[{"awards": "2031121 Junge, Karen", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Tue, 30 Jul 2024 00:00:00 GMT", "description": "The ozone hole that develops over the Antarctic continent every spring is one of the features attributed to human activity, in particular production of the CFC (chlorofluorocarbons in refrigerants) released to the atmosphere. In spite of the CFC ban from the Montreal Protocol established in the year 1987, the recovery has been slower than predicted. Bromocarbons, known to produce the stratospheric ozone depletion, have recently been estimated to contribute to the pool of bromines in the lower atmosphere. What is the origin of the bromocarbons in Antarctic sea ice? Is this an additional source of chemicals creating the ozone hole? This project will test if bromocarbons in sea ice are produced and degraded by microalgae and bacteria found in sea ice, in snow and the interface between the two. The project will collect a suite of chemical and biological measurements of sea ice and snow to determine bromocarbon concentrations, microbial activity associated with them, and intra-cellular genes and proteins involved in bromocarbon metabolism. This project benefits NSF\u2019s goals of expanding fundamental knowledge of Antarctic systems, biota, and processes, and improving the understanding of interactions among the Antarctic systems, cryosphere and organisms. The work will be carried out at McMurdo Station in late austral spring, including sampling of snow and ice that will be concentrated in the laboratory, and 24-hour experiments to measure algal and bacterial activity. Genes controlling synthesis of enzymes involved in bromocarbon metabolism are of interest in biotechnology and bioremediation, including products that repair damaged skin from UltraViolet Radiation. The project will train undergraduate students on chemical and biological techniques. The Principal Investigators will be involved in the Pacific Science Center in Seattle with ~10,000 visitors per weekend where they will develop a project-specific exhibit. The microbial processes in snow and ice associated with bromocarbon synthesis and degradation have not been studied in Antarctica during winter and spring. This study will inform about microbial activity in relation to the release of bromocarbons compounds from the snow and ice surfaces, compounds known to degrade stratospheric ozone. The estimation of chemical bromocarbons will be combined with metagenomics and metaproteomics approaches for understanding the potential role of microbes in snow and sea ice. The environmental, chemical and biological data will be synthesized with multivariate analysis and significant differences between sites and experimental treatments with ANOVA. A collaborator from the University of Goteborg in Sweden will collaborate on bromocarbon analyses. The study will also address \u201csaline snow\u201d a new environment not previously studied for microbial life. In addition, this is the first study of meta-proteomics in snow and ice. The Principal Investigators expect their results will help inform ozone hole recovery in the 21st century.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "McMurdo Sound; COASTAL; BACTERIA/ARCHAEA; SEA ICE; SNOW/ICE", "locations": "McMurdo Sound", "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Junge, Karen; Nunn, Brook L", "platforms": null, "repositories": null, "science_programs": null, "south": null, "title": "Sea-ice Snow Microbial Communities\u2019 Impact on Antarctic Bromocarbon Budgets and Processes", "uid": "p0010472", "west": null}, {"awards": "1643431 Bitz, Cecilia", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Analysis code, processed observational data and climate model output required to produce figures for Roach et al (2022); Model output: CICE experiments with varying floe and wave physics described in Roach et al. (2019); Model output from experiments (FSD-M21) described in Cooper et al 2022.; Model output from experiments (IC4M1) described in Cooper et al 2022.; Model output from experiments (IC4M2) described in Cooper et al 2022.; Model output from experiments (IC4M3rad) described in Cooper et al 2022.; Model output from experiments (IC4M4) described in Cooper et al 2022.; Model output from experiments (IC4M5) described in Cooper et al 2022.; Model output from experiments (IC4M7) described in Cooper et al 2022.; Model output: NEMO-CICE with an emergent sea ice floe size distribution described in Roach et al (2018)", "datasets": [{"dataset_uid": "200302", "doi": "10.5281/zenodo.6213793", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Model output from experiments (IC4M2) described in Cooper et al 2022.", "url": "https://zenodo.org/record/6213793"}, {"dataset_uid": "200310", "doi": "10.5281/zenodo.1193930", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Model output: NEMO-CICE with an emergent sea ice floe size distribution described in Roach et al (2018)", "url": "https://zenodo.org/record/1193930"}, {"dataset_uid": "200309", "doi": "10.5281/zenodo.3463580", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Model output: CICE experiments with varying floe and wave physics described in Roach et al. (2019)", "url": "https://zenodo.org/record/3463580"}, {"dataset_uid": "200308", "doi": "10.5281/zenodo.5913959", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Analysis code, processed observational data and climate model output required to produce figures for Roach et al (2022)", "url": "https://zenodo.org/record/5913959"}, {"dataset_uid": "200307", "doi": "10.5281/zenodo.6212232", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Model output from experiments (FSD-M21) described in Cooper et al 2022.", "url": "https://zenodo.org/record/6212232"}, {"dataset_uid": "200306", "doi": "10.5281/zenodo.6212423", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Model output from experiments (IC4M7) described in Cooper et al 2022.", "url": "https://zenodo.org/record/6212423"}, {"dataset_uid": "200305", "doi": "10.5281/zenodo.6214998", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Model output from experiments (IC4M5) described in Cooper et al 2022.", "url": "https://zenodo.org/record/6214998"}, {"dataset_uid": "200301", "doi": "10.5281/zenodo.6213441", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Model output from experiments (IC4M1) described in Cooper et al 2022.", "url": "https://zenodo.org/record/6213441"}, {"dataset_uid": "200304", "doi": "10. 5281/zenodo.6214555", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Model output from experiments (IC4M4) described in Cooper et al 2022.", "url": "https://zenodo.org/record/6214555"}, {"dataset_uid": "200303", "doi": "10.5281/zenodo.6214364", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Model output from experiments (IC4M3rad) described in Cooper et al 2022.", "url": "https://zenodo.org/record/6214364"}], "date_created": "Tue, 19 Jul 2022 00:00:00 GMT", "description": "Sea-ice coverage surrounding Antarctica has expanded during the era of satellite observations, in contrast to rapidly shrinking Arctic sea ice. Most climate models predict Antarctic sea ice loss, rather than growth, indicating that there is much to learn about Antarctic sea ice in terms of its natural variability, processes and interactions affecting annual growth and retreat, and the impact of atmospheric factors such increasing greenhouse gases and stratospheric ozone depletion. This project is designed to improve model simulations of sea ice and examine the role of wind and wave forcing on changes in sea ice around Antarctica.\u003cbr/\u003e\u003cbr/\u003eThis project seeks to explain basic interactions of the coupled atmosphere, ocean, and ice dynamics in the Antarctic climate system, especially in the region near the sea ice edge. The summer evolution of sea ice cover and the near surface heat exchange of atmosphere and ocean depend on the geometric distribution of floes and the open water surrounding them. The distribution of floes has the greatest impact on the sea ice state in the marginal seas, where the distribution itself can vary rapidly. This project would develop and implement a model of sea ice floes in the Los Alamos sea ice model, known as CICE5. This sea ice component would be coupled to the third generation WaveWatch model within the Community Climate System Model Version 2. The coupled model would be used to study sea ice-wave interactions and the role of modeling sea ice floes in the Antarctic. The broader impacts of this project include outreach, support of female scientists, and improvement of the sea-ice codes in widely used climate models.