USAP-DC

{"dp_type": "Project", "free_text": "Gas Age"}

[{"awards": "1745078 Brook, Edward J.", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ; Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation; Carbon-13 and Deuterium isotopic composition of atmospheric methane across Heinrich Stadial 4, and Dansgaard Oesgher Event 8, WAIS Divide Replicate Ice Core, Antarctica; Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "datasets": [{"dataset_uid": "601737", "doi": "10.15784/601737", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Ice Core Records; Methane; West Antarctic Ice Sheet", "people": "Edwards, Jon S.; Rosen, Julia; Martin, Kaden; Lee, James; Riddell-Young, Benjamin; Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ", "url": "https://www.usap-dc.org/view/dataset/601737"}, {"dataset_uid": "601736", "doi": "10.15784/601736", "keywords": "Antarctica; Greenland; Methane; Paleoclimate; West Antarctic Ice Sheet", "people": "Brook, Edward J.; Edwards, Jon S.; Lee, James; Martin, Kaden; Blunier, Thomas; Fischer, Hubertus; Schmitt, Jochen; Rosen, Julia; Buizert, Christo; Riddell-Young, Benjamin; M\u00fchl, Michaela", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601736"}, {"dataset_uid": "601813", "doi": "10.15784/601813", "keywords": "Abrupt Climate Change; Antarctica; Atmospheric Gases; Biogeochemical Cycles; Carbon Cycle; Cryosphere; Greenhouse Gas; Methane; West Antarctic Ice Sheet Divide", "people": "Bauska, Thomas; Brook, Edward J.; Clark, Reid; Iseli, Rene; Menking, Andy; Fischer, Hubertus; Schmitt, Jochen; Lee, James; Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Carbon-13 and Deuterium isotopic composition of atmospheric methane across Heinrich Stadial 4, and Dansgaard Oesgher Event 8, WAIS Divide Replicate Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601813"}, {"dataset_uid": "601683", "doi": "10.15784/601683", "keywords": "Antarctica; Methane; West Antarctic Ice Sheet", "people": "Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601683"}], "date_created": "Mon, 01 May 2023 00:00:00 GMT", "description": "This project will develop methods to measure the ratios of carbon-13 to carbon-12, and heavy to light hydrogen in methane in air trapped in ice cores. The ratios of the different forms of carbon and hydrogen are \"fingerprints\" of different sources of this gas in the past--for example wetlands in the tropics versus methane frozen in the sea floor. Once the analysis method is developed, the measurements will be used to examine why methane changed abruptly in the past, both during the last ice age, and during previous warm periods. The data will be used to understand how methane sources like wildfires, methane hydrates, and wetlands respond to climate change. This information is needed to understand future risks of large changes in methane in the atmosphere as Earth warms. The project involves two tasks. First, the investigators will build and test a gas extraction system for methane isotopic measurements using continuous flow methods, with the goal of equaling or bettering the precision attained by the few other laboratories that make these measurements. The system will be interfaced with existing mass spectrometers at Oregon State University. The system consists of a vacuum chamber and sequence of traps, purification columns, and furnaces that separate methane from other gases and convert it to carbon dioxide or hydrogen for mass spectrometry. Second, the team will measure the isotopic composition of methane across large changes in concentration associated with two past interglacial periods and during abrupt methane changes of the last ice age. These measurements will be used to understand if the main reason for these concentration changes is climate-driven changes in emissions from wetlands, or whether other sources are involved, for example methane hydrates or wildfires. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Antarctic Ice Sheet; TRACE GASES/TRACE SPECIES; METHANE", "locations": "Antarctic Ice Sheet", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Tracing Past Methane Variations with Stable Isotopes in Antarctic Ice Cores", "uid": "p0010416", "west": -180.0}, {"awards": "1643722 Brook, Edward J.", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole Ice Core Methane Data and Gas Age Time Scale; South Pole ice core (SPC14) total air content (TAC)", "datasets": [{"dataset_uid": "601329", "doi": "10.15784/601329", "keywords": "Antarctica; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; South Pole", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Methane Data and Gas Age Time Scale", "url": "https://www.usap-dc.org/view/dataset/601329"}, {"dataset_uid": "601546", "doi": "10.15784/601546", "keywords": "Antarctica; South Pole", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) total air content (TAC)", "url": "https://www.usap-dc.org/view/dataset/601546"}], "date_created": "Tue, 02 Jun 2020 00:00:00 GMT", "description": "Brook/1643722 This award supports a project to measure the concentration of the gas methane in air trapped in an ice core collected from the South Pole. The data will provide an age scale (age as a function of depth) by matching the South Pole methane changes with similar data from other ice cores for which the age vs. depth relationship is well known. The ages provided will allow all other gas measurements made on the South Pole core (by the PI and other NSF supported investigators) to be interpreted accurately as a function of time. This is critical because a major goal of the South Pole coring project is to understand the history of rare gases in the atmosphere like carbon monoxide, carbon dioxide, ethane, propane, methyl chloride, and methyl bromide. Relatively little is known about what controls these gases in the atmosphere despite their importance to atmospheric chemistry and climate. Undergraduate assistants will work on the project and be introduced to independent research through their work. The PI will continue visits to local middle schools to introduce students to polar science, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) as part of the project. Methane concentrations from a major portion (2 depth intervals, excluding the brittle ice-zone which is being measured at Penn State University) of the new South Pole ice core will be used to create a gas chronology by matching the new South Pole ice core record with that from the well-dated WAIS Divide ice core record. In combination with measurements made at Penn State, this will provide gas dating for the entire 50,000-year record. Correlation will be made using a simple but powerful mid-point method that has been previously demonstrated, and other methods of matching records will be explored. The intellectual merit of this work is that the gas chronology will be a fundamental component of this ice core project, and will be used by the PI and other investigators for dating records of atmospheric composition, and determining the gas age-ice age difference independently of glaciological models, which will constrain processes that affected firn densification in the past. The methane data will also provide direct stratigraphic markers of important perturbations to global biogeochemical cycles (e.g., rapid methane variations synchronous with abrupt warming and cooling in the Northern Hemisphere) that will tie other ice core gas records directly to those perturbations. A record of the total air content will also be produced as a by-product of the methane measurements and will contribute to understanding of this parameter. The broader impacts include that the work will provide a fundamental data set for the South Pole ice core project and the age scale (or variants of it) will be used by all other investigators working on gas records from the core. The project will employ an undergraduate assistant(s) in both years who will conduct an undergraduate research project which will be part of the student\u0027s senior thesis or other research paper. The project will also offer at least one research position for the Oregon State University Summer REU site program. Visits to local middle schools, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) will also be part of the project.