USAP-DC

{"dp_type": "Project", "free_text": "Msa"}

[{"awards": "0944686 Kieber, David; 0944659 Kiene, Ronald", "bounds_geometry": "POLYGON((-180 -68,-177 -68,-174 -68,-171 -68,-168 -68,-165 -68,-162 -68,-159 -68,-156 -68,-153 -68,-150 -68,-150 -69,-150 -70,-150 -71,-150 -72,-150 -73,-150 -74,-150 -75,-150 -76,-150 -77,-150 -78,-153 -78,-156 -78,-159 -78,-162 -78,-165 -78,-168 -78,-171 -78,-174 -78,-177 -78,180 -78,178 -78,176 -78,174 -78,172 -78,170 -78,168 -78,166 -78,164 -78,162 -78,160 -78,160 -77,160 -76,160 -75,160 -74,160 -73,160 -72,160 -71,160 -70,160 -69,160 -68,162 -68,164 -68,166 -68,168 -68,170 -68,172 -68,174 -68,176 -68,178 -68,-180 -68))", "dataset_titles": "Ecophysiology of DMSP and related compounds and their contributions to carbon and sulfur dynamics in Phaeocystis antarctica", "datasets": [{"dataset_uid": "600117", "doi": "10.15784/600117", "keywords": "Biota; Ross Sea; Southern Ocean", "people": "Kieber, David John", "repository": "USAP-DC", "science_program": null, "title": "Ecophysiology of DMSP and related compounds and their contributions to carbon and sulfur dynamics in Phaeocystis antarctica", "url": "https://www.usap-dc.org/view/dataset/600117"}, {"dataset_uid": "600150", "doi": "10.15784/600150", "keywords": "Antarctica; Biota; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Oceans; Ross Sea", "people": "Kiene, Ronald", "repository": "USAP-DC", "science_program": null, "title": "Ecophysiology of DMSP and related compounds and their contributions to carbon and sulfur dynamics in Phaeocystis antarctica", "url": "https://www.usap-dc.org/view/dataset/600150"}], "date_created": "Wed, 16 Dec 2015 00:00:00 GMT", "description": "Spectacular blooms of Phaeocystis antarctica in the Ross Sea, Antarctica are the source of some of the world\u0027s highest concentrations of dimethylsulfoniopropionate (DMSP) and its volatile degradation product, dimethylsulfide (DMS). The flux of DMS from the oceans to the atmosphere in this region and its subsequent gas phase oxidation generates aerosols that have a strong influence on cloud properties and possibly climate. In the oceans, DMS and DMSP are quantitatively significant components of the carbon, sulfur, and energy flows in marine food webs, especially in the Ross Sea. Despite its central role in carbon and sulfur biogeochemistry in the Ross Sea, surprisingly little is known about the physiological functions of DMSP in P. Antarctica. The research will isolate and characterize DMSP lyases from P. antarctica, with the goal of obtaining amino acid and gene sequence information on these important enzymes. The physiological studies will focus on the effects of varying intensities of photosynthetically active radiation, with and without ultraviolet radiation as these are factors that we have found to be important controls on DMSP and DMS dynamics. The research also will examine the effects of prolonged darkness on the dynamics of DMSP and related compounds in P. antarctica, as survival of this species during the dark Antarctic winter and at sub-euphotic depths appears to be an important part of the Phaeocystis? ecology. A unique aspect of this work is the focus on measurements of intracellular MSA, which if detected, would provide strong evidence for in vivo radical scavenging functions for methyl sulfur compounds. The study will advance understanding of what controls DMSP cycling and ultimately DMS emissions from the Ross Sea and also provide information on what makes P. antarctica so successful in this extreme environment. The research will directly benefit and build on several interrelated ocean-atmosphere programs including the International Surface Ocean Lower Atmosphere Study (SOLAS) program. The PIs will participate in several activities involving K-12 education, High School teacher training, public education and podcasting through the auspices of the Dauphin Island Sea Lab Discovery Hall program and SUNY ESF. Two graduate students will be employed full time, and six undergraduates (2 each summer) will be trained as part of this project.", "east": -150.0, "geometry": "POINT(-175 -73)", "instruments": null, "is_usap_dc": true, "keywords": "Amd/Us; Not provided; Ecophysiology; AMD; USAP-DC; FIELD SURVEYS", "locations": null, "north": -68.