USAP-DC

{"dp_type": "Project", "free_text": "Nitrogen Isotopes"}

[{"awards": "1903681 Brook, Edward J.", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Final N2O isotopic data including isotopomer ratios for the last deglaciation and Heinrich Stadia 4/Dansgaard Oeschger Event 8; Preliminary nitrous oxide site preference isotopic data for last deglaciation from Taylor Glacier", "datasets": [{"dataset_uid": "601592", "doi": "10.15784/601592", "keywords": "Antarctica; Nitrous Oxide; Taylor Glacier", "people": "Menking, Andy; Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "Preliminary nitrous oxide site preference isotopic data for last deglaciation from Taylor Glacier", "url": "https://www.usap-dc.org/view/dataset/601592"}, {"dataset_uid": "601803", "doi": "10.15784/601803", "keywords": "Antarctica; Cryosphere; Ice Core; Nitrous Oxide; Taylor Glacier", "people": "Brook, Edward J.; Menking, Andy", "repository": "USAP-DC", "science_program": null, "title": "Final N2O isotopic data including isotopomer ratios for the last deglaciation and Heinrich Stadia 4/Dansgaard Oeschger Event 8", "url": "https://www.usap-dc.org/view/dataset/601803"}], "date_created": "Wed, 19 Jun 2024 00:00:00 GMT", "description": "The objective of this project is to understand why the nitrous oxide (N2O) content of the atmosphere was lower during the last ice age (about 20,000-100,000 years ago) than in the subsequent warm period (10,000 years ago to present) and why it fluctuated during climate changes within the ice age. Nitrous oxide is a greenhouse gas that contributes to modern global warming. It is thought that modern warming will in turn cause increases in natural sources of nitrous oxide from bacteria in soils and the ocean, creating a \"positive feedback.\" However, the amount these sources will increase is uncertain because the different ways that nitrous oxide are produced, and how sensitive they are to warmer climate, are not well known. This project will measure a unique property of the nitrous oxide molecule in very large ancient air samples from a glacier in Antarctica. This method can distinguish between different microbial processes that produce nitrous oxide but it has not been applied yet to the time periods in question. The data will provide information about how natural climate changes affect nitrous oxide production. This, in turn, will be useful for predicting future changes and for understanding why the Earth\u0027s climate shifts from ice ages to warm periods and back again. Ice-core records of greenhouse gas isotopic composition are useful for determining past changes in natural source and sink strengths and for understanding how natural emissions are linked to climate change. This project will develop two records of the intramolecular site preference of Nitrogen-15 in N2O. One record spans the last deglaciation (10,000-21,000 years ago) when atmospheric N2O concentration rose by 30 percent, and the other record spans millennial-scale climate changes during the last ice age when N2O varied by smaller amounts (Heinrich Stadial 4 and Dansgaard Oeschger 8, 35,000-41,000 years ago). The records will be used to understand what changes in the nitrogen cycle caused atmospheric N2O concentration to vary and what mechanisms link the N2O emissions to climate change. Ideally, studying the two different time periods will isolate the millennial climate responses entangled with the full deglacial sequence, creating a clearer picture of how N2O biogeochemistry responds to climate change. This work will also allow exploration of an isotopic tracer for in situ production of N2O that contaminates the atmospheric signal in particularly dusty ice. The project will use a unique, well-dated suite of ice samples from Taylor Glacier, Antarctica and continuous flow isotope ratio mass spectrometry on a custom gas extraction line operated in the Oregon State University laboratory. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Taylor Glacier; Nitrous Oxide; TRACE GASES/TRACE SPECIES; Ice Core; Stable Isotopes; NITROUS OXIDE", "locations": "Taylor Glacier", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Earth Sciences", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY", "persons": "Brook, Edward", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Deciphering Changes in Atmospheric Nitrous Oxide Concentration During the Last Ice Age Using the Intramolecular Site-Preference of Nitrogen Isotopes", "uid": "p0010465", "west": -180.0}, {"awards": "1542723 Alexander, Becky", "bounds_geometry": "POINT(-112.05 -79.28)", "dataset_titles": "WAIS Divide ice core nitrate isotopes", "datasets": [{"dataset_uid": "601456", "doi": "10.15784/601456", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Chemistry; Ice Core Records; Nitrate; Nitrate Isotopes; WAIS Divide Ice Core; West Antarctic Ice Sheet", "people": "Alexander, Becky", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide ice core nitrate isotopes", "url": "https://www.usap-dc.org/view/dataset/601456"}], "date_created": "Mon, 13 Feb 2023 00:00:00 GMT", "description": "The Earth\u0027s atmosphere is a highly oxidizing medium. The abundance of oxidants such as ozone in the atmosphere strongly influences the concentrations of pollutants and greenhouse gases, with implications for human health and welfare. Because oxidants are not preserved in geological archives, knowledge of how oxidants have varied in the past under changing climate conditions is extremely limited. This award will measure a proxy for oxidant concentrations in a West Antarctic ice core over several major climate transitions over the past 50,000 years. These measurements will complement similar measurements from a Greenland ice core, which showed significant changes in atmospheric oxidants over major climate transitions covering this same time period. The addition of measurements from Antarctica will allow researchers to examine if the oxidant changes suggested by the Greenland ice core record are regional or global in scale. Knowledge of how oxidants vary naturally with climate will better inform predictions of the composition of the future atmosphere under a warming climate. This award will support measurements of the isotopic composition of nitrate in a West Antarctic ice core as a proxy for oxidant concentrations in the past atmosphere. The nitrogen isotopes of nitrate provide information on the degree of preservation of nitrate in the ice core record, and thus aid in the interpretation of the observed variability in the observed nitrate concentrations and oxygen isotopes in ice core records. By providing information about the spatial scale of oxidant changes over abrupt climate change events during the last glacial period, this project may also improve our understanding of mechanisms driving these abrupt events. Insight from this project will prove valuable for forecasting the response of stratospheric circulation to climate change, which has large implications for climate feedbacks and tropospheric composition. In addition, the information gleaned from this project on the mechanisms and feedbacks during abrupt climate change events will help determine the likelihood of such rapid events occurring in the future, which would have dramatic impacts on humankind. This award will provide training for one graduate and one undergraduate student, and will support the development of a hands-on activity related to rapid climate change to be used at the annual Polar Science Weekend at the Pacific Science Center in Seattle, WA.", "east": -112.05, "geometry": "POINT(-112.05 -79.28)", "instruments": null, "is_usap_dc": true, "keywords": "Nitrate Isotopes; ICE CORE RECORDS; WAIS Divide; LABORATORY", "locations": "WAIS Divide", "north": -79.28, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Alexander, Becky", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -79.28, "title": "Measuring an Ice-core Proxy for Relative Oxidant Abundances over Glacial-interglacial and Rapid Climate changes in a West Antarctic Ice Core", "uid": "p0010403", "west": -112.05}, {"awards": "2103032 Schmittner, Andreas", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 09 Sep 2021 00:00:00 GMT", "description": "This project investigates Antarctic ice-ocean interactions of the last 20,000 years. The Antarctic ice sheet is an important component of Earth\u2019s climate system, as it interacts with the atmosphere, the surrounding Southern Ocean, and the underlaying solid Earth. The ice sheet is also the largest potential contributor to future sea-level rise and a major uncertainty in climate projections. Climate change may trigger instabilities that may lead to fast and irreversible collapse of parts of the ice sheet. However, little is known about how interactions between the Antarctic ice sheet and the rest of the climate system affect its behavior, climate, and sea level, partly because most climate models currently do not have fully-interactive ice-sheet components. The project team will construct a numerical climate model that includes an interactive Antarctic ice sheet, improving computational infrastructure for research. The model code will be made freely available to the public on a code-sharing site. In addition, the team will synthesize paleoclimate data and compare these with model simulations. This model-data comparison will test three scientific hypotheses regarding past changes in deep-ocean circulation, ice sheet, carbon, and sea level. The project will contribute to a better understanding of ice-ocean interactions and past climate variability. The project will test ideas that ice-ocean interactions have been important for setting deep ocean circulation and carbon storage during the Last Glacial Maximum and subsequent deglaciation. The new model will consist of three existing and well-tested components: (1) an isotope-enabled climate-carbon cycle model of intermediate complexity; (2) a model of the combined Antarctic ice sheet, solid Earth, and sea level; and (3) an iceberg model. The coupling will include ocean-temperature effects on basal melting of ice shelves; freshwater fluxes from the ice sheet to the ocean; and calving, transport and melting of icebergs. Once constructed and optimized, the model will be applied to simulate the Last Glacial Maximum and subsequent deglaciation. Differences between model versions with full, partial, or no coupling will be used to investigate the effects of ice-ocean interactions on the Meridional Overturning Circulation, deep ocean carbon storage, and ice-sheet fluctuations. Paleoclimate data synthesis will include temperature, carbon and nitrogen isotopes, radiocarbon ages, protactinium-thorium ratios, neodymium isotopes, carbonate ion, dissolved oxygen, relative sea level, and terrestrial cosmogenic ages into one multi-proxy database with a consistent updated chronology. The project will support an early-career scientist, one graduate student, undergraduate students, and new and ongoing national and international collaborations. Outreach activities in collaboration with a local science museum will benefit rural communities in Oregon by improving their climate literacy. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "ICE CORE RECORDS; Amd/Us; USA/NSF; OCEAN TEMPERATURE; GLACIERS/ICE SHEETS; BIOGEOCHEMICAL CYCLES; MODELS; AMD; United States Of America; OCEAN CURRENTS; ICEBERGS; PALEOCLIMATE RECONSTRUCTIONS", "locations": "United States Of America", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Schmittner, Andreas; Haight, Andrew ; Clark, Peter", "platforms": "OTHER \u003e MODELS \u003e MODELS", "repositories": null, "science_programs": null, "south": -90.0, "title": "Investigating Antarctic Ice Sheet-Ocean-Carbon Cycle Interactions During the Last Deglaciation", "uid": "p0010256", "west": -180.0}, {"awards": "1745080 Gillikin, David; 1745057 Walker, Sally; 1745064 Perez-Huerta, Alberto", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Analysis of striae groups and interstrial increments from Adamussium colbecki valves from Explorers Cove and Bay of Sails; Annual growth of Adamussium colbecki from Explorers Cove and Bay of Sails; Linking Modern Benthic Communities and Taphonomic Processes to the Stratigraphic Record of Antarctic Cores; Nitrogen, carbon, and oxygen isotopes in the shell of the Antarctic scallop Adamussium colbecki as a proxy for sea ice cover in Antarctica.; Stable isotopes of Oxygen and Carbon in Adamissium colbecki from Explorers Cove and Bay of Sails", "datasets": [{"dataset_uid": "601469", "doi": "10.15784/601469", "keywords": "Adamussium Colbecki; Antarctica; McMurdo", "people": "Walker, Sally; Cronin, Kelly", "repository": "USAP-DC", "science_program": null, "title": "Analysis of striae groups and interstrial increments from Adamussium colbecki valves from Explorers Cove and Bay of Sails", "url": "https://www.usap-dc.org/view/dataset/601469"}, {"dataset_uid": "600077", "doi": "10.15784/600077", "keywords": "Antarctica; Biota; Glaciers/ice Sheet; Glaciers/Ice Sheet; McMurdo Sound; Oceans; Sample/collection Description; Sample/Collection Description", "people": "Walker, Sally", "repository": "USAP-DC", "science_program": null, "title": "Linking Modern Benthic Communities and Taphonomic Processes to the Stratigraphic Record of Antarctic Cores", "url": "https://www.usap-dc.org/view/dataset/600077"}, {"dataset_uid": "601761", "doi": "10.15784/601761", "keywords": "Adamussium Colbecki; Antarctica; Bay Of Sails; Carbon; Explorers Cove; McMurdo Sound; Oxygen; Stable