating tool. Significant gaps remain in our understanding of the natural carbon cycle, as well as in its responses to global climate change. The proposed high-resolution, high-precision records of \u0026#948;13C of CO2 would provide new information on carbon cycle changes both during times of rising CO2 in a warming climate and falling CO2 in a cooling climate. N2O is an important greenhouse gas that increased by ~30% during the last deglaciation. The causes of this increase are still largely uncertain, and the proposed high-precision record of N2O concentration and isotopes would provide further insights into N2O source changes in a warming world. The broader impacts of proposed work include an improvement in our understanding of the response of these greenhouse gas budgets to global warming and inform societally important model projections of future climate change. The continued age-mapping of Taylor Glacier ablation ice will add value to this high-quality, easily accessible archive of natural environmental variability. Establishing 14CO as a robust new tracer for past cosmic ray flux would inform paleoclimate studies and constitute a valuable contribution to the study of the societally important issue of climate change. The proposed work will contribute to the development of new laboratory and field analytical systems. The data from the study will be made available to the scientific community and the broad public through the NSIDC and NOAA Paleoclimatology data centers. 1 graduate student each will be trained at UR, OSU and SIO, and the work will contribute to the training of a postdoc at OSU. 3 UR undergraduates will be involved in fieldwork and research. The work will support a new, junior UR faculty member, Petrenko. All PIs have a strong history of and commitment to scientific outreach in the forms of media interviews, participation in filming of field projects, as well as speaking to schools and the public about their research, and will continue these activities as part of the proposed work. This award has field work in Antarctica.", "east": 162.167, "geometry": "POINT(162.167 -77.733)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Not provided; USAP-DC; Stable Isotopes; FIELD INVESTIGATION; Ablation Zone; Stratigraphy; Taylor Glacier; FIELD SURVEYS; Antarctica; Methane; Nitrous Oxide; USA/NSF; LABORATORY; AMD; Ice Core; Cosmogenic; paleoenvironmental; AMD/US; Carbon Dioxide; FIXED OBSERVATION STATIONS", "locations": "Taylor Glacier; Antarctica", "north": -77.733, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Brook, Edward J.; Severinghaus, Jeffrey P.; PETRENKO, VASILLI", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e FIXED OBSERVATION STATIONS; Not provided; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.733, "title": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "uid": "p0000283", "west": 162.167}, {"awards": "1043092 Steig, Eric", "bounds_geometry": null, "dataset_titles": "17O excess from WAIS Divide, 0 to 25 ka BP; WAIS Divide WDC06A Oxygen Isotope Record", "datasets": [{"dataset_uid": "609629", "doi": "10.7265/N5GT5K41", "keywords": "Antarctica; Chemistry:Fluid; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Paleoclimate; WAIS divide; WAIS Divide Ice Core", "people": "Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide WDC06A Oxygen Isotope Record", "url": "https://www.usap-dc.org/view/dataset/609629"}, {"dataset_uid": "601413", "doi": "10.15784/601413", "keywords": "Antarctica; Cryosphere; Ice Core; Oxygen Isotopes; WAIS divide", "people": "Schoenemann, Spruce; Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "17O excess from WAIS Divide, 0 to 25 ka BP", "url": "https://www.usap-dc.org/view/dataset/601413"}], "date_created": "Sat, 06 Dec 2014 00:00:00 GMT", "description": "This award supports a project to contribute one of the cornerstone analyses, stable isotopes of ice (Delta-D, Delta-O18) to the ongoing West Antarctic Ice Sheet Divide (WAIS) deep ice core. The WAIS Divide drilling project, a multi-institution project to obtain a continuous high resolution ice core record from central West Antarctica, reached a depth of 2560 m in early 2010; it is expected to take one or two more field seasons to reach the ice sheet bed (~3300 m), plus an additional four seasons for borehole logging and other activities including proposed replicate coring. The current proposal requests support to complete analyses on the WAIS Divide core to the base, where the age will be ~100,000 years or more. These analyses will form the basis for the investigation of a number of outstanding questions in climate and glaciology during the