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "ICE FLOES; Southern Ocean; SEA ICE", "locations": "Southern Ocean", "north": -60.0, "nsf_funding_programs": "Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Bitz, Cecilia", "platforms": null, "repo": "Zenodo", "repositories": "Zenodo", "science_programs": null, "south": -90.0, "title": "The Role of Wave-sea Ice Floe Interactions in Recent Antarctic Sea Ice Change", "uid": "p0010350", "west": -180.0}, {"awards": "1952199 Schneider, David", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Variable-resolution CESM2 over Antarctica (ANTSI): Monthly outputs used for evaluation", "datasets": [{"dataset_uid": "200417", "doi": "10.5281/zenodo.7335891", "keywords": null, "people": null, "repository": "Zenodo", "science_program": null, "title": "Variable-resolution CESM2 over Antarctica (ANTSI): Monthly outputs used for evaluation", "url": "https://zenodo.org/records/7335892"}], "date_created": "Wed, 21 Jul 2021 00:00:00 GMT", "description": "The Antarctic Ice Sheet (AIS) is sensitive to and an indicator of climate change. While dynamic ice loss is largely driven by ocean forcing, this ice loss might be mitigated by enhanced snowfall on the ice sheet. By developing and understanding of the processes governing snowfall variability and change on the AIS, this project will contribute to the objective of understanding the long-term role of the AIS as a contributor to sea level rise. This project is strongly embedded in the collaborative, open-source framework of the Community Earth System Model version 2 (CESM2) and will deliver new datasets of Antarctic precipitation for the community to use. The project will help to build a diverse geoscience workforce by recruiting and training a SOARs student to be directly involved in the research. A graduate student will also be recruited, and they will play a pivotal role in the proposed work. \r\n\r\nIn this project, we propose to leverage the Climate Model Intercomparison Project 6 (CMIP6) climate model ensemble as a whole, and CESM2 in particular, to disentangle the major sources of uncertainty and to elucidate the underlying mechanisms of Antarctic precipitation change, with a particular focus on the role of atmospheric circulation changes relative to that of atmospheric warming. Using the variable resolution capabilities of CESM2, we will provide the community with precipitation estimates at a very high horizontal resolution. The proposed analyses will also use a forthcoming 100-member large ensemble. The project seeks to answer the following questions: 1) How well does the CESM2 represent the present-day Antarctic surface climate, precipitation, and surface mass balance (SMB), including the mean and its variability? 2) What is the sensitivity of simulated Antarctic precipitation to model resolution in present-day and future climates? 3) What are the roles of thermodynamics (warming atmosphere and ocean) and dynamics (changes in atmospheric circulation) in observed and projected snowfall changes? How do these break down into forced and internal variability? In particular, is there a significant forced precipitation trend due to circulation changes driven by stratospheric ozone depletion and recovery and increases in greenhouse gas concentration? 4) What processes and boundary conditions drive the ensemble spread of AIS precipitation in single-model and multi-model ensembles? How does the spread driven by initial surface conditions (including sea ice cover, surface fluxes, inversion strength) compare with the irreducible uncertainty due to internal climate system variability?\r\n\r\n", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "USA/NSF; ICE SHEETS; Amd/Us; Antarctica; AMD; SNOW; MODELS; USAP-DC", "locations": "Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Integrated System Science; Antarctic Glaciology; Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Schneider, David; Datta, Rajashree Tri", "platforms": "OTHER \u003e MODELS \u003e MODELS", "repo": "Zenodo", "repositories": "Zenodo", "science_programs": null, "south": -90.0, "title": "Collaborative Research: Uncertainty and Mechanisms of Antarctica\u2019s Changing Snowfall and its Role in Sea Level Change", "uid": "p0010233", "west": -180.0}, {"awards": "1543229 Severinghaus, Jeffrey; 1543267 Brook, Edward J.", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Multi-site ice core Krypton stable isotope ratios; Noble Gas Data from recent ice in Antarctica for 86Kr problem", "datasets": [{"dataset_uid": "601195", "doi": "10.15784/601195", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Krypton; Noble Gas; Xenon", "people": "Shackleton, Sarah; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Noble Gas Data from recent ice in Antarctica for 86Kr problem", "url": "https://www.usap-dc.org/view/dataset/601195"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Mosley-Thompson, Ellen; Buizert, Christo; Severinghaus, Jeffrey P.; Brook, Edward J.; Baggenstos, Daniel; Bereiter, Bernhard; Etheridge, David; Bertler, Nancy; Pyne, Rebecca L.; Mulvaney, Robert; Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Shackleton, Sarah; Etheridge, David; Mosley-Thompson, Ellen; Bereiter, Bernhard; Mulvaney, Robert; Pyne, Rebecca L.; Baggenstos, Daniel; Severinghaus, Jeffrey P.; Bertler, Nancy; Buizert, Christo; Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Brook, Edward J.; Baggenstos, Daniel; Mulvaney, Robert; Bereiter, Bernhard; Etheridge, David; Shackleton, Sarah; Bertler, Nancy; Buizert, Christo; Mosley-Thompson, Ellen; Pyne, Rebecca L.; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}], "date_created": "Wed, 10 Jul 2019 00:00:00 GMT", "description": "Overview: The funded work investigated whether ice core 86Kr acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere (SH) westerly winds. Pressure variations drive macroscopic air movement in the firn column, which reduces the gravitational isotopic enrichment of slow-diffusing gases (such as Kr). The 86Kr deviation from gravitational equilibrium (denoted D86Kr) thus reflects the magnitude of pressure variations (among other things). Atmospheric reanalysis data suggest that pressure variability over Antarctica is linked to the Southern Annular Mode (SAM) index and the position of the SH westerly winds. Preliminary data from the WAIS Divide ice core show a large excursion in D86Kr during the last deglaciation (20-9 ka before present). In this project the investigators (1) performed high-precision 86Kr analysis on ice core and firn air samples to establish whether D86Kr is linked to pressure variability; (2) Refined the deglacial WAIS Divide record of Kr isotopes; (3) Investigated the role of pressure variability in firn air transport using firn air models with firn microtomography data and Lattice- Boltzmann modeling; and (4) Investigated how barometric pressure variability in Antarctica is linked to the SAM index and the position/strength of the SH westerlies in past and present climates using GCM and reanalysis data. A key finding was that D86Kr in recent ice samples (e.g. last 50 years) from a broad spatial array of sites in Antarctica and Greenland showed a significant correlation with directly measured barometric pressure variability at the ice core site. This strongly supports the hypothesis that 86Kr can be used as a paleo-proxy for storminess.\r\nIntellectual Merit: The SH westerlies are a key component of the global climate system; they are an important control on the global oceanic overturning circulation and possibly on atmospheric CO2 concentrations. Poleward movement of the SH westerlies during the last deglaciation has been hypothesized, yet evidence from proxy and modeling studies remains inconclusive. The funded work could provide valuable new constraints on deglacial movement of the SH westerlies. This record can be compared to high-resolution CO2 data from the same core, allowing us to test hypotheses that link CO2 to the SH westerlies. Climate proxies are at the heart of paleoclimate research. The funded work has apparently led to the discovery of a completely new proxy, opening up exciting new research possibilities and increasing the scientific value of existing ice cores. Once validated, the 86Kr proxy could be applied to other time periods as well, providing a long-term perspective on the movement of the SH westerlies. The funded work has furthermore provided valuable new insights into firn air transport. \r\n\r\nBroader impact: The Southern Ocean is presently an important sink of atmospheric CO2, thereby reducing the warming associated with anthropogenic CO2 emissions. Stratospheric ozone depletion and greenhouse warming have displaced the SH westerlies poleward, with potential consequences for the future magnitude of this oceanic carbon uptake. The funded work may provide a paleo-perspective on past movement of the SH westerlies and its link to atmospheric CO2, which could guide projections of future oceanic CO2 uptake, with strong societal benefits. The awarded funds supported and trained an early-career postdoctoral scholar at OSU, and fostered (international) collaboration. Data from the study will be available to the scientific community and the broad public through recognized data centers. During this project the PI and senior personnel have continued their commitment to public outreach through media interviews and speaking to schools and the public about their work. The PI provides services to the community by chairing the IPICS (International Partnership in Ice Core Sciences) working group and organizing annual PIRE (Partnerships in International Research and Education) workshops.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "USA/NSF; FIRN; ICE CORE RECORDS; USAP-DC; Greenland; Xenon; Noble Gas; Ice Core; Amd/Us; Antarctica; AMD; LABORATORY; Krypton; ATMOSPHERIC PRESSURE", "locations": "Greenland; Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Collaborative research: Kr-86 as a proxy for barometric pressure variability and movement of the SH westerlies during the last\r\ndeglaciation", "uid": "p0010037", "west": -180.0}, {"awards": "1043145 Obbard, Rachel", "bounds_geometry": "POLYGON((164.1005 -77.1188,164.36443 -77.1188,164.62836 -77.1188,164.89229 -77.1188,165.15622 -77.1188,165.42015 -77.1188,165.68408 -77.1188,165.94801 -77.1188,166.21194 -77.1188,166.47587 -77.1188,166.7398 -77.1188,166.7398 -77.19337,166.7398 -77.26794,166.7398 -77.34251,166.7398 -77.41708,166.7398 -77.49165,166.7398 -77.56622,166.7398 -77.64079,166.7398 -77.71536,166.7398 -77.78993,166.7398 -77.8645,166.47587 -77.8645,166.21194 -77.8645,165.94801 -77.8645,165.68408 -77.8645,165.42015 -77.8645,165.15622 -77.8645,164.89229 -77.8645,164.62836 -77.8645,164.36443 -77.8645,164.1005 -77.8645,164.1005 -77.78993,164.1005 -77.71536,164.1005 -77.64079,164.1005 -77.56622,164.1005 -77.49165,164.1005 -77.41708,164.1005 -77.34251,164.1005 -77.26794,164.1005 -77.19337,164.1005 -77.1188))", "dataset_titles": "Bromide in Snow in the Sea Ice Zone", "datasets": [{"dataset_uid": "600158", "doi": "10.15784/600158", "keywords": "Atmosphere; Chemistry:ice; Chemistry:Ice; Critical Zone; Crystals; Glaciology; Oceans; Photo/video; Photo/Video; Ross