[{"awards": "0839066 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Major Ion Chemistry Data of WAIS Divide Ice Core Brittle Ice", "datasets": [{"dataset_uid": "609546", "doi": "10.7265/N5RF5S0D", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; WAIS Divide; WAIS Divide Ice Core", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Major Ion Chemistry Data of WAIS Divide Ice Core Brittle Ice", "url": "https://www.usap-dc.org/view/dataset/609546"}], "date_created": "Wed, 19 Mar 2014 00:00:00 GMT", "description": "Cole-Dai/0839066\u003cbr/\u003e\u003cbr/\u003eThis award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to make continuous major ion analyses in the West Antarctica Ice Sheet Divide (WAIS Divide) ice core by sampling the brittle ice zone (approximately from 500 m to 1500 m). The intellectual merit of the project is that these will likely be the only chemical measurements on the brittle ice zone and, therefore, will bridge the gap in the expected continuous records of climate, ice sheet dynamics and biological evolution based on chemical measurements. High resolution sampling and analysis, probably on selected portions and depth intervals in the brittle ice zone, will help with the independent, high-precision dating of the WAIS Divide core and contribute to the achievement of the major objectives of the WAIS Divide project?development of high resolution climate records with which to investigate issues of climate forcing by greenhouse gases and the role of Antarctica and Southern Hemisphere in the global climate system. Planned collaboration with other WAIS Divide investigators will develop the longest and most detailed volcanic record from Antarctica ice cores. The broader impacts of this project include a contribution to enhancing our knowledge of the climate system. Such improvements in understanding of the global climate system and the ability to predict the magnitude and uncertainty of future changes are highly relevant to the global community. The project will support post-doctoral scientists and graduate students, including those from under-represented groups, will contribute to education, an help to train future scientists and promote diversity in research and education. Public outreach activities of this project will contribute to informal science education of school age children in the Eastern South Dakota region.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Paleoclimate; LABORATORY; Ions; GROUND-BASED OBSERVATIONS; WAISCORES; Ion Chromatograph; Not provided; Ice Core", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "NOT APPLICABLE", "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Major Ion Chemical Analysis of Brittle Ice in the WAIS Divide Ice Core", "uid": "p0000047", "west": null}, {"awards": "0538674 Winebrenner, Dale; 0537752 Creyts, Timothy", "bounds_geometry": null, "dataset_titles": "Millennially Averaged Accumulation Rates for Lake Vostok; Modeled Radar Attenuation Rate Profile at the Vostok 5G Ice Core Site, Antarctica", "datasets": [{"dataset_uid": "609501", "doi": "10.7265/N59K485D", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Lake Vostok; Radar Attenuation Rate; Vostok Ice Core", "people": "Macgregor, Joseph A.; Matsuoka, Kenichi; Studinger, Michael S.", "repository": "USAP-DC", "science_program": null, "title": "Modeled Radar Attenuation Rate Profile at the Vostok 5G Ice Core Site, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609501"}, {"dataset_uid": "609500", "doi": "10.7265/N5F769HV", "keywords": "Accumulation Rate; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Lake Vostok", "people": "Studinger, Michael S.; Winebrenner, Dale; Matsuoka, Kenichi; Macgregor, Joseph A.; Waddington, Edwin D.", "repository": "USAP-DC", "science_program": null, "title": "Millennially Averaged Accumulation Rates for Lake Vostok", "url": "https://www.usap-dc.org/view/dataset/609500"}], "date_created": "Thu, 09 Aug 2012 00:00:00 GMT", "description": "0538674\u003cbr/\u003eMatsuoka\u003cbr/\u003eThis award supports a project to evaluate radio-echo intensities in the available SOAR ice-penetrating radar data along grids covering Lake Vostok, and along four regional tracks from Ridge B toward the lake. The project has two objectives; first, it will examine the upper surface of the lake and reflectors hypothesized to be a boundary between the meteoric and accreted ice. They will provide crucial knowledge on the dynamic evolution of the lake. Second, this project will examine a poorly understood echo-free zone within the deep ice in central East Antarctica. This zone may consist of distorted stagnant ice, while its upper boundary may be a shear zone. The SOAR radar data provide a unique resource to examine spatiotemporal water circulation patterns that should be understood in order to select the best direct-sampling strategy to the lake. The Vostok ice core provides a unique opportunity to do this work. First, the path effects, i.e. propagation loss and birefringence, will be derived at the ice-core site using ice temperature, chemistry, and fabric data. Second, lateral variations of the propagation loss will be estimated by tracking chemistry associated with radar-detected isochronous layers, and by inferring temperatures from an ice-flow model that can replicate those layers. Ice-fabric patterns will be inferred from anisotropy in the reflectivity at about 100 radar-track cross-over sites. In terms of broader impacts, a graduate student will be trained to interpret the radar data in the light of radar theory and glaciological context of Lake Vostok and summer workshops for K-12 teachers will be provided in Seattle and New York. This project will contribute to ongoing efforts to study Lake Vostok and will complement the site selection for a North Vostok ice core, which has been proposed by Russia and France as an IPY program.