USAP-DC

{"dp_type": "Project", "free_text": "Chromatography"}

[{"awards": "1847067 Levy, Joseph", "bounds_geometry": "POLYGON((161 -76,161.35 -76,161.7 -76,162.05 -76,162.4 -76,162.75 -76,163.1 -76,163.45 -76,163.8 -76,164.15 -76,164.5 -76,164.5 -76.2,164.5 -76.4,164.5 -76.6,164.5 -76.8,164.5 -77,164.5 -77.2,164.5 -77.4,164.5 -77.6,164.5 -77.8,164.5 -78,164.15 -78,163.8 -78,163.45 -78,163.1 -78,162.75 -78,162.4 -78,162.05 -78,161.7 -78,161.35 -78,161 -78,161 -77.8,161 -77.6,161 -77.4,161 -77.2,161 -77,161 -76.8,161 -76.6,161 -76.4,161 -76.2,161 -76))", "dataset_titles": "Biogeochemical measurements of water tracks and adjacent dry soils from the McMurdo Dry Valleys; Surface Water Geochemistry from the McMurdo Dry Valleys", "datasets": [{"dataset_uid": "601684", "doi": "10.15784/601684", "keywords": "Antarctica; Cation Exchange; Chemistry:soil; Chemistry:Soil; Dry Valleys; Organic Matter; Salt; Soil", "people": "Levy, Joseph", "repository": "USAP-DC", "science_program": null, "title": "Biogeochemical measurements of water tracks and adjacent dry soils from the McMurdo Dry Valleys", "url": "https://www.usap-dc.org/view/dataset/601684"}, {"dataset_uid": "601703", "doi": "10.15784/601703", "keywords": "Antarctica; Dry Valleys", "people": "Levy, Joseph", "repository": "USAP-DC", "science_program": null, "title": "Surface Water Geochemistry from the McMurdo Dry Valleys", "url": "https://www.usap-dc.org/view/dataset/601703"}], "date_created": "Fri, 24 Dec 2021 00:00:00 GMT", "description": "Antarctic groundwater drives the regional carbon cycle and can accelerate permafrost thaw shaping Antarctic surface features. However, groundwater extent, flow, and processes on a continent virtually locked in ice are poorly understood. The proposed work investigates the interplay between groundwater, sediment, and ice in Antarctica\u0027s cold desert landscape to determine when, where, and why Antarctic groundwater is flowing, and how it may evolve Antarctic frozen deserts from dry and stable to wet and dynamic. Mapping the changing extent of Antarctic near-surface groundwater requires the ability to measure soil moisture rapidly and repeatedly over large areas. The research will capture changes in near-surface groundwater distribution through an unmanned aerial vehicle (UAV) mapping approach. The project integrates a diverse range of sensors with new UAV technologies to provide a higher-resolution and more frequent assessment of Antarctic groundwater extent and composition than can be accomplished using satellite observations alone. To complement the research objectives, the PI will develop a new UAV summer field school, the Geosciences UAV Academy, focused on training undergraduate-level UAV pilots in conducting novel earth sciences research using cutting edge imaging tools. The integration of research and technology will prepare students for careers in UAV-related industries and research. The project will deliver new UAV tools and workflows for soil moisture mapping relevant to arid regions including Antarctica as well as temperate desert and dryland systems and will train student research pilots to tackle next generation airborne challenges. Water tracks are the basic hydrological unit that currently feeds the rapidly-changing permafrost and wetlands in the Antarctic McMurdo Dry Valleys (MDV). Despite the importance of water tracks in the MDV hydrologic cycle and their influence on biogeochemistry, little is known about how these water tracks control the unique brine processes operating in Antarctic ice-free areas. Both groundwater availability and geochemistry shape Antarctic microbial communities, connecting soil geology and hydrology to carbon cycling and ecosystem functioning. The objectives of this CAREER proposal are to 1) map water tracks to determine the spatial distribution and seasonal magnitude of groundwater impacts on the MDV near-surface environment to determine how near-surface groundwater drives permafrost thaw and enhances chemical weathering and biogeochemical cycling; 2) establish a UAV academy training earth sciences students to answer geoscience questions using drone-based platforms and remote sensing techniques; and 3) provide a formative step in the development of the PI as a teacher-scholar. UAV-borne hyperspectral imaging complemented with field soil sampling will determine the aerial extent and timing of inundation, water level, and water budget of representative water tracks in the MDV. Soil moisture will be measured via near-infrared reflectance spectroscopy while bulk chemistry of soils and groundwater will be analyzed via ion chromatography and soil x-ray fluorescence. Sedimentological and hydrological properties will be determined via analysis of intact core samples. These data will be used to test competing hypotheses regarding the origin of water track solutions and water movement through seasonal wetlands. The work will provide a regional understanding of groundwater sources, shallow groundwater flux, and the influence of regional hydrogeology on solute export to the Southern Ocean and on soil/atmosphere linkages in earth\u0027s carbon budget. The UAV school will 1) provide comprehensive instruction at the undergraduate level in both how and why UAVs can advance geoscience research and learning; and 2) provide educational infrastructure for an eventual self-sustaining summer program for undergraduate UAV education. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 164.5, "geometry": "POINT(162.75 -77)", "instruments": null, "is_usap_dc": true, "keywords": "FIELD SURVEYS; Amd/Us; USA/NSF; AMD; USAP-DC; FROZEN GROUND; Taylor Valley", "locations": "Taylor Valley", "north": -76.