USAP-DC

{"dp_type": "Project", "free_text": "Trace Gases"}

[{"awards": "1745078 Brook, Edward", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ; Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation; Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "datasets": [{"dataset_uid": "601737", "doi": "10.15784/601737", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Ice Core Records; Methane; West Antarctic Ice Sheet", "people": "Riddell-Young, Benjamin; Brook, Edward; Edwards, Jon S.; Martin, Kaden; Lee, James; Rosen, Julia", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ", "url": "https://www.usap-dc.org/view/dataset/601737"}, {"dataset_uid": "601683", "doi": "10.15784/601683", "keywords": "Antarctica; Methane; West Antarctic Ice Sheet", "people": "Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601683"}, {"dataset_uid": "601736", "doi": "10.15784/601736", "keywords": "Antarctica; Greenland; Methane; Paleoclimate; West Antarctic Ice Sheet", "people": "Brook, Edward; Blunier, Thomas; Fischer, Hubertus; Schmitt, Jochen; M\u00fchl, Michaela; Edwards, Jon S.; Lee, James; Martin, Kaden; Buizert, Christo; Rosen, Julia; Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601736"}], "date_created": "Mon, 01 May 2023 00:00:00 GMT", "description": "This project will develop methods to measure the ratios of carbon-13 to carbon-12, and heavy to light hydrogen in methane in air trapped in ice cores. The ratios of the different forms of carbon and hydrogen are \"fingerprints\" of different sources of this gas in the past--for example wetlands in the tropics versus methane frozen in the sea floor. Once the analysis method is developed, the measurements will be used to examine why methane changed abruptly in the past, both during the last ice age, and during previous warm periods. The data will be used to understand how methane sources like wildfires, methane hydrates, and wetlands respond to climate change. This information is needed to understand future risks of large changes in methane in the atmosphere as Earth warms. \u003cbr/\u003e\u003cbr/\u003eThe project involves two tasks. First, the investigators will build and test a gas extraction system for methane isotopic measurements using continuous flow methods, with the goal of equaling or bettering the precision attained by the few other laboratories that make these measurements. The system will be interfaced with existing mass spectrometers at Oregon State University. The system consists of a vacuum chamber and sequence of traps, purification columns, and furnaces that separate methane from other gases and convert it to carbon dioxide or hydrogen for mass spectrometry. Second, the team will measure the isotopic composition of methane across large changes in concentration associated with two past interglacial periods and during abrupt methane changes of the last ice age. These measurements will be used to understand if the main reason for these concentration changes is climate-driven changes in emissions from wetlands, or whether other sources are involved, for example methane hydrates or wildfires.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Antarctic Ice Sheet; TRACE GASES/TRACE SPECIES; METHANE", "locations": "Antarctic Ice Sheet", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Tracing Past Methane Variations with Stable Isotopes in Antarctic Ice Cores", "uid": "p0010416", "west": -180.0}, {"awards": "1543511 Stephens, Britton; 1543457 Munro, David", "bounds_geometry": "POLYGON((-73 -53,-71.2 -53,-69.4 -53,-67.6 -53,-65.8 -53,-64 -53,-62.2 -53,-60.4 -53,-58.6 -53,-56.8 -53,-55 -53,-55 -54.4,-55 -55.8,-55 -57.2,-55 -58.6,-55 -60,-55 -61.4,-55 -62.8,-55 -64.2,-55 -65.6,-55 -67,-56.8 -67,-58.6 -67,-60.4 -67,-62.2 -67,-64 -67,-65.8 -67,-67.6 -67,-69.4 -67,-71.2 -67,-73 -67,-73 -65.6,-73 -64.2,-73 -62.8,-73 -61.4,-73 -60,-73 -58.6,-73 -57.2,-73 -55.8,-73 -54.4,-73 -53))", "dataset_titles": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the Southern Ocean, Drake Passage and South Atlantic Ocean in 2018, processed by NOAA (NCEI Accession 0184338); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, Drake Passage, South Atlantic Ocean in 2022 (NCEI Accession 0276577); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Atlantic Ocean in 2021 (NCEI Accession 0246983); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean from 2019-02-16 to 2020-02-11 (NCEI Accession 0208838); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean in 2020 (NCEI Accession 0225445); Underway measurements of pCO2 in the Surface Waters and the Atmosphere During the ARSV Laurence M. Gould 2017 Expeditions processed by NOAA (NCEI Accession 0170337)", "datasets": [{"dataset_uid": "200353", "doi": "https://doi.org/10.25921/fq0a-7y11", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, Drake Passage, South Atlantic Ocean in 2022 (NCEI Accession 0276577)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200350", "doi": "https://doi.org/10.25921/3ysc-pm11", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean from 2019-02-16 to 2020-02-11 (NCEI Accession 0208838)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200351", "doi": "https://doi.org/10.25921/z0pk-pv81", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean in 2020 (NCEI Accession 0225445)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200352", "doi": "https://doi.org/10.25921/f94g-zp40", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Atlantic Ocean in 2021 (NCEI Accession 0246983)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200349", "doi": "https://doi.org/10.25921/b4jn-ef56", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the Southern Ocean, Drake Passage and South Atlantic Ocean in 2018, processed by NOAA (NCEI Accession 0184338)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200348", "doi": "https://doi.org/10.7289/v5tq5zt1", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Underway measurements of pCO2 in the Surface Waters and the Atmosphere During the ARSV Laurence M. Gould 2017 Expeditions processed by NOAA (NCEI Accession 0170337)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}], "date_created": "Wed, 22 Feb 2023 00:00:00 GMT", "description": "The Southern Ocean plays a key role in modulating the global carbon cycle, but the size and even the sign of the flux of carbon dioxide between the ocean and atmosphere in this region is still uncertain. This is in part due to the lack of measurements in this remote region of the world ocean. This project continues a multi-year time series of shipboard chemical measurements in the Drake Passage to detect changes in the ocean carbon cycle and to improve the understanding of mechanisms driving natural variability and long-term change in the Southern Ocean. More specifically, this project is a continuation of the collection of underway upper ocean measurements of the surface partial pressure of carbon dioxide during crossings of the Drake Passage by the Antarctic Research and Supply Vessel Laurence M. Gould. This project also includes collection and analysis of discrete samples relevant to ocean carbon cycle studies including macronutrient concentrations, total carbon dioxide concentrations, and the carbon isotopic composition of total carbon dioxide. The Drake Passage data are made readily available to the international science community and serve as both validation and constraints of remotely sensed observations and numerical coupled earth systems models.", "east": -55.0, "geometry": "POINT(-64 -60)", "instruments": null, "is_usap_dc": true, "keywords": "Drake Passage; NUTRIENTS; BIOGEOCHEMICAL CYCLES; DISSOLVED GASES; TRACE GASES/TRACE SPECIES", "locations": "Drake Passage", "north": -53.0, "nsf_funding_programs": "Antarctic Ocean and Atmospheric Sciences; Antarctic Organisms and Ecosystems; Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Munro, David; Sweeney, Colm; Lovenduski, Nicole S; Stephens, Britton", "platforms": null, "repo": "NCEI", "repositories": "NCEI", "science_programs": null, "south": -67.0, "title": "Collaborative Research: Investigating Biogeochemical Fluxes and Linkages To Climate Change With Multi-Scale Observations In The Drake Passage", "uid": "p0010407", "west": -73.0}, {"awards": "1643669 Petrenko, Vasilii; 1643716 Buizert, Christo; 1643664 Severinghaus, Jeffrey", "bounds_geometry": "POLYGON((112 -66,112.2 -66,112.4 -66,112.6 -66,112.8 -66,113 -66,113.2 -66,113.4 -66,113.6 -66,113.8 -66,114 -66,114 -66.1,114 -66.2,114 -66.3,114 -66.4,114 -66.5,114 -66.6,114 -66.7,114 -66.8,114 -66.9,114 -67,113.8 -67,113.6 -67,113.4 -67,113.2 -67,113 -67,112.8 -67,112.6 -67,112.4 -67,112.2 -67,112 -67,112 -66.9,112 -66.8,112 -66.7,112 -66.6,112 -66.5,112 -66.4,112 -66.3,112 -66.2,112 -66.1,112 -66))", "dataset_titles": "Concentration and isotopic composition of atmospheric N2O over the last century; Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2; Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy", "datasets": [{"dataset_uid": "601598", "doi": "10.15784/601598", "keywords": "Antarctica; Firn; Firn Density; Gravitational Settling; Inert Gases; Law Dome", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2", "url": "https://www.usap-dc.org/view/dataset/601598"}, {"dataset_uid": "601693", "doi": "10.15784/601693", "keywords": "Antarctic; Antarctica; Anthropogenic Emission; Atmosphere; Greenhouse Gas; Greenland; Ice Core Data; Nitrification And Denitrification Processes; Nitrous Oxide; Site-Specific 15N Isotopomer; Styx Glacier", "people": "Etheridge, David; Yoshida, Naohiro ; Ahn, Jinho ; Langenfelds, Ray L ; Buizert, Christo ; Joong Kim, Seong; Toyoda, Sakae ; Ghosh, Sambit", "repository": "USAP-DC", "science_program": null, "title": "Concentration and isotopic composition of atmospheric N2O over the last century", "url": "https://www.usap-dc.org/view/dataset/601693"}, {"dataset_uid": "601597", "doi": "10.15784/601597", "keywords": "Antarctica; Ice Core; Law Dome; Noble Gas", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy", "url": "https://www.usap-dc.org/view/dataset/601597"}], "date_created": "Fri, 17 Jun 2022 00:00:00 GMT", "description": "Hydroxyl radicals are responsible for removal of most atmospheric trace gases, including pollutants and important greenhouse gases. They have been called the \"detergent of the atmosphere\". Changes in hydroxyl radical concentration in response to large changes in reactive trace gas emissions, which may happen in the future, are uncertain. This project aims to provide the first estimates of the variability of atmospheric hydroxyl radicals since about 1880 AD when anthropogenic emissions of reactive trace gases were minimal. This will improve understanding of their stability in response to large changes in emissions. The project will also investigate whether ice cores record past changes in Southern Hemisphere westerly winds. These winds are a key component of the global climate system, and have an important influence on ocean circulation and possibly on atmospheric carbon dioxide concentrations. The project team will include three early career scientists, a postdoctoral researcher, and graduate and undergraduate students, working in collaboration with senior scientists and Australian collaborators. \u003cbr/\u003e \u003cbr/\u003eFirn air and shallow ice to a depth of about 233 m will be sampled at the Law Dome high-accumulation coastal site in East Antarctica. Trapped air will be extracted from the ice cores on site immediately after drilling. Carbon-14 of carbon monoxide (14CO) will be analyzed in firn and ice-core air samples. Corrections will be made for the in situ cosmogenic 14CO component in the ice, allowing for the atmospheric 14CO history to be reconstructed. This 14CO history will be interpreted with the aid of a chemistry-transport model to place the first observational constraints on the variability of Southern Hemisphere hydroxyl radical concentration after about 1880 AD. An additional component of the project will analyze Krypton-86 in the firn-air and ice-core samples. These measurements will explore whether ice-core Krypton-86 acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere westerly winds.