USAP-DC

{"dp_type": "Project", "free_text": "isotope ratios"}

[{"awards": "2123491 John, Seth; 2123354 Conway, Timothy; 2123333 Fitzsimmons, Jessica", "bounds_geometry": "POLYGON((-135 -66,-131.5 -66,-128 -66,-124.5 -66,-121 -66,-117.5 -66,-114 -66,-110.5 -66,-107 -66,-103.5 -66,-100 -66,-100 -67,-100 -68,-100 -69,-100 -70,-100 -71,-100 -72,-100 -73,-100 -74,-100 -75,-100 -76,-103.5 -76,-107 -76,-110.5 -76,-114 -76,-117.5 -76,-121 -76,-124.5 -76,-128 -76,-131.5 -76,-135 -76,-135 -75,-135 -74,-135 -73,-135 -72,-135 -71,-135 -70,-135 -69,-135 -68,-135 -67,-135 -66))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 08 Sep 2022 00:00:00 GMT", "description": "The goal of the international GEOTRACES program is to understand the distributions of trace chemical elements and their isotopes (TEIs) in the oceans. Many trace metals such as iron are essential for life and thus considered nutrients for phytoplankton growth, with trace metal cycling being especially important for influencing carbon cycling in the iron-limited Southern Ocean, where episodic supply of iron from a range of different external sources is important. The primary goal of this project is to measure the dissolved concentrations, size partitioning, and dissolved isotope signature of Fe on a transect of water-column stations throughout the Amundsen Sea and surrounding region of the Antarctic Margin, as part of the GP17-ANT Expedition. The secondary goal of this project is to analyze the concentrations and size partitioning of the trace metals manganese, zinc, copper, cadmium, nickel, and lead in all water-column samples, measure the isotope ratios of zinc, cadmium, nickel, and copper in a subset of water column samples, and measure the Fe isotopic signature of aerosols, porewaters, and particles. Observations from this project will be incorporated into regional and global biogeochemistry models to assess TEI cycling within the Amundsen Sea and implications for the wider Southern Ocean. This project spans three institutions, four graduate students, undergraduate students, and will provide ultrafiltered samples and data to other PIs as service.\r\n\r\nThe US GEOTRACES GP17 ANT expedition, planned for austral summer 2023/2024 aims to determine the distribution and cycling of trace elements and their isotopes in the Amundsen Sea Sector (100-135\u00b0W) of the Antarctic Margin. The cruise will follow the Amundsen Sea \u2018conveyor belt\u2019 by sampling waters coming from the Antarctic Circumpolar Current onto the continental shelf, including near the Dotson and Pine Island ice shelves, the productive Amundsen Sea Polynya (ASP), and outflowing waters. Episodic addition of dissolved Fe and other TEIs from dust, ice-shelves, melting ice, and sediments drive seasonal primary productivity and carbon export over the Antarctic shelf and offshore into Southern Ocean. Seasonal coastal polynyas such as the highly productive ASP thus act as key levers on global carbon cycling. However, field observations of TEIs in such regions remain scarce, and biogeochemical cycling processes are poorly captured in models of ocean biogeochemistry. The investigators will use their combined analytical toolbox, in collaboration with the diagnostic chemical tracers and regional models of other funded groups to address four main objectives: 1) What is the relative importance of different sources in supplying Fe and other TEIs to the ASP? 2) What is the physiochemical speciation of this Fe, and its potential for transport? 3) How do biological uptake, scavenging and regeneration in the ASP influence TEI distributions, stoichiometry, and nutrient limitation? 4) What is the flux and signature of TEIs transported offshore to the ACC and Southern Ocean?", "east": -100.0, "geometry": "POINT(-117.5 -71)", "instruments": null, "is_usap_dc": true, "keywords": "R/V NBP; Amundsen Sea; TRACE ELEMENTS; BIOGEOCHEMICAL CYCLES", "locations": "Amundsen Sea", "north": -66.0, "nsf_funding_programs": "Chemical Oceanography; Chemical Oceanography; Chemical Oceanography", "paleo_time": null, "persons": "Conway, Timothy; Fitzsimmons, Jessica; John, Seth", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repositories": null, "science_programs": null, "south": -76.0, "title": "Collaborative Research: US GEOTRACES GP17-ANT: Dissolved concentrations, isotopes, and colloids of the bioactive trace metals", "uid": "p0010374", "west": -135.0}, {"awards": "1443105 Steig, Eric", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "Continuous-flow measurements of the complete water isotope ratios (D/H, 17O/16O, 18O/16) from the South Pole ice core; South Pole high resolution ice core water stable isotope record for dD, d18O; South Pole Ice Core Holocene Major Ion Dataset; SP19 Gas Chronology; Temperature, accumulation rate, and layer thinning from the South Pole ice core (SPC14)", "datasets": [{"dataset_uid": "601399", "doi": "10.15784/601399", "keywords": "Antarctica; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Holocene Major Ion Dataset", "url": "https://www.usap-dc.org/view/dataset/601399"}, {"dataset_uid": "601239", "doi": "10.15784/601239", "keywords": "Antarctica; Cavity Ring Down Spectrometers; Delta 18O; Delta Deuterium; Deuterium Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core; Ice Core Chemistry; Ice Core Data; Oxygen Isotope; Snow/ice; Snow/Ice; Stable Isotopes", "people": "Schauer, Andrew; Jones, Tyler R.; White, James; Steig, Eric J.; Morris, Valerie; Vaughn, Bruce; Kahle, Emma", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole high resolution ice core water stable isotope record for dD, d18O", "url": "https://www.usap-dc.org/view/dataset/601239"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601396", "doi": "10.15784/601396", "keywords": "Accumulation; Antarctica; Diffusion Length; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Dynamic; Layer Thinning; Oxygen Isotope; South Pole; SPICEcore; Temperature", "people": "Vaughn, Bruce; White, James; Epifanio, Jenna; Buizert, Christo; Waddington, Edwin D.; Conway, Howard; Stevens, Max; Schauer, Andrew; Morris, Valerie; Koutnik, Michelle; Fudge, T. J.; Jones, Tyler R.; Steig, Eric J.; Kahle, Emma", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Temperature, accumulation rate, and layer thinning from the South Pole ice core (SPC14)", "url": "https://www.usap-dc.org/view/dataset/601396"}, {"dataset_uid": "601429", "doi": "10.15784/601429", "keywords": "Antarctica; Climate; Deuterium; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Hydrogen; Ice; Ice Core; Ice Core Chemistry; Oxygen; Paleoclimate; Snow/ice; Snow/Ice; South Pole; Stable Isotopes", "people": "Steig, Eric J.; White, James; Kahle, Emma; Schauer, Andrew; Vaughn, Bruce; Jones, Tyler R.; Morris, Valerie", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Continuous-flow measurements of the complete water isotope ratios (D/H, 17O/16O, 18O/16) from the South Pole ice core", "url": "https://www.usap-dc.org/view/dataset/601429"}], "date_created": "Sun, 17 Nov 2019 00:00:00 GMT", "description": "This project will develop a record of the stable-isotope ratios of water from an ice core at the South Pole, Antarctica. Water-isotope ratio measurements provide a means to determine variability in temperature through time. South Pole is distinct from most other locations in Antarctica in showing no warming in recent decades, but little is known about temperature variability in this location prior to the installation of weather stations in 1957. The measurements made as part of this project will result in a much longer temperature record, extending at least 40,000 years, aiding our ability to understand what controls Antarctic climate, and improving projections of future Antarctic climate change. Data from this project will be critical to other investigators working on the South Pole ice core, and of general interest to other scientists and the public. Data will be provided rapidly to other investigators and made public as soon as possible.