USAP-DC

{"dp_type": "Project", "free_text": "Firn Air"}

[{"awards": "1643669 Petrenko, Vasilii; 1643664 Severinghaus, Jeffrey; 1643716 Buizert, Christo", "bounds_geometry": "POLYGON((112 -66,112.2 -66,112.4 -66,112.6 -66,112.8 -66,113 -66,113.2 -66,113.4 -66,113.6 -66,113.8 -66,114 -66,114 -66.1,114 -66.2,114 -66.3,114 -66.4,114 -66.5,114 -66.6,114 -66.7,114 -66.8,114 -66.9,114 -67,113.8 -67,113.6 -67,113.4 -67,113.2 -67,113 -67,112.8 -67,112.6 -67,112.4 -67,112.2 -67,112 -67,112 -66.9,112 -66.8,112 -66.7,112 -66.6,112 -66.5,112 -66.4,112 -66.3,112 -66.2,112 -66.1,112 -66))", "dataset_titles": "Concentration and isotopic composition of atmospheric N2O over the last century; Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2; Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy; Law Dome firn air and ice core 14CO concentration", "datasets": [{"dataset_uid": "601846", "doi": "10.15784/601846", "keywords": "Antarctica; Carbon-14; Cryosphere; Firn Air; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Law Dome; Snow/ice; Snow/Ice", "people": "Petrenko, Vasilii", "repository": "USAP-DC", "science_program": null, "title": "Law Dome firn air and ice core 14CO concentration", "url": "https://www.usap-dc.org/view/dataset/601846"}, {"dataset_uid": "601597", "doi": "10.15784/601597", "keywords": "Antarctica; Ice Core; Law Dome; Noble Gas", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy", "url": "https://www.usap-dc.org/view/dataset/601597"}, {"dataset_uid": "601693", "doi": "10.15784/601693", "keywords": "Antarctic; Antarctica; Anthropogenic Emission; Atmosphere; Greenhouse Gas; Greenland; Ice Core Data; Nitrification And Denitrification Processes; Nitrous Oxide; Site-Specific 15N Isotopomer; Styx Glacier", "people": "Etheridge, David; Buizert, Christo ; Langenfelds, Ray L ; Ahn, Jinho ; Yoshida, Naohiro ; Joong Kim, Seong; Ghosh, Sambit; Toyoda, Sakae ", "repository": "USAP-DC", "science_program": null, "title": "Concentration and isotopic composition of atmospheric N2O over the last century", "url": "https://www.usap-dc.org/view/dataset/601693"}, {"dataset_uid": "601598", "doi": "10.15784/601598", "keywords": "Antarctica; Firn; Firn Density; Gravitational Settling; Inert Gases; Law Dome", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2", "url": "https://www.usap-dc.org/view/dataset/601598"}], "date_created": "Fri, 17 Jun 2022 00:00:00 GMT", "description": "Hydroxyl radicals are responsible for removal of most atmospheric trace gases, including pollutants and important greenhouse gases. They have been called the \"detergent of the atmosphere\". Changes in hydroxyl radical concentration in response to large changes in reactive trace gas emissions, which may happen in the future, are uncertain. This project aims to provide the first estimates of the variability of atmospheric hydroxyl radicals since about 1880 AD when anthropogenic emissions of reactive trace gases were minimal. This will improve understanding of their stability in response to large changes in emissions. The project will also investigate whether ice cores record past changes in Southern Hemisphere westerly winds. These winds are a key component of the global climate system, and have an important influence on ocean circulation and possibly on atmospheric carbon dioxide concentrations. The project team will include three early career scientists, a postdoctoral researcher, and graduate and undergraduate students, working in collaboration with senior scientists and Australian collaborators. \u003cbr/\u003e \u003cbr/\u003eFirn air and shallow ice to a depth of about 233 m will be sampled at the Law Dome high-accumulation coastal site in East Antarctica. Trapped air will be extracted from the ice cores on site immediately after drilling. Carbon-14 of carbon monoxide (14CO) will be analyzed in firn and ice-core air samples. Corrections will be made for the in situ cosmogenic 14CO component in the ice, allowing for the atmospheric 14CO history to be reconstructed. This 14CO history will be interpreted with the aid of a chemistry-transport model to place the first observational constraints on the variability of Southern Hemisphere hydroxyl radical concentration after about 1880 AD. An additional component of the project will analyze Krypton-86 in the firn-air and ice-core samples. These measurements will explore whether ice-core Krypton-86 acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere westerly winds.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 114.0, "geometry": "POINT(113 -66.5)", "instruments": null, "is_usap_dc": true, "keywords": "AMD; TRACE GASES/TRACE SPECIES; Law Dome; Amd/Us; USAP-DC; LABORATORY; ICE CORE AIR BUBBLES; USA/NSF", "locations": "Law Dome", "north": -66.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Murray, Lee T; Buizert, Christo; Petrenko, Vasilii; Murray, Lee T", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -67.0, "title": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability", "uid": "p0010341", "west": 112.0}, {"awards": "1907974 Saltzman, Eric", "bounds_geometry": "POLYGON((129.26 -89.86,130.261 -89.86,131.262 -89.86,132.263 -89.86,133.264 -89.86,134.265 -89.86,135.266 -89.86,136.267 -89.86,137.268 -89.86,138.269 -89.86,139.27 -89.86,139.27 -89.861,139.27 -89.862,139.27 -89.863,139.27 -89.864,139.27 -89.865,139.27 -89.866,139.27 -89.867,139.27 -89.868,139.27 -89.869,139.27 -89.87,138.269 -89.87,137.268 -89.87,136.267 -89.87,135.266 -89.87,134.265 -89.87,133.264 -89.87,132.263 -89.87,131.262 -89.87,130.261 -89.87,129.26 -89.87,129.26 -89.869,129.26 -89.868,129.26 -89.867,129.26 -89.866,129.26 -89.865,129.26 -89.864,129.26 -89.863,129.26 -89.862,129.26 -89.861,129.26 -89.86))", "dataset_titles": "H2 in South Pole firn air", "datasets": [{"dataset_uid": "601332", "doi": "10.15784/601332", "keywords": "Antarctica; Firn; Glaciology; Hydrogen; Ice Core Records; Snow/ice; Snow/Ice; South Pole", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "H2 in South Pole firn air", "url": "https://www.usap-dc.org/view/dataset/601332"}], "date_created": "Tue, 09 Jun 2020 00:00:00 GMT", "description": "Hydrogen (H2) is one of the most abundant trace gases in the atmosphere, with a mean level of 500 ppb and an atmospheric lifetime of about two years. Hydrogen has an impact on both air quality and climate, due to its role as a precursor for tropospheric ozone and stratospheric water vapor. Projections indicate that a future \"hydrogen economy\" would increase hydrogen emissions. Understanding of the atmospheric hydrogen budget is largely based on a 30-year record of surface air measurements, but there are no long-term records with which to assess either: 1) the influence of climate change on atmospheric hydrogen, or 2) the extent to which humans have impacted the hydrogen budget. Polar ice core records of hydrogen will advance our understanding of the atmospheric hydrogen cycle and provide a stronger basis for projecting future changes to atmospheric levels of hydrogen and their impacts. \u003cbr/\u003e\u003cbr/\u003eThe research will involve laboratory work to enable the collection and analysis of hydrogen in polar ice cores. Hydrogen is a highly diffusive molecule and, unlike most other atmospheric gases, diffusion of hydrogen in ice is so rapid that ice samples must be stored in impermeable containers immediately upon drilling and recovery. This project will: 1) construct a laboratory system for extracting and analyzing hydrogen in polar ice, 2) develop and test materials and construction designs for vessels to store ice core samples in the field, and 3) test the method on samples of opportunity previously stored in the field. The goal of this project is a proven, cost-effective design for storage flasks to be fabricated for use on future polar ice coring projects. This project will support the dissertation research of a graduate student in the UC Irvine Department of Earth System Science.