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Levy, Joseph", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -78.0, "title": "Linking Antarctic Cold Desert Groundwater to Thermokarst \u0026 Chemical Weathering in Partnership with the Geoscience UAV Academy", "uid": "p0010286", "west": 161.0}, {"awards": "1851022 Fudge, Tyler; 1851094 Baker, Ian", "bounds_geometry": null, "dataset_titles": "Code for calculating mean gradient for EDC sulfate data; EPICA Dome C Sulfate Data 7-3190m; Forward Diffusion Model used to calculate widening of volcanic layer widths; Volcanic Widths in Dome C Interglacials and Glacials", "datasets": [{"dataset_uid": "601855", "doi": "10.15784/601855", "keywords": "Antarctica; Cryosphere", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": null, "title": "Volcanic Widths in Dome C Interglacials and Glacials", "url": "https://www.usap-dc.org/view/dataset/601855"}, {"dataset_uid": "601759", "doi": "10.15784/601759", "keywords": "Antarctica", "people": "Fudge, T. J.; Severi, Mirko", "repository": "USAP-DC", "science_program": "COLDEX", "title": "EPICA Dome C Sulfate Data 7-3190m", "url": "https://www.usap-dc.org/view/dataset/601759"}, {"dataset_uid": "601857", "doi": "10.15784/601857", "keywords": "Antarctica; Cryosphere", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": null, "title": "Forward Diffusion Model used to calculate widening of volcanic layer widths", "url": "https://www.usap-dc.org/view/dataset/601857"}, {"dataset_uid": "601856", "doi": "10.15784/601856", "keywords": "Antarctica; Cryosphere", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": null, "title": "Code for calculating mean gradient for EDC sulfate data", "url": "https://www.usap-dc.org/view/dataset/601856"}], "date_created": "Mon, 28 Jun 2021 00:00:00 GMT", "description": "The ice of the polar ice sheets is among the purest substances on Earth, yet the small amount of impurities --such as acids-- are important to how the ice flows and what can be learned from ice cores about past climate. The goal of this project is to understand the role of such acids on the deformation of polycrystalline ice by comparing the deformation behavior of pure and sulfuric acid-doped samples. Sulfuric acid was chosen both because of its importance for interpreting past climate and because it can lead to water veins in ice at low temperatures. This work will focus on the location, movement, and impact of acids in polycrystalline ice that are more complex than in single crystals of ice. By deforming samples and performing microstructural characterization, the role of acids on deformation rate, grain evolution, and the movement of the acids themselves, will be assessed. The work will lead to the education of a Ph.D. student at Dartmouth College, introduce undergraduate students to research at both the University of Washington and Dartmouth College. Despite the ubiquitous use of the constitutive relation for ice commonly referred to as \"Glen\u0027s Flow Law\", significant uncertainty exists particularly with regard to the role of impurities and the development of oriented fabrics. The aim of this project is to improve the constitutive relationship for ice by performing deformation tests and microstructural characterization of pure and sulfuric acid-doped ice. The project will focus on sulfuric acid\u0027s impact on ice viscosity, fabric evolution, and diffusivity. Sulfuric acid can have both direct and indirect effects on the mechanical properties of polycrystalline ice. The direct effects change the dislocation velocity and/or density, and the indirect effects change the grain size and fabric. The complexity and interaction of these effects means that it is not possible to understand the effects of sulfuric acid by simply examining ice core specimens. In this project, the team will deform four types of ice: lab-grown ice samples doped with similar-to-natural concentrations of sulfuric acid, lab-grown high-purity ice, layered doped and pure ice, and natural ice from Antarctic ice cores. Deformation will be performed in both uniaxial compression and simple shear. The addition of simple shear tests is critical for relating the laboratory-observed deformation behavior to the behavior of polar ice sheets where the shear strain dominates ice motion in basal ice. After deformation to strains from 5 percent up to 25 percent, the microstructural development will be assessed with methods including a variety of scanning electron microscope techniques, Raman microscopy, synchrotron-based Nano-X-ray fluorescence, and ion chromatography. These analysis techniques will allow the determination of 1) the segregation and movement of impurities, 2) the rate of grain-boundary migration, 3) the number of recrystallized grains; and 4) the full orientation of the ice crystals. The results will enable both microstructural modeling of the effects of sulfuric acid and numerical modeling of diffusion in ice cores. The net result will be a better understanding of ice deformation that improves ice-core interpretation and ice-sheet modeling. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "AMD; Polycrystalline Ice; LABORATORY; Epica Dome C; SNOW/ICE; USA/NSF; USAP-DC; Ice Core; Amd/Us", "locations": "Epica Dome C", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Science and Technology; Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Fudge, T. J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: The Impact of Impurities and Stress State on Polycrystalline Ice Deformation", "uid": "p0010211", "west": null}, {"awards": "1643722 Brook, Edward J.", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole Ice Core Methane Data and Gas Age Time Scale; South Pole ice core (SPC14) total air content (TAC)", "datasets": [{"dataset_uid": "601546", "doi": "10.15784/601546", "keywords": "Antarctica; South Pole", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) total air content (TAC)", "url": "https://www.usap-dc.org/view/dataset/601546"}, {"dataset_uid": "601329", "doi": "10.15784/601329", "keywords": "Antarctica; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; South Pole", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Methane Data and Gas Age Time Scale", "url": "https://www.usap-dc.org/view/dataset/601329"}], "date_created": "Tue, 02 Jun 2020 00:00:00 GMT", "description": "Brook/1643722 This award supports a project to measure the concentration of the gas methane in air trapped in an ice core collected from the South Pole. The data will provide an age scale (age as a function of depth) by matching the South Pole methane changes with similar data from other ice cores for which the age vs. depth relationship