\u003cbr/\u003e\u003cbr/\u003eThis project will obtain records of the stable-isotope ratios of water on the ice core currently being obtained at South Pole. The core will reach a depth of 1500 m and an age of 40,000 years. The project will use laser spectroscopy to obtain both an ultra-high-resolution record of oxygen 18/16 and deuterium-hydrogen ratios, and a lower-resolution record of oxygen 17/16 ratios. The high-resolution measurements will be used to aid in dating the core, and to provide estimates of isotope diffusion that constrain the process of firn densification. The novel 17/16 measurement provides additional constraints on the isotope fractionation due to the temperature-dependent supersaturation ratio, which affects the fractionation of water during the liquid-solid condensate transition. Together, these techniques will allow for improved accuracy in the use of the water isotope ratios as proxies for ice-sheet temperature, sea-surface temperature, and atmospheric circulation. The result will be a record of decadal through centennial and millennial scale climate change in a climatically distinct region in East Antarctica that has not been previously sampled by deep ice coring. The project will support a graduate student who will be co-advised by faculty at the University of Washington and the University of Colorado, and will be involved in all aspects of the work.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "SPICEcore; D18O; LABORATORY; OXYGEN ISOTOPE ANALYSIS; Oxygen Isotope; South Pole; USAP-DC; GLACIERS/ICE SHEETS; Antarctica; AMD; FIELD INVESTIGATION; Ice Core", "locations": "Antarctica; South Pole", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Steig, Eric J.; White, James", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Record of the Triple-oxygen Isotope and Hydrogen Isotope Composition of Ice from an Ice Core at South Pole", "uid": "p0010065", "west": 0.0}, {"awards": "1543267 Brook, Edward; 1543229 Severinghaus, Jeffrey", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Multi-site ice core Krypton stable isotope ratios; Noble Gas Data from recent ice in Antarctica for 86Kr problem", "datasets": [{"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Mulvaney, Robert; Severinghaus, Jeffrey P.; Buizert, Christo; Pyne, Rebecca L.; Brook, Edward J.; Shackleton, Sarah; Baggenstos, Daniel; Mosley-Thompson, Ellen; Bertler, Nancy; Etheridge, David; Bereiter, Bernhard", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601195", "doi": "10.15784/601195", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Krypton; Noble Gas; Xenon", "people": "Shackleton, Sarah; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Noble Gas Data from recent ice in Antarctica for 86Kr problem", "url": "https://www.usap-dc.org/view/dataset/601195"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Bertler, Nancy; Etheridge, David; Baggenstos, Daniel; Brook, Edward J.; Severinghaus, Jeffrey P.; Pyne, Rebecca L.; Mulvaney, Robert; Buizert, Christo; Mosley-Thompson, Ellen; Bereiter, Bernhard; Shackleton, Sarah", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Buizert, Christo; Severinghaus, Jeffrey P.; Shackleton, Sarah; Bertler, Nancy; Brook, Edward J.; Baggenstos, Daniel; Bereiter, Bernhard; Mosley-Thompson, Ellen; Etheridge, David; Pyne, Rebecca L.; Mulvaney, Robert", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}], "date_created": "Wed, 10 Jul 2019 00:00:00 GMT", "description": "Overview: The funded work investigated whether ice core 86Kr acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere (SH) westerly winds. Pressure variations drive macroscopic air movement in the firn column, which reduces the gravitational isotopic enrichment of slow-diffusing gases (such as Kr). The 86Kr deviation from gravitational equilibrium (denoted D86Kr) thus reflects the magnitude of pressure variations (among other things). Atmospheric reanalysis data suggest that pressure variability over Antarctica is linked to the Southern Annular Mode (SAM) index and the position of the SH westerly winds. Preliminary data from the WAIS Divide ice core show a large excursion in D86Kr during the last deglaciation (20-9 ka before present). In this project the investigators (1) performed high-precision 86Kr analysis on ice core and firn air samples to establish whether D86Kr is linked to pressure variability; (2) Refined the deglacial WAIS Divide record of Kr isotopes; (3) Investigated the role of pressure variability in firn air transport using firn air models with firn microtomography data and Lattice- Boltzmann modeling; and (4) Investigated how barometric pressure variability in Antarctica is linked to the SAM index and the position/strength of the SH westerlies in past and present climates using GCM and reanalysis data. A key finding was that D86Kr in recent ice samples (e.g. last 50 years) from a broad spatial array of sites in Antarctica and Greenland showed a significant correlation with directly measured barometric pressure variability at the ice core site. This strongly supports the hypothesis that 86Kr can be used as a paleo-proxy for storminess.\r\nIntellectual Merit: The SH westerlies are a key component of the global climate system; they are an important control on the global oceanic overturning circulation and possibly on atmospheric CO2 concentrations. Poleward movement of the SH westerlies during the last deglaciation has been hypothesized, yet evidence from proxy and modeling studies remains inconclusive. The funded work could provide valuable new constraints on deglacial movement of the SH westerlies. This record can be compared to high-resolution CO2 data from the same core, allowing us to test hypotheses that link CO2 to the SH westerlies. Climate proxies are at the heart of paleoclimate research. The funded work has apparently led to the discovery of a completely new proxy, opening up exciting new research possibilities and increasing the scientific value of existing ice cores. Once validated, the 86Kr proxy could be applied to other time periods as well, providing a long-term perspective on the movement of the SH westerlies. The funded work has furthermore provided valuable new insights into firn air transport. \r\n\r\nBroader impact: The Southern Ocean is presently an important sink of atmospheric CO2, thereby reducing the warming associated with anthropogenic CO2 emissions. Stratospheric ozone depletion and greenhouse warming have displaced the SH westerlies poleward, with potential consequences for the future magnitude of this oceanic carbon uptake. The funded work may provide a paleo-perspective on past movement of the SH westerlies and its link to atmospheric CO2, which could guide projections of future oceanic CO2 uptake, with strong societal benefits. The awarded funds supported and trained an early-career postdoctoral scholar at OSU, and fostered (international) collaboration. Data from the study will be available to the scientific community and the broad public through recognized data centers. During this project the PI and senior personnel have continued their commitment to public outreach through media interviews and speaking to schools and the public about their work. The PI provides services to the community by chairing the IPICS (International Partnership in Ice Core Sciences) working group and organizing annual PIRE (Partnerships in International Research and Education) workshops.