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 114.0, "geometry": "POINT(113 -66.5)", "instruments": null, "is_usap_dc": true, "keywords": "AMD; TRACE GASES/TRACE SPECIES; Law Dome; Amd/Us; USAP-DC; LABORATORY; ICE CORE AIR BUBBLES; USA/NSF", "locations": "Law Dome", "north": -66.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Murray, Lee T; Buizert, Christo; Petrenko, Vasilii; Murray, Lee T", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -67.0, "title": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability", "uid": "p0010341", "west": 112.0}, {"awards": "1443482 Mak, John", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Carbon monoxide mixing ratios and stable isotopic values, SPICE", "datasets": [{"dataset_uid": "601356", "doi": "10.15784/601356", "keywords": "Antarctica; CO; Delta 13C; Delta 18O; South Pole; SPICEcore", "people": "Mak, John", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Carbon monoxide mixing ratios and stable isotopic values, SPICE", "url": "https://www.usap-dc.org/view/dataset/601356"}], "date_created": "Thu, 09 Jul 2020 00:00:00 GMT", "description": "The investigators plan to reconstruct historical variations in the sources of atmospheric carbon monoxide (CO) from measurements of the concentration and stable isotopic abundance of carbon monoxide ([CO], 13CO and C18O) in the South Pole Ice Core, which is being drilled in 2014-2016. The goal is to strategically sample and reconstruct the relative variations in CO source strengths over the past 20,000 years. These will be the first measurements to extend the CO record beyond 650 years before present, back to the last glacial maximum. Both atmospheric chemical processes and variations in CO sources can impact the CO budget, and variations in the CO budget are useful in identifying and quantifying chemistry-climate interactions.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "LABORATORY; TRACE GASES/TRACE SPECIES; FIELD INVESTIGATION; South Pole", "locations": "South Pole", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Mak, John", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Using Stable Isotopes to Constrain the Atmospheric Carbon Monoxide Budget over the Last 20,000 Years", "uid": "p0010117", "west": -180.0}, {"awards": "1907974 Saltzman, Eric", "bounds_geometry": "POLYGON((129.26 -89.86,130.261 -89.86,131.262 -89.86,132.263 -89.86,133.264 -89.86,134.265 -89.86,135.266 -89.86,136.267 -89.86,137.268 -89.86,138.269 -89.86,139.27 -89.86,139.27 -89.861,139.27 -89.862,139.27 -89.863,139.27 -89.864,139.27 -89.865,139.27 -89.866,139.27 -89.867,139.27 -89.868,139.27 -89.869,139.27 -89.87,138.269 -89.87,137.268 -89.87,136.267 -89.87,135.266 -89.87,134.265 -89.87,133.264 -89.87,132.263 -89.87,131.262 -89.87,130.261 -89.87,129.26 -89.87,129.26 -89.869,129.26 -89.868,129.26 -89.867,129.26 -89.866,129.26 -89.865,129.26 -89.864,129.26 -89.863,129.26 -89.862,129.26 -89.861,129.26 -89.86))", "dataset_titles": "H2 in South Pole firn air", "datasets": [{"dataset_uid": "601332", "doi": "10.15784/601332", "keywords": "Antarctica; Firn; Glaciology; Hydrogen; Ice Core Records; Snow/ice; Snow/Ice; South Pole", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "H2 in South Pole firn air", "url": "https://www.usap-dc.org/view/dataset/601332"}], "date_created": "Tue, 09 Jun 2020 00:00:00 GMT", "description": "Hydrogen (H2) is one of the most abundant trace gases in the atmosphere, with a mean level of 500 ppb and an atmospheric lifetime of about two years. Hydrogen has an impact on both air quality and climate, due to its role as a precursor for tropospheric ozone and stratospheric water vapor. Projections indicate that a future \"hydrogen economy\" would increase hydrogen emissions. Understanding of the atmospheric hydrogen budget is largely based on a 30-year record of surface air measurements, but there are no long-term records with which to assess either: 1) the influence of climate change on atmospheric hydrogen, or 2) the extent to which humans have impacted the hydrogen budget. Polar ice core records of hydrogen will advance our understanding of the atmospheric hydrogen cycle and provide a stronger basis for projecting future changes to atmospheric levels of hydrogen and their impacts. \u003cbr/\u003e\u003cbr/\u003eThe research will involve laboratory work to enable the collection and analysis of hydrogen in polar ice cores. Hydrogen is a highly diffusive molecule and, unlike most other atmospheric gases, diffusion of hydrogen in ice is so rapid that ice samples must be stored in impermeable containers immediately upon drilling and recovery. This project will: 1) construct a laboratory system for extracting and analyzing hydrogen in polar ice, 2) develop and test materials and construction designs for vessels to store ice core samples in the field, and 3) test the method on samples of opportunity previously stored in the field. The goal of this project is a proven, cost-effective design for storage flasks to be fabricated for use on future polar ice coring projects. This project will support the dissertation research of a graduate student in the UC Irvine Department of Earth System Science.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 139.27, "geometry": "POINT(134.265 -89.865)", "instruments": null, "is_usap_dc": true, "keywords": "LABORATORY; Firn; TRACE GASES/TRACE SPECIES; South Pole; FIELD INVESTIGATION; USAP-DC", "locations": "South Pole", "north": -89.86, "nsf_funding_programs": "Antarctic Instrumentation and Facilities; Antarctic Glaciology; Antarctic Instrumentation and Support", "paleo_time": null, "persons": "Saltzman, Eric", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -89.87, "title": "EAGER: Feasibility of Reconstructing the Atmospheric History of Molecular Hydrogen from Antarctic Ice", "uid": "p0010106", "west": 129.26}, {"awards": "1443470 Aydin, Murat", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "South Pole ice core (SPC14) discrete methane data; SP19 Gas Chronology; SPC14 carbonyl sulfide, methyl chloride, and methyl bromide measurements from South Pole, Antarctica", "datasets": [{"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kahle, Emma; Sowers, Todd A.; Edwards, Jon S.; Kennedy, Joshua A.; Aydin, Murat; Kreutz, Karl; Buizert, Christo; Brook, Edward J.; Epifanio, Jenna; Fudge, T. J.; Osterberg, Erich; Winski, Dominic A.; Hood, Ekaterina; Kalk, Michael; Steig, Eric J.; Ferris, David G.; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601270", "doi": "10.15784/601270", "keywords": "Antarctica", "people": "Aydin, Murat", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPC14 carbonyl sulfide, methyl chloride, and methyl bromide measurements from South Pole, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601270"}], "date_created": "Thu, 26 Mar 2020 00:00:00 GMT", "description": "In the past, Earth\u0027s climate underwent dramatic changes that influenced physical, chemical, geological, and biological processes on a global scale. Such changes left an imprint in Earth\u0027s atmosphere, as shown by the variability in abundances of trace gases like carbon dioxide and methane. In return, changes in the atmospheric trace gas composition affected Earth\u0027s climate. Studying compositional variations of the past atmosphere helps us understand the history of interactions between global biogeochemical cycles and Earth?s climate. The most reliable information on past atmospheric composition comes from analysis of air entrapped in polar ice cores. This project aims to generate ice-core records of relatively short-lived, very-low-abundance trace gases to determine the range of past variability in their atmospheric levels and investigate the changes in global biogeochemical cycles that caused this variability. This project measures three such gases: carbonyl sulfide, methyl chloride, and methyl bromide. Changes in carbonyl sulfide can indicate changes in primary productivity and photosynthetic update of carbon dioxide. Changes in methyl chloride and methyl bromide significantly impact natural variability in stratospheric ozone. In addition, the processes that control atmospheric levels of methyl chloride and methyl bromide are shared with those controlling levels of atmospheric methane. The measurements will be made in the new ice core from the South Pole, which is expected to provide a 40,000-year record.\u003cbr/\u003e\u003cbr/\u003eThe primary focus of this project is to develop high-quality trace gas records for the entire Holocene period (the past 11,000 years), with additional, more exploratory measurements from the last glacial period including the period from 29,000-36,000 years ago when there were large changes in atmospheric methane. Due to the cold temperatures of the South Pole ice, the proposed carbonyl sulfide measurements are expected to provide a direct measure of the past atmospheric variability of this gas without the large hydrolysis corrections that are necessary for interpretation of measurements from ice cores in warmer settings. Furthermore, we will test the expectation that contemporaneous measurements from the last glacial period in the deep West Antarctic Ice Sheet Divide ice core will not require hydrolysis loss corrections. With respect to methyl chloride, we aim to verify and improve the existing Holocene atmospheric history from the Taylor Dome ice core in Antarctica. The higher resolution of our measurements compared with those from Taylor Dome will allow us to derive a more statistically significant relationship between methyl chloride and methane. With respect to methyl bromide, we plan to extend the existing 2,000-year database to 11,000 years. Together, the methyl bromide and methyl chloride records will provide strong measurement-based constraints on the natural variability of stratospheric halogens during the Holocene period. In addition, the methyl bromide record will provide insight into the correlation between methyl chloride and methane during the Holocene period due to common sources and sinks.