Sea; Sea Ice; Sea Surface; Snow; Southern Ocean", "people": "Obbard, Rachel", "repository": "USAP-DC", "science_program": null, "title": "Bromide in Snow in the Sea Ice Zone", "url": "https://www.usap-dc.org/view/dataset/600158"}], "date_created": "Tue, 01 Mar 2016 00:00:00 GMT", "description": "A range of chemical and microphysical pathways in polar latitudes, including spring time (tropospheric) ozone depletion, oxidative pathways for mercury, and cloud condensation nuclei (CCN) production leading to changes in the cloud cover and attendant surface energy budgets, have been invoked as being dependent upon the emission of halogen gases formed in sea-ice. \u003cbr/\u003e\u003cbr/\u003eThe prospects for climate warming induced reductions in sea ice extent causing alteration of these incompletely known surface-atmospheric feedbacks and interactions requires confirmation of mechanistic details in both laboratory studies and field campaigns. One such mechanistic question is how bromine (BrO and Br) enriched snow migrates or is formed through processes in sea-ice, prior to its subsequent mobilization as an aerosol fraction into the atmosphere by strong winds. Once aloft, it may react with ozone and other atmospheric species. Dartmouth researchers will collect snow from the surface of sea ice, from freely blowing snow and in sea-ice cores from Cape Byrd, Ross Sea. A range of spectroscopic, microanalytic and and microstructural approaches will be subsequently used to determine the Br distribution gradients through sea-ice, in order to shed light on how sea-ice first forms and then releases bromine species into the polar atmospheric boundary layer.", "east": 166.7398, "geometry": "POINT(165.42015 -77.49165)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -77.1188, "nsf_funding_programs": "Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Obbard, Rachel", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.8645, "title": "Bromide in Snow in the Sea Ice Zone", "uid": "p0000414", "west": 164.1005}, {"awards": "0230499 Kieber, David", "bounds_geometry": "POLYGON((-179.99998 -43.58056,-143.999984 -43.58056,-107.999988 -43.58056,-71.999992 -43.58056,-35.999996 -43.58056,0 -43.58056,35.999996 -43.58056,71.999992 -43.58056,107.999988 -43.58056,143.999984 -43.58056,179.99998 -43.58056,179.99998 -46.971468,179.99998 -50.362376,179.99998 -53.753284,179.99998 -57.144192,179.99998 -60.5351,179.99998 -63.926008,179.99998 -67.316916,179.99998 -70.707824,179.99998 -74.098732,179.99998 -77.48964,143.999984 -77.48964,107.999988 -77.48964,71.999992 -77.48964,35.999996 -77.48964,0 -77.48964,-35.999996 -77.48964,-71.999992 -77.48964,-107.999988 -77.48964,-143.999984 -77.48964,-179.99998 -77.48964,-179.99998 -74.098732,-179.99998 -70.707824,-179.99998 -67.316916,-179.99998 -63.926008,-179.99998 -60.5351,-179.99998 -57.144192,-179.99998 -53.753284,-179.99998 -50.362376,-179.99998 -46.971468,-179.99998 -43.58056))", "dataset_titles": "Expedition Data", "datasets": [{"dataset_uid": "001616", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP0409"}], "date_created": "Tue, 17 Jan 2012 00:00:00 GMT", "description": "Areas of the Southern Ocean have spectacular blooms of phytoplankton during the austral spring and early summer. One of the dominant phytoplankton species, the haptophyte Phaeocystis antarctica, is a prolific producer of the organic sulfur compound dimethylsulfoniopropionate (DMSP) and Phaeocystis blooms are associated with some of the world\u0027s highest concentrations of DMSP and its volatile degradation product, dimethylsulfide (DMS). Sulfur, in the form of DMS, is transferred from the oceans to the atmosphere and can affect the chemistry of precipitation and influence cloud properties and possibly climate. DMSP and DMS are also quantitatively significant components of the carbon, sulfur and energy flows in many marine food webs, although very little information is available on these processes in high latitude systems. \u003cbr/\u003e\u003cbr/\u003eThis project will study how solar radiation and iron cycling affect DMSP and DMS production by phytoplankton, and the subsequent utilization of these labile forms of organic matter by the microbial food web. Four interrelated hypotheses will be tested in field-based experiments and in situ observations: 1) solar radiation, including enhanced UV-B due to seasonal ozone depletion, plays an important role in determining the net ecosystem production of DMS in the Ross Sea; 2) development of shallow mixed layers promotes the accumulation of DMS in surface waters, because of enhanced exposure of plankton communities to high doses of solar radiation; 3) DMSP production and turnover represent a significant part of the carbon and sulfur flux through polar food webs; 4) bloom development and resulting nutrient depletion (e.g., iron) will result in high production rates of DMSP and high DMS concentrations and atmospheric fluxes. Results from this study will greatly improve understanding of the underlying mechanisms controlling DMSP and DMS concentrations in polar waters, thereby improving our ability to predict DMS fluxes to the atmosphere from this important climatic region. \u003cbr/\u003e\u003cbr/\u003eBoth Drs. Kieber and Kiene actively engage high school, undergraduate and graduate students in their research and are involved in formal programs that target underrepresented groups (NSF-REU and the American Chemical Society-SEED). This project will continue this type of educational outreach. The PIs also teach undergraduate and graduate courses and incorporation of research experiences into their classes will enrich student learning experiences.", "east": 179.99998, "geometry": "POINT(0 -89.999)", "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS", "is_usap_dc": false, "keywords": "R/V NBP", "locations": null, "north": -43.58056, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Kiene, Ronald", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": -77.48964, "title": "Collaborative Research: Impact of Solar Radiation and Nutrients on Biogeochemical Cycling of DMSP and DMS in the Ross Sea, Antarctica", "uid": "p0000582", "west": -179.99998}, {"awards": "0230497 Kiene, Ronald", "bounds_geometry": null, "dataset_titles": "Expedition Data; Expedition data of NBP0409", "datasets": [{"dataset_uid": "001616", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP0409"}, {"dataset_uid": "002640", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of NBP0409", "url": "https://www.rvdata.us/search/cruise/NBP0409"}], "date_created": "Tue, 17 Jan 2012 00:00:00 GMT", "description": "Areas of the Southern Ocean have spectacular blooms of phytoplankton during the austral spring and early summer. One of the dominant phytoplankton species, the haptophyte Phaeocystis antarctica, is a prolific producer of the organic sulfur compound dimethylsulfoniopropionate (DMSP) and Phaeocystis blooms are associated with some of the world\u0027s highest concentrations of DMSP and its volatile degradation product, dimethylsulfide (DMS). Sulfur, in the form of DMS, is transferred from the oceans to the atmosphere and can affect the chemistry of precipitation and influence cloud properties and possibly climate. DMSP and DMS are also quantitatively significant components of the carbon, sulfur and energy flows in many marine food webs, although very little information is available on these processes in high latitude systems. \u003cbr/\u003e\u003cbr/\u003eThis project will study how solar radiation and iron cycling affect DMSP and DMS production by phytoplankton, and the subsequent utilization of these labile forms of organic matter by the microbial food web. Four interrelated hypotheses will be tested in field-based experiments and in situ observations: 1) solar radiation, including enhanced UV-B due to seasonal ozone depletion, plays an important role in determining the net ecosystem production of DMS in the Ross Sea; 2) development of shallow mixed layers promotes the accumulation of DMS in surface waters, because of enhanced exposure of plankton communities to high doses of solar radiation; 3) DMSP production and turnover represent a significant part of the carbon and sulfur flux through polar food webs; 4) bloom development and resulting nutrient depletion (e.g., iron) will result in high production rates of DMSP and high DMS concentrations and atmospheric fluxes. Results from this study will greatly improve understanding of the underlying mechanisms controlling DMSP and DMS concentrations in polar waters, thereby improving our ability to predict DMS fluxes to the atmosphere from this important climatic region. \u003cbr/\u003e\u003cbr/\u003eBoth Drs. Kieber and Kiene actively engage high school, undergraduate and graduate students in their research and are involved in formal programs that target underrepresented groups (NSF-REU and the American Chemical Society-SEED). This project will continue this type of educational outreach. The PIs also teach undergraduate and graduate courses and incorporation of research experiences into their classes will enrich student learning experiences.