USAP-DC

{"dp_type": "Project", "free_text": "Methane Concentration"}

[{"awards": "1744993 Higgins, John; 1745007 Mayewski, Paul; 1745006 Brook, Edward J.; 1744832 Severinghaus, Jeffrey; 0838843 Kurbatov, Andrei", "bounds_geometry": "POLYGON((159.16667 -76.66667,159.19167 -76.66667,159.21667 -76.66667,159.24167 -76.66667,159.26667 -76.66667,159.29167 -76.66667,159.31667 -76.66667,159.34167 -76.66667,159.36667 -76.66667,159.39167 -76.66667,159.41667 -76.66667,159.41667 -76.673336,159.41667 -76.680002,159.41667 -76.686668,159.41667 -76.693334,159.41667 -76.7,159.41667 -76.706666,159.41667 -76.713332,159.41667 -76.719998,159.41667 -76.726664,159.41667 -76.73333,159.39167 -76.73333,159.36667 -76.73333,159.34167 -76.73333,159.31667 -76.73333,159.29167 -76.73333,159.26667 -76.73333,159.24167 -76.73333,159.21667 -76.73333,159.19167 -76.73333,159.16667 -76.73333,159.16667 -76.726664,159.16667 -76.719998,159.16667 -76.713332,159.16667 -76.706666,159.16667 -76.7,159.16667 -76.693334,159.16667 -76.686668,159.16667 -76.680002,159.16667 -76.673336,159.16667 -76.66667))", "dataset_titles": "Allan Hills 2022-23 Shallow Ice Core Field Report; Allan Hills CMC3 ice core d18Oatm, d15N, dO2/N2, dAr/N2, d40/36Ar, d40/38Ar 2021 \u0026 2022; Allan Hills Stable Water Isotopes; CO2 and CH4 from Allan Hills ice cores ALHIC1901, 1902, and 1903; Heavy noble gases (Ar/Xe/Kr) from ALHIC1901, 1902, and 1903; I-165-M GPR Field Report 2019-2020; MOT data (Xe/Kr) from Allan Hills ice cores ALHIC1901, 1902, and 1903; Snapshot record of CO2 and CH4 from the Allan Hills, Antarctica, ranging from 400,000 to 3 million years old", "datasets": [{"dataset_uid": "609541", "doi": "10.7265/N5NP22DF", "keywords": "Allan Hills; Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Isotope", "people": "Spaulding, Nicole; Kurbatov, Andrei V.; Introne, Douglas; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Allan Hills Stable Water Isotopes", "url": "https://www.usap-dc.org/view/dataset/609541"}, {"dataset_uid": "601878", "doi": "10.15784/601878", "keywords": "Allan Hills; Antarctica; Blue Ice; Carbon Dioxide; Cryosphere; Methane", "people": "Shackleton, Sarah; Severinghaus, Jeffrey P.; Hishamunda, Valens; Kalk, Michael; Brook, Edward; Marks Peterson, Julia", "repository": "USAP-DC", "science_program": "COLDEX", "title": "Snapshot record of CO2 and CH4 from the Allan Hills, Antarctica, ranging from 400,000 to 3 million years old", "url": "https://www.usap-dc.org/view/dataset/601878"}, {"dataset_uid": "601620", "doi": "10.15784/601620", "keywords": "18O; Allan Hills; Allan Hills Blue Ice; Antarctica; Blue Ice; Delta 15N; Delta 18O; Dole Effect; Firn Thickness; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Chronology; Ice Core Records", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Allan Hills CMC3 ice core d18Oatm, d15N, dO2/N2, dAr/N2, d40/36Ar, d40/38Ar 2021 \u0026 2022", "url": "https://www.usap-dc.org/view/dataset/601620"}, {"dataset_uid": "601895", "doi": "10.15784/601895", "keywords": "Allan Hills; Antarctica; Cryosphere; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Noble Gas", "people": "Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Heavy noble gases (Ar/Xe/Kr) from ALHIC1901, 1902, and 1903", "url": "https://www.usap-dc.org/view/dataset/601895"}, {"dataset_uid": "601896", "doi": "10.15784/601896", "keywords": "Allan Hills; Antarctica; Ch4; CO2; Cryosphere; Glaciology; Glaciology; Ice Core Data; Ice Core Records", "people": "Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "CO2 and CH4 from Allan Hills ice cores ALHIC1901, 1902, and 1903", "url": "https://www.usap-dc.org/view/dataset/601896"}, {"dataset_uid": "601897", "doi": "10.15784/601897", "keywords": "Allan Hills; Antarctica; Cryosphere; Glaciology; Ice Core Data; MOT; Ocean Temperature; Paleoclimate; Xe/Kr", "people": "Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "MOT data (Xe/Kr) from Allan Hills ice cores ALHIC1901, 1902, and 1903", "url": "https://www.usap-dc.org/view/dataset/601897"}, {"dataset_uid": "601696", "doi": "10.15784/601696", "keywords": "Allan Hills; Antarctica; Ice Core", "people": "Shackleton, Sarah; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Allan Hills 2022-23 Shallow Ice Core Field Report", "url": "https://www.usap-dc.org/view/dataset/601696"}, {"dataset_uid": "601669", "doi": "10.15784/601669", "keywords": "Allan Hills; Antarctica; GPR; Ice Core; Report", "people": "Nesbitt, Ian; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "I-165-M GPR Field Report 2019-2020", "url": "https://www.usap-dc.org/view/dataset/601669"}], "date_created": "Fri, 27 Aug 2021 00:00:00 GMT", "description": "Bubbles of ancient air trapped in ice cores have been used to directly reconstruct atmospheric composition, and its links to Antarctic and global climate, over the last 800,000 years. Previous field expeditions to the Allan Hills Blue Ice Area, Antarctica, have recovered ice cores that extend as far back as 2.7 million years, by far the oldest polar ice samples yet recovered. These ice cores extend direct observations of atmospheric carbon dioxide and methane concentrations and indirect records of Antarctic climate into a period of Earth\u0027s climate history that represents a plausible geologic analogue to future anthropogenic climate change. The results demonstrate a smaller glacial-interglacial variability of climate and greenhouse gases, and a persistent linkage between Antarctic climate and atmospheric carbon dioxide, between 1 and 2 million years ago. Through this project, the team will return to the Allan Hills Blue Ice Area to recover additional ice cores that date to 2 million years or older. The climate records developed from these ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Project results will help answer questions about issues associated with anthropogenic change including the relationship between temperature change and the mass balance of Antarctic ice and the relationship between atmospheric greenhouse gases and global climate change. Earth has been cooling, and ice sheets expanding, over the past ~52 million years. Superimposed on this cooling are periodic changes in Earth\u0027s climate system driven by variations in the eccentricity, precession, and