USAP-DC

{"dp_type": "Project", "free_text": "Gas Record"}

[{"awards": "1643722 Brook, Edward J.", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole Ice Core Methane Data and Gas Age Time Scale; South Pole ice core (SPC14) total air content (TAC)", "datasets": [{"dataset_uid": "601546", "doi": "10.15784/601546", "keywords": "Antarctica; South Pole", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) total air content (TAC)", "url": "https://www.usap-dc.org/view/dataset/601546"}, {"dataset_uid": "601329", "doi": "10.15784/601329", "keywords": "Antarctica; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; South Pole", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Methane Data and Gas Age Time Scale", "url": "https://www.usap-dc.org/view/dataset/601329"}], "date_created": "Tue, 02 Jun 2020 00:00:00 GMT", "description": "This award supports a project to measure the concentration of the gas methane in air trapped in an ice core collected from the South Pole. The data will provide an age scale (age as a function of depth) by matching the South Pole methane changes with similar data from other ice cores for which the age vs. depth relationship is well known. The ages provided will allow all other gas measurements made on the South Pole core (by the PI and other NSF supported investigators) to be interpreted accurately as a function of time. This is critical because a major goal of the South Pole coring project is to understand the history of rare gases in the atmosphere like carbon monoxide, carbon dioxide, ethane, propane, methyl chloride, and methyl bromide. Relatively little is known about what controls these gases in the atmosphere despite their importance to atmospheric chemistry and climate. Undergraduate assistants will work on the project and be introduced to independent research through their work. The PI will continue visits to local middle schools to introduce students to polar science, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) as part of the project. \u003cbr/\u003e\u003cbr/\u003eMethane concentrations from a major portion (2 depth intervals, excluding the brittle ice-zone which is being measured at Penn State University) of the new South Pole ice core will be used to create a gas chronology by matching the new South Pole ice core record with that from the well-dated WAIS Divide ice core record. In combination with measurements made at Penn State, this will provide gas dating for the entire 50,000-year record. Correlation will be made using a simple but powerful mid-point method that has been previously demonstrated, and other methods of matching records will be explored. The intellectual merit of this work is that the gas chronology will be a fundamental component of this ice core project, and will be used by the PI and other investigators for dating records of atmospheric composition, and determining the gas age-ice age difference independently of glaciological models, which will constrain processes that affected firn densification in the past. The methane data will also provide direct stratigraphic markers of important perturbations to global biogeochemical cycles (e.g., rapid methane variations synchronous with abrupt warming and cooling in the Northern Hemisphere) that will tie other ice core gas records directly to those perturbations. A record of the total air content will also be produced as a by-product of the methane measurements and will contribute to understanding of this parameter. The broader impacts include that the work will provide a fundamental data set for the South Pole ice core project and the age scale (or variants of it) will be used by all other investigators working on gas records from the core. The project will employ an undergraduate assistant(s) in both years who will conduct an undergraduate research project which will be part of the student\u0027s senior thesis or other research paper. The project will also offer at least one research position for the Oregon State University Summer REU site program. Visits to local middle schools, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) will also be part of the project.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "AMD; LABORATORY; METHANE; ICE CORE RECORDS; Gas Chromatography; South Pole; USAP-DC", "locations": "South Pole", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "A High Resolution Atmospheric Methane Record from the South Pole Ice Core", "uid": "p0010102", "west": 0.0}, {"awards": "1443470 Aydin, Murat", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "South Pole ice core (SPC14) discrete methane data; SP19 Gas Chronology; SPC14 carbonyl sulfide, methyl chloride, and methyl bromide measurements from South Pole, Antarctica", "datasets": [{"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601270", "doi": "10.15784/601270", "keywords": "Antarctica", "people": "Aydin, Murat", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPC14 carbonyl sulfide, methyl chloride, and methyl bromide measurements from South Pole, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601270"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Osterberg, Erich; Buizert, Christo; Fudge, T. J.; Hood, Ekaterina; Ferris, David G.; Kennedy, Joshua A.; Kalk, Michael; Kahle, Emma; Steig, Eric J.; Winski, Dominic A.; Edwards, Jon S.; Aydin, Murat; Kreutz, Karl; Brook, Edward J.; Epifanio, Jenna; Sowers, Todd A.; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}], "date_created": "Thu, 26 Mar 2020 00:00:00 GMT", "description": "In the past, Earth\u0027s climate underwent dramatic changes that influenced physical, chemical, geological, and biological processes on a global scale. Such changes left an imprint in Earth\u0027s atmosphere, as shown by the variability in abundances of trace gases like carbon dioxide and methane. In return, changes in the atmospheric trace gas composition affected Earth\u0027s climate. Studying compositional variations of the past atmosphere helps us understand the history of interactions between global biogeochemical cycles and Earth?s climate. The most reliable information on past atmospheric composition comes from analysis of air entrapped in polar ice cores. This project aims to generate ice-core records of relatively short-lived, very-low-abundance trace gases to determine the range of past variability in their atmospheric levels and investigate the changes in global biogeochemical cycles that caused this variability. This project measures three such gases: carbonyl sulfide, methyl chloride, and methyl bromide. Changes in carbonyl sulfide can indicate changes in primary productivity and photosynthetic update of carbon dioxide. Changes in methyl chloride and methyl bromide significantly impact natural variability in stratospheric ozone. In addition, the processes that control atmospheric levels of methyl chloride and methyl bromide are shared with those controlling levels of atmospheric methane. The measurements will be made in the new ice core from the South Pole, which is expected to provide a 40,000-year record.\u003cbr/\u003e\u003cbr/\u003eThe primary focus of this project is to develop high-quality trace gas records for the entire Holocene period (the past 11,000 years), with additional, more exploratory measurements from the last glacial period including the period from 29,000-36,000 years ago when there were large changes in atmospheric methane. Due to the cold temperatures of the South Pole ice, the proposed carbonyl sulfide measurements are expected to provide a direct measure of the past atmospheric variability of this gas without the large hydrolysis corrections that are necessary for interpretation of measurements from ice cores in warmer settings. Furthermore, we will test the expectation that contemporaneous measurements from the last glacial period in the deep West Antarctic Ice Sheet Divide ice core will not require hydrolysis loss corrections. With respect to methyl chloride, we aim to verify and improve the existing Holocene atmospheric history from the Taylor Dome ice core in Antarctica. The higher resolution of our measurements compared with those from Taylor Dome will allow us to derive a more statistically significant relationship between methyl chloride and methane. With respect to methyl bromide, we plan to extend the existing 2,000-year database to 11,000 years. Together, the methyl bromide and methyl chloride records will provide strong measurement-based constraints on the natural variability of stratospheric halogens during the Holocene period. In addition, the methyl bromide record will provide insight into the correlation between methyl chloride and methane during the Holocene period due to common sources and sinks.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "NOT APPLICABLE; CARBONYL SULFIDE; HALOCARBONS AND HALOGENS; TRACE GASES/TRACE SPECIES; Antarctic; USAP-DC", "locations": "Antarctic", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Carbonyl Sulfide, Methyl Chloride, and Methyl Bromide Measurements in the New Intermediate-depth South Pole Ice Core", "uid": "p0010089", "west": -180.0}, {"awards": "1443550 Brook, Edward J.", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Polar Ice Cores 3,000 Year Nitrous Oxide d15N and d18O Data; SPICEcore Holocene CO2 and N2O data", "datasets": [{"dataset_uid": "200055", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Polar Ice Cores 3,000 Year Nitrous Oxide d15N and d18O Data", "url": "https://www.ncdc.noaa.gov/paleo-search/study/25530"}, {"dataset_uid": "601197", "doi": "10.15784/601197", "keywords": "Antarctica; Carbon Dioxide; Ice Core Gas Records; Nitrous Oxide; South Pole; SPICEcore", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPICEcore Holocene CO2 and N2O data", "url": "https://www.usap-dc.org/view/dataset/601197"}], "date_created": "Tue, 06 Aug 2019 00:00:00 GMT", "description": "The temperature of the earth is controlled, in part, by heat trapping gases that include carbon dioxide, methane, and nitrous oxide. Despite their importance to climate, direct measurements of these gases in the atmosphere are limited to the last 50 years at best. Air trapped in ice cores extends those data back hundreds of millennia, and measurements of greenhouse gases in ice cores underpin much of our understanding of global chemical cycles relevant to modern climate change. Existing records vary in quality and detail. The proposed work fills gaps in our knowledge of nitrous oxide and carbon dioxide over the last 10,000 years. New measurements from an ice core from the South Pole will be used to determine what role changes in ocean and land based processes played in controlling these gases, which decreased during the first 2,000 years of this time period, then gradually increased toward the present. The work will address a major controversy over whether early human activities could have impacted the atmosphere, and provide data to improve mathematical models of the land-ocean-atmosphere system that predict how future climate change will impact the composition of the atmosphere and climate. \u003cbr/\u003e\u003cbr/\u003eFor nitrous oxide the work will improve on existing concentration records It will also develop measurement of the isotopomers of nitrous oxide and explore their utility for understanding aspects of the Holocene nitrous oxide budget. The primary goal is to determine if marine and/or terrestrial emissions of nitrous oxide change in response to changes in Holocene climate. A new Holocene isotopic record for carbon dioxide (stable carbon and oxygen isotopes), will improve the precision of existing records by a factor 5 and increase the temporal resolution. These data will be used to evaluate controversial hypotheses about why carbon dioxide concentrations changed in the Holocene and provide insight into millennial scale processes in the carbon cycle, which are not resolved by current isotopic data. A graduate student and post doc will receive advanced training during and the student and principle investigator will conduct outreach efforts targeted at local middle school students. The proposed work will also contribute to teaching efforts by the PI and to public lectures on climate and climate change. The results will be disseminated through publications, data archive, and the OSU Ice Core Lab web site. New analytical methods of wide utility will also be developed and documented.