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS", "is_usap_dc": false, "keywords": "R/V NBP", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Kiene, Ronald", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "Collaborative Research: Impact of Solar Radiation and Nutrients on Biogeochemical Cycling of DMSP and DMS in the Ross Sea, Antarctica", "uid": "p0000832", "west": null}, {"awards": "9615342 Neale, Patrick", "bounds_geometry": null, "dataset_titles": "Expedition data of LMG9809", "datasets": [{"dataset_uid": "002719", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of LMG9809", "url": "https://www.rvdata.us/search/cruise/LMG9809"}, {"dataset_uid": "002720", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of LMG9809", "url": "https://www.rvdata.us/search/cruise/LMG9809"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "Increases in ultraviolet-B radiation (UV-B, 280-320) associated with the Antarctic ozone hole have been shown to inhibit the photosynthesis of phytoplankton, but the overall effect on water column production is still a matter of debate and continued investigation. Investigations have also revealed that even at \"normal\" levels of Antarctic stratospheric ozone, UV-B and UV-A (320-400 nm) appear to have strong effects on water column production. The role of UV in the ecology of phytoplankton primary production has probably been underappreciated in the past and could be particularly important to the estimation of primary production in the presence of vertical mixing. This research focuses on quantifying UV effects on photosynthesis of Antarctic phytoplankton by defining biological weighting functions for UV-inhibition. In the past, techniques were developed to describe photosynthesis as a function of UV and visible irradiance using laboratory cultures. Further experimentation with natural assemblages from McMurdo Station in Antarctica showed that biological weighting functions are strongly related to light history. Most recently, measurements in the open waters of the Southern Ocean confirmed that there is substantial variability in the susceptibility of phytoplankton assemblages to UV. It was also discovered that inhibition of photosynthesis in Antarctic phytoplankton got progressively worse on the time scale of hours, with no evidence of recovery. Even under benign conditions, losses of photosynthetic capability persisted unchanged for several hours. This was in contrast with laboratory cultures and some natural assemblages which quickly attained a steady- state rate of photosynthesis during exposure to UV, reflecting a balance between damage and recovery processes. Slow reversal of UV-induced damage has profound consequences for water-column photosynthesis, especially during vertical mixing. Results to date have been used to model th e influence of UV, ozone depletion and vertical mixing on photosynthesis in Antarctic waters. Data indicate that normal levels of UV can have a significant impact on natural phytoplankton and that the effects can be exacerbated by ozone depletion as well as vertical mixing. Critical questions remain poorly resolved, however, and these are the focus of the present proposal. New theoretical and experimental approaches will be used to investigate UV responses in both the open waters of the Weddell-Scotia confluence and coastal waters near Palmer Station. In particular, measurements will be made of the kinetics of UV inhibition and recovery on time scales ranging from minutes to days. Variability in biological weighting functions between will be calculated for pelagic and coastal phytoplankton in the Southern Ocean. The results will provide absolute estimates of photosynthesis under in situ, as well as under altered, UV irradiance; broaden the range of assemblages for which biological weighting functions have been determined; and clarify how kinetics of inhibition and recovery should be represented in mixed layer models.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": false, "keywords": "R/V LMG", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Mopper, Kenneth; Neale, Patrick", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V LMG", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "New Approaches to Measuring and Understanding the Effects of Ultraviolet Radiation on Photosynthesis by Antarctic Phytoplankton", "uid": "p0000871", "west": null}, {"awards": "0125818 Gargett, Ann", "bounds_geometry": null, "dataset_titles": "Expedition Data; Expedition data of NBP0508", "datasets": [{"dataset_uid": "002610", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of NBP0508", "url": "https://www.rvdata.us/search/cruise/NBP0508"}, {"dataset_uid": "001584", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP0508"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "Ultraviolet radiation influences the dynamics of plankton processes in the near-surface waters of most aquatic ecosystems. In particular, the Southern Ocean is affected in the austral spring period when biologically damaging ultraviolet radiation is enhanced by ozone depletion. While progress has been made in estimating the quantitative impact of ultraviolet radiation on bacteria and phytoplankton in the Southern Ocean, some important issues remain to be resolved. Little is known about responses in systems dominated by the colonial haptophyte Phaeocystis antarctica, which dominates spring blooms in a polyna that develops in the southern Ross Sea. The Ross Sea is also of interest because of the occurrence of open water at a far southerly location in the spring, well within the ozone hole, and continuous daylight, with implications for the regulation of DNA repair. A number of studies suggest that vertical mixing can significant modify the impact of ultraviolet radiation in the Southern Ocean and elsewhere. However, there are limited measurements of turbulence intensity in the surface layer and measurements have not been integrated with parallel studies of ultraviolet radiation effects on phytoplankton and bacterioplankton. To address these issues, this collaborative study will focus on vertical mixing and the impact of ultraviolet radiation in the Ross Sea. The spectral and temporal responses of phytoplankton and bacterioplankton to ultraviolet radiation will be characterized in both laboratory and solar incubations. These will lead to the definition of biological weighting functions and response models capable of predicting the depth and time distribution of ultraviolet radiation impacts on photosynthesis, bacterial incorporation and DNA damage in the surface layer. Diel sampling will measure depth-dependent profiles of DNA damage, bacterial incorporation, photosynthesis and fluorescence parameters over a 24 h cycle. Sampling will include stations with contrasting wind-driven mixing and stratification as the polyna develops. The program of vertical mixing measurements is optimized for the typical springtime Ross Sea situation in which turbulence of intermediate intensity is insufficient to mix the upper layer thoroughly in the presence of stabilizing influences like solar heating and/or surface freshwater input from melting ice. Fine-scale vertical density profiles will be measured with a free-fall CTD unit and the profiles will be used to directly estimate large-eddy scales by determining Thorpe scales. Eddy scales and estimated turbulent diffusivities will be directly related to surface layer effects, and used to generate lagrangian depth-time trajectories in models of ultraviolet radiation responses in the surface mixed layer. The proposed research will be the first in-depth study of ultraviolet radiation effects in the Ross Sea and provide a valuable comparison with previous work in the Weddell-Scotia Confluence and Palmer Station regions. It will also enhance the understanding of vertical mixing processes, trophic interactions and biogeochemical cycling in the Ross Sea.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e CTD; IN SITU/LABORATORY INSTRUMENTS \u003e MAGNETIC/MOTION SENSORS \u003e GRAVIMETERS \u003e GRAVIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e PRESSURE/HEIGHT METERS \u003e PRESSURE SENSORS; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e TURBIDITY METERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e ADCP", "is_usap_dc": false, "keywords": "R/V NBP; B-15J", "locations": "B-15J", "north": null, "nsf_funding_programs": "Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Neale, Patrick", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "Collaborative Research: Interactive effects of UV and vertical mixing on phytoplankton and bacterioplankton in the Ross Sea", "uid": "p0000822", "west": null}, {"awards": "8917076 Smith, Raymond", "bounds_geometry": "POLYGON((-49.8233 -60.2167,-48.99564 -60.2167,-48.16798 -60.2167,-47.34032 -60.2167,-46.51266 -60.2167,-45.685 -60.2167,-44.85734 -60.2167,-44.02968 -60.2167,-43.20202 -60.2167,-42.37436 -60.2167,-41.5467 -60.2167,-41.5467 -60.35003,-41.5467 -60.48336,-41.5467 -60.61669,-41.5467 -60.75002,-41.5467 -60.88335,-41.5467 -61.01668,-41.5467 -61.15001,-41.5467 -61.28334,-41.5467 -61.41667,-41.5467 -61.55,-42.37436 -61.55,-43.20202 -61.55,-44.02968 -61.55,-44.85734 -61.55,-45.685 -61.55,-46.51266 -61.55,-47.34032 -61.55,-48.16798 -61.55,-48.99564 -61.55,-49.8233 -61.55,-49.8233 -61.41667,-49.8233 -61.28334,-49.8233 -61.15001,-49.8233 -61.01668,-49.8233 -60.88335,-49.8233 -60.75002,-49.8233 -60.61669,-49.8233 -60.48336,-49.8233 -60.35003,-49.8233 -60.2167))", "dataset_titles": "Expedition Data", "datasets": [{"dataset_uid": "002326", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP9206"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "The Antarctic is now experiencing large springtime losses of stratospheric ozone, resulting in an increase in ultraviolet B (UVB, 280-320nm) radiation. The magnitude of ultraviolet radiation reaching the surface now approaches that measured in tropical latitudes. Perhaps more importantly, UVB radiation has increased in the Antarctic while both UVA (320-400nm) and photosynthetically available radiation (PAR, 400-700nm) have remained unchanged. Recent improvements in atmospheric modeling and technology in oceanographic instrumentation will be used in a six week field study during the austral spring 1990. The prime objective will be to document the impact of UV radiation on the phytoplankton community during the ice-edge spring bloom. During this time, oceanographic processes create favorable conditions for increased UVB susceptibility. Biological and bio-optical information will be used to define and quantify linkages between ozone-dependent oscillations in UV to PAR ratios and phytoplankton productivity. Special emphasis will be placed on defining