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "USA/NSF; FIRN; ICE CORE RECORDS; USAP-DC; Greenland; Xenon; Noble Gas; Ice Core; Amd/Us; Antarctica; AMD; LABORATORY; Krypton; ATMOSPHERIC PRESSURE", "locations": "Greenland; Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Collaborative research: Kr-86 as a proxy for barometric pressure variability and movement of the SH westerlies during the last\r\ndeglaciation", "uid": "p0010037", "west": -180.0}, {"awards": "1443472 Brook, Edward; 1443464 Sowers, Todd; 1443710 Severinghaus, Jeffrey", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole CH4 data for termination; South Pole Ice Core Isotopes of N2 and Ar; South Pole ice core (SPC14) discrete methane data; South Pole ice core total air content; South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2; SP19 Gas Chronology", "datasets": [{"dataset_uid": "601231", "doi": "10.15784/601231", "keywords": "Air Content; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core total air content", "url": "https://www.usap-dc.org/view/dataset/601231"}, {"dataset_uid": "601152", "doi": "10.15784/601152", "keywords": "Antarctica; Antarctic Ice Sheet; Chemistry:gas; Chemistry:Gas; Chemistry:ice; Chemistry:Ice; Delta 18O; Dole Effect; Firn Thickness; Gas Isotopes; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Gravitational Settling; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Inert Gases; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2", "url": "https://www.usap-dc.org/view/dataset/601152"}, {"dataset_uid": "601230", "doi": "10.15784/601230", "keywords": "Antarctica; Atmospheric CH4; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Data; Methane; Methane Concentration; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole CH4 data for termination", "url": "https://www.usap-dc.org/view/dataset/601230"}, {"dataset_uid": "601517", "doi": "10.15784/601517", "keywords": "Antarctica; Argon; Argon Isotopes; Firn; Firn Temperature Gradient; Firn Thickness; Gas Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Nitrogen; Nitrogen Isotopes; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.; Morgan, Jacob", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Isotopes of N2 and Ar", "url": "https://www.usap-dc.org/view/dataset/601517"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kreutz, Karl; Buizert, Christo; Brook, Edward J.; Epifanio, Jenna; Severinghaus, Jeffrey P.; Kennedy, Joshua A.; Ferris, David G.; Kalk, Michael; Hood, Ekaterina; Fudge, T. J.; Osterberg, Erich; Winski, Dominic A.; Steig, Eric J.; Kahle, Emma; Sowers, Todd A.; Edwards, Jon S.; Aydin, Murat", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}], "date_created": "Sat, 02 Feb 2019 00:00:00 GMT", "description": "Gases trapped in ice cores have revealed astonishing things about the greenhouse gas composition of the past atmosphere, including the fact that carbon dioxide concentrations never rose above 300 parts per million during the last 800,000 years. This places today\u0027s concentration of 400 parts per million in stark contrast. Furthermore, these gas records show that natural sources of greenhouse gas such as oceans and ecosystems act as amplifiers of climate change by increasing emissions of gases during warmer periods. Such amplification is expected to occur in the future, adding to the human-produced gas burden. The South Pole ice core will build upon these prior findings by expanding the suite of gases to include, for the first time, those potent trace gases that both trapped heat and depleted ozone during the past 40,000 years. The present project on inert gases and methane in the South Pole ice core will improve the dating of this crucial record, to unprecedented precision, so that the relative timing of events can be used to learn about the mechanism of trace gas production and destruction, and consequent climate change amplification. Ultimately, this information will inform predictions of future atmospheric chemical cleansing mechanisms and climate in the context of our rapidly changing atmosphere. This award also engages young people in the excitement of discovery and polar research, helping to entrain the next generations of scientists and educators. Education of graduate students, a young researcher (Buizert), and training of technicians, will add to the nation?s human resource base. \u003cbr/\u003e \u003cbr/\u003eThis award funds the construction of the gas chronology for the South Pole 1500m ice core, using measured inert gases (d15N and d40Ar--Nitrogen and Argon isotope ratios, respectively) and methane in combination with a next-generation firn densification model that treats the stochastic nature of air trapping and the role of impurities on densification. The project addresses fundamental gaps in scientific understanding that limit the accuracy of gas chronologies, specifically a poor knowledge of the controls on ice-core d15N and the possible role of layering and impurities in firn densification. These gaps will be addressed by studying the gas enclosure process in modern firn at the deep core site. The work will comprise the first-ever firn air pumping experiment that has tightly co-located measurements of firn structural properties on the core taken from the same borehole.\u003cbr/\u003e\u003cbr/\u003eThe project will test the hypothesis that the lock-in horizon as defined by firn air d15N, CO2, and methane is structurally controlled by impermeable layers, which are in turn created by high-impurity content horizons in which densification is enhanced. Thermal signals will be sought using the inert gas measurements, which improve the temperature record with benefits to the firn densification modeling. Neon, argon, and oxygen will be measured in firn air and a limited number of deep core samples to test whether glacial period layering was enhanced, which could explain low observed d15N in the last glacial period. Drawing on separate volcanic and methane synchronization to well-dated ice cores to create independent ice and gas tie points, independent empirical estimates of the gas age-ice age difference will be made to check the validity of the firn densification model-inert gas approach to calculating the gas age-ice age difference. These points will also be used to test whether the anomalously low d15N seen during the last glacial period in east Antarctic ice cores is due to deep air convection in the firn, or a missing impurity dependence in the firn densification models. \u003cbr/\u003e\u003cbr/\u003eThe increased physical understanding gained from these studies, combined with new high-precision measurements, will lead to improved accuracy of the gas chronology of the South Pole ice core, which will enhance the overall science return from this gas-oriented core. This will lead to clarification of timing of atmospheric gas variations and temperature, and aid in efforts to understand the biogeochemical feedbacks among trace gases. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. Ozone-depleting substances will be measured in the South Pole ice core record, and a precise gas chronology will add value. Lastly, by seeking a better understanding of the physics of gas entrapment, the project aims to have an impact on ice-core science in general.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "USAP-DC; AMD; LABORATORY; Antarctica; NITROGEN ISOTOPES; USA/NSF; METHANE; Amd/Us; FIELD INVESTIGATION", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Sowers, Todd A.