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Antarctica; ICE CORE RECORDS; CARBON DIOXIDE; NOT APPLICABLE; USAP-DC; TRACE GASES/TRACE SPECIES; NITROUS OXIDE", "locations": "Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "NCEI", "repositories": "NCEI; USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Controls on Variations in Atmospheric Carbon Dioxide and Nitrous Oxide During the Last 10,000 years", "uid": "p0010043", "west": -180.0}, {"awards": "1443710 Severinghaus, Jeffrey; 1443472 Brook, Edward J.; 1443464 Sowers, Todd", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole CH4 data for termination; South Pole Ice Core Isotopes of N2 and Ar; South Pole ice core (SPC14) discrete methane data; South Pole ice core total air content; South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2; SP19 Gas Chronology", "datasets": [{"dataset_uid": "601231", "doi": "10.15784/601231", "keywords": "Air Content; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core total air content", "url": "https://www.usap-dc.org/view/dataset/601231"}, {"dataset_uid": "601517", "doi": "10.15784/601517", "keywords": "Antarctica; Argon; Argon Isotopes; Firn; Firn Temperature Gradient; Firn Thickness; Gas Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Nitrogen; Nitrogen Isotopes; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.; Morgan, Jacob", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Isotopes of N2 and Ar", "url": "https://www.usap-dc.org/view/dataset/601517"}, {"dataset_uid": "601230", "doi": "10.15784/601230", "keywords": "Antarctica; Atmospheric CH4; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Data; Methane; Methane Concentration; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole CH4 data for termination", "url": "https://www.usap-dc.org/view/dataset/601230"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601152", "doi": "10.15784/601152", "keywords": "Antarctica; Antarctic Ice Sheet; Chemistry:gas; Chemistry:Gas; Chemistry:ice; Chemistry:Ice; Delta 18O; Dole Effect; Firn Thickness; Gas Isotopes; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Gravitational Settling; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Inert Gases; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2", "url": "https://www.usap-dc.org/view/dataset/601152"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Osterberg, Erich; Buizert, Christo; Fudge, T. J.; Hood, Ekaterina; Ferris, David G.; Kennedy, Joshua A.; Kalk, Michael; Kahle, Emma; Steig, Eric J.; Winski, Dominic A.; Edwards, Jon S.; Aydin, Murat; Kreutz, Karl; Brook, Edward J.; Epifanio, Jenna; Sowers, Todd A.; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}], "date_created": "Sat, 02 Feb 2019 00:00:00 GMT", "description": "Gases trapped in ice cores have revealed astonishing things about the greenhouse gas composition of the past atmosphere, including the fact that carbon dioxide concentrations never rose above 300 parts per million during the last 800,000 years. This places today\u0027s concentration of 400 parts per million in stark contrast. Furthermore, these gas records show that natural sources of greenhouse gas such as oceans and ecosystems act as amplifiers of climate change by increasing emissions of gases during warmer periods. Such amplification is expected to occur in the future, adding to the human-produced gas burden. The South Pole ice core will build upon these prior findings by expanding the suite of gases to include, for the first time, those potent trace gases that both trapped heat and depleted ozone during the past 40,000 years. The present project on inert gases and methane in the South Pole ice core will improve the dating of this crucial record, to unprecedented precision, so that the relative timing of events can be used to learn about the mechanism of trace gas production and destruction, and consequent climate change amplification. Ultimately, this information will inform predictions of future atmospheric chemical cleansing mechanisms and climate in the context of our rapidly changing atmosphere. This award also engages young people in the excitement of discovery and polar research, helping to entrain the next generations of scientists and educators. Education of graduate students, a young researcher (Buizert), and training of technicians, will add to the nation?s human resource base. \u003cbr/\u003e \u003cbr/\u003eThis award funds the construction of the gas chronology for the South Pole 1500m ice core, using measured inert gases (d15N and d40Ar--Nitrogen and Argon isotope ratios, respectively) and methane in combination with a next-generation firn densification model that treats the stochastic nature of air trapping and the role of impurities on densification. The project addresses fundamental gaps in scientific understanding that limit the accuracy of gas chronologies, specifically a poor knowledge of the controls on ice-core d15N and the possible role of layering and impurities in firn densification. These gaps will be addressed by studying the gas enclosure process in modern firn at the deep core site. The work will comprise the first-ever firn air pumping experiment that has tightly co-located measurements of firn structural properties on the core taken from the same borehole.\u003cbr/\u003e\u003cbr/\u003eThe project will test the hypothesis that the lock-in horizon as defined by firn air d15N, CO2, and methane is structurally controlled by impermeable layers, which are in turn created by high-impurity content horizons in which densification is enhanced. Thermal signals will be sought using the inert gas measurements, which improve the temperature record with benefits to the firn densification modeling. Neon, argon, and oxygen will be measured in firn air and a limited number of deep core samples to test whether glacial period layering was enhanced, which could explain low observed d15N in the last glacial period. Drawing on separate volcanic and methane synchronization to well-dated ice cores to create independent ice and gas tie points, independent empirical estimates of the gas age-ice age difference will be made to check the validity of the firn densification model-inert gas approach to calculating the gas age-ice age difference. These points will also be used to test whether the anomalously low d15N seen during the last glacial period in east Antarctic ice cores is due to deep air convection in the firn, or a missing impurity dependence in the firn densification models. \u003cbr/\u003e\u003cbr/\u003eThe increased physical understanding gained from these studies, combined with new high-precision measurements, will lead to improved accuracy of the gas chronology of the South Pole ice core, which will enhance the overall science return from this gas-oriented core. This will lead to clarification of timing of atmospheric gas variations and temperature, and aid in efforts to understand the biogeochemical feedbacks among trace gases. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. Ozone-depleting substances will be measured in the South Pole ice core record, and a precise gas chronology will add value. Lastly, by seeking a better understanding of the physics of gas entrapment, the project aims to have an impact on ice-core science in general.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "USAP-DC; AMD; LABORATORY; Antarctica; NITROGEN ISOTOPES; USA/NSF; METHANE; Amd/Us; FIELD INVESTIGATION", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Sowers, Todd A.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Inert Gas and Methane Based Climate Records throughout the South Pole Deep Ice Core", "uid": "p0010005", "west": 0.0}, {"awards": "1443306 Mayewski, Paul; 1443263 Higgins, John", "bounds_geometry": null, "dataset_titles": "Allan Hills ice water stable isotope record for dD, d18O; Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores; Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores; Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores; Greenhouse gas composition in the Allan Hills S27 ice core; Methane concentration in Allan Hills ice cores; Stable isotope composition of the trapped air in the Allan Hills S27 ice core; Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "datasets": [{"dataset_uid": "601201", "doi": "10.15784/601201", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Argon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Data; Ice Core Gas Records; Krypton; Mass Spectrometer; Noble Gas; Snow/ice; Snow/Ice; Xenon", "people": "Bender, Michael; Yan, Yuzhen; Severinghaus, Jeffrey P.; Ng, Jessica; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601201"}, {"dataset_uid": "601425", "doi": "10.15784/601425", "keywords": "Allan Hills; Antarctica; Blue Ice; Carbon Dioxide; Ice Core; Methane", "people": "Yan, Yuzhen; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Greenhouse gas composition in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601425"}, {"dataset_uid": "601128", "doi": "10.15784/601128", "keywords": "Allan Hills; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope Record; Mass Spectrometry; Stable Water Isotopes", "people": "Mayewski, Paul A.; Introne, Douglas; Yan, Yuzhen; Kurbatov, Andrei V.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601128"}, {"dataset_uid": "601863", "doi": null, "keywords": "Allan Hills; Antarctica; Cryosphere; Isotope Data", "people": "Introne, Douglas; Brook, Edward; Kurbatov, Andrei V.; Mayewski, Paul A.; Higgins, John; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Allan Hills ice water stable isotope record for dD, d18O", "url": "https://www.usap-dc.org/view/dataset/601863"}, {"dataset_uid": "601863", "doi": null, "keywords": "Allan Hills; Antarctica; Cryosphere; Isotope Data", "people": "Mayewski, Paul A.; Brook, Edward; Severinghaus, Jeffrey P.; Kurbatov, Andrei V.; Introne, Douglas; Higgins, John", "repository": "USAP-DC", "science_program": "COLDEX", "title": "Allan Hills ice water stable isotope record for dD, d18O", "url": "https://www.usap-dc.org/view/dataset/601863"}, {"dataset_uid": "601202", "doi": "10.15784/601202", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Carbon Dioxide; Carbon Isotopes; Chemistry:ice; Chemistry:Ice; CO2; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Data; Ice Core Gas Records; Ice Core Records; Mass Spectrometer; Mass Spectrometry; Methane; Snow/ice; Snow/Ice", "people": "Higgins, John; Bender, Michael; Brook, Edward J.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601202"}, {"dataset_uid": "601203", "doi": "10.15784/601203", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Chemistry:ice; Chemistry:Ice; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenhouse Gas; Ice; Ice Core Data; Ice Core Gas Records; Methane; Snow/ice; Snow/Ice", "people": "Bender, Michael; Higgins, John; Brook, Edward J.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Methane concentration in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601203"}, {"dataset_uid": "601129", "doi": "10.15784/601129", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Isotope Data; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Introne, Douglas; Mayewski, Paul A.; Kurbatov, Andrei V.