Isotopes", "people": "Perez-Huerta, Alberto; Cronin, Kelly; Gillikin, David; Puhalski, Emma; Camarra, Steve; Andrus, Fred; Verheyden, Anouk; Bowser, Samuel S.; Walker, Sally", "repository": "USAP-DC", "science_program": null, "title": "Stable isotopes of Oxygen and Carbon in Adamissium colbecki from Explorers Cove and Bay of Sails", "url": "https://www.usap-dc.org/view/dataset/601761"}, {"dataset_uid": "601764", "doi": "10.15784/601764", "keywords": "Adamussium Colbecki; Antarctica; Biota; Carbon Isotopes; Explorers Cove; Nitrogen Isotopes; Oxygen Isotope; Scallop", "people": "Puhalski, Emma; Walker, Sally; Verheyden, Anouk; Cronin, Kelly; Camarra, Steve; Gillikin, David", "repository": "USAP-DC", "science_program": null, "title": "Nitrogen, carbon, and oxygen isotopes in the shell of the Antarctic scallop Adamussium colbecki as a proxy for sea ice cover in Antarctica.", "url": "https://www.usap-dc.org/view/dataset/601764"}, {"dataset_uid": "601468", "doi": "10.15784/601468", "keywords": "Adamussium Colbecki; Antarctica; Growth; McMurdo Sound; Shell Fish", "people": "Walker, Sally; Cronin, Kelly", "repository": "USAP-DC", "science_program": null, "title": "Annual growth of Adamussium colbecki from Explorers Cove and Bay of Sails", "url": "https://www.usap-dc.org/view/dataset/601468"}], "date_created": "Fri, 06 Aug 2021 00:00:00 GMT", "description": "The goal of this project is to discover whether the Antarctic scallop, Adamussium colbecki, provides a guide to sea-ice conditions in nearshore Antarctica today and in the past. Scallops may grow slower and live longer in habitats where sea ice persists for many years, limited by food, compared to habitats where sea ice melts out annually. Also, the chemicals retained in the shell during growth may provide crucial habitat information related to not only changing sea-ice conditions but also the type of food, whether it is recycled from the seafloor or produced by algae blooming when sea ice has melted. Unlocking the ecological imprint captured within the shell of the Antarctic Scallop will increase our understanding of changing sea-ice conditions in Antarctica. Further, because the Antarctic scallop had relatives living at the time when the Antarctic ice sheet first appeared, the scallop shell record may contain information on the stability of the ice sheet and the history of Antarctic shallow seas. Funding will also be integral for training a new generation of geoscientists in fossil and chemical forensics related to shallow sea habitats in Antarctica. Scallops are worldwide in distribution, are integral for structuring marine communities have an extensive fossil record dating to the late Devonian, and are increasingly recognized as important paleoenvironmental proxies because they are generally well preserved in the sediment and rock record. The primary goal of this project is to assess the differences in growth, lifespan, and chemistry (stable isotopes, trace elements) archived in the shell of the Antarctic scallop that may be indicative of two ice states: persistent (multiannual) sea ice at Explorers Cove (EC) and annual sea ice (that melts out every year) at Bay of Sails (BOS), western McMurdo Sound, Antarctica. This project will investigate growth and lifespan proxies (physical and geochemical) and will use high-resolution records of stable oxygen isotopes to determine if a melt-water signal is archived in A. colbecki shells and whether that signal captures the differing ice behavior at two sites (EC versus BOS). Stable isotopes of carbon and nitrogen in association with trace elements will be used to examine subannual productivity spikes indicative of phytoplankton blooms, which are predicted to be more pronounced during open ocean conditions. Small growth increments in the outer calcite layer will be assessed to determine if they represent fortnightly growth, if so, they could provide a high-resolution proxy for monthly environmental processes. Unlocking the environmental archive preserved in A. colbecki shells may prove to be an important proxy for understanding changing sea-ice conditions in Antarctica\u0027s past. Funding will support a Ph.D. student and undergraduates from multiple institutions working on independent research projects. Web content focused on Antarctic marine communities will be designed for museum outreach, reaching thousands of middle-school children each year. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Amd/Us; PALEOCLIMATE RECONSTRUCTIONS; AMD; Dry Valleys; USAP-DC; LABORATORY; USA/NSF", "locations": "Dry Valleys", "north": -60.0, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": null, "persons": "Walker, Sally; Gillikin, David; Perez-Huerta, Alberto; Andrus, Fred", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Collaborative research: The Antarctic Scallop as Key to Paleoenvironments and Sea Ice Conditions: Understanding the Modern to Predict the Past", "uid": "p0010238", "west": -180.0}, {"awards": "1744871 Robinson, Rebecca", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Diatom assemblage from IODP Site U1357; Diatom-bound and bulk sedimentary N isotopes from ODP Site 1098, Western Antarctic Peninsula; Diatom-bound and bulk sedimentary nitrogen isotopes from IODP Site U1357; Dissolved nutrients, cell counts, and nitrogen isotope measurements from Chaetoceros socialis culture experiments; ODP Site 1098 deglacial diatom assemblage; Sediment chemistry of ODP Site 1098", "datasets": [{"dataset_uid": "601818", "doi": "10.15784/601818", "keywords": "Antarctica; Cryosphere; Geochemistry; Sediment; Wilkes Land", "people": "Dove, Isabel", "repository": "USAP-DC", "science_program": null, "title": "Diatom assemblage from IODP Site U1357", "url": "https://www.usap-dc.org/view/dataset/601818"}, {"dataset_uid": "601816", "doi": "10.15784/601816", "keywords": "Antarctica; Antarctic Peninsula; Cryosphere; Geochemistry; Sediment", "people": "Jones, Colin; Kelly, Roger; Robinson, Rebecca; Dove, Isabel", "repository": "USAP-DC", "science_program": null, "title": "Diatom-bound and bulk sedimentary N isotopes from ODP Site 1098, Western Antarctic Peninsula", "url": "https://www.usap-dc.org/view/dataset/601816"}, {"dataset_uid": "601778", "doi": "10.15784/601778", "keywords": "Antarctica; Antarctic Peninsula; Cryosphere", "people": "Dove, Isabel", "repository": "USAP-DC", "science_program": null, "title": "Sediment chemistry of ODP Site 1098", "url": "https://www.usap-dc.org/view/dataset/601778"}, {"dataset_uid": "601817", "doi": "10.15784/601817", "keywords": "Antarctica; Cryosphere; Wilkes Land", "people": "Dove, Isabel; Kelly, Roger; Robinson, Rebecca", "repository": "USAP-DC", "science_program": null, "title": "Diatom-bound and bulk sedimentary nitrogen isotopes from IODP Site U1357", "url": "https://www.usap-dc.org/view/dataset/601817"}, {"dataset_uid": "601777", "doi": "10.15784/601777", "keywords": "Antarctica; Antarctic Peninsula; Cryosphere; Sediment Core Data", "people": "Dove, Isabel", "repository": "USAP-DC", "science_program": null, "title": "ODP Site 1098 deglacial diatom assemblage", "url": "https://www.usap-dc.org/view/dataset/601777"}, {"dataset_uid": "601727", "doi": "10.15784/601727", "keywords": "Antarctica", "people": "Dove, Isabel", "repository": "USAP-DC", "science_program": null, "title": "Dissolved nutrients, cell counts, and nitrogen isotope measurements from Chaetoceros socialis culture experiments", "url": "https://www.usap-dc.org/view/dataset/601727"}], "date_created": "Wed, 28 Jul 2021 00:00:00 GMT", "description": "The chemical composition of diatom fossils in the Southern Ocean provides information about the environmental history of Antarctica, including sea ice extent, biological production, and ocean nutrient distribution. The sea ice zone is an important habitat for a group of diatoms, largely from the genus Chaetoceros, that have a unique life cycle stage under environmental stress, when they produce a structure called a resting spore. Resting spores are meant to reseed the surface ocean when conditions are more favorable. The production of these heavy resting spores tends to remove significant amounts of carbon and silicon, essential nutrients, out of the surface ocean. As a result, this group has the potential to remove carbon from the surface ocean and can impact the sedimentary record scientists use to reconstruct environmental change. This project explores the role of resting spores in the sedimentary record using the nitrogen isotopic signature of these fossils and how those measurements are used to estimate carbon cycle changes. The work will include laboratory incubations of these organisms to answer if and how the chemistry of the resting spores differs from that of a typical diatom cell. The incubation results will be used to evaluate nutrient drawdown in sea ice environments during two contrasting intervals in earth history, the last ice age and the warm Pliocene. This work should have significant impact on how the scientific community considers the impact of seasonal sea ice cover in the Southern Ocean in terms of how it responds to and regulates global climate. The project provides training and research opportunities for undergraduate and graduate students. Ongoing research efforts in Antarctic earth sciences will be disseminated through an interactive display at the home institution. The work proposed here will address uncertainties in how Chaetoceros resting spores record surface nutrient conditions in their nitrogen stable isotopic composition, the relative impact of their specific signal with respect to the full sedimentary assemblage, and their potential to bias or enhance environmental reconstructions in the sea ice zone. Measurements of nitrogen stable isotopes of nitrate, biomass, and diatom-bound nitrogen and silicon-to-nitrogen ratios of individual species grown in the laboratory will be used to quantify how resting spores record nutrient drawdown in the water column and to what degree their signature is biased toward low nutrient conditions. These relationships will be used to inform diatom-bound nitrogen isotope reconstructions of nutrient drawdown from a Pliocene coastal polyna and an open ocean core that spans the last glacial maximum. This proposal capitalizes on the availability of Southern Ocean isolates of Chaetoceros spp. collected in 2017 for the proposed culture work and archived sediment cores and/or existing data. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Amd/Us; USAP-DC; Antarctica; ISOTOPES; MARINE SEDIMENTS; LABORATORY; USA/NSF; NITROGEN; AMD", "locations": "Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Robinson, Rebecca", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "The nitrogen isotopic composition of diatom resting spores in Southern Ocean sediments: A source of bias and/or paleoenvironmental information?", "uid": "p0010234", "west": -180.0}, {"awards": "1542962 Anderson, Robert", "bounds_geometry": "POLYGON((-171 -57,-170.8 -57,-170.6 -57,-170.4 -57,-170.2 -57,-170 -57,-169.8 -57,-169.6 -57,-169.4 -57,-169.2 -57,-169 -57,-169 -57.72,-169 -58.44,-169 -59.16,-169 -59.88,-169 -60.6,-169 -61.32,-169 -62.04,-169 -62.76,-169 -63.48,-169 -64.2,-169.2 -64.2,-169.4 -64.2,-169.6 -64.2,-169.8 -64.2,-170 -64.2,-170.2 -64.2,-170.4 -64.2,-170.6 -64.2,-170.8 -64.2,-171 -64.2,-171 -63.48,-171 -62.76,-171 -62.04,-171 -61.32,-171 -60.6,-171 -59.88,-171 -59.16,-171 -58.44,-171 -57.72,-171 -57))", "dataset_titles": "Expedition Data of NBP1702; Water Mass Structure and Bottom Water Formation in the Ice-age Southern Ocean ; Water Mass Structure and Bottom Water Formation in the Ice-age Southern Ocean (SNOWBIRDS)", "datasets": [{"dataset_uid": "200166", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Water Mass Structure and Bottom Water Formation in the Ice-age Southern Ocean ", "url": "https://www.ncdc.noaa.gov/paleo/study/31312"}, {"dataset_uid": "200165", "doi": "", "keywords": null, "people": null, "repository": "BCO-DMO", "science_program": null, "title": "Water Mass Structure and Bottom Water Formation in the Ice-age Southern Ocean (SNOWBIRDS)", "url": "https://www.bco-dmo.org/dataset/813379/data"}, {"dataset_uid": "200126", "doi": "10.7284/907211", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data of NBP1702", "url": "https://www.rvdata.us/search/cruise/NBP1702"}], "date_created": "Fri, 25 Sep 2020 00:00:00 GMT", "description": "Scientists established more than 30 years ago that the climate-related variability of carbon dioxide levels in the atmosphere over Earth\u0027s ice-age cycles was regulated by the ocean. Hypotheses to explain how the ocean regulates atmospheric carbon dioxide have long been debated, but they have proven to be difficult to test. Work proposed here will test one leading hypothesis, specifically that the ocean experienced greater density stratification during the ice ages. That is, with greater stratification during the ice ages and slower replacement of deep water by cold dense water formed near the poles, the deep ocean would have held more carbon dioxide, which is produced by biological respiration of the organic carbon that constantly rains to the abyss in the form of dead organisms and organic debris that sink from the sunlit surface ocean. To test this hypothesis, the degree of ocean stratification during the last ice age and the rate of deep-water replacement will be constrained by comparing the radiocarbon ages of organisms that grew in the surface ocean and at the sea floor within a critical region around Antarctica, where most of the replacement of deep