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e RADAR SOUNDERS \u003e RADAR ECHO SOUNDERS; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e RADAR SOUNDERS \u003e RADAR; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e LIDAR/LASER SOUNDERS \u003e LASERS; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e ALTIMETERS \u003e RADAR ALTIMETERS \u003e ALTIMETERS; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e ALTIMETERS \u003e RADAR ALTIMETERS \u003e RADAR ALTIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMOMETERS \u003e THERMOMETERS", "is_usap_dc": true, "keywords": "Airborne Radar Sounding; DHC-6; Salinity; Lake Vostok; Antarctic Ice Sheet; Modeling; FIELD SURVEYS; Model Output; Accumulation Rate; MODELS; Numerical Model; Ice Sheet; Not provided; Hydrostatic; Aerogeophysical; Subglacial; Attenuation Rate; Radar; FIELD INVESTIGATION; Model; Circulation; LABORATORY", "locations": "Lake Vostok; Antarctic Ice Sheet", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Matsuoka, Kenichi; Winebrenner, Dale; Creyts, Timothy; Macgregor, Joseph A.; Studinger, Michael S.; Waddington, Edwin D.", "platforms": "AIR-BASED PLATFORMS \u003e PROPELLER \u003e DHC-6; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e MODELS \u003e MODELS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Deciphering the Deep Ice and the Ice-water Interface over Lake Vostok Using Existing Radar Data", "uid": "p0000090", "west": null}, {"awards": "0636767 Dunbar, Nelia; 0636740 Kreutz, Karl", "bounds_geometry": "POINT(112.11666 -79.46666)", "dataset_titles": "Microparticle, Conductivity, and Density Measurements from the WAIS Divide Deep Ice Core, Antarctica; Snowpit Chemistry - Methods Comparison, WAIS Divide, Antarctica; Snowpit evidence of the 2011 Puyehue-Cordon Caulle (Chile) eruption in West Antarctica; WAIS Divide Microparticle Concentration and Size Distribution, 0-2400 ka; WAIS Divide Snowpit Chemical and Isotope Measurements, Antarctica; WAIS Divide WDC06A Discrete ICP-MS Chemistry", "datasets": [{"dataset_uid": "601036", "doi": "10.15784/601036", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Intracontinental Magmatism; IntraContinental Magmatism; Snow Pit; Tephra; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl; Koffman, Bess", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Snowpit evidence of the 2011 Puyehue-Cordon Caulle (Chile) eruption in West Antarctica", "url": "https://www.usap-dc.org/view/dataset/601036"}, {"dataset_uid": "609499", "doi": "10.7265/N5K07264", "keywords": "Antarctica; Density; Electrical Conductivity; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Microparticle Concentration; Physical Properties; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl; Koffman, Bess; Breton, Daniel; Hamilton, Gordon S.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Microparticle, Conductivity, and Density Measurements from the WAIS Divide Deep Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609499"}, {"dataset_uid": "609620", "doi": "10.7265/N5Q81B1X", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Trace Elements; WAIS Divide; WAIS Divide Ice Core", "people": "Koffman, Bess; Kreutz, Karl", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Snowpit Chemistry - Methods Comparison, WAIS Divide, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609620"}, {"dataset_uid": "609616", "doi": "10.7265/N5KK98QZ", "keywords": "Antarctica; Dust; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Particle Size; WAIS Divide; WAIS Divide Ice Core", "people": "Koffman, Bess; Kreutz, Karl", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Microparticle Concentration and Size Distribution, 0-2400 ka", "url": "https://www.usap-dc.org/view/dataset/609616"}, {"dataset_uid": "601023", "doi": "10.15784/601023", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; ICP-MS; Isotope; WAIS Divide; WAIS Divide Ice Core", "people": "Kreutz, Karl", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide WDC06A Discrete ICP-MS Chemistry", "url": "https://www.usap-dc.org/view/dataset/601023"}, {"dataset_uid": "609506", "doi": "10.7265/N5SJ1HHN", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Isotope; Microparticle Concentration; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core", "people": "Koffman, Bess; Kreutz, Karl", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Snowpit Chemical and Isotope Measurements, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609506"}], "date_created": "Tue, 19 Jun 2012 00:00:00 GMT", "description": "This award supports a project to perform continuous microparticle concentration and size distribution measurements (using coulter counter and state-of-the-art laser detector methods), analysis of biologically relevant trace elements associated with microparticles (Fe, Zn, Co, Cd, Cu), and tephra measurements on the WAIS Divide ice core. This initial three-year project includes analysis of ice core spanning the instrumental (~1850-present) to mid- Holocene (~5000 years BP) period, with sample resolution ranging from subannual to decadal. The intellectual merit of the project is that it will help in establishing the relationships among climate, atmospheric aerosols from terrestrial and volcanic sources, ocean biogeochemistry, and greenhouse gases on several timescales which remain a fundamental problem in paleoclimatology. The atmospheric mineral dust plays an important but uncertain role in direct radiative forcing, and the microparticle datasets produced in this project will allow us to examine changes in South Pacific aerosol loading, atmospheric dynamics, and dust source area climate. The phasing of changes in aerosol properties within Antarctica, throughout the Southern Hemisphere, and globally is unclear, largely due to the limited number of annually dated records extending into the glacial period and the lack of a\u003cbr/\u003etephra framework to correlate records. The broader impacts of the proposed research are an interdisciplinary approach to climate science problems, and will contribute to several WAIS Divide science themes as well as the broader paleoclimate and oceanographic communities. Because the research topics have a large and direct societal relevance, the project will form a centerpiece of various outreach efforts at UMaine and NMT including institution websites, public speaking, local K-12 school interaction, media interviews and news releases, and popular literature. At least one PhD student and one MS student will be directly supported by this project, including fieldwork, core processing, laboratory analysis, and data interpretation/publication. We expect that one graduate student per year will apply for a core handler/assistant driller position through the WAIS Divide Science Coordination Office, and