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "NOT APPLICABLE; CARBONYL SULFIDE; HALOCARBONS AND HALOGENS; TRACE GASES/TRACE SPECIES; Antarctic; USAP-DC", "locations": "Antarctic", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Carbonyl Sulfide, Methyl Chloride, and Methyl Bromide Measurements in the New Intermediate-depth South Pole Ice Core", "uid": "p0010089", "west": -180.0}, {"awards": "1341494 Gao, Yuan", "bounds_geometry": "POINT(-64.05 -64.77)", "dataset_titles": "Concentrations and Particle Size Distributions of Aerosol Trace Elements; Particle sizes of aerosol iron", "datasets": [{"dataset_uid": "601257", "doi": "10.15784/601257", "keywords": "Aerosol Concentration; Antarctica; Chemistry:gas; Chemistry:Gas; Iron; Palmer Station; Particle Size", "people": "Gao, Yuan", "repository": "USAP-DC", "science_program": null, "title": "Particle sizes of aerosol iron", "url": "https://www.usap-dc.org/view/dataset/601257"}, {"dataset_uid": "601370", "doi": "10.15784/601370", "keywords": "Antarctica; Antarctic Peninsula; Palmer Station; Trace Elements", "people": "Gao, Yuan", "repository": "USAP-DC", "science_program": null, "title": "Concentrations and Particle Size Distributions of Aerosol Trace Elements", "url": "https://www.usap-dc.org/view/dataset/601370"}], "date_created": "Thu, 20 Feb 2020 00:00:00 GMT", "description": "The research seeks to further quantify the input of atmospheric Fe into the sparsely sampled Southern Ocean (SO), specifically in the vicinity of the West Antarctic Peninsula (WAP) and adjacent continental shelf waters in the Drake Passage. This is typically a high nutrient low chlorophyll region where surface trace metal and primary productivity data are suggestive of Fe limitation. The WAP is characterized by high productivity in the austral summer, and at this time may be in the path of northern dust (aeolian Fe) input or subject to melt influx of elevated Fe accumulated from glacial and present-day sea ice sources.\u003cbr/\u003e\u003cbr/\u003ePrimary scientific questions are: (1) to what extent does atmospheric Fe contribute to nutrient cycles and ecosystem dynamics in the SO? (2) How is warming climate occurring in the WAP affecting the aerosol composition of the maritime atmosphere. The primary productivity of the Southern Ocean is key to understanding oceanic uptake of anthropogenic greenhouse gases such as carbon dioxide.", "east": -64.05, "geometry": "POINT(-64.05 -64.77)", "instruments": null, "is_usap_dc": true, "keywords": "Aerosol Concentration; TRACE GASES/TRACE SPECIES; Particle Size; Palmer Station; FIELD INVESTIGATION; Trace Elements; Iron; AEROSOL OPTICAL DEPTH/THICKNESS; USAP-DC", "locations": "Palmer Station", "north": -64.77, "nsf_funding_programs": "Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Gao, Yuan", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -64.77, "title": "Quantifying Atmospheric Iron Properties over West Antarctic Peninsula", "uid": "p0010082", "west": -64.05}, {"awards": "1443550 Brook, Edward", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Polar Ice Cores 3,000 Year Nitrous Oxide d15N and d18O Data; SPICEcore Holocene CO2 and N2O data", "datasets": [{"dataset_uid": "601197", "doi": "10.15784/601197", "keywords": "Antarctica; Carbon Dioxide; Ice Core Gas Records; Nitrous Oxide; South Pole; SPICEcore", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPICEcore Holocene CO2 and N2O data", "url": "https://www.usap-dc.org/view/dataset/601197"}, {"dataset_uid": "200055", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Polar Ice Cores 3,000 Year Nitrous Oxide d15N and d18O Data", "url": "https://www.ncdc.noaa.gov/paleo-search/study/25530"}], "date_created": "Tue, 06 Aug 2019 00:00:00 GMT", "description": "The temperature of the earth is controlled, in part, by heat trapping gases that include carbon dioxide, methane, and nitrous oxide. Despite their importance to climate, direct measurements of these gases in the atmosphere are limited to the last 50 years at best. Air trapped in ice cores extends those data back hundreds of millennia, and measurements of greenhouse gases in ice cores underpin much of our understanding of global chemical cycles relevant to modern climate change. Existing records vary in quality and detail. The proposed work fills gaps in our knowledge of nitrous oxide and carbon dioxide over the last 10,000 years. New measurements from an ice core from the South Pole will be used to determine what role changes in ocean and land based processes played in controlling these gases, which decreased during the first 2,000 years of this time period, then gradually increased toward the present. The work will address a major controversy over whether early human activities could have impacted the atmosphere, and provide data to improve mathematical models of the land-ocean-atmosphere system that predict how future climate change will impact the composition of the atmosphere and climate. \u003cbr/\u003e\u003cbr/\u003eFor nitrous oxide the work will improve on existing concentration records It will also develop measurement of the isotopomers of nitrous oxide and explore their utility for understanding aspects of the Holocene nitrous oxide budget. The primary goal is to determine if marine and/or terrestrial emissions of nitrous oxide change in response to changes in Holocene climate. A new Holocene isotopic record for carbon dioxide (stable carbon and oxygen isotopes), will improve the precision of existing records by a factor 5 and increase the temporal resolution. These data will be used to evaluate controversial hypotheses about why carbon dioxide concentrations changed in the Holocene and provide insight into millennial scale processes in the carbon cycle, which are not resolved by current isotopic data. A graduate student and post doc will receive advanced training during and the student and principle investigator will conduct outreach efforts targeted at local middle school students. The proposed work will also contribute to teaching efforts by the PI and to public lectures on climate and climate change. The results will be disseminated through publications, data archive, and the OSU Ice Core Lab web site. New analytical methods of wide utility will also be developed and documented.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Antarctica; ICE CORE RECORDS; CARBON DIOXIDE; NOT APPLICABLE; USAP-DC; TRACE GASES/TRACE SPECIES; NITROUS OXIDE", "locations": "Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "NCEI; USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Controls on Variations in Atmospheric Carbon Dioxide and Nitrous Oxide During the Last 10,000 years", "uid": "p0010043", "west": -180.0}, {"awards": "1341606 Stammerjohn, Sharon; 1341717 Ackley, Stephen; 1543483 Sedwick, Peter; 1341725 Guest, Peter; 1341513 Maksym, Edward", "bounds_geometry": "POLYGON((-180 -55,-177 -55,-174 -55,-171 -55,-168 -55,-165 -55,-162 -55,-159 -55,-156 -55,-153 -55,-150 -55,-150 -57.3,-150 -59.6,-150 -61.9,-150 -64.2,-150 -66.5,-150 -68.8,-150 -71.1,-150 -73.4,-150 -75.7,-150 -78,-153 -78,-156 -78,-159 -78,-162 -78,-165 -78,-168 -78,-171 -78,-174 -78,-177 -78,180 -78,178 -78,176 -78,174 -78,172 -78,170 -78,168 -78,166 -78,164 -78,162 -78,160 -78,160 -75.7,160 -73.4,160 -71.1,160 -68.8,160 -66.5,160 -64.2,160 -61.9,160 -59.6,160 -57.3,160 -55,162 -55,164 -55,166 -55,168 -55,170 -55,172 -55,174 -55,176 -55,178 -55,-180 -55))", "dataset_titles": "ASPeCt Visual Ice Observations on PIPERS Cruise NBP1704 April-June 2017; Expedition data of NBP1704; Impact of Convective Processes and Sea Ice Formation on the Distribution of Iron in the Ross Sea: Closing the Seasonal Cycle; NBP1704 CTD sensor data; NBP1704 Expedition Data; PIPERS airborne lidar; PIPERS lidar data; PIPERS Meteorology Rawinsonde Data; PIPERS Meteorology Time Series; PIPERS Noble Gases; Sea Ice Layer Cakes, PIPERS 2017; SUMO unmanned aerial system (UAS) atmospheric data", "datasets": [{"dataset_uid": "002663", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of NBP1704", "url": "https://www.rvdata.us/search/cruise/NBP1704"}, {"dataset_uid": "200150", "doi": "", "keywords": null, "people": null, "repository": "BCO-DMO", "science_program": null, "title": "Impact of Convective Processes and Sea Ice Formation on the Distribution of Iron in the Ross Sea: Closing the Seasonal Cycle", "url": "https://www.bco-dmo.org/project/815403"}, {"dataset_uid": "601422", "doi": "10.15784/601422", "keywords": "Antarctica; CTD; CTD Data; NBP1704; Ocean Profile Data; Ross Sea; R/v Nathaniel B. Palmer; Salinity; Temperature", "people": "Stammerjohn, Sharon", "repository": "USAP-DC", "science_program": null, "title": "NBP1704 CTD sensor data", "url": "https://www.usap-dc.org/view/dataset/601422"}, {"dataset_uid": "601183", "doi": "10.15784/601183", "keywords": "Antarctica; Glaciology; Ice Concentration; Ice Thickness; Ice Type; NBP1704; Oceans; Ross Sea; R/v Nathaniel B. Palmer; Sea Ice; Snow Depth; Snow/ice; Snow/Ice; Visual Observations", "people": "Ackley, Stephen", "repository": "USAP-DC", "science_program": null, "title": "ASPeCt Visual Ice Observations on PIPERS Cruise NBP1704 April-June 2017", "url": "https://www.usap-dc.org/view/dataset/601183"}, {"dataset_uid": "601184", "doi": "10.15784/601184 ", "keywords": "Air Temperature; Antarctica; Atmosphere; Meteorology; Near-Surface Air Temperatures; PIPERS; Radiation; Sea Ice Temperatures; Temperature; Weather Station Data; Wind Direction; Wind Speed", "people": "Guest, Peter", "repository": "USAP-DC", "science_program": null, "title": "PIPERS Meteorology Time Series", "url": "https://www.usap-dc.org/view/dataset/601184"}, {"dataset_uid": "601185", "doi": "10.15784/601185 ", "keywords": "Air Temperature; Antarctica; Atmosphere; Atmospheric Surface Winds; Meteorology; NBP1704; PIPERS; Pressure; Radiosonde; Rawinsonde; Relative Humidity; Ross Sea; R/v Nathaniel B. Palmer; Wind Direction; Wind Speed", "people": "Guest, Peter", "repository": "USAP-DC", "science_program": null, "title": "PIPERS Meteorology Rawinsonde Data", "url": "https://www.usap-dc.org/view/dataset/601185"}, {"dataset_uid": "601188", "doi": "", "keywords": "Aerogeophysics; Airborne