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "AMD; LABORATORY; METHANE; ICE CORE RECORDS; Gas Chromatography; South Pole; USAP-DC", "locations": "South Pole", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "A High Resolution Atmospheric Methane Record from the South Pole Ice Core", "uid": "p0010102", "west": 0.0}, {"awards": "1443710 Severinghaus, Jeffrey; 1443472 Brook, Edward J.; 1443464 Sowers, Todd", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole CH4 data for termination; South Pole Ice Core Isotopes of N2 and Ar; South Pole ice core (SPC14) discrete methane data; South Pole ice core total air content; South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2; SP19 Gas Chronology", "datasets": [{"dataset_uid": "601517", "doi": "10.15784/601517", "keywords": "Antarctica; Argon; Argon Isotopes; Firn; Firn Temperature Gradient; Firn Thickness; Gas Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Nitrogen; Nitrogen Isotopes; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.; Morgan, Jacob", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Isotopes of N2 and Ar", "url": "https://www.usap-dc.org/view/dataset/601517"}, {"dataset_uid": "601230", "doi": "10.15784/601230", "keywords": "Antarctica; Atmospheric CH4; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Data; Methane; Methane Concentration; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole CH4 data for termination", "url": "https://www.usap-dc.org/view/dataset/601230"}, {"dataset_uid": "601231", "doi": "10.15784/601231", "keywords": "Air Content; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core total air content", "url": "https://www.usap-dc.org/view/dataset/601231"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Winski, Dominic A.; Epifanio, Jenna; Brook, Edward J.; Buizert, Christo; Kreutz, Karl; Aydin, Murat; Edwards, Jon S.; Sowers, Todd A.; Kahle, Emma; Steig, Eric J.; Osterberg, Erich; Fudge, T. J.; Hood, Ekaterina; Kalk, Michael; Ferris, David G.; Kennedy, Joshua A.; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601152", "doi": "10.15784/601152", "keywords": "Antarctica; Antarctic Ice Sheet; Chemistry:gas; Chemistry:Gas; Chemistry:ice; Chemistry:Ice; Delta 18O; Dole Effect; Firn Thickness; Gas Isotopes; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Gravitational Settling; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Inert Gases; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2", "url": "https://www.usap-dc.org/view/dataset/601152"}], "date_created": "Sat, 02 Feb 2019 00:00:00 GMT", "description": "Gases trapped in ice cores have revealed astonishing things about the greenhouse gas composition of the past atmosphere, including the fact that carbon dioxide concentrations never rose above 300 parts per million during the last 800,000 years. This places today\u0027s concentration of 400 parts per million in stark contrast. Furthermore, these gas records show that natural sources of greenhouse gas such as oceans and ecosystems act as amplifiers of climate change by increasing emissions of gases during warmer periods. Such amplification is expected to occur in the future, adding to the human-produced gas burden. The South Pole ice core will build upon these prior findings by expanding the suite of gases to include, for the first time, those potent trace gases that both trapped heat and depleted ozone during the past 40,000 years. The present project on inert gases and methane in the South Pole ice core will improve the dating of this crucial record, to unprecedented precision, so that the relative timing of events can be used to learn about the mechanism of trace gas production and destruction, and consequent climate change amplification. Ultimately, this information will inform predictions of future atmospheric chemical cleansing mechanisms and climate in the context of our rapidly changing atmosphere. This award also engages young people in the excitement of discovery and polar research, helping to entrain the next generations of scientists and educators. Education of graduate students, a young researcher (Buizert), and training of technicians, will add to the nation?s human resource base. This award funds the construction of the gas chronology for the South Pole 1500m ice core, using measured inert gases (d15N and d40Ar--Nitrogen and Argon isotope ratios, respectively) and methane in combination with a next-generation firn densification model that treats the stochastic nature of air trapping and the role of impurities on densification. The project addresses fundamental gaps in scientific understanding that limit the accuracy of gas chronologies, specifically a poor knowledge of the controls on ice-core d15N and the possible role of layering and impurities in firn densification. These gaps will be addressed by studying the gas enclosure process in modern firn at the deep core site. The work will comprise the first-ever firn air pumping experiment that has tightly co-located measurements of firn structural properties on the core taken from the same borehole. The project will test the hypothesis that the lock-in horizon as defined by firn air d15N, CO2, and methane is structurally controlled by impermeable layers, which are in turn created by high-impurity content horizons in which densification is enhanced. Thermal signals will be sought using the inert gas measurements, which improve the temperature record with benefits to the firn densification modeling. Neon, argon, and oxygen will be measured in firn air and a limited number of deep core samples to test whether glacial period layering was enhanced, which could explain low observed d15N in the last glacial period. Drawing on separate volcanic and methane synchronization to well-dated ice cores to create independent ice and gas tie points, independent empirical estimates of the gas age-ice age difference will be made to check the validity of the firn densification model-inert gas approach to calculating the gas age-ice age difference. These points will also be used to test whether the anomalously low d15N seen during the last glacial period in east Antarctic ice cores is due to deep air convection in the firn, or a missing impurity dependence in the firn densification models. The increased physical understanding gained from these studies, combined with new high-precision measurements, will lead to improved accuracy of the gas chronology of the South Pole ice core, which will enhance the overall science return from this gas-oriented core. This will lead to clarification of timing of atmospheric gas variations and temperature, and aid in efforts to understand the biogeochemical feedbacks among trace gases. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. Ozone-depleting substances will be measured in the South Pole ice core record, and a precise gas chronology will add value. Lastly, by seeking a better understanding of the physics of gas entrapment, the project aims to have an impact on ice-core science in general.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "USAP-DC; AMD; LABORATORY; Antarctica; NITROGEN ISOTOPES; USA/NSF; METHANE; Amd/Us; FIELD INVESTIGATION", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Sowers, Todd A.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Inert Gas and Methane Based Climate Records throughout the South Pole Deep Ice Core", "uid": "p0010005", "west": 0.0}, {"awards": "0944021 Brook, Edward J.; 0944307 Conway, Howard; 0943466 Hawley, Robert", "bounds_geometry": "POLYGON((-163 -79,-162.8 -79,-162.6 -79,-162.4 -79,-162.2 -79,-162 -79,-161.8 -79,-161.6 -79,-161.4 -79,-161.2 -79,-161 -79,-161 -79.05,-161 -79.1,-161 -79.15,-161 -79.2,-161 -79.25,-161 -79.3,-161 -79.35,-161 -79.4,-161 -79.45,-161 -79.5,-161.2 -79.5,-161.4 -79.5,-161.6 -79.5,-161.8 -79.5,-162 -79.5,-162.2 -79.5,-162.4 -79.5,-162.6 -79.5,-162.8 -79.5,-163 -79.5,-163 -79.45,-163 -79.4,-163 -79.35,-163 -79.3,-163 -79.25,-163 -79.2,-163 -79.15,-163 -79.1,-163 -79.05,-163 -79))", "dataset_titles": "Roosevelt Island Borehole Firn temperatures; Roosevelt Island Borehole Optical Televiewer logs; Roosevelt Island Ice Core Time Scale and Associated Data; Roosevelt Island: Radar and GPS", "datasets": [{"dataset_uid": "601085", "doi": "10.15784/601085", "keywords": "Antarctica; Borehole; Firn; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Records; Ice Fabric; Optical Images; Roosevelt Island; Snow/ice; Snow/Ice; Temperature", "people": "Hawley, Robert L.; Clemens-Sewall, David; Giese, Alexandra", "repository": "USAP-DC", "science_program": null, "title": "Roosevelt Island Borehole Firn temperatures", "url": "https://www.usap-dc.org/view/dataset/601085"}, {"dataset_uid": "601359", "doi": "10.15784/601359", "keywords": "Antarctica; CO2; Ice Core; Roosevelt Island", "people": "Lee, James; Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "Roosevelt Island Ice Core Time Scale and Associated Data", "url": "https://www.usap-dc.org/view/dataset/601359"}, {"dataset_uid": "601070", "doi": "10.15784/601070", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; GPR; GPS