USAP-DC

{"dp_type": "Project", "free_text": "Atmospheric Chemistry"}

[{"awards": "1841228 Lyons, W. Berry", "bounds_geometry": "POLYGON((163.37428 -77.558627,163.3922735 -77.558627,163.410267 -77.558627,163.4282605 -77.558627,163.446254 -77.558627,163.4642475 -77.558627,163.482241 -77.558627,163.5002345 -77.558627,163.518228 -77.558627,163.5362215 -77.558627,163.554215 -77.558627,163.554215 -77.56397510000001,163.554215 -77.5693232,163.554215 -77.5746713,163.554215 -77.5800194,163.554215 -77.5853675,163.554215 -77.59071560000001,163.554215 -77.5960637,163.554215 -77.60141180000001,163.554215 -77.6067599,163.554215 -77.612108,163.5362215 -77.612108,163.518228 -77.612108,163.5002345 -77.612108,163.482241 -77.612108,163.4642475 -77.612108,163.446254 -77.612108,163.4282605 -77.612108,163.410267 -77.612108,163.3922735 -77.612108,163.37428 -77.612108,163.37428 -77.6067599,163.37428 -77.60141180000001,163.37428 -77.5960637,163.37428 -77.59071560000001,163.37428 -77.5853675,163.37428 -77.5800194,163.37428 -77.5746713,163.37428 -77.5693232,163.37428 -77.56397510000001,163.37428 -77.558627))", "dataset_titles": "Commonwealth Stream Diel Water Chemistry; Hyporheic zone geochemistry of Wales Stream, Taylor Valley, Antarctica; isotopic signature of massive buried ice, eastern Taylor Valley, Antarctica", "datasets": [{"dataset_uid": "601844", "doi": "10.15784/601844", "keywords": "Antarctica; Commonwealth Stream; Cryosphere; Diel; Inlandwaters; McMurdo Dry Valleys; Stream Chemistry; Water Chemisty", "people": "Gardner, Christopher B.", "repository": "USAP-DC", "science_program": null, "title": "Commonwealth Stream Diel Water Chemistry", "url": "https://www.usap-dc.org/view/dataset/601844"}, {"dataset_uid": "601847", "doi": "10.15784/601847", "keywords": "Antarctica; Cryosphere; Nutrients; Stable Isotopes; Taylor Valley; Trace Elements", "people": "Gardner, Christopher B.", "repository": "USAP-DC", "science_program": null, "title": "Hyporheic zone geochemistry of Wales Stream, Taylor Valley, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601847"}, {"dataset_uid": "601848", "doi": "10.15784/601848", "keywords": "Antarctica; Buried Ice; Cryosphere; Stable Isotopes; Stable Water Isotopes; Taylor Valley", "people": "Gardner, Christopher B.", "repository": "USAP-DC", "science_program": null, "title": "isotopic signature of massive buried ice, eastern Taylor Valley, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601848"}], "date_created": "Wed, 16 Oct 2024 00:00:00 GMT", "description": "Phytoplankton, or microscopic marine algae, are an important part of the carbon cycle and can lower the rates of atmospheric carbon dioxide by transferring the atmospheric carbon into the oceans. The concentration of phytoplankton in the Southern Ocean is regularly limited by the availability of marine iron. This in turn influences the rate of carbon transfer from the atmosphere to the ocean. The primary source of iron in the Southern Ocean is eroded continental rock. Understanding the current and future sources of iron to the Southern Ocean as a result of increased melting of terrestrial glaciers is necessary for predicting future concentrations of Southern Ocean phytoplankton and the subsequent influence on the carbon cycle. A poorly understood source of iron to the Southern Ocean is stream input from ice-free regions such as the McMurdo Dry Valleys in Antarctica. This source of iron is likely to become larger if glaciers retreat. This study investigates the sources and amount of iron transported by McMurdo Dry Valley streams directly into the Southern Ocean. Because not all forms of iron can be used by phytoplankton, experiments will be performed to determine how available iron is to phytoplankton and how iron mixes with seawater. Immersive 360-degree video, infographics, and educational videos of findings from this project will be shared on social media, at schools and science events, and in an urban science center. In the Southern Ocean (SO) there is an excess of macronutrients but regional primary production is limited or co-limited due to iron. An addition of iron to the ocean will affect biochemical cycles, increase primary production, and affect the structure and composition of phytoplankton communities in the SO. Iron flux to the SO is globally significant, as increased Fe fertilization leads to increased carbon sequestration which acts as a negative feedback to increased atmospheric pCO2. One source of potentially bioavailable iron to the coastal regions of the SO is from direct sub-aerial stream discharge in ice-free areas of Antarctica, a source that may become more important if terrestrial glaciers retreat. It is imperative to understand the source, nature, potential fate, and flux of iron to the SO if better predictive models for the carbon cycle and atmospheric chemistry are to be developed. This project will investigate in-stream processes and characteristics controlling dissolved iron draining into the Ross Sea including photoreduction, temperature, and complexation with organic matter. The novel study will quantify bioavailability of particulate iron and bioavailability of dissolved iron in Antarctic in streams draining into the SO. On-site speciation measurements will be performed on dissolved iron species, particulate iron speciation will be determined using high-resolution spectroscopy, mixing experiments will be performed with coastal marine water, and the bioavailability of Fe will be determined through marine bioassays. This project will provide two students with valuable Antarctic field experience and reach thousands of individuals through existing partnerships with K-12 schools, public STEM events, an urban science center, and a strong social media presence. This award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 163.554215, "geometry": "POINT(163.4642475 -77.5853675)", "instruments": null, "is_usap_dc": true, "keywords": "SURFACE WATER CHEMISTRY; Iron Fertilization; McMurdo Dry Valleys; Weathering", "locations": "McMurdo Dry Valleys", "north": -77.558627, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Lyons, W. Berry; Gardner, Christopher B.", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.612108, "title": "Fe Behavior and Bioavailability in Sub-aerial Runoff into the Ross Sea", "uid": "p0010483", "west": 163.37428}, {"awards": "1445205 Putkonen, Jaakko", "bounds_geometry": "POLYGON((157.6 -83.2,157.62 -83.2,157.64 -83.2,157.66 -83.2,157.68 -83.2,157.7 -83.2,157.72 -83.2,157.74 -83.2,157.76 -83.2,157.78 -83.2,157.8 -83.2,157.8 -83.21,157.8 -83.22,157.8 -83.23,157.8 -83.24,157.8 -83.25,157.8 -83.26,157.8 -83.27,157.8 -83.28,157.8 -83.29,157.8 -83.3,157.78 -83.3,157.76 -83.3,157.74 -83.3,157.72 -83.3,157.7 -83.3,157.68 -83.3,157.66 -83.3,157.64 -83.3,157.62 -83.3,157.6 -83.3,157.6 -83.29,157.6 -83.28,157.6 -83.27,157.6 -83.26,157.6 -83.25,157.6 -83.24,157.6 -83.23,157.6 -83.22,157.6 -83.21,157.6 -83.2))", "dataset_titles": "Cosmogenic-Nuclide data at ICE-D; Old Ice, Ong Valley, Transantarctic Mountains", "datasets": [{"dataset_uid": "601665", "doi": "10.15784/601665", "keywords": "Antarctica; Buried Ice; Cosmogenic Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Old Ice; Ong