Laser Altimetry; Antarctica; LIDAR; PIPERS; Ross Sea; Sea Ice", "people": "Bell, Robin", "repository": "USAP-DC", "science_program": null, "title": "PIPERS airborne lidar", "url": "https://www.usap-dc.org/view/dataset/601188"}, {"dataset_uid": "001363", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "NBP1704 Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP1704"}, {"dataset_uid": "601191", "doi": "10.15784/601191", "keywords": "Air Temperature; Antarctica; Atmosphere; Meteorology; NBP1704; PIPERS; R/v Nathaniel B. Palmer; Southern Ocean; Temperature Profiles; UAV; Unmanned Aircraft", "people": "Cassano, John", "repository": "USAP-DC", "science_program": null, "title": "SUMO unmanned aerial system (UAS) atmospheric data", "url": "https://www.usap-dc.org/view/dataset/601191"}, {"dataset_uid": "601207", "doi": "10.15784/601207", "keywords": "Antarctica; Digital Elevation Model; Glaciology; Ice; Ice Thickness; Ice Thickness Distribution; LIDAR; NBP1704; PIPERS; Ross Sea; R/v Nathaniel B. Palmer; Sea Ice; Snow; Snow Depth; Surface Elevation", "people": "Mei, M. Jeffrey; Jeffrey Mei, M.; Maksym, Edward", "repository": "USAP-DC", "science_program": null, "title": "Sea Ice Layer Cakes, PIPERS 2017", "url": "https://www.usap-dc.org/view/dataset/601207"}, {"dataset_uid": "601609", "doi": "10.15784/601609", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Mass Spectrometer; NBP1704; Noble Gas; Oceans; Ross Sea; R/v Nathaniel B. Palmer", "people": "Loose, Brice", "repository": "USAP-DC", "science_program": null, "title": "PIPERS Noble Gases", "url": "https://www.usap-dc.org/view/dataset/601609"}, {"dataset_uid": "200101", "doi": "", "keywords": null, "people": null, "repository": "PI website", "science_program": null, "title": "PIPERS lidar data", "url": "http://wonder.ldeo.columbia.edu/data/publicationData/PIPERS/"}], "date_created": "Mon, 10 Jun 2019 00:00:00 GMT", "description": "The one place on Earth consistently showing increases in sea ice area, duration, and concentration is the Ross Sea in Antarctica. Satellite imagery shows about half of the Ross Sea increases are associated with changes in the austral fall, when the new sea ice is forming. The most pronounced changes are also located near polynyas, which are areas of open ocean surrounded by sea ice. To understand the processes driving the sea ice increase, and to determine if the increase in sea ice area is also accompanied by a change in ice thickness, this project will conduct an oceanographic cruise to the polynyas of the Ross Sea in April and May, 2017, which is the austral fall. The team will deploy state of the art research tools including unmanned airborne systems (UASs, commonly called drones), autonomous underwater vehicles (AUVs), and remotely operated underwater vehicles (ROVs). Using these tools and others, the team will study atmospheric, oceanic, and sea ice properties and processes concurrently. A change in sea ice production will necessarily change the ocean water below, which may have significant consequences for global ocean circulation patterns, a topic of international importance. All the involved institutions will be training students, and all share the goal of expanding climate literacy in the US, emphasizing the role high latitudes play in the Earth\u0027s dynamic climate.\u003cbr/\u003e\u003cbr/\u003eThe main goal of the project is to improve estimates of sea ice production and water mass transformation in the Ross Sea. The team will fully capture the spatial and temporal changes in air-ice-ocean interactions when they are initiated in the austral fall, and then track the changes into the winter and spring using ice buoys, and airborne mapping with the newly commissioned IcePod instrument system, which is deployed on the US Antarctic Program\u0027s LC-130 fleet. The oceanographic cruise will include stations in and outside of both the Terra Nova Bay and Ross Ice Shelf polynyas. Measurements to be made include air-sea boundary layer fluxes of heat, freshwater, and trace gases, radiation, and meteorology in the air; ice formation processes, ice thickness, snow depth, mass balance, and ice drift within the sea ice zone; and temperature, salinity, and momentum in the ocean below. Following collection of the field data, the team will improve both model parameterizations of air-sea-ice interactions and remote sensing algorithms. Model parameterizations are needed to determine if sea-ice production has increased in crucial areas, and if so, why (e.g., stronger winds or fresher oceans). The remote sensing validation will facilitate change detection over wider areas and verify model predictions over time. Accordingly this project will contribute to the international Southern Ocean Observing System (SOOS) goal of measuring essential climate variables continuously to monitor the state of the ocean and ice cover into the future.", "east": -150.0, "geometry": "POINT(-175 -66.5)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e CTD; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e LIDAR/LASER SOUNDERS \u003e LIDAR; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUOROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e MAGNETIC/MOTION SENSORS \u003e GRAVIMETERS \u003e GRAVIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e RECORDERS/LOGGERS \u003e AWS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e XBT; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e ECHO SOUNDERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e MBES; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e THERMOSALINOGRAPHS", "is_usap_dc": true, "keywords": "OCEAN MIXED LAYER; TRACE ELEMENTS; CARBON DIOXIDE; ATMOSPHERIC RADIATION; ICE GROWTH/MELT; AMD; BOUNDARY LAYER TEMPERATURE; SULFUR COMPOUNDS; NBP1704; HEAT FLUX; ICE DEPTH/THICKNESS; R/V NBP; USA/NSF; BOUNDARY LAYER WINDS; SNOW DEPTH; VERTICAL PROFILES; METHANE; POLYNYAS; CONDUCTIVITY; SEA ICE; Ross Sea; WATER MASSES; TURBULENCE; USAP-DC; Amd/Us", "locations": "Ross Sea", "north": -55.0, "nsf_funding_programs": "Antarctic Integrated System Science; Antarctic Ocean and Atmospheric Sciences; Antarctic Integrated System Science; Antarctic Integrated System Science; Antarctic Integrated System Science; Antarctic Instrumentation and Support", "paleo_time": null, "persons": "Ackley, Stephen; Bell, Robin; Weissling, Blake; Nuss, Wendell; Maksym, Edward; Stammerjohn, Sharon; Cassano, John; Guest, Peter; Sedwick, Peter; Xie , Hongjie", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "BCO-DMO; PI website; R2R; USAP-DC", "science_programs": null, "south": -78.0, "title": "Collaborative Research: Seasonal Sea Ice Production in the Ross Sea, Antarctica", "uid": "p0010032", "west": 160.0}, {"awards": "1443464 Sowers, Todd; 1443472 Brook, Edward; 1443710 Severinghaus, Jeffrey", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole CH4 data for termination; South Pole Ice Core Isotopes of N2 and Ar; South Pole ice core (SPC14) discrete methane data; South Pole ice core total air content; South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2; SP19 Gas Chronology", "datasets": [{"dataset_uid": "601231", "doi": "10.15784/601231", "keywords": "Air Content; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core total air content", "url": "https://www.usap-dc.org/view/dataset/601231"}, {"dataset_uid": "601152", "doi": "10.15784/601152", "keywords": "Antarctica; Antarctic Ice Sheet; Chemistry:gas; Chemistry:Gas; Chemistry:ice; Chemistry:Ice; Delta 18O; Dole Effect; Firn Thickness; Gas Isotopes; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Gravitational Settling; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Inert Gases; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2", "url": "https://www.usap-dc.org/view/dataset/601152"}, {"dataset_uid": "601230", "doi": "10.15784/601230", "keywords": "Antarctica; Atmospheric CH4; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Data; Methane; Methane Concentration; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole CH4 data for termination", "url": "https://www.usap-dc.org/view/dataset/601230"}, {"dataset_uid": "601517", "doi": "10.15784/601517", "keywords": "Antarctica; Argon; Argon Isotopes; Firn; Firn Temperature Gradient; Firn Thickness; Gas Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Nitrogen; Nitrogen Isotopes; South Pole; SPICEcore", "people": "Morgan, Jacob; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Isotopes of N2 and Ar", "url": "https://www.usap-dc.org/view/dataset/601517"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kahle, Emma; Sowers, Todd A.; Edwards, Jon S.; Kennedy, Joshua A.; Aydin, Murat; Kreutz, Karl; Buizert, Christo; Brook, Edward J.; Epifanio, Jenna; Fudge, T. J.; Osterberg, Erich; Winski, Dominic A.; Hood, Ekaterina; Kalk, Michael; Steig, Eric J.; Ferris, David G.; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}], "date_created": "Sat, 02 Feb 2019 00:00:00 GMT", "description": "Gases trapped in ice cores have revealed astonishing things about the greenhouse gas composition of the past atmosphere, including the fact that carbon dioxide concentrations never rose above 300 parts per million during the last 800,000 years. This places today\u0027s concentration of 400 parts per million in stark contrast. Furthermore, these gas records show that natural sources of greenhouse gas such as oceans and ecosystems act as amplifiers of climate change by increasing emissions of gases during warmer periods. Such amplification is expected to occur in the future, adding to the human-produced gas burden. The South Pole ice core will build upon these prior findings by expanding the suite of gases to include, for the first time, those potent trace gases that both trapped heat and depleted ozone during the past 40,000 years. The present project on inert gases and methane in the South Pole ice core will improve the dating of this crucial record, to unprecedented precision, so that the relative timing of events can be used to learn about the mechanism of trace gas production and destruction, and consequent climate change amplification. Ultimately, this information will inform predictions of future atmospheric chemical cleansing mechanisms and climate in the context of our rapidly changing atmosphere. This award also engages young people in the excitement of discovery and polar research, helping to entrain the next generations of scientists and educators. Education of graduate students, a young researcher (Buizert), and training of technicians, will add to the nation?s human resource base. \u003cbr/\u003e \u003cbr/\u003eThis award funds the construction of the gas chronology for the South Pole 1500m ice core, using measured inert gases (d15N and d40Ar--Nitrogen and Argon isotope ratios, respectively) and methane in combination with a next-generation firn densification model that treats the stochastic nature of air trapping and the role of impurities on densification. The project addresses fundamental gaps in scientific understanding that limit the accuracy of gas chronologies, specifically a poor knowledge of the controls on ice-core d15N and the possible role of layering and impurities in firn densification. These gaps will be addressed by studying the gas enclosure process in modern firn at the deep core site. The work will comprise the first-ever firn air pumping experiment that has tightly co-located measurements of firn structural properties on the core taken from the same borehole.