is well known. The ages provided will allow all other gas measurements made on the South Pole core (by the PI and other NSF supported investigators) to be interpreted accurately as a function of time. This is critical because a major goal of the South Pole coring project is to understand the history of rare gases in the atmosphere like carbon monoxide, carbon dioxide, ethane, propane, methyl chloride, and methyl bromide. Relatively little is known about what controls these gases in the atmosphere despite their importance to atmospheric chemistry and climate. Undergraduate assistants will work on the project and be introduced to independent research through their work. The PI will continue visits to local middle schools to introduce students to polar science, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) as part of the project. Methane concentrations from a major portion (2 depth intervals, excluding the brittle ice-zone which is being measured at Penn State University) of the new South Pole ice core will be used to create a gas chronology by matching the new South Pole ice core record with that from the well-dated WAIS Divide ice core record. In combination with measurements made at Penn State, this will provide gas dating for the entire 50,000-year record. Correlation will be made using a simple but powerful mid-point method that has been previously demonstrated, and other methods of matching records will be explored. The intellectual merit of this work is that the gas chronology will be a fundamental component of this ice core project, and will be used by the PI and other investigators for dating records of atmospheric composition, and determining the gas age-ice age difference independently of glaciological models, which will constrain processes that affected firn densification in the past. The methane data will also provide direct stratigraphic markers of important perturbations to global biogeochemical cycles (e.g., rapid methane variations synchronous with abrupt warming and cooling in the Northern Hemisphere) that will tie other ice core gas records directly to those perturbations. A record of the total air content will also be produced as a by-product of the methane measurements and will contribute to understanding of this parameter. The broader impacts include that the work will provide a fundamental data set for the South Pole ice core project and the age scale (or variants of it) will be used by all other investigators working on gas records from the core. The project will employ an undergraduate assistant(s) in both years who will conduct an undergraduate research project which will be part of the student\u0027s senior thesis or other research paper. The project will also offer at least one research position for the Oregon State University Summer REU site program. Visits to local middle schools, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) will also be part of the project.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "AMD; LABORATORY; METHANE; ICE CORE RECORDS; Gas Chromatography; South Pole; USAP-DC", "locations": "South Pole", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "A High Resolution Atmospheric Methane Record from the South Pole Ice Core", "uid": "p0010102", "west": 0.0}, {"awards": "1643684 Saito, Mak; 1644073 DiTullio, Giacomo", "bounds_geometry": "POLYGON((-180 -72,-173.6 -72,-167.2 -72,-160.8 -72,-154.4 -72,-148 -72,-141.6 -72,-135.2 -72,-128.8 -72,-122.4 -72,-116 -72,-116 -72.7,-116 -73.4,-116 -74.1,-116 -74.8,-116 -75.5,-116 -76.2,-116 -76.9,-116 -77.6,-116 -78.3,-116 -79,-122.4 -79,-128.8 -79,-135.2 -79,-141.6 -79,-148 -79,-154.4 -79,-160.8 -79,-167.2 -79,-173.6 -79,180 -79,178 -79,176 -79,174 -79,172 -79,170 -79,168 -79,166 -79,164 -79,162 -79,160 -79,160 -78.3,160 -77.6,160 -76.9,160 -76.2,160 -75.5,160 -74.8,160 -74.1,160 -73.4,160 -72.7,160 -72,162 -72,164 -72,166 -72,168 -72,170 -72,172 -72,174 -72,176 -72,178 -72,-180 -72))", "dataset_titles": "Algal pigment concentrations from the Ross Sea; Biogenic silica concentrations from the Ross Sea; NBP1801 Expedition data; Nutrients from NBP18-01 CICLOPS", "datasets": [{"dataset_uid": "601225", "doi": "10.15784/601225", "keywords": "Antarctica; Biogenic Silica; Biogenic Silica Concentrations; Chemistry:Water; Geochemistry; NBP1801; Oceans; Ross Sea; R/v Nathaniel B. Palmer; Sea Water; Southern Ocean; Spectroscopy; Water Measurements; Water Samples", "people": "Ditullio, Giacomo; Schanke, Nicole", "repository": "USAP-DC", "science_program": null, "title": "Biogenic silica concentrations from the Ross Sea", "url": "https://www.usap-dc.org/view/dataset/601225"}, {"dataset_uid": "601428", "doi": "10.15784/601428", "keywords": "Amundsen Sea; Antarctica; NBP1801; Nitrate; Nitrite; Nutrients; Phosphate; Ross Sea; R/v Nathaniel B. Palmer; Silicic Acid; Terra Nova Bay", "people": "Saito, Mak", "repository": "USAP-DC", "science_program": null, "title": "Nutrients from NBP18-01 CICLOPS", "url": "https://www.usap-dc.org/view/dataset/601428"}, {"dataset_uid": "200056", "doi": "10.7284/907753", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "NBP1801 Expedition data", "url": "https://www.rvdata.us/search/cruise/NBP1801"}, {"dataset_uid": "601205", "doi": "10.15784/601205", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Chlorophyll; Chromatography; Liquid Chromatograph; Oceans; Ross Sea; R/v Nathaniel B. Palmer; Sea Water; Seawater Measurements; Southern Ocean; Water Measurements; Water Samples", "people": "Ditullio, Giacomo", "repository": "USAP-DC", "science_program": null, "title": "Algal pigment concentrations from the Ross Sea", "url": "https://www.usap-dc.org/view/dataset/601205"}], "date_created": "Thu, 08 Aug 2019 00:00:00 GMT", "description": "Phytoplankton blooms in the coastal waters of the Ross Sea, Antarctica are typically dominated by either diatoms or Phaeocystis Antarctica (a flagellated algae that often can form large colonies in a gelatinous matrix). The project seeks to determine if an association of bacterial populations with Phaeocystis antarctica colonies can directly supply Phaeocystis with Vitamin B12, which can be an important co-limiting micronutrient in the Ross