Valley", "people": "Putkonen, Jaakko; Bergelin, Marie", "repository": "USAP-DC", "science_program": null, "title": "Old Ice, Ong Valley, Transantarctic Mountains", "url": "https://www.usap-dc.org/view/dataset/601665"}, {"dataset_uid": "200295", "doi": "", "keywords": null, "people": null, "repository": "ICE-D", "science_program": null, "title": "Cosmogenic-Nuclide data at ICE-D", "url": "https://version2.ice-d.org/antarctica/nsf/"}], "date_created": "Fri, 16 Jul 2021 00:00:00 GMT", "description": "Putkonen/1445205 This award supports the study of a large body of ice that is buried beneath approximately a meter of debris in the Ong Valley of the Transantarctic Mountains of East Antarctica. Preliminary analyses of this material suggest that it could be over a million years old. Most glacial ice contains tiny air bubbles that have trapped the atmospheric gases and other atmospherically transported materials existing at the time that the ice was deposited such as plant pollen, microbes and mineral dust. Samples will be collected from this buried ice mass, down to a depth of 10 meters, and cosmogenic nuclide concentrations both in the overlying debris and in the till contained in the ice will be measured. This site could contain some of the oldest ice on Earth and studies of the material contained within it may help researchers to better understand the processes involved in its survival for such long periods of time. This work will also help inform scientists about the processes involved in the development of landforms here on earth as well as those on Mars where similar dirt covered glaciers are found today. Samples of the buried ice will be collected in Ong Valley and analyzed to determine the cosmogenic nuclide concentrations in both the overlying debris and in the mineral matter suspended in the ice. The combined analysis of the target cosmogenic nuclides (Beryllium-10, Aluminum-26, and Neon-21) will allow the age of the ice to be uniquely determined and will enable determination of the rate that the ice is sublimating. The intellectual merit of this research is to unequivocally determine the age of the ice and the sublimation rate of the ice in Ong Valley, Antarctica and to better understand if this an uniquely Antarctic process or whether it could exist elsewhere on earth or on other planets. The work may also lead to the recognition of the oldest buried ice ever found on Earth and would provide a source from which direct information about the atmospheric chemistry, ancient life forms, and geology of that time could be measured. The broader impacts of this work are that it will be relevant to researchers in a number of different fields including glaciology, paleoclimatology, planetary geology, and biology. Several students will also participate in the project, conducting Antarctic field work, making measurements in the lab, attending meetings, participating in outreach activities, and producing videos. A graduate student will also write a thesis on this research. The results will be published in scientific journals and presented at conferences. The project requires field work in Antarctica.", "east": 157.8, "geometry": "POINT(157.7 -83.25)", "instruments": null, "is_usap_dc": true, "keywords": "USAP-DC; USA/NSF; FIELD SURVEYS; Transantarctic Mountains; GLACIERS/ICE SHEETS; AMD; Amd/Us", "locations": "Transantarctic Mountains", "north": -83.2, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Glaciology", "paleo_time": null, "persons": "putkonen, jaakko; Balco, Gregory; Morgan, Daniel", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS", "repo": "USAP-DC", "repositories": "ICE-D; USAP-DC", "science_programs": null, "south": -83.3, "title": "Collaborative Research: Long Term Sublimation/Preservation of Two Separate, Buried Glacier Ice Masses, Ong Valley, Southern Transantarctic Mountains", "uid": "p0010231", "west": 157.6}, {"awards": "1643722 Brook, Edward J.", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole Ice Core Methane Data and Gas Age Time Scale; South Pole ice core (SPC14) total air content (TAC)", "datasets": [{"dataset_uid": "601546", "doi": "10.15784/601546", "keywords": "Antarctica; South Pole", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) total air content (TAC)", "url": "https://www.usap-dc.org/view/dataset/601546"}, {"dataset_uid": "601329", "doi": "10.15784/601329", "keywords": "Antarctica; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; South Pole", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Methane Data and Gas Age Time Scale", "url": "https://www.usap-dc.org/view/dataset/601329"}], "date_created": "Tue, 02 Jun 2020 00:00:00 GMT", "description": "Brook/1643722 This award supports a project to measure the concentration of the gas methane in air trapped in an ice core collected from the South Pole. The data will provide an age scale (age as a function of depth) by matching the South Pole methane changes with similar data from other ice cores for which the age vs. depth relationship is well known. The ages provided will allow all other gas measurements made on the South Pole core (by the PI and other NSF supported investigators) to be interpreted accurately as a function of time. This is critical because a major goal of the South Pole coring project is to understand the history of rare gases in the atmosphere like carbon monoxide, carbon dioxide, ethane, propane, methyl chloride, and methyl bromide. Relatively little is known about what controls these gases in the atmosphere despite their importance to atmospheric chemistry and climate. Undergraduate assistants will work on the project and be introduced to independent research through their work. The PI will continue visits to local middle schools to introduce students to polar science, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) as part of the project. Methane concentrations from a major portion (2 depth intervals, excluding the brittle ice-zone which is being measured at Penn State University) of the new South Pole ice core will be used to create a gas chronology by matching the new South Pole ice core record with that from the well-dated WAIS Divide ice core record. In combination with measurements made at Penn State, this will provide gas dating for the entire 50,000-year record. Correlation will be made using a simple but powerful mid-point method that has been previously demonstrated, and other methods of matching records will be explored. The intellectual merit of this work is that the gas chronology will be a fundamental component of this ice core project, and will be used by the PI and other investigators for dating records of atmospheric composition, and determining the gas age-ice age difference independently of glaciological models, which will constrain processes that affected firn densification in the past. The methane data will also provide direct stratigraphic markers of important perturbations to global biogeochemical cycles (e.g., rapid methane variations synchronous with abrupt warming and cooling in the Northern Hemisphere) that will tie other ice core gas records directly to those perturbations. A record of the total air content will also be produced as a by-product of the methane measurements and will contribute to understanding of this parameter. The broader impacts include that the work will provide a fundamental data set for the South Pole ice core project and the age scale (or variants of it) will be used by all other investigators working on gas records from the core. The project will employ an undergraduate assistant(s) in both years who will conduct an undergraduate research project which will be part of the student\u0027s senior thesis or other research paper. The project will also offer at least one research position for the Oregon State University Summer REU site program. Visits to local middle schools, and other outreach activities (e.g. laboratory tours, talks to local civic or professional organizations) will also be part of the project.