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Kiene, Ronald; Kieber, David John", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -78.0, "title": "Collaborative Research: Ecophysiology of DMSP and related compounds and their contributions to carbon and sulfur dynamics in Phaeocystis antarctica", "uid": "p0000085", "west": 160.0}, {"awards": "0939628 Barletta, Robert", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 06 Aug 2015 00:00:00 GMT", "description": "Biogenic sulfur compounds, such as dimethyl sulfide (DMS), its precursors dimethyl sulfoniopropionate (DMSP) and dimethyl sulfoxide (DMSO), and its atmospheric oxidation product, methane sulfonic acid (MSA), are important components of the global sulfur cycle that significantly impact global climate. The roles of DMSP and DMSO within the organisms that produce them, as well as their intracellular concentrations, are poorly understood. DMSO has been speculated to play a role in intracellular osmoregulation, cryoprotection and scavenging of reactive oxygen species, but its intracellular concentration in plankton has only been inferred. Quantitative measurement of the concentration of biogenic sulfur compounds in vivo is necessary to more completely understand their biogeochemistry. The principal investigator has developed methods for the quantitative analysis of biogenic sulfur compounds using Raman spectroscopy, which have resulted in the detection of DMSO with a sensitivity of \u003c10 mM - far lower than the current estimates of its intracellular concentrations. The research will extend this technique to DMSP. The direct determination of the intracellular DMSP and DMSO, will allow the proposed roles of these compounds in phytoplankton to be investigated. Lastly, using field-collected cores, measurements will be made of the intracellular sulfur compounds as well as the concentration of molecular anions in the sea ice micro-environment. As an RUI project, successful completion of this work will have a substantial impact on undergraduate education in the Chemistry Department at the University of South Alabama, exposing undergraduates and, particularly, under-represented minorities in the sciences to cutting-edge research. It will provide financial support for their education and allow them to present research in journal articles and at technical meetings. Contacts with scientists in the field of Antarctic research at other institutions will give students the opportunity to interact with researchers in related fields, broadening their experience base.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -60.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Barletta, Robert", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -90.0, "title": "RUI: Analysis of Intracellular Biogenic Sulfur Using micro-Raman Spectroscopy", "uid": "p0000403", "west": -180.0}, {"awards": "0228052 Kreutz, Karl", "bounds_geometry": "POLYGON((161.0434 -77.3002,161.241645 -77.3002,161.43989 -77.3002,161.638135 -77.3002,161.83638 -77.3002,162.034625 -77.3002,162.23287 -77.3002,162.431115 -77.3002,162.62936 -77.3002,162.827605 -77.3002,163.02585 -77.3002,163.02585 -77.3784846,163.02585 -77.4567692,163.02585 -77.5350538,163.02585 -77.6133384,163.02585 -77.691623,163.02585 -77.7699076,163.02585 -77.8481922,163.02585 -77.9264768,163.02585 -78.0047614,163.02585 -78.083046,162.827605 -78.083046,162.62936 -78.083046,162.431115 -78.083046,162.23287 -78.083046,162.034625 -78.083046,161.83638 -78.083046,161.638135 -78.083046,161.43989 -78.083046,161.241645 -78.083046,161.0434 -78.083046,161.0434 -78.0047614,161.0434 -77.9264768,161.0434 -77.8481922,161.0434 -77.7699076,161.0434 -77.691623,161.0434 -77.6133384,161.0434 -77.5350538,161.0434 -77.4567692,161.0434 -77.3784846,161.0434 -77.3002))", "dataset_titles": "Late Holocene Climate Variability, Dry Valleys, Antarctica", "datasets": [{"dataset_uid": "609399", "doi": "10.7265/N5FF3Q92", "keywords": "Antarctica; Borehole Temperature; Chemistry:ice; Chemistry:Ice; Dry Valleys; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Mass Balance; Paleoclimate; Physical Properties", "people": "Mayewski, Paul A.; Kreutz, Karl", "repository": "USAP-DC", "science_program": null, "title": "Late Holocene Climate Variability, Dry Valleys, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609399"}], "date_created": "Tue, 21 Oct 2008 00:00:00 GMT", "description": "This award supports a project to collect and develop high-resolution ice core records from the Dry Valleys region of Antarctica, and provide interpretations of interannual to decadal-scale climate variability during the last 2000 years (late Holocene). The project will test hypotheses related to ocean/atmosphere teleconnections (e.g., El Nino Southern Oscillation, Antarctic Oscillation) that may be responsible for major late Holocene climate events such as the Little Ice Age in the Southern Hemisphere. Conceptual and quantitative models of these processes in the Dry Valleys during the late Holocene are critical for understanding recent climate changes, and represent the main scientific merit of the project. We plan to collect intermediate-length ice cores (100-200m) at four sites along transects in Taylor Valley and Wright Valley, and analyze each core at high resolution for stable isotopes (d18O, dD), major ions (Na+, Mg2+, Ca2+, K+, NH4+, Cl-, NO3-, SO42-, MSA), and trace elements (Al, Fe, S, Sr, B). A suite of statistical techniques will be applied to the multivariate glaciochemical dataset to identify chemical associations and to calibrate the time-series records with available instrumental data. Broader impacts of the project include: 