biological restraints imposed by enhanced UVB and altered UVB:UVA:PAR ratios on the balance of UVB photodamage to photorepair, photoprotective and photosynthetic mechanisms operating in the Southern Ocean. The overall aim is to test the hypothesis that phytoplankton in Antarctic waters are adversely influenced by ozone depletion.", "east": -41.5467, "geometry": "POINT(-45.685 -60.88335)", "instruments": null, "is_usap_dc": false, "keywords": "R/V NBP", "locations": null, "north": -60.2167, "nsf_funding_programs": null, "paleo_time": null, "persons": "Smith, Raymond", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": -61.55, "title": "Ozone Diminution, Ultraviolet Radiation and Photoplankton Biology in Antarctic Waters", "uid": "p0000650", "west": -49.8233}, {"awards": "9220373 Neale, Patrick", "bounds_geometry": null, "dataset_titles": "Expedition Data; Expedition data of NBP9306", "datasets": [{"dataset_uid": "002282", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP9306"}, {"dataset_uid": "002589", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of NBP9306", "url": "https://www.rvdata.us/search/cruise/NBP9306"}], "date_created": "Fri, 19 Jun 2009 00:00:00 GMT", "description": "Increases in middle ultraviolet radiation associated with the Antarctic ozone hole have been shown to inhibit the photosynthesis of phytoplankton, and results have been extrapolated to estimate the effect of ozone depletion on primary productivity in the marginal ice zone. This research will refine the assessment by specifying detailed wavelength-dependent biological weighting functions for the inhibition of photosynthesis by ultraviolet radiation, and by considering the mitigating effects of vertical mixing. Biological weighting functions of phytoplankton in the marginal ice zone will be measured under controlled conditions and applied in a new model of photosynthesis to predict primary productivity in situ, as well as under altered ultraviolet irradiance. These predictions will be compared with observations on samples from the water column and with measurements during incubations of several hours under different irradiance regimes. Results of these comparisons will be used to test the model and to quantify the potential artifact of long incubations. Assumptions about the kinetics of photoinhibition and recovery, critical to modeling the effects of vertical mixing, will be examined with time-course experiments. Results will be incorporated into a model of photosynthesis and photoinhibition in the water column that will be used to predict the influence of ozone depletion on marine primary production, particularly in the marginal zone.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS", "is_usap_dc": false, "keywords": "R/V NBP", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Neale, Patrick", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "Effects of Ultraviolet Radiation on the Photosynthesis of Phytoplankton in the Antarctic Marginal Ice Zone", "uid": "p0000808", "west": null}, {"awards": "0127022 Jeffrey, Wade", "bounds_geometry": "POLYGON((-177.639 -43.5676,-143.1091 -43.5676,-108.5792 -43.5676,-74.0493 -43.5676,-39.5194 -43.5676,-4.9895 -43.5676,29.5404 -43.5676,64.0703 -43.5676,98.6002 -43.5676,133.1301 -43.5676,167.66 -43.5676,167.66 -46.99877,167.66 -50.42994,167.66 -53.86111,167.66 -57.29228,167.66 -60.72345,167.66 -64.15462,167.66 -67.58579,167.66 -71.01696,167.66 -74.44813,167.66 -77.8793,133.1301 -77.8793,98.6002 -77.8793,64.0703 -77.8793,29.5404 -77.8793,-4.9895 -77.8793,-39.5194 -77.8793,-74.0493 -77.8793,-108.5792 -77.8793,-143.1091 -77.8793,-177.639 -77.8793,-177.639 -74.44813,-177.639 -71.01696,-177.639 -67.58579,-177.639 -64.15462,-177.639 -60.72345,-177.639 -57.29228,-177.639 -53.86111,-177.639 -50.42994,-177.639 -46.99877,-177.639 -43.5676))", "dataset_titles": "Expedition Data; Ross Sea microbial biomass and production", "datasets": [{"dataset_uid": "600029", "doi": "10.15784/600029", "keywords": "Biota; Chemistry:fluid; Chemistry:Fluid; CTD Data; Microbiology; Oceans; Phytoplankton; Ross Sea; Southern Ocean", "people": "Jeffrey, Wade H.", "repository": "USAP-DC", "science_program": null, "title": "Ross Sea microbial biomass and production", "url": "https://www.usap-dc.org/view/dataset/600029"}, {"dataset_uid": "001690", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP0304B"}, {"dataset_uid": "001584", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP0508"}], "date_created": "Thu, 12 Jun 2008 00:00:00 GMT", "description": "Ultraviolet radiation influences the dynamics of plankton processes in the near-surface waters of most aquatic ecosystems. In particular, the Southern Ocean is affected in the austral spring period when biologically damaging ultraviolet radiation is enhanced by ozone depletion. While progress has been made in estimating the quantitative impact of ultraviolet radiation on bacteria and phytoplankton in the Southern Ocean, some important issues remain to be resolved. Little is known about responses in systems dominated by the colonial haptophyte Phaeocystis antarctica, which dominates spring blooms in a polyna that develops in the southern Ross Sea. The Ross Sea is also of interest because of the occurrence of open water at a far southerly location in the spring, well within the ozone hole, and continuous daylight, with implications for the regulation of DNA repair. A number of studies suggest that vertical mixing can significant modify the impact of ultraviolet radiation in the Southern Ocean and elsewhere. However, there are limited measurements of turbulence intensity in the surface layer and measurements have not been integrated with parallel studies of ultraviolet radiation effects on phytoplankton and bacterioplankton. To address these issues, this collaborative study will focus on vertical mixing and the impact of ultraviolet radiation in the Ross Sea. The spectral and temporal responses of phytoplankton and bacterioplankton to ultraviolet radiation will be characterized in both laboratory and solar incubations. These will lead to the definition of biological weighting functions and response models capable of predicting the depth and time distribution of ultraviolet radiation impacts on photosynthesis, bacterial incorporation and DNA damage in the surface layer. Diel sampling will measure depth-dependent profiles of DNA damage, bacterial incorporation, photosynthesis and fluorescence parameters over a 24 h cycle. Sampling will include stations with contrasting wind-driven mixing and stratification as the polyna develops. The program of vertical mixing measurements is optimized for the typical springtime Ross Sea situation in which turbulence of intermediate intensity is insufficient to mix the upper layer thoroughly in the presence of stabilizing influences like solar heating and/or surface freshwater input from melting ice. Fine-scale vertical density profiles will be measured with a free-fall CTD unit and the profiles will be used to directly estimate large-eddy scales by determining Thorpe scales. Eddy scales and estimated turbulent diffusivities will be directly related to surface layer effects, and used to generate lagrangian depth-time trajectories in models of ultraviolet radiation responses in the surface mixed layer. The proposed research will be the first in-depth study of ultraviolet radiation effects in the Ross Sea and provide a valuable comparison with previous work in the Weddell-Scotia Confluence and Palmer Station regions. It will also enhance the understanding of vertical mixing processes, trophic interactions and biogeochemical cycling in the Ross Sea.", "east": 167.66, "geometry": "POINT(-4.9895 -60.72345)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e CTD; IN SITU/LABORATORY INSTRUMENTS \u003e MAGNETIC/MOTION SENSORS \u003e GRAVIMETERS \u003e GRAVIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e PRESSURE/HEIGHT METERS \u003e PRESSURE SENSORS; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e TURBIDITY METERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e ADCP; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e WATER BOTTLES; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e MSBS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUORESCENCE MICROSCOPY; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e MICROSCOPES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUOROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e GO-FLO BOTTLES", "is_usap_dc": true, "keywords": "R/V NBP; B-15J", "locations": "B-15J", "north": -43.5676, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Jeffrey, Wade H.; Neale, Patrick", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "USAP-DC", "repositories": "R2R; USAP-DC", "science_programs": null, "south": -77.8793, "title": "Collaborative Proposal: Interactive Effects of UV Radiation and Vertical Mixing on Phytoplankton and Bacterial Productivity of Ross See Phaeocystis Blooms", "uid": "p0000578", "west": -177.639}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}, {"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}, {"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Williams, Margaret; Saltzman, Eric; Aydin, Murat; Tatum, Cheryl", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; Carbonyl Sulfide; Siple Coast; Chloride; Trapped Gases; Snow; Ice Core Chemistry; Chromatography; Siple; GROUND STATIONS; Atmospheric Gases; Ozone Depletion; AWS Siple; Ice Sheet; Ice Core Data; Antarctica; Glaciology; West Antarctica; Atmospheric Chemistry; Ice Core; Stratigraphy; LABORATORY; Methane; Mass Spectrometer; GROUND-BASED OBSERVATIONS; WAISCORES; Msa; Mass Spectrometry; Not provided; Siple Dome; Gas Measurement", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica; Siple", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}]
X
X
Help on the Results MapX
This window can be dragged by its header, and can be resized from the bottom right corner.