obliquity of Earth\u0027s orbit around the Sun. Climate reconstructions based on measurements of oxygen isotopes in foraminiferal calcite indicate that, from ~2.8 to 1.2 million years before present (Ma), Earth\u0027s climate system oscillated between glacial and interglacial states every ~40,000 years (the \"40k world\"). Between 1.2-0.8 Ma and continuing to the present, the period of glacial cycles increased in amplitude and lengthened to ~100,000 years (the \"100k world\"). Ice cores preserve ancient air that allows direct reconstructions of atmospheric carbon dioxide and methane. They also archive proxy records of regional climate, mean ocean temperature, global oxygen cycling, and the aridity of nearby continents. Studies of stratigraphically continuous ice cores, extending to 800,000 years before present, have demonstrated that atmospheric carbon dioxide is strongly linked to climate, and it is of great interest to extend the ice-core record into the 40k world. Recent discoveries of well-preserved ice dating from 1.0 to 2.7 Ma from ice cores drilled in the Allan Hills Blue Ice Area (BIA), Antarctica, demonstrate the potential to retrieve stratigraphically discontinuous old ice at shallow depths (\u003c200 meters). This project will continue this work by retrieving new large-volume ice cores and measuring paleoclimate properties in both new and existing ice from the Allan Hills BIA. The experimental objectives are to more fully characterize fundamental properties of the climate system and the carbon cycle during the 40k world. Project results will have implications for Pleistocene climate change, and will provide new constraints on the processes that regulate atmospheric carbon dioxide, methane, and oxygen on geologic timescales. Given a demonstrated age of the ice at the Allan Hills BIA of at least 2 million years, the team will drill additional cores to prospect for ice that predates the initiation of Northern Hemisphere glaciation at the Plio-Pleistocene transition (~2.8 Ma). This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 159.41667, "geometry": "POINT(159.29167 -76.7)", "instruments": null, "is_usap_dc": true, "keywords": "AMD; USAP-DC; SNOW/ICE; Allan Hills; FIELD SURVEYS; USA/NSF; Amd/Us; LABORATORY", "locations": "Allan Hills", "north": -76.66667, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Mayewski, Paul A.; Kurbatov, Andrei V.; Brook, Edward J.; Severinghaus, Jeffrey P.; Higgins, John", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Allan Hills", "south": -76.73333, "title": "Collaborative research: Snapshots of Early and Mid-Pleistocene Climate and Atmospheric Composition from the Allan Hills Blue Ice Area ", "uid": "p0010253", "west": 159.16667}, {"awards": "1643722 Brook, Edward J.", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole Ice Core Methane Data and Gas Age Time Scale; South Pole ice core (SPC14) total air content (TAC)", "datasets": [{"dataset_uid": "601546", "doi": "10.15784/601546", "keywords": "Antarctica; South Pole", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) total air content (TAC)", "url": "https://www.usap-dc.org/view/dataset/601546"}, {"dataset_uid": "601329", "doi": "10.15784/601329", "keywords": "Antarctica; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; South Pole", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Methane Data and Gas Age Time Scale", "url": "https://www.usap-dc.org/view/dataset/601329"}], "date_created": "Tue, 02 Jun 2020 00:00:00 GMT", "description": "Brook/1643722 This award supports a project to measure the concentration of the gas methane in air trapped in an ice core collected from the South Pole. The data will provide an age scale (age as a function of depth) by matching the South Pole methane changes with similar data from other ice cores for which the age vs. depth relationship is well known. The ages provided will allow all other gas measurements made on the South Pole core (by the PI and other NSF supported investigators) to be interpreted accurately as a function of time. This is critical because a major goal of the South Pole coring project is to understand the history of rare gases in the atmosphere like carbon monoxide, carbon dioxide, ethane, propane, methyl chloride, and methyl bromide. Relatively little is known about what controls these gases in the atmosphere despite their importance to atmospheric chemistry and climate. Undergraduate assistants will work on the project and be introduced to independent research through their work. The PI will continue visits to local middle schools to introduce students to polar science, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) as part of the project. Methane concentrations from a major portion (2 depth intervals, excluding the brittle ice-zone which is being measured at Penn State University) of the new South Pole ice core will be used to create a gas chronology by matching the new South Pole ice core record with that from the well-dated WAIS Divide ice core record. In combination with measurements made at Penn State, this will provide gas dating for the entire 50,000-year record. Correlation will be made using a simple but powerful mid-point method that has been previously demonstrated, and other methods of matching records will be explored. The intellectual merit of this work is that the gas chronology will be a fundamental component of this ice core project, and will be used by the PI and other investigators for dating records of atmospheric composition, and determining the gas age-ice age difference independently of glaciological models, which will constrain processes that affected firn densification in the past. The methane data will also provide direct stratigraphic markers of important perturbations to global biogeochemical cycles (e.g., rapid methane variations synchronous with abrupt warming and cooling in the Northern Hemisphere) that will tie other ice core gas records directly to those perturbations. A record of the total air content will also be produced as a by-product of the methane measurements and will contribute to understanding of this parameter. The broader impacts include that the work will provide a fundamental data set for the South Pole ice core project and the age scale (or variants of it) will be used by all other investigators working on gas records from the core. The project will employ an undergraduate assistant(s) in both years who will conduct an undergraduate research project which will be part of the student\u0027s senior thesis or other research paper. The project will also offer at least one research position for the Oregon State University Summer REU site program. Visits to local middle schools, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) will also be part of the project.