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Inert Gas and Methane Based Climate Records throughout the South Pole Deep Ice Core", "uid": "p0010005", "west": 0.0}, {"awards": "1443263 Higgins, John; 1443306 Mayewski, Paul", "bounds_geometry": null, "dataset_titles": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores; Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores; Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores; Greenhouse gas composition in the Allan Hills S27 ice core; Methane concentration in Allan Hills ice cores; Stable isotope composition of the trapped air in the Allan Hills S27 ice core; Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "datasets": [{"dataset_uid": "601203", "doi": "10.15784/601203", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Chemistry:ice; Chemistry:Ice; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenhouse Gas; Ice; Ice Core Data; Ice Core Gas Records; Methane; Snow/ice; Snow/Ice", "people": "Brook, Edward J.; Yan, Yuzhen; Bender, Michael; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Methane concentration in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601203"}, {"dataset_uid": "601512", "doi": "10.15784/601512", "keywords": "Allan Hills; Antarctica; Blue Ice; Ice Core; Ice Core Gas Records; Isotope; Nitrogen; Oxygen", "people": "Higgins, John; Yan, Yuzhen; Bender, Michael", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable isotope composition of the trapped air in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601512"}, {"dataset_uid": "601201", "doi": "10.15784/601201", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Argon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Data; Ice Core Gas Records; Krypton; Mass Spectrometer; Noble Gas; Snow/ice; Snow/Ice; Xenon", "people": "Bender, Michael; Higgins, John; Yan, Yuzhen; Ng, Jessica; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601201"}, {"dataset_uid": "601483", "doi": "10.15784/601483", "keywords": "Allan Hills; Antarctica; Argon; Ice; Ice Core Data; Ice Core Gas Records; Isotope; Mass Spectrometry; Nitrogen; Oxygen", "people": "Bender, Michael; Yan, Yuzhen; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601483"}, {"dataset_uid": "601130", "doi": "10.15784/601130", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Delta Deuterium; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Gas Records; Ice Core Records; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Introne, Douglas; Kurbatov, Andrei V.; Mayewski, Paul A.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601130"}, {"dataset_uid": "601129", "doi": "10.15784/601129", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Isotope Data; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Yan, Yuzhen; Kurbatov, Andrei V.; Introne, Douglas; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601129"}, {"dataset_uid": "601128", "doi": "10.15784/601128", "keywords": "Allan Hills; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope Record; Mass Spectrometry; Stable Water Isotopes", "people": "Mayewski, Paul A.; Kurbatov, Andrei V.; Yan, Yuzhen; Introne, Douglas", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601128"}, {"dataset_uid": "601425", "doi": "10.15784/601425", "keywords": "Allan Hills; Antarctica; Blue Ice; Carbon Dioxide; Ice Core; Methane", "people": "Yan, Yuzhen; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Greenhouse gas composition in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601425"}, {"dataset_uid": "601202", "doi": "10.15784/601202", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Carbon Dioxide; Carbon Isotopes; Chemistry:ice; Chemistry:Ice; CO2; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Data; Ice Core Gas Records; Ice Core Records; Mass Spectrometer; Mass Spectrometry; Methane; Snow/ice; Snow/Ice", "people": "Bender, Michael; Yan, Yuzhen; Higgins, John; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601202"}], "date_created": "Thu, 18 Oct 2018 00:00:00 GMT", "description": "Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800,000 years. Previous field expeditions to the Allan Hills blue ice area, Antarctica, have recovered ice cores that date to one million years, the oldest ice cores yet recovered from Antarctica. These records have revealed that interglacial CO2 concentrations decreased by 800,000 years ago and that, in the warmer world 1 million years ago, CO2 and Antarctic temperature were linked as during the last 800,000 years. This project will return to the Allan Hills blue ice area to recover additional ice cores that date to 1 million years or older. The climate records developed from the drilled ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Our results will help answer questions about issues associated with anthropogenic change. These include the relationship between temperature change and the mass balance of Antarctic ice; precipitation and aridity variations associated with radiatively forced climate change; and the climate significance of sea ice extent. The project will entrain two graduate students and a postdoctoral scholar, and will conduct outreach including workshops to engage teachers in carbon science and ice cores.\u003cbr/\u003e\u003cbr/\u003eBetween about 2.8-0.9 million years ago, Earth\u0027s climate was characterized by 40,000-year cycles, driven or paced by changes in the tilt of Earth\u0027s spin axis. Much is known about the \"40,000-year\" world from studies of deep-sea sediments, but our understanding of climate change during this period is incomplete because we lack records of Antarctic climate and direct records of atmospheric greenhouse gas concentrations. We propose to address these issues by building on our recent studies of ancient ice from the Main Ice Field, Allan Hills, Antarctica. During previous field seasons we recovered ice extending, discontinuously, from 0.1-1.0 million years old. Ice was dated by measuring the 40Ar/38Ar (Argon) ratio of the trapped gases. Our discovery of million year-old ice demonstrates that there is gas-record-quality ice from the 40,000-year world in the Allan Hills Main Ice Field. We have identified two different sites, each overlying bedrock at ~ 200 m depth, that are attractive targets for coring ice dating to 1 million years and older. This project aims to core the ice at these two sites, re-occupy a previous site with million year-old ice and drill it down to the bedrock, and generate 10-20 short (~10-meter) cores in areas where our previous work and terrestrial meteorite ages suggest ancient surface ice. We plan to date the ice using the 40Ar/38Ar ages of trapped Argon. We also plan to characterize the continuity of our cores by measuring the deuterium and oxygen isotope ratios in the ice, methane, ratios of Oxygen and Argon to Nitrogen in trapped gas, the Nitrogen-15 isotope (d15N) of Nitrogen, and the Oxygen-18 isotope (d18O) of Oxygen. As the ice may be stratigraphically disturbed, these measurements will provide diagnostic properties for assessing the continuity of the ice-core records. Successful retrieval of ice older than one million years will provide the opportunity for follow-up work to measure the CO2 concentration and other properties within the ice to inform on the temperature history of the Allan Hills region, dust sources and source-area aridity, moisture sources, densification conditions, global average ocean temperature, and greenhouse gas concentrations. We will analyze the data in the context of leading hypotheses of the 40,000-year world and the Mid-Pleistocene Transition to the 100,000-year world. We expect to advance understanding of climate dynamics during these periods.