USAP-DC

{"dp_type": "Project", "free_text": "Ion Chemistry"}

[{"awards": "0839066 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Major Ion Chemistry Data of WAIS Divide Ice Core Brittle Ice", "datasets": [{"dataset_uid": "609546", "doi": "10.7265/N5RF5S0D", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; WAIS Divide; WAIS Divide Ice Core", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Major Ion Chemistry Data of WAIS Divide Ice Core Brittle Ice", "url": "https://www.usap-dc.org/view/dataset/609546"}], "date_created": "Wed, 19 Mar 2014 00:00:00 GMT", "description": "Cole-Dai/0839066\u003cbr/\u003e\u003cbr/\u003eThis award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to make continuous major ion analyses in the West Antarctica Ice Sheet Divide (WAIS Divide) ice core by sampling the brittle ice zone (approximately from 500 m to 1500 m). The intellectual merit of the project is that these will likely be the only chemical measurements on the brittle ice zone and, therefore, will bridge the gap in the expected continuous records of climate, ice sheet dynamics and biological evolution based on chemical measurements. High resolution sampling and analysis, probably on selected portions and depth intervals in the brittle ice zone, will help with the independent, high-precision dating of the WAIS Divide core and contribute to the achievement of the major objectives of the WAIS Divide project?development of high resolution climate records with which to investigate issues of climate forcing by greenhouse gases and the role of Antarctica and Southern Hemisphere in the global climate system. Planned collaboration with other WAIS Divide investigators will develop the longest and most detailed volcanic record from Antarctica ice cores. The broader impacts of this project include a contribution to enhancing our knowledge of the climate system. Such improvements in understanding of the global climate system and the ability to predict the magnitude and uncertainty of future changes are highly relevant to the global community. The project will support post-doctoral scientists and graduate students, including those from under-represented groups, will contribute to education, an help to train future scientists and promote diversity in research and education. Public outreach activities of this project will contribute to informal science education of school age children in the Eastern South Dakota region.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Paleoclimate; LABORATORY; Ions; GROUND-BASED OBSERVATIONS; WAISCORES; Ion Chromatograph; Not provided; Ice Core", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "NOT APPLICABLE", "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Major Ion Chemical Analysis of Brittle Ice in the WAIS Divide Ice Core", "uid": "p0000047", "west": null}, {"awards": "0538553 Cole-Dai, Jihong", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Major Ion Concentrations in WDC05Q and WDC06A Ice Cores (WAIS Divide)", "datasets": [{"dataset_uid": "609544", "doi": "10.7265/N54M92H3", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; WAIS Divide; WAIS Divide Ice Core", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Major Ion Concentrations in WDC05Q and WDC06A Ice Cores (WAIS Divide)", "url": "https://www.usap-dc.org/view/dataset/609544"}], "date_created": "Wed, 25 Aug 2010 00:00:00 GMT", "description": "Cole-Dai\u003cbr/\u003e0538553\u003cbr/\u003e\u003cbr/\u003eThis award supports a project that will contribute to the US West Antarctica Ice Sheet Ice Divide ice core (WAIS Divide) project by developing new instrumentation and analytical procedures to measure concentrations of major ions (Cl-, NO3-, SO42-, Na+, K+, NH4+, Mg2+, Ca2+). A melter-based, continuous flow, multi-ion-chromatograph technique (CFA-IC) has been developed recently at South Dakota State University (SDSU). This project will further expand and improve the CFA-IC technique and instrumentation and develop procedures for routine analysis of major ions in ice cores. In addition, training of personnel (operators) to perform continuous, high resolution major ion analysis of the deep core will be accomplished through this project. The temporal resolution of the major ion measurement will be as low as 0.5 cm with the fully developed CFA-IC technique. At this resolution, it will be possible to use annual cycles of sulfate and sea-salt ion concentrations to determine annual layers in the WAIS Divide ice core. Annual layer counting using CFA-IC chemical measurements and other high resolution measurements will contribute significantly to the major WAIS Divide project objective of producing precisely (i.e., annually) dated climate records. The project will support the integration of research and education, train future scientists and promote human resource development through the participation of graduate and undergraduate students. In particular, undergraduate participation will contribute to a current REU (Research Experience for Undergraduates) chemistry site program at SDSU. Development and utilization of multi-user instrumentation will promote research collaboration and advance environmental science. NSF support for SDSU will contribute to the economic development and strengthen the infrastructure for research and education in South Dakota.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "LABORATORY; WAIS Divide; Ice Core; West Antarctic Ice Sheet; Ion Chromatograph; GROUND-BASED OBSERVATIONS; Not provided; Major Ion; Ions", "locations": "WAIS Divide; West Antarctic Ice Sheet", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Major Ion Chemistry of WAIS Divide Ice Core", "uid": "p0000035", "west": -112.085}, {"awards": "0125761 Thiemens, Mark", "bounds_geometry": null, "dataset_titles": "Atmospheric Nitrate Isotopic Analysis at Amundsen-Scott South Pole Station, A Twenty-Five Year Record", "datasets": [{"dataset_uid": "609281", "doi": "10.7265/N5TT4NWF", "keywords": "Aerosol; Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; NBP1502; Snow/ice; Snow/Ice; South Pole Station", "people": "Savarino, Joel; Thiemens, Mark H.", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric Nitrate Isotopic Analysis at Amundsen-Scott South Pole Station, A Twenty-Five Year Record", "url": "https://www.usap-dc.org/view/dataset/609281"}], "date_created": "Tue, 