1) contributions to several ongoing interdisciplinary Antarctic research programs; 2) graduate and undergraduate student involvement in field, laboratory, and data interpretation activities; 3) use of project data and ideas in several UMaine courses and outreach activities; and 4) data dissemination through peer-reviewed publications, UMaine and other paleoclimate data archive websites, and presentations at national and international meetings.", "east": 163.02585, "geometry": "POINT(162.034625 -77.691623)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MC-ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e RECORDERS/LOGGERS \u003e AWS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e HUMIDITY SENSORS; IN SITU/LABORATORY INSTRUMENTS \u003e PRESSURE/HEIGHT METERS \u003e PRESSURE SENSORS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e TEMPERATURE SENSORS", "is_usap_dc": true, "keywords": "Holocene; Climate Research; AWS Climate Data; Paleoclimate; Climate Variation; Dry Valleys; Wright Valley; Little Ice Age; Stable Isotopes; Glaciochemical; Ice Core; FIELD INVESTIGATION; Enso; Antarctic Oscillation; Climate; GPS; El Nino-Southern Oscillation; LABORATORY; Not provided; Climate Change; Ice Core Records; Antarctica; Taylor Valley; FIELD SURVEYS; Variability", "locations": "Antarctica; Dry Valleys; Taylor Valley; Wright Valley", "north": -77.3002, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Kreutz, Karl; Arcone, Steven; Mayewski, Paul A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY; SPACE-BASED PLATFORMS \u003e NAVIGATION SATELLITES \u003e GLOBAL POSITIONING SYSTEM (GPS) \u003e GPS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -78.083046, "title": "Dry Valleys Late Holocene Climate Variability", "uid": "p0000155", "west": 161.0434}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}, {"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Williams, Margaret; Saltzman, Eric; Aydin, Murat; Tatum, Cheryl", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; Carbonyl Sulfide; Siple Coast; Chloride; Trapped Gases; Snow; Ice Core Chemistry; Chromatography; Siple; GROUND STATIONS; Atmospheric Gases; Ozone Depletion; AWS Siple; Ice Sheet; Ice Core Data; Antarctica; Glaciology; West Antarctica; Atmospheric Chemistry; Ice Core; Stratigraphy; LABORATORY; Methane; Mass Spectrometer; GROUND-BASED OBSERVATIONS; WAISCORES; Msa; Mass Spectrometry; Not provided; Siple Dome; Gas Measurement", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica; Siple", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}, {"awards": "9615333 Saltzman, Eric", "bounds_geometry": "POINT(-148.8 -81.7)", "dataset_titles": "Biogenic Sulfur in the Siple Dome Ice Core", "datasets": [{"dataset_uid": "609201", "doi": "10.7265/N5S180F1", "keywords": "Antarctica; Biota; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Finley, Brandon; Dioumaeva, Irina; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Biogenic Sulfur in the Siple Dome Ice Core", "url": "https://www.usap-dc.org/view/dataset/609201"}], "date_created": "Tue, 09 Mar 2004 00:00:00 GMT", "description": "This award is for support for four years of funding for a program of biogenic sulfur measurements on the Siple Dome ice core. Biogenic sulfur is a major aerosol-forming constituent of the atmosphere and has potentially important links to the earth\u0027s radiation budget. Previous work on the Vostok ice core has demonstrated a remarkable climate-related variability in biogenic sulfur, suggesting that the sulfur cycle may act to stabilize climate (keep the glacial atmosphere cool and the interglacial atmosphere warm) in the Southern Hemisphere. In this study, methane-sulfonate (MSA) will be measured on the Siple Dome ice core as part of the West Antarctic ice sheet program (WAIS). Siple Dome is located in a region which is strongly impacted by the incursion of marine air onto the Antarctic plateau. Because of its proximity to the coast and meteorological setting, it is expected that variability in high-latitude marine biogenic sulfur emissions should dominate the MSA record at this site. In addition to the deep ice core record, samples from shallow cores will also be analyzed to provide information about regional variability and decadal-to-centennial scale variability in the deposition of sulfur-containing aerosols from high latitude source regions over the past 200 years.", "east": -148.8, "geometry": "POINT(-148.8 -81.7)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "FIELD SURVEYS; Siple Dome; GROUND-BASED OBSERVATIONS; Biogenic Sulfur; FIELD INVESTIGATION; Not provided; LABORATORY; Methane Sulfonate", "locations": "Siple Dome", "north": -81.7, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Dioumaeva, Irina; Finley, Brandon", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.7, "title": "Biogenic Sulfur in the Siple Dome Ice Core", "uid": "p0000251", "west": -148.8}]

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