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "AMD; LABORATORY; METHANE; ICE CORE RECORDS; Gas Chromatography; South Pole; USAP-DC", "locations": "South Pole", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "A High Resolution Atmospheric Methane Record from the South Pole Ice Core", "uid": "p0010102", "west": 0.0}, {"awards": "1443710 Severinghaus, Jeffrey; 1443464 Sowers, Todd; 1443472 Brook, Edward J.", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole CH4 data for termination; South Pole Ice Core Isotopes of N2 and Ar; South Pole ice core (SPC14) discrete methane data; South Pole ice core total air content; South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2; SP19 Gas Chronology", "datasets": [{"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Winski, Dominic A.; Severinghaus, Jeffrey P.; Brook, Edward J.; Epifanio, Jenna; Kennedy, Joshua A.; Ferris, David G.; Kalk, Michael; Hood, Ekaterina; Fudge, T. J.; Osterberg, Erich; Steig, Eric J.; Kahle, Emma; Sowers, Todd A.; Edwards, Jon S.; Aydin, Murat; Kreutz, Karl; Buizert, Christo", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601517", "doi": "10.15784/601517", "keywords": "Antarctica; Argon; Argon Isotopes; Firn; Firn Temperature Gradient; Firn Thickness; Gas Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Nitrogen; Nitrogen Isotopes; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.; Morgan, Jacob", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Isotopes of N2 and Ar", "url": "https://www.usap-dc.org/view/dataset/601517"}, {"dataset_uid": "601231", "doi": "10.15784/601231", "keywords": "Air Content; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core total air content", "url": "https://www.usap-dc.org/view/dataset/601231"}, {"dataset_uid": "601230", "doi": "10.15784/601230", "keywords": "Antarctica; Atmospheric CH4; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Data; Methane; Methane Concentration; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole CH4 data for termination", "url": "https://www.usap-dc.org/view/dataset/601230"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601152", "doi": "10.15784/601152", "keywords": "Antarctica; Antarctic Ice Sheet; Chemistry:gas; Chemistry:Gas; Chemistry:ice; Chemistry:Ice; Delta 18O; Dole Effect; Firn Thickness; Gas Isotopes; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Gravitational Settling; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Inert Gases; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2", "url": "https://www.usap-dc.org/view/dataset/601152"}], "date_created": "Sat, 02 Feb 2019 00:00:00 GMT", "description": "Gases trapped in ice cores have revealed astonishing things about the greenhouse gas composition of the past atmosphere, including the fact that carbon dioxide concentrations never rose above 300 parts per million during the last 800,000 years. This places today\u0027s concentration of 400 parts per million in stark contrast. Furthermore, these gas records show that natural sources of greenhouse gas such as oceans and ecosystems act as amplifiers of climate change by increasing emissions of gases during warmer periods. Such amplification is expected to occur in the future, adding to the human-produced gas burden. The South Pole ice core will build upon these prior findings by expanding the suite of gases to include, for the first time, those potent trace gases that both trapped heat and depleted ozone during the past 40,000 years. The present project on inert gases and methane in the South Pole ice core will improve the dating of this crucial record, to unprecedented precision, so that the relative timing of events can be used to learn about the mechanism of trace gas production and destruction, and consequent climate change amplification. Ultimately, this information will inform predictions of future atmospheric chemical cleansing mechanisms and climate in the context of our rapidly changing atmosphere. This award also engages young people in the excitement of discovery and polar research, helping to entrain the next generations of scientists and educators. Education of graduate students, a young researcher (Buizert), and training of technicians, will add to the nation?s human resource base. This award funds the construction of the gas chronology for the South Pole 1500m ice core, using measured inert gases (d15N and d40Ar--Nitrogen and Argon isotope ratios, respectively) and methane in combination with a next-generation firn densification model that treats the stochastic nature of air trapping and the role of impurities on densification. The project addresses fundamental gaps in scientific understanding that limit the accuracy of gas chronologies, specifically a poor knowledge of the controls on ice-core d15N and the possible role of layering and impurities in firn densification. These gaps will be addressed by studying the gas enclosure process in modern firn at the deep core site. The work will comprise the first-ever firn air pumping experiment that has tightly co-located measurements of firn structural properties on the core taken from the same borehole. The project will test the hypothesis that the lock-in horizon as defined by firn air d15N, CO2, and methane is structurally controlled by impermeable layers, which are in turn created by high-impurity content horizons in which densification is enhanced. Thermal signals will be sought using the inert gas measurements, which improve the temperature record with benefits to the firn densification modeling. Neon, argon, and oxygen will be measured in firn air and a limited number of deep core samples to test whether glacial period layering