\u003cbr/\u003e\u003cbr/\u003eThe project will test the hypothesis that the lock-in horizon as defined by firn air d15N, CO2, and methane is structurally controlled by impermeable layers, which are in turn created by high-impurity content horizons in which densification is enhanced. Thermal signals will be sought using the inert gas measurements, which improve the temperature record with benefits to the firn densification modeling. Neon, argon, and oxygen will be measured in firn air and a limited number of deep core samples to test whether glacial period layering was enhanced, which could explain low observed d15N in the last glacial period. Drawing on separate volcanic and methane synchronization to well-dated ice cores to create independent ice and gas tie points, independent empirical estimates of the gas age-ice age difference will be made to check the validity of the firn densification model-inert gas approach to calculating the gas age-ice age difference. These points will also be used to test whether the anomalously low d15N seen during the last glacial period in east Antarctic ice cores is due to deep air convection in the firn, or a missing impurity dependence in the firn densification models. \u003cbr/\u003e\u003cbr/\u003eThe increased physical understanding gained from these studies, combined with new high-precision measurements, will lead to improved accuracy of the gas chronology of the South Pole ice core, which will enhance the overall science return from this gas-oriented core. This will lead to clarification of timing of atmospheric gas variations and temperature, and aid in efforts to understand the biogeochemical feedbacks among trace gases. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. Ozone-depleting substances will be measured in the South Pole ice core record, and a precise gas chronology will add value. Lastly, by seeking a better understanding of the physics of gas entrapment, the project aims to have an impact on ice-core science in general.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "USAP-DC; AMD; LABORATORY; Antarctica; NITROGEN ISOTOPES; USA/NSF; METHANE; Amd/Us; FIELD INVESTIGATION", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Sowers, Todd A.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Inert Gas and Methane Based Climate Records throughout the South Pole Deep Ice Core", "uid": "p0010005", "west": 0.0}, {"awards": "1644245 Aydin, Murat", "bounds_geometry": null, "dataset_titles": "Ice Core Air Ethane and Acetylene Measurements - South Pole SPC14 Ice Core (SPICEcore project); Ice core ethane measurements, Greenland and Antarctica, 1000-1900 CE.", "datasets": [{"dataset_uid": "601367", "doi": "10.15784/601367", "keywords": "Antarctica; Ethane", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Ice Core Air Ethane and Acetylene Measurements - South Pole SPC14 Ice Core (SPICEcore project)", "url": "https://www.usap-dc.org/view/dataset/601367"}, {"dataset_uid": "002574", "doi": "", "keywords": null, "people": null, "repository": "Arctic Data Center", "science_program": null, "title": "Ice core ethane measurements, Greenland and Antarctica, 1000-1900 CE.", "url": "https://arcticdata.io/catalog/view/doi:10.18739/A2CR5NC1B"}], "date_created": "Tue, 13 Nov 2018 00:00:00 GMT", "description": "Aydin/1644245\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to measure ethane in ice core air extracted from the recently drilled intermediate depth South Pole ice core (SPICECORE). Ethane is an abundant hydrocarbon in the atmosphere. The ice core samples that will be used in this analysis will span about 150 years before present to about 55,000 years before present and therefore, ethane emissions linked to human activities are not a subject of this study. The study will focus on quantifying the variability in the natural sources of ethane and the processes that govern its removal from the atmosphere. A long-term ice core ethane record will provide new knowledge on the chemistry of Earth?s atmosphere during time periods when human influence was either much smaller than present day or non-existent. The broader impacts of this work include education and training of students and a contribution to a better understanding of the chemistry of the atmosphere in the past and how it has been impacted by past changes in climate.\u003cbr/\u003e\u003cbr/\u003eNatural sources that emit ethane are both geologic (e.g. seeps, vents, mud volcanoes etc.) and pyrogenic (wild fires) which is commonly called biomass burning. Ethane is removed from the atmosphere via oxidation reactions. The ice core ethane measurements have great potential as a proxy for gaseous emissions from biomass burning. This is especially true for time periods preceding the industrial revolution when atmospheric variability of trace gases was largely controlled by natural processes. Another objective of this study is to improve understanding of the causes of atmospheric methane variability apparent which are in the existing ice core records. Methane is a simpler hydrocarbon than ethane and more abundant in the atmosphere. Even though the project does not include any methane measurements; the commonalities between the sources and removal of atmospheric ethane and methane mean that ethane measurements can be used to gain insight into the causes of changes in atmospheric methane levels. The broader impacts of the project include partial support for one Ph.D. student and support for undergraduate researchers at UC Irvine. The PIs group currently has 4 undergraduate researchers. The PI and the graduate students in the UCI ice core laboratory regularly participate in on- and off-campus activities such as laboratory tours and lectures directed towards educating high-school students and science teachers, and the local community at large about the scientific value of polar ice cores as an environmental record of our planet\u0027s past. The results of this research will be disseminated via peer-review publications and will contribute to policy-relevant activities such as the IPCC Climate Assessment. Data resulting from this project will be archived in a national data repository. This award does not have field work in Antarctica.", "east": null, "geometry": null, "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "USAP-DC; NOT APPLICABLE", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "Arctic Data Center; USAP-DC", "science_programs": "SPICEcore", "south": null, "title": "Ethane Measurements in the Intermediate Depth South Pole Ice Core (SPICECORE)", "uid": "p0000762", "west": null}, {"awards": "1443232 Waddington, Edwin", "bounds_geometry": "POLYGON((110 -89,117 -89,124 -89,131 -89,138 -89,145 -89,152 -89,159 -89,166 -89,173 -89,180 -89,180 -89.1,180 -89.2,180 -89.3,180 -89.4,180 -89.5,180 -89.6,180 -89.7,180 -89.8,180 -89.9,180 -90,173 -90,166 -90,159 -90,152 -90,145 -90,138 -90,131 -90,124 -90,117 -90,110 -90,110 -89.9,110 -89.8,110 -89.7,110 -89.6,110 -89.5,110 -89.4,110 -89.3,110 -89.2,110 -89.1,110 -89))", "dataset_titles": "AC-ECM for SPICEcore; ECM (DC and AC) multi-track data and images from 2016 processing season", "datasets": [{"dataset_uid": "601189", "doi": " 10.15784/601189 ", "keywords": "Antarctica; Electrical Conductivity; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Physical Properties; Snow/ice; Snow/Ice; South Pole; SPICEcore; Volcanic", "people": "Fudge, T. J.; Waddington, Edwin D.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "AC-ECM for SPICEcore", "url": "https://www.usap-dc.org/view/dataset/601189"}, {"dataset_uid": "601366", "doi": "10.15784/601366", "keywords": "Antarctica", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "ECM (DC and AC) multi-track data and images from 2016 processing season", "url": "https://www.usap-dc.org/view/dataset/601366"}], "date_created": "Tue, 08 May 2018 00:00:00 GMT", "description": "Ice cores record detailed histories of past climate variations. The South Pole ice core will allow investigation of atmospheric trace gases and fill an important gap in understanding the pattern of climate variability across Antarctica. An accurate timescale that assigns an age to the ice at each depth in the core is essential to interpretation of the ice-core records. This work will use electrical methods to identify volcanic eruptions throughout the past ~40,000 years in the core by detecting the enhanced electrical conductance in those layers due to volcanic impurities in the ice. These eruptions will be pattern-matched to other cores across Antarctica, synchronizing the timing of climate variations among cores and allowing the precise timescales developed for other Antarctic ice cores to be transferred to the South Pole ice core. The well-dated records of volcanic forcing will be combined with records of atmospheric gases, stable water-isotopes, and aerosols to better understand the large natural climate variations of the past 40,000 years. \u003cbr/\u003e \u003cbr/\u003eThe electrical conductance method and dielectric profiling measurements will be made along the length of each section of the South Pole ice core at the National Ice Core Lab. These measurements will help to establish a timescale for the core. Electrical measurements will provide a continuous record of volcanic events for the entire core including through the brittle ice (550-1250m representing ~10,000-20,000 year-old ice) where the core quality and thin annual layers may prevent continuous melt analysis and cause discrete measurements to miss volcanic events. The electrical measurements also produce a 2-D image of the electrical layering on a longitudinal cut surface of each core. These data will be used to identify any irregular or absent layering that would indicate a stratigraphic disturbance in the core. A robust chronology is essential to interpretation of the paleoclimate records from the South Pole ice core. The investigators will engage teachers through talks and webinars with the National Science Teachers Association and will share information with the public at events such as Polar Science Weekend at the Pacific Science Center. Results will be disseminated through publications and conference presentations and the data will be archived and publicly available.", "east": 180.0, "geometry": "POINT(145 -89.5)", "instruments": null, "is_usap_dc": true, "keywords": "USAP-DC; USA/NSF; Amd/Us; AMD; LABORATORY", "locations": null, "north": -89.