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 139.27, "geometry": "POINT(134.265 -89.865)", "instruments": null, "is_usap_dc": true, "keywords": "LABORATORY; Firn; TRACE GASES/TRACE SPECIES; South Pole; FIELD INVESTIGATION; USAP-DC", "locations": "South Pole", "north": -89.86, "nsf_funding_programs": "Antarctic Instrumentation and Support; Antarctic Glaciology; Antarctic Instrumentation and Facilities", "paleo_time": null, "persons": "Saltzman, Eric", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -89.87, "title": "EAGER: Feasibility of Reconstructing the Atmospheric History of Molecular Hydrogen from Antarctic Ice", "uid": "p0010106", "west": 129.26}, {"awards": "1543267 Brook, Edward J.; 1543229 Severinghaus, Jeffrey", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Multi-site ice core Krypton stable isotope ratios; Noble Gas Data from recent ice in Antarctica for 86Kr problem", "datasets": [{"dataset_uid": "601195", "doi": "10.15784/601195", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Krypton; Noble Gas; Xenon", "people": "Shackleton, Sarah; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Noble Gas Data from recent ice in Antarctica for 86Kr problem", "url": "https://www.usap-dc.org/view/dataset/601195"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Shackleton, Sarah; Brook, Edward J.; Etheridge, David; Buizert, Christo; Bereiter, Bernhard; Baggenstos, Daniel; Severinghaus, Jeffrey P.; Bertler, Nancy; Pyne, Rebecca L.; Mulvaney, Robert; Mosley-Thompson, Ellen", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Bereiter, Bernhard; Mosley-Thompson, Ellen; Mulvaney, Robert; Pyne, Rebecca L.; Bertler, Nancy; Etheridge, David; Baggenstos, Daniel; Brook, Edward J.; Severinghaus, Jeffrey P.; Shackleton, Sarah; Buizert, Christo", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Baggenstos, Daniel; Etheridge, David; Severinghaus, Jeffrey P.; Bereiter, Bernhard; Buizert, Christo; Pyne, Rebecca L.; Bertler, Nancy; Mulvaney, Robert; Brook, Edward J.; Mosley-Thompson, Ellen; Shackleton, Sarah", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}], "date_created": "Wed, 10 Jul 2019 00:00:00 GMT", "description": "Overview: The funded work investigated whether ice core 86Kr acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere (SH) westerly winds. Pressure variations drive macroscopic air movement in the firn column, which reduces the gravitational isotopic enrichment of slow-diffusing gases (such as Kr). The 86Kr deviation from gravitational equilibrium (denoted D86Kr) thus reflects the magnitude of pressure variations (among other things). Atmospheric reanalysis data suggest that pressure variability over Antarctica is linked to the Southern Annular Mode (SAM) index and the position of the SH westerly winds. Preliminary data from the WAIS Divide ice core show a large excursion in D86Kr during the last deglaciation (20-9 ka before present). In this project the investigators (1) performed high-precision 86Kr analysis on ice core and firn air samples to establish whether D86Kr is linked to pressure variability; (2) Refined the deglacial WAIS Divide record of Kr isotopes; (3) Investigated the role of pressure variability in firn air transport using firn air models with firn microtomography data and Lattice- Boltzmann modeling; and (4) Investigated how barometric pressure variability in Antarctica is linked to the SAM index and the position/strength of the SH westerlies in past and present climates using GCM and reanalysis data. A key finding was that D86Kr in recent ice samples (e.g. last 50 years) from a broad spatial array of sites in Antarctica and Greenland showed a significant correlation with directly measured barometric pressure variability at the ice core site. This strongly supports the hypothesis that 86Kr can be used as a paleo-proxy for storminess.\r\nIntellectual Merit: The SH westerlies are a key component of the global climate system; they are an important control on the global oceanic overturning circulation and possibly on atmospheric CO2 concentrations. Poleward movement of the SH westerlies during the last deglaciation has been hypothesized, yet evidence from proxy and modeling studies remains inconclusive. The funded work could provide valuable new constraints on deglacial movement of the SH westerlies. This record can be compared to high-resolution CO2 data from the same core, allowing us to test hypotheses that link CO2 to the SH westerlies. Climate proxies are at the heart of paleoclimate research. The funded work has apparently led to the discovery of a completely new proxy, opening up exciting new research possibilities and increasing the scientific value of existing ice cores. Once validated, the 86Kr proxy could be applied to other time periods as well, providing a long-term perspective on the movement of the SH westerlies. The funded work has furthermore provided valuable new insights into firn air transport. \r\n\r\nBroader impact: The Southern Ocean is presently an important sink of atmospheric CO2, thereby reducing the warming associated with anthropogenic CO2 emissions. Stratospheric ozone depletion and greenhouse warming have displaced the SH westerlies poleward, with potential consequences for the future magnitude of this oceanic carbon uptake. The funded work may provide a paleo-perspective on past movement of the SH westerlies and its link to atmospheric CO2, which could guide projections of future oceanic CO2 uptake, with strong societal benefits. The awarded funds supported and trained an early-career postdoctoral scholar at OSU, and fostered (international) collaboration. Data from the study will be available to the scientific community and the broad public through recognized data centers. During this project the PI and senior personnel have continued their commitment to public outreach through media interviews and speaking to schools and the public about their work. The PI provides services to the community by chairing the IPICS (International Partnership in Ice Core Sciences) working group and organizing annual PIRE (Partnerships in International Research and Education) workshops.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "USA/NSF; FIRN; ICE CORE RECORDS; USAP-DC; Greenland; Xenon; Noble Gas; Ice Core; Amd/Us; Antarctica; AMD; LABORATORY; Krypton; ATMOSPHERIC PRESSURE", "locations": "Greenland; Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Collaborative research: Kr-86 as a proxy for barometric pressure variability and movement of the SH westerlies during the last\r\ndeglaciation", "uid": "p0010037", "west": -180.0}, {"awards": "1443472 Brook, Edward J.; 1443464 Sowers, Todd; 1443710 Severinghaus, Jeffrey", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole CH4 data for termination; South Pole Ice Core Isotopes of N2 and Ar; South Pole ice core (SPC14) discrete methane data; South Pole ice core total air content; South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2; SP19 Gas Chronology", "datasets": [{"dataset_uid": "601231", "doi": "10.15784/601231", "keywords": "Air Content; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core total air content", "url": "https://www.usap-dc.org/view/dataset/601231"}, {"dataset_uid": "601152", "doi": "10.15784/601152", "keywords": "Antarctica; Antarctic Ice Sheet; Chemistry:gas; Chemistry:Gas; Chemistry:ice; Chemistry:Ice; Delta 18O; Dole Effect; Firn Thickness; Gas Isotopes; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Gravitational Settling; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Inert Gases; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2", "url": "https://www.usap-dc.org/view/dataset/601152"}, {"dataset_uid": "601517", "doi": "10.15784/601517", "keywords": "Antarctica; Argon; Argon Isotopes; Firn; Firn Temperature Gradient; Firn Thickness; Gas Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Nitrogen; Nitrogen Isotopes; South Pole; SPICEcore", "people": "Morgan, Jacob; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Isotopes of N2 and Ar", "url": "https://www.usap-dc.org/view/dataset/601517"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kalk, Michael; Ferris, David G.; Kennedy, Joshua A.; Epifanio, Jenna; Brook, Edward J.; Buizert, Christo; Kreutz, Karl; Aydin, Murat; Edwards, Jon S.; Sowers, Todd A.; Kahle, Emma; Steig, Eric J.; Winski, Dominic A.; Osterberg, Erich; Fudge, T. J.; Hood, Ekaterina; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601230", "doi": "10.15784/601230", "keywords": "Antarctica; Atmospheric CH4; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Data; Methane; Methane Concentration; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole CH4 data for termination", "url": "https://www.usap-dc.org/view/dataset/601230"}], "date_created": "Sat, 02 Feb 2019 00:00:00 GMT", "description": "Gases trapped in ice cores have revealed astonishing things about the greenhouse gas composition of the past atmosphere, including the fact that carbon dioxide concentrations never rose above 300 parts per million during the last 800,000 years. This places today\u0027s concentration of 400 parts per million in stark contrast. Furthermore, these gas records show that natural sources of greenhouse gas such as oceans and ecosystems act as amplifiers of climate change by increasing emissions of gases during warmer periods. Such amplification is expected to occur in the future, adding to the human-produced gas burden. The South Pole ice core will build upon these prior findings by expanding the suite of gases to include, for the first time, those potent trace gases that both trapped heat and depleted ozone during the past 40,000 years. The present project on inert gases and methane in the South Pole ice core will improve the dating of this crucial record, to unprecedented precision, so that the relative timing of events can be used to learn about the mechanism of trace gas production and destruction, and consequent climate change amplification. Ultimately, this information will inform predictions of future atmospheric chemical cleansing mechanisms and climate in the context of our rapidly changing atmosphere. This award also engages young people in the excitement of discovery and polar research, helping to entrain the next generations of scientists and educators. Education of graduate students, a young researcher (Buizert), and training of technicians, will add to the nation?s human resource base. \u003cbr/\u003e \u003cbr/\u003eThis award funds the construction of the gas chronology for the South Pole 1500m ice core, using measured inert gases (d15N and d40Ar--Nitrogen and Argon isotope ratios, respectively) and methane in combination with a next-generation firn densification model that treats the stochastic nature of air trapping and the role of impurities on densification. The project addresses fundamental gaps in scientific understanding that limit the accuracy of gas chronologies, specifically a poor knowledge of the controls on ice-core d15N and the possible role of layering and impurities in firn densification. These gaps will be addressed by studying the gas enclosure process in modern firn at the deep core site. The work will comprise the first-ever firn air pumping experiment that has tightly co-located measurements of firn structural properties on the core taken from the same borehole.