{"dp_type": "Project", "free_text": "Atmospheric Gases"}
[{"awards": "1745078 Brook, Edward J.", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ; Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation; Carbon-13 and Deuterium isotopic composition of atmospheric methane across Heinrich Stadial 4, and Dansgaard Oesgher Event 8, WAIS Divide Replicate Ice Core, Antarctica; Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "datasets": [{"dataset_uid": "601737", "doi": "10.15784/601737", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Ice Core Records; Methane; West Antarctic Ice Sheet", "people": "Martin, Kaden; Edwards, Jon S.; Lee, James; Brook, Edward J.; Rosen, Julia; Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ", "url": "https://www.usap-dc.org/view/dataset/601737"}, {"dataset_uid": "601736", "doi": "10.15784/601736", "keywords": "Antarctica; Greenland; Methane; Paleoclimate; West Antarctic Ice Sheet", "people": "Fischer, Hubertus; Blunier, Thomas; Schmitt, Jochen; M\u00fchl, Michaela; Edwards, Jon S.; Lee, James; Martin, Kaden; Brook, Edward J.; Buizert, Christo; Rosen, Julia; Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601736"}, {"dataset_uid": "601813", "doi": "10.15784/601813", "keywords": "Abrupt Climate Change; Antarctica; Atmospheric Gases; Biogeochemical Cycles; Carbon Cycle; Cryosphere; Greenhouse Gas; Methane; West Antarctic Ice Sheet Divide", "people": "Clark, Reid; Bauska, Thomas; Riddell-Young, Benjamin; Lee, James; Brook, Edward J.; Iseli, Rene; Schmitt, Jochen; Menking, Andy; Fischer, Hubertus", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Carbon-13 and Deuterium isotopic composition of atmospheric methane across Heinrich Stadial 4, and Dansgaard Oesgher Event 8, WAIS Divide Replicate Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601813"}, {"dataset_uid": "601683", "doi": "10.15784/601683", "keywords": "Antarctica; Methane; West Antarctic Ice Sheet", "people": "Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601683"}], "date_created": "Mon, 01 May 2023 00:00:00 GMT", "description": "This project will develop methods to measure the ratios of carbon-13 to carbon-12, and heavy to light hydrogen in methane in air trapped in ice cores. The ratios of the different forms of carbon and hydrogen are \"fingerprints\" of different sources of this gas in the past--for example wetlands in the tropics versus methane frozen in the sea floor. Once the analysis method is developed, the measurements will be used to examine why methane changed abruptly in the past, both during the last ice age, and during previous warm periods. The data will be used to understand how methane sources like wildfires, methane hydrates, and wetlands respond to climate change. This information is needed to understand future risks of large changes in methane in the atmosphere as Earth warms. The project involves two tasks. First, the investigators will build and test a gas extraction system for methane isotopic measurements using continuous flow methods, with the goal of equaling or bettering the precision attained by the few other laboratories that make these measurements. The system will be interfaced with existing mass spectrometers at Oregon State University. The system consists of a vacuum chamber and sequence of traps, purification columns, and furnaces that separate methane from other gases and convert it to carbon dioxide or hydrogen for mass spectrometry. Second, the team will measure the isotopic composition of methane across large changes in concentration associated with two past interglacial periods and during abrupt methane changes of the last ice age. These measurements will be used to understand if the main reason for these concentration changes is climate-driven changes in emissions from wetlands, or whether other sources are involved, for example methane hydrates or wildfires. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Antarctic Ice Sheet; TRACE GASES/TRACE SPECIES; METHANE", "locations": "Antarctic Ice Sheet", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Tracing Past Methane Variations with Stable Isotopes in Antarctic Ice Cores", "uid": "p0010416", "west": -180.0}, {"awards": "2046800 Thurber, Andrew", "bounds_geometry": "POLYGON((162 -77,162.6 -77,163.2 -77,163.8 -77,164.4 -77,165 -77,165.6 -77,166.2 -77,166.8 -77,167.4 -77,168 -77,168 -77.1,168 -77.2,168 -77.3,168 -77.4,168 -77.5,168 -77.6,168 -77.7,168 -77.8,168 -77.9,168 -78,167.4 -78,166.8 -78,166.2 -78,165.6 -78,165 -78,164.4 -78,163.8 -78,163.2 -78,162.6 -78,162 -78,162 -77.9,162 -77.8,162 -77.7,162 -77.6,162 -77.5,162 -77.4,162 -77.3,162 -77.2,162 -77.1,162 -77))", "dataset_titles": null, "datasets": null, "date_created": "Sat, 21 Aug 2021 00:00:00 GMT", "description": "Part I: Non-technical description: Methane is one of the more effective atmospheric gases at retaining heat in the lower atmosphere and the earth\u2019s crust contains large quantities of methane. Research that identifies the factors that control methane\u2019s release into the atmosphere is critical to understanding and mitigating climate change. One of the most effective natural processes that inhibits the release of methane from aquatic habitats is a community of bacteria and Archaea (microbes) that use the chemical energy stored in methane, transforming methane into less-climate-sensitive compounds. The amount of methane that may be released in Antarctica is unknown, and it is unclear which microbes consume the methane before it is released from the ocean in Antarctica. This project will study one of the few methane seeps known in Antarctica to advance our understanding of which microbes inhibit the release of methane in marine environments. The research will also identify if methane is a source of energy for other Antarctic organisms. The researchers will analyze the microbial species associated with methane consumption over several years of field and laboratory research based at an Antarctic US station, McMurdo. This project clearly expands the fundamental knowledge of Antarctic systems, biota, and processes outlined as a goal in the Antarctic solicitation. This research communicates and produces educational material for K-12, college, and graduate students to inspire and inform the public about the role Antarctic ecosystems play in the global environment. This project also provides a young professor an opportunity to establish himself as an expert in the field of Antarctic microbial ecology to help solidify his academic career. Part II: Technical description: Microbes act as filter to methane release from the ocean into the atmosphere, where microbial chemosynthetic production harvests the chemical energy stored in this greenhouse gas. In spite of methane reservoirs in Antarctica being as large as Arctic permafrost, we know only a little about the taxa or dominant processes involved in methane consumption in Antarctica. The principal investigator will undertake a genomic and transcriptomic study of microbial communities developed and still developing after initiation of methane seepage in McMurdo Sound. An Antarctic methane seep was discovered at this location in 2012 after it began seeping in 2011. Five years after it began releasing methane, the methane-oxidizing microbial community was underdeveloped and methane was still escaping from the seafloor. This project will be essential in elucidating the response of microbial communities to methane release and identify how methane oxidation occurs within the constraints of the low polar temperatures. This investigation is based on 4 years of field sampling and will establish a time series of the development of cold seep microbial communities in Antarctica. A genome-to-ecosystem approach will establish how the Southern Ocean microbial community is adapted to prevent methane release into the ocean. As methane is an organic carbon source, results from this study will have implications for the Southern Ocean carbon cycle. Two graduate students will be trained and supported with undergraduates participating in laboratory activities. The researcher aims to educate, inspire and communicate about Antarctic methane seeps to a broad community. A mixed-media approach, with videos, art and education in schools will be supported in collaboration with a filmmaker, teachers and a visual artist. Students will be trained in filmmaking and K-12 students from under-represented communities will be introduced to Antarctic science through visual arts. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 168.0, "geometry": "POINT(165 -77.5)", "instruments": null, "is_usap_dc": true, "keywords": "AMD; USA/NSF; USAP-DC; BACTERIA/ARCHAEA; McMurdo Sound; BENTHIC; FIELD SURVEYS; Amd/Us; ECOSYSTEM FUNCTIONS", "locations": "McMurdo Sound", "north": -77.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Thurber, Andrew", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repositories": null, "science_programs": null, "south": -78.0, "title": "CAREER: Ecosystem Impacts of Microbial Succession and Production at Antarctic Methane Seeps", "uid": "p0010250", "west": 162.0}, {"awards": "1445205 Putkonen, Jaakko", "bounds_geometry": "POLYGON((157.6 -83.2,157.62 -83.2,157.64 -83.2,157.66 -83.2,157.68 -83.2,157.7 -83.2,157.72 -83.2,157.74 -83.2,157.76 -83.2,157.78 -83.2,157.8 -83.2,157.8 -83.21,157.8 -83.22,157.8 -83.23,157.8 -83.24,157.8 -83.25,157.8 -83.26,157.8 -83.27,157.8 -83.28,157.8 -83.29,157.8 -83.3,157.78 -83.3,157.76 -83.3,157.74 -83.3,157.72 -83.3,157.7 -83.3,157.68 -83.3,157.66 -83.3,157.64 -83.3,157.62 -83.3,157.6 -83.3,157.6 -83.29,157.6 -83.28,157.6 -83.27,157.6 -83.26,157.6 -83.25,157.6 -83.24,157.6 -83.23,157.6 -83.22,157.6 -83.21,157.6 -83.2))", "dataset_titles": "Cosmogenic-Nuclide data at ICE-D; Old Ice, Ong Valley, Transantarctic Mountains", "datasets": [{"dataset_uid": "601665", "doi": "10.15784/601665", "keywords": "Antarctica; Buried Ice; Cosmogenic Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Old Ice; Ong Valley", "people": "Putkonen, Jaakko; Bergelin, Marie", "repository": "USAP-DC", "science_program": null, "title": "Old Ice, Ong Valley, Transantarctic Mountains", "url": "https://www.usap-dc.org/view/dataset/601665"}, {"dataset_uid": "200295", "doi": "", "keywords": null, "people": null, "repository": "ICE-D", "science_program": null, "title": "Cosmogenic-Nuclide data at ICE-D", "url": "https://version2.ice-d.org/antarctica/nsf/"}], "date_created": "Fri, 16 Jul 2021 00:00:00 GMT", "description": "Putkonen/1445205 This award supports the study of a large body of ice that is buried beneath approximately a meter of debris in the Ong Valley of the Transantarctic Mountains of East Antarctica. Preliminary analyses of this material suggest that it could be over a million years old. Most glacial ice contains tiny air bubbles that have trapped the atmospheric gases and other atmospherically transported materials existing at the time that the ice was deposited such as plant pollen, microbes and mineral dust. Samples will be collected from this buried ice mass, down to a depth of 10 meters, and cosmogenic nuclide concentrations both in the overlying debris and in the till contained in the ice will be measured. This site could contain some of the oldest ice on Earth and studies of the material contained within it may help researchers to better understand the processes involved