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Fudge, T. J.; Waddington, Edwin D.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Using Electrical Conductance Measurements to Develop the South Pole Ice Core Chronology", "uid": "p0000378", "west": 110.0}, {"awards": "1542778 Alley, Richard", "bounds_geometry": null, "dataset_titles": "c-Axis Fabric of the South Pole Ice Core, SPC14; South Pole Ice Core (SPIcecore) Visual Observations", "datasets": [{"dataset_uid": "601057", "doi": "10.15784/601057", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; South Pole; SPICEcore", "people": "Voigt, Donald E.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "c-Axis Fabric of the South Pole Ice Core, SPC14", "url": "https://www.usap-dc.org/view/dataset/601057"}, {"dataset_uid": "601088", "doi": "10.15784/601088", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Physical Properties; Snow/ice; Snow/Ice; South Pole; Visual Observations", "people": "Alley, Richard; Fegyveresi, John", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core (SPIcecore) Visual Observations", "url": "https://www.usap-dc.org/view/dataset/601088"}], "date_created": "Fri, 29 Sep 2017 00:00:00 GMT", "description": "This award supports a three-year effort to study physical properties of the South Pole ice core to help provide a high-time-resolution history of trace gases and other paleoclimatic indicators from an especially cold site with high preservation potential for important signals. The physical-properties studies include visual inspection to identify any flow disturbances and for identifying annual layers and other features, and combined bubble, grain and ice crystal orientation studies to better understand the processes occurring in the ice that affect the climate record and the ice-sheet behavior. Success of these efforts will provide necessary support for dating and quality control to others studying the ice core, as well as determining the climate history of the site, flow state, and key physical processes in ice.\u003cbr/\u003e\u003cbr/\u003eThe intellectual merits of the project include better understanding of physical processes, paleoclimatic reconstruction, dating of the ice, and quality assurance. Visual inspection of the core will help identify evidence of flow disturbances that would disrupt the integrity of the climate record and will reveal volcanic horizons and other features of interest. Annual layer counting will be conducted to help estimate accumulation rate over time as recorded in the ice core. Measurements of C-axis fabric, grain size and shapes, and bubble characteristics will provide information about processes occurring in the ice sheet as well as the history of ice flow, current flow state and how the ice is flowing and how easily it will flow in the future. Analysis of this data in conjunction with microCT data will help to reveal grain-scale processes. The broader impacts of the project include support for an early-career, post-doctoral researcher, and improved paleoclimatic data of societal relevance. The results will be incorporated into the active program of education and outreach which have educated many students, members of the public and policy makers through the sharing of information and educational materials about all aspects of ice core science and paleoclimate.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Alley, Richard; Fegyveresi, John; Voigt, Donald E.", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": null, "title": "Climate History and Flow Processes from Physical Analyses of the SPICECORE South Pole Ice Core", "uid": "p0000141", "west": null}, {"awards": "1043780 Aydin, Murat", "bounds_geometry": null, "dataset_titles": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core; Ultra-trace Measurements in the WAIS Divide 06A Ice Core", "datasets": [{"dataset_uid": "609659", "doi": "10.7265/N5CV4FPK", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Ultra-trace Measurements in the WAIS Divide 06A Ice Core", "url": "https://www.usap-dc.org/view/dataset/609659"}, {"dataset_uid": "601361", "doi": "10.15784/601361", "keywords": "Antarctica; Carbonyl Sulfide; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/601361"}], "date_created": "Tue, 27 Oct 2015 00:00:00 GMT", "description": "Aydin/1043780\u003cbr/\u003eThis award supports the analysis of the trace gas carbonyl sulfide (COS) in a deep ice core from West Antarctic Ice Sheet Divide (WAIS-D), Antarctica. COS is the most abundant sulfur gas in the troposphere and a precursor of stratospheric sulfate. It has a large terrestrial COS sink that is tightly coupled to the photosynthetic uptake of atmospheric carbon dioxide (CO2). The primary goal of this project is to develop high a resolution Holocene record of COS from the WAIS-D 06A ice core. The main objectives are 1) to assess the natural variability of COS and the extent to which its atmospheric variability was influenced by climate variability, and 2) to examine the relationship between changes in atmospheric COS and CO2. This project also includes low-resolution sampling and analysis of COS from 10,000-30,000 yrs BP, covering the transition from the Last Glacial Maximum into the early Holocene. The goal of this work is to assess the stability of COS in ice core air over long time scales and to establish the COS levels during the last glacial maximum and the magnitude of the change between glacial and interglacial conditions. The results of this work will be disseminated via peer-review publications and will contribute to environmental assessments such as the WMO Stratospheric Ozone Assessment and IPCC Climate Assessment. This project will support a PhD student and undergraduate researcher in the Department of Earth System Science at the University of California, Irvine, and will create summer research opportunities for undergraduates from non-research active Universities.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ethane; LABORATORY; N-Butane; Carbonyl Sulfide; Propane; Methyl Bromide; Methyl Chloride; Carbon Disulfide", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat; Saltzman, Eric", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Carbonyl Sulfide Measurements in the Deep West Antarctic Ice Sheet Divide Ice Core", "uid": "p0000055", "west": null}, {"awards": "0839075 Priscu, John; 0839093 McConnell, Joseph; 0839122 Saltzman, Eric", "bounds_geometry": "POINT(112.05 -79.28)", "dataset_titles": "Fluorescence spectroscopy data from the West Antarctic Ice Sheet (WAIS) Divide ice core, WDC06A; Holocene Black Carbon in Antarctica; Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core; Prokaryotic cell concentration record from the WAIS Divide ice core", "datasets": [{"dataset_uid": "601361", "doi": "10.15784/601361", "keywords": "Antarctica; Carbonyl Sulfide; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/601361"}, {"dataset_uid": "601072", "doi": "10.15784/601072", "keywords": "Antarctica; Biota; Cell Counts; Glaciology; Microbiology; WAIS Divide; WAIS Divide Ice Core", "people": "Priscu, John; Santibanez, Pamela", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Prokaryotic cell concentration record from the WAIS Divide ice core", "url": "https://www.usap-dc.org/view/dataset/601072"}, {"dataset_uid": "601034", "doi": "10.15784/601034", "keywords": "Antarctica; Atmosphere; Black Carbon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "Arienzo, Monica; McConnell, Joseph", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Holocene Black Carbon in Antarctica", "url": "https://www.usap-dc.org/view/dataset/601034"}, {"dataset_uid": "601006", "doi": "10.15784/601006", "keywords": "Antarctica; Fluorescence Spectroscopy; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Physical Properties; WAIS Divide; WAIS Divide Ice Core", "people": "D\u0027Andrilli, Juliana; Priscu, John", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Fluorescence spectroscopy data from the West Antarctic Ice Sheet (WAIS) Divide ice core, WDC06A", "url": "https://www.usap-dc.org/view/dataset/601006"}], "date_created": "Fri, 30 May 2014 00:00:00 GMT", "description": "This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to use the WAIS Divide deep core to investigate the Last Deglaciation at sub-annual resolution through an integrated set of chemical and biological analyses. The intellectual merit of the project is that these analyses, combined with others, will take advantage of the high snow accumulation WAIS Divide site yielding the highest time resolution glacio-biogeochemical and gas record of any deep Antarctic ice core. With other high resolution Greenland cores (GISP2 and GRIP) and lower resolution Antarctic cores, the combined record will yield new insights into worldwide climate dynamics and abrupt change. The proposed chemical, biological, and elemental tracer measurements will also be used to address all of the WAIS Divide science themes. The broader impacts of the project include education and outreach activities such as numerous presentations to local K-12 students; opportunities for student and teacher involvement in the laboratory work; a teacher training program in Earth sciences in the heavily minority Santa Ana, Compton, and Costa Mesa, California school districts; and development of high school curricula. Extensive graduate and undergraduate student involvement also is planned and will include one post doctoral associate, one graduate student, and undergraduate hourly involvement at DRI; a graduate student and undergraduates at University of California, Irvine (UCI); and a post doctoral fellow at MSU. Student recruitment will be made from underrepresented groups building on a long track record of involvement and will include the NSF funded California Alliance for Minority Participation (CAMP) and the Montana American Indian Research Opportunities (AIRO).