Sea. The supply of an essential vitamin coupled with the ability to grow at lower iron concentrations may put Phaeocystis at a competitive advantage over diatoms. Because Phaeocystis cells can fix more carbon than diatoms and Phaeocystis are not grazed as efficiently as diatoms, the project will help in refining understanding of carbon dynamics in the region as well as the basis of the food web webs. Such understanding also has the potential to help refine predictive ecological models for the region. The project will conduct public outreach activities and will contribute to undergraduate and graduate research. Engagement of underrepresented students will occur during summer student internships. A collaboration with Italian Antarctic researchers, who have been studying the Terra Nova Bay ecosystem since the 1980s, aims to enhance the project and promote international scientific collaborations. The study will test whether a mutualistic symbioses between attached bacteria and Phaeocystis provides colonial cells a mechanism for alleviating chronic Vitamin B12 co-limitation effects thereby conferring them with a competitive advantage over diatom communities. The use of drifters in a time series study will provide the opportunity to track in both space and time a developing algal bloom in Terra Nova Bay and to determine community structure and the physiological nutrient status of microbial populations. A combination of flow cytometry, proteomics, metatranscriptomics, radioisotopic and stable isotopic labeling experiments will determine carbon and nutrient uptake rates and the role of bacteria in mitigating potential vitamin B12 and iron limitation. Membrane inlet and proton transfer reaction mass spectrometry will also be used to estimate net community production and release of volatile organic carbon compounds that are climatically active. Understanding how environmental parameters can influence microbial community dynamics in Antarctic coastal waters will advance an understanding of how changes in ocean stratification and chemistry could impact the biogeochemistry and food web dynamics of Southern Ocean ecosystems.", "east": 160.0, "geometry": "POINT(-158 -75.5)", "instruments": null, "is_usap_dc": true, "keywords": "BIOGEOCHEMICAL CYCLES; NBP1801; Amd/Us; USA/NSF; USAP-DC; NUTRIENTS; PIGMENTS; CHLOROPHYLL; R/V NBP; Ross Sea; AMD", "locations": "Ross Sea", "north": -72.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Integrated System Science; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "DiTullio, Giacomo; Lee, Peter", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "USAP-DC", "repositories": "R2R; USAP-DC", "science_programs": null, "south": -79.0, "title": "Collaborative Research: Cobalamin and Iron Co-Limitation Of Phytoplankton Species in Terra Nova Bay", "uid": "p0010045", "west": -116.0}, {"awards": "1443263 Higgins, John; 1443306 Mayewski, Paul", "bounds_geometry": null, "dataset_titles": "Allan Hills ice water stable isotope record for dD, d18O; Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores; Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores; Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores; Greenhouse gas composition in the Allan Hills S27 ice core; Methane concentration in Allan Hills ice cores; Stable isotope composition of the trapped air in the Allan Hills S27 ice core; Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "datasets": [{"dataset_uid": "601203", "doi": "10.15784/601203", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Chemistry:ice; Chemistry:Ice; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenhouse Gas; Ice; Ice Core Data; Ice Core Gas Records; Methane; Snow/ice; Snow/Ice", "people": "Bender, Michael; Brook, Edward J.; Yan, Yuzhen; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Methane concentration in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601203"}, {"dataset_uid": "601201", "doi": "10.15784/601201", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Argon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Data; Ice Core Gas Records; Krypton; Mass Spectrometer; Noble Gas; Snow/ice; Snow/Ice; Xenon", "people": "Yan, Yuzhen; Ng, Jessica; Higgins, John; Severinghaus, Jeffrey P.; Bender, Michael", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601201"}, {"dataset_uid": "601128", "doi": "10.15784/601128", "keywords": "Allan Hills; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope Record; Mass Spectrometry; Stable Water Isotopes", "people": "Kurbatov, Andrei V.; Mayewski, Paul A.; Introne, Douglas; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601128"}, {"dataset_uid": "601129", "doi": "10.15784/601129", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Isotope Data; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Kurbatov, Andrei V.; Mayewski, Paul A.; Introne, Douglas; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601129"}, {"dataset_uid": "601130", "doi": "10.15784/601130", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Delta Deuterium; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Gas Records; Ice Core Records; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Introne, Douglas; Kurbatov, Andrei V.; Mayewski, Paul A.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601130"}, {"dataset_uid": "601483", "doi": "10.15784/601483", "keywords": "Allan Hills; Antarctica; Argon; Ice; Ice Core Data; Ice Core Gas Records; Isotope; Mass Spectrometry; Nitrogen; Oxygen", "people": "Higgins, John; Bender, Michael; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601483"}, {"dataset_uid": "601863", "doi": null, "keywords": "Allan Hills; Antarctica; Cryosphere; Isotope Data", "people": "Higgins, John; Severinghaus, Jeffrey P.; Introne, Douglas; Mayewski, Paul A.; Brook, Edward; Kurbatov, Andrei V.", "repository": "USAP-DC", "science_program": "COLDEX", "title": "Allan Hills ice water stable isotope record for dD, d18O", "url": "https://www.usap-dc.org/view/dataset/601863"}, {"dataset_uid": "601863", "doi": null, "keywords": "Allan Hills; Antarctica; Cryosphere; Isotope Data", "people": "Kurbatov, Andrei V.; Mayewski, Paul A.; Brook, Edward; Introne, Douglas; Higgins, John; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Allan Hills ice water stable isotope record for dD, d18O", "url": "https://www.usap-dc.org/view/dataset/601863"}, {"dataset_uid": "601512", "doi": "10.15784/601512", "keywords": "Allan Hills; Antarctica; Blue Ice; Ice Core; Ice Core Gas Records; Isotope; Nitrogen; Oxygen", "people": "Yan, Yuzhen; Higgins, John; Bender, Michael", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable isotope composition of the trapped air in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601512"}, {"dataset_uid": "601425", "doi": "10.15784/601425", "keywords": "Allan Hills; Antarctica; Blue Ice; Carbon Dioxide; Ice Core; Methane", "people": "Brook, Edward J.