that undergraduate student involvement will result in several Capstone experience projects (a UMaine graduation requirement). Data and ideas generated from the project will be integrated into undergraduate and graduate course curricula at both institutions.", "east": 112.11666, "geometry": "POINT(112.11666 -79.46666)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PARTICLE DETECTORS; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ELECTRON MICROPROBES; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e LOPC-PMS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e ICE CORE MELTER; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PARTICLE DETECTORS", "is_usap_dc": true, "keywords": "Ice Core Dust; Tephra; Radiative Forcing; Greenhouse Gas; West Antarctica; Atmospheric Aerosols; Oxygen Isotope; Not provided; WAIS Divide; Snow Pit; Ice Core Chemistry; Microparticle; Wais Divide-project; Microparticles Size; Paleoclimate; LABORATORY; Ice Core Data; Atmospheric Dynamics; Antarctica; FIELD SURVEYS; Ice Core; Trace Elements; FIELD INVESTIGATION; Holocene; Isotope; Snow Chemistry", "locations": "Antarctica; WAIS Divide; West Antarctica", "north": -79.46666, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Koffman, Bess; Kreutz, Karl; Breton, Daniel; Dunbar, Nelia; Hamilton, Gordon S.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.46666, "title": "Collaborative Research: Microparticle/tephra analysis of the WAIS Divide ice core", "uid": "p0000040", "west": 112.11666}, {"awards": "0538553 Cole-Dai, Jihong", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Major Ion Concentrations in WDC05Q and WDC06A Ice Cores (WAIS Divide)", "datasets": [{"dataset_uid": "609544", "doi": "10.7265/N54M92H3", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; WAIS Divide; WAIS Divide Ice Core", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Major Ion Concentrations in WDC05Q and WDC06A Ice Cores (WAIS Divide)", "url": "https://www.usap-dc.org/view/dataset/609544"}], "date_created": "Wed, 25 Aug 2010 00:00:00 GMT", "description": "Cole-Dai\u003cbr/\u003e0538553\u003cbr/\u003e\u003cbr/\u003eThis award supports a project that will contribute to the US West Antarctica Ice Sheet Ice Divide ice core (WAIS Divide) project by developing new instrumentation and analytical procedures to measure concentrations of major ions (Cl-, NO3-, SO42-, Na+, K+, NH4+, Mg2+, Ca2+). A melter-based, continuous flow, multi-ion-chromatograph technique (CFA-IC) has been developed recently at South Dakota State University (SDSU). This project will further expand and improve the CFA-IC technique and instrumentation and develop procedures for routine analysis of major ions in ice cores. In addition, training of personnel (operators) to perform continuous, high resolution major ion analysis of the deep core will be accomplished through this project. The temporal resolution of the major ion measurement will be as low as 0.5 cm with the fully developed CFA-IC technique. At this resolution, it will be possible to use annual cycles of sulfate and sea-salt ion concentrations to determine annual layers in the WAIS Divide ice core. Annual layer counting using CFA-IC chemical measurements and other high resolution measurements will contribute significantly to the major WAIS Divide project objective of producing precisely (i.e., annually) dated climate records. The project will support the integration of research and education, train future scientists and promote human resource development through the participation of graduate and undergraduate students. In particular, undergraduate participation will contribute to a current REU (Research Experience for Undergraduates) chemistry site program at SDSU. Development and utilization of multi-user instrumentation will promote research collaboration and advance environmental science. NSF support for SDSU will contribute to the economic development and strengthen the infrastructure for research and education in South Dakota.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "LABORATORY; WAIS Divide; Ice Core; West Antarctic Ice Sheet; Ion Chromatograph; GROUND-BASED OBSERVATIONS; Not provided; Major Ion; Ions", "locations": "WAIS Divide; West Antarctic Ice Sheet", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Major Ion Chemistry of WAIS Divide Ice Core", "uid": "p0000035", "west": -112.085}, {"awards": "0636506 Mayewski, Paul", "bounds_geometry": "POLYGON((-137.7 -75.7,-137.4 -75.7,-137.1 -75.7,-136.8 -75.7,-136.5 -75.7,-136.2 -75.7,-135.9 -75.7,-135.6 -75.7,-135.3 -75.7,-135 -75.7,-134.7 -75.7,-134.7 -75.773,-134.7 -75.846,-134.7 -75.919,-134.7 -75.992,-134.7 -76.065,-134.7 -76.138,-134.7 -76.211,-134.7 -76.284,-134.7 -76.357,-134.7 -76.43,-135 -76.43,-135.3 -76.43,-135.6 -76.43,-135.9 -76.43,-136.2 -76.43,-136.5 -76.43,-136.8 -76.43,-137.1 -76.43,-137.4 -76.43,-137.7 -76.43,-137.7 -76.357,-137.7 -76.284,-137.7 -76.211,-137.7 -76.138,-137.7 -76.065,-137.7 -75.992,-137.7 -75.919,-137.7 -75.846,-137.7 -75.773,-137.7 -75.7))", "dataset_titles": "Ion Concentrations from SPRESSO Ice Core, Antarctica; Mt. Moulton Ice Trench Mass Spectrometry Data, Antarctica", "datasets": [{"dataset_uid": "609471", "doi": "10.7265/N508638J", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; ITASE; Paleoclimate; South Pole; SPRESSO Ice Core", "people": "Korotkikh, Elena; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": null, "title": "Ion Concentrations from SPRESSO Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609471"}, {"dataset_uid": "609472", "doi": "10.7265/N5VH5KSV", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Mt Moulton; Paleoclimate", "people": "Mayewski, Paul A.; Korotkikh, Elena", "repository": "USAP-DC", "science_program": null, "title": "Mt. Moulton Ice Trench Mass Spectrometry Data, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609472"}], "date_created": "Thu, 29 Jul 2010 00:00:00 GMT", "description": "This award supports a project to examine an existing ice core of opportunity from South Pole (SPRESO core) to develop a 2000+ year long climate record. SPRESO ice core will be an annually dated, sub-annually-resolved reconstruction of past climate (atmospheric circulation, temperature, precipitation rate, and atmospheric chemistry) utilizing continuous, co-registered measurements (n=45) of: major ions, trace