{"dp_type": "Project", "free_text": "Snow Chemistry"}
[{"awards": "0636740 Kreutz, Karl; 0636767 Dunbar, Nelia", "bounds_geometry": "POINT(112.11666 -79.46666)", "dataset_titles": "Microparticle, Conductivity, and Density Measurements from the WAIS Divide Deep Ice Core, Antarctica; Snowpit Chemistry - Methods Comparison, WAIS Divide, Antarctica; Snowpit evidence of the 2011 Puyehue-Cordon Caulle (Chile) eruption in West Antarctica; WAIS Divide Microparticle Concentration and Size Distribution, 0-2400 ka; WAIS Divide Snowpit Chemical and Isotope Measurements, Antarctica; WAIS Divide WDC06A Discrete ICP-MS Chemistry", "datasets": [{"dataset_uid": "609620", "doi": "10.7265/N5Q81B1X", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Trace Elements; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl; Koffman, Bess", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Snowpit Chemistry - Methods Comparison, WAIS Divide, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609620"}, {"dataset_uid": "601036", "doi": "10.15784/601036", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Intracontinental Magmatism; IntraContinental Magmatism; Snow Pit; Tephra; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl; Koffman, Bess", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Snowpit evidence of the 2011 Puyehue-Cordon Caulle (Chile) eruption in West Antarctica", "url": "https://www.usap-dc.org/view/dataset/601036"}, {"dataset_uid": "609506", "doi": "10.7265/N5SJ1HHN", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Isotope; Microparticle Concentration; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl; Koffman, Bess", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Snowpit Chemical and Isotope Measurements, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609506"}, {"dataset_uid": "601023", "doi": "10.15784/601023", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; ICP-MS; Isotope; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide WDC06A Discrete ICP-MS Chemistry", "url": "https://www.usap-dc.org/view/dataset/601023"}, {"dataset_uid": "609499", "doi": "10.7265/N5K07264", "keywords": "Antarctica; Density; Electrical Conductivity; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Microparticle Concentration; Physical Properties; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl; Koffman, Bess; Breton, Daniel; Hamilton, Gordon S.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Microparticle, Conductivity, and Density Measurements from the WAIS Divide Deep Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609499"}, {"dataset_uid": "609616", "doi": "10.7265/N5KK98QZ", "keywords": "Antarctica; Dust; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Particle Size; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl; Koffman, Bess", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Microparticle Concentration and Size Distribution, 0-2400 ka", "url": "https://www.usap-dc.org/view/dataset/609616"}], "date_created": "Tue, 19 Jun 2012 00:00:00 GMT", "description": "This award supports a project to perform continuous microparticle concentration and size distribution measurements (using coulter counter and state-of-the-art laser detector methods), analysis of biologically relevant trace elements associated with microparticles (Fe, Zn, Co, Cd, Cu), and tephra measurements on the WAIS Divide ice core. This initial three-year project includes analysis of ice core spanning the instrumental (~1850-present) to mid- Holocene (~5000 years BP) period, with sample resolution ranging from subannual to decadal. The intellectual merit of the project is that it will help in establishing the relationships among climate, atmospheric aerosols from terrestrial and volcanic sources, ocean biogeochemistry, and greenhouse gases on several timescales which remain a fundamental problem in paleoclimatology. The atmospheric mineral dust plays an important but uncertain role in direct radiative forcing, and the microparticle datasets produced in this project will allow us to examine changes in South Pacific aerosol loading, atmospheric dynamics, and dust source area climate. The phasing of changes in aerosol properties within Antarctica, throughout the Southern Hemisphere, and globally is unclear, largely due to the limited number of annually dated records extending into the glacial period and the lack of a\u003cbr/\u003etephra framework to correlate records. The broader impacts of the proposed research are