in its survival for such long periods of time. This work will also help inform scientists about the processes involved in the development of landforms here on earth as well as those on Mars where similar dirt covered glaciers are found today. Samples of the buried ice will be collected in Ong Valley and analyzed to determine the cosmogenic nuclide concentrations in both the overlying debris and in the mineral matter suspended in the ice. The combined analysis of the target cosmogenic nuclides (Beryllium-10, Aluminum-26, and Neon-21) will allow the age of the ice to be uniquely determined and will enable determination of the rate that the ice is sublimating. The intellectual merit of this research is to unequivocally determine the age of the ice and the sublimation rate of the ice in Ong Valley, Antarctica and to better understand if this an uniquely Antarctic process or whether it could exist elsewhere on earth or on other planets. The work may also lead to the recognition of the oldest buried ice ever found on Earth and would provide a source from which direct information about the atmospheric chemistry, ancient life forms, and geology of that time could be measured. The broader impacts of this work are that it will be relevant to researchers in a number of different fields including glaciology, paleoclimatology, planetary geology, and biology. Several students will also participate in the project, conducting Antarctic field work, making measurements in the lab, attending meetings, participating in outreach activities, and producing videos. A graduate student will also write a thesis on this research. The results will be published in scientific journals and presented at conferences. The project requires field work in Antarctica.", "east": 157.8, "geometry": "POINT(157.7 -83.25)", "instruments": null, "is_usap_dc": true, "keywords": "USAP-DC; USA/NSF; FIELD SURVEYS; Transantarctic Mountains; GLACIERS/ICE SHEETS; AMD; Amd/Us", "locations": "Transantarctic Mountains", "north": -83.2, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Glaciology", "paleo_time": null, "persons": "putkonen, jaakko; Balco, Gregory; Morgan, Daniel", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repo": "USAP-DC", "repositories": "ICE-D; USAP-DC", "science_programs": null, "south": -83.3, "title": "Collaborative Research: Long Term Sublimation/Preservation of Two Separate, Buried Glacier Ice Masses, Ong Valley, Southern Transantarctic Mountains", "uid": "p0010231", "west": 157.6}, {"awards": "1907974 Saltzman, Eric", "bounds_geometry": "POLYGON((129.26 -89.86,130.261 -89.86,131.262 -89.86,132.263 -89.86,133.264 -89.86,134.265 -89.86,135.266 -89.86,136.267 -89.86,137.268 -89.86,138.269 -89.86,139.27 -89.86,139.27 -89.861,139.27 -89.862,139.27 -89.863,139.27 -89.864,139.27 -89.865,139.27 -89.866,139.27 -89.867,139.27 -89.868,139.27 -89.869,139.27 -89.87,138.269 -89.87,137.268 -89.87,136.267 -89.87,135.266 -89.87,134.265 -89.87,133.264 -89.87,132.263 -89.87,131.262 -89.87,130.261 -89.87,129.26 -89.87,129.26 -89.869,129.26 -89.868,129.26 -89.867,129.26 -89.866,129.26 -89.865,129.26 -89.864,129.26 -89.863,129.26 -89.862,129.26 -89.861,129.26 -89.86))", "dataset_titles": "H2 in South Pole firn air", "datasets": [{"dataset_uid": "601332", "doi": "10.15784/601332", "keywords": "Antarctica; Firn; Glaciology; Hydrogen; Ice Core Records; Snow/ice; Snow/Ice; South Pole", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "H2 in South Pole firn air", "url": "https://www.usap-dc.org/view/dataset/601332"}], "date_created": "Tue, 09 Jun 2020 00:00:00 GMT", "description": "Hydrogen (H2) is one of the most abundant trace gases in the atmosphere, with a mean level of 500 ppb and an atmospheric lifetime of about two years. Hydrogen has an impact on both air quality and climate, due to its role as a precursor for tropospheric ozone and stratospheric water vapor. Projections indicate that a future \"hydrogen economy\" would increase hydrogen emissions. Understanding of the atmospheric hydrogen budget is largely based on a 30-year record of surface air measurements, but there are no long-term records with which to assess either: 1) the influence of climate change on atmospheric hydrogen, or 2) the extent to which humans have impacted the hydrogen budget. Polar ice core records of hydrogen will advance our understanding of the atmospheric hydrogen cycle and provide a stronger basis for projecting future changes to atmospheric levels of hydrogen and their impacts. The research will involve laboratory work to enable the collection and analysis of hydrogen in polar ice cores. Hydrogen is a highly diffusive molecule and, unlike most other atmospheric gases, diffusion of hydrogen in ice is so rapid that ice samples must be stored in impermeable containers immediately upon drilling and recovery. This project will: 1) construct a laboratory system for extracting and analyzing hydrogen in polar ice, 2) develop and test materials and construction designs for vessels to store ice core samples in the field, and 3) test the method on samples of opportunity previously stored in the field. The goal of this project is a proven, cost-effective design for storage flasks to be fabricated for use on future polar ice coring projects. This project will support the dissertation research of a graduate student in the UC Irvine Department of Earth System Science. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 139.27, "geometry": "POINT(134.265 -89.865)", "instruments": null, "is_usap_dc": true, "keywords": "LABORATORY; Firn; TRACE GASES/TRACE SPECIES; South Pole; FIELD INVESTIGATION; USAP-DC", "locations": "South Pole", "north": -89.86, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Instrumentation and Support; Antarctic Instrumentation and Facilities", "paleo_time": null, "persons": "Saltzman, Eric", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -89.87, "title": "EAGER: Feasibility of Reconstructing the Atmospheric History of Molecular Hydrogen from Antarctic Ice", "uid": "p0010106", "west": 129.26}, {"awards": "1142517 Aydin, Murat; 1141839 Steig, Eric; 1142646 Twickler, Mark", "bounds_geometry": "POINT(90 -90)", "dataset_titles": "South Pole Ice Core Holocene Major Ion Dataset; South Pole Ice Core Sea Salt and Major Ions; South Pole ice core (SPC14) discrete methane data; South Pole Ice Core (SPICEcore) SPC14 Core Quality Versus Depth; SP19 Gas Chronology; Temperature, accumulation rate, and layer thinning from the South Pole ice core (SPC14)", "datasets": [{"dataset_uid": "601396", "doi": "10.15784/601396", "keywords": "Accumulation; Antarctica; Diffusion Length; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Dynamic; Layer Thinning; Oxygen Isotope; South Pole; SPICEcore; Temperature", "people": "Conway, Howard; Stevens, Max; Steig, Eric J.; Schauer, Andrew; Vaughn, Bruce; Morris, Valerie; Kahle, Emma; Koutnik, Michelle; Fudge, T. J.; Buizert, Christo; White, James; Epifanio, Jenna; Jones, Tyler R.; Waddington, Edwin D.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Temperature, accumulation rate, and layer thinning from the South Pole ice core (SPC14)", "url": "https://www.usap-dc.org/view/dataset/601396"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Aydin, Murat; Severinghaus, Jeffrey P.; Kennedy, Joshua A.; Ferris, David G.; Kalk, Michael; Hood, Ekaterina; Fudge, T. J.; Osterberg, Erich; Winski, Dominic A.; Steig, Eric J.; Kahle, Emma; Sowers, Todd A.; Edwards, Jon S.; Kreutz, Karl; Buizert, Christo; Brook, Edward J.; Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601851", "doi": "10.15784/601851", "keywords": "Antarctica; Cryosphere; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Sea Salt and Major Ions", "url": "https://www.usap-dc.org/view/dataset/601851"}, {"dataset_uid": "601221", "doi": "10.15784/601221", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Data; Ice Core Depth; Ice Core Records; Snow/ice; Snow/Ice; SPICEcore", "people": "Fudge, T. J.; Kahle, Emma; Nicewonger, Melinda R.; Hargreaves, Geoff; Nunn, Richard; Steig, Eric J.; Aydin, Murat; Casey, Kimberly A.; Fegyveresi, John; Twickler, Mark; Souney, Joseph Jr.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core (SPICEcore) SPC14 Core Quality Versus Depth", "url": "https://www.usap-dc.org/view/dataset/601221"}, {"dataset_uid": "601850", "doi": "10.15784/601850", "keywords": "Antarctica; Cryosphere; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Holocene Major Ion Dataset", "url": "https://www.usap-dc.org/view/dataset/601850"}], "date_created": "Wed, 30 Oct 2019 00:00:00 GMT", "description": "1142517/Saltzman This proposal requests support for a project to drill and recover a new ice core from South Pole, Antarctica. The South Pole ice core will be drilled to a depth of 1500 m, providing an environmental record spanning approximately 40 kyrs. This core will be recovered using a new intermediate drill, which is under development by the U.S. Ice Drilling Design and Operations (IDDO) group in collaboration with Danish scientists. This proposal seeks support to provide: 1) scientific management and oversight for the South Pole ice core project, 2) personnel for ice core drilling and core processing, 3) data management, and 3) scientific coordination and communication via scientific workshops. The intellectual merit of the work is that the analysis of stable isotopes, atmospheric gases, and aerosol-borne chemicals in polar ice has provided unique information about the magnitude and timing of changes in climate and climate forcing through time. The international ice core research community has articulated the goal of developing spatial arrays of ice cores across Antarctica and Greenland, allowing the reconstruction of regional patterns of climate variability in order to provide greater insight into the mechanisms driving climate change. The broader impacts of the project include obtaining the South Pole ice core will support a wide range of ice core science projects, which will contribute to the societal need for a basic understanding of climate and the capability to predict climate and ice sheet stability on long time scales. Second, the project will help train the next generation of ice core scientists by providing the opportunity for hands-on field and core processing experience for graduate students and postdoctoral researchers. A postdoctoral researcher at the University of Washington will be directly supported by this project, and many other young scientists will interact with the project through individual science proposals. Third, the project will result in the development of a new intermediate drill which will become an important resource to US ice core science community. This drill will have a light logistical footprint which will enable a wide range of ice core projects to be carried out that are not currently feasible. Finally, although this project does not request funds for outreach activities, the project will run workshops that will encourage and enable proposals for coordinated outreach activities involving the South Pole ice core science team.", "east": 90.0, "geometry": "POINT(90 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "USAP-DC; Amd/Us; Antarctica; ANALYTICAL LAB; USA/NSF; AMD; South Pole; ICE CORE RECORDS; FIELD INVESTIGATION; Ice Core", "locations": "Antarctica; South