\u003cbr/\u003e\u003cbr/\u003eThe project will test the hypothesis that the lock-in horizon as defined by firn air d15N, CO2, and methane is structurally controlled by impermeable layers, which are in turn created by high-impurity content horizons in which densification is enhanced. Thermal signals will be sought using the inert gas measurements, which improve the temperature record with benefits to the firn densification modeling. Neon, argon, and oxygen will be measured in firn air and a limited number of deep core samples to test whether glacial period layering was enhanced, which could explain low observed d15N in the last glacial period. Drawing on separate volcanic and methane synchronization to well-dated ice cores to create independent ice and gas tie points, independent empirical estimates of the gas age-ice age difference will be made to check the validity of the firn densification model-inert gas approach to calculating the gas age-ice age difference. These points will also be used to test whether the anomalously low d15N seen during the last glacial period in east Antarctic ice cores is due to deep air convection in the firn, or a missing impurity dependence in the firn densification models. \u003cbr/\u003e\u003cbr/\u003eThe increased physical understanding gained from these studies, combined with new high-precision measurements, will lead to improved accuracy of the gas chronology of the South Pole ice core, which will enhance the overall science return from this gas-oriented core. This will lead to clarification of timing of atmospheric gas variations and temperature, and aid in efforts to understand the biogeochemical feedbacks among trace gases. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. Ozone-depleting substances will be measured in the South Pole ice core record, and a precise gas chronology will add value. Lastly, by seeking a better understanding of the physics of gas entrapment, the project aims to have an impact on ice-core science in general.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "USAP-DC; AMD; LABORATORY; Antarctica; NITROGEN ISOTOPES; USA/NSF; METHANE; Amd/Us; FIELD INVESTIGATION", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Sowers, Todd A.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Inert Gas and Methane Based Climate Records throughout the South Pole Deep Ice Core", "uid": "p0010005", "west": 0.0}, {"awards": "1043421 Severinghaus, Jeffrey; 1043522 Brook, Edward J.", "bounds_geometry": "POINT(-112.09 -79.47)", "dataset_titles": "WAIS Divide Replicate Core Methane Isotopic Data Set", "datasets": [{"dataset_uid": "601059", "doi": "10.15784/601059", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Replicate Core Methane Isotopic Data Set", "url": "https://www.usap-dc.org/view/dataset/601059"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "1043421/Severinghaus\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to obtain samples of ice in selected intervals for replication and verification of the validity and spatial representativeness of key results in the WAIS Divide ice core, and to obtain additional ice samples in areas of intense scientific interest where demand is high. The US Ice Core Working Group recommended in 2003 that NSF pursue the means to take replicate samples, termed \"replicate coring\". This recommendation was part of an agreement to reduce the diameter of the (then) new drilling system (the DISC drill) core to 12.2 cm to lighten logistics burdens, and the science community accepted the reduction in ice sample with the understanding that replicate coring would be able to provide extra sample volume in key intervals. The WAIS Divide effort would particularly benefit from replicate coring, because of the unique quality of the expected gas record and the large samples needed for gases and gas isotopes; thus this proposal to employ replicate coring at WAIS Divide. In addition, scientific demand for ice samples has been, and will continue to be, very unevenly distributed, with the ice core archive being completely depleted in depth intervals of high scientific interest (abrupt climate changes, volcanic sulfate horizons, meteor impact horizons, for example). The broader impacts of the proposed research may include identification of leads and lags between Greenland, tropical, and Antarctic climate change, enabling critical tests of hypotheses for the mechanism of abrupt climate change. Improved understanding of volcanic impacts on atmospheric chemistry and climate may also emerge. This understanding may ultimately help improve climate models and prediction of the Earth System feedback response to ongoing human perturbation in coming centuries. Outreach and public education about climate change are integral components of the PIs\u0027 activities and the proposed work will enhance these efforts. Broader impacts also include education and training of 2 postdoctoral scholars and 1 graduate student, and invaluable field experience for the graduate and undergraduate students who will likely make up the core processing team at WAIS Divide.", "east": -112.09, "geometry": "POINT(-112.09 -79.47)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": false, "keywords": "Ice Core Gas Records; Firn Air Isotopes; LABORATORY; FIELD SURVEYS; Mass Spectrometry; Not provided; FIELD INVESTIGATION; Ice Core; WAIS Divide", "locations": "WAIS Divide", "north": -79.47, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Earth Sciences; Antarctic Earth Sciences; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -79.47, "title": "Collaborative Research: Replicate Coring at WAIS Divide to Obtain Additional Samples at Events of High Scientific Interest", "uid": "p0000751", "west": -112.09}, {"awards": "0944078 Albert, Mary", "bounds_geometry": "POINT(112.05 79.28)", "dataset_titles": "Firn Permeability and Density at WAIS Divide", "datasets": [{"dataset_uid": "609602", "doi": "10.7265/N57942NT", "keywords": "Antarctica; Firn; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Physical Properties; WAIS Divide; WAIS Divide Ice Core", "people": "Albert, Mary R.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Firn Permeability and Density at WAIS Divide", "url": "https://www.usap-dc.org/view/dataset/609602"}], "date_created": "Fri, 15 Aug 2014 00:00:00 GMT", "description": "This award supports a project to investigate the transformations from snow to firn to ice and the underlying physics controlling firn\u0027s ability to store atmospheric samples from the past. Senior researchers, a graduate student, and several undergraduates will make high-resolution measurements of both the diffusivity and permeability profiles of firn cores from several sites in Antarctica and correlate the results with their microstructures quantified using advanced materials characterization techniques (scanning electron microscopy and x-ray computed tomography). The use of cores from different sites will enable us to examine the influence of different local climate conditions on the firn structure. We will use the results to help interpret existing measurements of firn air chemical composition at several sites where firn air measurements exist. There are three closely-linked goals of this project: to quantify the dependence of interstitial transport properties on firn microstructure from the surface down to the pore close-off depth, to determine at what depths bubbles form and entrap air, and investigate the extent to which these features exhibit site-to-site differences, and to use the measurements of firn air composition and firn structure to better quantify the differences between atmospheric composition (present and past), and the air trapped in both the firn and in air bubbles within ice by comparing the results of the proposed work with firn air measurements that have been made at the WAIS Divide and Megadunes sites. The broader impacts of this project are that the study will this study will enable us to elucidate the fundamental controls on the metamorphism of firn microstructure and its impact on processes of gas entrapment that are important to understanding ice core evidence of past atmospheric composition and climate change. The project will form the basis for the graduate research of a PhD student at Dartmouth, with numerous opportunities for undergraduate involvement in cold room measurements and outreach. The investigators have a track record of successfully mentoring women students, and will build on this experience. In conjunction with local earth science teachers, and graduate and undergraduate students will design a teacher-training module on the role of the Polar Regions in climate change. Once developed and tested, this module will be made available to the broader polar research community for their use with teachers in their communities.", "east": -112.05, "geometry": "POINT(-112.05 -79.28)", "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e MICROTOMOGRAPHY; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e MICROSCOPES; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES", "is_usap_dc": true, "keywords": "Firn Air; FIELD SURVEYS; Physics; GROUND-BASED OBSERVATIONS; Antarctica; Megadunes; Tomography; Wais Divide-project; Firn Core; FIELD INVESTIGATION; Not provided; Firn Permeability; LABORATORY; Visual Observations; Ice; Firn; WAIS Divide; Microstructure; Density", "locations": "Antarctica; WAIS Divide", "north": -79.28, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Albert, Mary R.