last glacial period, focused on the dynamics of the West Antarctic Ice Sheet and the relationship of West Antarctic climate to that of the Northern polar regions, the tropical Pacific, and the rest of the globe, on time scales ranging from years to tens of thousands of years. One new aspect of this work is the growing expertise at the University of Washington in climate modeling with isotope-tracer-enabled general circulation models, which will aid in the interpretation of the data. Another major new aspect is the completion and use of a high-resolution, semi-automated sampling system at the University of Colorado, which will permit the continuous analysis of isotope ratios via laser spectroscopy, at an effective resolution of ~2 cm or less, providing inter-annual time resolution for most of the core. Because continuous flow analyses of stable ice isotopes is a relatively new measurement, we will complement them with parallel measurements, every ~10-20 m, using traditional discrete sampling and analysis by mass spectrometry at the University of Washington. The intellectual merit and the overarching goal of the work are to see Inland WAIS become the reference ice isotope record for West Antarctica. The broader impacts of the work are that the data generated in this project pertain directly to policy-relevant and immediate questions of the stability of the West Antarctic ice sheet, and thus past and future changes in sea level, as well as the nature of climate change in the high southern latitudes. The project will also contribute to the development of modern isotope analysis techniques using laser spectroscopy, with applications well beyond ice cores. The project will involve a graduate student and postdoc who will work with both P.I.s, and spend time at both institutions. Data will be made available rapidly through the Antarctic Glaciological Data Center, for use by other researchers and the public.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e INFRARED LASER SPECTROSCOPY; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e INFRARED LASER SPECTROSCOPY", "is_usap_dc": true, "keywords": "AGDC-project; AMD; ANALYTICAL LAB; USAP-DC; FIELD SURVEYS; WAIS Divide-project; USA/NSF; LABORATORY; AMD/US", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Steig, Eric J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e ANALYTICAL LAB; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Collaborative Research: Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "uid": "p0000010", "west": null}, {"awards": "0739684 Hatcher, Patrick", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Wed, 26 Sep 2012 00:00:00 GMT", "description": "This award supports a project to fully develop the analytical protocols needed to exploit a relatively new technique for the analysis of soluble organic matter in ice core samples. The technique couples Electrospray ionization to high resolution Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS). Sample volume will be reduced and pre-concentration steps will be eliminated. Following method optimization a suite of ice core samples will be studied from several Antarctic and Greenland locations to address several hypothesis driven research questions. Preliminary results show that a vast record of relatively high molecular weight organic material exists in ice core samples and intriguing results from a few samples warrant further investigation. Several important questions related to developing a better understanding of the nature and paleo record of organic matter in ice cores will be addressed. These include developing a better understanding of the origin of nitrogen and sulfur isotopes in pre-industrial vs. modern samples, developing the methods to apply molecular biomarker techniques, routinely used by organic geochemists for sediment analyses, to the analysis of organic matter in ice cores, tracking the level of oxidation of homologous series of compounds and using them as a proxy for atmospheric oxidant levels in the past and determining whether or not high resolution FTICR mass spectral analysis can provide the ice core community with a robust method to analyze organic materials at the molecular level. The intellectual merit of this work is that this analytical method will provide a new understanding of the nature of organic matter in ice, possibly leading to the discovery of multitudes of molecular species indicative of global change processes whose abundances can be compared with other change proxies. The proposed studies are of an exploratory nature and potentially transformative for the field of ice core research and cryobiology. The