Data; Ice Velocity; Navigation; Radar; Roosevelt Island; Ross Sea", "people": "Conway, Howard", "repository": "USAP-DC", "science_program": null, "title": "Roosevelt Island: Radar and GPS", "url": "https://www.usap-dc.org/view/dataset/601070"}, {"dataset_uid": "601086", "doi": "10.15784/601086", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Roosevelt Island; Snow/ice; Snow/Ice", "people": "Clemens-Sewall, David; Hawley, Robert L.", "repository": "USAP-DC", "science_program": null, "title": "Roosevelt Island Borehole Optical Televiewer logs", "url": "https://www.usap-dc.org/view/dataset/601086"}], "date_created": "Fri, 16 Feb 2018 00:00:00 GMT", "description": "This award supports a project to use the Roosevelt Island ice core as a glaciological dipstick for the eastern Ross Sea. Recent attention has focused on the eastern Ross Embayment, where there are no geological constraints on ice thickness changes, due to the lack of protruding rock \"dipsticks\" where the ice sheet can leave datable records of high stands. Recent work has shown how dated ice cores can be used as dipsticks to derive ice-thickness histories. Partners from New Zealand and Denmark will extract an ice core from Roosevelt Island during the 2010-2011 and 2011-12 austral summers. Their science objective is to contribute to understanding of climate variability over the past 40kyr. The science goal of this project is not the climate record, but rather the history of deglaciation in the Ross Sea. The new history from the eastern Ross Sea will be combined with the glacial histories from the central Ross Sea (Siple Dome and Byrd) and existing and emerging histories from geologic and marine records along the western Ross Sea margin and will allow investigators to establish an updated, self-consistent model of the configuration and thickness of ice in the Ross Embayment during the LGM, and the timing of deglaciation. Results from this work will provide ground truth for new-generation ice-sheet models that incorporate ice streams and fast-flow dynamics. Realistic ice-sheet models are needed not only for predicting the response to future possible environments, but also for investigating past behaviors of ice sheets. This research contributes to the primary goals of the West Antarctic Ice Sheet Initiative as well as the IPY focus on ice-sheet history and dynamics. It also contributes to understanding spatial and temporal patterns of climate change and climate dynamics over the past 40kyr, one of the primary goals of the International Partnerships in Ice Core Sciences (IPICS). The project will help to develop the next generation of scientists and will contribute to the education and training of two Ph.D. students. All participants will benefit from the international collaboration, which will expose them to different field and laboratory techniques and benefit future collaborative work. All participants are involved in scientific outreach and undergraduate education, and are committed to fostering diversity. Outreach will be accomplished through regularly scheduled community and K-12 outreach events, talks and popular writing by the PIs, as well as through University press offices.", "east": -161.0, "geometry": "POINT(-162 -79.25)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "AMD; FIELD INVESTIGATION; Amd/Us; Deglaciation; USAP-DC; USA/NSF; NOT APPLICABLE; Ice Core; Not provided; Ross Sea Embayment", "locations": "Ross Sea Embayment", "north": -79.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Earth Sciences; Antarctic Glaciology; Antarctic Earth Sciences; Antarctic Glaciology; Antarctic Earth Sciences", "paleo_time": null, "persons": "Conway, Howard; Brook, Edward J.; Hawley, Robert L.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; Not provided; OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -79.5, "title": "Collaborative Research: Deglaciation of the Ross Sea Embayment - constraints from Roosevelt Island", "uid": "p0000272", "west": -163.0}, {"awards": "0944191 Taylor, Kendrick; 0944197 Waddington, Edwin", "bounds_geometry": "POLYGON((-180 -79,-173.3 -79,-166.6 -79,-159.9 -79,-153.2 -79,-146.5 -79,-139.8 -79,-133.1 -79,-126.4 -79,-119.7 -79,-113 -79,-113 -79.1,-113 -79.2,-113 -79.3,-113 -79.4,-113 -79.5,-113 -79.6,-113 -79.7,-113 -79.8,-113 -79.9,-113 -80,-119.7 -80,-126.4 -80,-133.1 -80,-139.8 -80,-146.5 -80,-153.2 -80,-159.9 -80,-166.6 -80,-173.3 -80,180 -80,150.9 -80,121.8 -80,92.7 -80,63.6 -80,34.5 -80,5.4 -80,-23.7 -80,-52.8 -80,-81.9 -80,-111 -80,-111 -79.9,-111 -79.8,-111 -79.7,-111 -79.6,-111 -79.5,-111 -79.4,-111 -79.3,-111 -79.2,-111 -79.1,-111 -79,-81.9 -79,-52.8 -79,-23.7 -79,5.4 -79,34.5 -79,63.6 -79,92.7 -79,121.8 -79,150.9 -79,-180 -79))", "dataset_titles": "Accumulation Rates from the WAIS Divide Ice Core; WAIS Divide Ice Core Electrical Conductance Measurements, Antarctica; WAIS Divide Multi Track Electrical Measurements; WD2014: Timescale for WAIS Divide Core 2006 A (WDC-06A)", "datasets": [{"dataset_uid": "601004", "doi": "10.15784/601004", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Snow Accumulation; WAIS Divide Ice Core", "people": "Waddington, Edwin D.; Buizert, Christo; Conway, Howard; Fudge, T. J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Accumulation Rates from the WAIS Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/601004"}, {"dataset_uid": "601172", "doi": "10.15784/601172", "keywords": "Antarctic; Antarctica; Electrical Conductivity; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Data; Ice Core Records; Physical Properties; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core; Wais Project; West Antarctic Ice Sheet", "people": "Taylor, Kendrick C.; Fudge, T. J.", "repository": "USAP-DC", "science_program": null, "title": "WAIS Divide Multi Track Electrical Measurements", "url": "https://www.usap-dc.org/view/dataset/601172"}, {"dataset_uid": "609591", "doi": "10.7265/N5B56GPJ", "keywords": "Antarctica; Electrical Conductivity; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Physical Properties; WAIS Divide; WAIS Divide Ice Core", "people": "Fudge, T. J.; Taylor, Kendrick C.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Ice Core Electrical Conductance Measurements, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609591"}, {"dataset_uid": "601015", "doi": "10.15784/601015", "keywords": "Antarctica; Depth-Age-Model; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WD2014: Timescale for WAIS Divide Core 2006 A (WDC-06A)", "url": "https://www.usap-dc.org/view/dataset/601015"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "This award supports a project to help to establish the depth-age chronology and the histories of accumulation and ice dynamics for the WAIS Divide ice core. The depth-age relationship and the histories of accumulation and ice dynamics are coupled. An accurate age scale is needed to infer histories of accumulation rate and ice-thickness change using ice-flow models. In turn, the accumulation-rate history is needed to calculate the age difference of ice to determine the age of the trapped gases. The accumulation history is also needed to calculate atmospheric concentrations of impurities trapped in the ice and is an important characteristic of climate. The history of ice-thickness change is also fundamental to understanding the stability of the WAIS. The primary goals of the WAIS Divide ice core project are to investigate climate forcing by greenhouse gases, the initiation of climate changes, and the stability of the West Antarctic Ice Sheet (WAIS). An accurate age scale is fundamental for achieving these goals. The first objective of this project is to establish an annually resolved depth-age relationship for the past 40,000 years. This will be done by measuring variations in electrical conductivity along the ice core, which are caused by seasonal variations in chemistry. We expect to be able to resolve annual layers back to 40,000 years before present (3,000 m depth) using this method. The second objective is to search for stratigraphic disturbances in the core that would compromise the paleoclimate record. Irregular layering will be identified by measuring the electrical conductivity of the ice in a vertical plan through the core. The third objective is to derive a preliminary chronology for the entire core. For the deeper ice we will use an ice-flow model to interpolate between known age markers, such as dated volcanic horizons and tie points from the methane gas chronology. The fourth objective is to derive a refined chronology simultaneously with histories of accumulation and ice-sheet thickness. An ice-flow model