[{"awards": "1841228 Lyons, W. Berry", "bounds_geometry": "POLYGON((163.37428 -77.558627,163.3922735 -77.558627,163.410267 -77.558627,163.4282605 -77.558627,163.446254 -77.558627,163.4642475 -77.558627,163.482241 -77.558627,163.5002345 -77.558627,163.518228 -77.558627,163.5362215 -77.558627,163.554215 -77.558627,163.554215 -77.56397510000001,163.554215 -77.5693232,163.554215 -77.5746713,163.554215 -77.5800194,163.554215 -77.5853675,163.554215 -77.59071560000001,163.554215 -77.5960637,163.554215 -77.60141180000001,163.554215 -77.6067599,163.554215 -77.612108,163.5362215 -77.612108,163.518228 -77.612108,163.5002345 -77.612108,163.482241 -77.612108,163.4642475 -77.612108,163.446254 -77.612108,163.4282605 -77.612108,163.410267 -77.612108,163.3922735 -77.612108,163.37428 -77.612108,163.37428 -77.6067599,163.37428 -77.60141180000001,163.37428 -77.5960637,163.37428 -77.59071560000001,163.37428 -77.5853675,163.37428 -77.5800194,163.37428 -77.5746713,163.37428 -77.5693232,163.37428 -77.56397510000001,163.37428 -77.558627))", "dataset_titles": "Commonwealth Stream Diel Water Chemistry; Hyporheic zone geochemistry of Wales Stream, Taylor Valley, Antarctica; isotopic signature of massive buried ice, eastern Taylor Valley, Antarctica", "datasets": [{"dataset_uid": "601847", "doi": "10.15784/601847", "keywords": "Antarctica; Cryosphere; Nutrients; Stable Isotopes; Taylor Valley; Trace Elements", "people": "Gardner, Christopher B.", "repository": "USAP-DC", "science_program": null, "title": "Hyporheic zone geochemistry of Wales Stream, Taylor Valley, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601847"}, {"dataset_uid": "601848", "doi": "10.15784/601848", "keywords": "Antarctica; Buried Ice; Cryosphere; Stable Isotopes; Stable Water Isotopes; Taylor Valley", "people": "Gardner, Christopher B.", "repository": "USAP-DC", "science_program": null, "title": "isotopic signature of massive buried ice, eastern Taylor Valley, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601848"}, {"dataset_uid": "601844", "doi": "10.15784/601844", "keywords": "Antarctica; Commonwealth Stream; Cryosphere; Diel; Inlandwaters; McMurdo Dry Valleys; Stream Chemistry; Water Chemisty", "people": "Gardner, Christopher B.", "repository": "USAP-DC", "science_program": null, "title": "Commonwealth Stream Diel Water Chemistry", "url": "https://www.usap-dc.org/view/dataset/601844"}], "date_created": "Wed, 16 Oct 2024 00:00:00 GMT", "description": "Phytoplankton, or microscopic marine algae, are an important part of the carbon cycle and can lower the rates of atmospheric carbon dioxide by transferring the atmospheric carbon into the oceans. The concentration of phytoplankton in the Southern Ocean is regularly limited by the availability of marine iron. This in turn influences the rate of carbon transfer from the atmosphere to the ocean. The primary source of iron in the Southern Ocean is eroded continental rock. Understanding the current and future sources of iron to the Southern Ocean as a result of increased melting of terrestrial glaciers is necessary for predicting future concentrations of Southern Ocean phytoplankton and the subsequent influence on the carbon cycle. A poorly understood source of iron to the Southern Ocean is stream input from ice-free regions such as the McMurdo Dry Valleys in Antarctica. This source of iron is likely to become larger if glaciers retreat. This study investigates the sources and amount of iron transported by McMurdo Dry Valley streams directly into the Southern Ocean. Because not all forms of iron can be used by phytoplankton, experiments will be performed to determine how available iron is to phytoplankton and how iron mixes with seawater. Immersive 360-degree video, infographics, and educational videos of findings from this project will be shared on social media, at schools and science events, and in an urban science center. In the Southern Ocean (SO) there is an excess of macronutrients but regional primary production is limited or co-limited due to iron. An addition of iron to the ocean will affect biochemical cycles, increase primary production, and affect the structure and composition of phytoplankton communities in the SO. Iron flux to the SO is globally significant, as increased Fe fertilization leads to increased carbon sequestration which acts as a negative feedback to increased atmospheric pCO2. One source of potentially bioavailable iron to the coastal regions of the SO is from direct sub-aerial stream discharge in ice-free areas of Antarctica, a source that may become more important if terrestrial glaciers retreat. It is imperative to understand the source, nature, potential fate, and flux of iron to the SO if better predictive models for the carbon cycle and atmospheric chemistry are to be developed. This project will investigate in-stream processes and characteristics controlling dissolved iron draining into the Ross Sea including photoreduction, temperature, and complexation with organic matter. The novel study will quantify bioavailability of particulate iron and bioavailability of dissolved iron in Antarctic in streams draining into the SO. On-site speciation measurements will be performed on dissolved iron species, particulate iron speciation will be determined using high-resolution spectroscopy, mixing experiments will be performed with coastal marine water, and the bioavailability of Fe will be determined through marine bioassays. This project will provide two students with valuable Antarctic field experience and reach thousands of individuals through existing partnerships with K-12 schools, public STEM events, an urban science center, and a strong social media presence. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 163.554215, "geometry": "POINT(163.4642475 -77.5853675)", "instruments": null, "is_usap_dc": true, "keywords": "SURFACE WATER CHEMISTRY; Iron Fertilization; McMurdo Dry Valleys; Weathering", "locations": "McMurdo Dry Valleys", "north": -77.558627, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Lyons, W. Berry; Gardner, Christopher B.", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.612108, "title": "Fe Behavior and Bioavailability in Sub-aerial Runoff into the Ross Sea", "uid": "p0010483", "west": 163.37428}, {"awards": "1847067 Levy, Joseph", "bounds_geometry": "POLYGON((161 -76,161.35 -76,161.7 -76,162.05 -76,162.4 -76,162.75 -76,163.1 -76,163.45 -76,163.8 -76,164.15 -76,164.5 -76,164.5 -76.2,164.5 -76.4,164.5 -76.6,164.5 -76.8,164.5 -77,164.5 -77.2,164.5 -77.4,164.5 -77.6,164.5 -77.8,164.5 -78,164.15 -78,163.8 -78,163.45 -78,163.1 -78,162.75 -78,162.4 -78,162.05 -78,161.7 -78,161.35 -78,161 -78,161 -77.8,161 -77.6,161 -77.4,161 -77.2,161 -77,161 -76.8,161 -76.6,161 -76.4,161 -76.2,161 -76))", "dataset_titles": "Biogeochemical measurements of water tracks and adjacent dry soils from the McMurdo Dry Valleys; Surface Water Geochemistry from the McMurdo Dry Valleys", "datasets": [{"dataset_uid": "601703", "doi": "10.15784/601703", "keywords": "Antarctica; Dry Valleys", "people": "Levy, Joseph", "repository": "USAP-DC", "science_program": null, "title": "Surface Water Geochemistry from the McMurdo Dry Valleys", "url": "https://www.usap-dc.org/view/dataset/601703"}, {"dataset_uid": "601684", "doi": "10.15784/601684", "keywords": "Antarctica; Cation Exchange; Chemistry:soil; Chemistry:Soil; Dry Valleys; Organic Matter; Salt; Soil", "people": "Levy, Joseph", "repository": "USAP-DC", "science_program": null, "title": "Biogeochemical measurements of water tracks and adjacent dry soils from the McMurdo Dry Valleys", "url": "https://www.usap-dc.org/view/dataset/601684"}], "date_created": "Fri, 24 Dec 2021 00:00:00 GMT", "description": "Antarctic groundwater drives the regional carbon cycle and can accelerate permafrost thaw shaping Antarctic surface features. However, groundwater extent, flow, and processes on a continent virtually locked in ice are poorly understood. The proposed work investigates the interplay between groundwater, sediment, and ice in Antarctica\u0027s cold desert landscape to determine when, where, and why Antarctic groundwater is flowing, and how it may evolve Antarctic frozen deserts from dry and stable to wet and dynamic. Mapping the changing extent of Antarctic near-surface groundwater requires the ability to measure soil moisture rapidly and repeatedly over large areas. The research will capture changes in near-surface groundwater distribution through an unmanned aerial vehicle (UAV) mapping approach. The project integrates a diverse range of sensors with new UAV technologies to provide a higher-resolution and more frequent assessment of Antarctic groundwater extent and composition than can be accomplished using satellite observations alone. To complement the research objectives, the PI will develop a new UAV summer field school, the Geosciences UAV Academy, focused on training undergraduate-level UAV pilots in conducting novel earth sciences research using cutting edge imaging tools. The integration of research and technology will prepare students for careers in UAV-related industries and research. The project will deliver new UAV tools and workflows for soil moisture mapping relevant to arid regions including Antarctica as well as temperate desert and dryland systems and will train student research pilots to tackle next generation airborne challenges. Water tracks are the basic hydrological unit that currently feeds the rapidly-changing permafrost and wetlands in the Antarctic McMurdo Dry Valleys (MDV). Despite the importance of water tracks in the MDV hydrologic cycle and their influence on biogeochemistry, little is known about how these water tracks control the unique brine processes operating in Antarctic ice-free areas. Both groundwater availability and geochemistry shape Antarctic microbial communities, connecting soil geology and hydrology to carbon cycling and ecosystem functioning. The objectives of this CAREER proposal are to 1) map water tracks to determine the spatial distribution and seasonal magnitude of groundwater impacts on the MDV near-surface environment to determine how near-surface groundwater drives permafrost thaw and enhances chemical weathering and biogeochemical cycling; 2) establish a UAV academy training earth sciences students to answer geoscience questions using drone-based platforms and remote sensing techniques; and 3) provide a formative step in the development of the PI as a teacher-scholar. UAV-borne hyperspectral imaging complemented with field soil sampling will determine the aerial extent and timing of inundation, water level, and water budget of representative water tracks in the MDV. Soil moisture will be measured via near-infrared reflectance spectroscopy while bulk chemistry of soils and groundwater will be analyzed via ion chromatography and soil x-ray fluorescence. Sedimentological and hydrological properties will be determined via analysis of intact core samples. These data will be used to test competing hypotheses regarding the origin of water track solutions and water movement through seasonal wetlands. The work will provide a regional understanding of groundwater sources, shallow groundwater flux, and the influence of regional hydrogeology on solute export to the Southern Ocean and on soil/atmosphere linkages in earth\u0027s carbon budget. The UAV school will 1) provide comprehensive instruction at the undergraduate level in both how and why UAVs can advance geoscience research and learning; and 2) provide educational infrastructure for an eventual self-sustaining summer program for undergraduate UAV education. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 164.5, "geometry": "POINT(162.75 -77)", "instruments": null, "is_usap_dc": true, "keywords": "FIELD SURVEYS; Amd/Us; USA/NSF; AMD; USAP-DC; FROZEN GROUND; Taylor Valley", "locations": "Taylor Valley", "north": -76.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Levy, Joseph", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -78.0, "title": "Linking Antarctic Cold Desert Groundwater to Thermokarst \u0026 Chemical Weathering in Partnership with the Geoscience UAV Academy", "uid": "p0010286", "west": 161.0}, {"awards": "1851022 Fudge, Tyler; 1851094 Baker, Ian", "bounds_geometry": null, "dataset_titles": "Code for calculating mean gradient for EDC sulfate data; EPICA Dome C Sulfate Data 7-3190m; Forward Diffusion Model used to calculate widening of volcanic layer widths; Volcanic Widths in Dome C Interglacials and Glacials", "datasets": [{"dataset_uid": "601855", "doi": "10.15784/601855", "keywords": "Antarctica; Cryosphere", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": null, "title": "Volcanic Widths in Dome C Interglacials and Glacials", "url": "https://www.usap-dc.org/view/dataset/601855"}, {"dataset_uid": "601759", "doi": "10.15784/601759", "keywords": "Antarctica", "people": "Severi, Mirko; Fudge, T. J.", "repository": "USAP-DC", "science_program": "COLDEX", "title": "EPICA Dome C Sulfate Data 7-3190m", "url": "https://www.usap-dc.org/view/dataset/601759"}, {"dataset_uid": "601856", "doi": "10.15784/601856", "keywords": "Antarctica; Cryosphere", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": null, "title": "Code for calculating mean gradient for EDC sulfate data", "url": "https://www.usap-dc.org/view/dataset/601856"}, {"dataset_uid": "601857", "doi": "10.15784/601857", "keywords": "Antarctica; Cryosphere", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": null, "title": "Forward Diffusion Model used to calculate widening of volcanic layer widths", "url": "https://www.usap-dc.org/view/dataset/601857"}], "date_created": "Mon, 28 Jun 2021 00:00:00 GMT", "description": "The ice of the polar ice sheets is among the purest substances on Earth, yet the small amount of impurities --such as acids-- are important to how the ice flows and what can be learned from ice cores about past climate. The goal of this project is to understand the role of such acids on the deformation of polycrystalline ice by comparing the deformation behavior of pure and sulfuric acid-doped samples. Sulfuric acid was chosen both because of its importance for interpreting past climate and because it can lead to water veins in ice at low temperatures. This work will focus on the location, movement, and impact of acids in polycrystalline ice that are more complex than in single crystals of ice. By deforming samples and performing microstructural characterization, the role of acids on deformation rate, grain evolution, and the movement of the acids themselves, will be assessed. The work will lead to the education of a