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Amd/Us; AMD; Allan Hills; USA/NSF; FIELD INVESTIGATION; USAP-DC; Ice Core; LABORATORY", "locations": "Allan Hills", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Mayewski, Paul A.; Kurbatov, Andrei V.; Higgins, John; Bender, Michael", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Allan Hills", "south": null, "title": "Collaborative Research: Window into the World with 40,000-year Glacial Cycles from Climate Records in Million Year-old Ice from the Allan Hills Blue Ice Area", "uid": "p0000760", "west": null}, {"awards": "1341360 Steig, Eric", "bounds_geometry": "POINT(106 -77.5)", "dataset_titles": "Seasonal 17O Isotope Data from Lake Vostok and WAIS Divide Snow Pits", "datasets": [{"dataset_uid": "601031", "doi": "10.15784/601031", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Lake Vostok; Snow Pit; WAIS Divide Ice Core", "people": "Schoenemann, Spruce; Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Seasonal 17O Isotope Data from Lake Vostok and WAIS Divide Snow Pits", "url": "https://www.usap-dc.org/view/dataset/601031"}], "date_created": "Tue, 06 Jun 2017 00:00:00 GMT", "description": "Steig/1341360\u003cbr/\u003e\u003cbr/\u003eThis award supports a two-year project to develop a method for rapid and precise measurements of the difference in 18O/16O and 17O/16O isotope ratios in water, referred to as the 17O-excess. Measurement of 17O-excess is a recent innovation in geochemistry, complementing traditional measurements of the ratios of hydrogen (D/H) and oxygen (18O/16O). Conventional measurements of 17O/16O are limited in number because of the time-consuming and laborious nature of the analyses, which involves the conversion of water to oxygen via fluorination, followed by high-precision mass spectrometry. This project will use a novel cavity ring-down spectroscopy (CRDS) system developed by a joint effort of the University of Washington and Picarro, Inc. (Santa Clara, CA), along with the Centre for Ice and Climate (Neils Bohr Institute, Copenhagen). The primary intellectual merit of the research is the improvement of the CRDS method for measurements of 17Oexcess of discrete samples of water, to obtain precision and accuracy competitive with conventional methods using mass spectrometry. This will be achieved by quantification of the effects of water vapor concentration variability and instrument memory, precise calibration of the instrument against standard waters, and improvements to the spectroscopic analyses. The CRDS system will also be coupled to continuous-flow systems for ice core analysis, in collaboration with the University of Colorado, Boulder. The goal is to have an operational system available for ice core processing associated with the next major U.S.-led ice core project at South Pole, in 2015-2017. The broader impacts of the research include the ability to measure 17O-excess in ambient atmospheric water vapor, which can be used to improve understanding of convection, moisture transport, and condensation. The instrument development work proposed here is relevant to research supported by several NSF-GEO programs, including Hydrology, Climate and Large Scale Dynamics, Paleoclimate, Atmosphere Chemistry, and both the Arctic and Antarctic Programs. This proposal will support a postdoctoral researcher.", "east": 106.0, "geometry": "POINT(106 -77.5)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -77.5, "nsf_funding_programs": "Antarctic Instrumentation and Support; Antarctic Glaciology", "paleo_time": null, "persons": "Steig, Eric J.", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -77.5, "title": "Development of a Laser Spectroscopy System for Analysis of 17Oexcess on Ice Cores", "uid": "p0000316", "west": 106.0}, {"awards": "0538520 Thiemens, Mark; 0538049 Steig, Eric", "bounds_geometry": "POINT(-112.085 -79.5)", "dataset_titles": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core; WAIS Divide sulfate and nitrate isotopes; WAIS ice core isotope data #387, 385 (full data link not provided)", "datasets": [{"dataset_uid": "601007", "doi": "10.15784/601007", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Nitrate; Oxygen Isotope; Sulfate; WAIS Divide; WAIS Divide Ice Core", "people": "Alexander, Becky; Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide sulfate and nitrate isotopes", "url": "https://www.usap-dc.org/view/dataset/601007"}, {"dataset_uid": "609479", "doi": "10.7265/N5BG2KXH", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Thiemens, Mark H.", "repository": "USAP-DC", "science_program": null, "title": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609479"}, {"dataset_uid": "002512", "doi": "", "keywords": null, "people": null, "repository": "Project website", "science_program": null, "title": "WAIS ice core isotope data #387, 385 (full data link not provided)", "url": "http://www.waisdivide.unh.edu/"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "0538520\u003cbr/\u003eThiemens\u003cbr/\u003eThis award supports a project to develop the first complete record of multiple isotope ratios of nitrate and sulfate covering the last ~100,000 years, from the deep ice core planned for the central ice divide of the West Antarctic Ice Sheet (WAIS). The WAIS Divide ice core will be the highest resolution long ice core obtained from Antarctica and we can expect important complementary information to be available, including accurate knowledge of past accumulation rates, temperatures, and compounds such as H2O2, CO and CH4. These compounds play significant roles in global atmospheric chemistry and climate. Especially great potential lies in the use of multiple isotope signatures. The unique mass independent fractionation (MIF) 17O signature of ozone is observed in both nitrate and sulfate, due to the interaction of their precursors with ozone. The development of methods to measure the multiple-isotope composition of small samples of sulfate and nitrate makes continuous high resolution measurements on ice cores feasible for the first time. Recent work has shown that such measurements can be used to determine the hydroxyl radial (OH) and ozone (O3) concentrations in the paleoatmosphere as well as to apportion sulfate and nitrate sources. There is also considerable potential in using these isotope measurements to quantify post depositional changes. In the first two years, continuous measurements from the upper ~100-m of ice at WAIS divide will be obtained, to provide a detailed look at seasonal through centennial scale variability. In the third year, measurements will be made throughout the available depth of the deep core (expected to reach ~500 m at this time). The broader impacts of the project include applications to diverse fields including atmospheric chemistry, glaciology, meteorology, and paleoclimatology. Because nitrate and sulfate are important atmospheric pollutants, the results will also have direct and relevance to global environmental policy. This project will coincide with the International Polar Year (2007-2008), and contributes to goals of the IPY, which include the fostering of interdisciplinary research toward enhanced understanding of atmospheric chemistry and climate in the polar regions.", "east": -112.085, "geometry": "POINT(-112.085 -79.5)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Isotope Ratios; Temperature; Sulfate; West Antarctic; Paleoatmosphere; LABORATORY; Ice Core; Ice Core Data; Mass Independent Fractionation; FIELD SURVEYS; Not provided; Accumulation Rate; Oxygen Isotope; FIELD INVESTIGATION; Ice Core Chemistry; Isotope", "locations": "West Antarctic", "north": -79.5, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Alexander, Becky; Steig, Eric J.; Thiemens, Mark H.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "Project website; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.5, "title": "Collaborative Research: Multiple-isotope Analysis of Nitrate and Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "uid": "p0000020", "west": -112.085}, {"awards": "1043167 White, James; 1043092 Steig, Eric", "bounds_geometry": "POINT(-112.08 -79.47)", "dataset_titles": "Resampling of Deep Polar Ice Cores using Information Theory; Seasonal temperatures in West Antarctica during the Holocene ; Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core; WAIS Divide Ice Core Discrete CH4 (80-3403m)", "datasets": [{"dataset_uid": "600169", "doi": "10.15784/600169", "keywords": "Antarctica; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Paleoclimate; Snow Accumulation; WAIS Divide; WAIS Divide Ice Core", "people": "Jones, Tyler R.; Morris, Valerie; Vaughn, Bruce; White, James", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "url": "https://www.usap-dc.org/view/dataset/600169"}, {"dataset_uid": "601741", "doi": "10.15784/601741", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; WAIS", "people": "Sowers, Todd A.; Brook, Edward", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Ice Core Discrete CH4 (80-3403m)", "url": "https://www.usap-dc.org/view/dataset/601741"}, {"dataset_uid": "601365", "doi": "10.15784/601365", "keywords": "Antarctica; Delta 18O; Isotope; WAIS Divide; WAIS Divide Ice Core; West Antarctic Ice Sheet", "people": "White, James; Jones, Tyler R.; Garland, Joshua; Vaughn, Bruce; Morris, Valerie", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Resampling of Deep Polar Ice Cores using Information Theory", "url": "https://www.usap-dc.org/view/dataset/601365"}, {"dataset_uid": "601603", "doi": "10.15784/601603", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Seasonality; Seasonal Temperatures; Temperature; Water Isotopes; West Antarctic Ice Sheet", "people": "Jones, Tyler R.