broader impacts of these studies are that they should provide compelling evidence regarding organic matter sources, atmospheric processing and anthropogenic inputs to polar ice and how these have varied over time. The collaborative work proposed here will partner atmospheric chemistry/polar ice chemistry expertise with organic geochemistry expertise, resulting in significant contributions to both fields of study and significant advances in ice core analysis. Training of both graduate and undergraduate students will be a key component of the project and students will be involved in collaborative research using advanced analytical instrumentation, presentation of research results at national meetings, and will participate in manuscript preparation.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": false, "keywords": "ice cores; Not provided; LABORATORY; sulfur; Mass Spectrometry; COMPUTERS; isotopes; molecular; Nitrogen; organic matter", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Hatcher, Patrick; Grannas, Amanda", "platforms": "Not provided; OTHER \u003e MODELS \u003e COMPUTERS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repositories": null, "science_programs": null, "south": null, "title": "Collaborative Research: Molecular Level Characterization of Organic Matter in Ice Cores using High-resolution FTICR mass spectrometry", "uid": "p0000707", "west": null}, {"awards": "0739491 Sowers, Todd; 0739598 Aydin, Murat", "bounds_geometry": null, "dataset_titles": "Alkanes in Firn Air Samples, Antarctica and Greenland; Methane Isotopes in South Pole Firn Air, 2008", "datasets": [{"dataset_uid": "609504", "doi": "10.7265/N5X9287C", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:Fluid; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Greenland; Snow/Ice; South Pole; WAIS divide", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Alkanes in Firn Air Samples, Antarctica and Greenland", "url": "https://www.usap-dc.org/view/dataset/609504"}, {"dataset_uid": "609502", "doi": "10.7265/N55T3HFP", "keywords": "Antarctica; Atmosphere; Chemistry:Fluid; Cryosphere; Geochemistry; Isotope; Paleoclimate; Snow/Ice; South Pole", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": null, "title": "Methane Isotopes in South Pole Firn Air, 2008", "url": "https://www.usap-dc.org/view/dataset/609502"}], "date_created": "Thu, 18 Aug 2011 00:00:00 GMT", "description": "This award supports a project to make measurements of methane and other trace gases in firn air collected at South Pole, Antarctica. The analyses will include: methane isotopes (delta-13CH4 and delta-DCH4), light non-methane hydrocarbons (ethane, propane, and n-butane), sulfur gases (COS, CS2), and methyl halides (CH3Cl and CH3Br). The atmospheric burdens of these trace gases reflect changes in atmospheric OH, biomass burning, biogenic activity in terrestrial, oceanic, and wetland ecosystems, and industrial/agricultural activity. The goal of this project is to develop atmospheric histories for these trace gases over the last century through examination of depth profiles of these gases in South Pole firn air. The project will involve two phases: 1) a field campaign at South Pole, Antarctica to drill two firn holes and fill a total of ~200 flasks from depths reaching 120 m, 2) analysis of firn air at University of California, Irvine, Penn State University, and several other collaborating laboratories. Atmospheric histories will be inferred from the measurements using a one dimensional advective/diffusive model of firn air transport. This study will provide new information about the recent changes in atmospheric levels of these gases, providing about a 90 year long time series record that connects the earlier surface and firn air measurements to present day. The project will also explore the possibility of in- situ production of light non-methane hydrocarbons in firn air that is relevant to the interpretation of ice core records. The broader impacts of this research are that it has the potential for significant societal impact by improving our understanding of climate change and man\u0027s input to the atmosphere. The results of this work will be disseminated through the peer review process, and will contribute to environmental assessments, such as the Inter-governmental Panel on Climate Change (IPCC) Climate Assessment and the Word Meteorological Organization (WMO) Stratospheric Ozone Assessment. This research will provide educational opportunities for graduate and undergraduate students, and will contribute to a teacher training program for K-12 teachers in minority school districts.