\u003cbr/\u003e\u003cbr/\u003eThis award does not involve field work in Antarctica.", "east": 112.05, "geometry": "POINT(112.05 -79.28)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e CARBON ANALYZERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUOROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e WAS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e ICE CORE MELTER; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PHOTOMETERS \u003e SPECTROPHOTOMETERS", "is_usap_dc": true, "keywords": "FIELD SURVEYS; Bacteria Ice Core; LABORATORY; Ice Core; FIELD INVESTIGATION; West Antarctica; Not provided; Dissolved Organic Carbon", "locations": "West Antarctica", "north": -79.28, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY", "persons": "Foreman, Christine; Skidmore, Mark; Saltzman, Eric; McConnell, Joseph; Priscu, John", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.28, "title": "Collaborative Research: Integrated High Resolution Chemical and Biological Measurements on the Deep WAIS Divide Core", "uid": "p0000273", "west": 112.05}, {"awards": "0738975 Baker, Ian", "bounds_geometry": null, "dataset_titles": "Siple Dome A (SDMA) Grain Orientation 640 - 790 Meters", "datasets": [{"dataset_uid": "609526", "doi": "10.7265/N53T9F5X", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Sample/collection Description; Sample/Collection Description; Siple Dome; Siple Dome Ice Core; South Pole; WAISCORES", "people": "Obbard, Rachel; Sieg, Katherine; Baker, Ian", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Siple Dome A (SDMA) Grain Orientation 640 - 790 Meters", "url": "https://www.usap-dc.org/view/dataset/609526"}], "date_created": "Mon, 26 Nov 2012 00:00:00 GMT", "description": "This award supports a project to fully characterize the microstructure in ice cores, in particular the microstructural locations of impurities, grain orientations and strain gradients. This work will complement the optical observations, electrical conductivity measurement, and precise, detailed measurements of the soluble ion and gas contents that are performed by others. Linking the concentrations of soluble ions and gases, measured to a few parts per billion, to the optically determined annual layer structure and the stable isotope data in ice cores has enabled a great deal to be established about the concentrations and depth/age distributions of particles, trace gases and impurities for several polar ice cores. Ice core studies carried out by several groups contribute immensely to our understanding of paleoclimate and, to our ability to predict future climate change. The work will build on previous measurements and technique development in this area, as well as focusing on new techniques to characterize ice cores. The work will use both scanning electron microscopy (SEM) coupled with X-ray energy dispersive spectroscopy (EDS) and confocal scanning optical microscopy coupled with Raman spectroscopy (RS) to determine the microstructural locations of impurities and correlate this information with depth/age, and impurity type and concentration for several polar ice cores. The Broader Impacts of the proposed work are that knowledge of the location of impurities coupled with the grain orientation (both c- and a-axis) and grain misorientation information will allow paleoclimatologists to better interpret ice core data and other scientists to understand and model the physical and mechanical properties of natural ice sheets. Other Broader Impacts of the work are that the work will be performed and lead to the education of a Ph.D. student. At the end of the project, as well as the knowledge gained from coursework, the graduate student will have experience in ice core specimen preparation and characterization using scanning electron microscopy, x-ray microanalysis, confocal scanning microscopy, Raman spectroscopy and ion chromatography. Results from the research will be published in refereed journals, presented at conferences, and placed on a web page.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES", "is_usap_dc": true, "keywords": "FEI Xl30 Environmental Scanning Electron Microscope - Field Emission Gun (esem - Feg); LABORATORY; Electron Backscatter Diffraction", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Obbard, Rachel; Sieg, Katherine", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Advanced Microstructural Characterization of Polar Ice Cores", "uid": "p0000178", "west": null}, {"awards": "0739598 Aydin, Murat; 0739491 Sowers, Todd", "bounds_geometry": null, "dataset_titles": "Alkanes in Firn Air Samples, Antarctica and Greenland; Methane Isotopes in South Pole Firn Air, 2008", "datasets": [{"dataset_uid": "609504", "doi": "10.7265/N5X9287C", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Snow/ice; Snow/Ice; South Pole; WAIS Divide", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Alkanes in Firn Air Samples, Antarctica and Greenland", "url": "https://www.usap-dc.org/view/dataset/609504"}, {"dataset_uid": "609502", "doi": "10.7265/N55T3HFP", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Isotope; Paleoclimate; Snow/ice; Snow/Ice; South Pole", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": null, "title": "Methane Isotopes in South Pole Firn Air, 2008", "url": "https://www.usap-dc.org/view/dataset/609502"}], "date_created": "Thu, 18 Aug 2011 00:00:00 GMT", "description": "This award supports a project to make measurements of methane and other trace gases in firn air collected at South Pole, Antarctica. The analyses will include: methane isotopes (delta-13CH4 and delta-DCH4), light non-methane hydrocarbons (ethane, propane, and n-butane), sulfur gases (COS, CS2), and methyl halides (CH3Cl and CH3Br). The atmospheric burdens of these trace gases reflect changes in atmospheric OH, biomass burning, biogenic activity in terrestrial, oceanic, and wetland ecosystems, and industrial/agricultural activity. The goal of this project is to develop atmospheric histories for these trace gases over the last century through examination of depth profiles of these gases in South Pole firn air. The project will involve two phases: 1) a field campaign at South Pole, Antarctica to drill two firn holes and fill a total of ~200 flasks from depths reaching 120 m, 2) analysis of firn air at University of California, Irvine, Penn State University, and several other collaborating laboratories. Atmospheric histories will be inferred from the measurements using a one dimensional advective/diffusive model of firn air transport. This study will provide new information about the recent changes in atmospheric levels of these gases, providing about a 90 year long time series record that connects the earlier surface and firn air measurements to present day. The project will also explore the possibility of in- situ production of light non-methane hydrocarbons in firn air that is relevant to the interpretation of ice core records. The broader impacts of this research are that it has the potential for significant societal impact by improving our understanding of climate change and man\u0027s input to the atmosphere. The results of this work will be disseminated through the peer review process, and will contribute to environmental assessments, such as the Inter-governmental Panel on Climate Change (IPCC) Climate Assessment and the Word Meteorological Organization (WMO) Stratospheric Ozone Assessment. This research will provide educational opportunities for graduate and undergraduate students, and will contribute to a teacher training program for K-12 teachers in minority school districts.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS", "is_usap_dc": true, "keywords": "FIELD INVESTIGATION; Isotope; Firn Air Chemistry; Firn Air Isotope Measurements; Not provided; LABORATORY; South Pole; Firn; Delta 13C; Carbon-13; Mass Spectrometer; Deuterium; Mass Spectrometry; Firn Air Samples; Carbon; Gas Chromatography; Polar Firn Air; GROUND-BASED OBSERVATIONS; Methane; Antarctica; Firn Air Isotopes; Delta Deuterium; FIELD SURVEYS; Firn Air; Chromatography; Methane Isotopes; Carbon Isotopes; Stable Isotopes", "locations": "Antarctica; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat; Saltzman, Eric; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air", "uid": "p0000162", "west": null}, {"awards": "0440759 Sowers, Todd; 0440602 Saltzman, Eric; 0440615 Brook, Edward; 0440498 White, James; 0440701 Severinghaus, Jeffrey; 0440509 Battle, Mark", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane Isotopes from the WAIS Divide Ice Core; Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A; WAIS ice core Methane Data, Carbon Dioxide Data", "datasets": [{"dataset_uid": "609638", "doi": "10.7265/N56971HF", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS Divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.; Orsi, Anais J.", "repository": "USAP-DC", "science_program": null, "title": "Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A", "url": "https://www.usap-dc.org/view/dataset/609638"}, {"dataset_uid": "609412", "doi": "10.7265/N5251G40", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609412"}, {"dataset_uid": "609435", "doi": "10.7265/N5J67DW0", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Methane Isotopes from the WAIS Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609435"}, {"dataset_uid": "609493", "doi": "10.7265/N5319SV3", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Brook, Edward J.; Mitchell, Logan E; Taylor, Kendrick C.; McConnell, Joseph; Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS ice core Methane Data, Carbon Dioxide Data", "url": "https://www.usap-dc.org/view/dataset/609493"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}], "date_created": "Tue, 03 Feb 2009 00:00:00 GMT", "description": "This award supports a project to measure the elemental and isotopic composition of firn air and occluded air in shallow boreholes and ice cores from the WAIS Divide site, the location of a deep ice-coring program planned for 2006-07 and subsequent seasons. The three primary objectives are: 1) to establish the nature of firn air movement and trapping at the site to aid interpretations of gas data from the deep core; 2) to expand the suite of atmospheric trace gas species that can be measured in ice and replicate existing records of other species; and 3) to inter-calibrate all collaborating labs to insure that compositional and isotopic data sets are inter-comparable. The program will be initiated with a shallow drilling program during the 05/06 field season which will recover two 300+m cores and firn air samples. The ice core and firn air will provide more than 700 years of atmospheric history that will be used to address a number of important questions related to atmospheric change over this time period. The research team consists of six US laboratories that also plan to participate in the deep core program. This collaborative research program has a number of advantages. First, the scientists will be able to coordinate sample allocation a priori to maximize the resolution and overlap of records of interrelated species. Second, sample registration will be exact, allowing direct comparison of all records. Third, a coherent data set will be produced at the same time and all PI.s will participate in interpreting and publishing the results. This will insure that the best possible understanding of gas records at the WAIS Divide site will be achieved, and that all work necessary to interpret the deep core is conducted in a timely fashion. The collaborative structure created by the proposal will encourage sharing of techniques, equipment, and ideas between the laboratories. The research will identify impacts of various industrial/agricultural activities and help to distinguish them from natural variations, and will include species for which there are no long records of anthropogenic impact. The work will also help to predict future atmospheric loadings. The project will contribute to training scientists at several levels, including seven undergraduates, two graduate students and one post doctoral fellow.