an interdisciplinary approach to climate science problems, and will contribute to several WAIS Divide science themes as well as the broader paleoclimate and oceanographic communities. Because the research topics have a large and direct societal relevance, the project will form a centerpiece of various outreach efforts at UMaine and NMT including institution websites, public speaking, local K-12 school interaction, media interviews and news releases, and popular literature. At least one PhD student and one MS student will be directly supported by this project, including fieldwork, core processing, laboratory analysis, and data interpretation/publication. We expect that one graduate student per year will apply for a core handler/assistant driller position through the WAIS Divide Science Coordination Office, and that undergraduate student involvement will result in several Capstone experience projects (a UMaine graduation requirement). Data and ideas generated from the project will be integrated into undergraduate and graduate course curricula at both institutions.", "east": 112.11666, "geometry": "POINT(112.11666 -79.46666)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PARTICLE DETECTORS; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ELECTRON MICROPROBES; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e LOPC-PMS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e ICE CORE MELTER; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PARTICLE DETECTORS", "is_usap_dc": true, "keywords": "Ice Core Dust; Tephra; Radiative Forcing; Greenhouse Gas; West Antarctica; Atmospheric Aerosols; Oxygen Isotope; Not provided; WAIS Divide; Snow Pit; Ice Core Chemistry; Microparticle; Wais Divide-project; Microparticles Size; Paleoclimate; LABORATORY; Ice Core Data; Atmospheric Dynamics; Antarctica; FIELD SURVEYS; Ice Core; Trace Elements; FIELD INVESTIGATION; Holocene; Isotope; Snow Chemistry", "locations": "Antarctica; WAIS Divide; West Antarctica", "north": -79.46666, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Koffman, Bess; Kreutz, Karl; Breton, Daniel; Dunbar, Nelia; Hamilton, Gordon S.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.46666, "title": "Collaborative Research: Microparticle/tephra analysis of the WAIS Divide ice core", "uid": "p0000040", "west": 112.11666}, {"awards": "0338008 Wemple, Beverley", "bounds_geometry": null, "dataset_titles": "Laboratory Studies of Isotopic Exchange in Snow; Snow Accumulation and Snow Melt in a Mixed Northern Hardwood-Conifer Forest", "datasets": [{"dataset_uid": "609441", "doi": "10.7265/N54X55R2", "keywords": "Snow/ice; Snow/Ice", "people": "Wemple, Beverley C.", "repository": "USAP-DC", "science_program": null, "title": "Snow Accumulation and Snow Melt in a Mixed Northern Hardwood-Conifer Forest", "url": "https://www.usap-dc.org/view/dataset/609441"}, {"dataset_uid": "609445", "doi": "10.7265/N51834DX", "keywords": "Atmosphere; Chemistry:ice; Chemistry:Ice; Snow/ice; Snow/Ice; Snow Sublimation Rate", "people": "Neumann, Thomas A.", "repository": "USAP-DC", "science_program": null, "title": "Laboratory Studies of Isotopic Exchange in Snow", "url": "https://www.usap-dc.org/view/dataset/609445"}], "date_created": "Fri, 01 Jan 2010 00:00:00 GMT", "description": "This award supports a project to develop a quantitative understanding of the processes active in isotopic exchange between snow/firn and water vapor, which is of paramount importance to ice core interpretation. Carefully controlled laboratory studies will be conducted at a variety of temperatures to empirically measure the mass transfer coefficient (the rate at which water moves from the solid to the vapor phase) for sublimating snow and to determine the time scale for isotopic equilibration between water vapor and ice. In addition the isotopic fractionation coefficient for vapor derived from sublimating ice will be determined and the results will be used to update existing models of mass transfer and isotopic evolution in firn. It is well known that water vapor moves through firn due to diffusion, free convection and forced convection. Although vapor movement through variably-saturated firn due to these processes has been modeled, because of a lack of laboratory data the mass transfer coefficient had to be estimated. Field studies have documented the magnitudes of post-depositional changes, but field studies do not permit rigorous analysis of the relative importance of the many processes which