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS", "is_usap_dc": true, "keywords": "FIELD INVESTIGATION; Carbon; Gas Chromatography; Firn Air Chemistry; Polar Firn Air; Firn Air Isotope Measurements; Not provided; GROUND-BASED OBSERVATIONS; Methane; Antarctica; LABORATORY; South Pole; isotopes; Firn; Firn Air Isotopes; deltaD; Delta 13C; Carbon-13; Mass Spectrometer; Delta Deuterium; FIELD SURVEYS; Deuterium; Mass Spectrometry; Firn Air; Chromatography; Methane Isotopes; Carbon Isotopes; Firn Air Samples; Stable Isotopes", "locations": "Antarctica; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat; Saltzman, Eric; Sowers, Todd A.", "platforms": "Not provided; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air", "uid": "p0000162", "west": null}, {"awards": "0636506 Mayewski, Paul", "bounds_geometry": "POLYGON((-137.7 -75.7,-137.4 -75.7,-137.1 -75.7,-136.8 -75.7,-136.5 -75.7,-136.2 -75.7,-135.9 -75.7,-135.6 -75.7,-135.3 -75.7,-135 -75.7,-134.7 -75.7,-134.7 -75.773,-134.7 -75.846,-134.7 -75.919,-134.7 -75.992,-134.7 -76.065,-134.7 -76.138,-134.7 -76.211,-134.7 -76.284,-134.7 -76.357,-134.7 -76.43,-135 -76.43,-135.3 -76.43,-135.6 -76.43,-135.9 -76.43,-136.2 -76.43,-136.5 -76.43,-136.8 -76.43,-137.1 -76.43,-137.4 -76.43,-137.7 -76.43,-137.7 -76.357,-137.7 -76.284,-137.7 -76.211,-137.7 -76.138,-137.7 -76.065,-137.7 -75.992,-137.7 -75.919,-137.7 -75.846,-137.7 -75.773,-137.7 -75.7))", "dataset_titles": "Ion Concentrations from SPRESSO Ice Core, Antarctica; Mt. Moulton Ice Trench Mass Spectrometry Data, Antarctica", "datasets": [{"dataset_uid": "609471", "doi": "10.7265/N508638J", "keywords": "Antarctica; Chemistry:Ice; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Ice Core Records; ITASE; Paleoclimate; South Pole; SPRESSO Ice Core", "people": "Mayewski, Paul A.; Korotkikh, Elena", "repository": "USAP-DC", "science_program": null, "title": "Ion Concentrations from SPRESSO Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609471"}, {"dataset_uid": "609472", "doi": "10.7265/N5VH5KSV", "keywords": "Antarctica; Chemistry:Ice; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Mt Moulton; Paleoclimate", "people": "Mayewski, Paul A.; Korotkikh, Elena", "repository": "USAP-DC", "science_program": null, "title": "Mt. Moulton Ice Trench Mass Spectrometry Data, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609472"}], "date_created": "Thu, 29 Jul 2010 00:00:00 GMT", "description": "This award supports a project to examine an existing ice core of opportunity from South Pole (SPRESO core) to develop a 2000+ year long climate record. SPRESO ice core will be an annually dated, sub-annually-resolved reconstruction of past climate (atmospheric circulation, temperature, precipitation rate, and atmospheric chemistry) utilizing continuous, co-registered measurements (n=45) of: major ions, trace elements, and stable isotope series, plus selected sections for microparticle size and composition. The intellectual merit of this project relates to the fact that few 2000+ year records of this quality exist in Antarctica despite increasing scientific interest in this critical time period as the framework within which to understand modern climate. The scientific impact of this ice core investigation are that it will provide an in-depth understanding of climate variability; a baseline for assessing modern climate variability in the context of human activity; and a contribution to the prediction of future climate variability. The broader impact of this work is that the proposed research addresses important questions concerning the role of Antarctica in past, present, and future global change. Results will be translated into publicly accessible information through public lectures, media appearances, and an extensive outreach activity housed in our Institute. Our ice core activities provide a major basis for curriculum in K-12 and University plus a basis for several field and laboratory based graduate theses and undergraduate student projects. The project will support one PhD student for 3 years and undergraduate salaries. The Climate Change Institute has a long history of gender and ethnically diverse student and staff involvement in research.", "east": -134.7, "geometry": "POINT(-136.2 -76.065)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctic Ice Sheet; Ice Core Interpretation; ice chemistry; ice cores; Ions; US ITASE; LABORATORY; EXPLORATIONS; Ice Core Data; Ice Core; Laboratory investigations; Field Investigations; Ice Core Chemistry; Horizontal Ice Core; Ice Analysis; Ice Sheet; Ice; Not provided", "locations": "Antarctic Ice