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "AMD; LABORATORY; METHANE; ICE CORE RECORDS; Gas Chromatography; South Pole; USAP-DC", "locations": "South Pole", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "A High Resolution Atmospheric Methane Record from the South Pole Ice Core", "uid": "p0010102", "west": 0.0}, {"awards": "1246223 Hastings, Meredith", "bounds_geometry": "POINT(-112.1115 -79.481)", "dataset_titles": "WAIS Divide WDC06A Nitrate Isotope Record", "datasets": [{"dataset_uid": "601022", "doi": "10.15784/601022", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Nitrate; WAIS Divide; WAIS Divide Ice Core", "people": "Buffen, Aron; Hastings, Meredith", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide WDC06A Nitrate Isotope Record", "url": "https://www.usap-dc.org/view/dataset/601022"}], "date_created": "Tue, 02 May 2017 00:00:00 GMT", "description": "Hastings/1246223 This award supports a project with the aim of distinguishing the sources of nitrate deposition to the West Antarctic Ice Sheet (WAIS) using isotopic ratios snow in archive snow and ice samples. The isotopic composition of nitrate has been shown to contain information about the source of the nitrate (i.e. nitrogen oxides = NOx = NO+NO2) and the oxidation processes that convert NOx to nitrate in the atmosphere prior to deposition. A difficulty in interpreting records in the context of NOx sources is that nitrate can be post-depositionally processed in surface snow, such that the archived record does not reflect the composition of the atmosphere. This intellectual merit of this work specifically aims to investigate variability in the isotopic composition of nitrate in snow and ice from the WAIS in the context of accumulation rate, NOx source emissions, and atmospheric chemistry. These records will be interpreted in the context of our understanding of biospheric (biomass burning, microbial processes in soils), atmospheric (lightning, transport, chemistry), and climate (temperature, accumulation rate) changes over time. A graduate student will be supported as part of this project, and both graduate student and PI will be involved in communicating the utility and results of polar research to elementary school students in the Providence, RI area. The broader impacts of the project also include making efforts to attract more young, female scientists to polar research by establishing a connection between the Earth Science Women\u0027s Network (ESWN), an organization PI Hastings helped to establish, and the Association of Polar Early Career Scientists (APECS). Finally, results of all measurements will be presented at relevant conferences, made available publicly and published in peer-reviewed journals.", "east": -112.1115, "geometry": "POINT(-112.1115 -79.481)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -79.481, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Hastings, Meredith", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.481, "title": "Investigating Source, Chemistry and Climate changes using the Isotopic Composition of Nitrate in Antarctic Snow and Ice", "uid": "p0000399", "west": -112.1115}, {"awards": "0538049 Steig, Eric; 0538520 Thiemens, Mark", "bounds_geometry": "POINT(-112.085 -79.5)", "dataset_titles": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core; WAIS Divide sulfate and nitrate isotopes; WAIS ice core isotope data #387, 385 (full data link not provided)", "datasets": [{"dataset_uid": "609479", "doi": "10.7265/N5BG2KXH", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Thiemens, Mark H.", "repository": "USAP-DC", "science_program": null, "title": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609479"}, {"dataset_uid": "601007", "doi": "10.15784/601007", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Nitrate; Oxygen Isotope; Sulfate; WAIS Divide; WAIS Divide Ice Core", "people": "Steig, Eric J.; Alexander, Becky", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide sulfate and nitrate isotopes", "url": "https://www.usap-dc.org/view/dataset/601007"}, {"dataset_uid": "002512", "doi": "", "keywords": null, "people": null, "repository": "Project website", "science_program": null, "title": "WAIS ice core isotope data #387, 385 (full data link not provided)", "url": "http://www.waisdivide.unh.edu/"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "0538520\u003cbr/\u003eThiemens\u003cbr/\u003eThis award supports a project to develop the first complete record of multiple isotope ratios of nitrate and sulfate covering the last ~100,000 years, from the deep ice core planned for the central ice divide of the West Antarctic Ice Sheet (WAIS). The WAIS Divide ice core will be the highest resolution long ice core obtained from Antarctica and we can expect important complementary information to be available, including accurate knowledge of past accumulation rates, temperatures, and compounds such as H2O2, CO and CH4. These compounds play significant roles in global atmospheric chemistry and climate. Especially great potential lies in the use of multiple isotope signatures. The unique mass independent fractionation (MIF) 17O signature of ozone is observed in both nitrate and sulfate, due to the interaction of their precursors with ozone. The development of methods to measure the multiple-isotope composition of small samples of sulfate and nitrate makes continuous high resolution measurements on ice cores feasible for the first time. Recent work has shown that such measurements can be used to determine the hydroxyl radial (OH) and ozone (O3) concentrations in the paleoatmosphere as well as to apportion sulfate and nitrate sources. There is also considerable potential in using these isotope measurements to quantify post depositional changes. In the first two years, continuous measurements from the upper ~100-m of ice at WAIS divide will be obtained, to provide a detailed look at seasonal through centennial scale variability. In the third year, measurements will be made throughout the available depth of the deep core (expected to reach ~500 m at this time). The broader impacts of the project include applications to diverse fields including atmospheric chemistry, glaciology, meteorology, and paleoclimatology. Because nitrate and sulfate are important atmospheric pollutants, the results will also have direct and relevance to global environmental policy. This project will coincide with the International Polar Year (2007-2008), and contributes to goals of the IPY, which include the fostering of interdisciplinary research toward enhanced understanding of atmospheric chemistry and climate in the polar regions.", "east": -112.085, "geometry": "POINT(-112.085 -79.5)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Isotope Ratios; Temperature; Sulfate; West Antarctic; Paleoatmosphere; LABORATORY; Ice Core; Ice Core Data; Mass Independent Fractionation; FIELD SURVEYS; Not provided; Accumulation Rate; Oxygen Isotope; FIELD INVESTIGATION; Ice Core Chemistry; Isotope", "locations": "West Antarctic", "north": -79.5, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Alexander, Becky; Steig, Eric J.; Thiemens, Mark H.