27 Dec 2005 00:00:00 GMT", "description": "This award supports a detailed laboratory analysis of the mass-independent isotopic composition of processes associated with atmospheric nitrate trapped in the snow pack at the South Pole. The project will specifically test if the oxygen isotopes 16O, 17O, 18O of nitrate can be used to probe the denitrification of the Antarctic stratosphere. Despite decades of research, there are several important issues in Antarctic atmospheric science, which are presently inadequately resolved. This includes quantification over time of the sources of nitrate aerosols. Today, little is known about the past denitrification of the stratosphere in high latitude regions. This lack of knowledge significantly limits our ability to understand the chemical state of ancient atmospheres and therefore evaluate present and past-coupled climate/atmosphere models. The role of nitrogen in environmental degradation is well known. This issue will also be addressed in this proposal. Atmospheric aerosols have now been shown to possess a mass-independent oxygen isotopic content. The proposed research will investigate the stable oxygen isotope ratios of nitrate in Antarctica both collected in real time and from the snow. Two periods of time will be covered. Full year nitrate aerosol collections, with week resolution time horizons, will be performed at the South Pole. Weekly aerosol collections will help us to identify any seasonal trend of the oxygen-17 excess anomaly, and eventually link this anomaly to the denitrification of the Antarctic stratosphere. This data set will also be used to test our assumption that the oxygen isotopic anomaly of nitrate is mainly formed in the stratosphere and is well preserved in the snow pack. If true, we will for the first time resolve an atmospheric signal extracted from a nitrate profile. The snow pit will allow us to see any trend in the data on a multiple decade timescale.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Snow; GROUND STATIONS; Ion Chemistry; South Pole; Not provided; Aerosol; Oxygen Isotope; GROUND-BASED OBSERVATIONS; Snow Pit; Antarctica; Admundsen-Scott Station", "locations": "Antarctica; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Savarino, Joel; Thiemens, Mark H.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "South Pole Atmospheric Nitrate Isotopic Analysis (SPANIA)", "uid": "p0000242", "west": null}, {"awards": "0087151 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Sulfate-Based Volcanic Record from South Pole Ice Core", "datasets": [{"dataset_uid": "609215", "doi": "10.7265/N5CR5R88", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Solid Earth; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Sulfate-Based Volcanic Record from South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609215"}], "date_created": "Fri, 09 Apr 2004 00:00:00 GMT", "description": "This award supports a two year project to analyze shallow (~150 m) ice cores from South Pole in order to construct an annually resolved, sulfate-based volcanic record covering the last 1400 years. Two shallow ice cores will be recovered at the South Pole during the 00/01 field season and will be used for this work. Volcanic records from polar ice cores provide valuable information for studies of the connection between volcanism and climate. The new records are expected to be continuous and to cover at least the last 1400 years. The information from these records will verify the volcanic events found in the few existing Antarctic records and resolve discrepancies in the timing and magnitude of major explosive eruptions \u003cbr/\u003edetermined from those earlier records. In order to achieve the objectives of the proposed research, funds are provided to assist with the construction of an analytical laboratory for ice core and environmental \u003cbr/\u003echemistry research.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core; Snow Chemistry; West Antarctica; GROUND-BASED OBSERVATIONS; Antarctica; Ice Core Gas Records; Ion Chemistry; Ice Core Data", "locations": "West Antarctica; Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "A Sulfate-based Volcanic Record from South Pole Ice Cores", "uid": "p0000167", "west": null}, {"awards": "9526449 Mayewski, Paul", "bounds_geometry": null, "dataset_titles": "WAISCORES Snow Pit Chemistry, Antarctica", "datasets": [{"dataset_uid": "609420", "doi": "10.7265/N5SQ8XBR", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; Snow Pit; WAIS; WAISCORES", "people": "Mayewski, Paul A.; Kreutz, Karl", "repository": "USAP-DC", "science_program": null, "title": "WAISCORES Snow Pit Chemistry, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609420"}], "date_created": "Thu, 11 Jul 2002 00:00:00 GMT", "description": "This award is for support for a program of glaciochemical analyses of shallow and deep ice cores from Siple Dome, West Antarctica. Measurements that have been proposed include chloride, nitrate, sulfate, calcium, magnesium, sodium, potassium, ammonium and methansulfonic acid. These measurements will provide information about past volcanic events, biomass source strength, sea ice fluctuations, atmospheric circulation, changes in ice-free areas and the environmental response to Earth orbit insolation changes and solar variability. The glaciochemical records from the Siple Dome core will be developed at a resolution sufficient to compare with the Summit, Greenland record, thus allowing a bipolar comparison of climate change event timing and magnitude. As part of this award, an international workshop will be held during the first year to formulate a science plan for the International Transantarctic Scientific Expedition (ITASE), a program of regional surveys documenting the spatial distribution of properties measured in ice cores .", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "Ion Chemistry; Antarctic; Snow Chemistry; Stable Isotopes; Snow Density; Siple Dome; GROUND-BASED OBSERVATIONS", "locations": "Antarctic; Siple Dome", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Kreutz, Karl; Mayewski, Paul A.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Siple Dome Deep Ice Core Glaciochemistry and Regional Survey - A Contribution to the WAIS Initiative", "uid": "p0000012", "west": null}]

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