and all available data will be used to formulate an inverse problem, in which we infer the most appropriate histories of accumulation and ice-thickness, together with estimates of uncertainties. The flow model associated with those preferred histories then produces the best estimate of the chronology. The research contributes directly to the primary goals of the West Antarctic Ice Sheet Initiative. The project will help develop the next generation of scientists through the education and training of one Ph.D. student and several undergraduate students. This project will result in instrumentation for measuring the electrical conductivity of ice cores being available at the National Ice Core Lab for other researchers to use on other projects. All collaborators are committed to fostering diversity and currently participate in scientific outreach and most participate in undergraduate education. Outreach will be accomplished through regularly scheduled community and K-12 outreach events at UW, talks and popular writing by the PIs, as well as through our respective press offices.", "east": -111.0, "geometry": "POINT(-112 -79.5)", "instruments": null, "is_usap_dc": true, "keywords": "Ice Core Depth; National Ice Core Lab; Electrical Conductivity; FIELD INVESTIGATION; Not provided", "locations": null, "north": -79.0, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Glaciology; Antarctic Glaciology; Antarctic Earth Sciences", "paleo_time": null, "persons": "Conway, Howard; Fudge, T. J.; Taylor, Kendrick C.; Waddington, Edwin D.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -80.0, "title": "Collaborative Research: Establishing the Chronology and Histories of Accumulation and Ice Dynamics for the WAIS Divide Core", "uid": "p0000026", "west": -113.0}, {"awards": "1245659 Petrenko, Vasilii; 1246148 Severinghaus, Jeffrey; 1245821 Brook, Edward J.", "bounds_geometry": "POINT(162.167 -77.733)", "dataset_titles": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores; Last Interglacial Mean Ocean Temperature; Mean Ocean Temperature in Marine Isotope Stage 4; Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation; N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica; Taylor Glacier CO2 Isotope Data 74-59 kyr; Taylor Glacier Noble Gases - Younger Dryas; The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "datasets": [{"dataset_uid": "601176", "doi": "10.15784/601176", "keywords": "Antarctica; CO2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; Noble Gas; Noble Gas Isotopes; Snow/ice; Snow/Ice; Taylor Glacier; Younger Dryas", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Taylor Glacier Noble Gases - Younger Dryas", "url": "https://www.usap-dc.org/view/dataset/601176"}, {"dataset_uid": "601198", "doi": "10.15784/601198", "keywords": "Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; CO2; Dust; Gas; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Mass Spectrometer; Methane; Nitrogen Isotopes; Oxygen Isotope; Paleoclimate; Snow/ice; Snow/Ice; Taylor Dome; Taylor Dome Ice Core", "people": "Dyonisius, Michael; Menking, James; Brook, Edward J.; Marcott, Shaun; Barker, Stephen; Shackleton, Sarah; Petrenko, Vasilii; McConnell, Joseph; Rhodes, Rachel; Bauska, Thomas; Severinghaus, Jeffrey P.; Baggenstos, Daniel", "repository": "USAP-DC", "science_program": null, "title": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/601198"}, {"dataset_uid": "600163", "doi": "10.15784/600163", "keywords": "Antarctica; Atmosphere; Geochemistry; Ice Core Records; Isotope; Paleoclimate; Taylor Glacier; Transantarctic Mountains", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "url": "https://www.usap-dc.org/view/dataset/600163"}, {"dataset_uid": "601398", "doi": "10.15784/601398", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Gas Records; Ice Core Records; Marine Isotope Stage 4; MIS 4; Nitrous Oxide; Pleistocene; Taylor Dome Ice Core; Taylor Glacier", "people": "Severinghaus, Jeffrey P.; Menking, James; Brook, Edward J.; Schilt, Adrian; Shackleton, Sarah; Dyonisius, Michael; Petrenko, Vasilii", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601398"}, {"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "601600", "doi": "10.15784/601600", "keywords": "Antarctica; Taylor Glacier", "people": "Bauska, Thomas; Buffen, Aron; Brook, Edward J.; Shackleton, Sarah; Menking, James; Menking, Andy; Petrenko, Vasilii; Dyonisius, Michael; Severinghaus, Jeffrey P.; Barker, Stephen", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier CO2 Isotope Data 74-59 kyr", "url": "https://www.usap-dc.org/view/dataset/601600"}, {"dataset_uid": "601260", "doi": "10.15784/601260", "keywords": "Antarctica; Carbon-14; Cosmogenic; Ice Core; Methane", "people": "Dyonisius, Michael; Petrenko, Vasilii", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601260"}, {"dataset_uid": "601415", "doi": "10.15784/601415", "keywords": "Antarctica; Glaciology; Ice Core Data; Ice Core Records; Paleoclimate; Paleotemperature; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": null, "title": "Mean Ocean Temperature in Marine Isotope Stage 4", "url": "https://www.usap-dc.org/view/dataset/601415"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "1245659/Petrenko This award supports a project to use the Taylor Glacier, Antarctica, ablation zone to collect ice samples for a range of paleoenvironmental studies. A record of carbon-14 of atmospheric methane (14CH4) will be obtained for the last deglaciation and the Early Holocene, together with a supporting record of CH4 stable isotopes. In-situ cosmogenic 14C content and partitioning of 14C between different species (14CH4, C-14 carbon monoxide (14CO) and C-14 carbon dioxide (14CO2)) will be determined with unprecedented precision in ice from the surface down to ~67 m. Further age-mapping of the ablating ice stratigraphy will take place using a combination of CH4, CO2, \u0026#948;18O of oxygen gas and H2O stable isotopes. High precision, high-resolution records of CO2, \u0026#948;13C of CO2, nitrous oxide (N2O) and N2O isotopes will be obtained for the last deglaciation and intervals during the last glacial period. The potential of 14CO2 and Krypton-81 (81Kr) as absolute dating tools for glacial ice will be investigated. The intellectual merit of proposed work includes the fact that the response of natural methane sources to continuing global warming is uncertain, and available evidence is insufficient to rule out the possibility of catastrophic releases from large 14C-depleted reservoirs such as CH4 clathrates and permafrost. The proposed paleoatmospheric 14CH4 record will improve our understanding of the possible magnitude and timing of CH4 release from these reservoirs during a large climatic warming. A thorough understanding of in-situ cosmogenic 14C in glacial ice (production rates by different mechanisms and partitioning between species) is currently lacking. Such an understanding will likely enable the use of in-situ 14CO in ice at accumulation sites as a reliable, uncomplicated tracer of the past cosmic ray flux and possibly past solar activity, as well as the use of 14CO2 at both ice accumulation and ice ablation sites as an absolute dating tool. Significant gaps remain in our understanding of the natural carbon cycle, as well as in its responses to global climate change. The proposed high-resolution, high-precision records of \u0026#948;13C of CO2 would provide new information on carbon cycle changes both during times of rising CO2 in a warming climate and falling CO2 in a cooling climate. N2O is an important greenhouse gas that increased by ~30% during the last deglaciation. The causes of this increase are still largely uncertain, and the proposed high-precision record of N2O concentration and isotopes would provide further insights into N2O source changes in a warming world. The broader impacts of proposed work include an improvement in our understanding of the response of these greenhouse gas budgets to global warming and inform societally important model projections of future climate change. The continued age-mapping of Taylor Glacier ablation ice will add value to this high-quality, easily accessible archive of natural environmental variability. Establishing 14CO as a robust new tracer for past cosmic ray flux would inform paleoclimate studies and constitute a valuable contribution to the study of the societally important issue of climate change. The proposed work will contribute to the development of new laboratory and field analytical systems. The data from the study will be made available to the scientific community and the broad public through the NSIDC and NOAA Paleoclimatology data centers. 