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "Project website; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.5, "title": "Collaborative Research: Multiple-isotope Analysis of Nitrate and Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "uid": "p0000020", "west": -112.085}, {"awards": "1043421 Severinghaus, Jeffrey; 1043522 Brook, Edward J.", "bounds_geometry": "POINT(-112.09 -79.47)", "dataset_titles": "WAIS Divide Replicate Core Methane Isotopic Data Set", "datasets": [{"dataset_uid": "601059", "doi": "10.15784/601059", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Replicate Core Methane Isotopic Data Set", "url": "https://www.usap-dc.org/view/dataset/601059"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "1043421/Severinghaus This award supports a project to obtain samples of ice in selected intervals for replication and verification of the validity and spatial representativeness of key results in the WAIS Divide ice core, and to obtain additional ice samples in areas of intense scientific interest where demand is high. The US Ice Core Working Group recommended in 2003 that NSF pursue the means to take replicate samples, termed \"replicate coring\". This recommendation was part of an agreement to reduce the diameter of the (then) new drilling system (the DISC drill) core to 12.2 cm to lighten logistics burdens, and the science community accepted the reduction in ice sample with the understanding that replicate coring would be able to provide extra sample volume in key intervals. The WAIS Divide effort would particularly benefit from replicate coring, because of the unique quality of the expected gas record and the large samples needed for gases and gas isotopes; thus this proposal to employ replicate coring at WAIS Divide. In addition, scientific demand for ice samples has been, and will continue to be, very unevenly distributed, with the ice core archive being completely depleted in depth intervals of high scientific interest (abrupt climate changes, volcanic sulfate horizons, meteor impact horizons, for example). The broader impacts of the proposed research may include identification of leads and lags between Greenland, tropical, and Antarctic climate change, enabling critical tests of hypotheses for the mechanism of abrupt climate change. Improved understanding of volcanic impacts on atmospheric chemistry and climate may also emerge. This understanding may ultimately help improve climate models and prediction of the Earth System feedback response to ongoing human perturbation in coming centuries. Outreach and public education about climate change are integral components of the PIs\u0027 activities and the proposed work will enhance these efforts. Broader impacts also include education and training of 2 postdoctoral scholars and 1 graduate student, and invaluable field experience for the graduate and undergraduate students who will likely make up the core processing team at WAIS Divide.", "east": -112.09, "geometry": "POINT(-112.09 -79.47)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": false, "keywords": "Ice Core Gas Records; Firn Air Isotopes; LABORATORY; FIELD SURVEYS; Mass Spectrometry; Not provided; FIELD INVESTIGATION; Ice Core; WAIS Divide", "locations": "WAIS Divide", "north": -79.47, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Glaciology; Antarctic Earth Sciences; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -79.47, "title": "Collaborative Research: Replicate Coring at WAIS Divide to Obtain Additional Samples at Events of High Scientific Interest", "uid": "p0000751", "west": -112.09}, {"awards": "0739684 Hatcher, Patrick", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Wed, 26 Sep 2012 00:00:00 GMT", "description": "This award supports a project to fully develop the analytical protocols needed to exploit a relatively new technique for the analysis of soluble organic matter in ice core samples. The technique couples Electrospray ionization to high resolution Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS). Sample volume will be reduced and pre-concentration steps will be eliminated. Following method optimization a suite of ice core samples will be studied from several Antarctic and Greenland locations to address several hypothesis driven research questions. Preliminary results show that a vast record of relatively high molecular weight organic material exists in ice core samples and intriguing results from a few samples warrant further investigation. Several important questions related to developing a better understanding of the nature and paleo record of organic matter in ice cores will be addressed. These include developing a better understanding of the origin of nitrogen and sulfur isotopes in pre-industrial vs. modern samples, developing the methods to apply molecular biomarker techniques, routinely used by organic geochemists for sediment analyses, to the analysis of organic matter in ice cores, tracking the level of oxidation of homologous series of compounds and using them as a proxy for atmospheric oxidant levels in the past and determining whether or not high resolution FTICR mass spectral analysis can provide the ice core community with a robust method to analyze organic materials at the molecular level. The intellectual merit of this work is that this analytical method will provide a new understanding of the nature of organic matter in ice, possibly leading to the discovery of multitudes of molecular species indicative of global change processes whose abundances can be compared with other change proxies. The proposed studies are of an exploratory nature and potentially transformative for the field of ice core research and cryobiology. The broader impacts of these studies are that they should provide compelling evidence regarding organic matter sources, atmospheric processing and anthropogenic inputs to polar ice and how these have varied over time. The collaborative work proposed here will partner atmospheric chemistry/polar ice chemistry expertise with organic geochemistry expertise, resulting in significant contributions to both fields of study and significant advances in ice core analysis. Training of both graduate and undergraduate students will be a key component of the project and students will be involved in collaborative research using advanced analytical instrumentation, presentation of research results at national meetings, and will participate in manuscript preparation.