Sheet", "north": -75.7, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Korotkikh, Elena; Kreutz, Karl; Kurbatov, Andrei V.; Mayewski, Paul A.", "platforms": "Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -76.43, "title": "Collaborative Proposal: 2000+ Year Detailed, Calibrated Climate Reconstruction from a South Pole Ice Core Set in an Antarctic - Global Scale Context", "uid": "p0000209", "west": -137.7}, {"awards": "0839042 Caffee, Marc", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Cosmogenic 10Be in WAIS Divide Ice core, 1190-2453 m; Cosmogenic Radionuclides in the WAIS Divide Ice Core", "datasets": [{"dataset_uid": "600383", "doi": "10.15784/600383", "keywords": "Antarctica; Cosmogenic Radionuclides; Cryosphere; Geochronology; Glaciers/Ice Sheet; Glaciology; Hydrothermal Vent; WAIS divide; WAIS Divide Ice Core", "people": "Welten, Kees", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Cosmogenic Radionuclides in the WAIS Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/600383"}, {"dataset_uid": "601466", "doi": "10.15784/601466", "keywords": "Antarctica; Cryosphere; West Antarctic Ice Sheet", "people": "Nishiizumi, Kunihiko; Welten, Kees; Caffee, M. W.; Woodruff, T. E.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Cosmogenic 10Be in WAIS Divide Ice core, 1190-2453 m", "url": "https://www.usap-dc.org/view/dataset/601466"}], "date_created": "Thu, 01 Jul 2010 00:00:00 GMT", "description": "Caffee/0839042 \u003cbr/\u003e\u003cbr/\u003eThis award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to measure the concentration of the cosmogenic radionuclide, Beryllium-10 in the deep WAIS divide ice core. Since cosmogenic radionuclides are one of the key parameters used for absolute dating of the ice core and deriving paleoaccumulation rates, it is essential that these measurements be made quickly and efficiently, and that the information is disseminated as soon as the results are available. The intellectual merit of the project is that it will allow a comparison to be made between the core from WAIS Divide and previously measured cosmogenic radionuclide records from Arctic ice cores, particularly GISP2 and GRIP This project will enable scientists to delineate those processes acting at a local level from those that produce global effects and will provide independent chronological markers to aid in the reconstruction of the WAIS Divide ice core chronology. The cosmogenic 10Be profile can also be used to investigate the possible role of solar activity on climate. The direct comparison of radionuclide concentrations with paleoclimate records in ice cores from different sites will provide more insight in the timing and magnitude of solar forcing of climate. The broader impacts of this project include: (i) the formation of a multi-disciplinary team of collaborators for the interpretation of future analyses of cosmogenic radionuclide data from the WAIS divide and other ice cores. (ii) the involvement and training of graduate and undergraduate students in the large scale project of climate research through detailed studies of ice samples. (iii) the opportunity to highlight to a wide range of lab visitors and students from local K-12 schools the importance of ice core and climate change studies.\u003cbr/\u003e\u003cbr/\u003eThis award does not involve field work in Antarctica.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e AMS", "is_usap_dc": false, "keywords": "Ice Core; Antarctica; WAIS divide; radionuclides; accelerator mass spectrometry; Not provided; Cosmogenic", "locations": "WAIS divide; Antarctica", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Welten, Kees; Nishiizumi, Kunihiko; Caffee, Marc; Woodruff, Thomas", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Collaborative Research: Cosmogenic Radionuclides in the Deep WAIS Divide Core", "uid": "p0000103", "west": -112.085}, {"awards": "9814692 Kellogg, Thomas", "bounds_geometry": "POLYGON((-179.99342 -58.74225,-143.994734 -58.74225,-107.996048 -58.74225,-71.997362 -58.74225,-35.998676 -58.74225,0.000010000000003 -58.74225,35.998696 -58.74225,71.997382 -58.74225,107.996068 -58.74225,143.994754 -58.74225,179.99344 -58.74225,179.99344 -60.716231,179.99344 -62.690212,179.99344 -64.664193,179.99344 -66.638174,179.99344 -68.612155,179.99344 -70.586136,179.99344 -72.560117,179.99344 -74.534098,179.99344 -76.508079,179.99344 -78.48206,143.994754 -78.48206,107.996068 -78.48206,71.997382 -78.48206,35.998696 -78.48206,0.000010000000003 -78.48206,-35.998676 -78.48206,-71.997362 -78.48206,-107.996048 -78.48206,-143.994734 -78.48206,-179.99342 -78.48206,-179.99342 -76.508079,-179.99342 -74.534098,-179.99342 -72.560117,-179.99342 -70.586136,-179.99342 -68.612155,-179.99342 -66.638174,-179.99342 -64.664193,-179.99342 -62.690212,-179.99342 -60.716231,-179.99342 -58.74225))", "dataset_titles": "Expedition Data", "datasets": [{"dataset_uid": "001992", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP0001"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a marine geological investigation of the Amundsen Sea region toward a better understanding of the deglaciation history of the West Antarctic Ice Sheet (WAIS). The WAIS may be inherently unstable because it is the last marine-based ice sheet in the world. Unlike other embayments in West Antarctica, major ice streams draining into the Amundsen Sea from the interior of the WAIS lack buttressing ice shelves. Mass balance data for the distal portions of these ice streams (Pine Island and Thwaites glaciers) appear to be in balance or may be becoming negative. Because both ice streams have beds that slope downward toward the center of the ice sheet, grounding-line recession resulting from either continued thinning or sea-level rise could trigger irreversible grounding-line retreat, leading to ice-sheet disintegration and consequent global sea-level rise. The limited marine geological and geophysical data available from the Amundsen Sea suggest that grounded ice or an ice shelf occupied the inner Amundsen Sea embayment until perhaps as recently as 1000 to 2000 years ago, and this ice may have retreated rapidly in historic time.\u003cbr/\u003e\u003cbr/\u003eThis project, a study of the marine geology and geophysics of the Amundsen Sea continental shelf from 100 degrees W to 130 degrees W, is designed to address the Amundsen Sea part of WAIS Science Plan Priority Goal H2: \"What is the deglaciation history in the eastern Ross, the Bellingshausen and Amundsen Seas?\" This project will examine bathymetric data of the Amundsen Sea continental shelf to determine the positions of former ice-steam channels, and to aid in choosing sites for sediment coring. Single-channel seismic reflection studies will be conducted in order to determine sediment-thickness patterns, to aid in choice of coring sites, and to locate and identify morphologic features indicative of former grounded ice (e.g., moraines, scours, flutes, striations, till wedges and deltas, etc.). Coring will be concentrated along former ice flow-lines. Core samples will be analyzed in the laboratory for sedimentology, to determine whether of not basal tills are present (indicating former grounded ice and its former extent), and for calcareous and siliceous microfossils. The chronology of grounding-line and ice-shelf retreat from a presumed Last Glacial Maximum position near the shelf break will be established using accelerator mass spectrometry (AMS) carbon-14 dates of acid-insoluble particulate organic carbon.\u003cbr/\u003e\u003cbr/\u003eThis project will share ship time in the Amundsen Sea with a physical oceanographic project. Marine geologic data and samples collected will be integrated with findings of other investigators toward developing a comprehensive interpretation of the history of the WAIS.", "east": 179.99344, "geometry": "POINT(0.000010000000003 -68.612155)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e MSBS", "is_usap_dc": false, "keywords": "R/V NBP", "locations": null, "north": -58.74225, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Kellogg, Thomas; Jacobs, Stanley", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "Other", "science_programs": null, "south": -78.48206, "title": "Glacial History of the Amundsen Sea Shelf", "uid": "p0000620", "west": -179.99342}, {"awards": "9615053 Domack, Eugene", "bounds_geometry": null, "dataset_titles": "Expedition data of LMG9802", "datasets": [{"dataset_uid": "002718", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of LMG9802", "url": "https://www.rvdata.us/search/cruise/LMG9802"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "Domack: OPP 9615053 Manley: OPP 9615670 Banerjee: OPP 9615695 Dunbar: OPP 9615668 Ishman: OPP 9615669 Leventer: OPP 9714371 Abstract This award supports a multi-disciplinary, multi-institutional effort to elucidate the detailed climate history of the Antarctic Peninsula during the Holocene epoch (the last 10,000 years). The Holocene is an important, but often overlooked, portion of the Antarctic paleoclimatic record because natural variability in Holocene climate on time scales of decades to millennia can be evaluated as a model for our present \"interglacial\" world. This project builds on over ten years of prior investigation into the depositional processes, productivity patterns and climate regime of