Pole", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Twickler, Mark; Souney, Joseph Jr.; Aydin, Murat; Steig, Eric J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e ANALYTICAL LAB", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: A 1500m Ice Core from South Pole", "uid": "p0010060", "west": 90.0}, {"awards": "1443341 Hawley, Robert; 1443471 Koutnik, Michelle", "bounds_geometry": "POLYGON((110 -89,117 -89,124 -89,131 -89,138 -89,145 -89,152 -89,159 -89,166 -89,173 -89,180 -89,180 -89.1,180 -89.2,180 -89.3,180 -89.4,180 -89.5,180 -89.6,180 -89.7,180 -89.8,180 -89.9,180 -90,173 -90,166 -90,159 -90,152 -90,145 -90,138 -90,131 -90,124 -90,117 -90,110 -90,110 -89.9,110 -89.8,110 -89.7,110 -89.6,110 -89.5,110 -89.4,110 -89.3,110 -89.2,110 -89.1,110 -89))", "dataset_titles": "7MHz radar in the vicinity of South Pole; Firn density and compaction rates 50km upstream of South Pole; Firn temperatures 50km upstream of South Pole; Shallow radar near South Pole; South Pole area GPS velocities; SPICEcore Advection", "datasets": [{"dataset_uid": "601369", "doi": "10.15784/601369", "keywords": "Antarctica; Ice Sheet", "people": "Waddington, Edwin D.; Fudge, T. J.; Koutnik, Michelle; Lilien, David; Conway, Howard; Stevens, Max", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "7MHz radar in the vicinity of South Pole", "url": "https://www.usap-dc.org/view/dataset/601369"}, {"dataset_uid": "601100", "doi": "10.15784/601100", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; GPS; Ice Velocity", "people": "Fudge, T. J.; Waddington, Edwin D.; Koutnik, Michelle; Lilien, David; Conway, Howard", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole area GPS velocities", "url": "https://www.usap-dc.org/view/dataset/601100"}, {"dataset_uid": "601099", "doi": "10.15784/601099", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Radar; Snow Accumulation; Snow/ice; Snow/Ice", "people": "Waddington, Edwin D.; Fudge, T. J.; Koutnik, Michelle; Lilien, David; Conway, Howard", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Shallow radar near South Pole", "url": "https://www.usap-dc.org/view/dataset/601099"}, {"dataset_uid": "601525", "doi": "10.15784/601525", "keywords": "Antarctica; Firn; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Snow/ice; Snow/Ice; South Pole; SPICEcore; Temperature", "people": "Stevens, Christopher Max; Lilien, David; Conway, Howard; Koutnik, Michelle; Waddington, Edwin D.; Fudge, T. J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Firn temperatures 50km upstream of South Pole", "url": "https://www.usap-dc.org/view/dataset/601525"}, {"dataset_uid": "601680", "doi": "10.15784/601680", "keywords": "Antarctica; Firn; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Snow/ice; Snow/Ice; South Pole; Temperature", "people": "Stevens, Christopher Max; Waddington, Edwin D.; Lilien, David; Conway, Howard; Fudge, T. J.; Koutnik, Michelle", "repository": "USAP-DC", "science_program": null, "title": "Firn density and compaction rates 50km upstream of South Pole", "url": "https://www.usap-dc.org/view/dataset/601680"}, {"dataset_uid": "601266", "doi": "10.15784/601266", "keywords": "Antarctica; Ice Core Data; South Pole; SPICEcore", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPICEcore Advection", "url": "https://www.usap-dc.org/view/dataset/601266"}], "date_created": "Thu, 14 Jun 2018 00:00:00 GMT", "description": "Ice-core records are critical to understanding past climate variations. An Antarctic ice core currently being drilled at the South Pole will allow detailed investigation of atmospheric gases and fill an important gap in understanding the pattern of climate variability across Antarctica. Critical to the interpretation of any ice core are: 1) accurate chronologies for both the ice and the trapped gas and 2) demonstration that records from the ice core reliably reflect climate. The proposed research will improve the ice and gas chronologies by making measurements of snow compaction in the upstream catchment in order to constrain age models of the ice. These measurements will be a key data set needed for better understanding and predicting time-varying conditions in the upper part of the ice sheet. The research team will measure the modern spatial gradients in accumulation rate, surface temperature, and water stable isotopes from shallow ice cores in the upstream catchment in order to determine the climate history from the ice-core record. The new ice-flow measurements will make it possible to define the path of ice from upstream to the South Pole ice-core drill site to assess spatial gradients in snowfall and to infer histories of snowfall from internal layers within the ice sheet. The project will be led by an early-career scientist, provide broad training to graduate students, and engage in public outreach on polar science. Ice-core records of stable isotopes, aerosol-born particles, and atmospheric gases are critical to understanding past climate variations. The proposed research will improve the ice and gas chronologies in the South Pole ice core by making in situ measurements of firn compaction in the upstream catchment to constrain models of the gas-age ice-age difference. The firn measurements will be a key data set needed to form a constitutive relationship for firn, and will drive better understanding and prediction of transient firn evolution. The research team will measure the modern gradients in accumulation rate, surface temperature, and water stable isotopes in the upstream catchment to separate spatial (advection) variations from temporal (climate) variations in the ice-core records. The ice-flow measurements will define the flowline upstream of the drill site, assess spatial gradients in accumulation, and infer histories of accumulation from radar-observed internal layers. Results will directly enhance interpretation of South Pole ice-core records, and also advance understanding of firn densification and drive next-generation firn models.", "east": 180.0, "geometry": "POINT(145 -89.5)", "instruments": null, "is_usap_dc": true, "keywords": "FIRN; Firn; USAP-DC; South Pole; Radar; FIELD SURVEYS; ICE CORE RECORDS", "locations": "South Pole", "north": -89.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Koutnik, Michelle; Conway, Howard; Waddington, Edwin D.; Fudge, T. J.; Hawley, Robert L.; Osterberg, Erich", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Characterization of Upstream Ice and Firn Dynamics affecting the South Pole Ice Core", "uid": "p0000200", "west": 110.0}, {"awards": "1443232 Waddington, Edwin", "bounds_geometry": "POLYGON((110 -89,117 -89,124 -89,131 -89,138 -89,145 -89,152 -89,159 -89,166 -89,173 -89,180 -89,180 -89.1,180 -89.2,180 -89.3,180 -89.4,180 -89.5,180 -89.6,180 -89.7,180 -89.8,180 -89.9,180 -90,173 -90,166 -90,159 -90,152 -90,145 -90,138 -90,131 -90,124 -90,117 -90,110 -90,110 -89.9,110 -89.8,110 -89.7,110 -89.6,110 -89.5,110 -89.4,110 -89.3,110 -89.2,110 -89.1,110 -89))", "dataset_titles": "AC-ECM for SPICEcore; ECM (DC and AC) multi-track data and images from 2016 processing season", "datasets": [{"dataset_uid": "601366", "doi": "10.15784/601366", "keywords": "Antarctica", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "ECM (DC and AC) multi-track data and images from 2016 processing season", "url": "https://www.usap-dc.org/view/dataset/601366"}, {"dataset_uid": "601189", "doi": " 10.15784/601189 ", "keywords": "Antarctica; Electrical Conductivity; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Physical Properties; Snow/ice; Snow/Ice; South Pole; SPICEcore; Volcanic", "people": "Fudge, T. J.; Waddington, Edwin D.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "AC-ECM for SPICEcore", "url": "https://www.usap-dc.org/view/dataset/601189"}], "date_created": "Tue, 08 May 2018 00:00:00 GMT", "description": "Ice cores record detailed histories of past climate variations. The South Pole ice core will allow investigation of atmospheric trace gases and fill an important gap in understanding the pattern of climate variability across Antarctica. An accurate timescale that assigns an age to the ice at each depth in the core is essential to interpretation of the ice-core records. This work will use electrical methods to identify volcanic eruptions throughout the past ~40,000 years in the core by detecting the enhanced electrical conductance in those layers due to volcanic impurities in the ice. These eruptions will be pattern-matched to other cores across Antarctica, synchronizing the timing of climate variations among cores and allowing the precise timescales developed for other Antarctic ice cores to be transferred to the South Pole ice core. The well-dated records of volcanic forcing will be combined with records of atmospheric gases, stable water-isotopes, and aerosols to better understand the large natural climate variations of the past 40,000 years. The electrical conductance method and dielectric profiling measurements will be made along the length of each section of the South Pole ice core at the National Ice Core Lab. These measurements will help to establish a timescale for the core. Electrical measurements will provide a continuous record of volcanic events for the entire core including through the brittle ice (550-1250m representing ~10,000-20,000 year-old ice) where the core quality and thin annual layers may prevent continuous melt analysis and cause discrete measurements to miss volcanic events. The electrical measurements also produce a 2-D image of the electrical layering on a longitudinal cut surface of each core. These data will be used to identify any irregular or absent layering that would indicate a stratigraphic disturbance in the core. A robust chronology is essential to interpretation of the paleoclimate records from the South Pole ice core. The investigators will engage teachers through talks and webinars with the National Science Teachers Association and will share information with the public at events such as Polar Science Weekend at the Pacific Science Center. Results will be disseminated through publications and conference presentations and the data will be archived and publicly available.", "east": 180.0, "geometry": "POINT(145 -89.5)", "instruments": null, "is_usap_dc": true, "keywords": "USAP-DC; USA/NSF; Amd/Us; AMD; LABORATORY", "locations": null, "north": -89.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Fudge, T. J.; Waddington, Edwin D.