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.28, "title": "Firn Metamorphism: Microstructure and Physical Properties", "uid": "p0000049", "west": -112.05}, {"awards": "0739598 Aydin, Murat; 0739491 Sowers, Todd", "bounds_geometry": null, "dataset_titles": "Alkanes in Firn Air Samples, Antarctica and Greenland; Methane Isotopes in South Pole Firn Air, 2008", "datasets": [{"dataset_uid": "609502", "doi": "10.7265/N55T3HFP", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Isotope; Paleoclimate; Snow/ice; Snow/Ice; South Pole", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": null, "title": "Methane Isotopes in South Pole Firn Air, 2008", "url": "https://www.usap-dc.org/view/dataset/609502"}, {"dataset_uid": "609504", "doi": "10.7265/N5X9287C", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Snow/ice; Snow/Ice; South Pole; WAIS Divide", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Alkanes in Firn Air Samples, Antarctica and Greenland", "url": "https://www.usap-dc.org/view/dataset/609504"}], "date_created": "Thu, 18 Aug 2011 00:00:00 GMT", "description": "This award supports a project to make measurements of methane and other trace gases in firn air collected at South Pole, Antarctica. The analyses will include: methane isotopes (delta-13CH4 and delta-DCH4), light non-methane hydrocarbons (ethane, propane, and n-butane), sulfur gases (COS, CS2), and methyl halides (CH3Cl and CH3Br). The atmospheric burdens of these trace gases reflect changes in atmospheric OH, biomass burning, biogenic activity in terrestrial, oceanic, and wetland ecosystems, and industrial/agricultural activity. The goal of this project is to develop atmospheric histories for these trace gases over the last century through examination of depth profiles of these gases in South Pole firn air. The project will involve two phases: 1) a field campaign at South Pole, Antarctica to drill two firn holes and fill a total of ~200 flasks from depths reaching 120 m, 2) analysis of firn air at University of California, Irvine, Penn State University, and several other collaborating laboratories. Atmospheric histories will be inferred from the measurements using a one dimensional advective/diffusive model of firn air transport. This study will provide new information about the recent changes in atmospheric levels of these gases, providing about a 90 year long time series record that connects the earlier surface and firn air measurements to present day. The project will also explore the possibility of in- situ production of light non-methane hydrocarbons in firn air that is relevant to the interpretation of ice core records. The broader impacts of this research are that it has the potential for significant societal impact by improving our understanding of climate change and man\u0027s input to the atmosphere. The results of this work will be disseminated through the peer review process, and will contribute to environmental assessments, such as the Inter-governmental Panel on Climate Change (IPCC) Climate Assessment and the Word Meteorological Organization (WMO) Stratospheric Ozone Assessment. This research will provide educational opportunities for graduate and undergraduate students, and will contribute to a teacher training program for K-12 teachers in minority school districts.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS", "is_usap_dc": true, "keywords": "FIELD INVESTIGATION; Isotope; Firn Air Chemistry; Firn Air Isotope Measurements; Not provided; LABORATORY; South Pole; Firn; Delta 13C; Carbon-13; Mass Spectrometer; Deuterium; Mass Spectrometry; Firn Air Samples; Carbon; Gas Chromatography; Polar Firn Air; GROUND-BASED OBSERVATIONS; Methane; Antarctica; Firn Air Isotopes; Delta Deuterium; FIELD SURVEYS; Firn Air; Chromatography; Methane Isotopes; Carbon Isotopes; Stable Isotopes", "locations": "Antarctica; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat; Saltzman, Eric; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air", "uid": "p0000162", "west": null}, {"awards": "0440975 Severinghaus, Jeffrey", "bounds_geometry": "POINT(-119.533333 -80.016667)", "dataset_titles": "Nitrogen and Oxygen Gas Isotopes in the Siple Dome and Byrd Ice Cores, Antarctica", "datasets": [{"dataset_uid": "609407", "doi": "10.7265/N55X26V0", "keywords": "Antarctica; Arctic; Atmosphere; Byrd Glacier; Byrd Ice Core; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Nitrogen and Oxygen Gas Isotopes in the Siple Dome and Byrd Ice Cores, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609407"}], "date_created": "Fri, 17 Jul 2009 00:00:00 GMT", "description": "The award supports the development of high-resolution nitrogen and oxygen isotope records on trapped gases in the Byrd and Siple Dome ice cores, and the Holocene part of the GISP2 ice core. The primary scientific goals of this work are to understand the enigmatic d15N anomalies seen thus far in the Siple Dome record at 15.3 ka and 35 ka, and to find other events that may occur in both cores. At these events, d15N of trapped air approaches zero, implying little or no gravitational fractionation of gases in the firn layer at the time of formation of the ice. These events may represent times of low accumulation rate and arid meteorological conditions, and thus may contain valuable information about the climatic history of West Antarctica. Alternatively, they may stem from crevassing and thus may reveal ice-dynamical processes. Finding the events in the Byrd core, which is located 500 km from Siple Dome, would place powerful constraints on their origin and significance. A second major goal is to explore the puzzling absence of the abrupt warming event at 22 ka (seen at Siple Dome) in the nearby Byrd 18O/16O record in the ice (d18Oice), and search for a possible correlative signal in Byrd d15N. A third goal takes advantage of the fact that precise measurements of the oxygen isotopic composition of atmospheric O2 (d18Oatm) are obtained as a byproduct of the d15N measurement. The proposed gas-isotopic measurements will underpin an integrated suite of West Antarctic climate and atmospheric gas records, which will ultimately include the WAIS Divide core. These records will help separate regional from global climate signals, and may place constraints on the cause of abrupt climate change. Education of two graduate students, and training of two staff members in the laboratory, contribute to the nation\u0027s human resource base. Education and outreach will be an important component of the project.", "east": -119.533333, "geometry": "POINT(-119.533333 -80.016667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Firn Air Isotopes; Not provided; Nitrogen Isotopes; LABORATORY; Firn Isotopes; Paleoclimate; FIELD SURVEYS; Ice Core; Oxygen Isotope; FIELD INVESTIGATION; Siple Dome", "locations": "Antarctica; Siple Dome", "north": -80.016667, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -80.016667, "title": "Nitrogen and oxygen gas isotopes in the Siple Dome and Byrd ice cores", "uid": "p0000450", "west": -119.533333}, {"awards": "9814810 Bales, Roger", "bounds_geometry": "POLYGON((-124 -76,-120 -76,-116 -76,-112 -76,-108 -76,-104 -76,-100 -76,-96 -76,-92 -76,-88 -76,-84 -76,-84 -77.4,-84 -78.8,-84 -80.2,-84 -81.6,-84 -83,-84 -84.4,-84 -85.8,-84 -87.2,-84 -88.6,-84 -90,-88 -90,-92 -90,-96 -90,-100 -90,-104 -90,-108 -90,-112 -90,-116 -90,-120 -90,-124 -90,-124 -88.6,-124 -87.2,-124 -85.8,-124 -84.4,-124 -83,-124 -81.6,-124 -80.2,-124 -78.8,-124 -77.4,-124 -76))", "dataset_titles": "Atmospheric Mixing Ratios of Hydroperoxides above the West Antarctic Ice Sheet; Twenty-Three Century-scale Ice Core Records of Hydrogen Peroxide (H2O2) from West Antarctica", "datasets": [{"dataset_uid": "609392", "doi": "10.7265/N5TM7826", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS", "people": "Frey, Markus; McConnell, Joseph; Bales, Roger", "repository": "USAP-DC", "science_program": null, "title": "Twenty-Three