are likely to act in natural snow packs. The results of these laboratory investigations will be broadly applicable to a number of studies and will allow for improvement of existing physically-based models of post-depositional isotopic change, isotopic diffusion in firn, and vapor motion in firn. A major component of this project will be the design and fabrication of the necessary, novel experimental apparatus, which will be facilitated by existing technical expertise, cold room facilities, and laboratory equipment at CRREL. This project is a necessary step toward a quantitative understanding of the isotopic effects of water vapor movement in firn. The proposed work has broader impacts in several different areas. The modeling results will be applicable to a wide range of studies of water in the polar environment, including studies of wind-blown or drifting snow. The proposed collaborative study will partially support a Dartmouth graduate student for three years. This project will also provide support for a young first-time NSF investigator at the University of Vermont. Undergraduate students from Dartmouth will be involved in the research through the Women in Science Project and undergraduate students at the University of Vermont will be supported through the Research Experiences for Undergraduates program. The principal investigators and graduate student will continue their tradition of k-12 school outreach by giving science lessons and talks in local schools each year. Research results will be disseminated through scientific conferences, journal publications, and institutional seminars.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e CAMERAS \u003e CAMERAS; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e SNOW TUBE; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e HYGROMETERS \u003e HYGROMETERS", "is_usap_dc": true, "keywords": "Snow Accumulation; Snow Chemistry; Snow Melt; Snowfall; Snow Water Equivalent; LABORATORY; Seasonal Snow Cover; Not provided; Snow; Sublimation Rate; FIELD SURVEYS; FIELD INVESTIGATION", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Neumann, Thomas A.; Wemple, Beverley C.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Laboratory Studies of Isotopic Exchange in Snow and Firn", "uid": "p0000132", "west": null}, {"awards": "9814810 Bales, Roger", "bounds_geometry": "POLYGON((-124 -76,-120 -76,-116 -76,-112 -76,-108 -76,-104 -76,-100 -76,-96 -76,-92 -76,-88 -76,-84 -76,-84 -77.4,-84 -78.8,-84 -80.2,-84 -81.6,-84 -83,-84 -84.4,-84 -85.8,-84 -87.2,-84 -88.6,-84 -90,-88 -90,-92 -90,-96 -90,-100 -90,-104 -90,-108 -90,-112 -90,-116 -90,-120 -90,-124 -90,-124 -88.6,-124 -87.2,-124 -85.8,-124 -84.4,-124 -83,-124 -81.6,-124 -80.2,-124 -78.8,-124 -77.4,-124 -76))", "dataset_titles": "Atmospheric Mixing Ratios of Hydroperoxides above the West Antarctic Ice Sheet; Twenty-Three Century-scale Ice Core Records of Hydrogen Peroxide (H2O2) from West Antarctica", "datasets": [{"dataset_uid": "609392", "doi": "10.7265/N5TM7826", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS", "people": "McConnell, Joseph; Bales, Roger; Frey, Markus", "repository": "USAP-DC", "science_program": null, "title": "Twenty-Three Century-scale Ice Core Records of Hydrogen Peroxide (H2O2) from West Antarctica", "url": "https://www.usap-dc.org/view/dataset/609392"}, {"dataset_uid": "609394", "doi": "10.7265/N5PZ56RS", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; ITASE; WAIS", "people": "McConnell, Joseph; Bales, Roger; Frey, Markus", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric Mixing Ratios of Hydroperoxides above the West Antarctic Ice Sheet", "url": "https://www.usap-dc.org/view/dataset/609394"}], "date_created": "Mon, 01 Jun 2009 00:00:00 GMT", "description": "This award supports a project to improve understanding of atmospheric photochemistry over West Antarctica, as recorded in snow, firn and ice. Atmospheric and firn sampling will be undertaken as part of the U.S. International Trans-Antarctic Scientific Expedition (US ITASE) traverses. Measurements of hydrogen peroxide (H2O2) and formaldehyde (HCHO) will be made on these samples and a recently developed, physically based atmosphere-to-snow transfer model will be used to relate photochemical model estimates of these components to the concentrations of these parameters in the atmosphere and snow. The efficiency of atmosphere-to-snow transfer and the preservation of these components is strongly related to the rate and timing