elements, and stable isotope series, plus selected sections for microparticle size and composition. The intellectual merit of this project relates to the fact that few 2000+ year records of this quality exist in Antarctica despite increasing scientific interest in this critical time period as the framework within which to understand modern climate. The scientific impact of this ice core investigation are that it will provide an in-depth understanding of climate variability; a baseline for assessing modern climate variability in the context of human activity; and a contribution to the prediction of future climate variability. The broader impact of this work is that the proposed research addresses important questions concerning the role of Antarctica in past, present, and future global change. Results will be translated into publicly accessible information through public lectures, media appearances, and an extensive outreach activity housed in our Institute. Our ice core activities provide a major basis for curriculum in K-12 and University plus a basis for several field and laboratory based graduate theses and undergraduate student projects. The project will support one PhD student for 3 years and undergraduate salaries. The Climate Change Institute has a long history of gender and ethnically diverse student and staff involvement in research.", "east": -134.7, "geometry": "POINT(-136.2 -76.065)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Interpretation; Ions; US ITASE; Explorations; LABORATORY; Ice Core Data; Ice Core; Ice Analysis; Ice; Not provided; Antarctic Ice Sheet; Laboratory Investigation; Field Investigations; Ice Core Chemistry; Horizontal Ice Core; Ice Chemistry; Ice Sheet", "locations": "Antarctic Ice Sheet", "north": -75.7, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Korotkikh, Elena; Kreutz, Karl; Kurbatov, Andrei V.; Mayewski, Paul A.", "platforms": "Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -76.43, "title": "Collaborative Proposal: 2000+ Year Detailed, Calibrated Climate Reconstruction from a South Pole Ice Core Set in an Antarctic - Global Scale Context", "uid": "p0000209", "west": -137.7}, {"awards": "9980379 Baker, Ian", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Mon, 15 Feb 2010 00:00:00 GMT", "description": "This award is for support for three years of funding to study the effects of impurities on the flow of poly-\u003cbr/\u003ecrystalline ice. It has been known for thirty years that both hydrofluoric acid (HF) and hydrochloric acid (HCl) dramatically decrease the strength of ice and recent work by the author\u0027s group has shown that sulfuric acid (H2SO4) produces a similar reduction in strength. However, these data are for single crystals at strain rates and stresses that far exceed those found in glaciers and ice sheets, and often at concentrations that far exceed those in natural ice. Therefore, it is not known how impurities found in nature affect the flow of polycrystalline ice at slow strain rates. In this research, the effects of nitric acid and sulfuric acid (which are naturally occurring impurities in ice) on the microstructure (dislocation structure, grain boundary structure and location of the acids) and creep of polycrystalline ice (at a range of temperatures and stresses) will be determined. The ice\u0027s response to creep deformation will be studied using a combination of x-ray topography, optical microscopy and scanning electron microscopy. X-ray microanalysis in an environmental scanning electron microscope will be used to study the location of impurities. The structure and creep behavior of the acid-doped ice will be compared with those of both high-purity laboratory-grown ice and ice from Byrd Station, Antarctica. The end-result of this project will be to elucidate the effects of naturally-occurring acid impurities on the mechanical properties of polycrystalline ice under conditions relevant to the deformation of glaciers and ice sheets, including and understanding of how impurities affect the underlying deformation mechanisms.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PARTICLE DETECTORS; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES", "is_usap_dc": true, "keywords": "Ice Core Data; Ice Core; Microstructure; Ice Sheet; Ice Core Chemistry; Antarctic Ice Sheet; LABORATORY", "locations": "Antarctic Ice Sheet", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Obbard, Rachel", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repositories": null, "science_programs": null, "south": null, "title": "The Effects of Impurities on the Flow of Polycrystalline Ice", "uid": "p0000015", "west": null}, {"awards": "0230288 Anastasio, Cort", "bounds_geometry": "POLYGON((123.30014 -75.093445,123.307404 -75.093445,123.314668 -75.093445,123.321932 -75.093445,123.329196 -75.093445,123.33646 -75.093445,123.343724 -75.093445,123.350988 -75.093445,123.358252 -75.093445,123.365516 -75.093445,123.37278 -75.093445,123.37278 -75.0952669,123.37278 -75.0970888,123.37278 -75.0989107,123.37278 -75.1007326,123.37278 -75.1025545,123.37278 -75.1043764,123.37278 -75.1061983,123.37278 -75.1080202,123.37278 -75.1098421,123.37278 -75.111664,123.365516 -75.111664,123.358252 -75.111664,123.350988 -75.111664,123.343724 -75.111664,123.33646 -75.111664,123.329196 -75.111664,123.321932 -75.111664,123.314668 -75.111664,123.307404 -75.111664,123.30014 -75.111664,123.30014 -75.1098421,123.30014 -75.1080202,123.30014 -75.1061983,123.30014 -75.1043764,123.30014 -75.1025545,123.30014 -75.1007326,123.30014 -75.0989107,123.30014 -75.0970888,123.30014 -75.0952669,123.30014 -75.093445))", "dataset_titles": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "datasets": [{"dataset_uid": "609519", "doi": "10.7265/N5MS3QP0", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Dome C Ice Core; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Physical Properties; Snow/ice; Snow/Ice", "people": "Anastasio, Cort; Robles, Tony", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609519"}], "date_created": "Wed, 07 Mar 2007 00:00:00 GMT", "description": "Photochemical reactions in snow can have important effects on the chemistry and composition of the snowpack as well as the overlying atmosphere. For example, recent measurements in the Antarctic and Arctic have revealed that sunlit snow releases