waters occurs. Completing this work will contribute toward improved models of future climate change. Climate scientists rely on models to estimate the amount of fossil fuel carbon dioxide that will be absorbed by the ocean in the future. Currently the ocean absorbs about 25% of the carbon dioxide produced by burning fossil fuels. Most of this carbon is absorbed in the Southern Ocean (the region around Antarctica). How this will change in the future is poorly known. Models have difficulty representing physical conditions in the Southern Ocean accurately, thereby adding substantial uncertainty to projections of future ocean uptake of carbon dioxide. Results of the proposed study will provide a benchmark to test the ability of models to simulate ocean processes under climate conditions distinctly different from those that occur today, ultimately leading to improvement of the models and to more reliable projections of future absorption of carbon dioxide by the ocean. The proposed work will add a research component to an existing scientific expedition to the Southern Ocean, in the region between the Ross Sea and New Zealand, that will collect sediment cores at three to five locations down the northern flank of the Pacific-Antarctic Ridge at approximately 170\u00b0W. The goal is to collect sediments at each location deposited since early in the peak of the last ice age. This region is unusual in the Southern Ocean in that sediments deposited during the last ice age contain foraminifera, tiny organisms with calcium carbonate shells, in much greater abundance than in other regions of the Southern Ocean. Foraminifera are widely used as an archive of several geochemical tracers of past ocean conditions. In the proposed work the radiocarbon age of foraminifera that inhabited the surface ocean will be compared with the age of contemporary specimens that grew on the seabed. The difference in age between surface and deep-swelling organisms will be used to discriminate between two proposed mechanisms of deep water renewal during the ice age: formation in coastal polynyas around the edge of Antarctica, much as occurs today, versus formation by open-ocean convection in deep-water regions far from the continent. If the latter mechanism prevails, then it is expected that surface and deep-dwelling foraminifera will exhibit similar radiocarbon ages. In the case of dominance of deep-water formation in coastal polynyas, one expects to find very different radiocarbon ages in the two populations of foraminifera. In the extreme case of greater ocean stratification during the last ice age, one even expects the surface dwellers to appear to be older than contemporary bottom dwellers because the targeted core sites lie directly under the region where the oldest deep waters return to the surface following their long circuitous transit through the deep ocean. The primary objective of the proposed work is to reconstruct the water mass age structure of the Southern Ocean during the last ice age, which, in turn, is a primary factor that controls the amount of carbon dioxide stored in the deep sea. In addition, the presence of foraminifera in the cores to be recovered provides a valuable resource for many other paleoceanographic applications, such as: 1) the application of nitrogen isotopes to constrain the level of nutrient utilization in the Southern Ocean and, thus, the efficiency of the ocean?s biological pump, 2) the application of neodymium isotopes to constrain the transport history of deep water masses, 3) the application of boron isotopes and boron/calcium ratios to constrain the pH and inorganic carbon system parameters of ice-age seawater, and 4) the exploitation of metal/calcium ratios in foraminifera to reconstruct the temperature (Mg/Ca) and nutrient content (Cd/Ca) of deep waters during the last ice age at a location near their source near Antarcitca.", "east": -169.0, "geometry": "POINT(-170 -60.6)", "instruments": null, "is_usap_dc": true, "keywords": "BIOGEOCHEMICAL CYCLES; SEDIMENT CHEMISTRY; South Pacific Ocean; SHIPS", "locations": "South Pacific Ocean", "north": -57.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Anderson, Robert; Fleisher, Martin; Pavia, Frank", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e SHIPS", "repo": "NCEI", "repositories": "BCO-DMO; NCEI; R2R", "science_programs": null, "south": -64.2, "title": "Water Mass Structure and Bottom Water Formation in the Ice-age Southern Ocean", "uid": "p0010130", "west": -171.0}, {"awards": "1744602 Iken, Katrin; 1744570 Galloway, Aaron; 1744584 Klein, Andrew; 1744550 Amsler, Charles", "bounds_geometry": "POLYGON((-70 -61,-69 -61,-68 -61,-67 -61,-66 -61,-65 -61,-64 -61,-63 -61,-62 -61,-61 -61,-60 -61,-60 -61.772,-60 -62.544,-60 -63.316,-60 -64.088,-60 -64.86,-60 -65.632,-60 -66.404,-60 -67.176,-60 -67.948,-60 -68.72,-61 -68.72,-62 -68.72,-63 -68.72,-64 -68.72,-65 -68.72,-66 -68.72,-67 -68.72,-68 -68.72,-69 -68.72,-70 -68.72,-70 -67.948,-70 -67.176,-70 -66.404,-70 -65.632,-70 -64.86,-70 -64.088,-70 -63.316,-70 -62.544,-70 -61.772,-70 -61))", "dataset_titles": "Average global horizontal solar irradiance at study sites; Carbon and nitrogen isotope data along a gradient at the Antarctic Peninsula; Chemical composition data for Desmarestia menziesii; Chemical composition data for Himantothallus grandifolius; Chemical composition data for Iridaea ; Chemical composition data for Sarcopeltis antarctica ; Computed fetch for project study sites; Five year mean annual and summer sea ice concentration grids for the Western Antarctic Peninsula from AMSR2, National Ice Center Charts and the Sea Ice Index ; Gridded sea ice concentrations from National Ice Center (NIC) Charts 2014-2019 for Western Antarctic Peninsula ; Initial release of code and data associated with Whippo et al. (2024) Fatty acid profiles and stable isotope composition of Antarctic macroalgae: A baseline for a combined biomarker approach in food web studies.; Landsat Sea Ice/Cloud classifications surrounding project study sites; Latitude and longitude data for project study sites; LMG1904 expedition data; Macroalgal species collected along horizontal transect components ; Modelled Solar Irradiance for Western Antarctic Pennisula; Sea Ice Concentration Timeseries for study sites; Underwater transect videos used for community analyses; Underwater video transect community analysis data; VIIRS KD(490) diffuse attenuation coefficients for study sites", "datasets": [{"dataset_uid": "601653", "doi": "10.15784/601653", "keywords": "Antarctica; Antarctic Peninsula; Biota; Carbon; Carbon Isotopes; LMG1904; Nitrogen Isotopes; Oceans", "people": "Iken, Katrin", "repository": "USAP-DC", "science_program": null, "title": "Carbon and nitrogen isotope data along a gradient at the Antarctic Peninsula", "url": "https://www.usap-dc.org/view/dataset/601653"}, {"dataset_uid": "601654", "doi": "10.15784/601654", "keywords": "Antarctica; Antarctic Peninsula; GIS; LANDSAT; LMG1904; Remote Sensing; R/v Laurence M. Gould", "people": "Klein, Andrew", "repository": "USAP-DC", "science_program": null, "title": "Landsat Sea Ice/Cloud classifications surrounding project study sites", "url": "https://www.usap-dc.org/view/dataset/601654"}, {"dataset_uid": "601885", "doi": "10.15784/601885", "keywords": "Antarctica; Antarctic Peninsula; Cryosphere; Macroalgae", "people": "Amsler, Charles", "repository": "USAP-DC", "science_program": null, "title": "Chemical composition data for Sarcopeltis antarctica ", "url": "https://www.usap-dc.org/view/dataset/601885"}, {"dataset_uid": "601725", "doi": "10.15784/601725", "keywords": "Antarctica; Antarctic Peninsula", "people": "Amsler, Charles", "repository": "USAP-DC", "science_program": null, "title": "Macroalgal species collected along horizontal transect components ", "url": "https://www.usap-dc.org/view/dataset/601725"}, {"dataset_uid": "200402", "doi": "10.5281/zenodo.10524919", "keywords": null, "people": null, "repository": "Zendo", "science_program": null, "title": "Initial release of code and data associated with Whippo et al. (2024) Fatty acid profiles and stable isotope composition of Antarctic macroalgae: A baseline for a combined biomarker approach in food web studies.", "url": "https://zenodo.org/records/10524920"}, {"dataset_uid": "601610", "doi": "10.15784/601610", "keywords": "Antarctica; Antarctic Peninsula; Benthic Communities; Biota; Macroalgae; Macroinvertebrates; Oceans; Video Transects", "people": "Amsler, Charles", "repository": "USAP-DC", "science_program": null, "title": "Underwater transect videos used for community analyses", "url": "https://www.usap-dc.org/view/dataset/601610"}, {"dataset_uid": "601619", "doi": "10.15784/601619", "keywords": "Antarctica; Antarctic Peninsula; Benthic Communities; Biota; Macroalgae; Macroinvertebrates; Oceans; Video Transects", "people": "Amsler, Charles", "repository": "USAP-DC", "science_program": null, "title": "Underwater video transect community analysis data", "url": "https://www.usap-dc.org/view/dataset/601619"}, {"dataset_uid": "601639", "doi": "10.15784/601639", "keywords": "Antarctica; Antarctic Peninsula; Biota; Fetch; LMG1904; R/v Laurence M. Gould", "people": "Klein, Andrew", "repository": "USAP-DC", "science_program": null, "title": "Computed fetch for project study sites", "url": "https://www.usap-dc.org/view/dataset/601639"}, {"dataset_uid": "601884", "doi": "10.15784/601884", "keywords": "Antarctica; Antarctic Peninsula; Cryosphere; Macroalgae", "people": "Amsler, Charles", "repository": "USAP-DC", "science_program": null, "title": "Chemical composition data for Iridaea ", "url": "https://www.usap-dc.org/view/dataset/601884"}, {"dataset_uid": "601883", "doi": "10.15784/601883", "keywords": "Antarctica; Antarctic Peninsula; Cryosphere; Macroalgae", "people": "Amsler, Charles", "repository": "USAP-DC", "science_program": null, "title": "Chemical composition data for Himantothallus grandifolius", "url": "https://www.usap-dc.org/view/dataset/601883"}, {"dataset_uid": "601640", "doi": "10.15784/601640", "keywords": "Antarctica; Biota; Diffuse Attenuation Coefficient; LMG1904; R/v Laurence M. Gould; Turbidity", "people": "Klein, Andrew", "repository": "USAP-DC", "science_program": null, "title": "VIIRS KD(490) diffuse attenuation coefficients for study sites", "url": "https://www.usap-dc.org/view/dataset/601640"}, {"dataset_uid": "601641", "doi": "10.15784/601641", "keywords": "Antarctica; Average Global Horizontal Solar Irradiance; Biota; LMG1904; R/v Laurence M. Gould", "people": "Klein, Andrew", "repository": "USAP-DC", "science_program": null, "title": "Average global horizontal solar irradiance at study sites", "url": "https://www.usap-dc.org/view/dataset/601641"}, {"dataset_uid": "601642", "doi": "10.15784/601642", "keywords": "Antarctica; Antarctic Peninsula; Biota; LMG1904; R/v Laurence M. Gould; Sea Ice Concentration", "people": "Klein, Andrew", "repository": "USAP-DC", "science_program": null, "title": "Sea Ice Concentration Timeseries for study sites", "url": "https://www.usap-dc.org/view/dataset/601642"}, {"dataset_uid": "601643", "doi": "10.15784/601643", "keywords": "Antarctica; Antarctic Peninsula; LMG1904; National Ice Center Charts; R/v Laurence M. Gould; Sea Ice Concentration", "people": "Klein, Andrew", "repository": "USAP-DC", "science_program": null, "title": "Gridded sea ice concentrations from National Ice Center (NIC) Charts 2014-2019 for Western Antarctic Peninsula ", "url": "https://www.usap-dc.org/view/dataset/601643"}, {"dataset_uid": "601649", "doi": "10.15784/601649", "keywords": "Antarctica; Antarctic Peninsula; LMG1904; National Ice Center Charts; Sea Ice Concentration", "people": "Klein, Andrew", "repository": "USAP-DC", "science_program": null, "title": "Five year mean annual and summer sea ice concentration grids for the Western Antarctic Peninsula from AMSR2, National Ice Center Charts and the Sea Ice Index ", "url": "https://www.usap-dc.org/view/dataset/601649"}, {"dataset_uid": "601651", "doi": "10.15784/601651", "keywords": "Antarctica; Antarctic Peninsula; Biota; GIS; GIS Data; LMG1904; R/v Laurence M. Gould; Solar Radiation", "people": "Klein, Andrew", "repository": "USAP-DC", "science_program": null, "title": "Modelled Solar Irradiance for Western Antarctic Pennisula", "url": "https://www.usap-dc.org/view/dataset/601651"}, {"dataset_uid": "200147", "doi": "10.7284/908260", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "LMG1904 expedition data", "url": "https://www.rvdata.us/search/cruise/LMG1904"}, {"dataset_uid": "601882", "doi": "10.15784/601882", "keywords": "Antarctica; Antarctic Peninsula; Cryosphere; Macroalgae", "people": "Amsler, Charles", "repository": "USAP-DC", "science_program": null, "title": "Chemical composition data for Desmarestia menziesii", "url": "https://www.usap-dc.org/view/dataset/601882"}, {"dataset_uid": "601330", "doi": "10.15784/601330", "keywords": "Antarctica; Antarctic Peninsula; Biota; LMG1904; R/v Laurence M. Gould; Sample Location", "people": "Amsler, Charles", "repository": "USAP-DC", "science_program": null, "title": "Latitude and longitude data for project study sites", "url": "https://www.usap-dc.org/view/dataset/601330"}], "date_created": "Thu, 04 Jun 2020 00:00:00 GMT", "description": "The western Antarctic Peninsula has become a model for understanding cold water communities and how they may be changing in Antarctica and elsewhere. Brown macroalgae (seaweeds) form extensive undersea forests in the northern portion of this region where they play a key role in providing both