Century-scale Ice Core Records of Hydrogen Peroxide (H2O2) from West Antarctica", "url": "https://www.usap-dc.org/view/dataset/609392"}, {"dataset_uid": "609394", "doi": "10.7265/N5PZ56RS", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; ITASE; WAIS", "people": "Bales, Roger; Frey, Markus; McConnell, Joseph", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric Mixing Ratios of Hydroperoxides above the West Antarctic Ice Sheet", "url": "https://www.usap-dc.org/view/dataset/609394"}], "date_created": "Mon, 01 Jun 2009 00:00:00 GMT", "description": "This award supports a project to improve understanding of atmospheric photochemistry over West Antarctica, as recorded in snow, firn and ice. Atmospheric and firn sampling will be undertaken as part of the U.S. International Trans-Antarctic Scientific Expedition (US ITASE) traverses. Measurements of hydrogen peroxide (H2O2) and formaldehyde (HCHO) will be made on these samples and a recently developed, physically based atmosphere-to-snow transfer model will be used to relate photochemical model estimates of these components to the concentrations of these parameters in the atmosphere and snow. The efficiency of atmosphere-to-snow transfer and the preservation of these components is strongly related to the rate and timing of snow accumulation. This information will be obtained by analyzing the concentration of seasonally dependent species such as hydrogen peroxide, nitric acid and stable isotopes of oxygen. Collection of samples along the US ITASE traverses will allow sampling at a wide variety of locations, reflecting both a number of different depositional environments and covering much of the West Antarctic region.", "east": -84.0, "geometry": "POINT(-104 -83)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUORESCENCE SPECTROSCOPY; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS SENSORS", "is_usap_dc": true, "keywords": "Ice Core; Ice Core Chemistry; FIELD INVESTIGATION; FIELD SURVEYS; Antarctica; West Antarctica; Antarctic; LABORATORY; Ice Core Gas Records; Not provided; Ice Core Data; Polar Firn Air; Hydrogen Peroxide; West Antarctic Ice Sheet; Shallow Firn Air; US ITASE; Antarctic Ice Sheet; Snow Chemistry", "locations": "Antarctica; West Antarctica; Antarctic; Antarctic Ice Sheet; West Antarctic Ice Sheet", "north": -76.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Bales, Roger; Frey, Markus; McConnell, Joseph", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Hydrogen Peroxide, Formaldehyde, and Sub-Annual Snow Accumulation in West Antarctica: Participation in West Antarctic Traverse", "uid": "p0000253", "west": -124.0}, {"awards": "0440759 Sowers, Todd; 0440602 Saltzman, Eric; 0440701 Severinghaus, Jeffrey; 0440509 Battle, Mark; 0440498 White, James; 0440615 Brook, Edward J.", "bounds_geometry": "POINT(-112.085 -79.467)", "dataset_titles": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane Isotopes from the WAIS Divide Ice Core; Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A; WAIS ice core Methane Data, Carbon Dioxide Data", "datasets": [{"dataset_uid": "609638", "doi": "10.7265/N56971HF", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS Divide; WAIS Divide Ice Core", "people": "Orsi, Anais J.; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A", "url": "https://www.usap-dc.org/view/dataset/609638"}, {"dataset_uid": "609412", "doi": "10.7265/N5251G40", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609412"}, {"dataset_uid": "609435", "doi": "10.7265/N5J67DW0", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Methane Isotopes from the WAIS Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609435"}, {"dataset_uid": "609493", "doi": "10.7265/N5319SV3", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Mitchell, Logan E; McConnell, Joseph; Brook, Edward J.; Taylor, Kendrick C.; Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS ice core Methane Data, Carbon Dioxide Data", "url": "https://www.usap-dc.org/view/dataset/609493"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}], "date_created": "Tue, 03 Feb 2009 00:00:00 GMT", "description": "This award supports a project to measure the elemental and isotopic composition of firn air and occluded air in shallow boreholes and ice cores from the WAIS Divide site, the location of a deep ice-coring program planned for 2006-07 and subsequent seasons. The three primary objectives are: 1) to establish the nature of firn air movement and trapping at the site to aid interpretations of gas data from the deep core; 2) to expand the suite of atmospheric trace gas species that can be measured in ice and replicate existing records of other species; and 3) to inter-calibrate all collaborating labs to insure that compositional and isotopic data sets are inter-comparable. The program will be initiated with a shallow drilling program during the 05/06 field season which will recover two 300+m cores and firn air samples. The ice core and firn air will provide more than 700 years of atmospheric history that will be used to address a number of important questions related to atmospheric change over this time period. The research team consists of six US laboratories that also plan to participate in the deep core program. This collaborative research program has a number of advantages. First, the scientists will be able to coordinate sample allocation a priori to maximize the resolution and overlap of records of interrelated species. Second, sample registration will be exact, allowing direct comparison of all records. Third, a coherent data set will be produced at the same time and all PI.s will participate in interpreting and publishing the results. This will insure that the best possible understanding of gas records at the WAIS Divide site will be achieved, and that all work necessary to interpret the deep core is conducted in a timely fashion. The collaborative structure created by the proposal will encourage sharing of techniques, equipment, and ideas between the laboratories. The research will identify impacts of various industrial/agricultural activities and help to distinguish them from natural variations, and will include species for which there are no long records of anthropogenic impact. The work will also help to predict future atmospheric loadings. The project will contribute to training scientists at several levels, including seven undergraduates, two graduate students and one post doctoral fellow.", "east": -112.085, "geometry": "POINT(-112.085 -79.467)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e SPECTROMETERS/RADIOMETERS \u003e SPECTROMETERS \u003e SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; WAIS Divide; Firn; LABORATORY; Ice Core; Firn Air Isotope Measurements; Shallow Firn Air; FIELD INVESTIGATION; Ice Core Gas Records; GROUND-BASED OBSERVATIONS; Firn Isotopes; Wais Divide-project; Gas Data; Polar Firn Air; Not provided; Trace Gas Species; Trapped Gases; West Antarctic Ice Sheet; Deep Core; Ice Sheet; Gas; Firn Air Isotopes; FIELD SURVEYS; Air Samples; Atmospheric Gases; Isotope; Cores; Atmosphere; Ice Core Data; Surface Temperatures; Firn Air; Borehole; Antarctica", "locations": "West Antarctic Ice Sheet; Antarctica; WAIS Divide", "north": -79.467, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Battle, Mark; Mischler, John; Saltzman, Eric; Aydin, Murat; White, James; Brook, Edward J.; Orsi, Anais J.; Severinghaus, Jeffrey P.; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.467, "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "uid": "p0000368", "west": -112.085}, {"awards": "0636953 Saltzman, Eric", "bounds_geometry": "POINT(-148.82 -81.66)", "dataset_titles": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core; Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core; Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core; Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica; Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "datasets": [{"dataset_uid": "609599", "doi": "10.7265/N5S75D8P", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609599"}, {"dataset_uid": "601361", "doi": "10.15784/601361", "keywords": "Antarctica; Carbonyl Sulfide; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/601361"}, {"dataset_uid": "609598", "doi": "10.7265/N5X0650D", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609598"}, {"dataset_uid": "609600", "doi": "10.7265/N5PG1PPB", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609600"}, {"dataset_uid": "609356", "doi": "10.7265/N56W9807", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Aydin, Murat; Williams, Margaret; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609356"}], "date_created": "Wed, 22 Oct 2008 00:00:00 GMT", "description": "Saltzman/0636953\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to measure methyl chloride, methyl bromide, and carbonyl sulfide in air extracted from Antarctic ice cores. Previous measurements in firn air and shallow ice cores suggest that the ice archive contains paleo-atmospheric signals for these gases. The goal of this study is to extend