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Greenhouse gas composition in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601425"}, {"dataset_uid": "601202", "doi": "10.15784/601202", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Carbon Dioxide; Carbon Isotopes; Chemistry:ice; Chemistry:Ice; CO2; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Data; Ice Core Gas Records; Ice Core Records; Mass Spectrometer; Mass Spectrometry; Methane; Snow/ice; Snow/Ice", "people": "Brook, Edward J.; Bender, Michael; Yan, Yuzhen; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601202"}], "date_created": "Thu, 18 Oct 2018 00:00:00 GMT", "description": "Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800,000 years. Previous field expeditions to the Allan Hills blue ice area, Antarctica, have recovered ice cores that date to one million years, the oldest ice cores yet recovered from Antarctica. These records have revealed that interglacial CO2 concentrations decreased by 800,000 years ago and that, in the warmer world 1 million years ago, CO2 and Antarctic temperature were linked as during the last 800,000 years. This project will return to the Allan Hills blue ice area to recover additional ice cores that date to 1 million years or older. The climate records developed from the drilled ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Our results will help answer questions about issues associated with anthropogenic change. These include the relationship between temperature change and the mass balance of Antarctic ice; precipitation and aridity variations associated with radiatively forced climate change; and the climate significance of sea ice extent. The project will entrain two graduate students and a postdoctoral scholar, and will conduct outreach including workshops to engage teachers in carbon science and ice cores. Between about 2.8-0.9 million years ago, Earth\u0027s climate was characterized by 40,000-year cycles, driven or paced by changes in the tilt of Earth\u0027s spin axis. Much is known about the \"40,000-year\" world from studies of deep-sea sediments, but our understanding of climate change during this period is incomplete because we lack records of Antarctic climate and direct records of atmospheric greenhouse gas concentrations. We propose to address these issues by building on our recent studies of ancient ice from the Main Ice Field, Allan Hills, Antarctica. During previous field seasons we recovered ice extending, discontinuously, from 0.1-1.0 million years old. Ice was dated by measuring the 40Ar/38Ar (Argon) ratio of the trapped gases. Our discovery of million year-old ice demonstrates that there is gas-record-quality ice from the 40,000-year world in the Allan Hills Main Ice Field. We have identified two different sites, each overlying bedrock at ~ 200 m depth, that are attractive targets for coring ice dating to 1 million years and older. This project aims to core the ice at these two sites, re-occupy a previous site with million year-old ice and drill it down to the bedrock, and generate 10-20 short (~10-meter) cores in areas where our previous work and terrestrial meteorite ages suggest ancient surface ice. We plan to date the ice using the 40Ar/38Ar ages of trapped Argon. We also plan to characterize the continuity of our cores by measuring the deuterium and oxygen isotope ratios in the ice, methane, ratios of Oxygen and Argon to Nitrogen in trapped gas, the Nitrogen-15 isotope (d15N) of Nitrogen, and the Oxygen-18 isotope (d18O) of Oxygen. As the ice may be stratigraphically disturbed, these measurements will provide diagnostic properties for assessing the continuity of the ice-core records. Successful retrieval of ice older than one million years will provide the opportunity for follow-up work to measure the CO2 concentration and other properties within the ice to inform on the temperature history of the Allan Hills region, dust sources and source-area aridity, moisture sources, densification conditions, global average ocean temperature, and greenhouse gas concentrations. We will analyze the data in the context of leading hypotheses of the 40,000-year world and the Mid-Pleistocene Transition to the 100,000-year world. We expect to advance understanding of climate dynamics during these periods.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Amd/Us; AMD; Allan Hills; USA/NSF; FIELD INVESTIGATION; USAP-DC; Ice Core; LABORATORY", "locations": "Allan Hills", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Mayewski, Paul A.; Kurbatov, Andrei V.; Higgins, John; Bender, Michael", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Allan Hills", "south": null, "title": "Collaborative Research: Window into the World with 40,000-year Glacial Cycles from Climate Records in Million Year-old Ice from the Allan Hills Blue Ice Area", "uid": "p0000760", "west": null}, {"awards": "1141978 Foreman, Christine", "bounds_geometry": "POLYGON((160 -76,160.1 -76,160.2 -76,160.3 -76,160.4 -76,160.5 -76,160.6 -76,160.7 -76,160.8 -76,160.9 -76,161 -76,161 -76.1,161 -76.2,161 -76.3,161 -76.4,161 -76.5,161 -76.6,161 -76.7,161 -76.8,161 -76.9,161 -77,160.9 -77,160.8 -77,160.7 -77,160.6 -77,160.5 -77,160.4 -77,160.3 -77,160.2 -77,160.1 -77,160 -77,160 -76.9,160 -76.8,160 -76.7,160 -76.6,160 -76.5,160 -76.4,160 -76.3,160 -76.2,160 -76.1,160 -76))", "dataset_titles": "FT-ICR MS Metadata; Respiration Metadata; UPLC-Q-TOF data of Cotton Glacier