The Results Map and the Results Table
The Results Map displays the centroids of the geographic bounds of all the results returned by the search.
Results that are displayed in the current map view will be highlighted in blue and brought to the top of the Results Table.
As the map is panned or zoomed, the highlighted rows in the table will update.
If you click on a centroid on the map, it will turn yellow and display a popup with details for that project/dataset - including a link to the landing page.
The bounds for the project(s)/dataset(s) selected will be displayed in red.
The selected result(s) will be highlighted in red and brought to the top of the table.
The default table sorting order is: Selected, Visible, Date (descending), but this can be changed by clicking on column headers in the table.
Selecting Show on Map for an individual row will both display the geographic bounds for that result on a mini map, and also display the bounds
and highlight the centroid on the Results Map.
Clicking the 'Show boundaries' checkbox at the top of the Results Map will display all the bounds for the filtered results.
Defining a search area on the Results Map
If you click on the Rectangle or Polygon icons in the top right of the Results Map, you can define a search area which will be added to any other
search criteria already selected.
After you have drawn a polygon, you can edit it using the Edit Geometry dropdown in the search form at the top.
Clicking Clear in the map will clear any drawn polygon.
Clicking Search in the map, or Search on the form will have the same effect.
The returned results will be any projects/datasets with bounds that intersect the polygon.
Use the Exclude project/datasets checkbox to exclude any projects/datasets that cover the whole Antarctic region.
Viewing map layers on the Results Map
Clicking the Layers button - the blue square in the top left of the Results Map - will display a list of map layers you can add or remove
from the currently displayed map view.
Older retrieved projects from AMD. Warning: many have incomplete information.
To sort the table of search results, click the header of the column you wish to search by. To sort by multiple columns, hold down the shift key whilst selecting the sort columns in order.
The ozone hole that develops over the Antarctic continent every spring is one of the features attributed to human activity, in particular production of the CFC (chlorofluorocarbons in refrigerants) released to the atmosphere. In spite of the CFC ban from the Montreal Protocol established in the year 1987, the recovery has been slower than predicted. Bromocarbons, known to produce the stratospheric ozone depletion, have recently been estimated to contribute to the pool of bromines in the lower atmosphere. What is the origin of the bromocarbons in Antarctic sea ice? Is this an additional source of chemicals creating the ozone hole? This project will test if bromocarbons in sea ice are produced and degraded by microalgae and bacteria found in sea ice, in snow and the interface between the two. The project will collect a suite of chemical and biological measurements of sea ice and snow to determine bromocarbon concentrations, microbial activity associated with them, and intra-cellular genes and proteins involved in bromocarbon metabolism. This project benefits NSF’s goals of expanding fundamental knowledge of Antarctic systems, biota, and processes, and improving the understanding of interactions among the Antarctic systems, cryosphere and organisms. The work will be carried out at McMurdo Station in late austral spring, including sampling of snow and ice that will be concentrated in the laboratory, and 24-hour experiments to measure algal and bacterial activity. Genes controlling synthesis of enzymes involved in bromocarbon metabolism are of interest in biotechnology and bioremediation, including products that repair damaged skin from UltraViolet Radiation. The project will train undergraduate students on chemical and biological techniques. The Principal Investigators will be involved in the Pacific Science Center in Seattle with ~10,000 visitors per weekend where they will develop a project-specific exhibit. The microbial processes in snow and ice associated with bromocarbon synthesis and degradation have not been studied in Antarctica during winter and spring. This study will inform about microbial activity in relation to the release of bromocarbons compounds from the snow and ice surfaces, compounds known to degrade stratospheric ozone. The estimation of chemical bromocarbons will be combined with metagenomics and metaproteomics approaches for understanding the potential role of microbes in snow and sea ice. The environmental, chemical and biological data will be synthesized with multivariate analysis and significant differences between sites and experimental treatments with ANOVA. A collaborator from the University of Goteborg in Sweden will collaborate on bromocarbon analyses. The study will also address “saline snow” a new environment not previously studied for microbial life. In addition, this is the first study of meta-proteomics in snow and ice. The Principal Investigators expect their results will help inform ozone hole recovery in the 21st century.
Sea-ice coverage surrounding Antarctica has expanded during the era of satellite observations, in contrast to rapidly shrinking Arctic sea ice. Most climate models predict Antarctic sea ice loss, rather than growth, indicating that there is much to learn about Antarctic sea ice in terms of its natural variability, processes and interactions affecting annual growth and retreat, and the impact of atmospheric factors such increasing greenhouse gases and stratospheric ozone depletion. This project is designed to improve model simulations of sea ice and examine the role of wind and wave forcing on changes in sea ice around Antarctica.<br/><br/>This project seeks to explain basic interactions of the coupled atmosphere, ocean, and ice dynamics in the Antarctic climate system, especially in the region near the sea ice edge. The summer evolution of sea ice cover and the near surface heat exchange of atmosphere and ocean depend on the geometric distribution of floes and the open water surrounding them. The distribution of floes has the greatest impact on the sea ice state in the marginal seas, where the distribution itself can vary rapidly. This project would develop and implement a model of sea ice floes in the Los Alamos sea ice model, known as CICE5. This sea ice component would be coupled to the third generation WaveWatch model within the Community Climate System Model Version 2. The coupled model would be used to study sea ice-wave interactions and the role of modeling sea ice floes in the Antarctic. The broader impacts of this project include outreach, support of female scientists, and improvement of the sea-ice codes in widely used climate models.
The Antarctic Ice Sheet (AIS) is sensitive to and an indicator of climate change. While dynamic ice loss is largely driven by ocean forcing, this ice loss might be mitigated by enhanced snowfall on the ice sheet. By developing and understanding of the processes governing snowfall variability and change on the AIS, this project will contribute to the objective of understanding the long-term role of the AIS as a contributor to sea level rise. This project is strongly embedded in the collaborative, open-source framework of the Community Earth System Model version 2 (CESM2) and will deliver new datasets of Antarctic precipitation for the community to use. The project will help to build a diverse geoscience workforce by recruiting and training a SOARs student to be directly involved in the research. A graduate student will also be recruited, and they will play a pivotal role in the proposed work.
In this project, we propose to leverage the Climate Model Intercomparison Project 6 (CMIP6) climate model ensemble as a whole, and CESM2 in particular, to disentangle the major sources of uncertainty and to elucidate the underlying mechanisms of Antarctic precipitation change, with a particular focus on the role of atmospheric circulation changes relative to that of atmospheric warming. Using the variable resolution capabilities of CESM2, we will provide the community with precipitation estimates at a very high horizontal resolution. The proposed analyses will also use a forthcoming 100-member large ensemble. The project seeks to answer the following questions: 1) How well does the CESM2 represent the present-day Antarctic surface climate, precipitation, and surface mass balance (SMB), including the mean and its variability? 2) What is the sensitivity of simulated Antarctic precipitation to model resolution in present-day and future climates? 3) What are the roles of thermodynamics (warming atmosphere and ocean) and dynamics (changes in atmospheric circulation) in observed and projected snowfall changes? How do these break down into forced and internal variability? In particular, is there a significant forced precipitation trend due to circulation changes driven by stratospheric ozone depletion and recovery and increases in greenhouse gas concentration? 4) What processes and boundary conditions drive the ensemble spread of AIS precipitation in single-model and multi-model ensembles? How does the spread driven by initial surface conditions (including sea ice cover, surface fluxes, inversion strength) compare with the irreducible uncertainty due to internal climate system variability?