was enhanced, which could explain low observed d15N in the last glacial period. Drawing on separate volcanic and methane synchronization to well-dated ice cores to create independent ice and gas tie points, independent empirical estimates of the gas age-ice age difference will be made to check the validity of the firn densification model-inert gas approach to calculating the gas age-ice age difference. These points will also be used to test whether the anomalously low d15N seen during the last glacial period in east Antarctic ice cores is due to deep air convection in the firn, or a missing impurity dependence in the firn densification models. The increased physical understanding gained from these studies, combined with new high-precision measurements, will lead to improved accuracy of the gas chronology of the South Pole ice core, which will enhance the overall science return from this gas-oriented core. This will lead to clarification of timing of atmospheric gas variations and temperature, and aid in efforts to understand the biogeochemical feedbacks among trace gases. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. Ozone-depleting substances will be measured in the South Pole ice core record, and a precise gas chronology will add value. Lastly, by seeking a better understanding of the physics of gas entrapment, the project aims to have an impact on ice-core science in general.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "USAP-DC; AMD; LABORATORY; Antarctica; NITROGEN ISOTOPES; USA/NSF; METHANE; Amd/Us; FIELD INVESTIGATION", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Sowers, Todd A.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Inert Gas and Methane Based Climate Records throughout the South Pole Deep Ice Core", "uid": "p0010005", "west": 0.0}, {"awards": "1443306 Mayewski, Paul; 1443263 Higgins, John", "bounds_geometry": null, "dataset_titles": "Allan Hills ice water stable isotope record for dD, d18O; Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores; Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores; Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores; Greenhouse gas composition in the Allan Hills S27 ice core; Methane concentration in Allan Hills ice cores; Stable isotope composition of the trapped air in the Allan Hills S27 ice core; Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "datasets": [{"dataset_uid": "601483", "doi": "10.15784/601483", "keywords": "Allan Hills; Antarctica; Argon; Ice; Ice Core Data; Ice Core Gas Records; Isotope; Mass Spectrometry; Nitrogen; Oxygen", "people": "Higgins, John; Yan, Yuzhen; Bender, Michael", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601483"}, {"dataset_uid": "601130", "doi": "10.15784/601130", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Delta Deuterium; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Gas Records; Ice Core Records; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Yan, Yuzhen; Kurbatov, Andrei V.; Mayewski, Paul A.; Introne, Douglas", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601130"}, {"dataset_uid": "601425", "doi": "10.15784/601425", "keywords": "Allan Hills; Antarctica; Blue Ice; Carbon Dioxide; Ice Core; Methane", "people": "Brook, Edward J.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Greenhouse gas composition in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601425"}, {"dataset_uid": "601863", "doi": null, "keywords": "Allan Hills; Antarctica; Cryosphere; Isotope Data", "people": "Higgins, John; Severinghaus, Jeffrey P.; Kurbatov, Andrei V.; Mayewski, Paul A.; Brook, Edward; Introne, Douglas", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Allan Hills ice water stable isotope record for dD, d18O", "url": "https://www.usap-dc.org/view/dataset/601863"}, {"dataset_uid": "601203", "doi": "10.15784/601203", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Chemistry:ice; Chemistry:Ice; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenhouse Gas; Ice; Ice Core Data; Ice Core Gas Records; Methane; Snow/ice; Snow/Ice", "people": "Higgins, John; Yan, Yuzhen; Bender, Michael; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Methane concentration in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601203"}, {"dataset_uid": "601202", "doi": "10.15784/601202", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Carbon Dioxide; Carbon Isotopes; Chemistry:ice; Chemistry:Ice; CO2; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Data; Ice Core Gas Records; Ice Core Records; Mass Spectrometer; Mass Spectrometry; Methane; Snow/ice; Snow/Ice", "people": "Yan, Yuzhen; Bender, Michael; Brook, Edward J.; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601202"}, {"dataset_uid": "601201", "doi": "10.15784/601201", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Argon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Data; Ice Core Gas Records; Krypton; Mass Spectrometer; Noble Gas; Snow/ice; Snow/Ice; Xenon", "people": "Bender, Michael; Higgins, John; Ng, Jessica; Yan, Yuzhen; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601201"}, {"dataset_uid": "601512", "doi": "10.15784/601512", "keywords": "Allan Hills; Antarctica; Blue Ice; Ice Core; Ice Core Gas Records; Isotope; Nitrogen; Oxygen", "people": "Yan, Yuzhen; Bender, Michael; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable isotope composition of the trapped air in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601512"}, {"dataset_uid": "601863", "doi": null, "keywords": "Allan Hills; Antarctica; Cryosphere; Isotope Data", "people": "Higgins, John; Brook, Edward; Severinghaus, Jeffrey P.; Introne, Douglas; Mayewski, Paul A.; Kurbatov, Andrei V.", "repository": "USAP-DC", "science_program": "COLDEX", "title": "Allan Hills ice water stable isotope record for dD, d18O", "url": "https://www.usap-dc.org/view/dataset/601863"}, {"dataset_uid": "601128", "doi": "10.15784/601128", "keywords": "Allan Hills; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope Record; Mass Spectrometry; Stable Water Isotopes", "people": "Introne, Douglas; Kurbatov, Andrei V.; Mayewski, Paul A.