physical structure and a food (carbon) source for shallow water communities. Yet between Anvers Island (64 degrees S latitude) and Adelaide Island (67 S latitude) these macroalgae become markedly less abundant and diverse. This is probably because the habitat to the south is covered by more sea ice for a longer period, and the sea ice reduces the amount of light that reaches the algae. The reduced macroalgal cover undoubtedly impacts other organisms in the food web, but the ways in which it alters sea-floor community processes and organization is unknown. This project will quantitatively document the macroalgal communities at multiple sites between Anvers and Adelaide Islands using a combination of SCUBA diving, video surveys, and algal collections. Sea ice cover, light levels, and other environmental parameters on community structure will be modelled to determine which factors have the largest influence. Impacts on community structure, food webs, and carbon flow will be assessed through a mixture of SCUBA diving and video surveys. Broader impacts include the training of graduate students and a postdoctoral researcher, as well as numerous informal public education activities including lectures, presentations to K-12 groups, and a variety of social media-based outreach. Macroalgal communities are more abundance and diverse to the north along the Western Antarctic Peninsula, perhaps due to the greater light availability that is associated with shorter period of sea-ice cover. This project will determine the causes and community level consequence of this variation in algal community structure. First, satellite data on sea ice extent and water turbidity will be used to select study sites between 64 S and 69 S where the extent of annual sea ice cover is the primary factor influencing subsurface light levels. Then, variations in macroalgal cover across these study sites will be determined by video line-transect surveys conducted by SCUBA divers. The health, growth, and physiological status of species found at the different sites will be determined by quadrat sampling. The relative importance of macroalgal-derived carbon to the common invertebrate consumers in the foodweb will be assessed with stable isotope and fatty acid biomarker techniques. This will reveal how variation in macroalgal abundance and species composition across the sea ice cover gradient impacts sea floor community composition and carbon flow throughout the food web. In combination, this work will facilitate predictions of how the ongoing reductions in extent and duration of sea ice cover that is occurring in the region as a result of global climate change will impact the structure of nearshore benthic communities. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": -60.0, "geometry": "POINT(-65 -64.86)", "instruments": null, "is_usap_dc": true, "keywords": "COASTAL; R/V LMG; MACROALGAE (SEAWEEDS); BENTHIC; USAP-DC; Antarctic Peninsula", "locations": "Antarctic Peninsula", "north": -61.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Amsler, Charles; McClintock, James; Iken, Katrin; Galloway, Aaron; Klein, Andrew", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V LMG", "repo": "USAP-DC", "repositories": "R2R; USAP-DC; Zendo", "science_programs": null, "south": -68.72, "title": "Collaborative Research: Sea ice as a driver of Antarctic benthic macroalgal community composition and nearshore trophic connectivity", "uid": "p0010104", "west": -70.0}, {"awards": "1341464 Robinson, Rebecca; 1341432 Brzezinski, Mark", "bounds_geometry": "POLYGON((-175 -54,-174 -54,-173 -54,-172 -54,-171 -54,-170 -54,-169 -54,-168 -54,-167 -54,-166 -54,-165 -54,-165 -55.3,-165 -56.6,-165 -57.9,-165 -59.2,-165 -60.5,-165 -61.8,-165 -63.1,-165 -64.4,-165 -65.7,-165 -67,-166 -67,-167 -67,-168 -67,-169 -67,-170 -67,-171 -67,-172 -67,-173 -67,-174 -67,-175 -67,-175 -65.7,-175 -64.4,-175 -63.1,-175 -61.8,-175 -60.5,-175 -59.2,-175 -57.9,-175 -56.6,-175 -55.3,-175 -54))", "dataset_titles": "Diatom assemblage counts from NBP17-02 shipboard carboy experiments; Dissolved nutrient profiles from along 170\u00b0W between 67 and 54\u00b0S; Expedition Data of NBP1702; Particle composition measurements from along 170\u00b0W between 67-54\u00b0S; Particulate silicon and nitrogen concentrations and isotopic composition measurements in McLane pump profiles from 67\u00b0S to 55\u00b0S latitude in the Pacific Sector of the Southern Ocean; Silicon concentration and isotopic composition measurements in pore waters and sediments from 67\u00b0S to 55\u00b0S latitude in the Pacific Sector of the Southern Ocean; Surface Southern Ocean community growouts to evaluate the diatom bound N isotope proxy", "datasets": [{"dataset_uid": "601562", "doi": "10.15784/601562", "keywords": "Antarctica; Biogenic Silica; Chemistry:sediment; Chemistry:Sediment; Lithogenic Silica; Marine Geoscience; NBP1702; Pore Water Biogeochemistry; Sediment; Silicon Cycle; Silicon Stable Isotope; Southern Ocean", "people": "Closset, Ivia; Jones, Janice L.; Brzezinski, Mark", "repository": "USAP-DC", "science_program": null, "title": "Silicon concentration and isotopic composition measurements in pore waters and sediments from 67\u00b0S to 55\u00b0S latitude in the Pacific Sector of the Southern Ocean", "url": "https://www.usap-dc.org/view/dataset/601562"}, {"dataset_uid": "601269", "doi": "10.15784/601269", "keywords": "Antarctica; Chlorophyll; Southern Ocean", "people": "Brzezinski, Mark; Robinson, Rebecca", "repository": "USAP-DC", "science_program": null, "title": "Dissolved nutrient profiles from along 170\u00b0W between 67 and 54\u00b0S", "url": "https://www.usap-dc.org/view/dataset/601269"}, {"dataset_uid": "200126", "doi": "10.7284/907211", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data of NBP1702", "url": "https://www.rvdata.us/search/cruise/NBP1702"}, {"dataset_uid": "601522", "doi": "10.15784/601522", "keywords": "Antarctica; Nitrogen Isotopes; Oceans; Paleoproxies; Southern Ocean", "people": "Robinson, Rebecca ; Jones, Colin; Robinson, Rebecca; Brzezinski, Mark; Riesselman, Christina; Closset, Ivia; Kelly, Roger", "repository": "USAP-DC", "science_program": null, "title": "Surface Southern Ocean community growouts to evaluate the diatom bound N isotope proxy", "url": "https://www.usap-dc.org/view/dataset/601522"}, {"dataset_uid": "601576", "doi": "10.15784/601576", "keywords": "Antarctica; Biogenic Silica; Chemistry:sediment; Chemistry:Sediment; Diatom; Diatom Bound; Lithogenic Silica; Marine Geoscience; NBP1702; Nitrogen Isotopes; Silicon Cycle; Silicon Stable Isotope; Southern Ocean", "people": "Jones, Janice L.; Brzezinski, Mark; Robinson, Rebecca; Closset, Ivia", "repository": "USAP-DC", "science_program": null, "title": " Particulate silicon and nitrogen concentrations and isotopic composition measurements in McLane pump profiles from 67\u00b0S to 55\u00b0S latitude in the Pacific Sector of the Southern Ocean", "url": "https://www.usap-dc.org/view/dataset/601576"}, {"dataset_uid": "601523", "doi": "10.15784/601523", "keywords": "Antarctica; Biota; Carboy Growouts; Diatom; Diatom Assemblage Data; NBP1702; Oceans; R/v Nathaniel B. Palmer; Southern Ocean; Southern Ocean Summer", "people": "Jones, Colin; Robinson, Rebecca ; Riesselman, Christina; Robinson, Rebecca", "repository": "USAP-DC", "science_program": null, "title": "Diatom assemblage counts from NBP17-02 shipboard carboy experiments", "url": "https://www.usap-dc.org/view/dataset/601523"}, {"dataset_uid": "601276", "doi": "10.15784/601276", "keywords": "Antarctica; Biogenic Silica; Nitrogen Isotopes; Southern Ocean", "people": "Robinson, Rebecca; Brzezinski, Mark", "repository": "USAP-DC", "science_program": null, "title": "Particle composition measurements from along 170\u00b0W between 67-54\u00b0S", "url": "https://www.usap-dc.org/view/dataset/601276"}], "date_created": "Wed, 26 Feb 2020 00:00:00 GMT", "description": "Collaborative Proposal: A field and laboratory examination of the diatom N and Si isotope proxies: Implications for assessing the Southern Ocean biological pump The rise in atmospheric carbon dioxide concentrations and associated climate changes make understanding the role of the ocean in large scale carbon cycle a priority. Geologic samples allow exploration of potential mechanisms for carbon dioxide drawdown during glacial periods through the use of geochemical proxies. Nitrogen and silicon isotope signatures from fossil diatoms (microscopic plants) are used to investigate changes in the physical supply and biological demand for nutrients (like nitrogen and silicon and carbon) in the Southern Ocean. The project will evaluate the use the nitrogen and silicon isotope proxies through a series of laboratory experiments and Southern Ocean field sampling. The results will provide quantification of real relationships between nitrogen and silicon isotopes and nutrient usage in the Southern Ocean and allow exploration of the role of other factors, including biological diversity, ice cover, and mixing, in altering the chemical signatures recorded by diatoms. Seafloor sediment samples will be used to evaluate how well the signal created in the water column is recorded by fossil diatoms buried in the seafloor. Improving the nutrient isotope proxies will allow for a more quantitative understanding of the role of polar biology in regulating natural variation in atmospheric carbon dioxide. The project will also result in the training of a graduate student and development of outreach materials targeting a broad popular audience. This project seeks to test the fidelity of the diatom nitrogen and silicon isotope proxies, two commonly used paleoceanographic tools for investigating the role of the Southern Ocean biological pump in regulating atmospheric CO2 concentrations on glacial-interglacial timescales. Existing ground-truthing data, including culture experiments, surface sediment data and downcore reconstructions, all suggest that nutrient utilization is the primary driver of isotopic variation in the Southern Ocean. However, strong contribution of interspecific variation is implied by recent culture results. Moreover, field and laboratory studies present some contradictory results in terms of the relative importance of interspecific variation and of inferred post-depositional alteration of the nutrient isotope signals. Here, a first order test of the N and Si diatom nutrient isotope paleo-proxies, involving water column dissolved and particulate sampling and laboratory culturing of field-isolates, is proposed. Southern Ocean water, biomass, live diatoms and fossil diatom sampling will be conducted to investigate species and assemblage related variability in diatom nitrogen and silicon isotopes and their relationship to surface nutrient fields and early diagenesis. Access to fresh materials produced in an analogous environmental context to the sediments of primary interest is critical for making robust paleoceanographic reconstructions. Field sampling will occur along 175\u00b0W, transecting the Antarctic Circumpolar Current from the subtropics to the marginal ice edge. Collection of water, sinking/suspended particles and multi-core samples from 13 stations and 3 shipboard incubation experiments will be used to test four proposed hypotheses that together evaluate the significance of existing culture results and seek to allow the best use of diatom nutrient isotope proxies in evaluating the biological pump.", "east": -165.0, "geometry": "POINT(-170 -60.5)", "instruments": null, "is_usap_dc": true, "keywords": "Southern Ocean; AMD; NITROGEN ISOTOPES; R/V NBP; NSF/USA; NUTRIENTS; USAP-DC; Amd/Us", "locations": "Southern Ocean", "north": -54.0, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": null, "persons": "Robinson, Rebecca; Brzezinski, Mark", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "USAP-DC", "repositories": "R2R; USAP-DC", "science_programs": null, "south": -67.0, "title": "Collaborative Proposal: A Field and Laboratory Examination of the Diatom N and Si Isotope Proxies: Implications for Assessing the Southern Ocean Biological Pump", "uid": "p0010083", "west": -175.0}, {"awards": "1443663 Cole-Dai, Jihong; 1443336 Osterberg, Erich; 1443397 Kreutz, Karl", "bounds_geometry": "POINT(-180 -90)", "dataset_titles": "Preliminary SPC14 high-resolution Fe and Mn biologically relevant and dissolved trace metal concentrations spanning -42 \u2013 54,300 years BP.; South Pole Ice Core Holocene Major Ion Dataset; South Pole Ice Core Sea Salt and Major Ions; South Pole ice core (SPC14) discrete methane data; South Pole (SPC14) microparticle concentration, mass concentration, flux, particle-size-distribution mode, and aspect ratio measurements; SPICEcore 400-480 m Major Ions SDSU; The South Pole Ice Core (SPICEcore) chronology and supporting data", "datasets": [{"dataset_uid": "601675", "doi": "10.15784/601675", "keywords": "Antarctica; South Pole; SPICEcore", "people": "Kreutz, Karl", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Preliminary SPC14 high-resolution Fe and Mn biologically relevant and dissolved trace metal concentrations spanning -42 \u2013 54,300 years BP.", "url": "https://www.usap-dc.org/view/dataset/601675"}, {"dataset_uid": "601851", "doi": "10.15784/601851", "keywords": "Antarctica; Cryosphere; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Sea Salt and Major Ions", "url": "https://www.usap-dc.org/view/dataset/601851"}, {"dataset_uid": "601850", "doi": "10.15784/601850", "keywords": "Antarctica; Cryosphere; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Holocene