Ph.D. student at Dartmouth College, introduce undergraduate students to research at both the University of Washington and Dartmouth College. Despite the ubiquitous use of the constitutive relation for ice commonly referred to as \"Glen\u0027s Flow Law\", significant uncertainty exists particularly with regard to the role of impurities and the development of oriented fabrics. The aim of this project is to improve the constitutive relationship for ice by performing deformation tests and microstructural characterization of pure and sulfuric acid-doped ice. The project will focus on sulfuric acid\u0027s impact on ice viscosity, fabric evolution, and diffusivity. Sulfuric acid can have both direct and indirect effects on the mechanical properties of polycrystalline ice. The direct effects change the dislocation velocity and/or density, and the indirect effects change the grain size and fabric. The complexity and interaction of these effects means that it is not possible to understand the effects of sulfuric acid by simply examining ice core specimens. In this project, the team will deform four types of ice: lab-grown ice samples doped with similar-to-natural concentrations of sulfuric acid, lab-grown high-purity ice, layered doped and pure ice, and natural ice from Antarctic ice cores. Deformation will be performed in both uniaxial compression and simple shear. The addition of simple shear tests is critical for relating the laboratory-observed deformation behavior to the behavior of polar ice sheets where the shear strain dominates ice motion in basal ice. After deformation to strains from 5 percent up to 25 percent, the microstructural development will be assessed with methods including a variety of scanning electron microscope techniques, Raman microscopy, synchrotron-based Nano-X-ray fluorescence, and ion chromatography. These analysis techniques will allow the determination of 1) the segregation and movement of impurities, 2) the rate of grain-boundary migration, 3) the number of recrystallized grains; and 4) the full orientation of the ice crystals. The results will enable both microstructural modeling of the effects of sulfuric acid and numerical modeling of diffusion in ice cores. The net result will be a better understanding of ice deformation that improves ice-core interpretation and ice-sheet modeling. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "AMD; Polycrystalline Ice; LABORATORY; Epica Dome C; SNOW/ICE; USA/NSF; USAP-DC; Ice Core; Amd/Us", "locations": "Epica Dome C", "north": null, "nsf_funding_programs": "Antarctic Science and Technology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Fudge, T. J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: The Impact of Impurities and Stress State on Polycrystalline Ice Deformation", "uid": "p0010211", "west": null}, {"awards": "1341736 Adams, Byron", "bounds_geometry": "POLYGON((-177.4099 -84.4661,-177.08229 -84.4661,-176.75468 -84.4661,-176.42707 -84.4661,-176.09946 -84.4661,-175.77185 -84.4661,-175.44424 -84.4661,-175.11663000000001 -84.4661,-174.78902 -84.4661,-174.46141 -84.4661,-174.1338 -84.4661,-174.1338 -84.56828,-174.1338 -84.67045999999999,-174.1338 -84.77264,-174.1338 -84.87482,-174.1338 -84.977,-174.1338 -85.07918,-174.1338 -85.18136,-174.1338 -85.28354,-174.1338 -85.38571999999999,-174.1338 -85.4879,-174.46141 -85.4879,-174.78902 -85.4879,-175.11663000000001 -85.4879,-175.44424 -85.4879,-175.77185 -85.4879,-176.09946 -85.4879,-176.42707 -85.4879,-176.75468 -85.4879,-177.08229 -85.4879,-177.4099 -85.4879,-177.4099 -85.38571999999999,-177.4099 -85.28354,-177.4099 -85.18136,-177.4099 -85.07918,-177.4099 -84.977,-177.4099 -84.87482,-177.4099 -84.77264,-177.4099 -84.67045999999999,-177.4099 -84.56828,-177.4099 -84.4661))", "dataset_titles": "Dataset DS-TAMS: Genetic diversity of Collembola from the Transantarctic Mountains; GenBank accession numbers MN619477 to MN619610; Meteoric 10Be data of soils from the Shackleton Glacier region; Shackleton Glacier region soil water-soluble geochemical data; Shackleton Glacier region water-soluble salt isotopes; Soil invertebrate surveys from the Shackleton Glacier region of Antarctica during the 2017-2018 austral summer", "datasets": [{"dataset_uid": "601421", "doi": "10.15784/601421", "keywords": "Antarctica; Be-10; Beryllium-10; Cosmogenic Radionuclides; Geochemistry; Geomorphology; Shackleton Glacier; Surface Exposure Dates", "people": "Diaz, Melisa A.", "repository": "USAP-DC", "science_program": null, "title": "Meteoric 10Be data of soils from the Shackleton Glacier region", "url": "https://www.usap-dc.org/view/dataset/601421"}, {"dataset_uid": "601419", "doi": "10.15784/601419", "keywords": "Antarctica; Geochemistry; Nitrate; Shackleton Glacier; Stable Isotopes; Sulfate; Transantarctic Mountains", "people": "Diaz, Melisa A.; Gardner, Christopher B.; Lyons, W. Berry", "repository": "USAP-DC", "science_program": null, "title": "Shackleton Glacier region water-soluble salt isotopes", "url": "https://www.usap-dc.org/view/dataset/601419"}, {"dataset_uid": "200174", "doi": "10.5883/DS-TAMS", "keywords": null, "people": null, "repository": "Barcode of Life Datasystems (BOLD)", "science_program": null, "title": "Dataset DS-TAMS: Genetic diversity of Collembola from the Transantarctic Mountains", "url": "http://dx.doi.org/10.5883/DS-TAMS"}, {"dataset_uid": "200258", "doi": "doi:10.6073/pasta/7959821e5f6f8d56d94bb6a26873b3ae", "keywords": null, "people": null, "repository": "EDI", "science_program": null, "title": "Soil invertebrate surveys from the Shackleton Glacier region of Antarctica during the 2017-2018 austral summer", "url": "https://doi.org/10.6073/pasta/7959821e5f6f8d56d94bb6a26873b3ae"}, {"dataset_uid": "200175", "doi": "", "keywords": null, "people": null, "repository": "NCBI GenBank", "science_program": null, "title": "GenBank accession numbers MN619477 to MN619610", "url": "https://www.ncbi.nlm.nih.gov/nuccore/MN619477"}, {"dataset_uid": "601418", "doi": "10.15784/601418", "keywords": "Antarctica; Geochemistry; Shackleton Glacier", "people": "Gardner, Christopher B.; Diaz, Melisa A.; Lyons, W. Berry", "repository": "USAP-DC", "science_program": null, "title": "Shackleton Glacier region soil water-soluble geochemical data", "url": "https://www.usap-dc.org/view/dataset/601418"}], "date_created": "Mon, 02 Nov 2020 00:00:00 GMT", "description": "The project will characterize the functional, taxonomic, biotic and abiotic drivers of soil ecosystems in the Trans Antarctic Mountains (one of the most remote and harsh terrestrial landscapes on the planet). The work will utilize new high-throughput DNA and RNA sequencing technologies to identify members of the microbial communities and determine if the microbial community structures are independent of local environmental heterogeneities. In addition the project will determine if microbial diversity and function are correlated with time since the last glacial maximum (LGM). The expected results will greatly contribute to our knowledge regarding rates of microbial succession and help define the some of the limits to life and life-maintaining processes on Earth. The project will analyze genomes and RNA derived from these genomes to describe the relationships between biodiversity and ecosystem functioning from soils above and below LGM elevations and to correlate these with the environmental drivers associated with their development during the last ~18,000 years. The team will identify the taxonomic diversity and the functional genetic composition within a broad suite of soil biota and examine their patterns of assembly and distribution within the framework of their geological legacies. The project will mentor participants from undergraduate students to postdoctoral researchers and prepare them to effectively engage in research to meet their career aspirations. The project will contribute to ongoing public education efforts through relationships with K-12 teachers and administrators- to include University-Public School partnerships. Less formal activities include public lecture series and weblogs aimed at providing information on Antarctic polar desert ecosystems to the general public. Targeted classrooms near each PI\u0027s institution will participate in online, real-time discussions about current topics in Antarctic ecosystems research.", "east": -174.1338, "geometry": "POINT(-175.77185 -84.977)", "instruments": null, "is_usap_dc": true, "keywords": "FIELD INVESTIGATION; LABORATORY; AMD; Amd/Us; USA/NSF; TERRESTRIAL ECOSYSTEMS; Transantarctic Mountains; USAP-DC", "locations": "Transantarctic Mountains", "north": -84.4661, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Adams, Byron; Fierer, Noah; Wall, Diana; Diaz, Melisa A.; Gardner, Christopher B.; Lyons, W. Berry", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "Barcode of Life Datasystems (BOLD); EDI; NCBI GenBank; USAP-DC", "science_programs": null, "south": -85.4879, "title": "Collaborative Research: The Role of Glacial History on the Structure and Functioning of Ecological Communities in the Shackleton Glacier Region of the Transantarctic Mountains", "uid": "p0010140", "west": -177.4099}, {"awards": "1443663 Cole-Dai, Jihong; 1443336 Osterberg, Erich; 1443397 Kreutz, Karl", "bounds_geometry": "POINT(-180 -90)", "dataset_titles": "Preliminary SPC14 high-resolution Fe and Mn biologically relevant and dissolved trace metal concentrations spanning -42 \u2013 54,300 years BP.; South Pole Ice Core Holocene Major Ion Dataset; South Pole Ice Core Sea Salt and Major Ions; South Pole ice core (SPC14) discrete methane data; South Pole (SPC14) microparticle concentration, mass concentration, flux, particle-size-distribution mode, and aspect ratio measurements; SPICEcore 400-480 m Major Ions SDSU; The South Pole Ice Core (SPICEcore) chronology and supporting data", "datasets": [{"dataset_uid": "601206", "doi": "10.15784/601206", "keywords": "Antarctica; Calcium (ca); Chemistry:ice; Chemistry:Ice; Depth; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciochemistry; Glaciology; Ice; Ice Core; Ice Core Chemistry; Ice Core Data; Ice Core Records; Ice Core Stratigraphy; Nitrate; Nitrogen Isotopes; Paleoclimate; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Dunbar, Nelia; Buizert, Christo; Severinghaus, Jeffrey P.; Bay, Ryan; Souney, Joseph Jr.; Sigl, Michael; McConnell, Joseph; Fegyveresi, John; Cole-Dai, Jihong; Thundercloud, Zayta; Cox, Thomas S.; Kreutz, Karl; Epifanio, Jenna; Ortman, Nikolas; Brook, Edward J.; Beaudette, Ross; Sowers, Todd A.; Steig, Eric J.; Morris, Valerie; Ferris, David G.; Iverson, Nels; Jones, Tyler R.; Winski, Dominic A.; Fudge, T. J.; Casey, Kimberly A.; Nicewonger, Melinda R.; Aydin, Murat; Kahle, Emma; Osterberg, Erich; Waddington, Edwin D.; Alley, Richard", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "The South Pole Ice Core (SPICEcore) chronology and supporting data", "url": "https://www.usap-dc.org/view/dataset/601206"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.; Aydin, Murat; Kreutz, Karl; Buizert, Christo; Brook, Edward J.; Epifanio, Jenna; Sowers, Todd A.; Kahle, Emma; Steig, Eric J.; Winski, Dominic A.; Osterberg, Erich; Fudge, T. J.; Hood, Ekaterina; Kalk, Michael; Ferris, David G.; Kennedy, Joshua A.; Edwards, Jon S.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601553", "doi": "10.15784/601553", "keywords": "Antarctica; Dust; Ice Core; South Pole", "people": "Kreutz, Karl", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPC14) microparticle concentration, mass concentration, flux, particle-size-distribution mode, and aspect ratio measurements", "url": "https://www.usap-dc.org/view/dataset/601553"}, {"dataset_uid": "601675", "doi": "10.15784/601675", "keywords": "Antarctica; South Pole; SPICEcore", "people": "Kreutz, Karl", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Preliminary SPC14 high-resolution Fe and Mn biologically relevant and dissolved trace metal concentrations spanning -42 \u2013 54,300 years BP.", "url": "https://www.usap-dc.org/view/dataset/601675"}, {"dataset_uid": "601430", "doi": "10.15784/601430", "keywords": "Antarctica; Ions; South Pole; SPICEcore", "people": "Larrick, Carleigh; Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPICEcore 400-480 m Major Ions SDSU", "url": "https://www.usap-dc.org/view/dataset/601430"}, {"dataset_uid": "601851", "doi": "10.15784/601851", "keywords": "Antarctica; Cryosphere; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Sea Salt and Major Ions", "url": "https://www.usap-dc.org/view/dataset/601851"}, {"dataset_uid": "601850", "doi": "10.15784/601850", "keywords": "Antarctica; Cryosphere; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Holocene Major Ion Dataset", "url": "https://www.usap-dc.org/view/dataset/601850"}], "date_created": "Thu, 29 Aug 2019 00:00:00 GMT", "description": "This collaborative project explores the signatures and causes of natural climate change in the region surrounding Antarctica over the last 40,000 years as the Earth transitioned from an ice age into the modern warm period. The researchers will investigate how the wind belts that surround Antarctica changed in their strength and position through time, and document explosive volcanic eruptions and CO2 cycling in the Southern Ocean as potential climate forcing mechanisms over this interval. Understanding how and why the climate varied naturally in the past is critical for improving understanding of modern climate change and projections of future climate under higher levels of atmospheric CO2. The investigators plan to conduct a suite of chemical measurements along the 1500m length of the South Pole Ice Core, including major ion and trace element concentrations, and microparticle (dust) concentrations and size distributions. These measurements will (1) extend the South Pole record of explosive volcanic eruptions to 40,000 years using sulfate and particle data; (2) establish the relative timing of climate changes in dust source regions of Patagonia, New Zealand, and Australia using dust flux data; (3) investigate changes in the strength and position of the westerly wind belt using dust size distribution data; and (4) quantify the flux of bioavailable trace metals deposited as dust to the Southern Ocean over time. These chemistry records will also be critical for creating the timescale that will be used by all researchers studying records from the South Pole core. The project will support four graduate students and several undergraduate students across three different institutions, and become a focus of the investigators\u0027 efforts to disseminate outcomes