1 graduate student each will be trained at UR, OSU and SIO, and the work will contribute to the training of a postdoc at OSU. 3 UR undergraduates will be involved in fieldwork and research. The work will support a new, junior UR faculty member, Petrenko. All PIs have a strong history of and commitment to scientific outreach in the forms of media interviews, participation in filming of field projects, as well as speaking to schools and the public about their research, and will continue these activities as part of the proposed work. This award has field work in Antarctica.", "east": 162.167, "geometry": "POINT(162.167 -77.733)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Not provided; USAP-DC; FIELD INVESTIGATION; Stratigraphy; FIELD SURVEYS; Antarctica; Paleoenvironment; Methane; Ice Core; Carbon Dioxide; FIXED OBSERVATION STATIONS; Stable Isotopes; Ablation Zone; Taylor Glacier; Nitrous Oxide; USA/NSF; LABORATORY; AMD; Cosmogenic; Amd/Us", "locations": "Taylor Glacier; Antarctica", "north": -77.733, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Brook, Edward J.; Severinghaus, Jeffrey P.; PETRENKO, VASILLI", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e FIXED OBSERVATION STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.733, "title": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "uid": "p0000283", "west": 162.167}, {"awards": "0944764 Brook, Edward J.", "bounds_geometry": null, "dataset_titles": "Abrupt Change in Atmospheric CO2 During the Last Ice Age; High-resolution Atmospheric CO2 during 7.4-9.0 ka", "datasets": [{"dataset_uid": "609539", "doi": "10.7265/N5F47M23", "keywords": "Antarctica; Arctic; Byrd; Chemistry:fluid; Chemistry:Fluid; CO2; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome Ice Core; Taylor Dome; Taylor Dome Ice Core", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Abrupt Change in Atmospheric CO2 During the Last Ice Age", "url": "https://www.usap-dc.org/view/dataset/609539"}, {"dataset_uid": "609539", "doi": "10.7265/N5F47M23", "keywords": "Antarctica; Arctic; Byrd; Chemistry:fluid; Chemistry:Fluid; CO2; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome Ice Core; Taylor Dome; Taylor Dome Ice Core", "people": "Ahn, Jinho; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Byrd Ice Core", "title": "Abrupt Change in Atmospheric CO2 During the Last Ice Age", "url": "https://www.usap-dc.org/view/dataset/609539"}, {"dataset_uid": "609527", "doi": "10.7265/N5QF8QT5", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; South Pole; WAISCORES", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "High-resolution Atmospheric CO2 during 7.4-9.0 ka", "url": "https://www.usap-dc.org/view/dataset/609527"}, {"dataset_uid": "609539", "doi": "10.7265/N5F47M23", "keywords": "Antarctica; Arctic; Byrd; Chemistry:fluid; Chemistry:Fluid; CO2; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome Ice Core; Taylor Dome; Taylor Dome Ice Core", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Abrupt Change in Atmospheric CO2 During the Last Ice Age", "url": "https://www.usap-dc.org/view/dataset/609539"}], "date_created": "Thu, 08 Aug 2013 00:00:00 GMT", "description": "This award supports a project to create new, unprecedented high-resolution atmospheric carbon dioxide (CO2) records spanning intervals of abrupt climate changes during the last glacial period and the early Holocene. The proposed work will utilize high-precision methods on existing ice cores from high accumulation sites such as Siple Dome and Byrd Station, Antarctica and will improve our understanding of how fast CO2 can change naturally, how its variations are linked with climate, and, combined with a coupled climate-carbon cycle model, will clarify the role of terrestrial and oceanic processes during past abrupt changes of climate and CO2. The intellectual merit of this work is that CO2 is the most important anthropogenic greenhouse gas and understanding its past variations, its sources and sinks, and how they are linked to climate change is a major goal of the climate research community. This project will produce high quality data on centennial to multi-decadal time scales. Such high-resolution work has not been conducted before because of insufficient analytical precision, slow experimental procedures in previous studies, or lack of available samples. The proposed research will complement future high-resolution studies from WAIS Divide ice cores and will provide ice core CO2 records for the target age intervals, which are in the zone of clathrate formation in the WAIS ice cores. Clathrate hydrate is a phase composed of air and ice. CO2 analyses have historically been less precise in clathrate ice than in ?bubbly ice? such as the Siple Dome ice core that will be analyzed in the proposed project. High quality, high-resolution results from specific intervals in Siple Dome that we propose to analyze will provide important data for verifying the WAIS Divide record. The broader impacts of the work are that current models show a large uncertainty of future climate-carbon cycle interactions. The results of this proposed work will be used for testing coupled carbon cycle-climate models and may contribute to reducing this uncertainty. The project will contribute to the training of several undergraduate students and a full-time technician. Both will learn analytical techniques and the basic science involved. Minorities and female students will be highly encouraged to participate in this project. Outreach efforts will include participation in news media interviews, at a local festival celebrating art, science and technology, and giving seminar presentations in the US and foreign countries. The OSU ice core laboratory has begun a collaboration with a regional science museum and is developing ideas to build an exhibition booth to make public be aware of climate change and ice core research. All data will be archived at the National Snow and Ice Data Center and at other similar archives per the OPP data policy.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e CO2 ANALYZERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "GROUND-BASED OBSERVATIONS; CO2 Concentrations; Ice Core Gas Age; CO2 Uncertainty; LABORATORY; Ice Core Depth; Not provided; CH4 Concentrations", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "NOT APPLICABLE; NOT APPLICABLE", "persons": "Ahn, Jinho; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Atmospheric CO2 and Abrupt Climate Change", "uid": "p0000179", "west": null}, {"awards": "0538578 Brook, Edward J.; 0538538 Sowers, Todd", "bounds_geometry": null, "dataset_titles": "Late Holocene Methane Concentrations from WAIS Divide and GISP2; Methane Concentrations from the WAIS Divide Ice Core (WDC06A), 60 to 11,300 ybp; The Antarctic Glaciological Data Center (AGDC) at the National Snow and Ice Data Center (NSIDC) archives and distributes Antarctic glaciological and cryospheric system data collected by the U.S. Antarctic Program.", "datasets": [{"dataset_uid": "001303", "doi": "", "keywords": null, "people": null, "repository": "NSIDC", "science_program": null, "title": "The Antarctic Glaciological Data Center (AGDC) at the National Snow and Ice Data Center (NSIDC) archives and distributes Antarctic glaciological and cryospheric system data collected by the U.S. Antarctic Program.", "url": "https://nsidc.org/data/agdc"}, {"dataset_uid": "609509", "doi": "10.7265/N5J1013R", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Methane Concentrations from the WAIS Divide Ice Core (WDC06A), 60 to 11,300 ybp", "url": "https://www.usap-dc.org/view/dataset/609509"}, {"dataset_uid": "609586", "doi": "10.7265/N5W66HQQ", "keywords": "Antarctica; Arctic; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Mitchell, Logan E", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Late Holocene Methane Concentrations from WAIS Divide and GISP2", "url": "https://www.usap-dc.org/view/dataset/609586"}], "date_created": "Thu, 19 Apr 2012 00:00:00 GMT", "description": "Sowers/Brook\u003cbr/\u003e0538538\u003cbr/\u003eThis award supports a project to develop a high-resolution (every 50 yr) methane data set that will play a pivotal role in developing the timescale for the new deep ice core being drilled at the West Antarctic Ice Sheet Divide (WAIS Divde) site as well as providing a common stratigraphic framework for comparing climate records from Greenland and WAIS Divide. Certain key intervals will be measured at even higher resolution to assist in precisely defining the phasing of abrupt climate change between the northern and southern hemispheres. Concurrent analysis of a suit of samples from both the