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601128"}, {"dataset_uid": "601129", "doi": "10.15784/601129", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Isotope Data; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Yan, Yuzhen; Introne, Douglas; Mayewski, Paul A.; Kurbatov, Andrei V.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601129"}], "date_created": "Thu, 18 Oct 2018 00:00:00 GMT", "description": "Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800,000 years. Previous field expeditions to the Allan Hills blue ice area, Antarctica, have recovered ice cores that date to one million years, the oldest ice cores yet recovered from Antarctica. These records have revealed that interglacial CO2 concentrations decreased by 800,000 years ago and that, in the warmer world 1 million years ago, CO2 and Antarctic temperature were linked as during the last 800,000 years. This project will return to the Allan Hills blue ice area to recover additional ice cores that date to 1 million years or older. The climate records developed from the drilled ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Our results will help answer questions about issues associated with anthropogenic change. These include the relationship between temperature change and the mass balance of Antarctic ice; precipitation and aridity variations associated with radiatively forced climate change; and the climate significance of sea ice extent. The project will entrain two graduate students and a postdoctoral scholar, and will conduct outreach including workshops to engage teachers in carbon science and ice cores. Between about 2.8-0.9 million years ago, Earth\u0027s climate was characterized by 40,000-year cycles, driven or paced by changes in the tilt of Earth\u0027s spin axis. Much is known about the \"40,000-year\" world from studies of deep-sea sediments, but our understanding of climate change during this period is incomplete because we lack records of Antarctic climate and direct records of atmospheric greenhouse gas concentrations. We propose to address these issues by building on our recent studies of ancient ice from the Main Ice Field, Allan Hills, Antarctica. During previous field seasons we recovered ice extending, discontinuously, from 0.1-1.0 million years old. Ice was dated by measuring the 40Ar/38Ar (Argon) ratio of the trapped gases. Our discovery of million year-old ice demonstrates that there is gas-record-quality ice from the 40,000-year world in the Allan Hills Main Ice Field. We have identified two different sites, each overlying bedrock at ~ 200 m depth, that are attractive targets for coring ice dating to 1 million years and older. This project aims to core the ice at these two sites, re-occupy a previous site with million year-old ice and drill it down to the bedrock, and generate 10-20 short (~10-meter) cores in areas where our previous work and terrestrial meteorite ages suggest ancient surface ice. We plan to date the ice using the 40Ar/38Ar ages of trapped Argon. We also plan to characterize the continuity of our cores by measuring the deuterium and oxygen isotope ratios in the ice, methane, ratios of Oxygen and Argon to Nitrogen in trapped gas, the Nitrogen-15 isotope (d15N) of Nitrogen, and the Oxygen-18 isotope (d18O) of Oxygen. As the ice may be stratigraphically disturbed, these measurements will provide diagnostic properties for assessing the continuity of the ice-core records. Successful retrieval of ice older than one million years will provide the opportunity for follow-up work to measure the CO2 concentration and other properties within the ice to inform on the temperature history of the Allan Hills region, dust sources and source-area aridity, moisture sources, densification conditions, global average ocean temperature, and greenhouse gas concentrations. We will analyze the data in the context of leading hypotheses of the 40,000-year world and the Mid-Pleistocene Transition to the 100,000-year world. We expect to advance understanding of climate dynamics during these periods.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Amd/Us; AMD; Allan Hills; USA/NSF; FIELD INVESTIGATION; USAP-DC; Ice Core; LABORATORY", "locations": "Allan Hills", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Mayewski, Paul A.; Kurbatov, Andrei V.; Higgins, John; Bender, Michael", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Allan Hills", "south": null, "title": "Collaborative Research: Window into the World with 40,000-year Glacial Cycles from Climate Records in Million Year-old Ice from the Allan Hills Blue Ice Area", "uid": "p0000760", "west": null}, {"awards": "0839031 Severinghaus, Jeffrey; 0838936 Brook, Edward J.", "bounds_geometry": "POINT(161.75 -77.75)", "dataset_titles": "Measurements of 14C-methane for the Younger Dryas - Preboreal Transition from Taylor Glacier, Antarctica; Measurements of in situ cosmogenic 14C from Taylor Glacier, Antarctica; Taylor Glacier chemistry data and Taylor Dome TD2015 time scale; Taylor Glacier CO2 record; Taylor Glacier Gas Isotope Data", "datasets": [{"dataset_uid": "601029", "doi": "10.15784/601029", "keywords": "Antarctica; Chemistry:rock; Chemistry:Rock; Critical Zone; Geochemistry; Methane; Paleoclimate; Sample/collection Description; Sample/Collection Description; Solid Earth; Taylor Glacier; Transantarctic Mountains; Younger Dryas", "people": "Petrenko, Vasilii; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Measurements of 14C-methane for the Younger Dryas - Preboreal Transition from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601029"}, {"dataset_uid": "000158", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Taylor Glacier CO2 record", "url": "ftp://ftp.ncdc.noaa.gov/pub/data/paleo/icecore/antarctica/taylor/taylor2016d13co2.txt"}, {"dataset_uid": "601103", "doi": "10.15784/601103", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Horizontal Ice Core; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier chemistry data and Taylor Dome TD2015 time scale", "url": "https://www.usap-dc.org/view/dataset/601103"}, {"dataset_uid": "601033", "doi": "10.15784/601033", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciology; Ice Core Records; Isotope; Solid Earth; Taylor Glacier; Transantarctic Mountains", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier Gas Isotope