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Using Electrical Conductance Measurements to Develop the South Pole Ice Core Chronology", "uid": "p0000378", "west": 110.0}, {"awards": "1443260 Conway, Howard", "bounds_geometry": "POLYGON((159 -76.68,159.03 -76.68,159.06 -76.68,159.09 -76.68,159.12 -76.68,159.15 -76.68,159.18 -76.68,159.21 -76.68,159.24 -76.68,159.27 -76.68,159.3 -76.68,159.3 -76.697,159.3 -76.714,159.3 -76.731,159.3 -76.748,159.3 -76.765,159.3 -76.782,159.3 -76.799,159.3 -76.816,159.3 -76.833,159.3 -76.85,159.27 -76.85,159.24 -76.85,159.21 -76.85,159.18 -76.85,159.15 -76.85,159.12 -76.85,159.09 -76.85,159.06 -76.85,159.03 -76.85,159 -76.85,159 -76.833,159 -76.816,159 -76.799,159 -76.782,159 -76.765,159 -76.748,159 -76.731,159 -76.714,159 -76.697,159 -76.68))", "dataset_titles": "2015-2016 GPR Field Report for Allan Hills Shallow Ice Coring; Ground-based ice-penetrating radar profiles collected on the Allan Hills blue ice region", "datasets": [{"dataset_uid": "601005", "doi": "10.15784/601005", "keywords": "Allan Hills; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; GPR; Navigation; Radar", "people": "Conway, Howard", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Ground-based ice-penetrating radar profiles collected on the Allan Hills blue ice region", "url": "https://www.usap-dc.org/view/dataset/601005"}, {"dataset_uid": "601668", "doi": "10.15784/601668", "keywords": "Allan Hills; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; GPR; Ice Core; Report", "people": "MacKay, Sean; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "2015-2016 GPR Field Report for Allan Hills Shallow Ice Coring", "url": "https://www.usap-dc.org/view/dataset/601668"}], "date_created": "Tue, 02 May 2017 00:00:00 GMT", "description": "Marine paleoclimate archives show that approximately one million years ago Earth\u0027s climate transitioned from 40,000-year glacial /interglacial cycles to 100,000-year cycles. This award will support a study designed to map the distribution of one million year-old ice in the Allan Hills Blue Ice Area, Antarctica using state-of-the-art ground penetrating radar. The Allen Hills was demonstrated to contain a continuous record of the past 400,000 years and is also the collection location of the oldest ice samples (990,000 years) yet recovered. The maps resulting from this study will be used to select an ice-core drilling site at which a million-plus year-old continuous record of climate could be recovered. Ice cores contain the only kind of record to directly capture atmospheric gases and aerosols, but no ice-core-based climate record yet extends continuously beyond the past 800,000 years. A million-plus year-old record will allow better understanding of the major mechanisms and driving forces of natural climate variability in a world with 100,000-year glacial/interglacial cycles. The project will support two early career scientists in collaboration with senior scientists, as well as a graduate student, and will conduct outreach to schools and the public. The Allan Hills Blue Ice Area preserves a continuous climate record covering the last 400,000 years along an established glaciological flow line. Two kilometers to the east of this flow line, the oldest ice on Earth (~1 million years old) is found only 120 m below the surface. Meteorites collected in the area are reported to be as old as 1.8 million years, suggesting still older ice may be present. Combined, these data strongly suggest that the Allen Hills area could contain a continuous, well-resolved environmental record, spanning at least the last million years. As such, this area has been selected as an upcoming target for the new Intermediate Depth Ice Core Drill by the US Ice Core Working Group. This drill will recover a higher-quality core than previous dry drilling attempts. This project will conduct a comprehensive ground penetrating radar survey aimed at tracing the signature of the million-year-old ice layer throughout the region. The resulting map will be used to select a drill site from which an ice core containing the million-plus year-old continuous climate record will be collected. The proposed activities are a necessary precursor to the collection of the oldest known ice on Earth. Ice cores provide a robust reconstruction of past climate and extending this record beyond the 800,000 years currently available will open new opportunities to study the climate system. The data collected will also be used to investigate the bedrock and ice flow parameters favorable to the preservation of old ice, which may allow targeted investigation of other blue ice areas in Antarctica.", "east": 159.3, "geometry": "POINT(159.15 -76.765)", "instruments": null, "is_usap_dc": true, "keywords": "Allan Hills; FIELD SURVEYS; ICE SHEETS", "locations": "Allan Hills", "north": -76.68, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Conway, Howard", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Allan Hills", "south": -76.85, "title": "Collaborative Research: Allan HILLs Englacial Site (AHILLES) Selection", "uid": "p0000385", "west": 159.0}, {"awards": "0440759 Sowers, Todd; 0440498 White, James; 0440602 Saltzman, Eric; 0440509 Battle, Mark; 0440701 Severinghaus, Jeffrey; 0440615 Brook, Edward J.", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane Isotopes from the WAIS Divide Ice Core; Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A; WAIS ice core Methane Data, Carbon Dioxide Data", "datasets": [{"dataset_uid": "609493", "doi": "10.7265/N5319SV3", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.; McConnell, Joseph; Brook, Edward J.; Mitchell, Logan E; Taylor, Kendrick C.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS ice core Methane Data, Carbon Dioxide Data", "url": "https://www.usap-dc.org/view/dataset/609493"}, {"dataset_uid": "609435", "doi": "10.7265/N5J67DW0", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Methane Isotopes from the WAIS Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609435"}, {"dataset_uid": "609638", "doi": "10.7265/N56971HF", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS Divide; WAIS Divide Ice Core", "people": "Orsi, Anais J.; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A", "url": "https://www.usap-dc.org/view/dataset/609638"}, {"dataset_uid": "609412", "doi": "10.7265/N5251G40", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609412"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}], "date_created": "Tue, 03 Feb 2009 00:00:00 GMT", "description": "This award supports a project to measure the elemental and isotopic composition of firn air and occluded air in shallow boreholes and ice cores from the WAIS Divide site, the location of a deep ice-coring program planned for 2006-07 and subsequent seasons. The three primary objectives are: 1) to establish the nature of firn air movement and trapping at the site to aid interpretations of gas data from the deep core; 2) to expand the suite of atmospheric trace gas species that can be measured in ice and replicate existing records of other species; and 3) to inter-calibrate all collaborating labs to insure that compositional and isotopic data sets are inter-comparable. The program will be initiated with a shallow drilling program during the 05/06 field season which will recover two 300+m cores and firn air samples. The ice core and firn air will provide more than 700 years of atmospheric history that will be used to address a number of important questions related to atmospheric change over this time period. The research team consists of six US laboratories that also plan to participate in the deep core program. This collaborative research program has a number of advantages. First, the scientists will be able to coordinate sample allocation a priori to maximize the resolution and overlap of records of interrelated species. Second, sample registration will be exact, allowing direct comparison of all records. Third, a coherent data set will be produced at the same time and all PI.s will participate in interpreting and publishing the results. This will insure that the best possible understanding of gas records at the WAIS Divide site will be achieved, and that all work necessary to interpret the deep core is conducted in a timely fashion. The collaborative structure created by the proposal will encourage sharing of techniques, equipment, and ideas between the laboratories. The research will identify impacts of various industrial/agricultural activities and help to distinguish them from natural variations, and will include species for which there are no long records of anthropogenic impact. The work will also help to predict future atmospheric loadings. The project will contribute to training scientists at several levels, including seven undergraduates, two graduate students and one post doctoral fellow.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e SPECTROMETERS/RADIOMETERS \u003e SPECTROMETERS \u003e SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; WAIS Divide; Firn; LABORATORY; Ice Core; Firn Air Isotope Measurements; Shallow Firn Air; FIELD INVESTIGATION; Ice Core Gas Records; GROUND-BASED OBSERVATIONS; Firn Isotopes; Wais Divide-project; Gas Data; Polar Firn Air; Not provided; Trace Gas Species; Trapped Gases; West Antarctic Ice Sheet; Deep Core; Ice Sheet; Gas; Firn Air Isotopes; FIELD SURVEYS; Air Samples; Atmospheric Gases; Isotope; Cores; Atmosphere; Ice Core Data; Surface Temperatures; Firn Air; Borehole; Antarctica", "locations": "West Antarctic Ice Sheet; Antarctica; WAIS Divide", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Battle, Mark; Mischler, John; Saltzman, Eric; Aydin, Murat; White, James; Brook, Edward J.; Orsi, Anais J.; Severinghaus, Jeffrey P.; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "uid": "p0000368", "west": -112.085}, {"awards": "0337891 Brook, Edward J.", "bounds_geometry": "POINT(158 -77.666667)", "dataset_titles": "Atmospheric CO2 and Climate: Byrd Ice Core, Antarctica; Atmospheric CO2 and Climate: Taylor Dome Ice Core, Antarctica", "datasets": [{"dataset_uid": "609314", "doi": "10.7265/N58W3B80", "keywords": "Antarctica; Atmosphere; Byrd Glacier; Byrd Ice Core; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Byrd Ice Core", "title": "Atmospheric CO2 and Climate: Byrd Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609314"}, {"dataset_uid": "609315", "doi": "10.7265/N5542KJK", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Taylor Dome; Taylor Dome Ice Core", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Atmospheric CO2 and Climate: Taylor Dome Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609315"}], "date_created": "Mon, 05 Nov 2007 00:00:00 GMT", "description": "This award supports the development of a new laboratory capability in the U.S. to measure CO2 in ice cores and investigate millennial-scale changes in CO2 during the last glacial period using samples from the Byrd and Siple Dome ice cores. Both cores have precise relative chronologies based on correlation of methane and the isotopic composition of atmospheric oxygen with counterpart records from Greenland ice cores. The proposed work will therefore allow comparison of the timing of CO2 change, Antarctic temperature change, and Greenland temperature change on common time scales. Such comparisons are vital for evaluating models that explain changes in atmospheric CO2. The techniques being developed will also be available for future projects, specifically the proposed Inland WAIS ice core, for which a highly detailed CO2 record is a major objective, and studies greenhouse and other atmospheric gases and their isotopic composition for which dry extraction is necessary (stable isotopes in CO2, for example). There are many broad impacts of the proposed work. Ice core greenhouse gas records are central contributions of paleoclimatology to research and policy-making concerning global change. The proposed work will enhance those contributions by improving our understanding of the natural cycling of the most important greenhouse gas. It will contribute to the training of a postdoctoral researcher, who will be an integral part of an established research group and benefit from the diverse paleoclimate and geochemistry community at OSU. The PI teaches major and non-major undergraduate and graduate courses on climate and