exometabolites", "datasets": [{"dataset_uid": "601089", "doi": "10.15784/601089", "keywords": "Antarctica; Biota; Exometabolites; Mass Spectrometry; Microbes; Microbiology", "people": "Bothner, Brian; Foreman, Christine; Tigges, Michelle", "repository": "USAP-DC", "science_program": null, "title": "UPLC-Q-TOF data of Cotton Glacier exometabolites", "url": "https://www.usap-dc.org/view/dataset/601089"}, {"dataset_uid": "601077", "doi": "10.15784/601077", "keywords": "Antarctica; Biota; Chemistry:fluid; Chemistry:Fluid; Fluorescence Spectroscopy; Mass Spectrometry", "people": "Foreman, Christine; D\u0027Andrilli, Juliana", "repository": "USAP-DC", "science_program": null, "title": "FT-ICR MS Metadata", "url": "https://www.usap-dc.org/view/dataset/601077"}, {"dataset_uid": "601076", "doi": "10.15784/601076", "keywords": "Antarctica; Biota; Chemistry:fluid; Chemistry:Fluid; Fluorescence Spectroscopy; Mass Spectrometry", "people": "Smith, Heidi; Foreman, Christine", "repository": "USAP-DC", "science_program": null, "title": "Respiration Metadata", "url": "https://www.usap-dc.org/view/dataset/601076"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "Uncovering the dynamics of dissolved organic matter (DOM) is central to an understanding of the global carbon cycle, as organic material from lakes, streams, oceans and soils passes through this pool. DOM acts as a key energy source for microbes in many ecosystems and therefore can affect regional nutrient cycling patterns. For example, preliminary results suggest that organisms isolated from a supraglacial stream on Cotton Glacier, Antarctica, may be important in DOM cycling in this relatively simple, low temperature system. However, little is known about the functional attributes of the microbes that interact with DOM in the environment. This project will use state-of-the-art genomics, proteomics and metabolomics approaches to understand the mechanisms by which two microbial isolates, CG3 and CG9_1, affect DOM cycling. Liquid chromatography-mass spectrometry will also be used to better characterize the microbially-derived DOM from this ecosystem. This project will support the research and training of one undergraduate and two graduate students. Results will be widely disseminated through publications as well as through presentations at national and international meetings. In addition, raw data will be made available through open-access databases. Understanding the relationship between cold-adapted microbial metabolisms and DOM pools is important as more than 90% of the Earth?s oceans are below 5 degrees Celsius.", "east": 161.0, "geometry": "POINT(160.5 -76.5)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -76.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Foreman, Christine; Bothner, Brian", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.0, "title": "Multidimensional \"omics\" characterization of microbial metabolism and dissolved organic matter in Antarctica", "uid": "p0000408", "west": 160.0}, {"awards": "0738975 Baker, Ian", "bounds_geometry": null, "dataset_titles": "Siple Dome A (SDMA) Grain Orientation 640 - 790 Meters", "datasets": [{"dataset_uid": "609526", "doi": "10.7265/N53T9F5X", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Sample/collection Description; Sample/Collection Description; Siple Dome; Siple Dome Ice Core; South Pole; WAISCORES", "people": "Obbard, Rachel; Sieg, Katherine; Baker, Ian", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Siple Dome A (SDMA) Grain Orientation 640 - 790 Meters", "url": "https://www.usap-dc.org/view/dataset/609526"}], "date_created": "Mon, 26 Nov 2012 00:00:00 GMT", "description": "This award supports a project to fully characterize the microstructure in ice cores, in particular the microstructural locations of impurities, grain orientations and strain gradients. This work will complement the optical observations, electrical conductivity measurement, and precise, detailed measurements of the soluble ion and gas contents that are performed by others. Linking the concentrations of soluble ions and gases, measured to a few parts per billion, to the optically determined annual layer structure and the stable isotope data in ice cores has enabled a great deal to be established about the concentrations and depth/age distributions of particles, trace gases and impurities for several polar ice cores. Ice core studies carried out by several groups contribute immensely to our understanding of paleoclimate and, to our ability to predict future climate change. The work will build on previous measurements and technique development in this area, as well as focusing on new techniques to characterize ice cores. The work will use both scanning electron microscopy (SEM) coupled with X-ray energy dispersive spectroscopy (EDS) and confocal scanning optical microscopy coupled with Raman spectroscopy (RS) to determine the microstructural locations of impurities and correlate this information with depth/age, and impurity type and concentration for several polar ice cores. The Broader Impacts of the proposed work are that knowledge of the location of impurities coupled with the grain orientation (both c- and a-axis) and grain misorientation information will allow paleoclimatologists to better interpret ice core data and other scientists to understand and model the physical and mechanical properties of natural ice sheets. Other Broader Impacts of the work are that the work will be performed and lead to the education of a Ph.D. student. At the end of the project, as well as the knowledge gained from coursework, the graduate student will have experience in ice core specimen preparation and characterization using scanning electron microscopy, x-ray microanalysis, confocal scanning microscopy, Raman spectroscopy and ion chromatography. Results from the research will be published in refereed journals, presented at conferences, and placed on a web page.