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": false, "keywords": "Ice Core; Isotope; Organic Matter; Nitrogen; Sulfur; Not provided; LABORATORY; Mass Spectrometry; COMPUTERS; Molecular", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Hatcher, Patrick; Grannas, Amanda", "platforms": "Not provided; OTHER \u003e MODELS \u003e COMPUTERS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repositories": null, "science_programs": null, "south": null, "title": "Collaborative Research: Molecular Level Characterization of Organic Matter in Ice Cores using High-resolution FTICR mass spectrometry", "uid": "p0000707", "west": null}, {"awards": "0636929 Bales, Roger", "bounds_geometry": null, "dataset_titles": "Measurements of Air and Snow Photochemical Species at WAIS Divide, Antarctica", "datasets": [{"dataset_uid": "609585", "doi": "10.7265/N5GX48HW", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "Bales, Roger", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Measurements of Air and Snow Photochemical Species at WAIS Divide, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609585"}], "date_created": "Thu, 14 Jul 2011 00:00:00 GMT", "description": "This award supports a project to understand how recent changes in atmospheric chemistry, and historical changes as recorded in snow, firn and ice, have affected atmospheric photochemistry over Antarctica. Atmospheric, snow and firn core measurements of selected gas, meteorological and snow physical properties will be made and modeling of snow-atmosphere exchange will be carried out. The intellectual merit of the project is that it will lead to a better an understanding of the atmospheric chemistry in West Antarctica, its bi-directional linkages with the snowpack, and how it responds to regional influences. There are at least four broader impacts of this work. First is education of university students at both the graduate and undergraduate levels. One postdoctoral researcher and one graduate student will carry out much of the work, and a number of undergraduates will be involved. Second, involvement with the WAIS-Divide coring program will be used to help recruit under-represented groups as UC Merced students. As part of UC Merced\u0027s outreach efforts in the San Joaquin Valley, whose students are under-represented in the UC system, the PI and co-PI give short research talks to groups of prospective students, community college and high school educators and other groups. They will develop one such talk highlighting this project. Including high-profile research in these recruiting talks has proven to be an effective way to promote dialog, and interest students in UC Merced. Third, talks such as this also contribute to the scientific literacy of the general public. The PI and grad student will all seek opportunities to share project information with K-14 and community audiences. Fourth, results of the research will be disseminated broadly to the scientific community, and the researchers will seek additional applications for the transfer functions as tools to improve interpretation of ice-cores. This research is highly collaborative, and leverages the expertise and data from a number of other groups.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e CHEMILUMINESCENCE", "is_usap_dc": true, "keywords": "Snow; Atmospheric Chemistry; Not provided; LABORATORY; Antarctica; FIELD SURVEYS; Snow Physical Properties; Meteorology; Wais Divide-project; Firn; Atmosphere Exchange; WAIS Divide; FIELD INVESTIGATION", "locations": "Antarctica; WAIS Divide", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Bales, Roger", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Atmospheric, Snow and Firn Chemistry Studies for Interpretation of WAIS-Divide Cores", "uid": "p0000041", "west": null}, {"awards": "0739780 Taylor, Kendrick", "bounds_geometry": "POINT(-112.117 -79.666)", "dataset_titles": "WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning", "datasets": [{"dataset_uid": "600142", "doi": "10.15784/600142", "keywords": "Antarctica; Atmosphere; Black Carbon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "Taylor, Kendrick C.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning", "url": "https://www.usap-dc.org/view/dataset/600142"}], "date_created": "Thu, 28 Apr 2011 00:00:00 GMT", "description": "Edwards/0739780\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to develop a 2,000-year high-temporal resolution record of biomass burning from the analysis of black carbon in the WAIS Divide bedrock ice core. Pilot data for the WAIS WD05A core demonstrates that we now have the ability to reconstruct this record with minimal impact on the amount of ice available for other projects. The intellectual merit of this project is that black carbon (BC) aerosols result solely from combustion and play a critical but poorly quantified role in global climate forcing and the carbon cycle. When incorporated into snow and ice, BC increases absorption of solar radiation making seasonal snow packs, mountain glaciers, polar ice sheets, and sea ice much more vulnerable to climate warming. BC emissions in the Southern Hemisphere are dominated by biomass burning in the tropical regions of Southern Africa, South America and South Asia. Biomass burning, which results from both climate and human activities, alters the atmospheric composition of greenhouse gases, aerosols and perturbs key biogeochemical cycles. A long-term record of biomass burning is needed to aid in the interpretation of ice core gas composition and will provide important information regarding human impacts on the environment and climate before instrumental records. The broader impacts of the project are that it represents a paradigm shift in our ability to reconstruct the history of fire from ice core records and to understand its impact on atmospheric chemistry and climate over millennial time scales. This type of data is especially needed to drive global circulation model simulations of black carbon aerosols, which have been found to be an important component of global warming and which may be perturbing the hydrologic cycle. The project will also employ undergraduate students and is committed to attracting underrepresented groups to the physical sciences. The project?s outreach component will be conducted as part of the WAIS project outreach program and will reach a wide audience.", "east": -112.117, "geometry": "POINT(-112.117 -79.666)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; Not provided; Gas Record; Ice Core; Gas Measurement; Ice Core Gas Composition; Antarctica; LABORATORY; Bedrock Ice Core; Ice Core Gas Records; Wais Project; Greenhouse Gas; Atmospheric Chemistry; FIELD INVESTIGATION; Black Carbon; Biomass Burning; WAIS Divide; FIELD SURVEYS; West Antarctica; Methane", "locations": "Antarctica; West Antarctica; WAIS Divide", "north": -79.666, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.; McConnell, Joseph; Mitchell, Logan E; Sowers, Todd A.; Taylor, Kendrick C.