Major Ion Dataset", "url": "https://www.usap-dc.org/view/dataset/601850"}, {"dataset_uid": "601206", "doi": "10.15784/601206", "keywords": "Antarctica; Calcium (ca); Chemistry:ice; Chemistry:Ice; Depth; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciochemistry; Glaciology; Ice; Ice Core; Ice Core Chemistry; Ice Core Data; Ice Core Records; Ice Core Stratigraphy; Nitrate; Nitrogen Isotopes; Paleoclimate; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Osterberg, Erich; Iverson, Nels; Aydin, Murat; Severinghaus, Jeffrey P.; Ferris, David G.; Kahle, Emma; Morris, Valerie; Steig, Eric J.; Sowers, Todd A.; Beaudette, Ross; Brook, Edward J.; Ortman, Nikolas; Epifanio, Jenna; Kreutz, Karl; Cox, Thomas S.; Thundercloud, Zayta; Cole-Dai, Jihong; Fegyveresi, John; McConnell, Joseph; Sigl, Michael; Souney, Joseph Jr.; Bay, Ryan; Buizert, Christo; Dunbar, Nelia; Fudge, T. J.; Winski, Dominic A.; Nicewonger, Melinda R.; Waddington, Edwin D.; Jones, Tyler R.; Alley, Richard; Casey, Kimberly A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "The South Pole Ice Core (SPICEcore) chronology and supporting data", "url": "https://www.usap-dc.org/view/dataset/601206"}, {"dataset_uid": "601430", "doi": "10.15784/601430", "keywords": "Antarctica; Ions; South Pole; SPICEcore", "people": "Larrick, Carleigh; Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPICEcore 400-480 m Major Ions SDSU", "url": "https://www.usap-dc.org/view/dataset/601430"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kennedy, Joshua A.; Sowers, Todd A.; Osterberg, Erich; Hood, Ekaterina; Kalk, Michael; Ferris, David G.; Winski, Dominic A.; Fudge, T. J.; Edwards, Jon S.; Epifanio, Jenna; Severinghaus, Jeffrey P.; Steig, Eric J.; Kahle, Emma; Brook, Edward J.; Kreutz, Karl; Aydin, Murat; Buizert, Christo", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601553", "doi": "10.15784/601553", "keywords": "Antarctica; Dust; Ice Core; South Pole", "people": "Kreutz, Karl", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPC14) microparticle concentration, mass concentration, flux, particle-size-distribution mode, and aspect ratio measurements", "url": "https://www.usap-dc.org/view/dataset/601553"}], "date_created": "Thu, 29 Aug 2019 00:00:00 GMT", "description": "This collaborative project explores the signatures and causes of natural climate change in the region surrounding Antarctica over the last 40,000 years as the Earth transitioned from an ice age into the modern warm period. The researchers will investigate how the wind belts that surround Antarctica changed in their strength and position through time, and document explosive volcanic eruptions and CO2 cycling in the Southern Ocean as potential climate forcing mechanisms over this interval. Understanding how and why the climate varied naturally in the past is critical for improving understanding of modern climate change and projections of future climate under higher levels of atmospheric CO2. The investigators plan to conduct a suite of chemical measurements along the 1500m length of the South Pole Ice Core, including major ion and trace element concentrations, and microparticle (dust) concentrations and size distributions. These measurements will (1) extend the South Pole record of explosive volcanic eruptions to 40,000 years using sulfate and particle data; (2) establish the relative timing of climate changes in dust source regions of Patagonia, New Zealand, and Australia using dust flux data; (3) investigate changes in the strength and position of the westerly wind belt using dust size distribution data; and (4) quantify the flux of bioavailable trace metals deposited as dust to the Southern Ocean over time. These chemistry records will also be critical for creating the timescale that will be used by all researchers studying records from the South Pole core. The project will support four graduate students and several undergraduate students across three different institutions, and become a focus of the investigators\u0027 efforts to disseminate outcomes of climate change science to the broader community.", "east": -180.0, "geometry": "POINT(-180 -90)", "instruments": null, "is_usap_dc": true, "keywords": "Antarctica; ICE CORE RECORDS; USAP-DC; Amd/Us; USA/NSF; LABORATORY; AMD", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Osterberg, Erich", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: South Pole Ice Core Chronology and Climate Records using Chemical and Microparticle Measurements", "uid": "p0010051", "west": -180.0}, {"awards": "1443585 Polito, Michael; 1443424 McMahon, Kelton; 1826712 McMahon, Kelton; 1443386 Emslie, Steven", "bounds_geometry": "POLYGON((-180 -60,-166 -60,-152 -60,-138 -60,-124 -60,-110 -60,-96 -60,-82 -60,-68 -60,-54 -60,-40 -60,-40 -61.8,-40 -63.6,-40 -65.4,-40 -67.2,-40 -69,-40 -70.8,-40 -72.6,-40 -74.4,-40 -76.2,-40 -78,-54 -78,-68 -78,-82 -78,-96 -78,-110 -78,-124 -78,-138 -78,-152 -78,-166 -78,180 -78,178 -78,176 -78,174 -78,172 -78,170 -78,168 -78,166 -78,164 -78,162 -78,160 -78,160 -76.2,160 -74.4,160 -72.6,160 -70.8,160 -69,160 -67.2,160 -65.4,160 -63.6,160 -61.8,160 -60,162 -60,164 -60,166 -60,168 -60,170 -60,172 -60,174 -60,176 -60,178 -60,-180 -60))", "dataset_titles": "Amino acid nitrogen isotope values of modern and ancient Ad\u00e9lie penguin eggshells from the Ross Sea and Antarctic Peninsula regions; Amino acid nitrogen isotope values of penguins from the Antarctic Peninsula region 1930s to 2010s; Ancient Adelie penguin colony revealed by snowmelt at Cape Irizar, Ross Sea, Antarctica; Carbon and nitrogen stable isotope values of Antarctic Krill from the South Shetland Islands and the northern Antarctic Peninsula 2007 and 2009; Radiocarbon dates from pygoscelid penguin tissues excavated at Stranger Point, King George Island, Antarctic Peninsula; Radiocarbon dating and stable isotope values of penguin and seal tissues recovered from ornithogenic soils on Platter Island, Danger Islands Archipelago, Antarctic Peninsula in December 2015.; Radioisotope dates and carbon (\u03b413C) and nitrogen (\u03b415N) stable isotope values from modern and mummified Ad\u00e9lie Penguin chick carcasses and tissue from the Ross Sea, Antarctica; Radiometric dating, geochemical proxies, and predator biological remains obtained from aquatic sediment cores on South Georgia Island.; Receding ice drove parallel expansions in Southern Ocean penguin; SNP data from \"Receding ice drove parallel expansions in Southern Ocean penguins\".; Stable isotope analysis of multiple tissues from chick carcasses of three pygoscelid penguins in Antarctica; Stable isotopes of Adelie Penguin chick bone collagen; The rise and fall of an ancient Adelie penguin \u0027supercolony\u0027 at Cape Adare, Antarctica", "datasets": [{"dataset_uid": "601509", "doi": "10.15784/601509", "keywords": "Antarctica; Antarctic Fur Seal; Elemental Concentrations; King Penguin; Population Dynamics; South Atlantic Ocean; South Georgia Island; Stable Isotope Analysis; Sub-Antarctic", "people": "Maiti, Kanchan; McMahon, Kelton; Polito, Michael; Kristan, Allyson", "repository": "USAP-DC", "science_program": null, "title": "Radiometric dating, geochemical proxies, and predator biological remains obtained from aquatic sediment cores on South Georgia Island.", "url": "https://www.usap-dc.org/view/dataset/601509"}, {"dataset_uid": "601760", "doi": "10.15784/601760", "keywords": "Adelie Penguin; Amino Acids; Antarctica; Antarctic Peninsula; Ross Sea; Stable Isotope Analysis; Trophic Position", "people": "Patterson, William; Emslie, Steven D.; McCarthy, Matthew; Wonder, Michael; Polito, Michael; Michelson, Chantel; McMahon, Kelton", "repository": "USAP-DC", "science_program": null, "title": "Amino acid nitrogen isotope values of modern and ancient Ad\u00e9lie penguin eggshells from the Ross Sea and Antarctic Peninsula regions", "url": "https://www.usap-dc.org/view/dataset/601760"}, {"dataset_uid": "601212", "doi": "10.15784/601212", "keywords": "Abandoned Colonies; Antarctica; Antarctic Peninsula; Beach Deposit; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Holocene; Penguin; Radiocarbon; Radiocarbon Dates; Snow/ice; Snow/Ice; Stranger Point", "people": "Emslie, Steven D.", "repository": "USAP-DC", "science_program": null, "title": "Radiocarbon dates from pygoscelid penguin tissues excavated at Stranger Point, King George Island, Antarctic Peninsula", "url": "https://www.usap-dc.org/view/dataset/601212"}, {"dataset_uid": "601210", "doi": "10.15784/601210", "keywords": "Antarctica; Antarctic Krill; Antarctic Peninsula; Biota; Carbon Isotopes; Isotope Data; Krill; Nitrogen Isotopes; Oceans; Southern Ocean; Stable Isotope Analysis", "people": "Polito, Michael", "repository": "USAP-DC", "science_program": null, "title": "Carbon and nitrogen stable isotope values of Antarctic Krill from the South Shetland Islands and the northern Antarctic Peninsula 2007 and 2009", "url": "https://www.usap-dc.org/view/dataset/601210"}, {"dataset_uid": "601374", "doi": "10.15784/601374", "keywords": "Adelie Penguin; Antarctica; Cape Irizar; Drygalski Ice Tongue; Ross Sea; Stable Isotopes", "people": "Emslie, Steven D.", "repository": "USAP-DC", "science_program": null, "title": "Ancient Adelie penguin colony revealed by snowmelt at Cape Irizar, Ross Sea, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601374"}, {"dataset_uid": "200180", "doi": "", "keywords": null, "people": null, "repository": "NCBI BioProject", "science_program": null, "title": "Receding ice drove parallel expansions in Southern Ocean penguin", "url": "https://www.ncbi.nlm.nih.gov/bioproject/?term=PRJNA589336"}, {"dataset_uid": "200181", "doi": "10.6084/m9.figshare.c.4475300.v1", "keywords": null, "people": null, "repository": "Figshare", "science_program": null, "title": "SNP data from \"Receding ice drove parallel expansions in Southern Ocean penguins\".", "url": "https://doi.org/10.6084/m9.figshare.c.4475300.v1"}, {"dataset_uid": "601913", "doi": "10.15784/601913", "keywords": "Adelie Penguin; Antarctica; Cryosphere; Foraging; Polynya; Pygoscelis Adeliae; Ross Sea; Stable Isotopes", "people": "Reaves, Megan; Powers, Shannon; Emslie, Steven D.", "repository": "USAP-DC", "science_program": null, "title": "Stable isotopes of Adelie Penguin chick bone collagen", "url": "https://www.usap-dc.org/view/dataset/601913"}, {"dataset_uid": "601263", "doi": "10.15784/601263", "keywords": "Abandoned Colonies; Antarctica; Holocene; Penguin; Ross Sea; Stable Isotope Analysis", "people": "Patterson, William; Kristan, Allyson; Emslie, Steven D.", "repository": "USAP-DC", "science_program": null, "title": "Radioisotope dates and carbon (\u03b413C) and nitrogen (\u03b415N) stable isotope values from modern and mummified Ad\u00e9lie Penguin chick carcasses and tissue from the Ross Sea, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601263"}, {"dataset_uid": "601364", "doi": "10.15784/601364", "keywords": "Antarctica; Antarctic Peninsula; Arctocephalus Gazella; Carbon; Holocene; Nitrogen; Paleoecology; Penguin; Pygoscelis Spp.; Stable Isotope Analysis; Weddell Sea", "people": "Clucas, Gemma; Polito, Michael; Herman, Rachael; Kalvakaalva, Rohit", "repository": "USAP-DC", "science_program": null, "title": "Radiocarbon dating and stable isotope values of penguin and seal tissues recovered from ornithogenic soils on Platter Island, Danger Islands Archipelago, Antarctic Peninsula in December 2015.", "url": "https://www.usap-dc.org/view/dataset/601364"}, {"dataset_uid": "601327", "doi": "10.15784/601327", "keywords": "Adelie Penguin; Antarctica; Biota; Cape Adare; East Antarctica; Population Movement; Pygoscelis Adeliae; Radiocarbon; Ross Sea; Sea Level Rise; Stable Isotopes", "people": "McKenzie, Ashley; Patterson, William; Emslie, Steven D.", "repository": "USAP-DC", "science_program": null, "title": "The rise and fall of an ancient Adelie penguin \u0027supercolony\u0027 at Cape Adare, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601327"}, {"dataset_uid": "601382", "doi": "10.15784/601382", "keywords": "25 De Mayo/King George Island; Antarctica; Biota; Delta 13C; Delta 15N; Dietary Shifts; Opportunistic Sampling; Penguin; Pygoscelis Penguins; Stranger Point", "people": "Ciriani, Yanina; Emslie, Steven D.", "repository": "USAP-DC", "science_program": null, "title": "Stable isotope analysis of multiple tissues from chick carcasses of three pygoscelid penguins in Antarctica", "url": "https://www.usap-dc.org/view/dataset/601382"}, {"dataset_uid": "601232", "doi": "10.15784/601232", "keywords": "Amino Acids; Antarctica; Antarctic Peninsula; Biota; Isotope Data; Nitrogen Isotopes; Oceans; Penguin; Southern Ocean; Stable Isotope Analysis", "people": "McMahon, Kelton; Polito, Michael", "repository": "USAP-DC", "science_program": null, "title": "Amino acid nitrogen isotope values of penguins from the Antarctic Peninsula region 1930s to 2010s", "url": "https://www.usap-dc.org/view/dataset/601232"}], "date_created": "Thu, 08 Aug 2019 00:00:00 GMT", "description": "The Antarctic marine ecosystem is highly productive and supports a diverse range of ecologically and commercially important species. A key species in this ecosystem is Antarctic krill, which in addition to being commercially harvested, is the principle prey of a wide range of marine organisms including penguins, seals and whales. The aim of this study is to use penguins and other krill predators as sensitive indicators of past changes in the Antarctic marine food web resulting from climate variability and the historic