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES", "is_usap_dc": true, "keywords": "FEI Xl30 Environmental Scanning Electron Microscope - Field Emission Gun (esem - Feg); LABORATORY; Electron Backscatter Diffraction", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Obbard, Rachel; Sieg, Katherine", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Advanced Microstructural Characterization of Polar Ice Cores", "uid": "p0000178", "west": null}, {"awards": "0739766 Brook, Edward J.", "bounds_geometry": "POINT(-112.08 -79.47)", "dataset_titles": "WAIS Divide Ice Core CO2", "datasets": [{"dataset_uid": "609651", "doi": "10.7265/N5DV1GTZ", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Brook, Edward J.; Marcott, Shaun", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Ice Core CO2", "url": "https://www.usap-dc.org/view/dataset/609651"}], "date_created": "Wed, 30 May 2012 00:00:00 GMT", "description": "Brook 0739766\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to create a 25,000-year high-resolution record of atmospheric CO2 from the WAIS Divide ice core. The site has high ice accumulation rate, relatively cold temperatures, and annual layering that should be preserved back to 40,000 years, all prerequisite for preserving a high quality, well-dated CO2 record. The new record will be used to examine relationships between Antarctic climate, Northern Hemisphere climate, and atmospheric CO2 on glacial-interglacial to centennial time scales, at unprecedented temporal resolution. The intellectual merit of the proposed work is simply that CO2 is the most important greenhouse gas that humans directly impact, and understanding the sources, sinks, and controls of atmospheric CO2 is a major goal for the global scientific community. Accurate chronology and detailed records are primary requirements for developing and testing models that explain and predict CO2 variability. The proposed work has several broader impacts. It contributes to the training of a post-doctoral researcher, who will transfer to a research faculty position during the award period and who will participate in graduate teaching and guest lecture in undergraduate courses. An undergraduate researcher will gain valuable lab training and conduct independent research. Bringing the results of\u003cbr/\u003ethe proposed work to the classroom will enrich courses taught by the PI. Outreach efforts will expose pre-college students to ice core research. The proposed work will enhance the laboratory facilities for ice core research at OSU, insuring that the capability for CO2 measurements exists for future projects. All data will be archived at the National Snow and Ice Data Center and other similar archives, per OPP policy. Highly significant results will be disseminated to the news media through OSU?s very effective News and Communications group. Carbon dioxide is the most important greenhouse gas that humans are directly changing. Understanding how CO2 and climate are linked on all time scales is necessary for predicting the future behavior of the carbon cycle and climate system, primarily to insure that the appropriate processes are represented in carbon cycle/climate models. Part of the proposed work emphasizes the relationship of CO2 and abrupt climate change. Understanding how future abrupt change might impact the carbon cycle is an important issue for society.", "east": -112.08, "geometry": "POINT(-112.08 -79.47)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Carbon Dioxide; FIELD INVESTIGATION; CO2; Wais Divide-project; Ice Core; Antarctica; Climate; Gas Chromatography; Antarctic Ice Core; LABORATORY", "locations": "Antarctica", "north": -79.47, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Marcott, Shaun; Ahn, Jinho; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.47, "title": "Atmospheric Carbon Dioxide and Climate Change: The WAIS Divide Ice Core Record", "uid": "p0000044", "west": -112.08}, {"awards": "0739598 Aydin, Murat; 0739491 Sowers, Todd", "bounds_geometry": null, "dataset_titles": "Alkanes in Firn Air Samples, Antarctica and Greenland; Methane Isotopes in South Pole Firn Air, 2008", "datasets": [{"dataset_uid": "609504", "doi": "10.7265/N5X9287C", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Snow/ice; Snow/Ice; South Pole; WAIS Divide", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Alkanes in Firn Air Samples, Antarctica and Greenland", "url": "https://www.usap-dc.org/view/dataset/609504"}, {"dataset_uid": "609502", "doi": "10.7265/N55T3HFP", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Isotope; Paleoclimate; Snow/ice; Snow/Ice; South Pole", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": null, "title": "Methane Isotopes in South Pole Firn Air, 2008", "url": "https://www.usap-dc.org/view/dataset/609502"}], "date_created": "Thu, 18 Aug 2011 00:00:00 GMT", "description": "This award supports a project to make measurements of methane and other trace gases in firn air collected at South Pole, Antarctica. The analyses will include: methane isotopes (delta-13CH4 and delta-DCH4), light non-methane hydrocarbons (ethane, propane, and n-butane), sulfur gases (COS, CS2), and methyl halides (CH3Cl and CH3Br). The atmospheric burdens of these trace gases reflect changes in atmospheric OH, biomass burning, biogenic activity in terrestrial, oceanic, and wetland ecosystems, and industrial/agricultural activity. The goal of this project is to develop atmospheric histories for these trace gases over the last century through examination of depth profiles of these gases in South Pole firn air. The project will involve two phases: 1) a field campaign at South Pole, Antarctica to drill two firn holes and fill a total of ~200 flasks from depths reaching 120 m, 2) analysis of firn air at University of California, Irvine, Penn State University, and several other collaborating laboratories. Atmospheric histories will be inferred from the measurements using a one dimensional advective/diffusive model of firn air transport. This study will provide new information about the recent changes in atmospheric levels of these gases, providing about a 90 year long time series record that connects the earlier surface and firn air measurements to present day. The project will also explore the possibility of in- situ production of light non-methane hydrocarbons in firn air that is relevant to the interpretation of ice core records. The broader impacts of this research are that it has the potential for significant societal impact by improving our understanding of climate change and man\u0027s input to the atmosphere. The results of this work will be disseminated through the peer review process, and will contribute to environmental assessments, such as the Inter-governmental Panel on Climate Change (IPCC) Climate Assessment and the Word Meteorological Organization (WMO) Stratospheric Ozone Assessment. This research will provide educational opportunities for graduate and undergraduate students, and will contribute to a teacher training program for K-12 teachers in minority school districts.