of climate change science to the broader community.", "east": -180.0, "geometry": "POINT(-180 -90)", "instruments": null, "is_usap_dc": true, "keywords": "Antarctica; ICE CORE RECORDS; USAP-DC; Amd/Us; USA/NSF; LABORATORY; AMD", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Osterberg, Erich", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: South Pole Ice Core Chronology and Climate Records using Chemical and Microparticle Measurements", "uid": "p0010051", "west": -180.0}, {"awards": "0839066 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Major Ion Chemistry Data of WAIS Divide Ice Core Brittle Ice", "datasets": [{"dataset_uid": "609546", "doi": "10.7265/N5RF5S0D", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; WAIS Divide; WAIS Divide Ice Core", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Major Ion Chemistry Data of WAIS Divide Ice Core Brittle Ice", "url": "https://www.usap-dc.org/view/dataset/609546"}], "date_created": "Wed, 19 Mar 2014 00:00:00 GMT", "description": "Cole-Dai/0839066\u003cbr/\u003e\u003cbr/\u003eThis award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to make continuous major ion analyses in the West Antarctica Ice Sheet Divide (WAIS Divide) ice core by sampling the brittle ice zone (approximately from 500 m to 1500 m). The intellectual merit of the project is that these will likely be the only chemical measurements on the brittle ice zone and, therefore, will bridge the gap in the expected continuous records of climate, ice sheet dynamics and biological evolution based on chemical measurements. High resolution sampling and analysis, probably on selected portions and depth intervals in the brittle ice zone, will help with the independent, high-precision dating of the WAIS Divide core and contribute to the achievement of the major objectives of the WAIS Divide project?development of high resolution climate records with which to investigate issues of climate forcing by greenhouse gases and the role of Antarctica and Southern Hemisphere in the global climate system. Planned collaboration with other WAIS Divide investigators will develop the longest and most detailed volcanic record from Antarctica ice cores. The broader impacts of this project include a contribution to enhancing our knowledge of the climate system. Such improvements in understanding of the global climate system and the ability to predict the magnitude and uncertainty of future changes are highly relevant to the global community. The project will support post-doctoral scientists and graduate students, including those from under-represented groups, will contribute to education, an help to train future scientists and promote diversity in research and education. Public outreach activities of this project will contribute to informal science education of school age children in the Eastern South Dakota region.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Paleoclimate; LABORATORY; Ions; GROUND-BASED OBSERVATIONS; WAISCORES; Ion Chromatograph; Not provided; Ice Core", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "NOT APPLICABLE", "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Major Ion Chemical Analysis of Brittle Ice in the WAIS Divide Ice Core", "uid": "p0000047", "west": null}, {"awards": "0738975 Baker, Ian", "bounds_geometry": null, "dataset_titles": "Siple Dome A (SDMA) Grain Orientation 640 - 790 Meters", "datasets": [{"dataset_uid": "609526", "doi": "10.7265/N53T9F5X", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Sample/collection Description; Sample/Collection Description; Siple Dome; Siple Dome Ice Core; South Pole; WAISCORES", "people": "Baker, Ian; Sieg, Katherine; Obbard, Rachel", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Siple Dome A (SDMA) Grain Orientation 640 - 790 Meters", "url": "https://www.usap-dc.org/view/dataset/609526"}], "date_created": "Mon, 26 Nov 2012 00:00:00 GMT", "description": "This award supports a project to fully characterize the microstructure in ice cores, in particular the microstructural locations of impurities, grain orientations and strain gradients. This work will complement the optical observations, electrical conductivity measurement, and precise, detailed measurements of the soluble ion and gas contents that are performed by others. Linking the concentrations of soluble ions and gases, measured to a few parts per billion, to the optically determined annual layer structure and the stable isotope data in ice cores has enabled a great deal to be established about the concentrations and depth/age distributions of particles, trace gases and impurities for several polar ice cores. Ice core studies carried out by several groups contribute immensely to our understanding of paleoclimate and, to our ability to predict future climate change. The work will build on previous measurements and technique development in this area, as well as focusing on new techniques to characterize ice cores. The work will use both scanning electron microscopy (SEM) coupled with X-ray energy dispersive spectroscopy (EDS) and confocal scanning optical microscopy coupled with Raman spectroscopy (RS) to determine the microstructural locations of impurities and correlate this information with depth/age, and impurity type and concentration for several polar ice cores. The Broader Impacts of the proposed work are that knowledge of the location of impurities coupled with the grain orientation (both c- and a-axis) and grain misorientation information will allow paleoclimatologists to better interpret ice core data and other scientists to understand and model the physical and mechanical properties of natural ice sheets. Other Broader Impacts of the work are that the work will be performed and lead to the education of a Ph.D. student. At the end of the project, as well as the knowledge gained from coursework, the graduate student will have experience in ice core specimen preparation and characterization using scanning electron microscopy, x-ray microanalysis, confocal scanning microscopy, Raman spectroscopy and ion chromatography. Results from the research will be published in refereed journals, presented at conferences, and placed on a web page.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES", "is_usap_dc": true, "keywords": "FEI Xl30 Environmental Scanning Electron Microscope - Field Emission Gun (esem - Feg); LABORATORY; Electron Backscatter Diffraction", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Obbard, Rachel; Sieg, Katherine", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Advanced Microstructural Characterization of Polar Ice Cores", "uid": "p0000178", "west": null}, {"awards": "0537752 Creyts, Timothy; 0538674 Winebrenner, Dale", "bounds_geometry": null, "dataset_titles": "Millennially Averaged Accumulation Rates for Lake Vostok; Modeled Radar Attenuation Rate Profile at the Vostok 5G Ice Core Site, Antarctica", "datasets": [{"dataset_uid": "609500", "doi": "10.7265/N5F769HV", "keywords": "Accumulation Rate; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Lake Vostok", "people": "Studinger, Michael S.; Macgregor, Joseph A.; Matsuoka, Kenichi; Winebrenner, Dale; Waddington, Edwin D.", "repository": "USAP-DC", "science_program": null, "title": "Millennially Averaged Accumulation Rates for Lake Vostok", "url": "https://www.usap-dc.org/view/dataset/609500"}, {"dataset_uid": "609501", "doi": "10.7265/N59K485D", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Lake Vostok; Radar Attenuation Rate; Vostok Ice Core", "people": "Macgregor, Joseph A.; Matsuoka, Kenichi; Studinger, Michael S.", "repository": "USAP-DC", "science_program": null, "title": "Modeled Radar Attenuation Rate Profile at the Vostok 5G Ice Core Site, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609501"}], "date_created": "Thu, 09 Aug 2012 00:00:00 GMT", "description": "0538674\u003cbr/\u003eMatsuoka\u003cbr/\u003eThis award supports a project to evaluate radio-echo intensities in the available SOAR ice-penetrating radar data along grids covering Lake Vostok, and along four regional tracks from Ridge B toward the lake. The project has two objectives; first, it will examine the upper surface of the lake and reflectors hypothesized to be a boundary between the meteoric and accreted ice. They will provide crucial knowledge on the dynamic evolution of the lake. Second, this project will examine a poorly understood echo-free zone within the deep ice in central East Antarctica. This zone may consist of distorted stagnant ice, while its upper boundary may be a shear zone. The SOAR radar data provide a unique resource to examine spatiotemporal water circulation patterns that should be understood in order to select the best direct-sampling strategy to the lake. The Vostok ice core provides a unique opportunity to do this work. First, the path effects, i.e. propagation loss and birefringence, will be derived at the ice-core site using ice temperature, chemistry, and fabric data. Second, lateral variations of the propagation loss will be estimated by tracking chemistry associated with radar-detected isochronous layers, and by inferring temperatures from an ice-flow model that can replicate those layers. Ice-fabric patterns will be inferred from anisotropy in the reflectivity at about 100 radar-track cross-over sites. In terms of broader impacts, a graduate student will be trained to interpret the radar data in the light of radar theory and glaciological context of Lake Vostok and summer workshops for K-12 teachers will be provided in Seattle and New York. This project will contribute to ongoing efforts to study Lake Vostok and will complement the site selection for a North Vostok ice core, which has been proposed by Russia and France as an IPY program.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e RADAR SOUNDERS \u003e RADAR ECHO SOUNDERS; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e RADAR SOUNDERS \u003e RADAR; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e LIDAR/LASER SOUNDERS \u003e LASERS; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e ALTIMETERS \u003e RADAR ALTIMETERS \u003e ALTIMETERS; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e ALTIMETERS \u003e RADAR ALTIMETERS \u003e RADAR ALTIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMOMETERS \u003e THERMOMETERS", "is_usap_dc": true, "keywords": "Airborne Radar Sounding; DHC-6; Salinity; Lake Vostok; Antarctic Ice Sheet; Modeling; FIELD SURVEYS; Model Output; Accumulation Rate; MODELS; Numerical Model; Ice Sheet; Not provided; Hydrostatic; Aerogeophysical; Subglacial; Attenuation Rate; Radar; FIELD INVESTIGATION; Model; Circulation; LABORATORY", "locations": "Lake Vostok; Antarctic Ice Sheet", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Matsuoka, Kenichi; Winebrenner, Dale; Creyts, Timothy; Macgregor, Joseph A.; Studinger, Michael S.; Waddington, Edwin D.", "platforms": "AIR-BASED PLATFORMS \u003e PROPELLER \u003e DHC-6; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e MODELS \u003e MODELS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Deciphering the Deep Ice and the Ice-water Interface over Lake Vostok Using Existing Radar Data", "uid": "p0000090", "west": null}, {"awards": "0636767 Dunbar, Nelia; 0636740 Kreutz, Karl", "bounds_geometry": "POINT(112.11666 -79.46666)", "dataset_titles": "Microparticle, Conductivity, and Density Measurements from the WAIS Divide Deep Ice Core, Antarctica; Snowpit Chemistry - Methods Comparison, WAIS Divide, Antarctica; Snowpit evidence of the 2011 Puyehue-Cordon Caulle (Chile) eruption in West Antarctica; WAIS Divide Microparticle Concentration and Size Distribution, 0-2400 ka; WAIS Divide Snowpit Chemical and Isotope Measurements, Antarctica; WAIS Divide WDC06A Discrete ICP-MS Chemistry", "datasets": [{"dataset_uid": "601023", "doi": "10.15784/601023", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; ICP-MS; Isotope; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide WDC06A Discrete ICP-MS Chemistry", "url": "https://www.usap-dc.org/view/dataset/601023"}, {"dataset_uid": "601036", "doi": "10.15784/601036", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Intracontinental Magmatism; IntraContinental Magmatism; Snow Pit; Tephra; WAIS Divide; WAIS Divide Ice Core", "people": "Koffman, Bess; Kreutz, Karl", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Snowpit evidence of the 2011 Puyehue-Cordon Caulle (Chile) eruption in West Antarctica", "url": "https://www.usap-dc.org/view/dataset/601036"}, {"dataset_uid": "609620", "doi": "10.7265/N5Q81B1X", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Trace Elements; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl; Koffman, Bess", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Snowpit Chemistry - Methods Comparison, WAIS Divide, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609620"}, {"dataset_uid": "609616", "doi": "10.7265/N5KK98QZ", "keywords": "Antarctica; Dust; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Particle Size; WAIS Divide; WAIS Divide Ice Core", "people": "Koffman, Bess; Kreutz, Karl", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Microparticle Concentration and Size Distribution, 0-2400 ka", "url": "https://www.usap-dc.org/view/dataset/609616"}, {"dataset_uid": "609506", "doi": "10.7265/N5SJ1HHN", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Isotope; Microparticle Concentration; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl; Koffman, Bess", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Snowpit Chemical and Isotope Measurements, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609506"}, {"dataset_uid": "609499", "doi": "10.7265/N5K07264", "keywords": "Antarctica; Density; Electrical Conductivity; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Microparticle Concentration; Physical Properties; WAIS Divide; WAIS Divide Ice Core", "people": "Koffman, Bess; Kreutz, Karl; Hamilton, Gordon S.; Breton, Daniel", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Microparticle, Conductivity, and Density Measurements from the WAIS Divide Deep Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609499"}], "date_created": "Tue, 19 Jun 2012 00:00:00 GMT", "description": "This award supports a project to perform continuous microparticle concentration and size distribution measurements (using coulter counter and state-of-the-art laser detector methods), analysis of biologically relevant trace elements associated with microparticles (Fe, Zn, Co, Cd, Cu), and tephra measurements on the WAIS Divide ice core. This initial three-year project includes analysis of ice core spanning