harvesting of seals and whales by humans. Specifically this study will recover and analyze modern (\u003c20 year old), historic (20-200 year old) and ancient (200-10,000 year old) penguin and other krill predator tissues to track their past diets and population movements relative to shifts in climate and the availability of Antarctic krill. Understanding how krill predators were affected by these factors in the past will allow us to better understand how these predators, the krill they depend on, and the Antarctic marine ecosystem as a whole will respond to current challenges such as global climate change and an expanding commercial fishery for Antarctic krill. The project will further the NSF goals of training new generations of scientists and of making scientific discoveries available to the general public. This project will support the cross-institutional training of undergraduate and graduate students in advanced analytical techniques in the fields of ecology and biogeochemistry. In addition, this project includes educational outreach aimed encouraging participation in science careers by engaging K-12 students in scientific issues related to Antarctica, penguins, marine ecology, biogeochemistry, and global climate change. This research will help place recent ecological changes in the Southern Ocean into a larger historical context by examining decadal and millennial-scale shifts in the diets and population movements of Antarctic krill predators (penguins, seals, and squid) in concert with climate variability and commercial harvesting. This will be achieved by coupling advanced stable and radio isotope techniques, particularly compound-specific stable isotope analysis, with unprecedented access to modern, historical, and well-preserved paleo-archives of Antarctic predator tissues dating throughout the Holocene. This approach will allow the project to empirically test if observed shifts in Antarctic predator bulk tissue stable isotope values over the past millennia were caused by climate-driven shifts at the base of the food web in addition to, or rather than, shifts in predator diets due to a competitive release following the historic harvesting of krill eating whale and seals. In addition, this project will track the large-scale abandonment and reoccupation of penguin colonies around Antarctica in response to changes in climate and sea ice conditions over the past several millennia. These integrated field studies and laboratory analyses will provide new insights into the underlying mechanisms that influenced past shifts in the diets and population movements of charismatic krill predators such as penguins. This will allow for improved projections of the ecosystem consequences of future climate change and anthropogenic harvesting scenarios in the Antarctica that are likely to affect the availability of Antarctic krill.", "east": -40.0, "geometry": "POINT(-120 -69)", "instruments": null, "is_usap_dc": true, "keywords": "ANIMAL ECOLOGY AND BEHAVIOR; South Shetland Islands; Penguin; Stable Isotopes; Polar; Ross Sea; USA/NSF; Weddell Sea; AMD; MARINE ECOSYSTEMS; USAP-DC; Antarctica; PENGUINS; Southern Hemisphere; FIELD INVESTIGATION; Amd/Us; Krill; MACROFOSSILS", "locations": "Southern Hemisphere; Ross Sea; South Shetland Islands; Weddell Sea; Polar; Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Polito, Michael; Kelton, McMahon; Patterson, William; McCarthy, Matthew", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION", "repo": "USAP-DC", "repositories": "Figshare; NCBI BioProject; USAP-DC", "science_programs": null, "south": -78.0, "title": "Collaborative Research: Investigating Holocene Shifts in the Diets and Paleohistory of Antarctic Krill Predators", "uid": "p0010047", "west": 160.0}, {"awards": "1443464 Sowers, Todd; 1443710 Severinghaus, Jeffrey; 1443472 Brook, Edward J.", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole CH4 data for termination; South Pole Ice Core Isotopes of N2 and Ar; South Pole ice core (SPC14) discrete methane data; South Pole ice core total air content; South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2; SP19 Gas Chronology", "datasets": [{"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kennedy, Joshua A.; Sowers, Todd A.; Osterberg, Erich; Hood, Ekaterina; Kalk, Michael; Ferris, David G.; Winski, Dominic A.; Fudge, T. J.; Edwards, Jon S.; Epifanio, Jenna; Severinghaus, Jeffrey P.; Steig, Eric J.; Kahle, Emma; Brook, Edward J.; Kreutz, Karl; Aydin, Murat; Buizert, Christo", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601517", "doi": "10.15784/601517", "keywords": "Antarctica; Argon; Argon Isotopes; Firn; Firn Temperature Gradient; Firn Thickness; Gas Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Nitrogen; Nitrogen Isotopes; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.; Morgan, Jacob", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Isotopes of N2 and Ar", "url": "https://www.usap-dc.org/view/dataset/601517"}, {"dataset_uid": "601231", "doi": "10.15784/601231", "keywords": "Air Content; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core total air content", "url": "https://www.usap-dc.org/view/dataset/601231"}, {"dataset_uid": "601230", "doi": "10.15784/601230", "keywords": "Antarctica; Atmospheric CH4; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Data; Methane; Methane Concentration; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole CH4 data for termination", "url": "https://www.usap-dc.org/view/dataset/601230"}, {"dataset_uid": "601152", "doi": "10.15784/601152", "keywords": "Antarctica; Antarctic Ice Sheet; Chemistry:gas; Chemistry:Gas; Chemistry:ice; Chemistry:Ice; Delta 18O; Dole Effect; Firn Thickness; Gas Isotopes; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Gravitational Settling; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Inert Gases; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2", "url": "https://www.usap-dc.org/view/dataset/601152"}], "date_created": "Sat, 02 Feb 2019 00:00:00 GMT", "description": "Gases trapped in ice cores have revealed astonishing things about the greenhouse gas composition of the past atmosphere, including the fact that carbon dioxide concentrations never rose above 300 parts per million during the last 800,000 years. This places today\u0027s concentration of 400 parts per million in stark contrast. Furthermore, these gas records show that natural sources of greenhouse gas such as oceans and ecosystems act as amplifiers of climate change by increasing emissions of gases during warmer periods. Such amplification is expected to occur in the future, adding to the human-produced gas burden. The South Pole ice core will build upon these prior findings by expanding the suite of gases to include, for the first time, those potent trace gases that both trapped heat and depleted ozone during the past 40,000 years. The present project on inert gases and methane in the South Pole ice core will improve the dating of this crucial record, to unprecedented precision, so that the relative timing of events can be used to learn about the mechanism of trace gas production and destruction, and consequent climate change amplification. Ultimately, this information will inform predictions of future atmospheric chemical cleansing mechanisms and climate in the context of our rapidly changing atmosphere. This award also engages young people in the excitement of discovery and polar research, helping to entrain the next generations of scientists and educators. Education of graduate students, a young researcher (Buizert), and training of technicians, will add to the nation?s human resource base. This award funds the construction of the gas chronology for the South Pole 1500m ice core, using measured inert gases (d15N and d40Ar--Nitrogen and Argon isotope ratios, respectively) and methane in combination with a next-generation firn densification model that treats the stochastic nature of air trapping and the role of impurities on densification. The project addresses fundamental gaps in scientific understanding that limit the accuracy of gas chronologies, specifically a poor knowledge of the controls on ice-core d15N and the possible role of layering and impurities in firn densification. These gaps will be addressed by studying the gas enclosure process in modern firn at the deep core site. The work will comprise the first-ever firn air pumping experiment that has tightly co-located measurements of firn structural properties on the core taken from the same borehole. The project will test the hypothesis that the lock-in horizon as defined by firn air d15N, CO2, and methane is structurally controlled by impermeable layers, which are in turn created by high-impurity content horizons in which densification is enhanced. Thermal signals will be sought using the inert gas measurements, which improve the temperature record with benefits to the firn densification modeling. Neon, argon, and oxygen will be measured in firn air and a limited number of deep core samples to test whether glacial period layering was enhanced, which could explain low observed d15N in the last glacial period. Drawing on separate volcanic and methane synchronization to well-dated ice cores to create independent ice and gas tie points, independent empirical estimates of the gas age-ice age difference will be made to check the validity of the firn densification model-inert gas approach to calculating the gas age-ice age difference. These points will also be used to test whether the anomalously low d15N seen during the last glacial period in east Antarctic ice cores is due to deep air convection in the firn, or a missing impurity dependence in the firn densification models. The increased physical understanding gained from these studies, combined with new high-precision measurements, will lead to improved accuracy of the gas chronology of the South Pole ice core, which will enhance the overall science return from this gas-oriented core. This will lead to clarification of timing of atmospheric gas variations and temperature, and aid in efforts to understand the biogeochemical feedbacks among trace gases. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. Ozone-depleting substances will be measured in the South Pole ice core record, and a precise gas chronology will add value. Lastly, by seeking a better understanding of the physics of gas entrapment, the project aims to have an impact on ice-core science in general.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "USAP-DC; AMD; LABORATORY; Antarctica; NITROGEN ISOTOPES; USA/NSF; METHANE; Amd/Us; FIELD INVESTIGATION", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Sowers, Todd A.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Inert Gas and Methane Based Climate Records throughout the South Pole Deep Ice Core", "uid": "p0010005", "west": 0.0}, {"awards": "0538049 Steig, Eric; 0538520 Thiemens, Mark", "bounds_geometry": "POINT(-112.085 -79.5)", "dataset_titles": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core; WAIS Divide sulfate and nitrate isotopes; WAIS ice core isotope data #387, 385 (full data link not provided)", "datasets": [{"dataset_uid": "601007", "doi": "10.15784/601007", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Nitrate; Oxygen Isotope; Sulfate; WAIS Divide; WAIS Divide Ice Core", "people": "Steig, Eric J.; Alexander, Becky", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide sulfate and nitrate isotopes", "url": "https://www.usap-dc.org/view/dataset/601007"}, {"dataset_uid": "609479", "doi": "10.7265/N5BG2KXH", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Thiemens, Mark H.", "repository": "USAP-DC", "science_program": null, "title": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609479"}, {"dataset_uid": "002512", "doi": "", "keywords": null, "people": null, "repository": "Project website", "science_program": null, "title": "WAIS ice core isotope data #387, 385 (full data link not provided)", "url": "http://www.waisdivide.unh.edu/"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "0538520\u003cbr/\u003eThiemens\u003cbr/\u003eThis award supports a project to develop the first complete record of multiple isotope ratios of nitrate and sulfate covering the last ~100,000 years, from the deep ice core planned for the central ice divide of the West Antarctic Ice Sheet (WAIS). The WAIS Divide ice core will be the highest resolution long ice core obtained from Antarctica and we can expect important complementary information to be available, including accurate knowledge of past accumulation rates, temperatures, and compounds such as H2O2, CO and CH4. These compounds play significant roles in global atmospheric chemistry and climate. Especially great potential lies in the use of multiple isotope signatures. The unique mass independent fractionation (MIF) 17O signature of ozone is observed in both nitrate and sulfate, due to the interaction of their precursors with ozone. The development of methods to measure the multiple-isotope composition of small samples of sulfate and nitrate makes continuous high resolution measurements on ice cores feasible for the first time. Recent work has shown that such measurements can be used to determine the hydroxyl radial (OH) and ozone (O3) concentrations in the paleoatmosphere as well as to apportion sulfate and nitrate sources. There is also considerable potential in using these isotope measurements to quantify post depositional changes. In the first two years, continuous measurements from the upper ~100-m of ice at WAIS divide will be obtained, to provide a detailed look at seasonal through centennial scale variability. In the third year, measurements will be made throughout the available depth of the deep core (expected to reach ~500 m at this time). The broader impacts of the project include applications to diverse fields including atmospheric chemistry, glaciology, meteorology, and paleoclimatology. Because nitrate and sulfate are important atmospheric pollutants, the results will also have direct and relevance to global environmental policy. This project will coincide with the International Polar Year (2007-2008), and contributes to goals of the IPY, which include the fostering of interdisciplinary research toward enhanced understanding of atmospheric chemistry and climate in the polar regions.", "east": -112.085, "geometry": "POINT(-112.085 -79.5)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Isotope Ratios; Temperature; Sulfate; West Antarctic; Paleoatmosphere; LABORATORY; Ice Core; Ice Core Data; Mass Independent Fractionation; FIELD SURVEYS; Not provided; Accumulation Rate; Oxygen Isotope; FIELD INVESTIGATION; Ice Core Chemistry; Isotope", "locations": "West Antarctic", "north": -79.5, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Alexander, Becky; Steig, Eric J.; Thiemens, Mark H.