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS", "is_usap_dc": true, "keywords": "FIELD INVESTIGATION; Isotope; Firn Air Chemistry; Firn Air Isotope Measurements; Not provided; LABORATORY; South Pole; Firn; Delta 13C; Carbon-13; Mass Spectrometer; Deuterium; Mass Spectrometry; Firn Air Samples; Carbon; Gas Chromatography; Polar Firn Air; GROUND-BASED OBSERVATIONS; Methane; Antarctica; Firn Air Isotopes; Delta Deuterium; FIELD SURVEYS; Firn Air; Chromatography; Methane Isotopes; Carbon Isotopes; Stable Isotopes", "locations": "Antarctica; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat; Saltzman, Eric; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air", "uid": "p0000162", "west": null}, {"awards": "0636953 Saltzman, Eric", "bounds_geometry": "POINT(-148.82 -81.66)", "dataset_titles": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core; Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core; Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core; Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica; Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "datasets": [{"dataset_uid": "609598", "doi": "10.7265/N5X0650D", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609598"}, {"dataset_uid": "609356", "doi": "10.7265/N56W9807", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Saltzman, Eric; Williams, Margaret; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609356"}, {"dataset_uid": "609600", "doi": "10.7265/N5PG1PPB", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609600"}, {"dataset_uid": "601361", "doi": "10.15784/601361", "keywords": "Antarctica; Carbonyl Sulfide; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/601361"}, {"dataset_uid": "609599", "doi": "10.7265/N5S75D8P", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609599"}], "date_created": "Wed, 22 Oct 2008 00:00:00 GMT", "description": "Saltzman/0636953\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to measure methyl chloride, methyl bromide, and carbonyl sulfide in air extracted from Antarctic ice cores. Previous measurements in firn air and shallow ice cores suggest that the ice archive contains paleo-atmospheric signals for these gases. The goal of this study is to extend these records throughout the Holocene and into the last Glacial period to examine the behavior of these trace gases over longer time scales and a wider range of climatic conditions. These studies are exploratory, and both the stability of these trace gases and the extent to which they may be impacted by in situ processes will be assessed. This project will involve sampling and analyzing archived ice core samples from the Siple Dome, Taylor Dome, Byrd, and Vostok ice cores. The ice core samples will be analyzed by dry extraction, with gas chromatography/mass spectrometry with isotope dilution. The ice core measurements will generate new information about the range of natural variability of these trace gases in the atmosphere. The intellectual merit of this project is that this work will provide an improved basis for assessing the impact of anthropogenic activities on biogeochemical cycles, and new insight into the climatic sensitivity of the biogeochemical processes controlling atmospheric composition. The broader impact of this project is that there is a strong societal interest in understanding how man\u0027s activities impact the atmosphere, and how atmospheric chemistry may be altered by future climate change. The results of this study will contribute to the development of scenarios used for future projections of stratospheric ozone and climate change. In terms of human development, this project will support the doctoral dissertation of a graduate student in Earth System Science, and undergraduate research on polar ice core chemistry. This project will also contribute to the development of an Earth Sciences teacher training curriculum for high school teachers in the Orange County school system in collaboration with an established, NSF-sponsored Math and Science Partnership program (FOCUS).", "east": -148.82, "geometry": "POINT(-148.82 -81.66)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Methyl Bromide; Antarctic; Ice Core Gas Records; Ice Core Data; Carbonyl Sulfide; Methyl Chloride; Antarctic Ice Sheet; Siple Dome; Trace Gases; Ice Core Chemistry; Biogeochemical; Atmospheric Chemistry; West Antarctic Ice Sheet; LABORATORY; Ice Core; West Antarctica", "locations": "Antarctic; Antarctica; Antarctic Ice Sheet; Siple Dome; West Antarctica; West Antarctic Ice Sheet", "north": -81.66, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core; Siple Dome Ice Core", "south": -81.66, "title": "Methyl Chloride, Methyl Bromide, and Carbonyl Sulfide in Deep Antarctic Ice Cores", "uid": "p0000042", "west": -148.82}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}, {"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Williams, Margaret; Tatum, Cheryl; Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; Carbonyl Sulfide; Siple Coast; Chloride; Trapped Gases; Snow; Ice Core Chemistry; Chromatography; Siple; GROUND STATIONS; Atmospheric Gases; Ozone Depletion; AWS Siple; Ice Sheet; Ice Core Data; Antarctica; Glaciology; West Antarctica; Atmospheric Chemistry; Ice Core; Stratigraphy; LABORATORY; Methane; Mass Spectrometer; GROUND-BASED OBSERVATIONS; WAISCORES; Msa; Mass Spectrometry; Not provided; Siple Dome; Gas Measurement", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica; Siple", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}]

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