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601129"}, {"dataset_uid": "601483", "doi": "10.15784/601483", "keywords": "Allan Hills; Antarctica; Argon; Ice; Ice Core Data; Ice Core Gas Records; Isotope; Mass Spectrometry; Nitrogen; Oxygen", "people": "Bender, Michael; Yan, Yuzhen; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601483"}, {"dataset_uid": "601512", "doi": "10.15784/601512", "keywords": "Allan Hills; Antarctica; Blue Ice; Ice Core; Ice Core Gas Records; Isotope; Nitrogen; Oxygen", "people": "Higgins, John; Yan, Yuzhen; Bender, Michael", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable isotope composition of the trapped air in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601512"}, {"dataset_uid": "601130", "doi": "10.15784/601130", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Delta Deuterium; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Gas Records; Ice Core Records; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Yan, Yuzhen; Kurbatov, Andrei V.; Mayewski, Paul A.; Introne, Douglas", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601130"}], "date_created": "Thu, 18 Oct 2018 00:00:00 GMT", "description": "Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800,000 years. Previous field expeditions to the Allan Hills blue ice area, Antarctica, have recovered ice cores that date to one million years, the oldest ice cores yet recovered from Antarctica. These records have revealed that interglacial CO2 concentrations decreased by 800,000 years ago and that, in the warmer world 1 million years ago, CO2 and Antarctic temperature were linked as during the last 800,000 years. This project will return to the Allan Hills blue ice area to recover additional ice cores that date to 1 million years or older. The climate records developed from the drilled ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Our results will help answer questions about issues associated with anthropogenic change. These include the relationship between temperature change and the mass balance of Antarctic ice; precipitation and aridity variations associated with radiatively forced climate change; and the climate significance of sea ice extent. The project will entrain two graduate students and a postdoctoral scholar, and will conduct outreach including workshops to engage teachers in carbon science and ice cores.\u003cbr/\u003e\u003cbr/\u003eBetween about 2.8-0.9 million years ago, Earth\u0027s climate was characterized by 40,000-year cycles, driven or paced by changes in the tilt of Earth\u0027s spin axis. Much is known about the \"40,000-year\" world from studies of deep-sea sediments, but our understanding of climate change during this period is incomplete because we lack records of Antarctic climate and direct records of atmospheric greenhouse gas concentrations. We propose to address these issues by building on our recent studies of ancient ice from the Main Ice Field, Allan Hills, Antarctica. During previous field seasons we recovered ice extending, discontinuously, from 0.1-1.0 million years old. Ice was dated by measuring the 40Ar/38Ar (Argon) ratio of the trapped gases. Our discovery of million year-old ice demonstrates that there is gas-record-quality ice from the 40,000-year world in the Allan Hills Main Ice Field. We have identified two different sites, each overlying bedrock at ~ 200 m depth, that are attractive targets for coring ice dating to 1 million years and older. This project aims to core the ice at these two sites, re-occupy a previous site with million year-old ice and drill it down to the bedrock, and generate 10-20 short (~10-meter) cores in areas where our previous work and terrestrial meteorite ages suggest ancient surface ice. We plan to date the ice using the 40Ar/38Ar ages of trapped Argon. We also plan to characterize the continuity of our cores by measuring the deuterium and oxygen isotope ratios in the ice, methane, ratios of Oxygen and Argon to Nitrogen in trapped gas, the Nitrogen-15 isotope (d15N) of Nitrogen, and the Oxygen-18 isotope (d18O) of Oxygen. As the ice may be stratigraphically disturbed, these measurements will provide diagnostic properties for assessing the continuity of the ice-core records. Successful retrieval of ice older than one million years will provide the opportunity for follow-up work to measure the CO2 concentration and other properties within the ice to inform on the temperature history of the Allan Hills region, dust sources and source-area aridity, moisture sources, densification conditions, global average ocean temperature, and greenhouse gas concentrations. We will analyze the data in the context of leading hypotheses of the 40,000-year world and the Mid-Pleistocene Transition to the 100,000-year world. We expect to advance understanding of climate dynamics during these periods.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Amd/Us; AMD; Allan Hills; USA/NSF; FIELD INVESTIGATION; USAP-DC; Ice Core; LABORATORY", "locations": "Allan Hills", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Mayewski, Paul A.; Kurbatov, Andrei V.; Higgins, John; Bender, Michael", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Allan Hills", "south": null, "title": "Collaborative Research: Window into the World with 40,000-year Glacial Cycles from Climate Records in Million Year-old Ice from the Allan Hills Blue Ice Area", "uid": "p0000760", "west": null}, {"awards": "1142166 McConnell, Joseph", "bounds_geometry": "POINT(-112.1115 -79.481)", "dataset_titles": "WAIS Divide Ice-Core Aerosol Records from 1300 to 3404 m", "datasets": [{"dataset_uid": "601008", "doi": "10.15784/601008", "keywords": "Aerosol; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "McConnell, Joseph", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Ice-Core Aerosol Records from 1300 to 3404 m", "url": "https://www.usap-dc.org/view/dataset/601008"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "McConnell/1142166\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to use unprecedented aerosol and continuous gas (methane, carbon monoxide) measurements of the deepest section of the West Antarctic Ice Sheet (WAIS) Divide ice core to investigate rapid climate changes in Antarctica during the ~60,000 year long Marine Isotope Stage 3 period of the late Pleistocene. These analyses, combined with others, will take advantage of the high snow accumulation of the WAIS Divide ice core to yield the highest time resolution glaciochemical and gas record of any deep Antarctic ice core for this time period. The research will expand already funded discrete gas measurements and extend currently funded continuous aerosol measurements on the WAIS Divide ice core from ~25,000 to ~60,000 years before present, spanning Heinrich events 3 to 6 and Antarctic Isotope Maximum (AIM, corresponding to the Northern Hemisphere Dansgaard-Oeschger) events 3 to 14. With other high resolution Greenland cores and lower resolution Antarctic cores, the combined record will yield new insights into worldwide climate dynamics and abrupt change. The intellectual merit of the work is that it will be used to address the science goals of the WAIS Divide project including the identification of dust and biomass burning tracers such as black carbon and carbon monoxide which reflect mid- and low-latitude climate and atmospheric circulation patterns, and fallout from these sources affects marine and terrestrial biogeochemical cycles. Similarly, sea salt and ocean productivity tracers reflect changes in sea ice extent, marine primary productivity, wind speeds above the ocean, and atmospheric circulation. Volcanic tracers address the relationship between northern, tropical, and southern climates as well as stability of the West Antarctic ice sheet and sea level change. When combined with other gas records from WAIS Divide, the records developed here will transform understanding of mid- and low-latitude drivers of Antarctic, Southern Hemisphere, and global climate rapid changes and the timing of such changes. The broader impacts of the work are that it will enhance infrastructure through expansion of continuous ice core analytical techniques, train students and support collaboration between two U.S. institutions (DRI and OSU). All data will be made available to the scientific community and the public and will include participation the WAIS Divide Outreach Program. Extensive graduate and undergraduate student involvement is planned. Student recruitment will be made from under-represented groups building on a long track record. Broad outreach will be achieved through collaborations with the global and radiative modeling communities, NESTA-related and other educational outreach efforts, and public lectures. This proposed project does not require field work in the Antarctic.", "east": -112.1115, "geometry": "POINT(-112.1115 -79.481)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -79.481, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "McConnell, Joseph", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.481, "title": "Collaborative Research: Investigating Upper Pleistocene Rapid Climate Change using Continuous, Ultra-High-Resolution Aerosol and Gas Measurements in the WAIS Divide Ice Core", "uid": "p0000287", "west": -112.1115}, {"awards": "1246148 Severinghaus, Jeffrey; 1245659 Petrenko, Vasilii; 1245821 Brook, Edward J.", "bounds_geometry": "POINT(162.167 -77.733)", "dataset_titles": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores; Last Interglacial Mean Ocean Temperature; Mean Ocean Temperature in Marine Isotope Stage 4; Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation; N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica; Taylor Glacier CO2 Isotope Data 74-59 kyr; Taylor Glacier Noble Gases - Younger Dryas; The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "datasets": [{"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "600163", "doi": "10.15784/600163", "keywords": "Antarctica; Atmosphere; Geochemistry; Ice Core Records; Isotope; Paleoclimate; Taylor Glacier; Transantarctic Mountains", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "url": "https://www.usap-dc.org/view/dataset/600163"}, {"dataset_uid": "601415", "doi": "10.15784/601415", "keywords": "Antarctica; Glaciology; Ice Core Data; Ice Core Records; Paleoclimate; Paleotemperature; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": null, "title": "Mean Ocean Temperature in Marine Isotope Stage 4", "url": "https://www.usap-dc.org/view/dataset/601415"}, {"dataset_uid": "601398", "doi": "10.15784/601398", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Gas Records; Ice Core Records; Marine Isotope Stage 4; MIS 4; Nitrous Oxide; Pleistocene; Taylor Dome Ice Core; Taylor Glacier", "people": "Dyonisius, Michael; Petrenko, Vasilii; Severinghaus, Jeffrey P.; Shackleton, Sarah; Schilt, Adrian; Brook, Edward J.; Menking, James", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601398"}, {"dataset_uid": "601198", "doi": "10.15784/601198", "keywords": "Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; CO2; Dust; Gas; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Mass Spectrometer; Methane; Nitrogen Isotopes; Oxygen Isotope; Paleoclimate; Snow/ice; Snow/Ice; Taylor Dome; Taylor Dome Ice Core", "people": "Bauska, Thomas; Menking, James; Brook, Edward J.; Marcott, Shaun; Barker, Stephen; Shackleton, Sarah; Dyonisius, Michael; Petrenko, Vasilii; McConnell, Joseph; Rhodes, Rachel; Baggenstos, Daniel; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/601198"}, {"dataset_uid": "601600", "doi": "10.15784/601600", "keywords": "Antarctica; Taylor Glacier", "people": "Menking, James; Shackleton, Sarah; Bauska, Thomas; Buffen, Aron; Brook, Edward J.; Barker, Stephen; Severinghaus, Jeffrey P.; Dyonisius, Michael; Petrenko, Vasilii; Menking, Andy", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier CO2 Isotope Data 74-59 kyr", "url": "https://www.usap-dc.org/view/dataset/601600"}, {"dataset_uid": "601260", "doi": "10.15784/601260", "keywords": "Antarctica; Carbon-14; Cosmogenic; Ice Core; Methane", "people": "Petrenko, Vasilii; Dyonisius, Michael", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601260"}, {"dataset_uid": "601176", "doi": "10.15784/601176", "keywords": "Antarctica; CO2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; Noble Gas; Noble Gas Isotopes; Snow/ice; Snow/Ice; Taylor Glacier; Younger Dryas", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Taylor Glacier Noble Gases - Younger Dryas", "url": "https://www.usap-dc.org/view/dataset/601176"}, {"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "This award supports a project to use the Taylor Glacier, Antarctica, ablation zone to collect ice samples for a range of paleoenvironmental studies. A record of carbon-14 of atmospheric methane (14CH4) will be obtained for the last deglaciation and the Early Holocene, together with a supporting record of CH4 stable isotopes. In-situ cosmogenic 14C content and partitioning of 14C between different species (14CH4, C-14 carbon monoxide (14CO) and C-14 carbon dioxide (14CO2)) will be determined with unprecedented precision in ice from the surface down to ~67 m. Further age-mapping of the ablating ice stratigraphy will take place using a combination of CH4, CO2, \u0026#948;18O of oxygen gas and H2O stable isotopes. High precision, high-resolution records of CO2, \u0026#948;13C of CO2, nitrous oxide (N2O) and N2O isotopes will be obtained for the last deglaciation and intervals during the last glacial period. The potential of 14CO2 and Krypton-81 (81Kr) as absolute dating tools for glacial ice will be investigated. The intellectual merit of proposed work includes the fact that the response of natural methane sources to continuing global warming is uncertain, and available evidence is insufficient to rule out the possibility of catastrophic releases from large 14C-depleted reservoirs such as CH4 clathrates and permafrost. The proposed paleoatmospheric 14CH4 record will improve our understanding of the possible magnitude and timing of CH4 release from these reservoirs during a large climatic warming. A thorough understanding of in-situ cosmogenic 14C in glacial ice (production rates by different mechanisms and partitioning between species) is currently lacking. Such an understanding will likely enable the use of in-situ 14CO in ice at accumulation sites as a reliable, uncomplicated tracer of the past cosmic ray flux and possibly past solar activity, as well as the use of 14CO2 at both ice accumulation and ice ablation sites as an absolute dating tool. Significant gaps remain in our understanding of the natural carbon cycle, as well as in its responses to global climate change. The proposed high-resolution, high-precision records of \u0026#948;13C of CO2 would provide new information on carbon cycle changes both during times of rising CO2 in a warming climate and falling CO2 in a cooling climate. N2O is an important greenhouse gas that increased by ~30% during the last deglaciation. The causes of this increase are still largely uncertain, and the proposed high-precision record of N2O concentration and isotopes would provide further insights into N2O source changes in a warming world. The broader impacts of proposed work include an improvement in our understanding of the response of these greenhouse gas budgets to global warming and inform societally important model projections of future climate change. The continued age-mapping of Taylor Glacier ablation ice will add value to this high-quality, easily accessible archive of natural environmental variability. Establishing 14CO as a robust new tracer for past cosmic ray flux would inform paleoclimate studies and constitute a valuable contribution to the study of the societally important issue of climate change. The proposed work will contribute to the development of new laboratory and field analytical systems. The data from the study will be made available to the scientific community and the broad public through the NSIDC and NOAA Paleoclimatology data centers. 1 graduate student each will be trained at UR, OSU and SIO, and the work will contribute to the training of a postdoc at OSU. 3 UR undergraduates will be involved in fieldwork and research. The work will support a new, junior UR faculty member, Petrenko. All PIs have a strong history of and commitment to scientific outreach in the forms of media interviews, participation in filming of field projects, as well as speaking to schools and the public about their research, and will continue these activities as part of the proposed work. This award has field work in Antarctica.", "east": 162.167, "geometry": "POINT(162.167 -77.733)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Not provided; USAP-DC; FIELD INVESTIGATION; Stratigraphy; FIELD SURVEYS; Antarctica; Paleoenvironment; Methane; Ice Core; Carbon Dioxide; FIXED OBSERVATION STATIONS; Stable Isotopes; Ablation Zone; Taylor Glacier; Nitrous Oxide; USA/NSF; LABORATORY; AMD; Cosmogenic; Amd/Us", "locations": "Taylor Glacier; Antarctica", "north": -77.733, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Brook, Edward J.; Severinghaus, Jeffrey P.; PETRENKO, VASILLI", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e FIXED OBSERVATION STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.733, "title": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "uid": "p0000283", "west": 162.167}, {"awards": "1043421 Severinghaus, Jeffrey; 1043522 Brook, Edward J.", "bounds_geometry": "POINT(-112.09 -79.47)", "dataset_titles": "WAIS Divide Replicate Core Methane Isotopic Data Set", "datasets": [{"dataset_uid": "601059", "doi": "10.15784/601059", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Replicate Core Methane Isotopic Data Set", "url": "https://www.usap-dc.org/view/dataset/601059"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "1043421/Severinghaus\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to obtain samples of ice in selected intervals for replication and verification of the validity and spatial representativeness of key results in the WAIS Divide ice core, and to obtain additional ice samples in areas of intense scientific interest where demand is high. The US Ice Core Working Group recommended in 2003 that NSF pursue the means to take replicate samples, termed \"replicate coring\". This recommendation was part of an agreement to reduce the diameter of the (then) new drilling system (the DISC drill) core to 12.2 cm to lighten logistics burdens, and the science community accepted the reduction in ice sample with the understanding that replicate coring would be able to provide extra sample volume in key intervals. The WAIS Divide effort would particularly benefit from replicate coring, because of the unique quality of the expected gas record and the large samples needed for gases and gas isotopes; thus this proposal to employ replicate coring at WAIS Divide. In addition, scientific demand for ice samples has been, and will continue to be, very unevenly distributed, with the ice core archive being completely depleted in depth intervals of high scientific interest (abrupt climate changes, volcanic sulfate horizons, meteor impact horizons, for example). The broader impacts of the proposed research may include identification of leads and lags between Greenland, tropical, and Antarctic climate change, enabling critical tests of hypotheses for the mechanism of abrupt climate change. Improved understanding of volcanic impacts on atmospheric chemistry and climate may also emerge. This understanding may ultimately help improve climate models and prediction of the Earth System feedback response to ongoing human perturbation in coming centuries. Outreach and public education about climate change are integral components of the PIs\u0027 activities and the proposed work will enhance these efforts. Broader impacts also include education and training of 2 postdoctoral scholars and 1 graduate student, and invaluable field experience for the graduate and undergraduate students who will likely make up the core processing team at WAIS Divide.", "east": -112.09, "geometry": "POINT(-112.09 -79.47)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": false, "keywords": "Ice Core Gas Records; Firn Air Isotopes; LABORATORY; FIELD SURVEYS; Mass Spectrometry; Not provided; FIELD INVESTIGATION; Ice Core; WAIS Divide", "locations": "WAIS Divide", "north": -79.47, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Earth Sciences; Antarctic Earth Sciences; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -79.47, "title": "Collaborative Research: Replicate Coring at WAIS Divide to Obtain Additional Samples at Events of High Scientific Interest", "uid": "p0000751", "west": -112.09}, {"awards": "0944343 Severinghaus, Jeffrey", "bounds_geometry": "POINT(-112.05 -79.28)", "dataset_titles": null, "datasets": null, "date_created": "Fri, 15 Aug 2014 00:00:00 GMT", "description": "Severinghaus/0944343\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to develop both a record of past local temperature change at the WAIS Divide site, and past mean ocean temperature using solubility effects on atmospheric krypton and xenon. The two sets of products share some of the same measurements, because the local temperature is necessary to make corrections to krypton and xenon, and thus synergistically support each other. Further scientific synergy is obtained by the fact that the mean ocean temperature is constrained to vary rather slowly, on a 1000-yr timescale, due to the mixing time of the deep ocean. Thus rapid changes are not expected, and can be used to flag methodological problems if they appear in the krypton and xenon records. The mean ocean temperature record produced will have a temporal resolution of 500 years, and will cover the entire 3400 m length of the core. This record will be used to test hypotheses regarding the cause of atmospheric carbon dioxide (CO2) variations, including the notion that deep ocean stratification via a cold salty stagnant layer caused atmospheric CO2 drawdown during the last glacial period. The local surface temperature record that results will synergistically combine with independent borehole thermometry and water isotope records to produce a uniquely precise and accurate temperature history for Antarctica, on a par with the Greenland temperature histories. This history will be used to test hypotheses that the ?bipolar seesaw? is forced from the North Atlantic Ocean, which makes a specific prediction that the timing of Antarctic cooling should slightly lag abrupt Greenland warming. The WAIS Divide ice core is expected to be the premier atmospheric gas record of the past 100,000 years for the foreseeable future, and as such, making this set of high precision noble gas measurements adds value to the other gas records because they all share a common timescale and affect each other in terms of physical processes such as gravitational fractionation. Broader impact of the proposed work: The clarification of timing of atmospheric CO2 and Antarctic surface temperature, along with deep ocean temperature, will aid in efforts to understand the feedbacks among CO2, temperature, and ocean circulation. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. A deeper understanding of the mechanism of deglaciation, and the role of atmospheric CO2, will go a long way towards clarifying a topic that has become quite confused in the public mind in the public debate over climate change. Elucidating the role of the bipolar seesaw in ending glaciations and triggering CO2 increases may also provide an important warning that this represents a potential positive feedback, not currently considered by IPCC. Education of one graduate student, and training of one technician, will add to the nation?s human resource base. Outreach activities will be enhanced and will to continue to entrain young people in discovery, and excitement will enhance the training of the next generation of scientists and educators.", "east": -112.05, "geometry": "POINT(-112.05 -79.28)", "instruments": null, "is_usap_dc": false, "keywords": "Noble Gas; FIELD INVESTIGATION; Climate; Xenon; FIELD SURVEYS; Ice Core; Antarctica; Krypton; LABORATORY", "locations": "Antarctica", "north": -79.28, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repositories": null, "science_programs": null, "south": -79.28, "title": "Noble Gases in the WAIS Divide Ice Core as Indicators of Local and Mean-ocean Temperature", "uid": "p0000430", "west": -112.05}, {"awards": "0839075 Priscu, John; 0839122 Saltzman, Eric; 0839093 McConnell, Joseph", "bounds_geometry": "POINT(112.05 -79.28)", "dataset_titles": "Fluorescence spectroscopy data from the West Antarctic Ice Sheet (WAIS) Divide ice core, WDC06A; Holocene Black Carbon in Antarctica; Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core; Prokaryotic cell concentration record from the WAIS Divide ice core", "datasets": [{"dataset_uid": "601072", "doi": "10.15784/601072", "keywords": "Antarctica; Biota; Cell Counts; Glaciology; Microbiology; WAIS Divide; WAIS Divide Ice Core", "people": "Priscu, John; Santibanez, Pamela", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Prokaryotic cell concentration record from the WAIS Divide ice core", "url": "https://www.usap-dc.org/view/dataset/601072"}, {"dataset_uid": "601034", "doi": "10.15784/601034", "keywords": "Antarctica; Atmosphere; Black Carbon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "McConnell, Joseph; Arienzo, Monica", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Holocene Black Carbon in Antarctica", "url": "https://www.usap-dc.org/view/dataset/601034"}, {"dataset_uid": "601006", "doi": "10.15784/601006", "keywords": "Antarctica; Fluorescence Spectroscopy; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Physical Properties; WAIS Divide; WAIS Divide Ice Core", "people": "Priscu, John; D\u0027Andrilli, Juliana", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Fluorescence spectroscopy data from the West Antarctic Ice Sheet (WAIS) Divide ice core, WDC06A", "url": "https://www.usap-dc.org/view/dataset/601006"}, {"dataset_uid": "601361", "doi": "10.15784/601361", "keywords": "Antarctica; Carbonyl Sulfide; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/601361"}], "date_created": "Fri, 30 May 2014 00:00:00 GMT", "description": "This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to use the WAIS Divide deep core to investigate the Last Deglaciation at sub-annual resolution through an integrated set of chemical and biological analyses. The intellectual merit of the project is that these analyses, combined with others, will take advantage of the high snow accumulation WAIS Divide site yielding the highest time resolution glacio-biogeochemical and gas record of any deep Antarctic ice core. With other high resolution Greenland cores (GISP2 and GRIP) and lower resolution Antarctic cores, the combined record will yield new insights into worldwide climate dynamics and abrupt change. The proposed chemical, biological, and elemental tracer measurements will also be used to address all of the WAIS Divide science themes. The broader impacts of the project include education and outreach activities such as numerous presentations to local K-12 students; opportunities for student and teacher involvement in the laboratory work; a teacher training program in Earth sciences in the heavily minority Santa Ana, Compton, and Costa Mesa, California school districts; and development of high school curricula. Extensive graduate and undergraduate student involvement also is planned and will include one post doctoral associate, one graduate student, and undergraduate hourly involvement at DRI; a graduate student and undergraduates at University of California, Irvine (UCI); and a post doctoral fellow at MSU. Student recruitment will be made from underrepresented groups building on a long track record of involvement and will include the NSF funded California Alliance for Minority Participation (CAMP) and the Montana American Indian Research Opportunities (AIRO).\u003cbr/\u003e\u003cbr/\u003eThis award does not involve field work in Antarctica.", "east": 112.05, "geometry": "POINT(112.05 -79.28)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e CARBON ANALYZERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUOROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e WAS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e ICE CORE MELTER; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PHOTOMETERS \u003e SPECTROPHOTOMETERS", "is_usap_dc": true, "keywords": "FIELD SURVEYS; Bacteria Ice Core; LABORATORY; Ice Core; FIELD INVESTIGATION; West Antarctica; Not provided; Dissolved Organic Carbon", "locations": "West Antarctica", "north": -79.28, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY", "persons": "Foreman, Christine; Skidmore, Mark; Saltzman, Eric; McConnell, Joseph; Priscu, John", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.28, "title": "Collaborative Research: Integrated High Resolution Chemical and Biological Measurements on the Deep WAIS Divide Core", "uid": "p0000273", "west": 112.05}, {"awards": "0739780 Taylor, Kendrick", "bounds_geometry": "POINT(-112.117 -79.666)", "dataset_titles": "WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning", "datasets": [{"dataset_uid": "600142", "doi": "10.15784/600142", "keywords": "Antarctica; Atmosphere; Black Carbon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "Taylor, Kendrick C.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning", "url": "https://www.usap-dc.org/view/dataset/600142"}], "date_created": "Thu, 28 Apr 2011 00:00:00 GMT", "description": "Edwards/0739780\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to develop a 2,000-year high-temporal resolution record of biomass burning from the analysis of black carbon in the WAIS Divide bedrock ice core. Pilot data for the WAIS WD05A core demonstrates that we now have the ability to reconstruct this record with minimal impact on the amount of ice available for other projects. The intellectual merit of this project is that black carbon (BC) aerosols result solely from combustion and play a critical but poorly quantified role in global climate forcing and the carbon cycle. When incorporated into snow and ice, BC increases absorption of solar radiation making seasonal snow packs, mountain glaciers, polar ice sheets, and sea ice much more vulnerable to climate warming. BC emissions in the Southern Hemisphere are dominated by biomass burning in the tropical regions of Southern Africa, South America and South Asia. Biomass burning, which results from both climate and human activities, alters the atmospheric composition of greenhouse gases, aerosols and perturbs key biogeochemical cycles. A long-term record of biomass burning is needed to aid in the interpretation of ice core gas composition and will provide important information regarding human impacts on the environment and climate before instrumental records. The broader impacts of the project are that it represents a paradigm shift in our ability to reconstruct the history of fire from ice core records and to understand its impact on atmospheric chemistry and climate over millennial time scales. This type of data is especially needed to drive global circulation model simulations of black carbon aerosols, which have been found to be an important component of global warming and which may be perturbing the hydrologic cycle. The project will also employ undergraduate students and is committed to attracting underrepresented groups to the physical sciences. The project?s outreach component will be conducted as part of the WAIS project outreach program and will reach a wide audience.", "east": -112.117, "geometry": "POINT(-112.117 -79.666)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; Not provided; Gas Record; Ice Core; Gas Measurement; Ice Core Gas Composition; Antarctica; LABORATORY; Bedrock Ice Core; Ice Core Gas Records; Wais Project; Greenhouse Gas; Atmospheric Chemistry; FIELD INVESTIGATION; Black Carbon; Biomass Burning; WAIS Divide; FIELD SURVEYS; West Antarctica; Methane", "locations": "Antarctica; West Antarctica; WAIS Divide", "north": -79.666, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.; McConnell, Joseph; Mitchell, Logan E; Sowers, Todd A.; Taylor, Kendrick C.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.666, "title": "WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning", "uid": "p0000022", "west": -112.117}, {"awards": "0538657 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Borehole Temperature Measurement in WDC05A in January 2008 and January 2009; d15N and d18O of air in the WAIS Divide ice core; Low-res d15N and d18O of O2 in the WAIS Divide 06A Deep Core; Ultra-High Resolution LA-ICP-MS Results: DO-21 Rapid Warming Event; WAIS Divide d18Oatm and Siple Dome/WAIS Divide composite and individual delta epsilon LAND", "datasets": [{"dataset_uid": "601041", "doi": "10.15784/601041", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Gas; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; WAIS Divide Ice Core", "people": "Seltzer, Alan; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide d18Oatm and Siple Dome/WAIS Divide composite and individual delta epsilon LAND", "url": "https://www.usap-dc.org/view/dataset/601041"}, {"dataset_uid": "609635", "doi": "10.7265/N51J97PS", "keywords": "Arctic; Geochemistry; GISP; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate", "people": "Mayewski, Paul A.; Haines, Skylar; Kurbatov, Andrei V.", "repository": "USAP-DC", "science_program": null, "title": "Ultra-High Resolution LA-ICP-MS Results: DO-21 Rapid Warming Event", "url": "https://www.usap-dc.org/view/dataset/609635"}, {"dataset_uid": "609637", "doi": "10.7265/N5B27S7S", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS Divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.; Orsi, Anais J.", "repository": "USAP-DC", "science_program": null, "title": "Borehole Temperature Measurement in WDC05A in January 2008 and January 2009", "url": "https://www.usap-dc.org/view/dataset/609637"}, {"dataset_uid": "601747", "doi": "10.15784/601747", "keywords": "Antarctica; Delta 15N; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Gas Records; Ice Core Records; Isotope; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; WAIS; WAIS Divide", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "d15N and d18O of air in the WAIS Divide ice core", "url": "https://www.usap-dc.org/view/dataset/601747"}, {"dataset_uid": "609660", "doi": "10.7265/N5S46PWD", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Low-res d15N and d18O of O2 in the WAIS Divide 06A Deep Core", "url": "https://www.usap-dc.org/view/dataset/609660"}], "date_created": "Thu, 08 Jul 2010 00:00:00 GMT", "description": "0538657\u003cbr/\u003eSeveringhaus\u003cbr/\u003eThis award supports a project to develop high-resolution (20-yr) nitrogen and oxygen isotope records on trapped gases in the WAIS Divide ice core (Antarctica), with a comparison record for chronological purposes in the GISP2 (Greenland) ice core. The main scientific objective is to provide an independent temperature-change record for the past 100,000 years in West Antarctica that is not subject to the uncertainty inherent in ice isotopes (18O and deuterium), the classical paleothermometer. Nitrogen isotopes (Delta 15N) in air bubbles in glacial ice record rapid surface temperature change because of thermal fractionation of air in the porous firn layer, and this isotopic anomaly is recorded in bubbles as the firn becomes ice. Using this gas-based temperature-change record, in combination with methane data as interpolar stratigraphic markers, the proposed work will define the precise relative timing of abrupt warming in Greenland and abrupt cooling at the WAIS Divide site during the millennial-scale climatic oscillations of Marine Isotopic Stage 3 (30-70 kyr BP) and the last glacial termination. The nitrogen isotope record also provides constraints on past firn thickness, which inform temperature and accumulation rate histories from the ice core. A search for possible solar-related cycles will be conducted with the WAIS Divide Holocene (Delta 15N.) Oxygen isotopes of O2 (Delta 18Oatm) are obtained as a byproduct of the (Delta 15N) measurement. The gas-isotopic records will enhance the value of other atmospheric gas measurements in WAIS Divide, which are expected to be of unprecedented quality. The high-resolution (Delta 18Oatm) records will provide chronological control for use by the international ice coring community and for surface glacier ice dating. Education of a graduate student, and training of a staff member in the laboratory, will contribute to the nation\u0027s human resource base. Outreach activities in the context of the International Polar Year will be enhanced. International collaboration is planned with the laboratory of LSCE, University of Paris.