a number of important pollutants to the atmosphere. Our ability to understand and model this chemistry is currently limited, in part because we lack fundamental photochemical information for a number of important chemical species in snow. This award supports research that will help fill this gap by characterizing the low-temperature photochemistry of three of these key species: nitrite (NO2-), nitrous acid (HNO2), and hydrogen peroxide (HOOH). We will measure quantum yields for these reactions on ice using a sensitive technique that we recently developed during a study of nitrate (NO3-) photochemistry. In addition to this basic research, we will also measure the rates of formation of hydroxyl radical (OH), nitrogen oxides (NOx), and HOOH in illuminated Antarctic snow samples. These measurements will be important inputs for future models, and will allow us to test whether known species (e.g., NO3-, NO2- and HNO2) are responsible for most of snowpack reactivity (e.g., OH formation). Overall, results from this award will significantly improve our ability to understand snowpack chemistry, and the resulting effects on the atmosphere, both in the Antarctic as well as in the many other regions with permanent or seasonal snow. These results will also strengthen efforts to use ice core records to monitor global change. In addition to these impacts, this award will help train students and a postdoctoral fellow, and results from this work will be integrated into two classes in order to expose students to some of the important issues facing polar regions.", "east": 123.37278, "geometry": "POINT(123.33646 -75.1025545)", "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PHOTOMETERS \u003e SPECTROPHOTOMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e HPLC; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Snow Chemistry; Antarctica; Snowpack Chemistry; Snow Samples; Hydrogen Peroxide; Snow Properties; Pollutants; Chemistry; Light Absorption; Antarctic; Chemical Species; Snow; East Antarctica; Organic Compounds; Photochemistry; LABORATORY", "locations": "Antarctica; East Antarctica; Antarctic", "north": -75.093445, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Anastasio, Cort; Robles, Tony", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Dome C Ice Core", "south": -75.111664, "title": "Laboratory Studies of Photochemistry in Antarctic Snow and Ice", "uid": "p0000175", "west": 123.30014}, {"awards": "0337933 Cole-Dai, Jihong; 0338363 Thiemens, Mark", "bounds_geometry": null, "dataset_titles": "Major Ion Concentrations in 2004 South Pole Ice Core", "datasets": [{"dataset_uid": "609542", "doi": "10.7265/N5HX19N8", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Major Ion Concentrations in 2004 South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609542"}], "date_created": "Fri, 11 Aug 2006 00:00:00 GMT", "description": "This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Not provided; Ion Chromatograph; Ions; LABORATORY; GROUND-BASED OBSERVATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Investigating Atmospheric Chemistry and Dynamics through Oxygen and Sulfur Isotopes in Volcanic Sulfate from South Pole Ice Cores", "uid": "p0000031", "west": null}, {"awards": "0126343 Nishiizumi, Kunihiko", "bounds_geometry": "POINT(-148.812 -81.6588)", "dataset_titles": "Cosmogenic Radionuclides in the Siple Dome A Ice Core", "datasets": [{"dataset_uid": "609307", "doi": "10.7265/N5XK8CGS", "keywords": "Antarctica; Geochemistry; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Finkel, R. C.; Nishiizumi, Kunihiko", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Cosmogenic Radionuclides in the Siple Dome A Ice Core", "url": "https://www.usap-dc.org/view/dataset/609307"}], "date_created": "Mon, 12 Jun 2006 00:00:00 GMT", "description": "This award supports a three-year renewal project to complete measurement of cosmogenic nuclides in the Siple Dome ice core as part of the West Antarctic ice core program. The investigators will continue to measure profiles of Beryllium-10 (half-life = 1.5x10 6 years) and Chlorine-36 (half-life = 3.0x10 5 years) in the entire ice core which spans the time period from the present to about 100 kyr. It will be particularly instructive to compare the Antarctic record with the detailed Arctic record that was measured by these investigators as part of the GISP2 project. This comparison will help separate global from local effects at the different drill sites. Cosmogenic radionuclides in polar ice cores have been used to study the long-term variations in several important geophysical variables, including solar activity, geomagnetic field strength, atmospheric circulation, snow accumulation rates, and others. The time series of nuclide concentrations resulting from this work will be applied to several problem areas: perfecting the ice core chronology, deducing the history of solar activity, deducing the history of variations in the geomagnetic field, and studying the possible role of solar variations on climate. Comparison of Beryllium-10 and Chlorine-36 profiles in different cores will allow us to improve the ice core chronology and directly compare ice cores from different regions of the globe. Additional comparison with the Carbon-14 record will allow correlation of the ice core paleoenvironment record to other, Carbon-14 dated, paleoclimate records.", "east": -148.812, "geometry": "POINT(-148.812 -81.6588)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e AMS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; Antarctica; Ice Core; Cosmogenic Radionuclides; Chlorine-36; GROUND STATIONS; Beryllium-10; Siple Dome; West Antarctica", "locations": "Antarctica; Siple Dome; West Antarctica", "north": -81.6588, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Finkel, R. C.; Nishiizumi, Kunihiko", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.6588, "title": "Cosmogenic Radionuclides in the Siple Dome Ice Core", "uid": "p0000358", "west": -148.812}, {"awards": "9316564 Mayewski, Paul", "bounds_geometry": null, "dataset_titles": "Ross Ice Drainage System (RIDS) Glaciochemical Analysis; Siple Dome Ice Core Chemistry and Ion Data", "datasets": [{"dataset_uid": "609266", "doi": "10.7265/N5M906KG", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; Snow Pit", "people": "Meeker, Loren