the instrumental (~1850-present) to mid- Holocene (~5000 years BP) period, with sample resolution ranging from subannual to decadal. The intellectual merit of the project is that it will help in establishing the relationships among climate, atmospheric aerosols from terrestrial and volcanic sources, ocean biogeochemistry, and greenhouse gases on several timescales which remain a fundamental problem in paleoclimatology. The atmospheric mineral dust plays an important but uncertain role in direct radiative forcing, and the microparticle datasets produced in this project will allow us to examine changes in South Pacific aerosol loading, atmospheric dynamics, and dust source area climate. The phasing of changes in aerosol properties within Antarctica, throughout the Southern Hemisphere, and globally is unclear, largely due to the limited number of annually dated records extending into the glacial period and the lack of a\u003cbr/\u003etephra framework to correlate records. The broader impacts of the proposed research are an interdisciplinary approach to climate science problems, and will contribute to several WAIS Divide science themes as well as the broader paleoclimate and oceanographic communities. Because the research topics have a large and direct societal relevance, the project will form a centerpiece of various outreach efforts at UMaine and NMT including institution websites, public speaking, local K-12 school interaction, media interviews and news releases, and popular literature. At least one PhD student and one MS student will be directly supported by this project, including fieldwork, core processing, laboratory analysis, and data interpretation/publication. We expect that one graduate student per year will apply for a core handler/assistant driller position through the WAIS Divide Science Coordination Office, and that undergraduate student involvement will result in several Capstone experience projects (a UMaine graduation requirement). Data and ideas generated from the project will be integrated into undergraduate and graduate course curricula at both institutions.", "east": 112.11666, "geometry": "POINT(112.11666 -79.46666)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PARTICLE DETECTORS; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ELECTRON MICROPROBES; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e LOPC-PMS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e ICE CORE MELTER; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PARTICLE DETECTORS", "is_usap_dc": true, "keywords": "Ice Core Dust; Tephra; Radiative Forcing; Greenhouse Gas; West Antarctica; Atmospheric Aerosols; Oxygen Isotope; Not provided; WAIS Divide; Snow Pit; Ice Core Chemistry; Microparticle; Wais Divide-project; Microparticles Size; Paleoclimate; LABORATORY; Ice Core Data; Atmospheric Dynamics; Antarctica; FIELD SURVEYS; Ice Core; Trace Elements; FIELD INVESTIGATION; Holocene; Isotope; Snow Chemistry", "locations": "Antarctica; WAIS Divide; West Antarctica", "north": -79.46666, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Koffman, Bess; Kreutz, Karl; Breton, Daniel; Dunbar, Nelia; Hamilton, Gordon S.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.46666, "title": "Collaborative Research: Microparticle/tephra analysis of the WAIS Divide ice core", "uid": "p0000040", "west": 112.11666}, {"awards": "0538553 Cole-Dai, Jihong", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Major Ion Concentrations in WDC05Q and WDC06A Ice Cores (WAIS Divide)", "datasets": [{"dataset_uid": "609544", "doi": "10.7265/N54M92H3", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; WAIS Divide; WAIS Divide Ice Core", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Major Ion Concentrations in WDC05Q and WDC06A Ice Cores (WAIS Divide)", "url": "https://www.usap-dc.org/view/dataset/609544"}], "date_created": "Wed, 25 Aug 2010 00:00:00 GMT", "description": "Cole-Dai\u003cbr/\u003e0538553\u003cbr/\u003e\u003cbr/\u003eThis award supports a project that will contribute to the US West Antarctica Ice Sheet Ice Divide ice core (WAIS Divide) project by developing new instrumentation and analytical procedures to measure concentrations of major ions (Cl-, NO3-, SO42-, Na+, K+, NH4+, Mg2+, Ca2+). A melter-based, continuous flow, multi-ion-chromatograph technique (CFA-IC) has been developed recently at South Dakota State University (SDSU). This project will further expand and improve the CFA-IC technique and instrumentation and develop procedures for routine analysis of major ions in ice cores. In addition, training of personnel (operators) to perform continuous, high resolution major ion analysis of the deep core will be accomplished through this project. The temporal resolution of the major ion measurement will be as low as 0.5 cm with the fully developed CFA-IC technique. At this resolution, it will be possible to use annual cycles of sulfate and sea-salt ion concentrations to determine annual layers in the WAIS Divide ice core. Annual layer counting using CFA-IC chemical measurements and other high resolution measurements will contribute significantly to the major WAIS Divide project objective of producing precisely (i.e., annually) dated climate records. The project will support the integration of research and education, train future scientists and promote human resource development through the participation of graduate and undergraduate students. In particular, undergraduate participation will contribute to a current REU (Research Experience for Undergraduates) chemistry site program at SDSU. Development and utilization of multi-user instrumentation will promote research collaboration and advance environmental science. NSF support for SDSU will contribute to the economic development and strengthen the infrastructure for research and education in South Dakota.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "LABORATORY; WAIS Divide; Ice Core; West Antarctic Ice Sheet; Ion Chromatograph; GROUND-BASED OBSERVATIONS; Not provided; Major Ion; Ions", "locations": "WAIS Divide; West Antarctic Ice Sheet", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Major Ion Chemistry of WAIS Divide Ice Core", "uid": "p0000035", "west": -112.085}, {"awards": "0636506 Mayewski, Paul", "bounds_geometry": "POLYGON((-137.7 -75.7,-137.4 -75.7,-137.1 -75.7,-136.8 -75.7,-136.5 -75.7,-136.2 -75.7,-135.9 -75.7,-135.6 -75.7,-135.3 -75.7,-135 -75.7,-134.7 -75.7,-134.7 -75.773,-134.7 -75.846,-134.7 -75.919,-134.7 -75.992,-134.7 -76.065,-134.7 -76.138,-134.7 -76.211,-134.7 -76.284,-134.7 -76.357,-134.7 -76.43,-135 -76.43,-135.3 -76.43,-135.6 -76.43,-135.9 -76.43,-136.2 -76.43,-136.5 -76.43,-136.8 -76.43,-137.1 -76.43,-137.4 -76.43,-137.7 -76.43,-137.7 -76.357,-137.7 -76.284,-137.7 -76.211,-137.7 -76.138,-137.7 -76.065,-137.7 -75.992,-137.7 -75.919,-137.7 -75.846,-137.7 -75.773,-137.7 -75.7))", "dataset_titles": "Ion Concentrations from SPRESSO Ice Core, Antarctica; Mt. Moulton Ice Trench Mass Spectrometry Data, Antarctica", "datasets": [{"dataset_uid": "609471", "doi": "10.7265/N508638J", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; ITASE; Paleoclimate; South Pole; SPRESSO Ice Core", "people": "Mayewski, Paul A.; Korotkikh, Elena", "repository": "USAP-DC", "science_program": null, "title": "Ion Concentrations from SPRESSO Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609471"}, {"dataset_uid": "609472", "doi": "10.7265/N5VH5KSV", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Mt Moulton; Paleoclimate", "people": "Mayewski, Paul A.; Korotkikh, Elena", "repository": "USAP-DC", "science_program": null, "title": "Mt. Moulton Ice Trench Mass Spectrometry Data, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609472"}], "date_created": "Thu, 29 Jul 2010 00:00:00 GMT", "description": "This award supports a project to examine an existing ice core of opportunity from South Pole (SPRESO core) to develop a 2000+ year long climate record. SPRESO ice core will be an annually dated, sub-annually-resolved reconstruction of past climate (atmospheric circulation, temperature, precipitation rate, and atmospheric chemistry) utilizing continuous, co-registered measurements (n=45) of: major ions, trace elements, and stable isotope series, plus selected sections for microparticle size and composition. The intellectual merit of this project relates to the fact that few 2000+ year records of this quality exist in Antarctica despite increasing scientific interest in this critical time period as the framework within which to understand modern climate. The scientific impact of this ice core investigation are that it will provide an in-depth understanding of climate variability; a baseline for assessing modern climate variability in the context of human activity; and a contribution to the prediction of future climate variability. The broader impact of this work is that the proposed research addresses important questions concerning the role of Antarctica in past, present, and future global change. Results will be translated into publicly accessible information through public lectures, media appearances, and an extensive outreach activity housed in our Institute. Our ice core activities provide a major basis for curriculum in K-12 and University plus a basis for several field and laboratory based graduate theses and undergraduate student projects. The project will support one PhD student for 3 years and undergraduate salaries. The Climate Change Institute has a long history of gender and ethnically diverse student and staff involvement in research.", "east": -134.7, "geometry": "POINT(-136.2 -76.065)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Interpretation; Ions; US ITASE; Explorations; LABORATORY; Ice Core Data; Ice Core; Ice Analysis; Ice; Not provided; Antarctic Ice Sheet; Laboratory Investigation; Field Investigations; Ice Core Chemistry; Horizontal Ice Core; Ice Chemistry; Ice Sheet", "locations": "Antarctic Ice Sheet", "north": -75.7, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Korotkikh, Elena; Kreutz, Karl; Kurbatov, Andrei V.; Mayewski, Paul A.", "platforms": "Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -76.43, "title": "Collaborative Proposal: 2000+ Year Detailed, Calibrated Climate Reconstruction from a South Pole Ice Core Set in an Antarctic - Global Scale Context", "uid": "p0000209", "west": -137.7}, {"awards": "0538494 Meese, Debra", "bounds_geometry": null, "dataset_titles": "Microstructural Location and Composition of Impurities in Polar Ice Cores", "datasets": [{"dataset_uid": "609436", "doi": "10.7265/N5DF6P5P", "keywords": "Antarctica; Arctic; Byrd Glacier; Byrd Ice Core; Chemistry:ice; Chemistry:Ice; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Lake Vostok; Paleoclimate; Vostok Ice Core", "people": "Baker, Ian; Obbard, Rachel", "repository": "USAP-DC", "science_program": null, "title": "Microstructural Location and Composition of Impurities in Polar Ice Cores", "url": "https://www.usap-dc.org/view/dataset/609436"}], "date_created": "Thu, 03 Jun 2010 00:00:00 GMT", "description": "0538494\u003cbr/\u003eMeese\u003cbr/\u003eThis award supports a project for physical properties research on snow pits and firn/ice cores with specific objectives that include stratigraphic analysis including determination of accumulation rates, annual layers, depth hoar, ice and wind crusts and rates of grain growth with depth. Studies of firn densification rates and how these parameters relate to the meteorology and climatology over the last 200 years of snow accumulation in Antarctica will also be investigated. The project will also determine the seasonality of accumulation by co-registration of stratigraphy and chemistry and determination of chemical species at the grain boundaries, how these may change with depth/densification (and therefore temperature), precipitation, and may affect grain growth. Fabric analyses will be made, including variation with depth, location on undulations and if any variation exists with climate/chemistry. The large spatial coverage of the US ITASE program offers the opportunity to determine how these parameters are affected by a large range of temperature, precipitation and topographic effects. The intellectual merit of the project includes the fact that ITASE is the terrestrial equivalent of a polar research vessel that provides a unique, logistically efficient, multi-dimensional (x, y, z and time) view of the atmosphere, ice sheet and their histories. Physical properties measurements/ analyses are an integral part of understanding the dynamic processes to which the accumulated snow is subjected. Recent advancements in the field along with multiple core sites provide an excellent opportunity to gain a much broader understanding of the spatial, temporal and physical variables that impact firnification and the possible resultant impact on climatic interpretation. In terms of broader impacts, the data collected by US ITASE and its international ITASE partners is available to a broad scientific community. US ITASE has an extensive program of public outreach and provides significant opportunities for many students to experience multidisciplinary Antarctic research. A graduate student, a post-doctoral fellow and at least one undergraduate would be funded by this work. Dr. Meese is also a member of the New England Science Collaborative, an organization that educates the public on climate change based on recent scientific advancements.