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e LA-ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Borehole Temperature; LABORATORY; Depth; Not provided; GROUND-BASED OBSERVATIONS; Wais Divide-project; Ice Core; WAIS Divide", "locations": "WAIS Divide", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Haines, Skylar; Mayewski, Paul A.; Orsi, Anais J.; Kurbatov, Andrei V.; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Nitrogen and Oxygen Gas Isotopes in the WAIS Divide Ice Core as Constraints on Chronology, Temperature, and Accumulation Rate", "uid": "p0000036", "west": null}, {"awards": "0520523 Brook, Edward J.", "bounds_geometry": null, "dataset_titles": "Methane Measurements from the GISP2 and Siple Dome Ice Cores", "datasets": [{"dataset_uid": "609440", "doi": "10.7265/N58P5XFZ", "keywords": "Antarctica; Arctic; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane Measurements from the GISP2 and Siple Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/609440"}], "date_created": "Wed, 09 Dec 2009 00:00:00 GMT", "description": "Not Available", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Methane; Greenland Ice Cap; Ice Core Data; Siple Dome; Not provided; Ice Core Gas Records; DRILLING PLATFORMS; LABORATORY; Ice Core; Ice Core Chemistry; Antarctica; Greenland Ice Sheet Project 2", "locations": "Antarctica; Greenland Ice Cap; Siple Dome", "north": null, "nsf_funding_programs": "Arctic Natural Sciences", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY; WATER-BASED PLATFORMS \u003e FIXED PLATFORMS \u003e SURFACE \u003e DRILLING PLATFORMS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Collaborative Research: New insights into the Holocene methane budget from dual isotope systematics and a high resolution record of the interpolar gradient", "uid": "p0000131", "west": null}, {"awards": "0196105 Steig, Eric", "bounds_geometry": null, "dataset_titles": "US ITASE Stable Isotope Data, Antarctica", "datasets": [{"dataset_uid": "609425", "doi": "10.7265/N5NZ85MD", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; ITASE; Paleoclimate; WAIS", "people": "Steig, Eric J.", "repository": "USAP-DC", "science_program": "ITASE", "title": "US ITASE Stable Isotope Data, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609425"}], "date_created": "Thu, 01 Oct 2009 00:00:00 GMT", "description": "Not Available", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e AMS; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e SPECTROMETERS/RADIOMETERS \u003e LIDAR/LASER SPECTROMETERS \u003e PALMS", "is_usap_dc": true, "keywords": "Isotope; Depth; Ice Core Gas Records; Ice Core; Ice Core Data; Ice Core Chemistry; LABORATORY; Firn Isotopes; FIELD SURVEYS; Deuterium; Ice Age; Oxygen Isotope; Not provided", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Steig, Eric J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "ITASE", "south": null, "title": "Stable Isotope Studies at West Antarctic ITASE Sites", "uid": "p0000013", "west": null}, {"awards": "0440975 Severinghaus, Jeffrey", "bounds_geometry": "POINT(-119.533333 -80.016667)", "dataset_titles": "Nitrogen and Oxygen Gas Isotopes in the Siple Dome and Byrd Ice Cores, Antarctica", "datasets": [{"dataset_uid": "609407", "doi": "10.7265/N55X26V0", "keywords": "Antarctica; Arctic; Atmosphere; Byrd Glacier; Byrd Ice Core; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Nitrogen and Oxygen Gas Isotopes in the Siple Dome and Byrd Ice Cores, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609407"}], "date_created": "Fri, 17 Jul 2009 00:00:00 GMT", "description": "The award supports the development of high-resolution nitrogen and oxygen isotope records on trapped gases in the Byrd and Siple Dome ice cores, and the Holocene part of the GISP2 ice core. The primary scientific goals of this work are to understand the enigmatic d15N anomalies seen thus far in the Siple Dome record at 15.3 ka and 35 ka, and to find other events that may occur in both cores. At these events, d15N of trapped air approaches zero, implying little or no gravitational fractionation of gases in the firn layer at the time of formation of the ice. These events may represent times of low accumulation rate and arid meteorological conditions, and thus may contain valuable information about the climatic history of West Antarctica. Alternatively, they may stem from crevassing and thus may reveal ice-dynamical processes. Finding the events in the Byrd core, which is located 500 km from Siple Dome, would place powerful constraints on their origin and significance. A second major goal is to explore the puzzling absence of the abrupt warming event at 22 ka (seen at Siple Dome) in the nearby Byrd 18O/16O record in the ice (d18Oice), and search for a possible correlative signal in Byrd d15N. A third goal takes advantage of the fact that precise measurements of the oxygen isotopic composition of atmospheric O2 (d18Oatm) are obtained as a byproduct of the d15N measurement. The proposed gas-isotopic measurements will underpin an integrated suite of West Antarctic climate and atmospheric gas records, which will ultimately include the WAIS Divide core. These records will help separate regional from global climate signals, and may place constraints on the cause of abrupt climate change. Education of two graduate students, and training of two staff members in the laboratory, contribute to the nation\u0027s human resource base. Education and outreach will be an important component of the project.", "east": -119.533333, "geometry": "POINT(-119.533333 -80.016667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Firn Air Isotopes; Not provided; Nitrogen Isotopes; LABORATORY; Firn Isotopes; Paleoclimate; FIELD SURVEYS; Ice Core; Oxygen Isotope; FIELD INVESTIGATION; Siple Dome", "locations": "Antarctica; Siple Dome", "north": -80.016667, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -80.016667, "title": "Nitrogen and oxygen gas isotopes in the Siple Dome and Byrd ice cores", "uid": "p0000450", "west": -119.533333}, {"awards": "9814810 Bales, Roger", "bounds_geometry": "POLYGON((-124 -76,-120 -76,-116 -76,-112 -76,-108 -76,-104 -76,-100 -76,-96 -76,-92 -76,-88 -76,-84 -76,-84 -77.4,-84 -78.8,-84 -80.2,-84 -81.6,-84 -83,-84 -84.4,-84 -85.8,-84 -87.2,-84 -88.6,-84 -90,-88 -90,-92 -90,-96 -90,-100 -90,-104 -90,-108 -90,-112 -90,-116 -90,-120 -90,-124 -90,-124 -88.6,-124 -87.2,-124 -85.8,-124 -84.4,-124 -83,-124 -81.6,-124 -80.2,-124 -78.8,-124 -77.4,-124 -76))", "dataset_titles": "Atmospheric Mixing Ratios of Hydroperoxides above the West Antarctic Ice Sheet; Twenty-Three Century-scale Ice Core Records of Hydrogen Peroxide (H2O2) from West Antarctica", "datasets": [{"dataset_uid": "609392", "doi": "10.7265/N5TM7826", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS", "people": "Bales, Roger; Frey, Markus; McConnell, Joseph", "repository": "USAP-DC", "science_program": null, "title": "Twenty-Three Century-scale Ice Core Records of Hydrogen Peroxide (H2O2) from West Antarctica", "url": "https://www.usap-dc.org/view/dataset/609392"}, {"dataset_uid": "609394", "doi": "10.7265/N5PZ56RS", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; ITASE; WAIS", "people": "McConnell, Joseph; Frey, Markus; Bales, Roger", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric Mixing Ratios of Hydroperoxides above the West Antarctic Ice Sheet", "url": "https://www.usap-dc.org/view/dataset/609394"}], "date_created": "Mon, 01 Jun 2009 00:00:00 GMT", "description": "This award supports a project to improve understanding of atmospheric photochemistry over West Antarctica, as recorded in snow, firn and ice. Atmospheric and firn sampling will be undertaken as part of the U.S. International Trans-Antarctic Scientific Expedition (US ITASE) traverses. Measurements of hydrogen peroxide (H2O2) and formaldehyde (HCHO) will be made on these samples and a recently developed, physically based atmosphere-to-snow transfer model will be used to relate photochemical model estimates of these components to the concentrations of these parameters in the atmosphere and snow. The efficiency of atmosphere-to-snow transfer and the preservation of these components is strongly related to the rate and timing of snow accumulation. This information will be obtained by analyzing the concentration of seasonally dependent species such as hydrogen peroxide, nitric acid and stable isotopes of oxygen. Collection of samples along the US ITASE traverses will allow sampling at a wide variety of locations, reflecting both a number of different depositional environments and covering much of the West Antarctic region.", "east": -84.0, "geometry": "POINT(-104 -83)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUORESCENCE SPECTROSCOPY; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS SENSORS", "is_usap_dc": true, "keywords": "Ice Core; Ice Core Chemistry; FIELD INVESTIGATION; FIELD SURVEYS; Antarctica; West Antarctica; Antarctic; LABORATORY; Ice Core Gas Records; Not provided; Ice Core Data; Polar Firn Air; Hydrogen Peroxide; West Antarctic Ice Sheet; Shallow Firn Air; US ITASE; Antarctic Ice Sheet; Snow Chemistry", "locations": "Antarctica; West Antarctica; Antarctic; Antarctic Ice Sheet; West Antarctic Ice Sheet", "north": -76.