the Antarctic Peninsula. This previous work identified key locations that contain ultra-high resolution records of past climatic variation. These data indicate that solar cycles operating on multi-century and millennial time scales are important regulators of meltwater production and paleoproductivity. These marine records can be correlated with ice core records in Greenland and Antarctica. This project will focus on sediment dispersal patterns across the Palmer Deep region. The objective is to understand the present links between the modern climatic and oceanographic systems and sediment distribution. In particular, additional information is needed regarding the influence of sea ice on the distribution of both biogenic and terrigenous sediment distribution. Sediment samples will be collected with a variety of grab sampling and coring devices. Analytical work will include carbon-14 dating of surface sediments using accellerator mass spectrometry and standard sedimentologic, micropaleontologic and magnetic granulometric analyses. This multiparameter approach is the most effective way to extract the paleoclimatic signals contained in the marine sediment cores. Two additional objectives are the deployment of sediment traps in front of the Muller Ice Shelf in Lallemand Fjord and seismic reflection work in conjunction with site augmentation funded through the Joint Oceanographic Institute. The goal of sediment trap work is to address whether sand transport and deposition adjacent to the ice shelf calving line results from meltwater or aeolian processes. In addition, the relationship between sea ice conditions and primary productivity will be investigated. The collection of a short series of seismic lines across the Palmer Deep basins will fully resolve the question of depth to acoustic basement. The combination of investigators on this project, all with many years of experience working in high latitude settings, provides an effective team to complete the project in a timely fashion. A combination of undergraduate, graduate and post-graduate students will be involved in all stages of the project so that educational objectives will be met in-tandem with research goals of the project.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": false, "keywords": "R/V LMG", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Domack, Eugene Walter", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V LMG", "repo": "R2R", "repositories": "Other", "science_programs": null, "south": null, "title": "Holocene Paleoenvironmental Change Along the Antarctic Peninsula: A Test of the Solar/Bi-Polar Signal", "uid": "p0000869", "west": null}, {"awards": "0636953 Saltzman, Eric", "bounds_geometry": "POINT(-148.82 -81.66)", "dataset_titles": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core; Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core; Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core; Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica; Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "datasets": [{"dataset_uid": "609598", "doi": "10.7265/N5X0650D", "keywords": "Antarctica; Chemistry:Fluid; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609598"}, {"dataset_uid": "609356", "doi": "10.7265/N56W9807", "keywords": "Antarctica; Atmosphere; Chemistry:Fluid; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Saltzman, Eric; Williams, Margaret; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609356"}, {"dataset_uid": "609600", "doi": "10.7265/N5PG1PPB", "keywords": "Antarctica; Chemistry:Fluid; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609600"}, {"dataset_uid": "601361", "doi": "10.15784/601361", "keywords": "Antarctica; Carbonyl Sulfide; Cryosphere; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/601361"}, {"dataset_uid": "609599", "doi": "10.7265/N5S75D8P", "keywords": "Antarctica; Chemistry:Fluid; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609599"}], "date_created": "Wed, 22 Oct 2008 00:00:00 GMT", "description": "Saltzman/0636953\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to measure methyl chloride, methyl bromide, and carbonyl sulfide in air extracted from Antarctic ice cores. Previous measurements in firn air and shallow ice cores suggest that the ice archive contains paleo-atmospheric signals for these gases. The goal of this study is to extend these records throughout the Holocene and into the last Glacial period to examine the behavior of these trace gases over longer time scales and a wider range of climatic conditions. These studies are exploratory, and both the stability of these trace gases and the extent to