D.; Whitlow, Sallie; Twickler, Mark; Mayewski, Paul A.; Kreutz, Karl", "repository": "USAP-DC", "science_program": null, "title": "Ross Ice Drainage System (RIDS) Glaciochemical Analysis", "url": "https://www.usap-dc.org/view/dataset/609266"}, {"dataset_uid": "609251", "doi": "", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Kreutz, Karl; Mayewski, Paul A.; Dunbar, Nelia; Severinghaus, Jeffrey P.; Blunier, Thomas; Brook, Edward J.", "repository": "NCEI", "science_program": "Siple Dome Ice Core", "title": "Siple Dome Ice Core Chemistry and Ion Data", "url": "https://www.ncei.noaa.gov/access/paleo-search/study/2461"}], "date_created": "Thu, 26 Aug 2004 00:00:00 GMT", "description": "9316564 Mayewski This award is for support for a three year program to provide a high resolution record of the Antarctic climate through the acquisition, analysis, and interpretation of records of atmospheric chemical deposition taken from three ice cores located at sites within or immediately adjacent to the Ross Ice Drainage System (RIDS). These cores include one from Taylor Dome, and two from West Antarctic locations identified as potential deep drilling sites for the WAISCORES program. Collection of the two West Antarctic cores is intended to be a lightweight dry-drilling operation to depths of ~ 200 m, which will provide records of \u003e 2 kyr. Glaciochemical analyses will focus on the major cations and anions found in the antarctic atmosphere, plus methanesulfonic acid and selected measurements of the hydrogen ion, aluminum, iron, and silica. These analyses, and companion stable isotope and particle measurements to be carried out by other investigators require \u003c 7% by volume of each core, leaving \u003e 90% for other investigators and storage at the U.S. National Ice Core Laboratory. These records are intended to solve a variety of scientific objectives while also providing spatial sampling and reconnaissance for future U.S. efforts in West Antarctica. ***", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Magnesium; GROUND STATIONS; Nitrate; Methane Sulfonic Acid; Sodium; Ice Core Chemistry; Ammonium (NH4); Sulfate; Ice Core; Chloride; Potassium (k); Calcium (ca)", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Kreutz, Karl; Twickler, Mark; Whitlow, Sallie; Blunier, Thomas; Dunbar, Nelia; Brook, Edward J.; Mayewski, Paul A.; Meeker, Loren D.; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "NCEI; USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Ross Ice Drainage System (RIDS) Late Holocene Climate Variability", "uid": "p0000145", "west": null}, {"awards": "0087151 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Sulfate-Based Volcanic Record from South Pole Ice Core", "datasets": [{"dataset_uid": "609215", "doi": "10.7265/N5CR5R88", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Solid Earth; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Sulfate-Based Volcanic Record from South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609215"}], "date_created": "Fri, 09 Apr 2004 00:00:00 GMT", "description": "This award supports a two year project to analyze shallow (~150 m) ice cores from South Pole in order to construct an annually resolved, sulfate-based volcanic record covering the last 1400 years. Two shallow ice cores will be recovered at the South Pole during the 00/01 field season and will be used for this work. Volcanic records from polar ice cores provide valuable information for studies of the connection between volcanism and climate. The new records are expected to be continuous and to cover at least the last 1400 years. The information from these records will verify the volcanic events found in the few existing Antarctic records and resolve discrepancies in the timing and magnitude of major explosive eruptions \u003cbr/\u003edetermined from those earlier records. In order to achieve the objectives of the proposed research, funds are provided to assist with the construction of an analytical laboratory for ice core and environmental \u003cbr/\u003echemistry research.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core; Snow Chemistry; West Antarctica; GROUND-BASED OBSERVATIONS; Antarctica; Ice Core Gas Records; Ion Chemistry; Ice Core Data", "locations": "West Antarctica; Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "A Sulfate-based Volcanic Record from South Pole Ice Cores", "uid": "p0000167", "west": null}]
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Cole-Dai/0839066<br/><br/>This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).<br/><br/>This award supports a project to make continuous major ion analyses in the West Antarctica Ice Sheet Divide (WAIS Divide) ice core by sampling the brittle ice zone (approximately from 500 m to 1500 m). The intellectual merit of the project is that these will likely be the only chemical measurements on the brittle ice zone and, therefore, will bridge the gap in the expected continuous records of climate, ice sheet dynamics and biological evolution based on chemical measurements. High resolution sampling and analysis, probably on selected portions and depth intervals in the brittle ice zone, will help with the independent, high-precision dating of the WAIS Divide core and contribute to the achievement of the major objectives of the WAIS Divide project?development of high resolution climate records with which to investigate issues of climate forcing by greenhouse gases and the role of Antarctica and Southern Hemisphere in the global climate system. Planned collaboration with other WAIS Divide investigators will develop the longest and most detailed volcanic record from Antarctica ice cores. The broader impacts of this project include a contribution to enhancing our knowledge of the climate system. Such improvements in understanding of the global climate system and the ability to predict the magnitude and uncertainty of future changes are highly relevant to the global community. The project will support post-doctoral scientists and graduate students, including those from under-represented groups, will contribute to education, an help to train future scientists and promote diversity in research and education. Public outreach activities of this project will contribute to informal science education of school age children in the Eastern South Dakota region.