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Bales, Roger; Frey, Markus; McConnell, Joseph", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Hydrogen Peroxide, Formaldehyde, and Sub-Annual Snow Accumulation in West Antarctica: Participation in West Antarctic Traverse", "uid": "p0000253", "west": -124.0}, {"awards": "0440759 Sowers, Todd; 0440602 Saltzman, Eric; 0440498 White, James; 0440701 Severinghaus, Jeffrey; 0440615 Brook, Edward J.; 0440509 Battle, Mark", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane Isotopes from the WAIS Divide Ice Core; Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A; WAIS ice core Methane Data, Carbon Dioxide Data", "datasets": [{"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609412", "doi": "10.7265/N5251G40", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609412"}, {"dataset_uid": "609638", "doi": "10.7265/N56971HF", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS Divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.; Orsi, Anais J.", "repository": "USAP-DC", "science_program": null, "title": "Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A", "url": "https://www.usap-dc.org/view/dataset/609638"}, {"dataset_uid": "609493", "doi": "10.7265/N5319SV3", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Mitchell, Logan E; Taylor, Kendrick C.; Sowers, Todd A.; McConnell, Joseph; Brook, Edward J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS ice core Methane Data, Carbon Dioxide Data", "url": "https://www.usap-dc.org/view/dataset/609493"}, {"dataset_uid": "609435", "doi": "10.7265/N5J67DW0", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Methane Isotopes from the WAIS Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609435"}], "date_created": "Tue, 03 Feb 2009 00:00:00 GMT", "description": "This award supports a project to measure the elemental and isotopic composition of firn air and occluded air in shallow boreholes and ice cores from the WAIS Divide site, the location of a deep ice-coring program planned for 2006-07 and subsequent seasons. The three primary objectives are: 1) to establish the nature of firn air movement and trapping at the site to aid interpretations of gas data from the deep core; 2) to expand the suite of atmospheric trace gas species that can be measured in ice and replicate existing records of other species; and 3) to inter-calibrate all collaborating labs to insure that compositional and isotopic data sets are inter-comparable. The program will be initiated with a shallow drilling program during the 05/06 field season which will recover two 300+m cores and firn air samples. The ice core and firn air will provide more than 700 years of atmospheric history that will be used to address a number of important questions related to atmospheric change over this time period. The research team consists of six US laboratories that also plan to participate in the deep core program. This collaborative research program has a number of advantages. First, the scientists will be able to coordinate sample allocation a priori to maximize the resolution and overlap of records of interrelated species. Second, sample registration will be exact, allowing direct comparison of all records. Third, a coherent data set will be produced at the same time and all PI.s will participate in interpreting and publishing the results. This will insure that the best possible understanding of gas records at the WAIS Divide site will be achieved, and that all work necessary to interpret the deep core is conducted in a timely fashion. The collaborative structure created by the proposal will encourage sharing of techniques, equipment, and ideas between the laboratories. The research will identify impacts of various industrial/agricultural activities and help to distinguish them from natural variations, and will include species for which there are no long records of anthropogenic impact. The work will also help to predict future atmospheric loadings. The project will contribute to training scientists at several levels, including seven undergraduates, two graduate students and one post doctoral fellow.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e SPECTROMETERS/RADIOMETERS \u003e SPECTROMETERS \u003e SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; WAIS Divide; Firn; LABORATORY; Ice Core; Firn Air Isotope Measurements; Shallow Firn Air; FIELD INVESTIGATION; Ice Core Gas Records; GROUND-BASED OBSERVATIONS; Firn Isotopes; Wais Divide-project; Gas Data; Polar Firn Air; Not provided; Trace Gas Species; Trapped Gases; West Antarctic Ice Sheet; Deep Core; Ice Sheet; Gas; Firn Air Isotopes; FIELD SURVEYS; Air Samples; Atmospheric Gases; Isotope; Cores; Atmosphere; Ice Core Data; Surface Temperatures; Firn Air; Borehole; Antarctica", "locations": "West Antarctic Ice Sheet; Antarctica; WAIS Divide", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Battle, Mark; Mischler, John; Saltzman, Eric; Aydin, Murat; White, James; Brook, Edward J.; Orsi, Anais J.; Severinghaus, Jeffrey P.; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "uid": "p0000368", "west": -112.085}, {"awards": "0636953 Saltzman, Eric", "bounds_geometry": "POINT(-148.82 -81.66)", "dataset_titles": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core; Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core; Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core; Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica; Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "datasets": [{"dataset_uid": "609600", "doi": "10.7265/N5PG1PPB", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609600"}, {"dataset_uid": "609356", "doi": "10.7265/N56W9807", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Aydin, Murat; Williams, Margaret; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609356"}, {"dataset_uid": "601361", "doi": "10.15784/601361", "keywords": "Antarctica; Carbonyl Sulfide; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/601361"}, {"dataset_uid": "609598", "doi": "10.7265/N5X0650D", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609598"}, {"dataset_uid": "609599", "doi": "10.7265/N5S75D8P", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609599"}], "date_created": "Wed, 22 Oct 2008 00:00:00 GMT", "description": "Saltzman/0636953\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to measure methyl chloride, methyl bromide, and carbonyl sulfide in air extracted from Antarctic ice cores. Previous measurements in firn air and shallow ice cores suggest that the ice archive contains paleo-atmospheric signals for these gases. The goal of this study is to extend these records throughout the Holocene and into the last Glacial period to examine the behavior of these trace gases over longer time scales and a wider range of climatic conditions. These studies are exploratory, and both the stability of these trace gases and the extent to which they may be impacted by in situ processes will be assessed. This project will involve sampling and analyzing archived ice core samples from the Siple Dome, Taylor Dome, Byrd, and Vostok ice cores. The ice core samples will be analyzed by dry extraction, with gas chromatography/mass spectrometry with isotope dilution. The ice core measurements will generate new information about the range of natural variability of these trace gases in the atmosphere. The intellectual merit of this project is that this work will provide an improved basis for assessing the impact of anthropogenic activities on biogeochemical cycles, and new insight into the climatic sensitivity of the biogeochemical processes controlling atmospheric composition. The broader impact of this project is that there is a strong societal interest in understanding how man\u0027s activities impact the atmosphere, and how atmospheric chemistry may be altered by future climate change. The results of this study will contribute to the development of scenarios used for future projections of stratospheric ozone and climate change. In terms of human development, this project will support the doctoral dissertation of a graduate student in Earth System Science, and undergraduate research on polar ice core chemistry. This project will also contribute to the development of an Earth Sciences teacher training curriculum for high school teachers in the Orange County school system in collaboration with an established, NSF-sponsored Math and Science Partnership program (FOCUS).", "east": -148.82, "geometry": "POINT(-148.82 -81.66)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Methyl Bromide; Antarctic; Ice Core Gas Records; Ice Core Data; Carbonyl Sulfide; Methyl Chloride; Antarctic Ice Sheet; Siple Dome; Trace Gases; Ice Core Chemistry; Biogeochemical; Atmospheric Chemistry; West Antarctic Ice Sheet; LABORATORY; Ice Core; West Antarctica", "locations": "Antarctic; Antarctica; Antarctic Ice Sheet; Siple Dome; West Antarctica; West Antarctic Ice Sheet", "north": -81.66, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core; Siple Dome Ice Core", "south": -81.66, "title": "Methyl Chloride, Methyl Bromide, and Carbonyl Sulfide in Deep Antarctic Ice Cores", "uid": "p0000042", "west": -148.82}, {"awards": "0337891 Brook, Edward J.", "bounds_geometry": "POINT(158 -77.666667)", "dataset_titles": "Atmospheric CO2 and Climate: Byrd Ice Core, Antarctica; Atmospheric CO2 and Climate: Taylor Dome Ice Core, Antarctica", "datasets": [{"dataset_uid": "609315", "doi": "10.7265/N5542KJK", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Taylor Dome; Taylor Dome Ice Core", "people": "Ahn, Jinho; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Atmospheric CO2 and Climate: Taylor Dome Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609315"}, {"dataset_uid": "609314", "doi": "10.7265/N58W3B80", "keywords": "Antarctica; Atmosphere; Byrd Glacier; Byrd Ice Core; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Byrd Ice Core", "title": "Atmospheric CO2 and Climate: Byrd Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609314"}], "date_created": "Mon, 05 Nov 2007 00:00:00 GMT", "description": "This award supports the development of a new laboratory capability in the U.S. to measure CO2 in ice cores and investigate millennial-scale changes in CO2 during the last glacial period using samples from the Byrd and Siple Dome ice cores. Both cores have precise relative chronologies based on correlation of methane and the isotopic composition of atmospheric oxygen with counterpart records from Greenland ice cores. The proposed work will therefore allow comparison of the timing of CO2 change, Antarctic temperature change, and Greenland temperature change on common time scales. Such comparisons are vital for evaluating models that explain changes in atmospheric CO2. The techniques being developed will also be available for future projects, specifically the proposed Inland WAIS ice core, for which a highly detailed CO2 record is a major objective, and studies greenhouse and other atmospheric gases and their isotopic composition for which dry extraction is necessary (stable isotopes in CO2, for example). There are many broad impacts of the proposed work. Ice core greenhouse gas records are central contributions of paleoclimatology to research and policy-making concerning global change. The proposed work will enhance those contributions by improving our understanding of the natural cycling of the most important greenhouse gas. It will contribute to the training of a postdoctoral researcher, who will be an integral part of an established research group and benefit from the diverse paleoclimate and geochemistry community at OSU. The PI teaches major and non-major undergraduate and graduate courses on climate and global change. The proposed work will enrich those courses and the courses will provide an opportunity for the postdoctoral researcher to participate in teaching by giving guest lectures. The PI also participates in a summer climate workshop for high school teachers at Washington State University and the proposed work will enrich that contribution. The extraction device that is built and the expertise gained in using it will be resources for the ice core community and available for future projects. Data will be made available through established national data center and the equipment designs will also be made available to other researchers.", "east": 158.0, "geometry": "POINT(158 -77.666667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core; Climate Change; CO2; Atmospheric Chemistry; Atmospheric CO2; LABORATORY; Not provided; Ice Core Data; Climate; Ice Core Chemistry; Atmospheric Gases; Ice Core Gas Records; GROUND STATIONS; Climate Research", "locations": null, "north": -77.666667, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Ahn, Jinho; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.666667, "title": "Developing Dry Extraction of Ice Core Gases and Application to Millennial-Scale