Overview: The funded work investigated whether ice core 86Kr acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere (SH) westerly winds. Pressure variations drive macroscopic air movement in the firn column, which reduces the gravitational isotopic enrichment of slow-diffusing gases (such as Kr). The 86Kr deviation from gravitational equilibrium (denoted D86Kr) thus reflects the magnitude of pressure variations (among other things). Atmospheric reanalysis data suggest that pressure variability over Antarctica is linked to the Southern Annular Mode (SAM) index and the position of the SH westerly winds. Preliminary data from the WAIS Divide ice core show a large excursion in D86Kr during the last deglaciation (20-9 ka before present). In this project the investigators (1) performed high-precision 86Kr analysis on ice core and firn air samples to establish whether D86Kr is linked to pressure variability; (2) Refined the deglacial WAIS Divide record of Kr isotopes; (3) Investigated the role of pressure variability in firn air transport using firn air models with firn microtomography data and Lattice- Boltzmann modeling; and (4) Investigated how barometric pressure variability in Antarctica is linked to the SAM index and the position/strength of the SH westerlies in past and present climates using GCM and reanalysis data. A key finding was that D86Kr in recent ice samples (e.g. last 50 years) from a broad spatial array of sites in Antarctica and Greenland showed a significant correlation with directly measured barometric pressure variability at the ice core site. This strongly supports the hypothesis that 86Kr can be used as a paleo-proxy for storminess.
Intellectual Merit: The SH westerlies are a key component of the global climate system; they are an important control on the global oceanic overturning circulation and possibly on atmospheric CO2 concentrations. Poleward movement of the SH westerlies during the last deglaciation has been hypothesized, yet evidence from proxy and modeling studies remains inconclusive. The funded work could provide valuable new constraints on deglacial movement of the SH westerlies. This record can be compared to high-resolution CO2 data from the same core, allowing us to test hypotheses that link CO2 to the SH westerlies. Climate proxies are at the heart of paleoclimate research. The funded work has apparently led to the discovery of a completely new proxy, opening up exciting new research possibilities and increasing the scientific value of existing ice cores. Once validated, the 86Kr proxy could be applied to other time periods as well, providing a long-term perspective on the movement of the SH westerlies. The funded work has furthermore provided valuable new insights into firn air transport.
Broader impact: The Southern Ocean is presently an important sink of atmospheric CO2, thereby reducing the warming associated with anthropogenic CO2 emissions. Stratospheric ozone depletion and greenhouse warming have displaced the SH westerlies poleward, with potential consequences for the future magnitude of this oceanic carbon uptake. The funded work may provide a paleo-perspective on past movement of the SH westerlies and its link to atmospheric CO2, which could guide projections of future oceanic CO2 uptake, with strong societal benefits. The awarded funds supported and trained an early-career postdoctoral scholar at OSU, and fostered (international) collaboration. Data from the study will be available to the scientific community and the broad public through recognized data centers. During this project the PI and senior personnel have continued their commitment to public outreach through media interviews and speaking to schools and the public about their work. The PI provides services to the community by chairing the IPICS (International Partnership in Ice Core Sciences) working group and organizing annual PIRE (Partnerships in International Research and Education) workshops.
A range of chemical and microphysical pathways in polar latitudes, including spring time (tropospheric) ozone depletion, oxidative pathways for mercury, and cloud condensation nuclei (CCN) production leading to changes in the cloud cover and attendant surface energy budgets, have been invoked as being dependent upon the emission of halogen gases formed in sea-ice. <br/><br/>The prospects for climate warming induced reductions in sea ice extent causing alteration of these incompletely known surface-atmospheric feedbacks and interactions requires confirmation of mechanistic details in both laboratory studies and field campaigns. One such mechanistic question is how bromine (BrO and Br) enriched snow migrates or is formed through processes in sea-ice, prior to its subsequent mobilization as an aerosol fraction into the atmosphere by strong winds. Once aloft, it may react with ozone and other atmospheric species. Dartmouth researchers will collect snow from the surface of sea ice, from freely blowing snow and in sea-ice cores from Cape Byrd, Ross Sea. A range of spectroscopic, microanalytic and and microstructural approaches will be subsequently used to determine the Br distribution gradients through sea-ice, in order to shed light on how sea-ice first forms and then releases bromine species into the polar atmospheric boundary layer.
Areas of the Southern Ocean have spectacular blooms of phytoplankton during the austral spring and early summer. One of the dominant phytoplankton species, the haptophyte Phaeocystis antarctica, is a prolific producer of the organic sulfur compound dimethylsulfoniopropionate (DMSP) and Phaeocystis blooms are associated with some of the world's highest concentrations of DMSP and its volatile degradation product, dimethylsulfide (DMS). Sulfur, in the form of DMS, is transferred from the oceans to the atmosphere and can affect the chemistry of precipitation and influence cloud properties and possibly climate. DMSP and DMS are also quantitatively significant components of the carbon, sulfur and energy flows in many marine food webs, although very little information is available on these processes in high latitude systems. <br/><br/>This project will study how solar radiation and iron cycling affect DMSP and DMS production by phytoplankton, and the subsequent utilization of these labile forms of organic matter by the microbial food web. Four interrelated hypotheses will be tested in field-based experiments and in situ observations: 1) solar radiation, including enhanced UV-B due to seasonal ozone depletion, plays an important role in determining the net ecosystem production of DMS in the Ross Sea; 2) development of shallow mixed layers promotes the accumulation of DMS in surface waters, because of enhanced exposure of plankton communities to high doses of solar radiation; 3) DMSP production and turnover represent a significant part of the carbon and sulfur flux through polar food webs; 4) bloom development and resulting nutrient depletion (e.g., iron) will result in high production rates of DMSP and high DMS concentrations and atmospheric fluxes. Results from this study will greatly improve understanding of the underlying mechanisms controlling DMSP and DMS concentrations in polar waters, thereby improving our ability to predict DMS fluxes to the atmosphere from this important climatic region. <br/><br/>Both Drs. Kieber and Kiene actively engage high school, undergraduate and graduate students in their research and are involved in formal programs that target underrepresented groups (NSF-REU and the American Chemical Society-SEED). This project will continue this type of educational outreach. The PIs also teach undergraduate and graduate courses and incorporation of research experiences into their classes will enrich student learning experiences.
Areas of the Southern Ocean have spectacular blooms of phytoplankton during the austral spring and early summer. One of the dominant phytoplankton species, the haptophyte Phaeocystis antarctica, is a prolific producer of the organic sulfur compound dimethylsulfoniopropionate (DMSP) and Phaeocystis blooms are associated with some of the world's highest concentrations of DMSP and its volatile degradation product, dimethylsulfide (DMS). Sulfur, in the form of DMS, is transferred from the oceans to the atmosphere and can affect the chemistry of precipitation and influence cloud properties and possibly climate. DMSP and DMS are also quantitatively significant components of the carbon, sulfur and energy flows in many marine food webs, although very little information is available on these processes in high latitude systems. <br/><br/>This project will study how solar radiation and iron cycling affect DMSP and DMS production by phytoplankton, and the subsequent utilization of these labile forms of organic matter by the microbial food web. Four interrelated hypotheses will be tested in field-based experiments and in situ observations: 1) solar radiation, including enhanced UV-B due to seasonal ozone depletion, plays an important role in determining the net ecosystem production of DMS in the Ross Sea; 2) development of shallow mixed layers promotes the accumulation of DMS in surface waters, because of enhanced exposure of plankton communities to high doses of solar radiation; 3) DMSP production and turnover represent a significant part of the carbon and sulfur flux through polar food webs; 4) bloom development and resulting nutrient depletion (e.g., iron) will result in high production rates of DMSP and high DMS concentrations and atmospheric fluxes. Results from this study will greatly improve understanding of the underlying mechanisms controlling DMSP and DMS concentrations in polar waters, thereby improving our ability to predict DMS fluxes to the atmosphere from this important climatic region. <br/><br/>Both Drs. Kieber and Kiene actively engage high school, undergraduate and graduate students in their research and are involved in formal programs that target underrepresented groups (NSF-REU and the American Chemical Society-SEED). This project will continue this type of educational outreach. The PIs also teach undergraduate and graduate courses and incorporation of research experiences into their classes will enrich student learning experiences.