Data", "url": "https://www.usap-dc.org/view/dataset/601033"}, {"dataset_uid": "600165", "doi": "10.15784/600165", "keywords": "Antarctica; Cosmogenic; Geochemistry; Ice Core Records; Paleoclimate; Radiocarbon; Taylor Glacier; Transantarctic Mountains", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Measurements of in situ cosmogenic 14C from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/600165"}], "date_created": "Tue, 29 Mar 2016 00:00:00 GMT", "description": "Severinghaus/0839031 \u003cbr/\u003e\u003cbr/\u003eThis award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to develop a precise gas-based chronology for an archive of large-volume samples of the ancient atmosphere, which would enable ultra-trace gas measurements that are currently precluded by sample size limitations of ice cores. The intellectual merit of the proposed work is that it will provide a critical test of the \"clathrate hypothesis\" that methane clathrates contributed to the two abrupt atmospheric methane concentration increases during the last deglaciation 15 and 11 kyr ago. This approach employs large volumes of ice (\u003e1 ton) to measure carbon-14 on past atmospheric methane across the abrupt events. Carbon-14 is an ideal discriminator of fossil sources of methane to the atmosphere, because most methane sources (e.g., wetlands, termites, biomass burning) are rich in carbon-14, whereas clathrates and other fossil sources are devoid of carbon-14. The proposed work is a logical extension to Taylor Glacier, Antarctica, of an approach pioneered at the margin of the Greenland ice sheet over the past 7 years. The Greenland work found higher-than-expected carbon-14 values, likely due in part to contaminants stemming from the high impurity content of Greenland ice and the interaction of the ice with sediments from the glacier bed. The data also pointed to the possibility of a previously unknown process, in-situ cosmogenic production of carbon-14 methane (radiomethane) in the ice matrix. Antarctic ice in Taylor Glacier is orders of magnitude cleaner than the ice at the Greenland site, and is much colder and less stratigraphically disturbed, offering the potential for a clear resolution of this puzzle and a definitive test of the cosmogenic radiomethane hypothesis. Even if cosmogenic radiomethane in ice is found, it still may be possible to reconstruct atmospheric radiomethane with a correction enabled by a detailed understanding of the process, which will be sought by co-measuring carbon-14 in carbon monoxide and carbon dioxide. The broader impacts of the proposed work are that the clathrate test may shed light on the stability of the clathrate reservoir and its potential for climate feedbacks under human-induced warming. Development of Taylor Glacier as a \"horizontal ice core\" would provide a community resource for other researchers. Education of one postdoc, one graduate student, and one undergraduate, would add to human resources. This award has field work in Antarctica.", "east": 161.75, "geometry": "POINT(161.75 -77.75)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "NOT APPLICABLE; Not provided; USAP-DC", "locations": null, "north": -77.75, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Brook, Edward J.; Severinghaus, Jeffrey P.", "platforms": "Not provided; OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "NCEI; USAP-DC", "science_programs": null, "south": -77.75, "title": "Collaborative Research: A \"Horizontal Ice Core\" for Large-Volume Samples of the Past Atmosphere, Taylor Glacier, Antarctica", "uid": "p0000099", "west": 161.75}, {"awards": "1043518 Brook, Edward J.", "bounds_geometry": "POINT(-112.08648 -79.46763)", "dataset_titles": "Continuous, Ultra-high Resolution WAIS-Divide Ice Core Methane Record 9.8-67.2 ka BP; Early Holocene methane records from Siple Dome, Antarctica; Methan record", "datasets": [{"dataset_uid": "609628", "doi": "10.7265/N5JM27K4", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Rhodes, Rachel; Brook, Edward J.; McConnell, Joseph", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Continuous, Ultra-high Resolution WAIS-Divide Ice Core Methane Record 9.8-67.2 ka BP", "url": "https://www.usap-dc.org/view/dataset/609628"}, {"dataset_uid": "601055", "doi": "10.15784/601055", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Yang, Ji-Woong; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Early Holocene methane records from Siple Dome, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601055"}, {"dataset_uid": "601055", "doi": "10.15784/601055", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Ahn, Jinho; Yang, Ji-Woong", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Early Holocene methane records from Siple Dome, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601055"}, {"dataset_uid": "000176", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Methan record", "url": "https://www.ncdc.noaa.gov/data-access/paleoclimatology-data/datasets/ice-core"}], "date_created": "Tue, 12 Jan 2016 00:00:00 GMT", "description": "1043500/Sowers This award supports a project to develop a 50 yr resolution methane data set that will play a pivotal role in developing the WAIS Divide timescale as well as providing a common stratigraphic framework for comparing climate records from Greenland and West Antarctica. Even higher resolution data are proposed for key intervals to assist in precisely defining the phasing of abrupt climate change between the hemispheres. Concurrent analysis of a suit of samples from both the WAIS Divide and GISP-2 cores throughout the last 110,000 years is also proposed, to establish the interpolar methan (CH4) gradient that will be used to identify geographic areas responsible for the climate related methane emission changes. The intellectual merit of the proposed work is that it will provide chronological control needed to examine the timing of changes in climate proxies, and critical chronological ties to the Greenland ice core records via methane variations. One main objective is to understand the interpolar timing of millennial-scale climate change. This is an important scientific goal relevant to understanding climate change mechanisms in general. The proposed work will help