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Seasonal temperatures in West Antarctica during the Holocene ", "url": "https://www.usap-dc.org/view/dataset/601603"}, {"dataset_uid": "601274", "doi": "10.15784/601274", "keywords": "Antarctica; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core; West Antarctic Ice Sheet", "people": "Price, Michael; Garland, Joshua; Bradley, Elizabeth; Morris, Valerie; Jones, Tyler R.; White, James; Vaughn, Bruce", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "url": "https://www.usap-dc.org/view/dataset/601274"}], "date_created": "Thu, 15 Sep 2016 00:00:00 GMT", "description": "Steig/1043092\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to contribute one of the cornerstone analyses, stable isotopes of ice (Delta-D, Delta-O18) to the ongoing West Antarctic Ice Sheet Divide (WAIS) deep ice core. The WAIS Divide drilling project, a multi-institution project to obtain a continuous high resolution ice core record from central West Antarctica, reached a depth of 2560 m in early 2010; it is expected to take one or two more field seasons to reach the ice sheet bed (~3300 m), plus an additional four seasons for borehole logging and other activities including proposed replicate coring. The current proposal requests support to complete analyses on the WAIS Divide core to the base, where the age will be ~100,000 years or more. These analyses will form the basis for the investigation of a number of outstanding questions in climate and glaciology during the last glacial period, focused on the dynamics of the West Antarctic Ice Sheet and the relationship of West Antarctic climate to that of the Northern polar regions, the tropical Pacific, and the rest of the globe, on time scales ranging from years to tens of thousands of years. One new aspect of this work is the growing expertise at the University of Washington in climate modeling with isotope-tracer-enabled general circulation models, which will aid in the interpretation of the data. Another major new aspect is the completion and use of a high-resolution, semi-automated sampling system at the University of Colorado, which will permit the continuous analysis of isotope ratios via laser spectroscopy, at an effective resolution of ~2 cm or less, providing inter-annual time resolution for most of the core. Because continuous flow analyses of stable ice isotopes is a relatively new measurement, we will complement them with parallel measurements, every ~10-20 m, using traditional discrete sampling and analysis by mass spectrometry at the University of Washington. The intellectual merit and the overarching goal of the work are to see Inland WAIS become the reference ice isotope record for West Antarctica. The broader impacts of the work are that the data generated in this project pertain directly to policy-relevant and immediate questions of the stability of the West Antarctic ice sheet, and thus past and future changes in sea level, as well as the nature of climate change in the high southern latitudes. The project will also contribute to the development of modern isotope analysis techniques using laser spectroscopy, with applications well beyond ice cores. The project will involve a graduate student and postdoc who will work with both P.I.s, and spend time at both institutions. Data will be made available rapidly through the Antarctic Glaciological Data Center, for use by other researchers and the public.", "east": -112.08, "geometry": "POINT(-112.08 -79.47)", "instruments": null, "is_usap_dc": true, "keywords": "LABORATORY", "locations": null, "north": -79.47, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "White, James; Vaughn, Bruce; Jones, Tyler R.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.47, "title": "Collaborative Research: Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "uid": "p0000078", "west": -112.08}, {"awards": "1043167 White, James; 1043092 Steig, Eric", "bounds_geometry": null, "dataset_titles": "17O excess from WAIS Divide, 0 to 25 ka BP; WAIS Divide Ice Core Discrete CH4 (80-3403m); WAIS Divide WDC06A Oxygen Isotope Record", "datasets": [{"dataset_uid": "609629", "doi": "10.7265/N5GT5K41", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide WDC06A Oxygen Isotope Record", "url": "https://www.usap-dc.org/view/dataset/609629"}, {"dataset_uid": "601413", "doi": "10.15784/601413", "keywords": "Antarctica; Ice Core; Oxygen Isotope; WAIS Divide", "people": "Schoenemann, Spruce; Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "17O excess from WAIS Divide, 0 to 25 ka BP", "url": "https://www.usap-dc.org/view/dataset/601413"}, {"dataset_uid": "601741", "doi": "10.15784/601741", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; WAIS", "people": "Sowers, Todd A.; Brook, Edward", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Ice Core Discrete CH4 (80-3403m)", "url": "https://www.usap-dc.org/view/dataset/601741"}], "date_created": "Sat, 06 Dec 2014 00:00:00 GMT", "description": "This award supports a project to contribute one of the cornerstone analyses, stable isotopes of ice (Delta-D, Delta-O18) to the ongoing West Antarctic Ice Sheet Divide (WAIS) deep ice core. The WAIS Divide drilling project, a multi-institution project to obtain a continuous high resolution ice core record from central West Antarctica, reached a depth of 2560 m in early 2010; it is expected to take one or two more field seasons to reach the ice sheet bed (~3300 m), plus an additional four seasons for borehole logging and other activities including proposed replicate coring. The current proposal requests support to complete analyses on the WAIS Divide core to the base, where the age will be ~100,000 years or more. These analyses will form the basis for the investigation of a number of outstanding questions in climate and glaciology during the last glacial period, focused on the dynamics of the West Antarctic Ice Sheet and the relationship of West Antarctic climate to that of the Northern polar regions, the tropical Pacific, and the rest of the globe, on time scales ranging from years to tens of thousands of years. One new aspect of this work is the growing expertise at the University of Washington in climate modeling with isotope-tracer-enabled general circulation models, which will aid in the interpretation of the data. Another major new aspect is the completion and use of a high-resolution, semi-automated sampling system at the University of Colorado, which will permit the continuous analysis of isotope ratios via laser spectroscopy, at an effective resolution of ~2 cm or less, providing inter-annual time resolution for most of the core. Because continuous flow analyses of stable ice isotopes is a relatively new measurement, we will complement them with parallel measurements, every ~10-20 m, using traditional discrete sampling and analysis by mass spectrometry at the University of Washington. The intellectual merit and the overarching goal of the work are to see Inland WAIS become the reference ice isotope record for West Antarctica. The broader impacts of the work are that the data generated in this project pertain directly to policy-relevant and immediate questions of the stability of the West Antarctic ice sheet, and thus past and future changes in sea level, as well as the nature of climate change in the high southern latitudes. The project will also contribute to the development of modern isotope analysis techniques using laser spectroscopy, with applications well beyond ice cores. The project will involve a graduate student and postdoc who will work with both P.I.s, and spend time at both institutions. Data will be made available rapidly through the Antarctic Glaciological Data Center, for use by other researchers and the public.