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e MICROSCOPES; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES", "is_usap_dc": false, "keywords": "LABORATORY; Grain Growth; FIELD SURVEYS; Accumulation Rate; Firn Core; FIELD INVESTIGATION; Chemistry; Snow Pit; Depth Hoar; Firn Density; Ice Core; Not provided; Stratigraphic Analysis; Firn; US ITASE; Annual Layers", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Meese, Deb; MEESE, DEBRA", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "The Physical Properties of the US ITASE Firn and Ice Cores from South Pole to Taylor Dome", "uid": "p0000289", "west": null}, {"awards": "9980379 Baker, Ian", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Mon, 15 Feb 2010 00:00:00 GMT", "description": "This award is for support for three years of funding to study the effects of impurities on the flow of poly- crystalline ice. It has been known for thirty years that both hydrofluoric acid (HF) and hydrochloric acid (HCl) dramatically decrease the strength of ice and recent work by the author\u0027s group has shown that sulfuric acid (H2SO4) produces a similar reduction in strength. However, these data are for single crystals at strain rates and stresses that far exceed those found in glaciers and ice sheets, and often at concentrations that far exceed those in natural ice. Therefore, it is not known how impurities found in nature affect the flow of polycrystalline ice at slow strain rates. In this research, the effects of nitric acid and sulfuric acid (which are naturally occurring impurities in ice) on the microstructure (dislocation structure, grain boundary structure and location of the acids) and creep of polycrystalline ice (at a range of temperatures and stresses) will be determined. The ice\u0027s response to creep deformation will be studied using a combination of x-ray topography, optical microscopy and scanning electron microscopy. X-ray microanalysis in an environmental scanning electron microscope will be used to study the location of impurities. The structure and creep behavior of the acid-doped ice will be compared with those of both high-purity laboratory-grown ice and ice from Byrd Station, Antarctica. The end-result of this project will be to elucidate the effects of naturally-occurring acid impurities on the mechanical properties of polycrystalline ice under conditions relevant to the deformation of glaciers and ice sheets, including and understanding of how impurities affect the underlying deformation mechanisms.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PARTICLE DETECTORS; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES", "is_usap_dc": true, "keywords": "Ice Core Data; Ice Core; Microstructure; Ice Sheet; Ice Core Chemistry; Antarctic Ice Sheet; LABORATORY", "locations": "Antarctic Ice Sheet", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Obbard, Rachel", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repositories": null, "science_programs": null, "south": null, "title": "The Effects of Impurities on the Flow of Polycrystalline Ice", "uid": "p0000015", "west": null}, {"awards": "0230288 Anastasio, Cort", "bounds_geometry": "POLYGON((123.30014 -75.093445,123.307404 -75.093445,123.314668 -75.093445,123.321932 -75.093445,123.329196 -75.093445,123.33646 -75.093445,123.343724 -75.093445,123.350988 -75.093445,123.358252 -75.093445,123.365516 -75.093445,123.37278 -75.093445,123.37278 -75.0952669,123.37278 -75.0970888,123.37278 -75.0989107,123.37278 -75.1007326,123.37278 -75.1025545,123.37278 -75.1043764,123.37278 -75.1061983,123.37278 -75.1080202,123.37278 -75.1098421,123.37278 -75.111664,123.365516 -75.111664,123.358252 -75.111664,123.350988 -75.111664,123.343724 -75.111664,123.33646 -75.111664,123.329196 -75.111664,123.321932 -75.111664,123.314668 -75.111664,123.307404 -75.111664,123.30014 -75.111664,123.30014 -75.1098421,123.30014 -75.1080202,123.30014 -75.1061983,123.30014 -75.1043764,123.30014 -75.1025545,123.30014 -75.1007326,123.30014 -75.0989107,123.30014 -75.0970888,123.30014 -75.0952669,123.30014 -75.093445))", "dataset_titles": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "datasets": [{"dataset_uid": "609519", "doi": "10.7265/N5MS3QP0", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Dome C Ice Core; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Physical Properties; Snow/ice; Snow/Ice", "people": "Anastasio, Cort; Robles, Tony", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609519"}], "date_created": "Wed, 07 Mar 2007 00:00:00 GMT", "description": "Photochemical reactions in snow can have important effects on the chemistry and composition of the snowpack as well as the overlying atmosphere. For example, recent measurements in the Antarctic and Arctic have revealed that sunlit snow releases a number of important pollutants to the atmosphere. Our ability to understand and model this chemistry is currently limited, in part because we lack fundamental photochemical information for a number of important chemical species in snow. This award supports research that will help fill this gap by characterizing the low-temperature photochemistry of three of these key species: nitrite (NO2-), nitrous acid (HNO2), and hydrogen peroxide (HOOH). We will measure quantum yields for these reactions on ice using a sensitive technique that we recently developed during a study of nitrate (NO3-) photochemistry. In addition to this basic research, we will also measure the rates of formation of hydroxyl radical (OH), nitrogen oxides (NOx), and HOOH in illuminated Antarctic snow samples. These measurements will be important inputs for future models, and will allow us to test whether known species (e.g., NO3-, NO2- and HNO2) are responsible for most of snowpack reactivity (e.g., OH formation). Overall, results from this award will significantly improve our ability to understand snowpack chemistry, and the resulting effects on the atmosphere, both in the Antarctic as well as in the many other regions with permanent or seasonal snow. These results will also strengthen efforts to use ice core records to monitor global change. In addition to these impacts, this award will help train students and a postdoctoral fellow, and results from this work will be integrated into two classes in order to expose students to some of the important issues facing polar regions.", "east": 123.37278, "geometry": "POINT(123.33646 -75.1025545)", "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PHOTOMETERS \u003e SPECTROPHOTOMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e HPLC; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Snow Chemistry; Antarctica; Snowpack Chemistry; Snow Samples; Hydrogen Peroxide; Snow Properties; Pollutants; Chemistry; Light Absorption; Antarctic; Chemical Species; Snow; East Antarctica; Organic Compounds; Photochemistry; LABORATORY", "locations": "Antarctica; East Antarctica; Antarctic", "north": -75.093445, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Anastasio, Cort; Robles, Tony", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Dome C Ice Core", "south": -75.111664, "title": "Laboratory Studies of Photochemistry in Antarctic Snow and Ice", "uid": "p0000175", "west": 123.30014}, {"awards": "0337933 Cole-Dai, Jihong; 0338363 Thiemens, Mark", "bounds_geometry": null, "dataset_titles": "Major Ion Concentrations in 2004 South Pole Ice Core", "datasets": [{"dataset_uid": "609542", "doi": "10.7265/N5HX19N8", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Major Ion Concentrations in 2004 South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609542"}], "date_created": "Fri, 11 Aug 2006 00:00:00 GMT", "description": "This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Not provided; Ion Chromatograph; Ions; LABORATORY; GROUND-BASED OBSERVATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Investigating Atmospheric Chemistry and Dynamics through Oxygen and Sulfur Isotopes in Volcanic Sulfate from South Pole Ice Cores", "uid": "p0000031", "west": null}, {"awards": "0126343 Nishiizumi, Kunihiko", "bounds_geometry": "POINT(-148.812 -81.6588)", "dataset_titles": "Cosmogenic Radionuclides in the Siple Dome A Ice Core", "datasets": [{"dataset_uid": "609307", "doi": "10.7265/N5XK8CGS", "keywords": "Antarctica; Geochemistry; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Nishiizumi, Kunihiko; Finkel, R. C.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Cosmogenic Radionuclides in the Siple Dome A Ice Core", "url": "https://www.usap-dc.org/view/dataset/609307"}], "date_created": "Mon, 12 Jun 2006 00:00:00 GMT", "description": "This award supports a three-year renewal project to complete measurement of cosmogenic nuclides in the Siple Dome ice core as part of the West Antarctic ice core program. The investigators will continue to measure profiles of Beryllium-10 (half-life = 1.5x10 6 years) and Chlorine-36 (half-life = 3.0x10 5 years) in the entire ice core which spans the time period from the present to about 100 kyr. It will be particularly instructive to compare the Antarctic record with the detailed Arctic record that was measured by these investigators as part of the GISP2 project. This comparison will help separate global from local effects at the different drill sites. Cosmogenic radionuclides in polar ice cores have been used to study the long-term variations in several important geophysical variables, including solar activity, geomagnetic field strength, atmospheric circulation, snow accumulation rates, and others. The time series of nuclide concentrations resulting from this work will be applied to several problem areas: perfecting the ice core chronology, deducing the history of solar activity, deducing the history of variations in the geomagnetic field, and studying the possible role of solar variations on climate. Comparison of Beryllium-10 and Chlorine-36 profiles in different cores will allow us to improve the ice core chronology and directly compare ice cores from different regions of the globe. Additional comparison with the Carbon-14 record will allow correlation of the ice core paleoenvironment record to other, Carbon-14 dated, paleoclimate records.", "east": -148.812, "geometry": "POINT(-148.812 -81.6588)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e AMS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; Antarctica; Ice Core; Cosmogenic Radionuclides; Chlorine-36; GROUND STATIONS; Beryllium-10; Siple Dome; West Antarctica", "locations": "Antarctica; Siple Dome; West Antarctica", "north": -81.6588, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Finkel, R. C.; Nishiizumi, Kunihiko", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.6588, "title": "Cosmogenic Radionuclides in the Siple Dome Ice Core", "uid": "p0000358", "west": -148.812}, {"awards": "9316564 Mayewski, Paul", "bounds_geometry": null, "dataset_titles": "Ross Ice Drainage System (RIDS) Glaciochemical Analysis; Siple Dome Ice Core Chemistry and Ion Data", "datasets": [{"dataset_uid": "609266", "doi": "10.7265/N5M906KG", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; Snow Pit", "people": "Whitlow, Sallie; Kreutz, Karl; Twickler, Mark; Meeker, Loren D.; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": null, "title": "Ross Ice Drainage System (RIDS) Glaciochemical Analysis", "url": "https://www.usap-dc.org/view/dataset/609266"}, {"dataset_uid": "609251", "doi": "", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Dunbar, Nelia; Severinghaus, Jeffrey P.; Mayewski, Paul A.; Kreutz, Karl; Blunier, Thomas; Brook, Edward J.", "repository": "NCEI", "science_program": "Siple Dome Ice Core", "title": "Siple Dome Ice Core Chemistry and Ion Data", "url": "https://www.ncei.noaa.gov/access/paleo-search/study/2461"}], "date_created": "Thu, 26 Aug 2004 00:00:00 GMT", "description": "9316564 Mayewski This award is for support for a three year program to provide a high resolution record of the Antarctic climate through the acquisition, analysis, and interpretation of records of atmospheric chemical deposition taken from three ice cores located at sites within or immediately adjacent to the Ross Ice Drainage System (RIDS). These cores include one from Taylor Dome, and two from West Antarctic locations identified as potential deep drilling sites for the WAISCORES program. Collection of the two West Antarctic cores is intended to be a lightweight dry-drilling operation to depths of ~ 200 m, which will provide records of \u003e 2 kyr. Glaciochemical analyses will focus on the major cations and anions found in the antarctic atmosphere, plus methanesulfonic acid and selected measurements of the hydrogen ion, aluminum, iron, and silica. These analyses, and companion stable isotope and particle measurements to be carried out by other investigators require \u003c 7% by volume of each core, leaving \u003e 90% for other investigators and storage at the U.S. National Ice Core Laboratory. These records are intended to solve a variety of scientific objectives while also providing spatial sampling and reconnaissance for future U.S. efforts in West Antarctica. ***", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Magnesium; GROUND STATIONS; Nitrate; Methane Sulfonic Acid; Sodium; Ice Core Chemistry; Ammonium (NH4); Sulfate; Ice Core; Chloride; Potassium (k); Calcium (ca)", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Kreutz, Karl; Twickler, Mark; Whitlow, Sallie; Blunier, Thomas; Dunbar, Nelia; Brook, Edward J.; Mayewski, Paul A.; Meeker, Loren D.; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "NCEI; USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Ross Ice Drainage System (RIDS) Late Holocene Climate Variability", "uid": "p0000145", "west": null}, {"awards": "8411018 Frisic, David", "bounds_geometry": null, "dataset_titles": "Dominion Range Ice Core Beta Profiles, Chemistry, and Density Data; Newall Glacier Ice Core and Snow Pit Beta Profiles, Chemistry, and Stratigraphy; Newall Glacier Snow Pit and Ice Core, 1987 to 1989", "datasets": [{"dataset_uid": "609088", "doi": "10.7265/N5JM27JP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Newall Glacier; Paleoclimate; Snow/ice; Snow/Ice", "people": "Whitlow, Sallie; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": null, "title": "Newall Glacier Snow Pit and Ice Core, 1987 to 1989", "url": "https://www.usap-dc.org/view/dataset/609088"}, {"dataset_uid": "609249", "doi": "", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Newall Glacier; Paleoclimate; Physical Properties; Snow/ice; Snow/Ice; Statigraphy", "people": "Welch, Kathy A.; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": null, "title": "Newall Glacier Ice Core and Snow Pit Beta Profiles, Chemistry, and Stratigraphy", "url": "https://www.usap-dc.org/view/dataset/609249"}, {"dataset_uid": "609248", "doi": "", "keywords": "Antarctica; Beta Profiles; Chemistry:ice; Chemistry:Ice; Density; Dominion Range; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Physical Properties", "people": "Watson, M. Scott; Grootes, Pieter; Meese, Deb; Mayewski, Paul A.; Sowers, Todd A.; Saltzman, Eric; Gow, Tony", "repository": "USAP-DC", "science_program": null, "title": "Dominion Range Ice Core Beta Profiles, Chemistry, and Density Data", "url": "https://www.usap-dc.org/view/dataset/609248"}], "date_created": "Thu, 26 Aug 2004 00:00:00 GMT", "description": "Not available", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "GROUND STATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Frisic, David; Meese, Deb; Gow, Tony; Saltzman, Eric; Mayewski, Paul A.; Sowers, Todd A.; Welch, Kathy A.; Grootes, Pieter; Watson, M. Scott; Grootes, Peiter", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Characterization of Climatic Events for the Last 2 x 103y through the Retrieval of Ice Cores from the Transantarctic Mountains, Antarctica", "uid": "p0000169", "west": null}, {"awards": "0087151 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Sulfate-Based Volcanic Record from South Pole Ice Core", "datasets": [{"dataset_uid": "609215", "doi": "10.7265/N5CR5R88", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Solid Earth; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Sulfate-Based Volcanic Record from South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609215"}], "date_created": "Fri, 09 Apr 2004 00:00:00 GMT", "description": "This award supports a two year project to analyze shallow (~150 m) ice cores from South Pole in order to construct an annually resolved, sulfate-based volcanic record covering the last 1400 years. Two shallow ice cores will be recovered at the South Pole during the 00/01 field season and will be used for this work. Volcanic records from polar ice cores provide valuable information for studies of the connection between volcanism and climate. The new records are expected to be continuous and to cover at least the last 1400 years. The information from these records will verify the volcanic events found in the few existing Antarctic records and resolve discrepancies in the timing and magnitude of major explosive eruptions \u003cbr/\u003edetermined from those earlier records. In order to achieve the objectives of the proposed research, funds are provided to assist with the construction of an analytical laboratory for ice core and environmental \u003cbr/\u003echemistry research.