establish a chronological framework for addressing these issues. In addition, this proposal addresses the question of what methane sources were active during the ice age, through the work on the interpolar methane gradient. This work is directed at the fundamental question of what part of the biosphere controlled past methane variations, and is important for developing more sophisticated understanding of those variations. The broader impacts of the work are that the ultra-high resolution CH4 record will directly benefit all ice core paleoclimate research and the chronological refinements will impact paleoclimate studies that rely on ice core timescales for correlation purposes. The project will support both graduate and undergraduate students and the PIs will participate in outreach to the public.", "east": -112.08648, "geometry": "POINT(-112.08648 -79.46763)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e INFRARED LASER SPECTROSCOPY", "is_usap_dc": true, "keywords": "WAIS Divide; Not provided; LABORATORY; Wais Divide-project; Methane Concentration", "locations": "WAIS Divide", "north": -79.46763, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Rhodes, Rachel; Brook, Edward J.; McConnell, Joseph", "platforms": "Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "NCEI; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.46763, "title": "Collaborative Research: Completing an ultra-high resolution methane record from the WAIS Divide ice core", "uid": "p0000185", "west": -112.08648}, {"awards": "0538538 Sowers, Todd; 0538578 Brook, Edward J.", "bounds_geometry": null, "dataset_titles": "Late Holocene Methane Concentrations from WAIS Divide and GISP2; Methane Concentrations from the WAIS Divide Ice Core (WDC06A), 60 to 11,300 ybp; The Antarctic Glaciological Data Center (AGDC) at the National Snow and Ice Data Center (NSIDC) archives and distributes Antarctic glaciological and cryospheric system data collected by the U.S. Antarctic Program.", "datasets": [{"dataset_uid": "609586", "doi": "10.7265/N5W66HQQ", "keywords": "Antarctica; Arctic; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Mitchell, Logan E", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Late Holocene Methane Concentrations from WAIS Divide and GISP2", "url": "https://www.usap-dc.org/view/dataset/609586"}, {"dataset_uid": "001303", "doi": "", "keywords": null, "people": null, "repository": "NSIDC", "science_program": null, "title": "The Antarctic Glaciological Data Center (AGDC) at the National Snow and Ice Data Center (NSIDC) archives and distributes Antarctic glaciological and cryospheric system data collected by the U.S. Antarctic Program.", "url": "https://nsidc.org/data/agdc"}, {"dataset_uid": "609509", "doi": "10.7265/N5J1013R", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Methane Concentrations from the WAIS Divide Ice Core (WDC06A), 60 to 11,300 ybp", "url": "https://www.usap-dc.org/view/dataset/609509"}], "date_created": "Thu, 19 Apr 2012 00:00:00 GMT", "description": "Sowers/Brook\u003cbr/\u003e0538538\u003cbr/\u003eThis award supports a project to develop a high-resolution (every 50 yr) methane data set that will play a pivotal role in developing the timescale for the new deep ice core being drilled at the West Antarctic Ice Sheet Divide (WAIS Divde) site as well as providing a common stratigraphic framework for comparing climate records from Greenland and WAIS Divide. Certain key intervals will be measured at even higher resolution to assist in precisely defining the phasing of abrupt climate change between the northern and southern hemispheres. Concurrent analysis of a suit of samples from both the WAIS Divide and GISP2 ice cores throughout the last 110kyr is also proposed, to establish the inter-hemispheric methane gradient which will be used to identify geographic areas responsible for the climate-related methane emission changes. A large gas measurement inter-calibration of numerous laboratories, utilizing both compressed air cylinders and WAIS Divide ice core samples, will also be performed. The intellectual merit of the proposed work is that it will provide the chronological control needed to examine the timing of changes in climate proxies, and critical chronological ties to the Greenland ice core records via methane variations. In addition, the project addresses the question of what methane sources were active during the ice age and will help to answer the fundamental question of what part of the biosphere controlled past methane variations. The broader impact of the proposed work is that it will directly benefit all ice core paleoclimate research and will impact the paleoclimate studies that rely on ice core timescales for correlation purposes. The project will also support a Ph.D. student at Oregon State University who will have the opportunity to be involved in a major new ice coring effort with international elements. Undergraduates at Penn State will gain valuable laboratory experience and participate fully in the project. The proposed work will underpin the WAIS Divide chronology, which will be fundamental to all graduate student projects that involve the core. The international inter-calibration effort will strengthen ties between research institutions on four continents and will be conducted as part of the International Polar Year research agenda.