0538674<br/>Matsuoka<br/>This award supports a project to evaluate radio-echo intensities in the available SOAR ice-penetrating radar data along grids covering Lake Vostok, and along four regional tracks from Ridge B toward the lake. The project has two objectives; first, it will examine the upper surface of the lake and reflectors hypothesized to be a boundary between the meteoric and accreted ice. They will provide crucial knowledge on the dynamic evolution of the lake. Second, this project will examine a poorly understood echo-free zone within the deep ice in central East Antarctica. This zone may consist of distorted stagnant ice, while its upper boundary may be a shear zone. The SOAR radar data provide a unique resource to examine spatiotemporal water circulation patterns that should be understood in order to select the best direct-sampling strategy to the lake. The Vostok ice core provides a unique opportunity to do this work. First, the path effects, i.e. propagation loss and birefringence, will be derived at the ice-core site using ice temperature, chemistry, and fabric data. Second, lateral variations of the propagation loss will be estimated by tracking chemistry associated with radar-detected isochronous layers, and by inferring temperatures from an ice-flow model that can replicate those layers. Ice-fabric patterns will be inferred from anisotropy in the reflectivity at about 100 radar-track cross-over sites. In terms of broader impacts, a graduate student will be trained to interpret the radar data in the light of radar theory and glaciological context of Lake Vostok and summer workshops for K-12 teachers will be provided in Seattle and New York. This project will contribute to ongoing efforts to study Lake Vostok and will complement the site selection for a North Vostok ice core, which has been proposed by Russia and France as an IPY program.
This award supports a project to perform continuous microparticle concentration and size distribution measurements (using coulter counter and state-of-the-art laser detector methods), analysis of biologically relevant trace elements associated with microparticles (Fe, Zn, Co, Cd, Cu), and tephra measurements on the WAIS Divide ice core. This initial three-year project includes analysis of ice core spanning the instrumental (~1850-present) to mid- Holocene (~5000 years BP) period, with sample resolution ranging from subannual to decadal. The intellectual merit of the project is that it will help in establishing the relationships among climate, atmospheric aerosols from terrestrial and volcanic sources, ocean biogeochemistry, and greenhouse gases on several timescales which remain a fundamental problem in paleoclimatology. The atmospheric mineral dust plays an important but uncertain role in direct radiative forcing, and the microparticle datasets produced in this project will allow us to examine changes in South Pacific aerosol loading, atmospheric dynamics, and dust source area climate. The phasing of changes in aerosol properties within Antarctica, throughout the Southern Hemisphere, and globally is unclear, largely due to the limited number of annually dated records extending into the glacial period and the lack of a<br/>tephra framework to correlate records. The broader impacts of the proposed research are an interdisciplinary approach to climate science problems, and will contribute to several WAIS Divide science themes as well as the broader paleoclimate and oceanographic communities. Because the research topics have a large and direct societal relevance, the project will form a centerpiece of various outreach efforts at UMaine and NMT including institution websites, public speaking, local K-12 school interaction, media interviews and news releases, and popular literature. At least one PhD student and one MS student will be directly supported by this project, including fieldwork, core processing, laboratory analysis, and data interpretation/publication. We expect that one graduate student per year will apply for a core handler/assistant driller position through the WAIS Divide Science Coordination Office, and that undergraduate student involvement will result in several Capstone experience projects (a UMaine graduation requirement). Data and ideas generated from the project will be integrated into undergraduate and graduate course curricula at both institutions.
Cole-Dai<br/>0538553<br/><br/>This award supports a project that will contribute to the US West Antarctica Ice Sheet Ice Divide ice core (WAIS Divide) project by developing new instrumentation and analytical procedures to measure concentrations of major ions (Cl-, NO3-, SO42-, Na+, K+, NH4+, Mg2+, Ca2+). A melter-based, continuous flow, multi-ion-chromatograph technique (CFA-IC) has been developed recently at South Dakota State University (SDSU). This project will further expand and improve the CFA-IC technique and instrumentation and develop procedures for routine analysis of major ions in ice cores. In addition, training of personnel (operators) to perform continuous, high resolution major ion analysis of the deep core will be accomplished through this project. The temporal resolution of the major ion measurement will be as low as 0.5 cm with the fully developed CFA-IC technique. At this resolution, it will be possible to use annual cycles of sulfate and sea-salt ion concentrations to determine annual layers in the WAIS Divide ice core. Annual layer counting using CFA-IC chemical measurements and other high resolution measurements will contribute significantly to the major WAIS Divide project objective of producing precisely (i.e., annually) dated climate records. The project will support the integration of research and education, train future scientists and promote human resource development through the participation of graduate and undergraduate students. In particular, undergraduate participation will contribute to a current REU (Research Experience for Undergraduates) chemistry site program at SDSU. Development and utilization of multi-user instrumentation will promote research collaboration and advance environmental science. NSF support for SDSU will contribute to the economic development and strengthen the infrastructure for research and education in South Dakota.
This award supports a project to examine an existing ice core of opportunity from South Pole (SPRESO core) to develop a 2000+ year long climate record. SPRESO ice core will be an annually dated, sub-annually-resolved reconstruction of past climate (atmospheric circulation, temperature, precipitation rate, and atmospheric chemistry) utilizing continuous, co-registered measurements (n=45) of: major ions, trace elements, and stable isotope series, plus selected sections for microparticle size and composition. The intellectual merit of this project relates to the fact that few 2000+ year records of this quality exist in Antarctica despite increasing scientific interest in this critical time period as the framework within which to understand modern climate. The scientific impact of this ice core investigation are that it will provide an in-depth understanding of climate variability; a baseline for assessing modern climate variability in the context of human activity; and a contribution to the prediction of future climate variability. The broader impact of this work is that the proposed research addresses important questions concerning the role of Antarctica in past, present, and future global change. Results will be translated into publicly accessible information through public lectures, media appearances, and an extensive outreach activity housed in our Institute. Our ice core activities provide a major basis for curriculum in K-12 and University plus a basis for several field and laboratory based graduate theses and undergraduate student projects. The project will support one PhD student for 3 years and undergraduate salaries. The Climate Change Institute has a long history of gender and ethnically diverse student and staff involvement in research.