these records throughout the Holocene and into the last Glacial period to examine the behavior of these trace gases over longer time scales and a wider range of climatic conditions. These studies are exploratory, and both the stability of these trace gases and the extent to which they may be impacted by in situ processes will be assessed. This project will involve sampling and analyzing archived ice core samples from the Siple Dome, Taylor Dome, Byrd, and Vostok ice cores. The ice core samples will be analyzed by dry extraction, with gas chromatography/mass spectrometry with isotope dilution. The ice core measurements will generate new information about the range of natural variability of these trace gases in the atmosphere. The intellectual merit of this project is that this work will provide an improved basis for assessing the impact of anthropogenic activities on biogeochemical cycles, and new insight into the climatic sensitivity of the biogeochemical processes controlling atmospheric composition. The broader impact of this project is that there is a strong societal interest in understanding how man\u0027s activities impact the atmosphere, and how atmospheric chemistry may be altered by future climate change. The results of this study will contribute to the development of scenarios used for future projections of stratospheric ozone and climate change. In terms of human development, this project will support the doctoral dissertation of a graduate student in Earth System Science, and undergraduate research on polar ice core chemistry. This project will also contribute to the development of an Earth Sciences teacher training curriculum for high school teachers in the Orange County school system in collaboration with an established, NSF-sponsored Math and Science Partnership program (FOCUS).", "east": -148.82, "geometry": "POINT(-148.82 -81.66)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Methyl Bromide; Antarctic; Ice Core Gas Records; Ice Core Data; Carbonyl Sulfide; Methyl Chloride; Antarctic Ice Sheet; Siple Dome; Trace Gases; Ice Core Chemistry; Biogeochemical; Atmospheric Chemistry; West Antarctic Ice Sheet; LABORATORY; Ice Core; West Antarctica", "locations": "Antarctic; Antarctica; Antarctic Ice Sheet; Siple Dome; West Antarctica; West Antarctic Ice Sheet", "north": -81.66, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core; Siple Dome Ice Core", "south": -81.66, "title": "Methyl Chloride, Methyl Bromide, and Carbonyl Sulfide in Deep Antarctic Ice Cores", "uid": "p0000042", "west": -148.82}, {"awards": "9526556 Sowers, Todd", "bounds_geometry": "POINT(-148.3023 -81.403)", "dataset_titles": "Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica", "datasets": [{"dataset_uid": "609310", "doi": "10.7265/N5ST7MR2", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Siple Dome; Snow/ice; Snow/Ice; South Pole", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609310"}], "date_created": "Mon, 09 Jul 2007 00:00:00 GMT", "description": "This award is for support for a program to reconstruct records of the isotopic composition of paleoatmospheric methane and nitrous oxide covering the last 200,000 years. High resolution measurements of the carbon-13 isotopic composition of methane from shallow ice cores will help to determine the relative contributions of biogenic (wetlands, rice fields and ruminants) and abiogenic (biomass burning and natural gas) methane emissions which have caused the concentrations of this gas to increase at an exponential rate during the anthropogenic period. Isotopic data on methane and nitrous oxide over glacial/interglacial timescales will help determine the underlying cause of the large concentration variations that are known to occur. This project will make use of a new generation mass spectrometer which is capable of generating precise isotopic information on nanomolar quantities of methane and nitrous oxide, which means that samples can be 1000 times smaller than those needed for a standard isotope ratio instrument. The primary objective of the work is to further our understanding of the biogeochemical cycles of these two greenhouse gases throughout the anthropogenic period as well as over glacial interglacial timescales.", "east": -148.3023, "geometry": "POINT(-148.3023 -81.403)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core; Firn Air Isotope Measurements; Ice Core Chemistry; Firn Isotopes; Stable Isotopes; Methane; Carbon; Paleoclimate; LABORATORY; Siple Dome; Antarctica; Ice Core Data; Firn Air Isotopes; Antarctic Ice Sheet", "locations": "Antarctica; Antarctic Ice Sheet; Siple Dome", "north": -81.403, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Sowers, Todd A.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.403, "title": "Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide", "uid": "p0000611", "west": -148.3023}, {"awards": "0230452 Severinghaus, Jeffrey", "bounds_geometry": "POINT(124.5 -80.78)", "dataset_titles": "Antarctic megadunes", "datasets": [{"dataset_uid": "000191", "doi": "", "keywords": null, "people": null, "repository": "NSIDC", "science_program": null, "title": "Antarctic megadunes", "url": "http://nsidc.org/antarctica/megadunes/"}], "date_created": "Wed, 27 Sep 2006 00:00:00 GMT", "description": "This award supports a study of the chemical composition of air in the snow layer (firn) in a region of \"megadunes\" near Vostok station, Antarctica. It will test the hypothesis that a deep \"convective zone\" of vigorous wind-driven mixing can prevent gas fractionation in the upper one-third of the polar firn layer. In the megadunes, ultralow snow accumulation rates lead to structural changes (large grains, pipes, and cracks) that make the permeability of firn to air movement orders of magnitude higher than normal. The unknown thickness of the convective zone has hampered the interpretation of ice core 15N/14N and 40Ar/36Ar ratios as indicators of past firn thickness, which is a key constraint on the climatically important variables of temperature, accumulation rate, and gas age-ice age difference. Studying this \"extreme end-member\" example will better define the role of the convective zone in gas reconstructions. This study will pump air from a profile of ~20 depths in the firn, to definitively test for the presence of a convective zone based on the fit of observed 15 N/14N and 40Ar/36Ar to a molecular- and eddy-diffusion model. Permeability measurements on the core and 2-D air flow modeling (in collaboration with M. Albert) will permit a more physically realistic interpretation of the isotope data and will relate mixing vigor to air velocities. A new proxy indicator of convective zone thickness will be tested on firn and ice core bubble air, based on the principle that isotopes of slow-diffusing heavy noble gases (Kr, Xe) should be more affected by convection than isotopes of fast-diffusing N2 . These tools will be applied to a test of the hypothesis that the megadunes and a deep convective zone existed at the Vostok site during glacial periods, which would explain the anomalously low 15N/14N and 40Ar/36Ar in the Vostok ice core glacial periods. The broader impacts of this work include 1) clarification of phase relationships of greenhouse gases and temperature in ice core records, with implications for understanding of past and future climates, 2) education of one graduate student, and 3) building of collaborative relationships with five investigators.", "east": 124.5, "geometry": "POINT(124.5 -80.78)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS", "is_usap_dc": false, "keywords": "Antarctica; Methane; Carbon-14; Permeability; CO2; Firn Core; FIELD SURVEYS; Deuterium Excess; GROUND-BASED OBSERVATIONS; LABORATORY; Isotope; Ice Core Density; Firn Air; Megadunes; Ice Core; Not provided; FIELD INVESTIGATION", "locations": "Antarctica", "north": -80.78, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Bauer, Rob; Albert, Mary R.; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "NSIDC", "repositories": "NSIDC", "science_programs": null, "south": -80.78, "title": "How Thick Is the Convective Zone: A Study of Firn Air in the Megadunes Near Vostok, Antarctica", "uid": "p0000097", "west": 124.5}, {"awards": "0230260 Bender, Michael; 0230448 Severinghaus, Jeffrey", "bounds_geometry": "POLYGON((-75.34 86.6,-68.742 86.6,-62.144 86.6,-55.546 86.6,-48.948 86.6,-42.35 86.6,-35.752 86.6,-29.154 86.6,-22.556 86.6,-15.958 86.6,-9.36 86.6,-9.36 83.618,-9.36 80.636,-9.36 77.654,-9.36 74.672,-9.36 71.69,-9.36 68.708,-9.36 65.726,-9.36 62.744,-9.36 59.762,-9.36 56.78,-15.958 56.78,-22.556 56.78,-29.154 56.78,-35.752 56.78,-42.35 56.78,-48.948 56.78,-55.546 56.78,-62.144 56.78,-68.742 56.78,-75.34 56.78,-75.34 59.762,-75.34 62.744,-75.34 65.726,-75.34 68.708,-75.34 71.69,-75.34 74.672,-75.34 77.654,-75.34 80.636,-75.34 83.618,-75.34 86.6))", "dataset_titles": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001; Trapped Gas Composition and Chronology of the Vostok Ice Core", "datasets": [{"dataset_uid": "609311", "doi": "10.7265/N5P26W12", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Lake Vostok; Paleoclimate; Vostok; Vostok Ice