WAIS Divide and GISP2 ice cores throughout the last 110kyr is also proposed, to establish the inter-hemispheric methane gradient which will be used to identify geographic areas responsible for the climate-related methane emission changes. A large gas measurement inter-calibration of numerous laboratories, utilizing both compressed air cylinders and WAIS Divide ice core samples, will also be performed. The intellectual merit of the proposed work is that it will provide the chronological control needed to examine the timing of changes in climate proxies, and critical chronological ties to the Greenland ice core records via methane variations. In addition, the project addresses the question of what methane sources were active during the ice age and will help to answer the fundamental question of what part of the biosphere controlled past methane variations. The broader impact of the proposed work is that it will directly benefit all ice core paleoclimate research and will impact the paleoclimate studies that rely on ice core timescales for correlation purposes. The project will also support a Ph.D. student at Oregon State University who will have the opportunity to be involved in a major new ice coring effort with international elements. Undergraduates at Penn State will gain valuable laboratory experience and participate fully in the project. The proposed work will underpin the WAIS Divide chronology, which will be fundamental to all graduate student projects that involve the core. The international inter-calibration effort will strengthen ties between research institutions on four continents and will be conducted as part of the International Polar Year research agenda.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Antarctica; Ch4; West Antarctica; Wais Divide-project; GROUND-BASED OBSERVATIONS; FIELD INVESTIGATION; FIELD SURVEYS; Methane Concentration; Methane; Ice Core; WAIS Divide; Antarctic; LABORATORY", "locations": "Antarctic; WAIS Divide; Antarctica; West Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Organisms and Ecosystems; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; NOT APPLICABLE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Lee, James; Buizert, Christo; Brook, Edward J.; Mitchell, Logan E; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "NSIDC", "repositories": "NSIDC; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Collaborative Research: Constructing an Ultra-high Resolution Atmospheric Methane Record for the Last 140,000 Years from WAIS Divide Core.", "uid": "p0000025", "west": null}, {"awards": "0087521 Waddington, Edwin", "bounds_geometry": null, "dataset_titles": "Annual Layers at Siple Dome, Antarctica, from Borehole Optical Stratigraphy", "datasets": [{"dataset_uid": "609515", "doi": "10.7265/N5DB7ZRZ", "keywords": "Antarctica; Borehole Optical Stratigraphy; Geology/Geophysics - Other; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Siple Dome; Siple Dome Ice Core; Snow/ice; Snow/Ice", "people": "Waddington, Edwin D.; Alley, Richard; Taylor, Kendrick C.; Hawley, Robert L.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Annual Layers at Siple Dome, Antarctica, from Borehole Optical Stratigraphy", "url": "https://www.usap-dc.org/view/dataset/609515"}], "date_created": "Sun, 15 Apr 2012 00:00:00 GMT", "description": "This award supports a two year project to develop a new method for measuring vertical strain rates in polar firn. Vertical strain rate measurements in the firn are important because they can aid in the understanding of the dynamics of firn compaction, a key factor in determining ice age/gas age difference estimates for ice cores. Vertical strain rate measurements also determine ice advection for borehole paleothermometry models, and most importantly can be used to date the shallow sections of ice cores where ambiguities in chemical dating or counting of annual layers hinder dating by traditional methods. In this project a video logging tool will be used to create a unique \"optical fingerprint\" of variations in the optical properties of the firn with depth, and track the movement and deformation of the features of this fingerprint. Preliminary work at Siple Dome, Antarctica using an improvised logging system shows a series of optically bright and dark zones as the tool transits up or down the hole. Borehole fingerprinting has the potential to improve measurements of vertical strain in firn holes. This project represents a unique opportunity to interface with an existing field program where a borehole vertical strain rate project is already underway. A graduate student will be supported to conduct the work on this project as part of a PhD. dissertation on climate and physical processes in polar firn.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e CAMERAS \u003e CAMERAS", "is_usap_dc": true, "keywords": "Antarctica; Stratigraphy; Layers; Ice Core Stratigraphy; Siple Dome; Borehole; FIELD INVESTIGATION; Borehole Camera; Ice Stratigraphy", "locations": "Antarctica; Siple Dome", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Alley, Richard; Taylor, Kendrick C.; Waddington, Edwin D.; Hawley, Robert L.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Borehole Fingerprinting: Vertical Strain, Firn Compaction, and Firn Depth-Age Scales", "uid": "p0000173", "west": null}, {"awards": "0440602 Saltzman, Eric; 0440701 Severinghaus, Jeffrey; 0440509 Battle, Mark; 0440759 Sowers, Todd; 0440498 White, James; 0440615 Brook, Edward J.", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane Isotopes from the WAIS Divide Ice Core; Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A; WAIS ice core Methane Data, Carbon Dioxide Data", "datasets": [{"dataset_uid": "609493", "doi": "10.7265/N5319SV3", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Brook, Edward J.; Mitchell, Logan E; Sowers, Todd A.; Taylor, Kendrick C.; McConnell, Joseph", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS ice core Methane Data, Carbon Dioxide Data", "url": "https://www.usap-dc.org/view/dataset/609493"}, {"dataset_uid": "609638", "doi": "10.7265/N56971HF", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS Divide; WAIS Divide Ice Core", "people": "Orsi, Anais J.; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A", "url": "https://www.usap-dc.org/view/dataset/609638"}, {"dataset_uid": "609412", "doi": "10.7265/N5251G40", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609412"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609435", "doi": "10.7265/N5J67DW0", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Methane Isotopes from the WAIS Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609435"}], "date_created": "Tue, 03 Feb 2009 00:00:00 GMT", "description": "This award supports a project to measure the elemental and isotopic composition of firn air and occluded air in shallow boreholes and ice cores from the WAIS Divide site, the location of a deep ice-coring program planned for 2006-07 and subsequent seasons. The three primary objectives are: 1) to establish the nature of firn air movement and trapping at the site to aid interpretations of gas data from the deep core; 2) to expand the suite of atmospheric trace gas species that can be measured in ice and replicate existing records of other species; and 3) to inter-calibrate all collaborating labs to insure that compositional and isotopic data sets are inter-comparable. The program will be initiated with a shallow drilling program during the 05/06 field season which will recover two 300+m cores and firn air samples. The ice core and firn air will provide more than 700 years of atmospheric history that will be used to address a number of important questions related to atmospheric change over this time period. The research team consists of six US laboratories that also plan to participate in the deep core program. This collaborative research program has a number of advantages. First, the scientists will be able to coordinate sample allocation a priori to maximize the resolution and overlap of records of interrelated species. Second, sample registration will be exact, allowing direct comparison of all records. Third, a coherent data set will be produced at the same time and all PI.s will participate in interpreting and publishing the results. This will insure that the best possible understanding of gas records at the WAIS Divide site will be achieved, and that all work necessary to interpret the deep core is conducted in a timely fashion. The collaborative structure created by the proposal will encourage sharing of techniques, equipment, and ideas between the laboratories. The research will identify impacts of various industrial/agricultural activities and help to distinguish them from natural variations, and will include species for which there are no long records of anthropogenic impact. The work will also help to predict future atmospheric loadings. The project will contribute to training scientists at several levels, including seven undergraduates, two graduate students and one post doctoral fellow.