global change. The proposed work will enrich those courses and the courses will provide an opportunity for the postdoctoral researcher to participate in teaching by giving guest lectures. The PI also participates in a summer climate workshop for high school teachers at Washington State University and the proposed work will enrich that contribution. The extraction device that is built and the expertise gained in using it will be resources for the ice core community and available for future projects. Data will be made available through established national data center and the equipment designs will also be made available to other researchers.", "east": 158.0, "geometry": "POINT(158 -77.666667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core; Climate Change; CO2; Atmospheric Chemistry; Atmospheric CO2; LABORATORY; Not provided; Ice Core Data; Climate; Ice Core Chemistry; Atmospheric Gases; Ice Core Gas Records; GROUND STATIONS; Climate Research", "locations": null, "north": -77.666667, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Ahn, Jinho; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.666667, "title": "Developing Dry Extraction of Ice Core Gases and Application to Millennial-Scale Variability in Atmospheric CO2", "uid": "p0000268", "west": 158.0}, {"awards": "0230448 Severinghaus, Jeffrey; 0230260 Bender, Michael", "bounds_geometry": "POLYGON((-75.34 86.6,-68.742 86.6,-62.144 86.6,-55.546 86.6,-48.948 86.6,-42.35 86.6,-35.752 86.6,-29.154 86.6,-22.556 86.6,-15.958 86.6,-9.36 86.6,-9.36 83.618,-9.36 80.636,-9.36 77.654,-9.36 74.672,-9.36 71.69,-9.36 68.708,-9.36 65.726,-9.36 62.744,-9.36 59.762,-9.36 56.78,-15.958 56.78,-22.556 56.78,-29.154 56.78,-35.752 56.78,-42.35 56.78,-48.948 56.78,-55.546 56.78,-62.144 56.78,-68.742 56.78,-75.34 56.78,-75.34 59.762,-75.34 62.744,-75.34 65.726,-75.34 68.708,-75.34 71.69,-75.34 74.672,-75.34 77.654,-75.34 80.636,-75.34 83.618,-75.34 86.6))", "dataset_titles": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001; Trapped Gas Composition and Chronology of the Vostok Ice Core", "datasets": [{"dataset_uid": "609311", "doi": "10.7265/N5P26W12", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Lake Vostok; Paleoclimate; Vostok; Vostok Ice Core", "people": "Bender, Michael; Suwa, Makoto", "repository": "USAP-DC", "science_program": null, "title": "Trapped Gas Composition and Chronology of the Vostok Ice Core", "url": "https://www.usap-dc.org/view/dataset/609311"}, {"dataset_uid": "609290", "doi": "10.7265/N5FJ2DQC", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciology; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole", "people": "Bender, Michael; Battle, Mark; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001", "url": "https://www.usap-dc.org/view/dataset/609290"}], "date_created": "Wed, 18 Jan 2006 00:00:00 GMT", "description": "High latitude deep ice cores contain fundamental records of polar temperatures, atmospheric dust loads (and continental aridity), greenhouse gas concentrations, the status of the biosphere, and other essential properties of past environments. An accurate chronology for these records is needed if their significance is to be fully realized. The dating challenge has stimulated efforts at orbital tuning. In this approach, one varies a timescale, within allowable limits, to optimize the match between a paleoenvironmental property and a curve of insolation through time. The ideal property would vary with time due to direct insolation forcing. It would be unaffected by complex climate feedbacks and teleconnections, and it would give a clean record with high signal/noise ratio. It is argued strongly that the O2/N2 ratio of ice core trapped gases is such a property, and evidence is presented that this property, whose atmospheric ratio is nearly constant, is tied to local summertime insolation. This award will support a project to analyze the O2/N2 ratios at 1 kyr intervals from ~ 115-400 ka in the Vostok ice core. Ancillary measurements will be made of Ar/N2, and Ne/N2 and heavy noble gas ratios, in order to understand bubble close-off fractionation and its manifestation in the Vostok trapped gas record. O2/N2 variations will be matched with summertime insolation at Vostok to achieve a high-accuracy chronology for the Vostok core. The Vostok and other correlatable climate records will then be reexamined to improve our understanding of the dynamics of Pleistocene climate change.", "east": 106.8, "geometry": "POINT(106.8 -72.4667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Paleoclimate; Siple Dome; Ice Age; Shallow Firn Air; Firn Air Isotope Measurements; Polar Firn Air; Ice Sample Gas Integrity; Oxygen Isotope; Noble Gas; Ice Core Gas Records; Atmospheric Gases; Trapped Gases; Not provided; LABORATORY; Vostok; Firn Air Isotopes; Thermal Fractionation; Ice Core Chemistry; Trapped Air Bubbles; Ice Core; Antarctica; South Pole; Ice Core Data; GROUND-BASED OBSERVATIONS; Gas Age; Firn Isotopes", "locations": "Antarctica; Vostok; Siple Dome; South Pole", "north": -72.4667, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Bender, Michael; Suwa, Makoto; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -72.4667, "title": "Collaborative Research: Trapped Gas Composition and the Chronology of the Vostok Ice Core", "uid": "p0000257", "west": 106.8}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}, {"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Williams, Margaret; Tatum, Cheryl; Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; Carbonyl Sulfide; Siple Coast; Chloride; Trapped Gases; Snow; Ice Core Chemistry; Chromatography; Siple; GROUND STATIONS; Atmospheric Gases; Ozone Depletion; AWS Siple; Ice Sheet; Ice Core Data; Antarctica; Glaciology; West Antarctica; Atmospheric Chemistry; Ice Core; Stratigraphy; LABORATORY; Methane; Mass Spectrometer; GROUND-BASED OBSERVATIONS; WAISCORES; Msa; Mass Spectrometry; Not provided; Siple Dome; Gas Measurement", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica; Siple", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}, {"awards": "0125981 Sowers, Todd", "bounds_geometry": "POLYGON((-180 -62.83,-144 -62.83,-108 -62.83,-72 -62.83,-36 -62.83,0 -62.83,36 -62.83,72 -62.83,108 -62.83,144 -62.83,180 -62.83,180 -65.547,180 -68.264,180 -70.981,180 -73.698,180 -76.415,180 -79.132,180 -81.849,180 -84.566,180 -87.283,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.283,-180 -84.566,-180 -81.849,-180 -79.132,-180 -76.415,-180 -73.698,-180 -70.981,-180 -68.264,-180 -65.547,-180 -62.83))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 05 May 2005 00:00:00 GMT", "description": "0125981\u003cbr/\u003eSowers\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to construct an isotopic record of atmospheric methane and nitrous oxide over the last century from South Pole firn air. Over the last 150 years, atmospheric methane and nitrous oxide concentrations have risen in response to increased emissions from various anthropogenic activities. As this trend is liable to continue in the foreseeable future, it is important to understand the biogeochemical processes that contribute to the emissions of these two greenhouse gases. In this context, records of the variations in the atmospheric loading of trace gases found in ice cores and interstitial spaces in the snow near the surface of the ice sheet (firn air) provide fundamental boundary conditions for reconstructing historical emission records. One way to improve our understanding of the cycling of bioactive trace gases and their emission records is to use stable isotope tracers, which have been recorded in the ice cores and firn air. This project will develop records of carbon-13 and deuterium isotope ratios of methane, as well as the nitrogen-15, oxygen-18 and the isotopomer composition of nitrous oxide trapped in firn air samples collected in January 2001 at the South Pole. These measurements will allow isotopic records of these atmospheric gases to be reconstructed throughout the 20th century. Such records will help to establish the relative contribution of individual sources with a higher degree of confidence than is currently available.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": -62.83, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Sowers, Todd A.", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -90.0, "title": "Generating an Isotopic Record of Atmospheric Methane and Nitrous Oxide Over the Last Century from South Pole Firn Air", "uid": "p0000086", "west": -180.0}, {"awards": "9725305 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "datasets": [{"dataset_uid": "609098", "doi": "10.7265/N51N7Z2P", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciology; Isotope; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole; Temperature", "people": "Grachev, Alexi; Battle, Mark; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "url": "https://www.usap-dc.org/view/dataset/609098"}], "date_created": "Mon, 01 Jan 2001 00:00:00 GMT", "description": "9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Isotopic History; GROUND STATIONS; Thermal Diffusion; Firn Temperature Measurements; Not provided; Oxygen Isotope; Trapped Air Bubbles; Shallow Firn Air; Firn Air Isotope Measurements; Seasonal Temperature Gradients; Mass Spectrometry; GROUND-BASED OBSERVATIONS; Thermal Fractionation; Polar Firn Air; Isotopic Anomalies; Xenon; Atmospheric Gases; Argon Isotopes; Siple Dome; Krypton; Nitrogen Isotopes; Seasonal Temperature Changes; Antarctica; Ice Core Gas Records; Firn Air Isotopes; Mass Spectrometer; South Pole; Firn Isotopes; Borehole", "locations": "Antarctica; Siple Dome; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change", "uid": "p0000160", "west": null}]
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Project Title/Abstract/Map | NSF Award(s) | Date Created | PIs / Scientists | Dataset Links and Repositories | Abstract | Bounds Geometry | Geometry | Selected | Visible | |||||
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Tracing Past Methane Variations with Stable Isotopes in Antarctic Ice Cores
|
1745078 |
2023-05-01 | Brook, Edward | This project will develop methods to measure the ratios of carbon-13 to carbon-12, and heavy to light hydrogen in methane in air trapped in ice cores. The ratios of the different forms of carbon and hydrogen are "fingerprints" of different sources of this gas in the past--for example wetlands in the tropics versus methane frozen in the sea floor. Once the analysis method is developed, the measurements will be used to examine why methane changed abruptly in the past, both during the last ice age, and during previous warm periods. The data will be used to understand how methane sources like wildfires, methane hydrates, and wetlands respond to climate change. This information is needed to understand future risks of large changes in methane in the atmosphere as Earth warms. The project involves two tasks. First, the investigators will build and test a gas extraction system for methane isotopic measurements using continuous flow methods, with the goal of equaling or bettering the precision attained by the few other laboratories that make these measurements. The system will be interfaced with existing mass spectrometers at Oregon State University. The system consists of a vacuum chamber and sequence of traps, purification columns, and furnaces that separate methane from other gases and convert it to carbon dioxide or hydrogen for mass spectrometry. Second, the team will measure the isotopic composition of methane across large changes in concentration associated with two past interglacial periods and during abrupt methane changes of the last ice age. These measurements will be used to understand if the main reason for these concentration changes is climate-driven changes in emissions from wetlands, or whether other sources are involved, for example methane hydrates or wildfires. This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria. | POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60)) | POINT(0 -89.999) | false | false | ||||||