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e SPECTROMETERS/RADIOMETERS \u003e SPECTROMETERS \u003e SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; WAIS Divide; Firn; LABORATORY; Ice Core; Firn Air Isotope Measurements; Shallow Firn Air; FIELD INVESTIGATION; Ice Core Gas Records; GROUND-BASED OBSERVATIONS; Firn Isotopes; Wais Divide-project; Gas Data; Polar Firn Air; Not provided; Trace Gas Species; Trapped Gases; West Antarctic Ice Sheet; Deep Core; Ice Sheet; Gas; Firn Air Isotopes; FIELD SURVEYS; Air Samples; Atmospheric Gases; Isotope; Cores; Atmosphere; Ice Core Data; Surface Temperatures; Firn Air; Borehole; Antarctica", "locations": "West Antarctic Ice Sheet; Antarctica; WAIS Divide", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Battle, Mark; Mischler, John; Saltzman, Eric; Aydin, Murat; White, James; Brook, Edward J.; Orsi, Anais J.; Severinghaus, Jeffrey P.; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "uid": "p0000368", "west": -112.085}, {"awards": "0636953 Saltzman, Eric", "bounds_geometry": "POINT(-148.82 -81.66)", "dataset_titles": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core; Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core; Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core; Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica; Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "datasets": [{"dataset_uid": "601361", "doi": "10.15784/601361", "keywords": "Antarctica; Carbonyl Sulfide; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/601361"}, {"dataset_uid": "609598", "doi": "10.7265/N5X0650D", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609598"}, {"dataset_uid": "609599", "doi": "10.7265/N5S75D8P", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609599"}, {"dataset_uid": "609600", "doi": "10.7265/N5PG1PPB", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609600"}, {"dataset_uid": "609356", "doi": "10.7265/N56W9807", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Saltzman, Eric; Aydin, Murat; Williams, Margaret", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609356"}], "date_created": "Wed, 22 Oct 2008 00:00:00 GMT", "description": "Saltzman/0636953\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to measure methyl chloride, methyl bromide, and carbonyl sulfide in air extracted from Antarctic ice cores. Previous measurements in firn air and shallow ice cores suggest that the ice archive contains paleo-atmospheric signals for these gases. The goal of this study is to extend these records throughout the Holocene and into the last Glacial period to examine the behavior of these trace gases over longer time scales and a wider range of climatic conditions. These studies are exploratory, and both the stability of these trace gases and the extent to which they may be impacted by in situ processes will be assessed. This project will involve sampling and analyzing archived ice core samples from the Siple Dome, Taylor Dome, Byrd, and Vostok ice cores. The ice core samples will be analyzed by dry extraction, with gas chromatography/mass spectrometry with isotope dilution. The ice core measurements will generate new information about the range of natural variability of these trace gases in the atmosphere. The intellectual merit of this project is that this work will provide an improved basis for assessing the impact of anthropogenic activities on biogeochemical cycles, and new insight into the climatic sensitivity of the biogeochemical processes controlling atmospheric composition. The broader impact of this project is that there is a strong societal interest in understanding how man\u0027s activities impact the atmosphere, and how atmospheric chemistry may be altered by future climate change. The results of this study will contribute to the development of scenarios used for future projections of stratospheric ozone and climate change. In terms of human development, this project will support the doctoral dissertation of a graduate student in Earth System Science, and undergraduate research on polar ice core chemistry. This project will also contribute to the development of an Earth Sciences teacher training curriculum for high school teachers in the Orange County school system in collaboration with an established, NSF-sponsored Math and Science Partnership program (FOCUS).", "east": -148.82, "geometry": "POINT(-148.82 -81.66)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Methyl Bromide; Antarctic; Ice Core Gas Records; Ice Core Data; Carbonyl Sulfide; Methyl Chloride; Antarctic Ice Sheet; Siple Dome; Trace Gases; Ice Core Chemistry; Biogeochemical; Atmospheric Chemistry; West Antarctic Ice Sheet; LABORATORY; Ice Core; West Antarctica", "locations": "Antarctic; Antarctica; Antarctic Ice Sheet; Siple Dome; West Antarctica; West Antarctic Ice Sheet", "north": -81.66, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core; Siple Dome Ice Core", "south": -81.66, "title": "Methyl Chloride, Methyl Bromide, and Carbonyl Sulfide in Deep Antarctic Ice Cores", "uid": "p0000042", "west": -148.82}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Tatum, Cheryl; Saltzman, Eric; Aydin, Murat; Williams, Margaret", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}, {"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}, {"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; Carbonyl Sulfide; Siple Coast; Chloride; Trapped Gases; Snow; Ice Core Chemistry; Chromatography; Siple; GROUND STATIONS; Atmospheric Gases; Ozone Depletion; AWS Siple; Ice Sheet; Ice Core Data; Antarctica; Glaciology; West Antarctica; Atmospheric Chemistry; Ice Core; Stratigraphy; LABORATORY; Methane; Mass Spectrometer; GROUND-BASED OBSERVATIONS; WAISCORES; Msa; Mass Spectrometry; Not provided; Siple Dome; Gas Measurement", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica; Siple", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}, {"awards": "0125900 Sowers, Todd", "bounds_geometry": "POINT(-148.8 -81.7)", "dataset_titles": null, "datasets": null, "date_created": "Thu, 26 May 2005 00:00:00 GMT", "description": "0125900\u003cbr/\u003eSowers\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to improve the understanding of the biogeochemical processes that control CH4 emissions. Records of the concentration of methane in trapped gases in ice tell us about changes in atmospheric loading through time. Such records do not, however, provide information on the individual sources or sinks. One way to refine our understanding of the cycling of bioactive trace gases like methane is to use stable isotope records of trapped gases in ice cores. This project will measure the Deuterium/Hydrogen (D/H) ratio of methane trapped in shallow/recent ice (covering the last ~ 200 years) at Siple Dome, Antarctica. The proposed work will complement current efforts to measure the carbon-13 isotope ratio of methane in ice cores and will provide fundamental information on the various sources and sinks of atmospheric methane over the last 200 years.", "east": -148.8, "geometry": "POINT(-148.8 -81.7)", "instruments": null, "is_usap_dc": false, "keywords": "Siple Dome; Not provided; Ch4; Methane; Antarctica; Ice Core", "locations": "Siple Dome; Antarctica", "north": -81.7, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Sowers, Todd A.", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -81.7, "title": "Constructing the first D/H record of atmospheric methane covering the last two centuries.", "uid": "p0000754", "west": -148.8}, {"awards": "0125981 Sowers, Todd", "bounds_geometry": "POLYGON((-180 -62.83,-144 -62.83,-108 -62.83,-72 -62.83,-36 -62.83,0 -62.83,36 -62.83,72 -62.83,108 -62.83,144 -62.83,180 -62.83,180 -65.547,180 -68.264,180 -70.981,180 -73.698,180 -76.415,180 -79.132,180 -81.849,180 -84.566,180 -87.283,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.283,-180 -84.566,-180 -81.849,-180 -79.132,-180 -76.415,-180 -73.698,-180 -70.981,-180 -68.264,-180 -65.547,-180 -62.83))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 05 May 2005 00:00:00 GMT", "description": "0125981\u003cbr/\u003eSowers\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to construct an isotopic record of atmospheric methane and nitrous oxide over the last century from South Pole firn air. Over the last 150 years, atmospheric methane and nitrous oxide concentrations have risen in response to increased emissions from various anthropogenic activities. As this trend is liable to continue in the foreseeable future, it is important to understand the biogeochemical processes that contribute to the emissions of these two greenhouse gases. In this context, records of the variations in the atmospheric loading of trace gases found in ice cores and interstitial spaces in the snow near the surface of the ice sheet (firn air) provide fundamental boundary conditions for reconstructing historical emission records. One way to improve our understanding of the cycling of bioactive trace gases and their emission records is to use stable isotope tracers, which have been recorded in the ice cores and firn air. This project will develop records of carbon-13 and deuterium isotope ratios of methane, as well as the nitrogen-15, oxygen-18 and the isotopomer composition of nitrous oxide trapped in firn air samples collected in January 2001 at the South Pole. These measurements will allow isotopic records of these atmospheric gases to be reconstructed throughout the 20th century. Such records will help to establish the relative contribution of individual sources with a higher degree of confidence than is currently available.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": -62.83, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Sowers, Todd A.", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -90.0, "title": "Generating an Isotopic Record of Atmospheric Methane and Nitrous Oxide Over the Last Century from South Pole Firn Air", "uid": "p0000086", "west": -180.0}]

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