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.666, "title": "WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning", "uid": "p0000022", "west": -112.117}, {"awards": "0636506 Mayewski, Paul", "bounds_geometry": "POLYGON((-137.7 -75.7,-137.4 -75.7,-137.1 -75.7,-136.8 -75.7,-136.5 -75.7,-136.2 -75.7,-135.9 -75.7,-135.6 -75.7,-135.3 -75.7,-135 -75.7,-134.7 -75.7,-134.7 -75.773,-134.7 -75.846,-134.7 -75.919,-134.7 -75.992,-134.7 -76.065,-134.7 -76.138,-134.7 -76.211,-134.7 -76.284,-134.7 -76.357,-134.7 -76.43,-135 -76.43,-135.3 -76.43,-135.6 -76.43,-135.9 -76.43,-136.2 -76.43,-136.5 -76.43,-136.8 -76.43,-137.1 -76.43,-137.4 -76.43,-137.7 -76.43,-137.7 -76.357,-137.7 -76.284,-137.7 -76.211,-137.7 -76.138,-137.7 -76.065,-137.7 -75.992,-137.7 -75.919,-137.7 -75.846,-137.7 -75.773,-137.7 -75.7))", "dataset_titles": "Ion Concentrations from SPRESSO Ice Core, Antarctica; Mt. Moulton Ice Trench Mass Spectrometry Data, Antarctica", "datasets": [{"dataset_uid": "609471", "doi": "10.7265/N508638J", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; ITASE; Paleoclimate; South Pole; SPRESSO Ice Core", "people": "Mayewski, Paul A.; Korotkikh, Elena", "repository": "USAP-DC", "science_program": null, "title": "Ion Concentrations from SPRESSO Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609471"}, {"dataset_uid": "609472", "doi": "10.7265/N5VH5KSV", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Mt Moulton; Paleoclimate", "people": "Mayewski, Paul A.; Korotkikh, Elena", "repository": "USAP-DC", "science_program": null, "title": "Mt. Moulton Ice Trench Mass Spectrometry Data, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609472"}], "date_created": "Thu, 29 Jul 2010 00:00:00 GMT", "description": "This award supports a project to examine an existing ice core of opportunity from South Pole (SPRESO core) to develop a 2000+ year long climate record. SPRESO ice core will be an annually dated, sub-annually-resolved reconstruction of past climate (atmospheric circulation, temperature, precipitation rate, and atmospheric chemistry) utilizing continuous, co-registered measurements (n=45) of: major ions, trace elements, and stable isotope series, plus selected sections for microparticle size and composition. The intellectual merit of this project relates to the fact that few 2000+ year records of this quality exist in Antarctica despite increasing scientific interest in this critical time period as the framework within which to understand modern climate. The scientific impact of this ice core investigation are that it will provide an in-depth understanding of climate variability; a baseline for assessing modern climate variability in the context of human activity; and a contribution to the prediction of future climate variability. The broader impact of this work is that the proposed research addresses important questions concerning the role of Antarctica in past, present, and future global change. Results will be translated into publicly accessible information through public lectures, media appearances, and an extensive outreach activity housed in our Institute. Our ice core activities provide a major basis for curriculum in K-12 and University plus a basis for several field and laboratory based graduate theses and undergraduate student projects. The project will support one PhD student for 3 years and undergraduate salaries. The Climate Change Institute has a long history of gender and ethnically diverse student and staff involvement in research.", "east": -134.7, "geometry": "POINT(-136.2 -76.065)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Interpretation; Ions; US ITASE; Explorations; LABORATORY; Ice Core Data; Ice Core; Ice Analysis; Ice; Not provided; Antarctic Ice Sheet; Laboratory Investigation; Field Investigations; Ice Core Chemistry; Horizontal Ice Core; Ice Chemistry; Ice Sheet", "locations": "Antarctic Ice Sheet", "north": -75.7, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Korotkikh, Elena; Kreutz, Karl; Kurbatov, Andrei V.; Mayewski, Paul A.", "platforms": "Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -76.43, "title": "Collaborative Proposal: 2000+ Year Detailed, Calibrated Climate Reconstruction from a South Pole Ice Core Set in an Antarctic - Global Scale Context", "uid": "p0000209", "west": -137.7}, {"awards": "0636953 Saltzman, Eric", "bounds_geometry": "POINT(-148.82 -81.66)", "dataset_titles": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core; Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core; Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core; Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica; Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "datasets": [{"dataset_uid": "609598", "doi": "10.7265/N5X0650D", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Bromide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609598"}, {"dataset_uid": "609356", "doi": "10.7265/N56W9807", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Saltzman, Eric; Williams, Margaret; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methyl Chloride Measurements from the Siple Dome A Deep Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609356"}, {"dataset_uid": "609600", "doi": "10.7265/N5PG1PPB", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Methyl Chloride Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609600"}, {"dataset_uid": "601361", "doi": "10.15784/601361", "keywords": "Antarctica; Carbonyl Sulfide; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/601361"}, {"dataset_uid": "609599", "doi": "10.7265/N5S75D8P", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Carbonyl Sulfide Measurements in the Taylor Dome M3C1 Ice Core", "url": "https://www.usap-dc.org/view/dataset/609599"}], "date_created": "Wed, 22 Oct 2008 00:00:00 GMT", "description": "Saltzman/0636953\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to measure methyl chloride, methyl bromide, and carbonyl sulfide in air extracted from Antarctic ice cores. Previous measurements in firn air and shallow ice cores suggest that the ice archive contains paleo-atmospheric signals for these gases. The goal of this study is to extend these records throughout the Holocene and into the last Glacial period to examine the behavior of these trace gases over longer time scales and a wider range of climatic conditions. These studies are exploratory, and both the stability of these trace gases and the extent to which they may be impacted by in situ processes will be assessed. This project will involve sampling and analyzing archived ice core samples from the Siple Dome, Taylor Dome, Byrd, and Vostok ice cores. The ice core samples will be analyzed by dry extraction, with gas chromatography/mass spectrometry with isotope dilution. The ice core measurements will generate new information about the range of natural variability of these trace gases in the atmosphere. The intellectual merit of this project is that this work will provide an improved basis for assessing the impact of anthropogenic activities on biogeochemical cycles, and new insight into the climatic sensitivity of the biogeochemical processes controlling atmospheric composition. The broader impact of this project is that there is a strong societal interest in understanding how man\u0027s activities impact the atmosphere, and how atmospheric chemistry may be altered by future climate change. The results of this study will contribute to the development of scenarios used for future projections of stratospheric ozone and climate change. In terms of human development, this project will support the doctoral dissertation of a graduate