CAREER: Ecosystem Impacts of Microbial Succession and Production at Antarctic Methane Seeps
|
2046800 |
2021-08-21 | Thurber, Andrew | No dataset link provided | Part I: Non-technical description: Methane is one of the more effective atmospheric gases at retaining heat in the lower atmosphere and the earth’s crust contains large quantities of methane. Research that identifies the factors that control methane’s release into the atmosphere is critical to understanding and mitigating climate change. One of the most effective natural processes that inhibits the release of methane from aquatic habitats is a community of bacteria and Archaea (microbes) that use the chemical energy stored in methane, transforming methane into less-climate-sensitive compounds. The amount of methane that may be released in Antarctica is unknown, and it is unclear which microbes consume the methane before it is released from the ocean in Antarctica. This project will study one of the few methane seeps known in Antarctica to advance our understanding of which microbes inhibit the release of methane in marine environments. The research will also identify if methane is a source of energy for other Antarctic organisms. The researchers will analyze the microbial species associated with methane consumption over several years of field and laboratory research based at an Antarctic US station, McMurdo. This project clearly expands the fundamental knowledge of Antarctic systems, biota, and processes outlined as a goal in the Antarctic solicitation. This research communicates and produces educational material for K-12, college, and graduate students to inspire and inform the public about the role Antarctic ecosystems play in the global environment. This project also provides a young professor an opportunity to establish himself as an expert in the field of Antarctic microbial ecology to help solidify his academic career. Part II: Technical description: Microbes act as filter to methane release from the ocean into the atmosphere, where microbial chemosynthetic production harvests the chemical energy stored in this greenhouse gas. In spite of methane reservoirs in Antarctica being as large as Arctic permafrost, we know only a little about the taxa or dominant processes involved in methane consumption in Antarctica. The principal investigator will undertake a genomic and transcriptomic study of microbial communities developed and still developing after initiation of methane seepage in McMurdo Sound. An Antarctic methane seep was discovered at this location in 2012 after it began seeping in 2011. Five years after it began releasing methane, the methane-oxidizing microbial community was underdeveloped and methane was still escaping from the seafloor. This project will be essential in elucidating the response of microbial communities to methane release and identify how methane oxidation occurs within the constraints of the low polar temperatures. This investigation is based on 4 years of field sampling and will establish a time series of the development of cold seep microbial communities in Antarctica. A genome-to-ecosystem approach will establish how the Southern Ocean microbial community is adapted to prevent methane release into the ocean. As methane is an organic carbon source, results from this study will have implications for the Southern Ocean carbon cycle. Two graduate students will be trained and supported with undergraduates participating in laboratory activities. The researcher aims to educate, inspire and communicate about Antarctic methane seeps to a broad community. A mixed-media approach, with videos, art and education in schools will be supported in collaboration with a filmmaker, teachers and a visual artist. Students will be trained in filmmaking and K-12 students from under-represented communities will be introduced to Antarctic science through visual arts. This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria. | POLYGON((162 -77,162.6 -77,163.2 -77,163.8 -77,164.4 -77,165 -77,165.6 -77,166.2 -77,166.8 -77,167.4 -77,168 -77,168 -77.1,168 -77.2,168 -77.3,168 -77.4,168 -77.5,168 -77.6,168 -77.7,168 -77.8,168 -77.9,168 -78,167.4 -78,166.8 -78,166.2 -78,165.6 -78,165 -78,164.4 -78,163.8 -78,163.2 -78,162.6 -78,162 -78,162 -77.9,162 -77.8,162 -77.7,162 -77.6,162 -77.5,162 -77.4,162 -77.3,162 -77.2,162 -77.1,162 -77)) | POINT(165 -77.5) | false | false | |||||
Collaborative Research: Long Term Sublimation/Preservation of Two Separate, Buried Glacier Ice Masses, Ong Valley, Southern Transantarctic Mountains
|
1445205 |
2021-07-16 | putkonen, jaakko; Balco, Gregory; Morgan, Daniel |
|
Putkonen/1445205 This award supports the study of a large body of ice that is buried beneath approximately a meter of debris in the Ong Valley of the Transantarctic Mountains of East Antarctica. Preliminary analyses of this material suggest that it could be over a million years old. Most glacial ice contains tiny air bubbles that have trapped the atmospheric gases and other atmospherically transported materials existing at the time that the ice was deposited such as plant pollen, microbes and mineral dust. Samples will be collected from this buried ice mass, down to a depth of 10 meters, and cosmogenic nuclide concentrations both in the overlying debris and in the till contained in the ice will be measured. This site could contain some of the oldest ice on Earth and studies of the material contained within it may help researchers to better understand the processes involved in its survival for such long periods of time. This work will also help inform scientists about the processes involved in the development of landforms here on earth as well as those on Mars where similar dirt covered glaciers are found today. Samples of the buried ice will be collected in Ong Valley and analyzed to determine the cosmogenic nuclide concentrations in both the overlying debris and in the mineral matter suspended in the ice. The combined analysis of the target cosmogenic nuclides (Beryllium-10, Aluminum-26, and Neon-21) will allow the age of the ice to be uniquely determined and will enable determination of the rate that the ice is sublimating. The intellectual merit of this research is to unequivocally determine the age of the ice and the sublimation rate of the ice in Ong Valley, Antarctica and to better understand if this an uniquely Antarctic process or whether it could exist elsewhere on earth or on other planets. The work may also lead to the recognition of the oldest buried ice ever found on Earth and would provide a source from which direct information about the atmospheric chemistry, ancient life forms, and geology of that time could be measured. The broader impacts of this work are that it will be relevant to researchers in a number of different fields including glaciology, paleoclimatology, planetary geology, and biology. Several students will also participate in the project, conducting Antarctic field work, making measurements in the lab, attending meetings, participating in outreach activities, and producing videos. A graduate student will also write a thesis on this research. The results will be published in scientific journals and presented at conferences. The project requires field work in Antarctica. | POLYGON((157.6 -83.2,157.62 -83.2,157.64 -83.2,157.66 -83.2,157.68 -83.2,157.7 -83.2,157.72 -83.2,157.74 -83.2,157.76 -83.2,157.78 -83.2,157.8 -83.2,157.8 -83.21,157.8 -83.22,157.8 -83.23,157.8 -83.24,157.8 -83.25,157.8 -83.26,157.8 -83.27,157.8 -83.28,157.8 -83.29,157.8 -83.3,157.78 -83.3,157.76 -83.3,157.74 -83.3,157.72 -83.3,157.7 -83.3,157.68 -83.3,157.66 -83.3,157.64 -83.3,157.62 -83.3,157.6 -83.3,157.6 -83.29,157.6 -83.28,157.6 -83.27,157.6 -83.26,157.6 -83.25,157.6 -83.24,157.6 -83.23,157.6 -83.22,157.6 -83.21,157.6 -83.2)) | POINT(157.7 -83.25) | false | false | |||||
EAGER: Feasibility of Reconstructing the Atmospheric History of Molecular Hydrogen from Antarctic Ice
|
1907974 |
2020-06-09 | Saltzman, Eric |
|
Hydrogen (H2) is one of the most abundant trace gases in the atmosphere, with a mean level of 500 ppb and an atmospheric lifetime of about two years. Hydrogen has an impact on both air quality and climate, due to its role as a precursor for tropospheric ozone and stratospheric water vapor. Projections indicate that a future "hydrogen economy" would increase hydrogen emissions. Understanding of the atmospheric hydrogen budget is largely based on a 30-year record of surface air measurements, but there are no long-term records with which to assess either: 1) the influence of climate change on atmospheric hydrogen, or 2) the extent to which humans have impacted the hydrogen budget. Polar ice core records of hydrogen will advance our understanding of the atmospheric hydrogen cycle and provide a stronger basis for projecting future changes to atmospheric levels of hydrogen and their impacts. The research will involve laboratory work to enable the collection and analysis of hydrogen in polar ice cores. Hydrogen is a highly diffusive molecule and, unlike most other atmospheric gases, diffusion of hydrogen in ice is so rapid that ice samples must be stored in impermeable containers immediately upon drilling and recovery. This project will: 1) construct a laboratory system for extracting and analyzing hydrogen in polar ice, 2) develop and test materials and construction designs for vessels to store ice core samples in the field, and 3) test the method on samples of opportunity previously stored in the field. The goal of this project is a proven, cost-effective design for storage flasks to be fabricated for use on future polar ice coring projects. This project will support the dissertation research of a graduate student in the UC Irvine Department of Earth System Science. This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria. | POLYGON((129.26 -89.86,130.261 -89.86,131.262 -89.86,132.263 -89.86,133.264 -89.86,134.265 -89.86,135.266 -89.86,136.267 -89.86,137.268 -89.86,138.269 -89.86,139.27 -89.86,139.27 -89.861,139.27 -89.862,139.27 -89.863,139.27 -89.864,139.27 -89.865,139.27 -89.866,139.27 -89.867,139.27 -89.868,139.27 -89.869,139.27 -89.87,138.269 -89.87,137.268 -89.87,136.267 -89.87,135.266 -89.87,134.265 -89.87,133.264 -89.87,132.263 -89.87,131.262 -89.87,130.261 -89.87,129.26 -89.87,129.26 -89.869,129.26 -89.868,129.26 -89.867,129.26 -89.866,129.26 -89.865,129.26 -89.864,129.26 -89.863,129.26 -89.862,129.26 -89.861,129.26 -89.86)) | POINT(134.265 -89.865) | false | false | |||||
Collaborative Research: A 1500m Ice Core from South Pole
|
1142517 1141839 1142646 |