Increases in ultraviolet-B radiation (UV-B, 280-320) associated with the Antarctic ozone hole have been shown to inhibit the photosynthesis of phytoplankton, but the overall effect on water column production is still a matter of debate and continued investigation. Investigations have also revealed that even at "normal" levels of Antarctic stratospheric ozone, UV-B and UV-A (320-400 nm) appear to have strong effects on water column production. The role of UV in the ecology of phytoplankton primary production has probably been underappreciated in the past and could be particularly important to the estimation of primary production in the presence of vertical mixing. This research focuses on quantifying UV effects on photosynthesis of Antarctic phytoplankton by defining biological weighting functions for UV-inhibition. In the past, techniques were developed to describe photosynthesis as a function of UV and visible irradiance using laboratory cultures. Further experimentation with natural assemblages from McMurdo Station in Antarctica showed that biological weighting functions are strongly related to light history. Most recently, measurements in the open waters of the Southern Ocean confirmed that there is substantial variability in the susceptibility of phytoplankton assemblages to UV. It was also discovered that inhibition of photosynthesis in Antarctic phytoplankton got progressively worse on the time scale of hours, with no evidence of recovery. Even under benign conditions, losses of photosynthetic capability persisted unchanged for several hours. This was in contrast with laboratory cultures and some natural assemblages which quickly attained a steady- state rate of photosynthesis during exposure to UV, reflecting a balance between damage and recovery processes. Slow reversal of UV-induced damage has profound consequences for water-column photosynthesis, especially during vertical mixing. Results to date have been used to model th e influence of UV, ozone depletion and vertical mixing on photosynthesis in Antarctic waters. Data indicate that normal levels of UV can have a significant impact on natural phytoplankton and that the effects can be exacerbated by ozone depletion as well as vertical mixing. Critical questions remain poorly resolved, however, and these are the focus of the present proposal. New theoretical and experimental approaches will be used to investigate UV responses in both the open waters of the Weddell-Scotia confluence and coastal waters near Palmer Station. In particular, measurements will be made of the kinetics of UV inhibition and recovery on time scales ranging from minutes to days. Variability in biological weighting functions between will be calculated for pelagic and coastal phytoplankton in the Southern Ocean. The results will provide absolute estimates of photosynthesis under in situ, as well as under altered, UV irradiance; broaden the range of assemblages for which biological weighting functions have been determined; and clarify how kinetics of inhibition and recovery should be represented in mixed layer models.
Ultraviolet radiation influences the dynamics of plankton processes in the near-surface waters of most aquatic ecosystems. In particular, the Southern Ocean is affected in the austral spring period when biologically damaging ultraviolet radiation is enhanced by ozone depletion. While progress has been made in estimating the quantitative impact of ultraviolet radiation on bacteria and phytoplankton in the Southern Ocean, some important issues remain to be resolved. Little is known about responses in systems dominated by the colonial haptophyte Phaeocystis antarctica, which dominates spring blooms in a polyna that develops in the southern Ross Sea. The Ross Sea is also of interest because of the occurrence of open water at a far southerly location in the spring, well within the ozone hole, and continuous daylight, with implications for the regulation of DNA repair. A number of studies suggest that vertical mixing can significant modify the impact of ultraviolet radiation in the Southern Ocean and elsewhere. However, there are limited measurements of turbulence intensity in the surface layer and measurements have not been integrated with parallel studies of ultraviolet radiation effects on phytoplankton and bacterioplankton. To address these issues, this collaborative study will focus on vertical mixing and the impact of ultraviolet radiation in the Ross Sea. The spectral and temporal responses of phytoplankton and bacterioplankton to ultraviolet radiation will be characterized in both laboratory and solar incubations. These will lead to the definition of biological weighting functions and response models capable of predicting the depth and time distribution of ultraviolet radiation impacts on photosynthesis, bacterial incorporation and DNA damage in the surface layer. Diel sampling will measure depth-dependent profiles of DNA damage, bacterial incorporation, photosynthesis and fluorescence parameters over a 24 h cycle. Sampling will include stations with contrasting wind-driven mixing and stratification as the polyna develops. The program of vertical mixing measurements is optimized for the typical springtime Ross Sea situation in which turbulence of intermediate intensity is insufficient to mix the upper layer thoroughly in the presence of stabilizing influences like solar heating and/or surface freshwater input from melting ice. Fine-scale vertical density profiles will be measured with a free-fall CTD unit and the profiles will be used to directly estimate large-eddy scales by determining Thorpe scales. Eddy scales and estimated turbulent diffusivities will be directly related to surface layer effects, and used to generate lagrangian depth-time trajectories in models of ultraviolet radiation responses in the surface mixed layer. The proposed research will be the first in-depth study of ultraviolet radiation effects in the Ross Sea and provide a valuable comparison with previous work in the Weddell-Scotia Confluence and Palmer Station regions. It will also enhance the understanding of vertical mixing processes, trophic interactions and biogeochemical cycling in the Ross Sea.
The Antarctic is now experiencing large springtime losses of stratospheric ozone, resulting in an increase in ultraviolet B (UVB, 280-320nm) radiation. The magnitude of ultraviolet radiation reaching the surface now approaches that measured in tropical latitudes. Perhaps more importantly, UVB radiation has increased in the Antarctic while both UVA (320-400nm) and photosynthetically available radiation (PAR, 400-700nm) have remained unchanged. Recent improvements in atmospheric modeling and technology in oceanographic instrumentation will be used in a six week field study during the austral spring 1990. The prime objective will be to document the impact of UV radiation on the phytoplankton community during the ice-edge spring bloom. During this time, oceanographic processes create favorable conditions for increased UVB susceptibility. Biological and bio-optical information will be used to define and quantify linkages between ozone-dependent oscillations in UV to PAR ratios and phytoplankton productivity. Special emphasis will be placed on defining biological restraints imposed by enhanced UVB and altered UVB:UVA:PAR ratios on the balance of UVB photodamage to photorepair, photoprotective and photosynthetic mechanisms operating in the Southern Ocean. The overall aim is to test the hypothesis that phytoplankton in Antarctic waters are adversely influenced by ozone depletion.
Increases in middle ultraviolet radiation associated with the Antarctic ozone hole have been shown to inhibit the photosynthesis of phytoplankton, and results have been extrapolated to estimate the effect of ozone depletion on primary productivity in the marginal ice zone. This research will refine the assessment by specifying detailed wavelength-dependent biological weighting functions for the inhibition of photosynthesis by ultraviolet radiation, and by considering the mitigating effects of vertical mixing. Biological weighting functions of phytoplankton in the marginal ice zone will be measured under controlled conditions and applied in a new model of photosynthesis to predict primary productivity in situ, as well as under altered ultraviolet irradiance. These predictions will be compared with observations on samples from the water column and with measurements during incubations of several hours under different irradiance regimes. Results of these comparisons will be used to test the model and to quantify the potential artifact of long incubations. Assumptions about the kinetics of photoinhibition and recovery, critical to modeling the effects of vertical mixing, will be examined with time-course experiments. Results will be incorporated into a model of photosynthesis and photoinhibition in the water column that will be used to predict the influence of ozone depletion on marine primary production, particularly in the marginal zone.
Ultraviolet radiation influences the dynamics of plankton processes in the near-surface waters of most aquatic ecosystems. In particular, the Southern Ocean is affected in the austral spring period when biologically damaging ultraviolet radiation is enhanced by ozone depletion. While progress has been made in estimating the quantitative impact of ultraviolet radiation on bacteria and phytoplankton in the Southern Ocean, some important issues remain to be resolved. Little is known about responses in systems dominated by the colonial haptophyte Phaeocystis antarctica, which dominates spring blooms in a polyna that develops in the southern Ross Sea. The Ross Sea is also of interest because of the occurrence of open water at a far southerly location in the spring, well within the ozone hole, and continuous daylight, with implications for the regulation of DNA repair. A number of studies suggest that vertical mixing can significant modify the impact of ultraviolet radiation in the Southern Ocean and elsewhere. However, there are limited measurements of turbulence intensity in the surface layer and measurements have not been integrated with parallel studies of ultraviolet radiation effects on phytoplankton and bacterioplankton. To address these issues, this collaborative study will focus on vertical mixing and the impact of ultraviolet radiation in the Ross Sea. The spectral and temporal responses of phytoplankton and bacterioplankton to ultraviolet radiation will be characterized in both laboratory and solar incubations. These will lead to the definition of biological weighting functions and response models capable of predicting the depth and time distribution of ultraviolet radiation impacts on photosynthesis, bacterial incorporation and DNA damage in the surface layer. Diel sampling will measure depth-dependent profiles of DNA damage, bacterial incorporation, photosynthesis and fluorescence parameters over a 24 h cycle. Sampling will include stations with contrasting wind-driven mixing and stratification as the polyna develops. The program of vertical mixing measurements is optimized for the typical springtime Ross Sea situation in which turbulence of intermediate intensity is insufficient to mix the upper layer thoroughly in the presence of stabilizing influences like solar heating and/or surface freshwater input from melting ice. Fine-scale vertical density profiles will be measured with a free-fall CTD unit and the profiles will be used to directly estimate large-eddy scales by determining Thorpe scales. Eddy scales and estimated turbulent diffusivities will be directly related to surface layer effects, and used to generate lagrangian depth-time trajectories in models of ultraviolet radiation responses in the surface mixed layer. The proposed research will be the first in-depth study of ultraviolet radiation effects in the Ross Sea and provide a valuable comparison with previous work in the Weddell-Scotia Confluence and Palmer Station regions. It will also enhance the understanding of vertical mixing processes, trophic interactions and biogeochemical cycling in the Ross Sea.
This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.