student in Earth System Science, and undergraduate research on polar ice core chemistry. This project will also contribute to the development of an Earth Sciences teacher training curriculum for high school teachers in the Orange County school system in collaboration with an established, NSF-sponsored Math and Science Partnership program (FOCUS).", "east": -148.82, "geometry": "POINT(-148.82 -81.66)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Antarctica; Methyl Bromide; Antarctic; Ice Core Gas Records; Ice Core Data; Carbonyl Sulfide; Methyl Chloride; Antarctic Ice Sheet; Siple Dome; Trace Gases; Ice Core Chemistry; Biogeochemical; Atmospheric Chemistry; West Antarctic Ice Sheet; LABORATORY; Ice Core; West Antarctica", "locations": "Antarctic; Antarctica; Antarctic Ice Sheet; Siple Dome; West Antarctica; West Antarctic Ice Sheet", "north": -81.66, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core; Siple Dome Ice Core", "south": -81.66, "title": "Methyl Chloride, Methyl Bromide, and Carbonyl Sulfide in Deep Antarctic Ice Cores", "uid": "p0000042", "west": -148.82}, {"awards": "0337891 Brook, Edward J.", "bounds_geometry": "POINT(158 -77.666667)", "dataset_titles": "Atmospheric CO2 and Climate: Byrd Ice Core, Antarctica; Atmospheric CO2 and Climate: Taylor Dome Ice Core, Antarctica", "datasets": [{"dataset_uid": "609314", "doi": "10.7265/N58W3B80", "keywords": "Antarctica; Atmosphere; Byrd Glacier; Byrd Ice Core; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Byrd Ice Core", "title": "Atmospheric CO2 and Climate: Byrd Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609314"}, {"dataset_uid": "609315", "doi": "10.7265/N5542KJK", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Taylor Dome; Taylor Dome Ice Core", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Atmospheric CO2 and Climate: Taylor Dome Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609315"}], "date_created": "Mon, 05 Nov 2007 00:00:00 GMT", "description": "This award supports the development of a new laboratory capability in the U.S. to measure CO2 in ice cores and investigate millennial-scale changes in CO2 during the last glacial period using samples from the Byrd and Siple Dome ice cores. Both cores have precise relative chronologies based on correlation of methane and the isotopic composition of atmospheric oxygen with counterpart records from Greenland ice cores. The proposed work will therefore allow comparison of the timing of CO2 change, Antarctic temperature change, and Greenland temperature change on common time scales. Such comparisons are vital for evaluating models that explain changes in atmospheric CO2. The techniques being developed will also be available for future projects, specifically the proposed Inland WAIS ice core, for which a highly detailed CO2 record is a major objective, and studies greenhouse and other atmospheric gases and their isotopic composition for which dry extraction is necessary (stable isotopes in CO2, for example). There are many broad impacts of the proposed work. Ice core greenhouse gas records are central contributions of paleoclimatology to research and policy-making concerning global change. The proposed work will enhance those contributions by improving our understanding of the natural cycling of the most important greenhouse gas. It will contribute to the training of a postdoctoral researcher, who will be an integral part of an established research group and benefit from the diverse paleoclimate and geochemistry community at OSU. The PI teaches major and non-major undergraduate and graduate courses on climate and global change. The proposed work will enrich those courses and the courses will provide an opportunity for the postdoctoral researcher to participate in teaching by giving guest lectures. The PI also participates in a summer climate workshop for high school teachers at Washington State University and the proposed work will enrich that contribution. The extraction device that is built and the expertise gained in using it will be resources for the ice core community and available for future projects. Data will be made available through established national data center and the equipment designs will also be made available to other researchers.", "east": 158.0, "geometry": "POINT(158 -77.666667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Ice Core; Climate Change; CO2; Atmospheric Chemistry; Atmospheric CO2; LABORATORY; Not provided; Ice Core Data; Climate; Ice Core Chemistry; Atmospheric Gases; Ice Core Gas Records; GROUND STATIONS; Climate Research", "locations": null, "north": -77.666667, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Ahn, Jinho; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.666667, "title": "Developing Dry Extraction of Ice Core Gases and Application to Millennial-Scale Variability in Atmospheric CO2", "uid": "p0000268", "west": 158.0}, {"awards": "0229573 Mayewski, Paul", "bounds_geometry": null, "dataset_titles": "Antarctic Mean Annual Temperature Map", "datasets": [{"dataset_uid": "609318", "doi": "10.7265/N51C1TTV", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Temperature", "people": "Dixon, Daniel A.", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Mean Annual Temperature Map", "url": "https://www.usap-dc.org/view/dataset/609318"}], "date_created": "Wed, 04 Apr 2007 00:00:00 GMT", "description": "This award supports a science management office for a pilot ice-core drilling and analysis program to test the feasibility of obtaining well-dated, high-resolution isotope and chemistry records from East Antarctica. Shallow ice cores will be obtained from two locations: 1) ~100 km from South Pole towards the Pole of Inaccessibility, as an extension of the Byrd Station-to-South Pole ITASE traverse [International Trans Antarctic Scientific Expedition]; 2) at Taylor Dome, near the original deep coring site, and (3) possibly at AGO 3 and AGO 4 as part of a logistics traverse to these sites. All of the cores collected will be sampled at very high resolution (~1/2 cm) and analyzed for major ions. Results from this calibration work, along with those from another project that is analyzing stable isotopes will be used to help plan a program of larger scope, with the objective of mapping the spatial expression of climate variability in East Antarctica. Funds are also provided to organize a community workshop for coordination of the second phase of US ITASE and for one workshop per year for two years dedicated to writing and preparation of scientific papers from phase one of US ITASE. In addition, route selection activities for the follow-on traverse activities in East Antarctica will be conducted using satellite image mapping. A summary document will be produced and made available to the community to help with planning of related field programs (e.g. deep ice radar, firn radar profiling, atmospheric chemistry, ice coring, snow surface properties for satellite observations, ice surface elevation and mass balance).