This award is for support for three years of funding to study the effects of impurities on the flow of poly-<br/>crystalline ice. It has been known for thirty years that both hydrofluoric acid (HF) and hydrochloric acid (HCl) dramatically decrease the strength of ice and recent work by the author's group has shown that sulfuric acid (H2SO4) produces a similar reduction in strength. However, these data are for single crystals at strain rates and stresses that far exceed those found in glaciers and ice sheets, and often at concentrations that far exceed those in natural ice. Therefore, it is not known how impurities found in nature affect the flow of polycrystalline ice at slow strain rates. In this research, the effects of nitric acid and sulfuric acid (which are naturally occurring impurities in ice) on the microstructure (dislocation structure, grain boundary structure and location of the acids) and creep of polycrystalline ice (at a range of temperatures and stresses) will be determined. The ice's response to creep deformation will be studied using a combination of x-ray topography, optical microscopy and scanning electron microscopy. X-ray microanalysis in an environmental scanning electron microscope will be used to study the location of impurities. The structure and creep behavior of the acid-doped ice will be compared with those of both high-purity laboratory-grown ice and ice from Byrd Station, Antarctica. The end-result of this project will be to elucidate the effects of naturally-occurring acid impurities on the mechanical properties of polycrystalline ice under conditions relevant to the deformation of glaciers and ice sheets, including and understanding of how impurities affect the underlying deformation mechanisms.
Photochemical reactions in snow can have important effects on the chemistry and composition of the snowpack as well as the overlying atmosphere. For example, recent measurements in the Antarctic and Arctic have revealed that sunlit snow releases a number of important pollutants to the atmosphere. Our ability to understand and model this chemistry is currently limited, in part because we lack fundamental photochemical information for a number of important chemical species in snow. This award supports research that will help fill this gap by characterizing the low-temperature photochemistry of three of these key species: nitrite (NO2-), nitrous acid (HNO2), and hydrogen peroxide (HOOH). We will measure quantum yields for these reactions on ice using a sensitive technique that we recently developed during a study of nitrate (NO3-) photochemistry. In addition to this basic research, we will also measure the rates of formation of hydroxyl radical (OH), nitrogen oxides (NOx), and HOOH in illuminated Antarctic snow samples. These measurements will be important inputs for future models, and will allow us to test whether known species (e.g., NO3-, NO2- and HNO2) are responsible for most of snowpack reactivity (e.g., OH formation). Overall, results from this award will significantly improve our ability to understand snowpack chemistry, and the resulting effects on the atmosphere, both in the Antarctic as well as in the many other regions with permanent or seasonal snow. These results will also strengthen efforts to use ice core records to monitor global change. In addition to these impacts, this award will help train students and a postdoctoral fellow, and results from this work will be integrated into two classes in order to expose students to some of the important issues facing polar regions.
This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.
This award supports a three-year renewal project to complete measurement of cosmogenic nuclides in the Siple Dome ice core as part of the West Antarctic ice core program. The investigators will continue to measure profiles of Beryllium-10 (half-life = 1.5x10 6 years) and Chlorine-36 (half-life = 3.0x10 5 years) in the entire ice core which spans the time period from the present to about 100 kyr. It will be particularly instructive to compare the Antarctic record with the detailed Arctic record that was measured by these investigators as part of the GISP2 project. This comparison will help separate global from local effects at the different drill sites. Cosmogenic radionuclides in polar ice cores have been used to study the long-term variations in several important geophysical variables, including solar activity, geomagnetic field strength, atmospheric circulation, snow accumulation rates, and others. The time series of nuclide concentrations resulting from this work will be applied to several problem areas: perfecting the ice core chronology, deducing the history of solar activity, deducing the history of variations in the geomagnetic field, and studying the possible role of solar variations on climate. Comparison of Beryllium-10 and Chlorine-36 profiles in different cores will allow us to improve the ice core chronology and directly compare ice cores from different regions of the globe. Additional comparison with the Carbon-14 record will allow correlation of the ice core paleoenvironment record to other, Carbon-14 dated, paleoclimate records.
9316564 Mayewski This award is for support for a three year program to provide a high resolution record of the Antarctic climate through the acquisition, analysis, and interpretation of records of atmospheric chemical deposition taken from three ice cores located at sites within or immediately adjacent to the Ross Ice Drainage System (RIDS). These cores include one from Taylor Dome, and two from West Antarctic locations identified as potential deep drilling sites for the WAISCORES program. Collection of the two West Antarctic cores is intended to be a lightweight dry-drilling operation to depths of ~ 200 m, which will provide records of > 2 kyr. Glaciochemical analyses will focus on the major cations and anions found in the antarctic atmosphere, plus methanesulfonic acid and selected measurements of the hydrogen ion, aluminum, iron, and silica. These analyses, and companion stable isotope and particle measurements to be carried out by other investigators require < 7% by volume of each core, leaving > 90% for other investigators and storage at the U.S. National Ice Core Laboratory. These records are intended to solve a variety of scientific objectives while also providing spatial sampling and reconnaissance for future U.S. efforts in West Antarctica. ***
This award supports a two year project to analyze shallow (~150 m) ice cores from South Pole in order to construct an annually resolved, sulfate-based volcanic record covering the last 1400 years. Two shallow ice cores will be recovered at the South Pole during the 00/01 field season and will be used for this work. Volcanic records from polar ice cores provide valuable information for studies of the connection between volcanism and climate. The new records are expected to be continuous and to cover at least the last 1400 years. The information from these records will verify the volcanic events found in the few existing Antarctic records and resolve discrepancies in the timing and magnitude of major explosive eruptions <br/>determined from those earlier records. In order to achieve the objectives of the proposed research, funds are provided to assist with the construction of an analytical laboratory for ice core and environmental <br/>chemistry research.