of snow accumulation. This information will be obtained by analyzing the concentration of seasonally dependent species such as hydrogen peroxide, nitric acid and stable isotopes of oxygen. Collection of samples along the US ITASE traverses will allow sampling at a wide variety of locations, reflecting both a number of different depositional environments and covering much of the West Antarctic region.", "east": -84.0, "geometry": "POINT(-104 -83)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUORESCENCE SPECTROSCOPY; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS SENSORS", "is_usap_dc": true, "keywords": "Ice Core; Ice Core Chemistry; FIELD INVESTIGATION; FIELD SURVEYS; Antarctica; West Antarctica; Antarctic; LABORATORY; Ice Core Gas Records; Not provided; Ice Core Data; Polar Firn Air; Hydrogen Peroxide; West Antarctic Ice Sheet; Shallow Firn Air; US ITASE; Antarctic Ice Sheet; Snow Chemistry", "locations": "Antarctica; West Antarctica; Antarctic; Antarctic Ice Sheet; West Antarctic Ice Sheet", "north": -76.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Bales, Roger; Frey, Markus; McConnell, Joseph", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Hydrogen Peroxide, Formaldehyde, and Sub-Annual Snow Accumulation in West Antarctica: Participation in West Antarctic Traverse", "uid": "p0000253", "west": -124.0}, {"awards": "0230288 Anastasio, Cort", "bounds_geometry": "POLYGON((123.30014 -75.093445,123.307404 -75.093445,123.314668 -75.093445,123.321932 -75.093445,123.329196 -75.093445,123.33646 -75.093445,123.343724 -75.093445,123.350988 -75.093445,123.358252 -75.093445,123.365516 -75.093445,123.37278 -75.093445,123.37278 -75.0952669,123.37278 -75.0970888,123.37278 -75.0989107,123.37278 -75.1007326,123.37278 -75.1025545,123.37278 -75.1043764,123.37278 -75.1061983,123.37278 -75.1080202,123.37278 -75.1098421,123.37278 -75.111664,123.365516 -75.111664,123.358252 -75.111664,123.350988 -75.111664,123.343724 -75.111664,123.33646 -75.111664,123.329196 -75.111664,123.321932 -75.111664,123.314668 -75.111664,123.307404 -75.111664,123.30014 -75.111664,123.30014 -75.1098421,123.30014 -75.1080202,123.30014 -75.1061983,123.30014 -75.1043764,123.30014 -75.1025545,123.30014 -75.1007326,123.30014 -75.0989107,123.30014 -75.0970888,123.30014 -75.0952669,123.30014 -75.093445))", "dataset_titles": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "datasets": [{"dataset_uid": "609519", "doi": "10.7265/N5MS3QP0", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Dome C Ice Core; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Physical Properties; Snow/ice; Snow/Ice", "people": "Robles, Tony; Anastasio, Cort", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609519"}], "date_created": "Wed, 07 Mar 2007 00:00:00 GMT", "description": "Photochemical reactions in snow can have important effects on the chemistry and composition of the snowpack as well as the overlying atmosphere. For example, recent measurements in the Antarctic and Arctic have revealed that sunlit snow releases a number of important pollutants to the atmosphere. Our ability to understand and model this chemistry is currently limited, in part because we lack fundamental photochemical information for a number of important chemical species in snow. This award supports research that will help fill this gap by characterizing the low-temperature photochemistry of three of these key species: nitrite (NO2-), nitrous acid (HNO2), and hydrogen peroxide (HOOH). We will measure quantum yields for these reactions on ice using a sensitive technique that we recently developed during a study of nitrate (NO3-) photochemistry. In addition to this basic research, we will also measure the rates of formation of hydroxyl radical (OH), nitrogen oxides (NOx), and HOOH in illuminated Antarctic snow samples. These measurements will be important inputs for future models, and will allow us to test whether known species (e.g., NO3-, NO2- and HNO2) are responsible for most of snowpack reactivity (e.g., OH formation). Overall, results from this award will significantly improve our ability to understand snowpack chemistry, and the resulting effects on the atmosphere, both in the Antarctic as well as in the many other regions with permanent or seasonal snow. These results will also strengthen efforts to use ice core records to monitor global change. In addition to these impacts, this award will help train students and a postdoctoral fellow, and results from this work will