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "Project website; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.5, "title": "Collaborative Research: Multiple-isotope Analysis of Nitrate and Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "uid": "p0000020", "west": -112.085}, {"awards": "1245659 Petrenko, Vasilii; 1245821 Brook, Edward J.; 1246148 Severinghaus, Jeffrey", "bounds_geometry": "POINT(162.167 -77.733)", "dataset_titles": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores; Last Interglacial Mean Ocean Temperature; Mean Ocean Temperature in Marine Isotope Stage 4; Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation; N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica; Taylor Glacier CO2 Isotope Data 74-59 kyr; Taylor Glacier Noble Gases - Younger Dryas; The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "datasets": [{"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "601260", "doi": "10.15784/601260", "keywords": "Antarctica; Carbon-14; Cosmogenic; Ice Core; Methane", "people": "Petrenko, Vasilii; Dyonisius, Michael", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601260"}, {"dataset_uid": "601198", "doi": "10.15784/601198", "keywords": "Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; CO2; Dust; Gas; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Mass Spectrometer; Methane; Nitrogen Isotopes; Oxygen Isotope; Paleoclimate; Snow/ice; Snow/Ice; Taylor Dome; Taylor Dome Ice Core", "people": "Severinghaus, Jeffrey P.; Brook, Edward J.; Menking, James; Baggenstos, Daniel; Bauska, Thomas; Rhodes, Rachel; McConnell, Joseph; Petrenko, Vasilii; Dyonisius, Michael; Shackleton, Sarah; Barker, Stephen; Marcott, Shaun", "repository": "USAP-DC", "science_program": null, "title": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/601198"}, {"dataset_uid": "601176", "doi": "10.15784/601176", "keywords": "Antarctica; CO2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; Noble Gas; Noble Gas Isotopes; Snow/ice; Snow/Ice; Taylor Glacier; Younger Dryas", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Taylor Glacier Noble Gases - Younger Dryas", "url": "https://www.usap-dc.org/view/dataset/601176"}, {"dataset_uid": "601415", "doi": "10.15784/601415", "keywords": "Antarctica; Glaciology; Ice Core Data; Ice Core Records; Paleoclimate; Paleotemperature; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": null, "title": "Mean Ocean Temperature in Marine Isotope Stage 4", "url": "https://www.usap-dc.org/view/dataset/601415"}, {"dataset_uid": "601398", "doi": "10.15784/601398", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Gas Records; Ice Core Records; Marine Isotope Stage 4; MIS 4; Nitrous Oxide; Pleistocene; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah; Schilt, Adrian; Menking, James; Severinghaus, Jeffrey P.; Dyonisius, Michael; Petrenko, Vasilii; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601398"}, {"dataset_uid": "600163", "doi": "10.15784/600163", "keywords": "Antarctica; Atmosphere; Geochemistry; Ice Core Records; Isotope; Paleoclimate; Taylor Glacier; Transantarctic Mountains", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "url": "https://www.usap-dc.org/view/dataset/600163"}, {"dataset_uid": "601600", "doi": "10.15784/601600", "keywords": "Antarctica; Taylor Glacier", "people": "Buffen, Aron; Menking, James; Shackleton, Sarah; Bauska, Thomas; Brook, Edward J.; Barker, Stephen; Severinghaus, Jeffrey P.; Dyonisius, Michael; Petrenko, Vasilii; Menking, Andy", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier CO2 Isotope Data 74-59 kyr", "url": "https://www.usap-dc.org/view/dataset/601600"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "1245659/Petrenko This award supports a project to use the Taylor Glacier, Antarctica, ablation zone to collect ice samples for a range of paleoenvironmental studies. A record of carbon-14 of atmospheric methane (14CH4) will be obtained for the last deglaciation and the Early Holocene, together with a supporting record of CH4 stable isotopes. In-situ cosmogenic 14C content and partitioning of 14C between different species (14CH4, C-14 carbon monoxide (14CO) and C-14 carbon dioxide (14CO2)) will be determined with unprecedented precision in ice from the surface down to ~67 m. Further age-mapping of the ablating ice stratigraphy will take place using a combination of CH4, CO2, \u0026#948;18O of oxygen gas and H2O stable isotopes. High precision, high-resolution records of CO2, \u0026#948;13C of CO2, nitrous oxide (N2O) and N2O isotopes will be obtained for the last deglaciation and intervals during the last glacial period. The potential of 14CO2 and Krypton-81 (81Kr) as absolute dating tools for glacial ice will be investigated. The intellectual merit of proposed work includes the fact that the response of natural methane sources to continuing global warming is uncertain, and available evidence is insufficient to rule out the possibility of catastrophic releases from large 14C-depleted reservoirs such as CH4 clathrates and permafrost. The proposed paleoatmospheric 14CH4 record will improve our understanding of the possible magnitude and timing of CH4 release from these reservoirs during a large climatic warming. A thorough understanding of in-situ cosmogenic 14C in glacial ice (production rates by different mechanisms and partitioning between species) is currently lacking. Such an understanding will likely enable the use of in-situ 14CO in ice at accumulation sites as a reliable, uncomplicated tracer of the past cosmic ray flux and possibly past solar activity, as well as the use of 14CO2 at both ice accumulation and ice ablation sites as an absolute dating tool. Significant gaps remain in our understanding of the natural carbon cycle, as well as in its responses to global climate change. The proposed high-resolution, high-precision records of \u0026#948;13C of CO2 would provide new information on carbon cycle changes both during times of rising CO2 in a warming climate and falling CO2 in a cooling climate. N2O is an important greenhouse gas that increased by ~30% during the last deglaciation. The causes of this increase are still largely uncertain, and the proposed high-precision record of N2O concentration and isotopes would provide further insights into N2O source changes in a warming world. The broader impacts of proposed work include an improvement in our understanding of the response of these greenhouse gas budgets to global warming and inform societally important model projections of future climate change. The continued age-mapping of Taylor Glacier ablation ice will add value to this high-quality, easily accessible archive of natural environmental variability. Establishing 14CO as a robust new tracer for past cosmic ray flux would inform paleoclimate studies and constitute a valuable contribution to the study of the societally important issue of climate change. The proposed work will contribute to the development of new laboratory and field analytical systems. The data from the study will be made available to the scientific community and the broad public through the NSIDC and NOAA Paleoclimatology data centers. 1 graduate student each will be trained at UR, OSU and SIO, and the work will contribute to the training of a postdoc at OSU. 3 UR undergraduates will be involved in fieldwork and research. The work will support a new, junior UR faculty member, Petrenko. All PIs have a strong history of and commitment to scientific outreach in the forms of media interviews, participation in filming of field projects, as well as speaking to schools and the public about their research, and will continue these activities as part of the proposed work. This award has field work in Antarctica.", "east": 162.167, "geometry": "POINT(162.167 -77.733)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Not provided; USAP-DC; FIELD INVESTIGATION; Stratigraphy; FIELD SURVEYS; Antarctica; Paleoenvironment; Methane; Ice Core; Carbon Dioxide; FIXED OBSERVATION STATIONS; Stable Isotopes; Ablation Zone; Taylor Glacier; Nitrous Oxide; USA/NSF; LABORATORY; AMD; Cosmogenic; Amd/Us", "locations": "Taylor Glacier; Antarctica", "north": -77.733, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Brook, Edward J.; Severinghaus, Jeffrey P.; PETRENKO, VASILLI", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e FIXED OBSERVATION STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.733, "title": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "uid": "p0000283", "west": 162.167}, {"awards": "0636731 Bender, Michael; 0636705 Marchant, David", "bounds_geometry": "POLYGON((160.48705 -77.84513,160.501913 -77.84513,160.516776 -77.84513,160.531639 -77.84513,160.546502 -77.84513,160.561365 -77.84513,160.576228 -77.84513,160.591091 -77.84513,160.605954 -77.84513,160.620817 -77.84513,160.63568 -77.84513,160.63568 -77.8515624,160.63568 -77.8579948,160.63568 -77.8644272,160.63568 -77.8708596,160.63568 -77.877292,160.63568 -77.8837244,160.63568 -77.8901568,160.63568 -77.8965892,160.63568 -77.9030216,160.63568 -77.909454,160.620817 -77.909454,160.605954 -77.909454,160.591091 -77.909454,160.576228 -77.909454,160.561365 -77.909454,160.546502 -77.909454,160.531639 -77.909454,160.516776 -77.909454,160.501913 -77.909454,160.48705 -77.909454,160.48705 -77.9030216,160.48705 -77.8965892,160.48705 -77.8901568,160.48705 -77.8837244,160.48705 -77.877292,160.48705 -77.8708596,160.48705 -77.8644272,160.48705 -77.8579948,160.48705 -77.8515624,160.48705 -77.84513))", "dataset_titles": "Dating and Paleoenvironmental Studies on Ancient Ice in the Dry Valleys, Antarctica; Measurements of Trapped Air from Mullins Valley, Dry Valleys, Antarctica", "datasets": [{"dataset_uid": "600069", "doi": "10.15784/600069", "keywords": "Antarctica; Dry Valleys; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope Record; Lake Vostok; Paleoclimate", "people": "Bender, Michael", "repository": "USAP-DC", "science_program": null, "title": "Dating and Paleoenvironmental Studies on Ancient Ice in the Dry Valleys, Antarctica", "url": "https://www.usap-dc.org/view/dataset/600069"}, {"dataset_uid": "609597", "doi": "10.7265/N50R9MBM", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Dry Valleys; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Paleoclimate; Radar Interferometer", "people": "Yau, Audrey M.; Bender, Michael", "repository": "USAP-DC", "science_program": null, "title": "Measurements of Trapped Air from Mullins Valley, Dry Valleys, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609597"}], "date_created": "Thu, 03 Feb 2011 00:00:00 GMT", "description": "This project studies ancient ice buried in the Dry Valleys of Antarctica. The ice, which may approach ten million years in age, will be dated using argon and uranium radioisotope techniques. High-risk work, if successful it will offer the first and perhaps only samples of the Earth\u0027s atmosphere from millions of years in the past. These samples could offer critically important tests of paleoclimate records and proxies, as well as a glimpse into the characteristics of a past world much like the predicted future, warmer Earth. The broader impacts are graduate student education, and potentially contributing to society\u0027s understanding of global climate change and sea level rise.", "east": 160.63568, "geometry": "POINT(160.561365 -77.877292)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Elemental Ratios; Oxygen Isotope; Not provided; Nitrogen Isotopes; LABORATORY; Argon Isotopes; FIELD INVESTIGATION", "locations": null, "north": -77.84513, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": null, "persons": "Bender, Michael; Yau, Audrey M.