Core", "people": "Suwa, Makoto; Bender, Michael", "repository": "USAP-DC", "science_program": null, "title": "Trapped Gas Composition and Chronology of the Vostok Ice Core", "url": "https://www.usap-dc.org/view/dataset/609311"}, {"dataset_uid": "609290", "doi": "10.7265/N5FJ2DQC", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciology; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole", "people": "Bender, Michael; Severinghaus, Jeffrey P.; Battle, Mark", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001", "url": "https://www.usap-dc.org/view/dataset/609290"}], "date_created": "Wed, 18 Jan 2006 00:00:00 GMT", "description": "High latitude deep ice cores contain fundamental records of polar temperatures, atmospheric dust loads (and continental aridity), greenhouse gas concentrations, the status of the biosphere, and other essential properties of past environments. An accurate chronology for these records is needed if their significance is to be fully realized. The dating challenge has stimulated efforts at orbital tuning. In this approach, one varies a timescale, within allowable limits, to optimize the match between a paleoenvironmental property and a curve of insolation through time. The ideal property would vary with time due to direct insolation forcing. It would be unaffected by complex climate feedbacks and teleconnections, and it would give a clean record with high signal/noise ratio. It is argued strongly that the O2/N2 ratio of ice core trapped gases is such a property, and evidence is presented that this property, whose atmospheric ratio is nearly constant, is tied to local summertime insolation. This award will support a project to analyze the O2/N2 ratios at 1 kyr intervals from ~ 115-400 ka in the Vostok ice core. Ancillary measurements will be made of Ar/N2, and Ne/N2 and heavy noble gas ratios, in order to understand bubble close-off fractionation and its manifestation in the Vostok trapped gas record. O2/N2 variations will be matched with summertime insolation at Vostok to achieve a high-accuracy chronology for the Vostok core. The Vostok and other correlatable climate records will then be reexamined to improve our understanding of the dynamics of Pleistocene climate change.", "east": 106.8, "geometry": "POINT(106.8 -72.4667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Paleoclimate; Siple Dome; Ice Age; Shallow Firn Air; Firn Air Isotope Measurements; Polar Firn Air; Ice Sample Gas Integrity; Oxygen Isotope; Noble Gas; Ice Core Gas Records; Atmospheric Gases; Trapped Gases; Not provided; LABORATORY; Vostok; Firn Air Isotopes; Thermal Fractionation; Ice Core Chemistry; Trapped Air Bubbles; Ice Core; Antarctica; South Pole; Ice Core Data; GROUND-BASED OBSERVATIONS; Gas Age; Firn Isotopes", "locations": "Antarctica; Vostok; Siple Dome; South Pole", "north": -72.4667, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Bender, Michael; Suwa, Makoto; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -72.4667, "title": "Collaborative Research: Trapped Gas Composition and the Chronology of the Vostok Ice Core", "uid": "p0000257", "west": 106.8}, {"awards": "0125276 Albert, Mary; 0125570 Scambos, Ted", "bounds_geometry": null, "dataset_titles": "Access AGDC data online by navigating to Data Sets. Data sets are arranged by Principal Investigators. Access data that are combined into multiple data sets, or compiled products.; AWS Data: Characteristics of Snow Megadunes and Their Potential Effect on Ice Core Interpretation; GPR and GPS Data: Characteristics of Snow Megadunes and their Potential Effects on Ice Core Interpretation; Snow and Firn Permeability: Characteristics of Snow Megadunes and their Potential Effects on Ice Core Interpretation; The Antarctic Glaciological Data Center (AGDC) at the National Snow and Ice Data Center (NSIDC) archives and distributes Antarctic glaciological and cryospheric system data collected by the U.S. Antarctic Program.", "datasets": [{"dataset_uid": "609283", "doi": "10.7265/N5K935F3", "keywords": "Antarctica; Atmosphere; East Antarctic Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Meteorology; Snow/ice; Snow/Ice", "people": "Haran, Terry; Scambos, Ted; Bauer, Rob; Fahnestock, Mark", "repository": "USAP-DC", "science_program": null, "title": "AWS Data: Characteristics of Snow Megadunes and Their Potential Effect on Ice Core Interpretation", "url": "https://www.usap-dc.org/view/dataset/609283"}, {"dataset_uid": "609282", "doi": "10.7265/N5Q23X5F", "keywords": "Antarctica; East Antarctic Plateau; Glaciology; GPR; GPS; Navigation; Paleoclimate; Snow/ice; Snow/Ice", "people": "Scambos, Ted; Bauer, Rob", "repository": "USAP-DC", "science_program": null, "title": "GPR and GPS Data: Characteristics of Snow Megadunes and their Potential Effects on Ice Core Interpretation", "url": "https://www.usap-dc.org/view/dataset/609282"}, {"dataset_uid": "001343", "doi": "", "keywords": null, "people": null, "repository": "NSIDC", "science_program": null, "title": "The Antarctic Glaciological Data Center (AGDC) at the National Snow and Ice Data Center (NSIDC) archives and distributes Antarctic glaciological and cryospheric system data collected by the U.S. Antarctic Program.", "url": "https://nsidc.org/data/agdc/"}, {"dataset_uid": "609299", "doi": "10.7265/N5639MPD", "keywords": "Antarctica; East Antarctic Plateau; Glaciology; Physical Properties; Snow/ice; Snow/Ice", "people": "Cathles, Mac; Albert, Mary R.; Courville, Zoe", "repository": "USAP-DC", "science_program": null, "title": "Snow and Firn Permeability: Characteristics of Snow Megadunes and their Potential Effects on Ice Core Interpretation", "url": "https://www.usap-dc.org/view/dataset/609299"}, {"dataset_uid": "001669", "doi": "", "keywords": null, "people": null, "repository": "NSIDC", "science_program": null, "title": "Access AGDC data online by navigating to Data Sets. Data sets are arranged by Principal Investigators. Access data that are combined into multiple data sets, or compiled products.", "url": "http://nsidc.org/data/agdc_investigators.html"}], "date_created": "Wed, 04 Jan 2006 00:00:00 GMT", "description": "This award supports a program of field surveys of an area within the large, well-developed megadune field southeast of Vostok station. The objectives are to determine the physical characteristics of the firn across the dunes, including typical climate indicators such as stable isotopes and major chemical species, and to install instruments to measure the time variation of near-surface wind and temperature with depth, to test and refine hypotheses for megadune formation. Field study will consist of surface snowpit and shallow core sampling, ground penetrating radar (GPR) profiling, GPS topographic and ice motion surveys, AWS installation, accumulation/ ablation measurements, subsurface temperature, and firn permeability studies. Field work in two successive seasons is proposed. Continent-wide remote sensing studies of the dunes will be continued, using the new group of instruments that are now, or will shortly be available (e.g., MODIS, MISR, GLAS, AMSR). The earlier study of topographic, passive microwave, and SAR characteristics will be extended, with the intent of determining the relationships of dune amplitude and wavelength to climate parameters, and further development of models of dune formation. Diffusion, ventilation, and vapor transport processes within the dune firn will be modeled as well. A robust program of outreach is planned and reporting to inform both the public and scientists of the fundamental in-situ and remote sensing characteristics of these uniquely Antarctic features will be an important part of the work. Because of their extreme nature, their broad extent, and their potential impact on the climate record, it is important to improve our current understanding of these. Megadunes are a manifestation of an extreme terrestrial climate and may provide insight on past terrestrial climate, or to processes active on other planets. Megadunes are likely to represent an end-member in firn diagenesis, and as such, may have much to teach us about the processes involved.