be integrated into two classes in order to expose students to some of the important issues facing polar regions.", "east": 123.37278, "geometry": "POINT(123.33646 -75.1025545)", "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PHOTOMETERS \u003e SPECTROPHOTOMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e HPLC; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Snow Chemistry; Antarctica; Snowpack Chemistry; Snow Samples; Hydrogen Peroxide; Snow Properties; Pollutants; Chemistry; Light Absorption; Antarctic; Chemical Species; Snow; East Antarctica; Organic Compounds; Photochemistry; LABORATORY", "locations": "Antarctica; East Antarctica; Antarctic", "north": -75.093445, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Anastasio, Cort; Robles, Tony", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Dome C Ice Core", "south": -75.111664, "title": "Laboratory Studies of Photochemistry in Antarctic Snow and Ice", "uid": "p0000175", "west": 123.30014}, {"awards": "0087151 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Sulfate-Based Volcanic Record from South Pole Ice Core", "datasets": [{"dataset_uid": "609215", "doi": "10.7265/N5CR5R88", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Solid Earth; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Sulfate-Based Volcanic Record from South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609215"}], "date_created": "Fri, 09 Apr 2004 00:00:00 GMT", "description": "This award supports a two year project to analyze shallow (~150 m) ice cores from South Pole in order to construct an annually resolved, sulfate-based volcanic record covering the last 1400 years. Two shallow ice cores will be recovered at the South Pole during the 00/01 field season and will be used for this work. Volcanic records from polar ice cores provide valuable information for studies of the connection between volcanism and climate. The new records are expected to be continuous and to cover at least the last 1400 years. The information from these records will verify the volcanic events found in the few existing Antarctic records and resolve discrepancies in the timing and magnitude of major explosive eruptions \u003cbr/\u003edetermined from those earlier records. In order to achieve the objectives of the proposed research, funds are provided to assist with the construction of an analytical laboratory for ice core and environmental \u003cbr/\u003echemistry research.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core; Snow Chemistry; West Antarctica; GROUND-BASED OBSERVATIONS; Antarctica; Ice Core Gas Records; Ion Chemistry; Ice Core Data", "locations": "West Antarctica; Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "A Sulfate-based Volcanic Record from South Pole Ice Cores", "uid": "p0000167", "west": null}, {"awards": "9526449 Mayewski, Paul", "bounds_geometry": null, "dataset_titles": "WAISCORES Snow Pit Chemistry, Antarctica", "datasets": [{"dataset_uid": "609420", "doi": "10.7265/N5SQ8XBR", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; Snow Pit; WAIS; WAISCORES", "people": "Kreutz, Karl; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": null, "title": "WAISCORES Snow Pit Chemistry, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609420"}], "date_created": "Thu, 11 Jul 2002 00:00:00 GMT", "description": "This award is for support for a program of glaciochemical analyses of shallow and deep ice cores from Siple Dome, West Antarctica. Measurements that have been proposed include chloride, nitrate, sulfate, calcium, magnesium, sodium, potassium, ammonium and methansulfonic acid. These measurements will provide information about past volcanic events, biomass source strength, sea ice fluctuations, atmospheric circulation, changes in ice-free areas and the environmental response to Earth orbit insolation changes and solar variability. The glaciochemical records from the Siple Dome core will be developed at a resolution sufficient to compare with the Summit, Greenland record, thus allowing a bipolar comparison of climate change event timing and magnitude. As part of this award, an international workshop will be held during the first year to formulate a science plan for the International Transantarctic Scientific Expedition (ITASE), a program of regional surveys documenting the spatial distribution of properties measured in ice cores .", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "Ion Chemistry; Antarctic; Snow Chemistry; Stable Isotopes; Snow Density; Siple Dome; GROUND-BASED OBSERVATIONS", "locations": "Antarctic; Siple Dome", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Kreutz, Karl; Mayewski, Paul A.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Siple Dome Deep Ice Core Glaciochemistry and Regional Survey - A Contribution to the WAIS Initiative", "uid": "p0000012", "west": null}]