Variability in Atmospheric CO2", "uid": "p0000268", "west": 158.0}, {"awards": "0230348 Dunbar, Nelia; 0230021 Sowers, Todd; 0230316 White, James", "bounds_geometry": "POINT(135.1333 -76.05)", "dataset_titles": "Mount Moulton Isotopes and Other Ice Core Data", "datasets": [{"dataset_uid": "609640", "doi": "10.7265/N5FT8J0N", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Lake Vostok; Mount Moulton; Paleoclimate; Talos Dome; Taylor Dome", "people": "White, James; Popp, Trevor; Steig, Eric J.", "repository": "USAP-DC", "science_program": null, "title": "Mount Moulton Isotopes and Other Ice Core Data", "url": "https://www.usap-dc.org/view/dataset/609640"}], "date_created": "Tue, 01 Aug 2006 00:00:00 GMT", "description": "The summit crater of Mt. Moulton, in West Antarctica, contains a 600-m thick horizontally-exposed section of ice with intercalated tephra layers from nearby Mt Berlin. Argon-40/Argon-39 dating of the thick, near-source tephra indicates that the age of the horizontal ice section ranges between 15,000 and 492,000 years. Thus, the Mt Moulton site offers an unparalleled repository of ancient West Antarctic snow and trapped air that can be used to investigate West Antarctic climate over much of the past 500,000 years. The planar nature and consistent dips of the tephra layers suggests that, although the ice section has thinned, it is otherwise undeformed. The Mt. Moulton site was visited during the 1999/2000 field season, at which time a horizontal ice core representing approximately 400 meters of ice was collected, ranging in age from 15,000 to older than 480,000 years. In addition to this horizontal core, samples of ice at a range of depths were collected in order to test the quality of the climate record in the ice. Forty tephra layers intercalated in the ice were also collected in order to provide chronology for the ice section. The results of this first effort are extremely encouraging. Based on the d?18 O of ice, for example, there is clearly a useable record of past climate at Mt. Moulton extending back beyond 140,000 years. There is work to do, however, to realize the full potential of this horizontal ice core. The elemental and isotopic composition of trapped gases suggest some contamination with modern air, for example. As gas cross-dating of ice cores is the current standard by which climate records are intercompared, we need to understand why and how the gas record is compromised before adding Moulton to our arsenal of ice core paleoclimate records. This award supports a collaborative effort between three institutions with following objectives: 1) to evaluate more thoroughly the integrity of the climatic record through shallow drilling of the blue ice area, as well as the snow field upslope from the blue ice; 2) to improve the radioisotopic dating of specific tephra layers; 3) to obtain baseline information about modern snowfall deposition, mean annual temperature, and wind pumping around the summit of Mt. Moulton; and 4) to study how firn densification differs when surface accumulation changes from net accumulation to net ablation.", "east": 135.1333, "geometry": "POINT(135.1333 -76.05)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ELECTRON MICROPROBES", "is_usap_dc": true, "keywords": "LABORATORY; Climate; Argon-40; 40Ar; Argon-39; FIELD SURVEYS; Chronology; Ice Core Gas Age; Gas Record; Ice Core; FIELD INVESTIGATION; Tephra; Mount Moulton; Not provided; Caldera; 39Ar; Stratigraphy; Ice Core Depth", "locations": "Mount Moulton", "north": -76.05, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "White, James; Popp, Trevor; Dunbar, Nelia; Sowers, Todd A.; Steig, Eric J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -76.05, "title": "Collaborative Research: Refining a 500-kry Climate Record From the Moulton Blue Ice Field in West Antarctica", "uid": "p0000755", "west": 135.1333}, {"awards": "0230260 Bender, Michael; 0230448 Severinghaus, Jeffrey", "bounds_geometry": "POLYGON((-75.34 86.6,-68.742 86.6,-62.144 86.6,-55.546 86.6,-48.948 86.6,-42.35 86.6,-35.752 86.6,-29.154 86.6,-22.556 86.6,-15.958 86.6,-9.36 86.6,-9.36 83.618,-9.36 80.636,-9.36 77.654,-9.36 74.672,-9.36 71.69,-9.36 68.708,-9.36 65.726,-9.36 62.744,-9.36 59.762,-9.36 56.78,-15.958 56.78,-22.556 56.78,-29.154 56.78,-35.752 56.78,-42.35 56.78,-48.948 56.78,-55.546 56.78,-62.144 56.78,-68.742 56.78,-75.34 56.78,-75.34 59.762,-75.34 62.744,-75.34 65.726,-75.34 68.708,-75.34 71.69,-75.34 74.672,-75.34 77.654,-75.34 80.636,-75.34 83.618,-75.34 86.6))", "dataset_titles": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001; Trapped Gas Composition and Chronology of the Vostok Ice Core", "datasets": [{"dataset_uid": "609290", "doi": "10.7265/N5FJ2DQC", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciology; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole", "people": "Battle, Mark; Severinghaus, Jeffrey P.; Bender, Michael", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001", "url": "https://www.usap-dc.org/view/dataset/609290"}, {"dataset_uid": "609311", "doi": "10.7265/N5P26W12", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Lake Vostok; Paleoclimate; Vostok; Vostok Ice Core", "people": "Bender, Michael; Suwa, Makoto", "repository": "USAP-DC", "science_program": null, "title": "Trapped Gas Composition and Chronology of the Vostok Ice Core", "url": "https://www.usap-dc.org/view/dataset/609311"}], "date_created": "Wed, 18 Jan 2006 00:00:00 GMT", "description": "High latitude deep ice cores contain fundamental records of polar temperatures, atmospheric dust loads (and continental aridity), greenhouse gas concentrations, the status of the biosphere, and other essential properties of past environments. An accurate chronology for these records is needed if their significance is to be fully realized. The dating challenge has stimulated efforts at orbital tuning. In this approach, one varies a timescale, within allowable limits, to optimize the match between a paleoenvironmental property and a curve of insolation through time. The ideal property would vary with time due to direct insolation forcing. It would be unaffected by complex climate feedbacks and teleconnections, and it would give a clean record with high signal/noise ratio. It is argued strongly that the O2/N2 ratio of ice core trapped gases is such a property, and evidence is presented that this property, whose atmospheric ratio is nearly constant, is tied to local summertime insolation. This award will support a project to analyze the O2/N2 ratios at 1 kyr intervals from ~ 115-400 ka in the Vostok ice core. Ancillary measurements will be made of Ar/N2, and Ne/N2 and heavy noble gas ratios, in order to understand bubble close-off fractionation and its manifestation in the Vostok trapped gas record. O2/N2 variations will be matched with summertime insolation at Vostok to achieve a high-accuracy chronology for the Vostok core. The Vostok and other correlatable climate records will then be reexamined to improve our understanding of the dynamics of Pleistocene climate change.", "east": 106.8, "geometry": "POINT(106.8 -72.4667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Paleoclimate; Siple Dome; Ice Age; Shallow Firn Air; Firn Air Isotope Measurements; Polar Firn Air; Ice Sample Gas Integrity; Oxygen Isotope; Noble Gas; Ice Core Gas Records; Atmospheric Gases; Trapped Gases; Not provided; LABORATORY; Vostok; Firn Air Isotopes; Thermal Fractionation; Ice Core Chemistry; Trapped Air Bubbles; Ice Core; Antarctica; South Pole; Ice Core Data; GROUND-BASED OBSERVATIONS; Gas Age; Firn Isotopes", "locations": "Antarctica; Vostok; Siple Dome; South Pole", "north": -72.4667, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Bender, Michael; Suwa, Makoto; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -72.4667, "title": "Collaborative Research: Trapped Gas Composition and the Chronology of the Vostok Ice Core", "uid": "p0000257", "west": 106.8}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Tatum, Cheryl; Saltzman, Eric; Aydin, Murat; Williams, Margaret", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}, {"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; Carbonyl Sulfide; Siple Coast; Chloride; Trapped Gases; Snow; Ice Core Chemistry; Chromatography; Siple; GROUND STATIONS; Atmospheric Gases; Ozone Depletion; AWS Siple; Ice Sheet; Ice Core Data; Antarctica; Glaciology; West Antarctica; Atmospheric Chemistry; Ice Core; Stratigraphy; LABORATORY; Methane; Mass Spectrometer; GROUND-BASED OBSERVATIONS; WAISCORES; Msa; Mass Spectrometry; Not provided; Siple Dome; Gas Measurement", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica; Siple", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}, {"awards": "0087151 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Sulfate-Based Volcanic Record from South Pole Ice Core", "datasets": [{"dataset_uid": "609215", "doi": "10.7265/N5CR5R88", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Solid Earth; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Sulfate-Based Volcanic Record from South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609215"}], "date_created": "Fri, 09 Apr 2004 00:00:00 GMT", "description": "This award supports a two year project to analyze shallow (~150 m) ice cores from South Pole in order to construct an annually resolved, sulfate-based volcanic record covering the last 1400 years. Two shallow ice cores will be recovered at the South Pole during the 00/01 field season and will be used for this work. Volcanic records from polar ice cores provide valuable information for studies of the connection between volcanism and climate. The new records are expected to be continuous and to cover at least the last 1400 years. The information from these records will verify the volcanic events found in the few existing Antarctic records and resolve discrepancies in the timing and magnitude of major explosive eruptions \u003cbr/\u003edetermined from those earlier records. In order to achieve the objectives of the proposed research, funds are provided to assist with the construction of an analytical laboratory for ice core and environmental \u003cbr/\u003echemistry research.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core; Snow Chemistry; West Antarctica; GROUND-BASED OBSERVATIONS; Antarctica; Ice Core Gas Records; Ion Chemistry; Ice Core Data", "locations": "West Antarctica; Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "A Sulfate-based Volcanic Record from South Pole Ice Cores", "uid": "p0000167", "west": null}, {"awards": "9725305 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "datasets": [{"dataset_uid": "609098", "doi": "10.7265/N51N7Z2P", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciology; Isotope; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole; Temperature", "people": "Battle, Mark; Severinghaus, Jeffrey P.; Grachev, Alexi", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "url": "https://www.usap-dc.org/view/dataset/609098"}], "date_created": "Mon, 01 Jan 2001 00:00:00 GMT", "description": "9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Isotopic History; GROUND STATIONS; Thermal Diffusion; Firn Temperature Measurements; Not provided; Oxygen Isotope; Trapped Air Bubbles; Shallow Firn Air; Firn Air Isotope Measurements; Seasonal Temperature Gradients; Mass Spectrometry; GROUND-BASED OBSERVATIONS; Thermal Fractionation; Polar Firn Air; Isotopic Anomalies; Xenon; Atmospheric Gases; Argon Isotopes; Siple Dome; Krypton; Nitrogen Isotopes; Seasonal Temperature Changes; Antarctica; Ice Core Gas Records; Firn Air Isotopes; Mass Spectrometer; South Pole; Firn Isotopes; Borehole", "locations": "Antarctica; Siple Dome; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change", "uid": "p0000160", "west": null}]

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