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e INFRARED LASER SPECTROSCOPY; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e INFRARED LASER SPECTROSCOPY", "is_usap_dc": true, "keywords": "AMD; ANALYTICAL LAB; USAP-DC; Amd/Us; LABORATORY; ICE CORE RECORDS; Antarctica; Wais Divide-project; FIELD SURVEYS; USA/NSF", "locations": "Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Earth Sciences; Antarctic Glaciology; Antarctic Earth Sciences", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Steig, Eric J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; OTHER \u003e PHYSICAL MODELS \u003e ANALYTICAL LAB; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Collaborative Research: Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "uid": "p0000010", "west": null}, {"awards": "0537661 Cuffey, Kurt; 0537930 Steig, Eric; 0537593 White, James", "bounds_geometry": "POINT(-112.08 -79.47)", "dataset_titles": "Stable Isotope Lab at INSTAAR, University of Colorado; WAIS ice core isotope data #342, 347, 348, 349, 350, 351 (full data link not provided)", "datasets": [{"dataset_uid": "000140", "doi": "", "keywords": null, "people": null, "repository": "Project website", "science_program": null, "title": "WAIS ice core isotope data #342, 347, 348, 349, 350, 351 (full data link not provided)", "url": "http://www.waisdivide.unh.edu/"}, {"dataset_uid": "002561", "doi": "", "keywords": null, "people": null, "repository": "Project website", "science_program": null, "title": "Stable Isotope Lab at INSTAAR, University of Colorado", "url": "http://instaar.colorado.edu/sil/about/index.php"}], "date_created": "Mon, 09 Apr 2012 00:00:00 GMT", "description": "This award supports analyses of stable isotopes of water, dD, d18O and deuterium excess in the proposed West Antarctic Ice Sheet Divide (WAIS) deep ice core. The project will produce a continuous and high-resolution reconstruction of stable isotope ratios for the new core. dD and d18O values provide estimates of temperature change at the ice core site. Deuterium excess provides estimates of ocean surface conditions, such as sea surface temperature, at the moisture source areas. This new ice core is ideally situated to address questions ranging from ice sheet stability to abrupt climate change. WAIS Divide has high enough snowfall rates to record climate changes on annual to decadal time scales. It should also have ice old enough to capture the last interglacial period in detail. The West Antarctic ice sheet is the subject of great scrutiny as our modern climate warms and sea level rises. What are the prospects for added sea level rise from ice released by this ice sheet? Understanding how this ice sheet has responded to climate change in the past, which the data collected in this project will help to assess, is critical to answering this question. The high temporal resolution available in the WAIS Divide core will provide the best available basis for inter-comparison of millennial-scale climate changes between the poles, and thus a better understanding of the spatial expression and dynamics of rapid climate change events. Finally, the location of this core in the Pacific sector of West Antarctica makes it well situated for examining the influence of the tropical Pacific on Antarctica climate, on longer timescales than are available from the instrumental climate record. Analyses will include the measurement of sub-annually resolved isotope variations in the uppermost parts of the core, measurements at annual resolution throughout the last 10,000 years and during periods of rapid climate change prior to that, and measurements at 50-year resolution throughout the entire length of the core that is collected and processed during the period of this grant. We anticipate that this will be about half of the full core expected to be drilled. In terms of broader impacts, the PIs will share the advising of two graduate students, who will make this ice core the focus of their thesis projects. It will be done in an innovative multi-campus approach designed to foster a broader educational experience. As noted above, the data and interpretations generated by this proposal will address climate change questions not only of direct and immediate scientific interest, but also of direct and immediate policy interest.", "east": -112.08, "geometry": "POINT(-112.08 -79.47)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e MBES", "is_usap_dc": true, "keywords": "West Antarctic Ice Sheet Divide; Not provided; Ice Core; WAIS Divide; LABORATORY; FIELD SURVEYS; Isotope; FIELD INVESTIGATION; Antarctica; West Antarctica; Stable Isotope Ratios; Antarctic; Ice Sheet; Deuterium", "locations": "WAIS Divide; West Antarctica; Antarctic; Antarctica; West Antarctic Ice Sheet Divide", "north": -79.47, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY", "persons": "White, James; Steig, Eric J.; Cuffey, Kurt M.; Souney, Joseph Jr.; Vaughn, Bruce", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "Project website", "repositories": "Project website", "science_programs": null, "south": -79.47, "title": "Collaborative Research: Stable Isotopes of Ice in the WAIS Divide Deep Ice Core", "uid": "p0000294", "west": -112.08}, {"awards": "0125761 Thiemens, Mark", "bounds_geometry": null, "dataset_titles": "Atmospheric Nitrate Isotopic Analysis at Amundsen-Scott South Pole Station, A Twenty-Five Year Record", "datasets": [{"dataset_uid": "609281", "doi": "10.7265/N5TT4NWF", "keywords": "Aerosol; Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; NBP1502; Snow/ice; Snow/Ice; South Pole Station", "people": "Savarino, Joel; Thiemens, Mark H.", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric Nitrate Isotopic Analysis at Amundsen-Scott South Pole Station, A Twenty-Five Year Record", "url": "https://www.usap-dc.org/view/dataset/609281"}], "date_created": "Tue, 27 Dec 2005 00:00:00 GMT", "description": "This award supports a detailed laboratory analysis of the mass-independent isotopic composition of processes associated with atmospheric nitrate trapped in the snow pack at the South Pole. The project will specifically test if the oxygen isotopes 16O, 17O, 18O of nitrate can be used to probe the denitrification of the Antarctic stratosphere. Despite decades of research, there are several important issues in Antarctic atmospheric science, which are presently inadequately resolved. This includes quantification over time of the sources of nitrate aerosols. Today, little is known about the past denitrification of the stratosphere in high latitude regions. This lack of knowledge significantly limits our ability to understand the chemical state of ancient atmospheres and therefore evaluate present and past-coupled climate/atmosphere models. The role of nitrogen in environmental degradation is well known. This issue will also be addressed in this proposal. Atmospheric aerosols have now been shown to possess a mass-independent oxygen isotopic content. The proposed research will investigate the stable oxygen isotope ratios of nitrate in Antarctica both collected in real time and from the snow. Two periods of time will be covered. Full year nitrate aerosol collections, with week resolution time horizons, will be performed at the South Pole. Weekly aerosol collections will help us to identify any seasonal trend of the oxygen-17 excess anomaly, and eventually link this anomaly to the denitrification of the Antarctic stratosphere. This data set will also be used to test our assumption that the oxygen isotopic anomaly of nitrate is mainly formed in the stratosphere and is well preserved in the snow pack. If true, we will for the first time resolve an atmospheric signal extracted from a nitrate profile. The snow pit will allow us to see any trend in the data on a multiple decade timescale.