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Project Title/Abstract/Map | NSF Award(s) | Date Created | PIs / Scientists | Dataset Links and Repositories | Abstract | Bounds Geometry | Geometry | Selected | Visible | |||||
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Collaborative Research: Microparticle/tephra analysis of the WAIS Divide ice core
|
0636740 0636767 |
2012-06-19 | Koffman, Bess; Kreutz, Karl; Breton, Daniel; Dunbar, Nelia; Hamilton, Gordon S. | This award supports a project to perform continuous microparticle concentration and size distribution measurements (using coulter counter and state-of-the-art laser detector methods), analysis of biologically relevant trace elements associated with microparticles (Fe, Zn, Co, Cd, Cu), and tephra measurements on the WAIS Divide ice core. This initial three-year project includes analysis of ice core spanning the instrumental (~1850-present) to mid- Holocene (~5000 years BP) period, with sample resolution ranging from subannual to decadal. The intellectual merit of the project is that it will help in establishing the relationships among climate, atmospheric aerosols from terrestrial and volcanic sources, ocean biogeochemistry, and greenhouse gases on several timescales which remain a fundamental problem in paleoclimatology. The atmospheric mineral dust plays an important but uncertain role in direct radiative forcing, and the microparticle datasets produced in this project will allow us to examine changes in South Pacific aerosol loading, atmospheric dynamics, and dust source area climate. The phasing of changes in aerosol properties within Antarctica, throughout the Southern Hemisphere, and globally is unclear, largely due to the limited number of annually dated records extending into the glacial period and the lack of a<br/>tephra framework to correlate records. The broader impacts of the proposed research are an interdisciplinary approach to climate science problems, and will contribute to several WAIS Divide science themes as well as the broader paleoclimate and oceanographic communities. Because the research topics have a large and direct societal relevance, the project will form a centerpiece of various outreach efforts at UMaine and NMT including institution websites, public speaking, local K-12 school interaction, media interviews and news releases, and popular literature. At least one PhD student and one MS student will be directly supported by this project, including fieldwork, core processing, laboratory analysis, and data interpretation/publication. We expect that one graduate student per year will apply for a core handler/assistant driller position through the WAIS Divide Science Coordination Office, and that undergraduate student involvement will result in several Capstone experience projects (a UMaine graduation requirement). Data and ideas generated from the project will be integrated into undergraduate and graduate course curricula at both institutions. | POINT(112.11666 -79.46666) | POINT(112.11666 -79.46666) | false | false | ||||||
Collaborative Research: Laboratory Studies of Isotopic Exchange in Snow and Firn
|
0338008 |
2010-01-01 | Neumann, Thomas A.; Wemple, Beverley C. |
|
This award supports a project to develop a quantitative understanding of the processes active in isotopic exchange between snow/firn and water vapor, which is of paramount importance to ice core interpretation. Carefully controlled laboratory studies will be conducted at a variety of temperatures to empirically measure the mass transfer coefficient (the rate at which water moves from the solid to the vapor phase) for sublimating snow and to determine the time scale for isotopic equilibration between water vapor and ice. In addition the isotopic fractionation coefficient for vapor derived from sublimating ice will be determined and the results will be used to update existing models of mass transfer and isotopic evolution in firn. It is well known that water vapor moves through firn due to diffusion, free convection and forced convection. Although vapor movement through variably-saturated