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e SPECTROMETERS/RADIOMETERS \u003e SPECTROMETERS \u003e SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; WAIS Divide; Firn; LABORATORY; Ice Core; Firn Air Isotope Measurements; Shallow Firn Air; FIELD INVESTIGATION; Ice Core Gas Records; GROUND-BASED OBSERVATIONS; Firn Isotopes; Wais Divide-project; Gas Data; Polar Firn Air; Not provided; Trace Gas Species; Trapped Gases; West Antarctic Ice Sheet; Deep Core; Ice Sheet; Gas; Firn Air Isotopes; FIELD SURVEYS; Air Samples; Atmospheric Gases; Isotope; Cores; Atmosphere; Ice Core Data; Surface Temperatures; Firn Air; Borehole; Antarctica", "locations": "West Antarctic Ice Sheet; Antarctica; WAIS Divide", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Battle, Mark; Mischler, John; Saltzman, Eric; Aydin, Murat; White, James; Brook, Edward J.; Orsi, Anais J.; Severinghaus, Jeffrey P.; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "uid": "p0000368", "west": -112.085}, {"awards": "0126057 Brook, Edward J.; 0512971 Brook, Edward J.", "bounds_geometry": null, "dataset_titles": "Antarctic and Greenland Climate Change Comparison; GISP2 (B and D Core) Methane Concentrations; GISP2 (D Core) Helium Isotopes from Interplanetary Dust; GISP2 (D Core) Methane Concentration Data; Siple Dome Methane Record", "datasets": [{"dataset_uid": "609253", "doi": "", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Vostok Ice Core", "people": "Stauffer, Bernhard; Blunier, Thomas; Chappellaz, Jerome; Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "Antarctic and Greenland Climate Change Comparison", "url": "https://www.usap-dc.org/view/dataset/609253"}, {"dataset_uid": "609125", "doi": "", "keywords": "Arctic; Chemistry:fluid; Chemistry:Fluid; Chemistry:ice; Chemistry:Ice; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland; Ice Core Records; Methane; Paleoclimate", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "GISP2 (B and D Core) Methane Concentrations", "url": "https://www.usap-dc.org/view/dataset/609125"}, {"dataset_uid": "609361", "doi": "", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Lake Vostok; Paleoclimate; Vostok Ice Core", "people": "Brook, Edward J.; Kurz, Mark D.", "repository": "USAP-DC", "science_program": null, "title": "GISP2 (D Core) Helium Isotopes from Interplanetary Dust", "url": "https://www.usap-dc.org/view/dataset/609361"}, {"dataset_uid": "609360", "doi": "", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Methane; Paleoclimate; Taylor Dome", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "GISP2 (D Core) Methane Concentration Data", "url": "https://www.usap-dc.org/view/dataset/609360"}, {"dataset_uid": "609124", "doi": "10.7265/N5KH0K8R", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Siple Dome Methane Record", "url": "https://www.usap-dc.org/view/dataset/609124"}], "date_created": "Tue, 16 Dec 2008 00:00:00 GMT", "description": "This award supports work on trapped gases in Antarctic and other ice cores for paleoenvironmental and chronological purposes. The project will complete a ~ 100,000 year, high-resolution record of atmospheric methane from the Siple Dome ice core and use these data to construct a precise chronology for climate events recorded by the Siple Dome record. In addition, the resolution of the GISP2 (Greenland) ice core record will be increased in some critical intervals to help with the Siple Dome chronology and that of future ice cores. Finally, an upgrade to the analytical capabilities of the laboratory, including increasing precision and throughput and decreasing sample size needed for ice core methane measurements will be an important goal of this work. The proposed work will contribute to the understanding of the timing of rapid climate change in the Northern and Southern hemispheres during the last glacial period, the evolution of the global methane budget in the late Quaternary, and the late Quaternary climate history of Antarctica. It will also improve our ability to generate methane records for future ice coring projects, and inform and enrich the educational and outreach activities of our laboratory.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Isotope; Siple Coast; WAISCORES; GROUND-BASED OBSERVATIONS; Interplanetary Dust; FIELD SURVEYS; Not provided; Ice Sheet; Snow; GROUND STATIONS; Gas Measurement; Ice Core; Siple; Antarctica; Methane; Glaciology; Stratigraphy; Siple Dome", "locations": "Antarctica; Siple; Siple Coast; Siple Dome", "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Glaciology; Antarctic Organisms and Ecosystems; Antarctic Glaciology", "paleo_time": null, "persons": "Blunier, Thomas; Chappellaz, Jerome; Stauffer, Bernhard; Kurz, Mark D.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "High Resolution Records of Atmospheric Methane in Ice Cores and Implications for Late Quaternary Climate Change", "uid": "p0000034", "west": null}, {"awards": "0230452 Severinghaus, Jeffrey", "bounds_geometry": "POINT(124.5 -80.78)", "dataset_titles": "Antarctic megadunes", "datasets": [{"dataset_uid": "000191", "doi": "", "keywords": null, "people": null, "repository": "NSIDC", "science_program": null, "title": "Antarctic megadunes", "url": "http://nsidc.org/antarctica/megadunes/"}], "date_created": "Wed, 27 Sep 2006 00:00:00 GMT", "description": "This award supports a study of the chemical composition of air in the snow layer (firn) in a region of \"megadunes\" near Vostok station, Antarctica. It will test the hypothesis that a deep \"convective zone\" of vigorous wind-driven mixing can prevent gas fractionation in the upper one-third of the polar firn layer. In the megadunes, ultralow snow accumulation rates lead to structural changes (large grains, pipes, and cracks) that make the permeability of firn to air movement orders of magnitude higher than normal. The unknown thickness of the convective zone has hampered the interpretation of ice core 15N/14N and 40Ar/36Ar ratios as indicators of past firn thickness, which is a key constraint on the climatically important variables of temperature, accumulation rate, and gas age-ice age difference. Studying this \"extreme end-member\" example will better define the role of the convective zone in gas reconstructions. This study will pump air from a profile of ~20 depths in the firn, to definitively test for the presence of a convective zone based on the fit of observed 15 N/14N and 40Ar/36Ar to a molecular- and eddy-diffusion model. Permeability measurements on the core and 2-D air flow modeling (in collaboration with M. Albert) will permit a more physically realistic interpretation of the isotope data and will relate mixing vigor to air velocities. A new proxy indicator of convective zone thickness will be tested on firn and ice core bubble air, based on the principle that isotopes of slow-diffusing heavy noble gases (Kr, Xe) should be more affected by convection than isotopes of fast-diffusing N2 . These tools will be applied to a test of the hypothesis that the megadunes and a deep convective zone existed at the Vostok site during glacial periods, which would explain the anomalously low 15N/14N and 40Ar/36Ar in the Vostok ice core glacial periods. The broader impacts of this work include 1) clarification of phase relationships of greenhouse gases and temperature in ice core records, with implications for understanding of past and future climates, 2) education of one graduate student, and 3) building of collaborative relationships with five investigators.", "east": 124.5, "geometry": "POINT(124.5 -80.78)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS", "is_usap_dc": false, "keywords": "Antarctica; Methane; Carbon-14; Permeability; CO2; Firn Core; FIELD SURVEYS; Deuterium Excess; GROUND-BASED OBSERVATIONS; LABORATORY; Isotope; Ice Core Density; Firn Air; Megadunes; Ice Core; Not provided; FIELD INVESTIGATION", "locations": "Antarctica", "north": -80.78, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Bauer, Rob; Albert, Mary R.; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "NSIDC", "repositories": "NSIDC", "science_programs": null, "south": -80.78, "title": "How Thick Is the Convective Zone: A Study of Firn Air in the Megadunes Near Vostok, Antarctica", "uid": "p0000097", "west": 