which they may be impacted by in situ processes will be assessed. This project will involve sampling and analyzing archived ice core samples from the Siple Dome, Taylor Dome, Byrd, and Vostok ice cores. The ice core samples will be analyzed by dry extraction, with gas chromatography/mass spectrometry with isotope dilution. The ice core measurements will generate new information about the range of natural variability of these trace gases in the atmosphere. The intellectual merit of this project is that this work will provide an improved basis for assessing the impact of anthropogenic activities on biogeochemical cycles, and new insight into the climatic sensitivity of the biogeochemical processes controlling atmospheric composition. The broader impact of this project is that there is a strong societal interest in understanding how man\u0027s activities impact the atmosphere, and how atmospheric chemistry may be altered by future climate change. The results of this study will contribute to the development of scenarios used for future projections of stratospheric ozone and climate change. In terms of human development, this project will support the doctoral dissertation of a graduate student in Earth System Science, and undergraduate research on polar ice core chemistry. This project will also contribute to the development of an Earth Sciences teacher training curriculum for high school teachers in the Orange County school system in collaboration with an established, NSF-sponsored Math and Science Partnership program (FOCUS).", "east": -148.82, "geometry": "POINT(-148.82 -81.66)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Methyl Bromide; Antarctic; Ice Core Gas Records; Ice Core Data; Atmospheric Chemistry; biogeochemical; Carbonyl Sulfide; West Antarctic Ice Sheet; LABORATORY; AGDC-project; Methyl Chloride; ice cores; Antarctic Ice Sheet; Ice Core; Siple Dome; Trace Gases; Ice Core Chemistry; West Antarctica", "locations": "Antarctic; Antarctica; Antarctic Ice Sheet; Siple Dome; West Antarctica; West Antarctic Ice Sheet", "north": -81.66, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core; Siple Dome Ice Core", "south": -81.66, "title": "Methyl Chloride, Methyl Bromide, and Carbonyl Sulfide in Deep Antarctic Ice Cores", "uid": "p0000042", "west": -148.82}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:Ice; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Cryosphere; gas measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:Fluid; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Williams, Margaret; Saltzman, Eric; Aydin, Murat; Tatum, Cheryl", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}, {"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:Ice; Cryosphere; Geochemistry; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; gas measurement; Carbonyl Sulfide; AWS Siple; Ice Sheet; Ice Core Data; Siple Coast; Antarctica; NSIDC; Trapped Gases; Glaciology; West Antarctica; Snow; Atmospheric Chemistry; Ice Core; AGDC; Stratigraphy; Ice Core Chemistry; LABORATORY; Chromatography; Methane; Mass Spectrometer; ice cores; Siple; GROUND-BASED OBSERVATIONS; WAISCORES; Mass Spectrometry; Not provided; GROUND STATIONS; Chloride (CL); OZONE DEPLETION; Atmospheric Gases; MSA; Siple Dome", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}, {"awards": "9725305 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "datasets": [{"dataset_uid": "609098", "doi": "10.7265/N51N7Z2P", "keywords": "Antarctica; Atmosphere; Chemistry:Ice; Cryosphere; Geochemistry; Glaciology; Isotope; Paleoclimate; Siple Dome; Snow/Ice; South Pole; Temperature", "people": "Grachev, Alexi; Severinghaus, Jeffrey P.; Battle, Mark", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "url": "https://www.usap-dc.org/view/dataset/609098"}], "date_created": "Mon, 01 Jan 2001 00:00:00 GMT", "description": "9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Isotopic History; GROUND STATIONS; Thermal Fractionation; Thermal Diffusion; Polar Firn Air; Firn Temperature Measurements; Isotopic Anomalies; Xenon; Not provided; mass spectrometers; Atmospheric Gases; Argon Isotopes; Siple Dome; Krypton; Oxygen Isotopes; Trapped Air Bubbles; Nitrogen Isotopes; Seasonal Temperature Changes; Boreholes; Shallow Firn Air; Antarctica; Ice Core Gas Records; Firn Air Isotopes; Firn Air Isotope Measurements; South Pole; Seasonal Temperature Gradients; Firn Isotopes; Mass Spectrometry; GROUND-BASED OBSERVATIONS", "locations": "Antarctica; Siple Dome; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change", "uid": "p0000160", "west": null}]

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