firn due to these processes has been modeled, because of a lack of laboratory data the mass transfer coefficient had to be estimated. Field studies have documented the magnitudes of post-depositional changes, but field studies do not permit rigorous analysis of the relative importance of the many processes which are likely to act in natural snow packs. The results of these laboratory investigations will be broadly applicable to a number of studies and will allow for improvement of existing physically-based models of post-depositional isotopic change, isotopic diffusion in firn, and vapor motion in firn. A major component of this project will be the design and fabrication of the necessary, novel experimental apparatus, which will be facilitated by existing technical expertise, cold room facilities, and laboratory equipment at CRREL. This project is a necessary step toward a quantitative understanding of the isotopic effects of water vapor movement in firn. The proposed work has broader impacts in several different areas. The modeling results will be applicable to a wide range of studies of water in the polar environment, including studies of wind-blown or drifting snow. The proposed collaborative study will partially support a Dartmouth graduate student for three years. This project will also provide support for a young first-time NSF investigator at the University of Vermont. Undergraduate students from Dartmouth will be involved in the research through the Women in Science Project and undergraduate students at the University of Vermont will be supported through the Research Experiences for Undergraduates program. The principal investigators and graduate student will continue their tradition of k-12 school outreach by giving science lessons and talks in local schools each year. Research results will be disseminated through scientific conferences, journal publications, and institutional seminars. | None | None | false | false | |||||
Hydrogen Peroxide, Formaldehyde, and Sub-Annual Snow Accumulation in West Antarctica: Participation in West Antarctic Traverse
|
9814810 |
2009-06-01 | Bales, Roger; Frey, Markus; McConnell, Joseph |
|
This award supports a project to improve understanding of atmospheric photochemistry over West Antarctica, as recorded in snow, firn and ice. Atmospheric and firn sampling will be undertaken as part of the U.S. International Trans-Antarctic Scientific Expedition (US ITASE) traverses. Measurements of hydrogen peroxide (H2O2) and formaldehyde (HCHO) will be made on these samples and a recently developed, physically based atmosphere-to-snow transfer model will be used to relate photochemical model estimates of these components to the concentrations of these parameters in the atmosphere and snow. The efficiency of atmosphere-to-snow transfer and the preservation of these components is strongly related to the rate and timing of snow accumulation. This information will be obtained by analyzing the concentration of seasonally dependent species such as hydrogen peroxide, nitric acid and stable isotopes of oxygen. Collection of samples along the US ITASE traverses will allow sampling at a wide variety of locations, reflecting both a number of different depositional environments and covering much of the West Antarctic region. | POLYGON((-124 -76,-120 -76,-116 -76,-112 -76,-108 -76,-104 -76,-100 -76,-96 -76,-92 -76,-88 -76,-84 -76,-84 -77.4,-84 -78.8,-84 -80.2,-84 -81.6,-84 -83,-84 -84.4,-84 -85.8,-84 -87.2,-84 -88.6,-84 -90,-88 -90,-92 -90,-96 -90,-100 -90,-104 -90,-108 -90,-112 -90,-116 -90,-120 -90,-124 -90,-124 -88.6,-124 -87.2,-124 -85.8,-124 -84.4,-124 -83,-124 -81.6,-124 -80.2,-124 -78.8,-124 -77.4,-124 -76)) | POINT(-104 -83) | false | false | |||||
Laboratory Studies of Photochemistry in Antarctic Snow and Ice
|
0230288 |
2007-03-07 | Anastasio, Cort; Robles, Tony |
|