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core; Snow Chemistry; West Antarctica; GROUND-BASED OBSERVATIONS; Antarctica; Ice Core Gas Records; Ion Chemistry; Ice Core Data", "locations": "West Antarctica; Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "A Sulfate-based Volcanic Record from South Pole Ice Cores", "uid": "p0000167", "west": null}, {"awards": "9526572 Bales, Roger", "bounds_geometry": null, "dataset_titles": "Snow-atmosphere Transfer Function for Reversibly Deposited Chemical Species in West Antarctica", "datasets": [{"dataset_uid": "609122", "doi": "10.7265/N5ZP441W", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Siple Dome; Snow/ice; Snow/Ice; WAISCORES", "people": "McConnell, Joseph; Bales, Roger", "repository": "USAP-DC", "science_program": null, "title": "Snow-atmosphere Transfer Function for Reversibly Deposited Chemical Species in West Antarctica", "url": "https://www.usap-dc.org/view/dataset/609122"}], "date_created": "Thu, 11 Jul 2002 00:00:00 GMT", "description": "This award is for support for a program of measurements to improve our understanding of the relationship between formaldehyde (HCHO) and hydrogen peroxide (H2O2) in the atmosphere and the concentrations of the same species in Antarctic snow, firn and ice. This work aims to relate changes in concentrations in the snow, firn and ice to corresponding changes in tropospheric chemistry. Atmospheric and firn sampling for formaldehyde and hydrogen peroxide at one or more of the WAIS ice core drilling sites will be undertaken and controlled laboratory studies to estimate thermodynamic and rate parameters will be performed. In addition, this work will involve modeling of atmosphere-snow exchange processes to infer the \"transfer function\" for reactive species at the sites and atmospheric photochemical modeling to relate changes in concentrations of formaldehyde and hydrogen peroxide in snow, firn and ice to atmospheric oxidation capacity. This work will contribute to a better understanding of the relationship between atmospheric concentrations of various species and those same species measured in snow and ice samples.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "Siple Dome; Antarctica; Isotope; WAISCORES; GROUND-BASED OBSERVATIONS; GROUND STATIONS; Snow; Glaciology; LABORATORY; Siple; Siple Coast; Thermometry; Hydrogen Peroxide; Ice Sheet", "locations": "Antarctica; Siple; Siple Coast; Siple Dome", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Bales, Roger; McConnell, Joseph", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Snow-Atmosphere Transfer Function for Reversibly Deposited Chemical Species in West Antarctica", "uid": "p0000060", "west": null}, {"awards": "9526449 Mayewski, Paul", "bounds_geometry": null, "dataset_titles": "WAISCORES Snow Pit Chemistry, Antarctica", "datasets": [{"dataset_uid": "609420", "doi": "10.7265/N5SQ8XBR", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; Snow Pit; WAIS; WAISCORES", "people": "Kreutz, Karl; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": null, "title": "WAISCORES Snow Pit Chemistry, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609420"}], "date_created": "Thu, 11 Jul 2002 00:00:00 GMT", "description": "This award is for support for a program of glaciochemical analyses of shallow and deep ice cores from Siple Dome, West Antarctica. Measurements that have been proposed include chloride, nitrate, sulfate, calcium, magnesium, sodium, potassium, ammonium and methansulfonic acid. These measurements will provide information about past volcanic events, biomass source strength, sea ice fluctuations, atmospheric circulation, changes in ice-free areas and the environmental response to Earth orbit insolation changes and solar variability. The glaciochemical records from the Siple Dome core will be developed at a resolution sufficient to compare with the Summit, Greenland record, thus allowing a bipolar comparison of climate change event timing and magnitude. As part of this award, an international workshop will be held during the first year to formulate a science plan for the International Transantarctic Scientific Expedition (ITASE), a program of regional surveys documenting the spatial distribution of properties measured in ice cores .", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "Ion Chemistry; Antarctic; Snow Chemistry; Stable Isotopes; Snow Density; Siple Dome; GROUND-BASED OBSERVATIONS", "locations": "Antarctic; Siple Dome", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Kreutz, Karl; Mayewski, Paul A.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Siple Dome Deep Ice Core Glaciochemistry and Regional Survey - A Contribution to the WAIS Initiative", "uid": "p0000012", "west": null}]
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Phytoplankton, or microscopic marine algae, are an important part of the carbon cycle and can lower the rates of atmospheric carbon dioxide by transferring the atmospheric carbon into the oceans. The concentration of phytoplankton in the Southern Ocean is regularly limited by the availability of marine iron. This in turn influences the rate of carbon transfer from the atmosphere to the ocean. The primary source of iron in the Southern Ocean is eroded continental rock. Understanding the current and future sources of iron to the Southern Ocean as a result of increased melting of terrestrial glaciers is necessary for predicting future concentrations of Southern Ocean phytoplankton and the subsequent influence on the carbon cycle. A poorly understood source of iron to the Southern Ocean is stream input from ice-free regions such as the McMurdo Dry Valleys in Antarctica. This source of iron is likely to become larger if glaciers retreat. This study investigates the sources and amount of iron transported by McMurdo Dry Valley streams directly into the Southern Ocean. Because not all forms of iron can be used by phytoplankton, experiments will be performed to determine how available iron is to phytoplankton and how iron mixes with seawater. Immersive 360-degree video, infographics, and educational videos of findings from this project will be shared on social media, at schools and science events, and in an urban science center. In the Southern Ocean (SO) there is an excess of macronutrients but regional primary production is limited or co-limited due to iron. An addition of iron to the ocean will affect biochemical cycles, increase primary production, and affect the structure and composition of phytoplankton communities in the SO. Iron flux to the SO is globally significant, as increased Fe fertilization leads to increased carbon sequestration which acts as a negative feedback to increased atmospheric pCO2. One source of potentially bioavailable iron to the coastal regions of the SO is from direct sub-aerial stream discharge in ice-free areas of Antarctica, a source that may become more important if terrestrial glaciers retreat. It is imperative to understand the source, nature, potential fate, and flux of iron to the SO if better predictive models for the carbon cycle and atmospheric chemistry are to be developed. This project will investigate in-stream processes and characteristics controlling dissolved iron draining into the Ross Sea including photoreduction, temperature, and complexation with organic matter. The novel study will quantify bioavailability of particulate iron and bioavailability of dissolved iron in Antarctic in streams draining into the SO. On-site speciation measurements will be performed on dissolved iron species, particulate iron speciation will be determined using high-resolution spectroscopy, mixing experiments will be performed with coastal marine water, and the bioavailability of Fe will be determined through marine bioassays. This project will provide two students with valuable Antarctic field experience and reach thousands of individuals through existing partnerships with K-12 schools, public STEM events, an urban science center, and a strong social media presence. This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
Antarctic groundwater drives the regional carbon cycle and can accelerate permafrost thaw shaping Antarctic surface features. However, groundwater extent, flow, and processes on a continent virtually locked in ice are poorly understood. The proposed work investigates the interplay between groundwater, sediment, and ice in Antarctica's cold desert landscape to determine when, where, and why Antarctic groundwater is flowing, and how it may evolve Antarctic frozen deserts from dry and stable to wet and dynamic. Mapping the changing extent of Antarctic near-surface groundwater requires the ability to measure soil moisture rapidly and repeatedly over large areas. The research will capture changes in near-surface groundwater distribution through an unmanned aerial vehicle (UAV) mapping approach. The project integrates a diverse range of sensors with new UAV technologies to provide a higher-resolution and more frequent assessment of Antarctic groundwater extent and composition than can be accomplished using satellite observations alone. To complement the research objectives, the PI will develop a new UAV summer field school, the Geosciences UAV Academy, focused on training undergraduate-level UAV pilots in conducting novel earth sciences research using cutting edge imaging tools. The integration of research and technology will prepare students for careers in UAV-related industries and research. The project will deliver new UAV tools and workflows for soil moisture mapping relevant to arid regions including Antarctica as well as temperate desert and dryland systems and will train student research pilots to tackle next generation airborne challenges. Water tracks are the basic hydrological unit that currently feeds the rapidly-changing permafrost and wetlands in the Antarctic McMurdo Dry Valleys (MDV). Despite the importance of water tracks in the MDV hydrologic cycle and their influence on biogeochemistry, little is known about how these water tracks control the unique brine processes operating in Antarctic ice-free areas. Both groundwater availability and geochemistry shape Antarctic microbial communities, connecting soil geology and hydrology to carbon cycling and ecosystem functioning. The objectives of this CAREER proposal are to 1) map water tracks to determine the spatial distribution and seasonal magnitude of groundwater impacts on the MDV near-surface environment to determine how near-surface groundwater drives permafrost thaw and enhances chemical weathering and biogeochemical cycling; 2) establish a UAV academy training earth sciences students to answer geoscience questions using drone-based platforms and remote sensing techniques; and 3) provide a formative step in the development of the PI as a teacher-scholar. UAV-borne hyperspectral imaging complemented with field soil sampling will determine the aerial extent and timing of inundation, water level, and water budget of representative water tracks in the MDV. Soil moisture will be measured via near-infrared reflectance spectroscopy while bulk chemistry of soils and groundwater will be analyzed via ion chromatography and soil x-ray fluorescence. Sedimentological and hydrological properties will be determined via analysis of intact core samples. These data will be used to test competing hypotheses regarding the origin of water track solutions and water movement through seasonal wetlands. The work will provide a regional understanding of groundwater sources, shallow groundwater flux, and the influence of regional hydrogeology on solute export to the Southern Ocean and on soil/atmosphere linkages in earth's carbon budget. The UAV school will 1) provide comprehensive instruction at the undergraduate level in both how and why UAVs can advance geoscience research and learning; and 2) provide educational infrastructure for an eventual self-sustaining summer program for undergraduate UAV education. This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