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Antarctica; Ch4; West Antarctica; Wais Divide-project; GROUND-BASED OBSERVATIONS; FIELD INVESTIGATION; FIELD SURVEYS; Methane Concentration; Methane; Ice Core; WAIS Divide; Antarctic; LABORATORY", "locations": "Antarctic; WAIS Divide; Antarctica; West Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Organisms and Ecosystems", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; NOT APPLICABLE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Lee, James; Buizert, Christo; Brook, Edward J.; Mitchell, Logan E; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "NSIDC; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Collaborative Research: Constructing an Ultra-high Resolution Atmospheric Methane Record for the Last 140,000 Years from WAIS Divide Core.", "uid": "p0000025", "west": null}, {"awards": "0512971 Brook, Edward J.; 0126057 Brook, Edward J.", "bounds_geometry": null, "dataset_titles": "Antarctic and Greenland Climate Change Comparison; GISP2 (B and D Core) Methane Concentrations; GISP2 (D Core) Helium Isotopes from Interplanetary Dust; GISP2 (D Core) Methane Concentration Data; Siple Dome Methane Record", "datasets": [{"dataset_uid": "609361", "doi": "", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Lake Vostok; Paleoclimate; Vostok Ice Core", "people": "Kurz, Mark D.; Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "GISP2 (D Core) Helium Isotopes from Interplanetary Dust", "url": "https://www.usap-dc.org/view/dataset/609361"}, {"dataset_uid": "609125", "doi": "", "keywords": "Arctic; Chemistry:fluid; Chemistry:Fluid; Chemistry:ice; Chemistry:Ice; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland; Ice Core Records; Methane; Paleoclimate", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "GISP2 (B and D Core) Methane Concentrations", "url": "https://www.usap-dc.org/view/dataset/609125"}, {"dataset_uid": "609124", "doi": "10.7265/N5KH0K8R", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Siple Dome Methane Record", "url": "https://www.usap-dc.org/view/dataset/609124"}, {"dataset_uid": "609360", "doi": "", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Methane; Paleoclimate; Taylor Dome", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "GISP2 (D Core) Methane Concentration Data", "url": "https://www.usap-dc.org/view/dataset/609360"}, {"dataset_uid": "609253", "doi": "", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Vostok Ice Core", "people": "Stauffer, Bernhard; Chappellaz, Jerome; Brook, Edward J.; Blunier, Thomas", "repository": "USAP-DC", "science_program": null, "title": "Antarctic and Greenland Climate Change Comparison", "url": "https://www.usap-dc.org/view/dataset/609253"}], "date_created": "Tue, 16 Dec 2008 00:00:00 GMT", "description": "This award supports work on trapped gases in Antarctic and other ice cores for paleoenvironmental and chronological purposes. The project will complete a ~ 100,000 year, high-resolution record of atmospheric methane from the Siple Dome ice core and use these data to construct a precise chronology for climate events recorded by the Siple Dome record. In addition, the resolution of the GISP2 (Greenland) ice core record will be increased in some critical intervals to help with the Siple Dome chronology and that of future ice cores. Finally, an upgrade to the analytical capabilities of the laboratory, including increasing precision and throughput and decreasing sample size needed for ice core methane measurements will be an important goal of this work. The proposed work will contribute to the understanding of the timing of rapid climate change in the Northern and Southern hemispheres during the last glacial period, the evolution of the global methane budget in the late Quaternary, and the late Quaternary climate history of Antarctica. It will also improve our ability to generate methane records for future ice coring projects, and inform and enrich the educational and outreach activities of our laboratory.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Isotope; Siple Coast; WAISCORES; GROUND-BASED OBSERVATIONS; Interplanetary Dust; FIELD SURVEYS; Not provided; Ice Sheet; Snow; GROUND STATIONS; Gas Measurement; Ice Core; Siple; Antarctica; Methane; Glaciology; Stratigraphy; Siple Dome", "locations": "Antarctica; Siple; Siple Coast; Siple Dome", "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Blunier, Thomas; Chappellaz, Jerome; Stauffer, Bernhard; Kurz, Mark D.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "High Resolution Records of Atmospheric Methane in Ice Cores and Implications for Late Quaternary Climate Change", "uid": "p0000034", "west": null}, {"awards": "9714687 Brook, Edward J.", "bounds_geometry": null, "dataset_titles": "Byrd Ice Core Microparticle and Chemistry Data", "datasets": [{"dataset_uid": "609247", "doi": "", "keywords": "Antarctica; Byrd; Byrd Ice Core; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate", "people": "Thompson, Lonnie G.; Blunier, Thomas; Fluckiger, Jacqueline; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Byrd Ice Core", "title": "Byrd Ice Core Microparticle and Chemistry Data", "url": "https://www.usap-dc.org/view/dataset/609247"}], "date_created": "Thu, 26 Aug 2004 00:00:00 GMT", "description": "This award is for support for a program to make high resolution studies of variations in the concentration of methane, the oxygenisotope composition of paleoatmospheric oxygen, and the total gas content of deep Antarctic ice cores. Studies of the concentration and isotopic composition of air in the firn of the Antarctic ice sheet will also be continued. One objective of this work is to use the methane concentration and oxygen-isotope composition of oxygen of air in ice as time-stratigraphic markers for the precise intercorrelation of Greenland and Antarctic ice cores as well as the correlation of ice cores to other climatic records. A second objective is to use variations in the concentration and interhemispheric gradient of methane measured in Greenland and Antarctic ice cores to deduce changes in continental climates and biogeochemistry on which the atmospheric methane distribution depends. A third objective is to use data on the variability of total gas content in the Siple Dome ice core to reconstruct aspects of the glacial history of West Antarctica during the last glacial maximum. The fourth objective is to participate in collaborative studies of firn air chemistry at Vostok, Siple Dome, and South Pole which will yield much new information about gas trapping in ice as well as the concentration history and isotopic composition of greenhouse gases, oxygen, trace biogenic gases and trace anthropogenic gases during the last 100 years.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "GROUND STATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Blunier, Thomas; Fluckiger, Jacqueline; Thompson, Lonnie G.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Studies of Trapped Gases in Firn and Ice from Antarctic Deep Ice Cores", "uid": "p0000168", "west": null}]

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