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.909454, "title": "Collaborative Research: Dating and Paleoenvironmental Studies on Ancient Ice in the Dry Valleys, Antarctica", "uid": "p0000039", "west": 160.48705}, {"awards": "0538657 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Borehole Temperature Measurement in WDC05A in January 2008 and January 2009; d15N and d18O of air in the WAIS Divide ice core; Low-res d15N and d18O of O2 in the WAIS Divide 06A Deep Core; Ultra-High Resolution LA-ICP-MS Results: DO-21 Rapid Warming Event; WAIS Divide d18Oatm and Siple Dome/WAIS Divide composite and individual delta epsilon LAND", "datasets": [{"dataset_uid": "601747", "doi": "10.15784/601747", "keywords": "Antarctica; Delta 15N; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Gas Records; Ice Core Records; Isotope; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; WAIS; WAIS Divide", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "d15N and d18O of air in the WAIS Divide ice core", "url": "https://www.usap-dc.org/view/dataset/601747"}, {"dataset_uid": "601041", "doi": "10.15784/601041", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Gas; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; WAIS Divide Ice Core", "people": "Seltzer, Alan; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide d18Oatm and Siple Dome/WAIS Divide composite and individual delta epsilon LAND", "url": "https://www.usap-dc.org/view/dataset/601041"}, {"dataset_uid": "609635", "doi": "10.7265/N51J97PS", "keywords": "Arctic; Geochemistry; GISP; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate", "people": "Kurbatov, Andrei V.; Mayewski, Paul A.; Haines, Skylar", "repository": "USAP-DC", "science_program": null, "title": "Ultra-High Resolution LA-ICP-MS Results: DO-21 Rapid Warming Event", "url": "https://www.usap-dc.org/view/dataset/609635"}, {"dataset_uid": "609660", "doi": "10.7265/N5S46PWD", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Low-res d15N and d18O of O2 in the WAIS Divide 06A Deep Core", "url": "https://www.usap-dc.org/view/dataset/609660"}, {"dataset_uid": "609637", "doi": "10.7265/N5B27S7S", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS Divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.; Orsi, Anais J.", "repository": "USAP-DC", "science_program": null, "title": "Borehole Temperature Measurement in WDC05A in January 2008 and January 2009", "url": "https://www.usap-dc.org/view/dataset/609637"}], "date_created": "Thu, 08 Jul 2010 00:00:00 GMT", "description": "0538657\u003cbr/\u003eSeveringhaus\u003cbr/\u003eThis award supports a project to develop high-resolution (20-yr) nitrogen and oxygen isotope records on trapped gases in the WAIS Divide ice core (Antarctica), with a comparison record for chronological purposes in the GISP2 (Greenland) ice core. The main scientific objective is to provide an independent temperature-change record for the past 100,000 years in West Antarctica that is not subject to the uncertainty inherent in ice isotopes (18O and deuterium), the classical paleothermometer. Nitrogen isotopes (Delta 15N) in air bubbles in glacial ice record rapid surface temperature change because of thermal fractionation of air in the porous firn layer, and this isotopic anomaly is recorded in bubbles as the firn becomes ice. Using this gas-based temperature-change record, in combination with methane data as interpolar stratigraphic markers, the proposed work will define the precise relative timing of abrupt warming in Greenland and abrupt cooling at the WAIS Divide site during the millennial-scale climatic oscillations of Marine Isotopic Stage 3 (30-70 kyr BP) and the last glacial termination. The nitrogen isotope record also provides constraints on past firn thickness, which inform temperature and accumulation rate histories from the ice core. A search for possible solar-related cycles will be conducted with the WAIS Divide Holocene (Delta 15N.) Oxygen isotopes of O2 (Delta 18Oatm) are obtained as a byproduct of the (Delta 15N) measurement. The gas-isotopic records will enhance the value of other atmospheric gas measurements in WAIS Divide, which are expected to be of unprecedented quality. The high-resolution (Delta 18Oatm) records will provide chronological control for use by the international ice coring community and for surface glacier ice dating. Education of a graduate student, and training of a staff member in the laboratory, will contribute to the nation\u0027s human resource base. Outreach activities in the context of the International Polar Year will be enhanced. International collaboration is planned with the laboratory of LSCE, University of Paris.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e LA-ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Borehole Temperature; LABORATORY; Depth; Not provided; GROUND-BASED OBSERVATIONS; Wais Divide-project; Ice Core; WAIS Divide", "locations": "WAIS Divide", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Haines, Skylar; Mayewski, Paul A.; Orsi, Anais J.; Kurbatov, Andrei V.; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Nitrogen and Oxygen Gas Isotopes in the WAIS Divide Ice Core as Constraints on Chronology, Temperature, and Accumulation Rate", "uid": "p0000036", "west": null}, {"awards": "0440975 Severinghaus, Jeffrey", "bounds_geometry": "POINT(-119.533333 -80.016667)", "dataset_titles": "Nitrogen and Oxygen Gas Isotopes in the Siple Dome and Byrd Ice Cores, Antarctica", "datasets": [{"dataset_uid": "609407", "doi": "10.7265/N55X26V0", "keywords": "Antarctica; Arctic; Atmosphere; Byrd Glacier; Byrd Ice Core; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Nitrogen and Oxygen Gas Isotopes in the Siple Dome and Byrd Ice Cores, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609407"}], "date_created": "Fri, 17 Jul 2009 00:00:00 GMT", "description": "The award supports the development of high-resolution nitrogen and oxygen isotope records on trapped gases in the Byrd and Siple Dome ice cores, and the Holocene part of the GISP2 ice core. The primary scientific goals of this work are to understand the enigmatic d15N anomalies seen thus far in the Siple Dome record at 15.3 ka and 35 ka, and to find other events that may occur in both cores. At these events, d15N of trapped air approaches zero, implying little or no gravitational fractionation of gases in the firn layer at the time of formation of the ice. These events may represent times of low accumulation rate and arid meteorological conditions, and thus may contain valuable information about the climatic history of West Antarctica. Alternatively, they may stem from crevassing and thus may reveal ice-dynamical processes. Finding the events in the Byrd core, which is located 500 km from Siple Dome, would place powerful constraints on their origin and significance. A second major goal is to explore the puzzling absence of the abrupt warming event at 22 ka (seen at Siple Dome) in the nearby Byrd 18O/16O record in the ice (d18Oice), and search for a possible correlative signal in Byrd d15N. A third goal takes advantage of the fact that precise measurements of the oxygen isotopic composition of atmospheric O2 (d18Oatm) are obtained as a byproduct of the d15N measurement. The proposed gas-isotopic measurements will underpin an integrated suite of West Antarctic climate and atmospheric gas records, which will ultimately include the WAIS Divide core. These records will help separate regional from global climate signals, and may place constraints on the cause of abrupt climate change. Education of two graduate students, and training of two staff members in the laboratory, contribute to the nation\u0027s human resource base. Education and outreach will be an important component of the project.", "east": -119.533333, "geometry": "POINT(-119.533333 -80.016667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Firn Air Isotopes; Not provided; Nitrogen Isotopes; LABORATORY; Firn Isotopes; Paleoclimate; FIELD SURVEYS; Ice Core; Oxygen Isotope; FIELD INVESTIGATION; Siple Dome", "locations": "Antarctica; Siple Dome", "north": -80.016667, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -80.016667, "title": "Nitrogen and oxygen gas isotopes in the Siple Dome and Byrd ice cores", "uid": "p0000450", "west": -119.533333}, {"awards": "0739512 Walker, Sally; 0739496 Miller, Molly; 0739583 Bowser, Samuel", "bounds_geometry": "POLYGON((163.41667 -77.33333,163.46667 -77.33333,163.51667 -77.33333,163.56667 -77.33333,163.61667 -77.33333,163.66667 -77.33333,163.71667 -77.33333,163.76667 -77.33333,163.81667 -77.33333,163.86667 -77.33333,163.91667 -77.33333,163.91667 -77.369997,163.91667 -77.406664,163.91667 -77.443331,163.91667 -77.479998,163.91667 -77.516665,163.91667 -77.553332,163.91667 -77.589999,163.91667 -77.626666,163.91667 -77.663333,163.91667 -77.7,163.86667 -77.7,163.81667 -77.7,163.76667 -77.7,163.71667 -77.7,163.66667 -77.7,163.61667 -77.7,163.56667 -77.7,163.51667 -77.7,163.46667 -77.7,163.41667 -77.7,163.41667 -77.663333,163.41667 -77.626666,163.41667 -77.589999,163.41667 -77.553332,163.41667 -77.516665,163.41667 -77.479998,163.41667 -77.443331,163.41667 -77.406664,163.41667 -77.369997,163.41667 -77.33333))", "dataset_titles": "Linking Modern Benthic Communities and Taphonomic Processes to the Stratigraphic Record of Antarctic Cores; Nitrogen, carbon, and oxygen isotopes in the shell of the Antarctic scallop Adamussium colbecki as a proxy for sea ice cover in Antarctica.; Sequence Data", "datasets": [{"dataset_uid": "600076", "doi": "10.15784/600076", "keywords": "Biota; Geochronology; Marine Sediments; Oceans; Southern Ocean", "people": "Miller, Molly; Furbish, David", "repository": "USAP-DC", "science_program": null, "title": "Linking Modern Benthic Communities and Taphonomic Processes to the Stratigraphic Record of Antarctic Cores", "url": "https://www.usap-dc.org/view/dataset/600076"}, {"dataset_uid": "000144", "doi": "", "keywords": null, "people": null, "repository": "NCBI GenBank", "science_program": null, "title": "Sequence Data", "url": "http://www.ncbi.nlm.nih.gov/sites/myncbi/collections/public/1rMU2lBNcxWAsa9h9WyD8rzA8/"}, {"dataset_uid": "601764", "doi": "10.15784/601764", "keywords": "Adamussium Colbecki; Antarctica; Biota; Carbon Isotopes; Explorers Cove; Nitrogen Isotopes; Oxygen Isotope; Scallop", "people": "Puhalski, Emma; Walker, Sally; Verheyden, Anouk; Cronin, Kelly; Camarra, Steve; Gillikin, David", "repository": "USAP-DC", "science_program": null, "title": "Nitrogen, carbon, and oxygen isotopes in the shell of the Antarctic scallop Adamussium colbecki as a proxy for sea ice cover in Antarctica.", "url": "https://www.usap-dc.org/view/dataset/601764"}, {"dataset_uid": "600077", "doi": "10.15784/600077", "keywords": "Antarctica; Biota; Glaciers/ice Sheet; Glaciers/Ice Sheet; McMurdo Sound; Oceans; Sample/collection Description; Sample/Collection Description", "people": "Walker, Sally", "repository": "USAP-DC", "science_program": null, "title": "Linking Modern Benthic Communities and Taphonomic Processes to the Stratigraphic Record of Antarctic Cores", "url": "https://www.usap-dc.org/view/dataset/600077"}], "date_created": "Wed, 15 Jul 2009 00:00:00 GMT", "description": "This project answers a simple question: why are there so few fossils in sediment cores from Antarctica?s continental shelf? Antarctica?s benthos are as biologically rich as those of the tropics. Shell-secreting organisms should have left a trail throughout geologic time, but have not. This trail is particularly important because these organisms record regional climate in ways that are critical to interpreting the global climate record. This study uses field experiments and targeted observations of modern benthic systems to examine the biases inflicted by fossil preservation. By examining a spectrum of ice-affected habitats, this project provides paleoenvironmental insights into carbonate preservation, sedimentation rates, and burial processes; and will provide new approaches to reconstructing the Cenozoic history of Antarctica. Broader impacts include graduate and undergraduate research and education, development of undergraduate curricula to link art and science, K12 outreach, public outreach via the web, and societal relevance through improved understanding of records of global climate change.", "east": 163.91667, "geometry": "POINT(163.66667 -77.516665)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -77.33333, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": null, "persons": "Walker, Sally; Bowser, Samuel; Miller, Molly; Furbish, David", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "NCBI GenBank; USAP-DC", "science_programs": null, "south": -77.7, "title": "Collaborative Research: Linking Modern Benthic Communities and Taphonomic Processes to the Stratigraphic Record of Antarctic Cores", "uid": "p0000203", "west": 163.41667}, {"awards": "9725305 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "datasets": [{"dataset_uid": "609098", "doi": "10.7265/N51N7Z2P", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciology; Isotope; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole; Temperature", "people": "Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "url": "https://www.usap-dc.org/view/dataset/609098"}], "date_created": "Mon, 01 Jan 2001 00:00:00 GMT", "description": "9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Isotopic History; GROUND STATIONS; Thermal Diffusion; Firn Temperature Measurements; Not provided; Oxygen Isotope; Trapped Air Bubbles; Shallow Firn Air; Firn Air Isotope Measurements; Seasonal Temperature Gradients; Mass Spectrometry; GROUND-BASED OBSERVATIONS; Thermal Fractionation; Polar Firn Air; Isotopic Anomalies; Xenon; Atmospheric Gases; Argon Isotopes; Siple Dome; Krypton; Nitrogen Isotopes; Seasonal Temperature Changes; Antarctica; Ice Core Gas Records; Firn Air Isotopes; Mass Spectrometer; South Pole; Firn Isotopes; Borehole", "locations": "Antarctica; Siple Dome; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change", "uid": "p0000160", "west": null}]

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