The ice of the polar ice sheets is among the purest substances on Earth, yet the small amount of impurities --such as acids-- are important to how the ice flows and what can be learned from ice cores about past climate. The goal of this project is to understand the role of such acids on the deformation of polycrystalline ice by comparing the deformation behavior of pure and sulfuric acid-doped samples. Sulfuric acid was chosen both because of its importance for interpreting past climate and because it can lead to water veins in ice at low temperatures. This work will focus on the location, movement, and impact of acids in polycrystalline ice that are more complex than in single crystals of ice. By deforming samples and performing microstructural characterization, the role of acids on deformation rate, grain evolution, and the movement of the acids themselves, will be assessed. The work will lead to the education of a Ph.D. student at Dartmouth College, introduce undergraduate students to research at both the University of Washington and Dartmouth College. Despite the ubiquitous use of the constitutive relation for ice commonly referred to as "Glen's Flow Law", significant uncertainty exists particularly with regard to the role of impurities and the development of oriented fabrics. The aim of this project is to improve the constitutive relationship for ice by performing deformation tests and microstructural characterization of pure and sulfuric acid-doped ice. The project will focus on sulfuric acid's impact on ice viscosity, fabric evolution, and diffusivity. Sulfuric acid can have both direct and indirect effects on the mechanical properties of polycrystalline ice. The direct effects change the dislocation velocity and/or density, and the indirect effects change the grain size and fabric. The complexity and interaction of these effects means that it is not possible to understand the effects of sulfuric acid by simply examining ice core specimens. In this project, the team will deform four types of ice: lab-grown ice samples doped with similar-to-natural concentrations of sulfuric acid, lab-grown high-purity ice, layered doped and pure ice, and natural ice from Antarctic ice cores. Deformation will be performed in both uniaxial compression and simple shear. The addition of simple shear tests is critical for relating the laboratory-observed deformation behavior to the behavior of polar ice sheets where the shear strain dominates ice motion in basal ice. After deformation to strains from 5 percent up to 25 percent, the microstructural development will be assessed with methods including a variety of scanning electron microscope techniques, Raman microscopy, synchrotron-based Nano-X-ray fluorescence, and ion chromatography. These analysis techniques will allow the determination of 1) the segregation and movement of impurities, 2) the rate of grain-boundary migration, 3) the number of recrystallized grains; and 4) the full orientation of the ice crystals. The results will enable both microstructural modeling of the effects of sulfuric acid and numerical modeling of diffusion in ice cores. The net result will be a better understanding of ice deformation that improves ice-core interpretation and ice-sheet modeling. This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
The project will characterize the functional, taxonomic, biotic and abiotic drivers of soil ecosystems in the Trans Antarctic Mountains (one of the most remote and harsh terrestrial landscapes on the planet). The work will utilize new high-throughput DNA and RNA sequencing technologies to identify members of the microbial communities and determine if the microbial community structures are independent of local environmental heterogeneities. In addition the project will determine if microbial diversity and function are correlated with time since the last glacial maximum (LGM). The expected results will greatly contribute to our knowledge regarding rates of microbial succession and help define the some of the limits to life and life-maintaining processes on Earth. The project will analyze genomes and RNA derived from these genomes to describe the relationships between biodiversity and ecosystem functioning from soils above and below LGM elevations and to correlate these with the environmental drivers associated with their development during the last ~18,000 years. The team will identify the taxonomic diversity and the functional genetic composition within a broad suite of soil biota and examine their patterns of assembly and distribution within the framework of their geological legacies. The project will mentor participants from undergraduate students to postdoctoral researchers and prepare them to effectively engage in research to meet their career aspirations. The project will contribute to ongoing public education efforts through relationships with K-12 teachers and administrators- to include University-Public School partnerships. Less formal activities include public lecture series and weblogs aimed at providing information on Antarctic polar desert ecosystems to the general public. Targeted classrooms near each PI's institution will participate in online, real-time discussions about current topics in Antarctic ecosystems research.
This collaborative project explores the signatures and causes of natural climate change in the region surrounding Antarctica over the last 40,000 years as the Earth transitioned from an ice age into the modern warm period. The researchers will investigate how the wind belts that surround Antarctica changed in their strength and position through time, and document explosive volcanic eruptions and CO2 cycling in the Southern Ocean as potential climate forcing mechanisms over this interval. Understanding how and why the climate varied naturally in the past is critical for improving understanding of modern climate change and projections of future climate under higher levels of atmospheric CO2. The investigators plan to conduct a suite of chemical measurements along the 1500m length of the South Pole Ice Core, including major ion and trace element concentrations, and microparticle (dust) concentrations and size distributions. These measurements will (1) extend the South Pole record of explosive volcanic eruptions to 40,000 years using sulfate and particle data; (2) establish the relative timing of climate changes in dust source regions of Patagonia, New Zealand, and Australia using dust flux data; (3) investigate changes in the strength and position of the westerly wind belt using dust size distribution data; and (4) quantify the flux of bioavailable trace metals deposited as dust to the Southern Ocean over time. These chemistry records will also be critical for creating the timescale that will be used by all researchers studying records from the South Pole core. The project will support four graduate students and several undergraduate students across three different institutions, and become a focus of the investigators' efforts to disseminate outcomes of climate change science to the broader community.
Cole-Dai/0839066<br/><br/>This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).<br/><br/>This award supports a project to make continuous major ion analyses in the West Antarctica Ice Sheet Divide (WAIS Divide) ice core by sampling the brittle ice zone (approximately from 500 m to 1500 m). The intellectual merit of the project is that these will likely be the only chemical measurements on the brittle ice zone and, therefore, will bridge the gap in the expected continuous records of climate, ice sheet dynamics and biological evolution based on chemical measurements. High resolution sampling and analysis, probably on selected portions and depth intervals in the brittle ice zone, will help with the independent, high-precision dating of the WAIS Divide core and contribute to the achievement of the major objectives of the WAIS Divide project?development of high resolution climate records with which to investigate issues of climate forcing by greenhouse gases and the role of Antarctica and Southern Hemisphere in the global climate system. Planned collaboration with other WAIS Divide investigators will develop the longest and most detailed volcanic record from Antarctica ice cores. The broader impacts of this project include a contribution to enhancing our knowledge of the climate system. Such improvements in understanding of the global climate system and the ability to predict the magnitude and uncertainty of future changes are highly relevant to the global community. The project will support post-doctoral scientists and graduate students, including those from under-represented groups, will contribute to education, an help to train future scientists and promote diversity in research and education. Public outreach activities of this project will contribute to informal science education of school age children in the Eastern South Dakota region.
This award supports a project to fully characterize the microstructure in ice cores, in particular the microstructural locations of impurities, grain orientations and strain gradients. This work will complement the optical observations, electrical conductivity measurement, and precise, detailed measurements of the soluble ion and gas contents that are performed by others. Linking the concentrations of soluble ions and gases, measured to a few parts per billion, to the optically determined annual layer structure and the stable isotope data in ice cores has enabled a great deal to be established about the concentrations and depth/age distributions of particles, trace gases and impurities for several polar ice cores. Ice core studies carried out by several groups contribute immensely to our understanding of paleoclimate and, to our ability to predict future climate change. The work will build on previous measurements and technique development in this area, as well as focusing on new techniques to characterize ice cores. The work will use both scanning electron microscopy (SEM) coupled with X-ray energy dispersive spectroscopy (EDS) and confocal scanning optical microscopy coupled with Raman spectroscopy (RS) to determine the microstructural locations of impurities and correlate this information with depth/age, and impurity type and concentration for several polar ice cores. The Broader Impacts of the proposed work are that knowledge of the location of impurities coupled with the grain orientation (both c- and a-axis) and grain misorientation information will allow paleoclimatologists to better interpret ice core data and other scientists to understand and model the physical and mechanical properties of natural ice sheets. Other Broader Impacts of the work are that the work will be performed and lead to the education of a Ph.D. student. At the end of the project, as well as the knowledge gained from coursework, the graduate student will have experience in ice core specimen preparation and characterization using scanning electron microscopy, x-ray microanalysis, confocal scanning microscopy, Raman spectroscopy and ion chromatography. Results from the research will be published in refereed journals, presented at conferences, and placed on a web page.
0538674<br/>Matsuoka<br/>This award supports a project to evaluate radio-echo intensities in the available SOAR ice-penetrating radar data along grids covering Lake Vostok, and along four regional tracks from Ridge B toward the lake. The project has two objectives; first, it will examine the upper surface of the lake and reflectors hypothesized to be a boundary between the meteoric and accreted ice. They will provide crucial knowledge on the dynamic evolution of the lake. Second, this project will examine a poorly understood echo-free zone within the deep ice in central East Antarctica. This zone may consist of distorted stagnant ice, while its upper boundary may be a shear zone. The SOAR radar data provide a unique resource to examine spatiotemporal water circulation patterns that should be understood in order to select the best direct-sampling strategy to the lake. The Vostok ice core provides a unique opportunity to do this work. First, the path effects, i.e. propagation loss and birefringence, will be derived at the ice-core site using ice temperature, chemistry, and fabric data. Second, lateral variations of the propagation loss will be estimated by tracking chemistry associated with radar-detected isochronous layers, and by inferring temperatures from an ice-flow model that can replicate those layers. Ice-fabric patterns will be inferred from anisotropy in the reflectivity at about 100 radar-track cross-over sites. In terms of broader impacts, a graduate student will be trained to interpret the radar data in the light of radar theory and glaciological context of Lake Vostok and summer workshops for K-12 teachers will be provided in Seattle and New York. This project will contribute to ongoing efforts to study Lake Vostok and will complement the site selection for a North Vostok ice core, which has been proposed by Russia and France as an IPY program.
This award supports a project to perform continuous microparticle concentration and size distribution measurements (using coulter counter and state-of-the-art laser detector methods), analysis of biologically relevant trace elements associated with microparticles (Fe, Zn, Co, Cd, Cu), and tephra measurements on the WAIS Divide ice core. This initial three-year project includes analysis of ice core spanning the instrumental (~1850-present) to mid- Holocene (~5000 years BP) period, with sample resolution ranging from subannual to decadal. The intellectual merit of the project is that it will help in establishing the relationships among climate, atmospheric aerosols from terrestrial and volcanic sources, ocean biogeochemistry, and greenhouse gases on several timescales which remain a fundamental problem in paleoclimatology. The atmospheric mineral dust plays an important but uncertain role in direct radiative forcing, and the microparticle datasets produced in this project will allow us to examine changes in South Pacific aerosol loading, atmospheric dynamics, and dust source area climate. The phasing of changes in aerosol properties within Antarctica, throughout the Southern Hemisphere, and globally is unclear, largely due to the limited number of annually dated records extending into the glacial period and the lack of a<br/>tephra framework to correlate records. The broader impacts of the proposed research are an interdisciplinary approach to climate science problems, and will contribute to several WAIS Divide science themes as well as the broader paleoclimate and oceanographic communities. Because the research topics have a large and direct societal relevance, the project will form a centerpiece of various outreach efforts at UMaine and NMT including institution websites, public speaking, local K-12 school interaction, media interviews and news releases, and popular literature. At least one PhD student and one MS student will be directly supported by this project, including fieldwork, core processing, laboratory analysis, and data interpretation/publication. We expect that one graduate student per year will apply for a core handler/assistant driller position through the WAIS Divide Science Coordination Office, and that undergraduate student involvement will result in several Capstone experience projects (a UMaine graduation requirement). Data and ideas generated from the project will be integrated into undergraduate and graduate course curricula at both institutions.