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Snow; GROUND STATIONS; Ion Chemistry; South Pole; Not provided; Aerosol; Oxygen Isotope; GROUND-BASED OBSERVATIONS; Snow Pit; Antarctica; Admundsen-Scott Station", "locations": "Antarctica; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Savarino, Joel; Thiemens, Mark H.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "South Pole Atmospheric Nitrate Isotopic Analysis (SPANIA)", "uid": "p0000242", "west": null}, {"awards": "0125981 Sowers, Todd", "bounds_geometry": "POLYGON((-180 -62.83,-144 -62.83,-108 -62.83,-72 -62.83,-36 -62.83,0 -62.83,36 -62.83,72 -62.83,108 -62.83,144 -62.83,180 -62.83,180 -65.547,180 -68.264,180 -70.981,180 -73.698,180 -76.415,180 -79.132,180 -81.849,180 -84.566,180 -87.283,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.283,-180 -84.566,-180 -81.849,-180 -79.132,-180 -76.415,-180 -73.698,-180 -70.981,-180 -68.264,-180 -65.547,-180 -62.83))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 05 May 2005 00:00:00 GMT", "description": "0125981\u003cbr/\u003eSowers\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to construct an isotopic record of atmospheric methane and nitrous oxide over the last century from South Pole firn air. Over the last 150 years, atmospheric methane and nitrous oxide concentrations have risen in response to increased emissions from various anthropogenic activities. As this trend is liable to continue in the foreseeable future, it is important to understand the biogeochemical processes that contribute to the emissions of these two greenhouse gases. In this context, records of the variations in the atmospheric loading of trace gases found in ice cores and interstitial spaces in the snow near the surface of the ice sheet (firn air) provide fundamental boundary conditions for reconstructing historical emission records. One way to improve our understanding of the cycling of bioactive trace gases and their emission records is to use stable isotope tracers, which have been recorded in the ice cores and firn air. This project will develop records of carbon-13 and deuterium isotope ratios of methane, as well as the nitrogen-15, oxygen-18 and the isotopomer composition of nitrous oxide trapped in firn air samples collected in January 2001 at the South Pole. These measurements will allow isotopic records of these atmospheric gases to be reconstructed throughout the 20th century. Such records will help to establish the relative contribution of individual sources with a higher degree of confidence than is currently available.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": -62.83, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Sowers, Todd A.", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -90.0, "title": "Generating an Isotopic Record of Atmospheric Methane and Nitrous Oxide Over the Last Century from South Pole Firn Air", "uid": "p0000086", "west": -180.0}, {"awards": "0088054 Goldstein, Steven", "bounds_geometry": "POLYGON((-180 -39.57,-144 -39.57,-108 -39.57,-72 -39.57,-36 -39.57,0 -39.57,36 -39.57,72 -39.57,108 -39.57,144 -39.57,180 -39.57,180 -42.967,180 -46.364,180 -49.761,180 -53.158,180 -56.555,180 -59.952,180 -63.349,180 -66.746,180 -70.143,180 -73.54,144 -73.54,108 -73.54,72 -73.54,36 -73.54,0 -73.54,-36 -73.54,-72 -73.54,-108 -73.54,-144 -73.54,-180 -73.54,-180 -70.143,-180 -66.746,-180 -63.349,-180 -59.952,-180 -56.555,-180 -53.158,-180 -49.761,-180 -46.364,-180 -42.967,-180 -39.57))", "dataset_titles": null, "datasets": null, "date_created": "Tue, 26 Apr 2005 00:00:00 GMT", "description": "This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a project to investigate the sediment core from the Southern Ocean for paleoenvironmental research. The polar regions are susceptible to the largest changes in climate and are among the least accessible places on Earth. Current concern about the instability of the West Antarctic Ice Sheet has heightened awareness of the vulnerability of polar regions. This proposal seeks to gain a basic understanding of the isotopic characteristics of terrigenous sediment sources derived from Antarctica in the Holocene and Last Glacial Maximum, and their dispersal into the Southern Ocean. Terrigenous clastic sediments are brought to the ocean from continental sources via rivers, ice and wind, and distributed within the ocean by surface and deep currents. At present there are virtually no isotopic data on circumpolar detritus, save a few strontium (Sr) isotopic ratios in the Atlantic sector. This project will fill part of this gap. From the large range in geological ages of crustal provinces of Antarctica, we would predict that there are large isotopic differences in detritus around the continent. The main objectives are to (1) characterize the strontium-neodymium-lead-argon (Sr-Nd-Pb-Ar) isotope compositions of sediment sources derived from Antarctica, (2) to identify the composition and source ages of major ice rafted detritus (IRD) contributions by analyzing individual grains of hornblende and feldspar in conjunction with bulk isotopic analysis, and (3) track sediment dispersal into the Antarctic Circumpolar Current (ACC) during the Holocene and Last Glacial Maximum.\u003cbr/\u003e\u003cbr/\u003eBecause of the paucity of circumpolar data, this research necessarily has a large exploratory component. Consequently, it will provide a basic database for future studies. Nevertheless there are important hypothesis-driven questions that will be addressed in this primary pass. Can lessons learned in North Atlantic IRD studies be applied toward understanding the history of Antarctic ice sheets? Can the large geological variability around the Antarctic margin be treated as a series of natural tracer injections into the ACC, and thus characterize its trajectory, speed, and interaction with other current systems today and in the past? The proposed study is motivated by an exciting set of results from the South Atlantic, showing that detrital Sr isotope ratios are a sensitive current tracer in that region. This research should serve a basic need across many Earth Science disciplines if the use of long-lived radiogenic isotopes (Sr-Nd-Pb-Ar) as tracers of marine sediment sources is successful in elucidating processes related to changing climatic conditions. The results of this study will fill a basic gap in our knowledge of an important region of the Earth. At the same time, it will provide an essential basis for attempting reconstruction of the ACC during the LGM, as well as for future studies of Antarctic geology, ice sheet history, and the Southern Ocean circulation.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": -39.57, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Roy, Martin; Hemming, Sidney R.; Goldstein, Steven L.; Van De Flierdt, Christina-Maria", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -73.54, "title": "Establishing the Pattern of Holocene-LGM Changes in Sediment Contributions from Antarctica to the Southern Ocean", "uid": "p0000724", "west": -180.0}]

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