124.5}, {"awards": "0230316 White, James; 0230348 Dunbar, Nelia; 0230021 Sowers, Todd", "bounds_geometry": "POINT(135.1333 -76.05)", "dataset_titles": "Mount Moulton Isotopes and Other Ice Core Data", "datasets": [{"dataset_uid": "609640", "doi": "10.7265/N5FT8J0N", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Lake Vostok; Mount Moulton; Paleoclimate; Talos Dome; Taylor Dome", "people": "Steig, Eric J.; White, James; Popp, Trevor", "repository": "USAP-DC", "science_program": null, "title": "Mount Moulton Isotopes and Other Ice Core Data", "url": "https://www.usap-dc.org/view/dataset/609640"}], "date_created": "Tue, 01 Aug 2006 00:00:00 GMT", "description": "The summit crater of Mt. Moulton, in West Antarctica, contains a 600-m thick horizontally-exposed section of ice with intercalated tephra layers from nearby Mt Berlin. Argon-40/Argon-39 dating of the thick, near-source tephra indicates that the age of the horizontal ice section ranges between 15,000 and 492,000 years. Thus, the Mt Moulton site offers an unparalleled repository of ancient West Antarctic snow and trapped air that can be used to investigate West Antarctic climate over much of the past 500,000 years. The planar nature and consistent dips of the tephra layers suggests that, although the ice section has thinned, it is otherwise undeformed. The Mt. Moulton site was visited during the 1999/2000 field season, at which time a horizontal ice core representing approximately 400 meters of ice was collected, ranging in age from 15,000 to older than 480,000 years. In addition to this horizontal core, samples of ice at a range of depths were collected in order to test the quality of the climate record in the ice. Forty tephra layers intercalated in the ice were also collected in order to provide chronology for the ice section. The results of this first effort are extremely encouraging. Based on the d?18 O of ice, for example, there is clearly a useable record of past climate at Mt. Moulton extending back beyond 140,000 years. There is work to do, however, to realize the full potential of this horizontal ice core. The elemental and isotopic composition of trapped gases suggest some contamination with modern air, for example. As gas cross-dating of ice cores is the current standard by which climate records are intercompared, we need to understand why and how the gas record is compromised before adding Moulton to our arsenal of ice core paleoclimate records. This award supports a collaborative effort between three institutions with following objectives: 1) to evaluate more thoroughly the integrity of the climatic record through shallow drilling of the blue ice area, as well as the snow field upslope from the blue ice; 2) to improve the radioisotopic dating of specific tephra layers; 3) to obtain baseline information about modern snowfall deposition, mean annual temperature, and wind pumping around the summit of Mt. Moulton; and 4) to study how firn densification differs when surface accumulation changes from net accumulation to net ablation.", "east": 135.1333, "geometry": "POINT(135.1333 -76.05)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ELECTRON MICROPROBES", "is_usap_dc": true, "keywords": "LABORATORY; Climate; Argon-40; 40Ar; Argon-39; FIELD SURVEYS; Chronology; Ice Core Gas Age; Gas Record; Ice Core; FIELD INVESTIGATION; Tephra; Mount Moulton; Not provided; Caldera; 39Ar; Stratigraphy; Ice Core Depth", "locations": "Mount Moulton", "north": -76.05, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "White, James; Popp, Trevor; Dunbar, Nelia; Sowers, Todd A.; Steig, Eric J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -76.05, "title": "Collaborative Research: Refining a 500-kry Climate Record From the Moulton Blue Ice Field in West Antarctica", "uid": "p0000755", "west": 135.1333}, {"awards": "0230448 Severinghaus, Jeffrey; 0230260 Bender, Michael", "bounds_geometry": "POLYGON((-75.34 86.6,-68.742 86.6,-62.144 86.6,-55.546 86.6,-48.948 86.6,-42.35 86.6,-35.752 86.6,-29.154 86.6,-22.556 86.6,-15.958 86.6,-9.36 86.6,-9.36 83.618,-9.36 80.636,-9.36 77.654,-9.36 74.672,-9.36 71.69,-9.36 68.708,-9.36 65.726,-9.36 62.744,-9.36 59.762,-9.36 56.78,-15.958 56.78,-22.556 56.78,-29.154 56.78,-35.752 56.78,-42.35 56.78,-48.948 56.78,-55.546 56.78,-62.144 56.78,-68.742 56.78,-75.34 56.78,-75.34 59.762,-75.34 62.744,-75.34 65.726,-75.34 68.708,-75.34 71.69,-75.34 74.672,-75.34 77.654,-75.34 80.636,-75.34 83.618,-75.34 86.6))", "dataset_titles": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001; Trapped Gas Composition and Chronology of the Vostok Ice Core", "datasets": [{"dataset_uid": "609311", "doi": "10.7265/N5P26W12", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Lake Vostok; Paleoclimate; Vostok; Vostok Ice Core", "people": "Bender, Michael; Suwa, Makoto", "repository": "USAP-DC", "science_program": null, "title": "Trapped Gas Composition and Chronology of the Vostok Ice Core", "url": "https://www.usap-dc.org/view/dataset/609311"}, {"dataset_uid": "609290", "doi": "10.7265/N5FJ2DQC", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciology; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole", "people": "Battle, Mark; Severinghaus, Jeffrey P.; Bender, Michael", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001", "url": "https://www.usap-dc.org/view/dataset/609290"}], "date_created": "Wed, 18 Jan 2006 00:00:00 GMT", "description": "High latitude deep ice cores contain fundamental records of polar temperatures, atmospheric dust loads (and continental aridity), greenhouse gas concentrations, the status of the biosphere, and other essential properties of past environments. An accurate chronology for these records is needed if their significance is to be fully realized. The dating challenge has stimulated efforts at orbital tuning. In this approach, one varies a timescale, within allowable limits, to optimize the match between a paleoenvironmental property and a curve of insolation through time. The ideal property would vary with time due to direct insolation forcing. It would be unaffected by complex climate feedbacks and teleconnections, and it would give a clean record with high signal/noise ratio. It is argued strongly that the O2/N2 ratio of ice core trapped gases is such a property, and evidence is presented that this property, whose atmospheric ratio is nearly constant, is tied to local summertime insolation. This award will support a project to analyze the O2/N2 ratios at 1 kyr intervals from ~ 115-400 ka in the Vostok ice core. Ancillary measurements will be made of Ar/N2, and Ne/N2 and heavy noble gas ratios, in order to understand bubble close-off fractionation and its manifestation in the Vostok trapped gas record. O2/N2 variations will be matched with summertime insolation at Vostok to achieve a high-accuracy chronology for the Vostok core. The Vostok and other correlatable climate records will then be reexamined to improve our understanding of the dynamics of Pleistocene climate change.", "east": 106.8, "geometry": "POINT(106.8 -72.4667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Paleoclimate; Siple Dome; Ice Age; Shallow Firn Air; Firn Air Isotope Measurements; Polar Firn Air; Ice Sample Gas Integrity; Oxygen Isotope; Noble Gas; Ice Core Gas Records; Atmospheric Gases; Trapped Gases; Not provided; LABORATORY; Vostok; Firn Air Isotopes; Thermal Fractionation; Ice Core Chemistry; Trapped Air Bubbles; Ice Core; Antarctica; South Pole; Ice Core Data; GROUND-BASED OBSERVATIONS; Gas Age; Firn Isotopes", "locations": "Antarctica; Vostok; Siple Dome; South Pole", "north": -72.4667, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Bender, Michael; Suwa, Makoto; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -72.4667, "title": "Collaborative Research: Trapped Gas Composition and the Chronology of the Vostok Ice Core", "uid": "p0000257", "west": 106.8}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}, {"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}, {"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; Carbonyl Sulfide; Siple Coast; Chloride; Trapped Gases; Snow; Ice Core Chemistry; Chromatography; Siple; GROUND STATIONS; Atmospheric Gases; Ozone Depletion; AWS Siple; Ice Sheet; Ice Core Data; Antarctica; Glaciology; West Antarctica; Atmospheric Chemistry; Ice Core; Stratigraphy; LABORATORY; Methane; Mass Spectrometer; GROUND-BASED OBSERVATIONS; WAISCORES; Msa; Mass Spectrometry; Not provided; Siple Dome; Gas Measurement", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica; Siple", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}]

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