Cole-Dai<br/>0538553<br/><br/>This award supports a project that will contribute to the US West Antarctica Ice Sheet Ice Divide ice core (WAIS Divide) project by developing new instrumentation and analytical procedures to measure concentrations of major ions (Cl-, NO3-, SO42-, Na+, K+, NH4+, Mg2+, Ca2+). A melter-based, continuous flow, multi-ion-chromatograph technique (CFA-IC) has been developed recently at South Dakota State University (SDSU). This project will further expand and improve the CFA-IC technique and instrumentation and develop procedures for routine analysis of major ions in ice cores. In addition, training of personnel (operators) to perform continuous, high resolution major ion analysis of the deep core will be accomplished through this project. The temporal resolution of the major ion measurement will be as low as 0.5 cm with the fully developed CFA-IC technique. At this resolution, it will be possible to use annual cycles of sulfate and sea-salt ion concentrations to determine annual layers in the WAIS Divide ice core. Annual layer counting using CFA-IC chemical measurements and other high resolution measurements will contribute significantly to the major WAIS Divide project objective of producing precisely (i.e., annually) dated climate records. The project will support the integration of research and education, train future scientists and promote human resource development through the participation of graduate and undergraduate students. In particular, undergraduate participation will contribute to a current REU (Research Experience for Undergraduates) chemistry site program at SDSU. Development and utilization of multi-user instrumentation will promote research collaboration and advance environmental science. NSF support for SDSU will contribute to the economic development and strengthen the infrastructure for research and education in South Dakota.
This award supports a project to examine an existing ice core of opportunity from South Pole (SPRESO core) to develop a 2000+ year long climate record. SPRESO ice core will be an annually dated, sub-annually-resolved reconstruction of past climate (atmospheric circulation, temperature, precipitation rate, and atmospheric chemistry) utilizing continuous, co-registered measurements (n=45) of: major ions, trace elements, and stable isotope series, plus selected sections for microparticle size and composition. The intellectual merit of this project relates to the fact that few 2000+ year records of this quality exist in Antarctica despite increasing scientific interest in this critical time period as the framework within which to understand modern climate. The scientific impact of this ice core investigation are that it will provide an in-depth understanding of climate variability; a baseline for assessing modern climate variability in the context of human activity; and a contribution to the prediction of future climate variability. The broader impact of this work is that the proposed research addresses important questions concerning the role of Antarctica in past, present, and future global change. Results will be translated into publicly accessible information through public lectures, media appearances, and an extensive outreach activity housed in our Institute. Our ice core activities provide a major basis for curriculum in K-12 and University plus a basis for several field and laboratory based graduate theses and undergraduate student projects. The project will support one PhD student for 3 years and undergraduate salaries. The Climate Change Institute has a long history of gender and ethnically diverse student and staff involvement in research.
0538494<br/>Meese<br/>This award supports a project for physical properties research on snow pits and firn/ice cores with specific objectives that include stratigraphic analysis including determination of accumulation rates, annual layers, depth hoar, ice and wind crusts and rates of grain growth with depth. Studies of firn densification rates and how these parameters relate to the meteorology and climatology over the last 200 years of snow accumulation in Antarctica will also be investigated. The project will also determine the seasonality of accumulation by co-registration of stratigraphy and chemistry and determination of chemical species at the grain boundaries, how these may change with depth/densification (and therefore temperature), precipitation, and may affect grain growth. Fabric analyses will be made, including variation with depth, location on undulations and if any variation exists with climate/chemistry. The large spatial coverage of the US ITASE program offers the opportunity to determine how these parameters are affected by a large range of temperature, precipitation and topographic effects. The intellectual merit of the project includes the fact that ITASE is the terrestrial equivalent of a polar research vessel that provides a unique, logistically efficient, multi-dimensional (x, y, z and time) view of the atmosphere, ice sheet and their histories. Physical properties measurements/ analyses are an integral part of understanding the dynamic processes to which the accumulated snow is subjected. Recent advancements in the field along with multiple core sites provide an excellent opportunity to gain a much broader understanding of the spatial, temporal and physical variables that impact firnification and the possible resultant impact on climatic interpretation. In terms of broader impacts, the data collected by US ITASE and its international ITASE partners is available to a broad scientific community. US ITASE has an extensive program of public outreach and provides significant opportunities for many students to experience multidisciplinary Antarctic research. A graduate student, a post-doctoral fellow and at least one undergraduate would be funded by this work. Dr. Meese is also a member of the New England Science Collaborative, an organization that educates the public on climate change based on recent scientific advancements.
This award is for support for three years of funding to study the effects of impurities on the flow of poly- crystalline ice. It has been known for thirty years that both hydrofluoric acid (HF) and hydrochloric acid (HCl) dramatically decrease the strength of ice and recent work by the author's group has shown that sulfuric acid (H2SO4) produces a similar reduction in strength. However, these data are for single crystals at strain rates and stresses that far exceed those found in glaciers and ice sheets, and often at concentrations that far exceed those in natural ice. Therefore, it is not known how impurities found in nature affect the flow of polycrystalline ice at slow strain rates. In this research, the effects of nitric acid and sulfuric acid (which are naturally occurring impurities in ice) on the microstructure (dislocation structure, grain boundary structure and location of the acids) and creep of polycrystalline ice (at a range of temperatures and stresses) will be determined. The ice's response to creep deformation will be studied using a combination of x-ray topography, optical microscopy and scanning electron microscopy. X-ray microanalysis in an environmental scanning electron microscope will be used to study the location of impurities. The structure and creep behavior of the acid-doped ice will be compared with those of both high-purity laboratory-grown ice and ice from Byrd Station, Antarctica. The end-result of this project will be to elucidate the effects of naturally-occurring acid impurities on the mechanical properties of polycrystalline ice under conditions relevant to the deformation of glaciers and ice sheets, including and understanding of how impurities affect the underlying deformation mechanisms.
Photochemical reactions in snow can have important effects on the chemistry and composition of the snowpack as well as the overlying atmosphere. For example, recent measurements in the Antarctic and Arctic have revealed that sunlit snow releases a number of important pollutants to the atmosphere. Our ability to understand and model this chemistry is currently limited, in part because we lack fundamental photochemical information for a number of important chemical species in snow. This award supports research that will help fill this gap by characterizing the low-temperature photochemistry of three of these key species: nitrite (NO2-), nitrous acid (HNO2), and hydrogen peroxide (HOOH). We will measure quantum yields for these reactions on ice using a sensitive technique that we recently developed during a study of nitrate (NO3-) photochemistry. In addition to this basic research, we will also measure the rates of formation of hydroxyl radical (OH), nitrogen oxides (NOx), and HOOH in illuminated Antarctic snow samples. These measurements will be important inputs for future models, and will allow us to test whether known species (e.g., NO3-, NO2- and HNO2) are responsible for most of snowpack reactivity (e.g., OH formation). Overall, results from this award will significantly improve our ability to understand snowpack chemistry, and the resulting effects on the atmosphere, both in the Antarctic as well as in the many other regions with permanent or seasonal snow. These results will also strengthen efforts to use ice core records to monitor global change. In addition to these impacts, this award will help train students and a postdoctoral fellow, and results from this work will be integrated into two classes in order to expose students to some of the important issues facing polar regions.
This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.
This award supports a three-year renewal project to complete measurement of cosmogenic nuclides in the Siple Dome ice core as part of the West Antarctic ice core program. The investigators will continue to measure profiles of Beryllium-10 (half-life = 1.5x10 6 years) and Chlorine-36 (half-life = 3.0x10 5 years) in the entire ice core which spans the time period from the present to about 100 kyr. It will be particularly instructive to compare the Antarctic record with the detailed Arctic record that was measured by these investigators as part of the GISP2 project. This comparison will help separate global from local effects at the different drill sites. Cosmogenic radionuclides in polar ice cores have been used to study the long-term variations in several important geophysical variables, including solar activity, geomagnetic field strength, atmospheric circulation, snow accumulation rates, and others. The time series of nuclide concentrations resulting from this work will be applied to several problem areas: perfecting the ice core chronology, deducing the history of solar activity, deducing the history of variations in the geomagnetic field, and studying the possible role of solar variations on climate. Comparison of Beryllium-10 and Chlorine-36 profiles in different cores will allow us to improve the ice core chronology and directly compare ice cores from different regions of the globe. Additional comparison with the Carbon-14 record will allow correlation of the ice core paleoenvironment record to other, Carbon-14 dated, paleoclimate records.
9316564 Mayewski This award is for support for a three year program to provide a high resolution record of the Antarctic climate through the acquisition, analysis, and interpretation of records of atmospheric chemical deposition taken from three ice cores located at sites within or immediately adjacent to the Ross Ice Drainage System (RIDS). These cores include one from Taylor Dome, and two from West Antarctic locations identified as potential deep drilling sites for the WAISCORES program. Collection of the two West Antarctic cores is intended to be a lightweight dry-drilling operation to depths of ~ 200 m, which will provide records of > 2 kyr. Glaciochemical analyses will focus on the major cations and anions found in the antarctic atmosphere, plus methanesulfonic acid and selected measurements of the hydrogen ion, aluminum, iron, and silica. These analyses, and companion stable isotope and particle measurements to be carried out by other investigators require < 7% by volume of each core, leaving > 90% for other investigators and storage at the U.S. National Ice Core Laboratory. These records are intended to solve a variety of scientific objectives while also providing spatial sampling and reconnaissance for future U.S. efforts in West Antarctica. ***
This award supports a two year project to analyze shallow (~150 m) ice cores from South Pole in order to construct an annually resolved, sulfate-based volcanic record covering the last 1400 years. Two shallow ice cores will be recovered at the South Pole during the 00/01 field season and will be used for this work. Volcanic records from polar ice cores provide valuable information for studies of the connection between volcanism and climate. The new records are expected to be continuous and to cover at least the last 1400 years. The information from these records will verify the volcanic events found in the few existing Antarctic records and resolve discrepancies in the timing and magnitude of major explosive eruptions <br/>determined from those earlier records. In order to achieve the objectives of the proposed research, funds are provided to assist with the construction of an analytical laboratory for ice core and environmental <br/>chemistry research.
This award is for support for a program of measurements to improve our understanding of the relationship between formaldehyde (HCHO) and hydrogen peroxide (H2O2) in the atmosphere and the concentrations of the same species in Antarctic snow, firn and ice. This work aims to relate changes in concentrations in the snow, firn and ice to corresponding changes in tropospheric chemistry. Atmospheric and firn sampling for formaldehyde and hydrogen peroxide at one or more of the WAIS ice core drilling sites will be undertaken and controlled laboratory studies to estimate thermodynamic and rate parameters will be performed. In addition, this work will involve modeling of atmosphere-snow exchange processes to infer the "transfer function" for reactive species at the sites and atmospheric photochemical modeling to relate changes in concentrations of formaldehyde and hydrogen peroxide in snow, firn and ice to atmospheric oxidation capacity. This work will contribute to a better understanding of the relationship between atmospheric concentrations of various species and those same species measured in snow and ice samples.
This award is for support for a program of glaciochemical analyses of shallow and deep ice cores from Siple Dome, West Antarctica. Measurements that have been proposed include chloride, nitrate, sulfate, calcium, magnesium, sodium, potassium, ammonium and methansulfonic acid. These measurements will provide information about past volcanic events, biomass source strength, sea ice fluctuations, atmospheric circulation, changes in ice-free areas and the environmental response to Earth orbit insolation changes and solar variability. The glaciochemical records from the Siple Dome core will be developed at a resolution sufficient to compare with the Summit, Greenland record, thus allowing a bipolar comparison of climate change event timing and magnitude. As part of this award, an international workshop will be held during the first year to formulate a science plan for the International Transantarctic Scientific Expedition (ITASE), a program of regional surveys documenting the spatial distribution of properties measured in ice cores .