Photochemical reactions in snow can have important effects on the chemistry and composition of the snowpack as well as the overlying atmosphere. For example, recent measurements in the Antarctic and Arctic have revealed that sunlit snow releases a number of important pollutants to the atmosphere. Our ability to understand and model this chemistry is currently limited, in part because we lack fundamental photochemical information for a number of important chemical species in snow. This award supports research that will help fill this gap by characterizing the low-temperature photochemistry of three of these key species: nitrite (NO2-), nitrous acid (HNO2), and hydrogen peroxide (HOOH). We will measure quantum yields for these reactions on ice using a sensitive technique that we recently developed during a study of nitrate (NO3-) photochemistry. In addition to this basic research, we will also measure the rates of formation of hydroxyl radical (OH), nitrogen oxides (NOx), and HOOH in illuminated Antarctic snow samples. These measurements will be important inputs for future models, and will allow us to test whether known species (e.g., NO3-, NO2- and HNO2) are responsible for most of snowpack reactivity (e.g., OH formation). Overall, results from this award will significantly improve our ability to understand snowpack chemistry, and the resulting effects on the atmosphere, both in the Antarctic as well as in the many other regions with permanent or seasonal snow. These results will also strengthen efforts to use ice core records to monitor global change. In addition to these impacts, this award will help train students and a postdoctoral fellow, and results from this work will be integrated into two classes in order to expose students to some of the important issues facing polar regions. | POLYGON((123.30014 -75.093445,123.307404 -75.093445,123.314668 -75.093445,123.321932 -75.093445,123.329196 -75.093445,123.33646 -75.093445,123.343724 -75.093445,123.350988 -75.093445,123.358252 -75.093445,123.365516 -75.093445,123.37278 -75.093445,123.37278 -75.0952669,123.37278 -75.0970888,123.37278 -75.0989107,123.37278 -75.1007326,123.37278 -75.1025545,123.37278 -75.1043764,123.37278 -75.1061983,123.37278 -75.1080202,123.37278 -75.1098421,123.37278 -75.111664,123.365516 -75.111664,123.358252 -75.111664,123.350988 -75.111664,123.343724 -75.111664,123.33646 -75.111664,123.329196 -75.111664,123.321932 -75.111664,123.314668 -75.111664,123.307404 -75.111664,123.30014 -75.111664,123.30014 -75.1098421,123.30014 -75.1080202,123.30014 -75.1061983,123.30014 -75.1043764,123.30014 -75.1025545,123.30014 -75.1007326,123.30014 -75.0989107,123.30014 -75.0970888,123.30014 -75.0952669,123.30014 -75.093445)) | POINT(123.33646 -75.1025545) | false | false | |||||
A Sulfate-based Volcanic Record from South Pole Ice Cores
|
0087151 |
2004-04-09 | Cole-Dai, Jihong |
|
This award supports a two year project to analyze shallow (~150 m) ice cores from South Pole in order to construct an annually resolved, sulfate-based volcanic record covering the last 1400 years. Two shallow ice cores will be recovered at the South Pole during the 00/01 field season and will be used for this work. Volcanic records from polar ice cores provide valuable information for studies of the connection between volcanism and climate. The new records are expected to be continuous and to cover at least the last 1400 years. The information from these records will verify the volcanic events found in the few existing Antarctic records and resolve discrepancies in the timing and magnitude of major explosive eruptions <br/>determined from those earlier records. In order to achieve the objectives of the proposed research, funds are provided to assist with the construction of an analytical laboratory for ice core and environmental <br/>chemistry research. | None | None | false | false | |||||
Siple Dome Deep Ice Core Glaciochemistry and Regional Survey - A Contribution to the WAIS Initiative
|
9526449 |
2002-07-11 | Kreutz, Karl; Mayewski, Paul A. |
|
This award is for support for a program of glaciochemical analyses of shallow and deep ice cores from Siple Dome, West Antarctica. Measurements that have been proposed include chloride, nitrate, sulfate, calcium, magnesium, sodium, potassium, ammonium and methansulfonic acid. These measurements will provide information about past volcanic events, biomass source strength, sea ice fluctuations, atmospheric circulation, changes in ice-free areas and the environmental response to Earth orbit insolation changes and solar variability. The glaciochemical records from the Siple Dome core will be developed at a resolution sufficient to compare with the Summit, Greenland record, thus allowing a bipolar comparison of climate change event timing and magnitude. As part of this award, an international workshop will be held during the first year to formulate a science plan for the International Transantarctic Scientific Expedition (ITASE), a program of regional surveys documenting the spatial distribution of properties measured in ice cores . | None | None | false | false |