2019-10-30 | Twickler, Mark; Souney, Joseph Jr.; Aydin, Murat; Steig, Eric J. | 1142517/Saltzman This proposal requests support for a project to drill and recover a new ice core from South Pole, Antarctica. The South Pole ice core will be drilled to a depth of 1500 m, providing an environmental record spanning approximately 40 kyrs. This core will be recovered using a new intermediate drill, which is under development by the U.S. Ice Drilling Design and Operations (IDDO) group in collaboration with Danish scientists. This proposal seeks support to provide: 1) scientific management and oversight for the South Pole ice core project, 2) personnel for ice core drilling and core processing, 3) data management, and 3) scientific coordination and communication via scientific workshops. The intellectual merit of the work is that the analysis of stable isotopes, atmospheric gases, and aerosol-borne chemicals in polar ice has provided unique information about the magnitude and timing of changes in climate and climate forcing through time. The international ice core research community has articulated the goal of developing spatial arrays of ice cores across Antarctica and Greenland, allowing the reconstruction of regional patterns of climate variability in order to provide greater insight into the mechanisms driving climate change. The broader impacts of the project include obtaining the South Pole ice core will support a wide range of ice core science projects, which will contribute to the societal need for a basic understanding of climate and the capability to predict climate and ice sheet stability on long time scales. Second, the project will help train the next generation of ice core scientists by providing the opportunity for hands-on field and core processing experience for graduate students and postdoctoral researchers. A postdoctoral researcher at the University of Washington will be directly supported by this project, and many other young scientists will interact with the project through individual science proposals. Third, the project will result in the development of a new intermediate drill which will become an important resource to US ice core science community. This drill will have a light logistical footprint which will enable a wide range of ice core projects to be carried out that are not currently feasible. Finally, although this project does not request funds for outreach activities, the project will run workshops that will encourage and enable proposals for coordinated outreach activities involving the South Pole ice core science team. | POINT(90 -90) | POINT(90 -90) | false | false | ||||||
Collaborative Research: Characterization of Upstream Ice and Firn Dynamics affecting the South Pole Ice Core
|
1443341 1443471 |
2018-06-14 | Koutnik, Michelle; Conway, Howard; Waddington, Edwin D.; Fudge, T. J.; Hawley, Robert L.; Osterberg, Erich | Ice-core records are critical to understanding past climate variations. An Antarctic ice core currently being drilled at the South Pole will allow detailed investigation of atmospheric gases and fill an important gap in understanding the pattern of climate variability across Antarctica. Critical to the interpretation of any ice core are: 1) accurate chronologies for both the ice and the trapped gas and 2) demonstration that records from the ice core reliably reflect climate. The proposed research will improve the ice and gas chronologies by making measurements of snow compaction in the upstream catchment in order to constrain age models of the ice. These measurements will be a key data set needed for better understanding and predicting time-varying conditions in the upper part of the ice sheet. The research team will measure the modern spatial gradients in accumulation rate, surface temperature, and water stable isotopes from shallow ice cores in the upstream catchment in order to determine the climate history from the ice-core record. The new ice-flow measurements will make it possible to define the path of ice from upstream to the South Pole ice-core drill site to assess spatial gradients in snowfall and to infer histories of snowfall from internal layers within the ice sheet. The project will be led by an early-career scientist, provide broad training to graduate students, and engage in public outreach on polar science. Ice-core records of stable isotopes, aerosol-born particles, and atmospheric gases are critical to understanding past climate variations. The proposed research will improve the ice and gas chronologies in the South Pole ice core by making in situ measurements of firn compaction in the upstream catchment to constrain models of the gas-age ice-age difference. The firn measurements will be a key data set needed to form a constitutive relationship for firn, and will drive better understanding and prediction of transient firn evolution. The research team will measure the modern gradients in accumulation rate, surface temperature, and water stable isotopes in the upstream catchment to separate spatial (advection) variations from temporal (climate) variations in the ice-core records. The ice-flow measurements will define the flowline upstream of the drill site, assess spatial gradients in accumulation, and infer histories of accumulation from radar-observed internal layers. Results will directly enhance interpretation of South Pole ice-core records, and also advance understanding of firn densification and drive next-generation firn models. | POLYGON((110 -89,117 -89,124 -89,131 -89,138 -89,145 -89,152 -89,159 -89,166 -89,173 -89,180 -89,180 -89.1,180 -89.2,180 -89.3,180 -89.4,180 -89.5,180 -89.6,180 -89.7,180 -89.8,180 -89.9,180 -90,173 -90,166 -90,159 -90,152 -90,145 -90,138 -90,131 -90,124 -90,117 -90,110 -90,110 -89.9,110 -89.8,110 -89.7,110 -89.6,110 -89.5,110 -89.4,110 -89.3,110 -89.2,110 -89.1,110 -89)) | POINT(145 -89.5) | false | false | ||||||
Using Electrical Conductance Measurements to Develop the South Pole Ice Core Chronology
|
1443232 |
2018-05-08 | Fudge, T. J.; Waddington, Edwin D. |
|
Ice cores record detailed histories of past climate variations. The South Pole ice core will allow investigation of atmospheric trace gases and fill an important gap in understanding the pattern of climate variability across Antarctica. An accurate timescale that assigns an age to the ice at each depth in the core is essential to interpretation of the ice-core records. This work will use electrical methods to identify volcanic eruptions throughout the past ~40,000 years in the core by detecting the enhanced electrical conductance in those layers due to volcanic impurities in the ice. These eruptions will be pattern-matched to other cores across Antarctica, synchronizing the timing of climate variations among cores and allowing the precise timescales developed for other Antarctic ice cores to be transferred to the South Pole ice core. The well-dated records of volcanic forcing will be combined with records of atmospheric gases, stable water-isotopes, and aerosols to better understand the large natural climate variations of the past 40,000 years. The electrical conductance method and dielectric profiling measurements will be made along the length of each section of the South Pole ice core at the National Ice Core Lab. These measurements will help to establish a timescale for the core. Electrical measurements will provide a continuous record of volcanic events for the entire core including through the brittle ice (550-1250m representing ~10,000-20,000 year-old ice) where the core quality and thin annual layers may prevent continuous melt analysis and cause discrete measurements to miss volcanic events. The electrical measurements also produce a 2-D image of the electrical layering on a longitudinal cut surface of each core. These data will be used to identify any irregular or absent layering that would indicate a stratigraphic disturbance in the core. A robust chronology is essential to interpretation of the paleoclimate records from the South Pole ice core. The investigators will engage teachers through talks and webinars with the National Science Teachers Association and will share information with the public at events such as Polar Science Weekend at the Pacific Science Center. Results will be disseminated through publications and conference presentations and the data will be archived and publicly available. | POLYGON((110 -89,117 -89,124 -89,131 -89,138 -89,145 -89,152 -89,159 -89,166 -89,173 -89,180 -89,180 -89.1,180 -89.2,180 -89.3,180 -89.4,180 -89.5,180 -89.6,180 -89.7,180 -89.8,180 -89.9,180 -90,173 -90,166 -90,159 -90,152 -90,145 -90,138 -90,131 -90,124 -90,117 -90,110 -90,110 -89.9,110 -89.8,110 -89.7,110 -89.6,110 -89.5,110 -89.4,110 -89.3,110 -89.2,110 -89.1,110 -89)) | POINT(145 -89.5) | false | false | |||||
Collaborative Research: Allan HILLs Englacial Site (AHILLES) Selection
|
1443260 |
2017-05-02 | Conway, Howard |
|
Marine paleoclimate archives show that approximately one million years ago Earth's climate transitioned from 40,000-year glacial /interglacial cycles to 100,000-year cycles. This award will support a study designed to map the distribution of one million year-old ice in the Allan Hills Blue Ice Area, Antarctica using state-of-the-art ground penetrating radar. The Allen Hills was demonstrated to contain a continuous record of the past 400,000 years and is also the collection location of the oldest ice samples (990,000 years) yet recovered. The maps resulting from this study will be used to select an ice-core drilling site at which a million-plus year-old continuous record of climate could be recovered. Ice cores contain the only kind of record to directly capture atmospheric gases and aerosols, but no ice-core-based climate record yet extends continuously beyond the past 800,000 years. A million-plus year-old record will allow better understanding of the major mechanisms and driving forces of natural climate variability in a world with 100,000-year glacial/interglacial cycles. The project will support two early career scientists in collaboration with senior scientists, as well as a graduate student, and will conduct outreach to schools and the public. The Allan Hills Blue Ice Area preserves a continuous climate record covering the last 400,000 years along an established glaciological flow line. Two kilometers to the east of this flow line, the oldest ice on Earth (~1 million years old) is found only 120 m below the surface. Meteorites collected in the area are reported to be as old as 1.8 million years, suggesting still older ice may be present. Combined, these data strongly suggest that the Allen Hills area could contain a continuous, well-resolved environmental record, spanning at least the last million years. As such, this area has been selected as an upcoming target for the new Intermediate Depth Ice Core Drill by the US Ice Core Working Group. This drill will recover a higher-quality core than previous dry drilling attempts. This project will conduct a comprehensive ground penetrating radar survey aimed at tracing the signature of the million-year-old ice layer throughout the region. The resulting map will be used to select a drill site from which an ice core containing the million-plus year-old continuous climate record will be collected. The proposed activities are a necessary precursor to the collection of the oldest known ice on Earth. Ice cores provide a robust reconstruction of past climate and extending this record beyond the 800,000 years currently available will open new opportunities to study the climate system. The data collected will also be used to investigate the bedrock and ice flow parameters favorable to the preservation of old ice, which may allow targeted investigation of other blue ice areas in Antarctica. | POLYGON((159 -76.68,159.03 -76.68,159.06 -76.68,159.09 -76.68,159.12 -76.68,159.15 -76.68,159.18 -76.68,159.21 -76.68,159.24 -76.68,159.27 -76.68,159.3 -76.68,159.3 -76.697,159.3 -76.714,159.3 -76.731,159.3 -76.748,159.3 -76.765,159.3 -76.782,159.3 -76.799,159.3 -76.816,159.3 -76.833,159.3 -76.85,159.27 -76.85,159.24 -76.85,159.21 -76.85,159.18 -76.85,159.15 -76.85,159.12 -76.85,159.09 -76.85,159.06 -76.85,159.03 -76.85,159 -76.85,159 -76.833,159 -76.816,159 -76.799,159 -76.782,159 -76.765,159 -76.748,159 -76.731,159 -76.714,159 -76.697,159 -76.68)) | POINT(159.15 -76.765) | false | false | |||||
Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site
|
0440759 0440498 0440602 0440509 0440701 0440615 |
2009-02-03 | Battle, Mark; Mischler, John; Saltzman, Eric; Aydin, Murat; White, James; Brook, Edward J.; Orsi, Anais J.; Severinghaus, Jeffrey P.; Sowers, Todd A. | This award supports a project to measure the elemental and isotopic composition of firn air and occluded air in shallow boreholes and ice cores from the WAIS Divide site, the location of a deep ice-coring program planned for 2006-07 and subsequent seasons. The three primary objectives are: 1) to establish the nature of firn air movement and trapping at the site to aid interpretations of gas data from the deep core; 2) to expand the suite of atmospheric trace gas species that can be measured in ice and replicate existing records of other species; and 3) to inter-calibrate all collaborating labs to insure that compositional and isotopic data sets are inter-comparable. The program will be initiated with a shallow drilling program during the 05/06 field season which will recover two 300+m cores and firn air samples. The ice core and firn air will provide more than 700 years of atmospheric history that will be used to address a number of important questions related to atmospheric change over this time period. The research team consists of six US laboratories that also plan to participate in the deep core program. This collaborative research program has a number of advantages. First, the scientists will be able to coordinate sample allocation a priori to maximize the resolution and overlap of records of interrelated species. Second, sample registration will be exact, allowing direct comparison of all records. Third, a coherent data set will be produced at the same time and all PI.s will participate in interpreting and publishing the results. This will insure that the best possible understanding of gas records at the WAIS Divide site will be achieved, and that all work necessary to interpret the deep core is conducted in a timely fashion. The collaborative structure created by the proposal will encourage sharing of techniques, equipment, and ideas between the laboratories. The research will identify impacts of various industrial/agricultural activities and help to distinguish them from natural variations, and will include species for which there are no long records of anthropogenic impact. The work will also help to predict future atmospheric loadings. The project will contribute to training scientists at several levels, including seven undergraduates, two graduate students and one post doctoral fellow. | POINT(-112.085 -79.467) | POINT(-112.085 -79.467) | false | false | ||||||
Developing Dry Extraction of Ice Core Gases and Application to Millennial-Scale Variability in Atmospheric CO2
|
0337891 |
2007-11-05 | Ahn, Jinho; Brook, Edward J. |
|
This award supports the development of a new laboratory capability in the U.S. to measure CO2 in ice cores and investigate millennial-scale changes in CO2 during the last glacial period using samples from the Byrd and Siple Dome ice cores. Both cores have precise relative chronologies based on correlation of methane and the isotopic composition of atmospheric oxygen with counterpart records from Greenland ice cores. The proposed work will therefore allow comparison of the timing of CO2 change, Antarctic temperature change, and Greenland temperature change on common time scales. Such comparisons are vital for evaluating models that explain changes in atmospheric CO2. The techniques being developed will also be available for future projects, specifically the proposed Inland WAIS ice core, for which a highly detailed CO2 record is a major objective, and studies greenhouse and other atmospheric gases and their isotopic composition for which dry extraction is necessary (stable isotopes in CO2, for example). There are many broad impacts of the proposed work. Ice core greenhouse gas records are central contributions of paleoclimatology to research and policy-making concerning global change. The proposed work will enhance those contributions by improving our understanding of the natural cycling of the most important greenhouse gas. It will contribute to the training of a postdoctoral researcher, who will be an integral part of an established research group and benefit from the diverse paleoclimate and geochemistry community at OSU. The PI teaches major and non-major undergraduate and graduate courses on climate and global change. The proposed work will enrich those courses and the courses will provide an opportunity for the postdoctoral researcher to participate in teaching by giving guest lectures. The PI also participates in a summer climate workshop for high school teachers at Washington State University and the proposed work will enrich that contribution. The extraction device that is built and the expertise gained in using it will be resources for the ice core community and available for future projects. Data will be made available through established national data center and the equipment designs will also be made available to other researchers. | POINT(158 -77.666667) | POINT(158 -77.666667) | false | false | |||||
Collaborative Research: Trapped Gas Composition and the Chronology of the Vostok Ice Core
|
0230448 0230260 |
2006-01-18 | Battle, Mark; Bender, Michael; Suwa, Makoto; Severinghaus, Jeffrey P. |
|
High latitude deep ice cores contain fundamental records of polar temperatures, atmospheric dust loads (and continental aridity), greenhouse gas concentrations, the status of the biosphere, and other essential properties of past environments. An accurate chronology for these records is needed if their significance is to be fully realized. The dating challenge has stimulated efforts at orbital tuning. In this approach, one varies a timescale, within allowable limits, to optimize the match between a paleoenvironmental property and a curve of insolation through time. The ideal property would vary with time due to direct insolation forcing. It would be unaffected by complex climate feedbacks and teleconnections, and it would give a clean record with high signal/noise ratio. It is argued strongly that the O2/N2 ratio of ice core trapped gases is such a property, and evidence is presented that this property, whose atmospheric ratio is nearly constant, is tied to local summertime insolation. This award will support a project to analyze the O2/N2 ratios at 1 kyr intervals from ~ 115-400 ka in the Vostok ice core. Ancillary measurements will be made of Ar/N2, and Ne/N2 and heavy noble gas ratios, in order to understand bubble close-off fractionation and its manifestation in the Vostok trapped gas record. O2/N2 variations will be matched with summertime insolation at Vostok to achieve a high-accuracy chronology for the Vostok core. The Vostok and other correlatable climate records will then be reexamined to improve our understanding of the dynamics of Pleistocene climate change. | POLYGON((-75.34 86.6,-68.742 86.6,-62.144 86.6,-55.546 86.6,-48.948 86.6,-42.35 86.6,-35.752 86.6,-29.154 86.6,-22.556 86.6,-15.958 86.6,-9.36 86.6,-9.36 83.618,-9.36 80.636,-9.36 77.654,-9.36 74.672,-9.36 71.69,-9.36 68.708,-9.36 65.726,-9.36 62.744,-9.36 59.762,-9.36 56.78,-15.958 56.78,-22.556 56.78,-29.154 56.78,-35.752 56.78,-42.35 56.78,-48.948 56.78,-55.546 56.78,-62.144 56.78,-68.742 56.78,-75.34 56.78,-75.34 59.762,-75.34 62.744,-75.34 65.726,-75.34 68.708,-75.34 71.69,-75.34 74.672,-75.34 77.654,-75.34 80.636,-75.34 83.618,-75.34 86.6)) | POINT(106.8 -72.4667) | false | false | |||||
Methyl chloride and methyl bromide in Antarctic ice cores
|
0338359 |
2005-11-16 | Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl | This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students. | POINT(-148.81 -81.65) | POINT(-148.81 -81.65) | false | false | ||||||
Generating an Isotopic Record of Atmospheric Methane and Nitrous Oxide Over the Last Century from South Pole Firn Air
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0125981 |
2005-05-05 | Sowers, Todd A. | No dataset link provided | 0125981<br/>Sowers<br/><br/>This award supports a project to construct an isotopic record of atmospheric methane and nitrous oxide over the last century from South Pole firn air. Over the last 150 years, atmospheric methane and nitrous oxide concentrations have risen in response to increased emissions from various anthropogenic activities. As this trend is liable to continue in the foreseeable future, it is important to understand the biogeochemical processes that contribute to the emissions of these two greenhouse gases. In this context, records of the variations in the atmospheric loading of trace gases found in ice cores and interstitial spaces in the snow near the surface of the ice sheet (firn air) provide fundamental boundary conditions for reconstructing historical emission records. One way to improve our understanding of the cycling of bioactive trace gases and their emission records is to use stable isotope tracers, which have been recorded in the ice cores and firn air. This project will develop records of carbon-13 and deuterium isotope ratios of methane, as well as the nitrogen-15, oxygen-18 and the isotopomer composition of nitrous oxide trapped in firn air samples collected in January 2001 at the South Pole. These measurements will allow isotopic records of these atmospheric gases to be reconstructed throughout the 20th century. Such records will help to establish the relative contribution of individual sources with a higher degree of confidence than is currently available. | POLYGON((-180 -62.83,-144 -62.83,-108 -62.83,-72 -62.83,-36 -62.83,0 -62.83,36 -62.83,72 -62.83,108 -62.83,144 -62.83,180 -62.83,180 -65.547,180 -68.264,180 -70.981,180 -73.698,180 -76.415,180 -79.132,180 -81.849,180 -84.566,180 -87.283,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.283,-180 -84.566,-180 -81.849,-180 -79.132,-180 -76.415,-180 -73.698,-180 -70.981,-180 -68.264,-180 -65.547,-180 -62.83)) | POINT(0 -89.999) | false | false | |||||
Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change
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9725305 |
2001-01-01 | Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P. |
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9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period). | None | None | false | false |