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e RECORDERS/LOGGERS \u003e AWS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e ICE AUGERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e SNOWPACK TEMPERATURE PROBE; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e PERMEAMETERS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e CAMERAS \u003e CAMERAS; IN SITU/LABORATORY INSTRUMENTS \u003e CURRENT/WIND METERS \u003e ANEMOMETERS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS RECEIVERS; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e RADAR SOUNDERS \u003e RADAR; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e IMAGING RADARS \u003e SAR; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e RADAR SOUNDERS \u003e GPR; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e AIR PERMEAMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CURRENT/WIND METERS \u003e ANEMOMETERS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e RADIO \u003e ARGOS; IN SITU/LABORATORY INSTRUMENTS \u003e PRESSURE/HEIGHT METERS \u003e PRESSURE SENSORS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMOMETERS \u003e THERMOMETERS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e WIND PROFILERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e DENSIOMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e GAUGES \u003e BALANCE", "is_usap_dc": true, "keywords": "Internal Layering; ICESAT; Vapor-Redeposition; Antarctic; Wind Speed; FIELD INVESTIGATION; Surface Morphology; Antarctica; GROUND-BASED OBSERVATIONS; ARWS; Polar Firn Air; Microstructure; Gas Diffusivity; WEATHER STATIONS; Surface Temperatures; RADARSAT-2; Ice Core; Wind Direction; AWS; Ice Sheet; Snow Pit; Dunefields; Climate Record; Megadunes; GROUND STATIONS; METEOROLOGICAL STATIONS; Antarctic Ice Sheet; Density; Atmospheric Pressure; Firn Permeability; FIELD SURVEYS; Radar; Permeability; Field Survey; Firn Temperature Measurements; Snow Megadunes; Thermal Conductivity; LANDSAT; Firn; Ice Core Interpretation; East Antarctic Plateau; Not provided; Surface Winds; Sublimation; Snow Density; Ice Climate Record; Glaciology; Snow Permeability; Air Temperature; Paleoenvironment; Automated Weather Station", "locations": "Antarctica; Antarctic Ice Sheet; Antarctic; East Antarctic Plateau", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Courville, Zoe; Cathles, Mac; Scambos, Ted; Bauer, Rob; Fahnestock, Mark; Haran, Terry; Shuman, Christopher A.; Albert, Mary R.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e ARWS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e METEOROLOGICAL STATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e WEATHER STATIONS; Not provided; SPACE-BASED PLATFORMS \u003e EARTH OBSERVATION SATELLITES \u003e ICE, CLOUD AND LAND ELEVATION SATELLITE (ICESAT) \u003e ICESAT; SPACE-BASED PLATFORMS \u003e EARTH OBSERVATION SATELLITES \u003e LANDSAT \u003e LANDSAT; SPACE-BASED PLATFORMS \u003e EARTH OBSERVATION SATELLITES \u003e RADARSAT \u003e RADARSAT-2", "repo": "USAP-DC", "repositories": "NSIDC; USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Characteristics of Snow Megadunes and Their Potential Effect on Ice Core Interpretation", "uid": "p0000587", "west": null}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}, {"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}, {"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Aydin, Murat; Williams, Margaret; Tatum, Cheryl; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; Carbonyl Sulfide; Siple Coast; Chloride; Trapped Gases; Snow; Ice Core Chemistry; Chromatography; Siple; GROUND STATIONS; Atmospheric Gases; Ozone Depletion; AWS Siple; Ice Sheet; Ice Core Data; Antarctica; Glaciology; West Antarctica; Atmospheric Chemistry; Ice Core; Stratigraphy; LABORATORY; Methane; Mass Spectrometer; GROUND-BASED OBSERVATIONS; WAISCORES; Msa; Mass Spectrometry; Not provided; Siple Dome; Gas Measurement", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica; Siple", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}, {"awards": "0125981 Sowers, Todd", "bounds_geometry": "POLYGON((-180 -62.83,-144 -62.83,-108 -62.83,-72 -62.83,-36 -62.83,0 -62.83,36 -62.83,72 -62.83,108 -62.83,144 -62.83,180 -62.83,180 -65.547,180 -68.264,180 -70.981,180 -73.698,180 -76.415,180 -79.132,180 -81.849,180 -84.566,180 -87.283,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.283,-180 -84.566,-180 -81.849,-180 -79.132,-180 -76.415,-180 -73.698,-180 -70.981,-180 -68.264,-180 -65.547,-180 -62.83))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 05 May 2005 00:00:00 GMT", "description": "0125981\u003cbr/\u003eSowers\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to construct an isotopic record of atmospheric methane and nitrous oxide over the last century from South Pole firn air. Over the last 150 years, atmospheric methane and nitrous oxide concentrations have risen in response to increased emissions from various anthropogenic activities. As this trend is liable to continue in the foreseeable future, it is important to understand the biogeochemical processes that contribute to the emissions of these two greenhouse gases. In this context, records of the variations in the atmospheric loading of trace gases found in ice cores and interstitial spaces in the snow near the surface of the ice sheet (firn air) provide fundamental boundary conditions for reconstructing historical emission records. One way to improve our understanding of the cycling of bioactive trace gases and their emission records is to use stable isotope tracers, which have been recorded in the ice cores and firn air. This project will develop records of carbon-13 and deuterium isotope ratios of methane, as well as the nitrogen-15, oxygen-18 and the isotopomer composition of nitrous oxide trapped in firn air samples collected in January 2001 at the South Pole. These measurements will allow isotopic records of these atmospheric gases to be reconstructed throughout the 20th century. Such records will help to establish the relative contribution of individual sources with a higher degree of confidence than is currently available.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": -62.83, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Sowers, Todd A.", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -90.0, "title": "Generating an Isotopic Record of Atmospheric Methane and Nitrous Oxide Over the Last Century from South Pole Firn Air", "uid": "p0000086", "west": -180.0}, {"awards": "9714687 Brook, Edward J.", "bounds_geometry": null, "dataset_titles": "Byrd Ice Core Microparticle and Chemistry Data", "datasets": [{"dataset_uid": "609247", "doi": "", "keywords": "Antarctica; Byrd; Byrd Ice Core; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate", "people": "Blunier, Thomas; Thompson, Lonnie G.; Brook, Edward J.; Fluckiger, Jacqueline", "repository": "USAP-DC", "science_program": "Byrd Ice Core", "title": "Byrd Ice Core Microparticle and Chemistry Data", "url": "https://www.usap-dc.org/view/dataset/609247"}], "date_created": "Thu, 26 Aug 2004 00:00:00 GMT", "description": "This award is for support for a program to make high resolution studies of variations in the concentration of methane, the oxygenisotope composition of paleoatmospheric oxygen, and the total gas content of deep Antarctic ice cores. Studies of the concentration and isotopic composition of air in the firn of the Antarctic ice sheet will also be continued. One objective of this work is to use the methane concentration and oxygen-isotope composition of oxygen of air in ice as time-stratigraphic markers for the precise intercorrelation of Greenland and Antarctic ice cores as well as the correlation of ice cores to other climatic records. A second objective is to use variations in the concentration and interhemispheric gradient of methane measured in Greenland and Antarctic ice cores to deduce changes in continental climates and biogeochemistry on which the atmospheric methane distribution depends. A third objective is to use data on the variability of total gas content in the Siple Dome ice core to reconstruct aspects of the glacial history of West Antarctica during the last glacial maximum. The fourth objective is to participate in collaborative studies of firn air chemistry at Vostok, Siple Dome, and South Pole which will yield much new information about gas trapping in ice as well as the concentration history and isotopic composition of greenhouse gases, oxygen, trace biogenic gases and trace anthropogenic gases during the last 100 years.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "GROUND STATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Blunier, Thomas; Fluckiger, Jacqueline; Thompson, Lonnie G.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Studies of Trapped Gases in Firn and Ice from Antarctic Deep Ice Cores", "uid": "p0000168", "west": null}, {"awards": "9725305 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "datasets": [{"dataset_uid": "609098", "doi": "10.7265/N51N7Z2P", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciology; Isotope; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole; Temperature", "people": "Battle, Mark; Severinghaus, Jeffrey P.; Grachev, Alexi", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "url": "https://www.usap-dc.org/view/dataset/609098"}], "date_created": "Mon, 01 Jan 2001 00:00:00 GMT", "description": "9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Isotopic History; GROUND STATIONS; Thermal Diffusion; Firn Temperature Measurements; Not provided; Oxygen Isotope; Trapped Air Bubbles; Shallow Firn Air; Firn Air Isotope Measurements; Seasonal Temperature Gradients; Mass Spectrometry; GROUND-BASED OBSERVATIONS; Thermal Fractionation; Polar Firn Air; Isotopic Anomalies; Xenon; Atmospheric Gases; Argon Isotopes; Siple Dome; Krypton; Nitrogen Isotopes; Seasonal Temperature Changes; Antarctica; Ice Core Gas Records; Firn Air Isotopes; Mass Spectrometer; South Pole; Firn Isotopes; Borehole", "locations": "Antarctica; Siple Dome; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change", "uid": "p0000160", "west": null}]

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