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMOCOUPLES \u003e THERMOCOUPLES; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMOMETERS \u003e THERMOMETERS", "is_usap_dc": true, "keywords": "Antarctic Ice Sheet; West Antarctica; FIELD INVESTIGATION; West Antarctic Ice Sheet; Antarctic; Temperature; East Antarctic Plateau; FIELD SURVEYS; Antarctica; Not provided", "locations": "Antarctic; Antarctica; Antarctic Ice Sheet; West Antarctica; West Antarctic Ice Sheet; East Antarctic Plateau", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Dixon, Daniel A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "A Science Management Office for the U. S. Component of the International Trans Antarctic Expedition (US ITASE SMO)A Collaborative Pgrm of Research from S. Pole to N. Victoria Land", "uid": "p0000199", "west": null}, {"awards": "0126194 Harder, Susan", "bounds_geometry": null, "dataset_titles": "Access to data", "datasets": [{"dataset_uid": "001336", "doi": "", "keywords": null, "people": null, "repository": "NSIDC", "science_program": null, "title": "Access to data", "url": "http://nsidc.org/data/agdc_investigators.html"}], "date_created": "Tue, 20 Feb 2007 00:00:00 GMT", "description": "This award supports a two-year project to continue work developing the techniques to make carbon monoxide (CO) measurements in ice core samples. Carbon monoxide is an important atmospheric chemical constituent as it is a primary sink for hydroxyl radical (OH) (and therefore influences the oxidizing capacity of the atmosphere) and because the concentrations of three major greenhouses gases , carbon dioxide (CO2), methane (CH4) and ozone (O3) are directly tied to the concentration of CO. In light of recent anthropogenic increases in the emissions of CO, CO2, CH4 and NOx, it is desirable to understand this complex chemical system and the changes in the greenhouse forcing resulting from perturbation. Because it is difficult to test the accuracy of models for past and future conditions for which no direct atmospheric measurements of trace gas concentrations are available these measurements must be obtained in other ways. Polar ice cores provide a means to make these measurements. Further work is necessary to refine the analytical technique and additional measurements are necessary to investigate the accuracy of these results and to establish the nature of temporal trends in CO. It is anticipated that the CO record, combined with existing or new data for CO2, CH4 , N2O and other paleoclimate variables, will provide further constraints on model studies of the effect of changing atmospheric chemistry on greenhouse forcing.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Harder, Susan", "platforms": "Not provided", "repo": "NSIDC", "repositories": "NSIDC", "science_programs": null, "south": null, "title": "Ice Core Records of Atmospheric Carbon Monoxide", "uid": "p0000706", "west": null}, {"awards": "0338363 Thiemens, Mark; 0337933 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Major Ion Concentrations in 2004 South Pole Ice Core", "datasets": [{"dataset_uid": "609542", "doi": "10.7265/N5HX19N8", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Major Ion Concentrations in 2004 South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609542"}], "date_created": "Fri, 11 Aug 2006 00:00:00 GMT", "description": "This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Not provided; Ion Chromatograph; Ions; LABORATORY; GROUND-BASED OBSERVATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Investigating Atmospheric Chemistry and Dynamics through Oxygen and Sulfur Isotopes in Volcanic Sulfate from South Pole Ice Cores", "uid": "p0000031", "west": null}, {"awards": "0338359 Saltzman, Eric", "bounds_geometry": "POINT(-148.81 -81.65)", "dataset_titles": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br); Antarctic Ice Cores: Methyl Chloride and Methyl Bromide; Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core; Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "datasets": [{"dataset_uid": "609279", "doi": "10.7265/N53B5X3G", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Analysis of Siple Dome Ice Core: Carbonyl Sulfide (COS), Methyl Chloride (CH3Cl), and Methyl Bromide (CH3Br)", "url": "https://www.usap-dc.org/view/dataset/609279"}, {"dataset_uid": "609131", "doi": "10.7265/N5P848VP", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Siple Dome; Siple Dome Ice Core; WAISCORES", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Methane and Carbonyl Sulfide Analysis of Siple Dome Ice Core Subsamples", "url": "https://www.usap-dc.org/view/dataset/609131"}, {"dataset_uid": "601357", "doi": "10.15784/601357", "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "url": "https://www.usap-dc.org/view/dataset/601357"}, {"dataset_uid": "609313", "doi": "10.7265/N5DN430Q", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; ITASE; Paleoclimate; Siple Dome Ice Core; South Pole; SPRESSO; SPRESSO Ice Core", "people": "Williams, Margaret; Tatum, Cheryl; Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Antarctic Ice Cores: Methyl Chloride and Methyl Bromide", "url": "https://www.usap-dc.org/view/dataset/609313"}], "date_created": "Wed, 16 Nov 2005 00:00:00 GMT", "description": "This award supports the analysis, in Antarctic ice cores, of the ozone depleting substances methyl bromide (CH3Br) and methyl chloride (CH3Cl), and the sulfur-containing gas, carbonyl sulfide (OCS). The broad scientific goal is to assess the level and variability of these gases in the preindustrial atmosphere. This information will allow testing of current models for sources and sinks of these gases from the atmosphere, and to indirectly assess the impact of anthropogenic activities on their biogeochemical cycles. Longer-term records will shed light on the climatic sensitivity of the atmospheric burden of these gases, and ultimately on the biogeochemical processes controlling them. These gases are present in ice at parts per trillion levels, and the current database consists entirely of a small number of measurements made in from a shallow ice core from Siple Dome, Antarctica. This project will involve studies of ice core samples from three Antarctic sites: Siple Station, Siple Dome, and South Pole. The sampling strategy is designed to accomplish several objectives: 1) to verify the atmospheric mixing ratios previously observed in shallow Siple Dome ice for OCS, CH3Br, and CH3Cl at sites with very different accumulation rates and surface temperatures; 2) to obtain a well-dated, high resolution record from a high accumulation rate site (Siple Station), that can provide overlap in mean gas age with Antarctic firn air samples; 3) explore Holocene variability in trace gas mixing ratios; and 4) to make the first measurements of these trace gases in Antarctic glacial ice. In terms of broader impact on society, this research will help to provide a stronger scientific basis for policy decisions regulating the production and use of ozone-depleting and climate-active gases. Specifically, the methyl bromide results will contribute to the current debate on the impact of recent regulation (via the Montreal Protocol and its Amendments) on atmospheric levels. Determination of pre-industrial atmospheric variability of ozone-depleting substances will help place more realistic constraints on scenarios used for future projections of stratospheric ozone and its climatic impacts. This research will involve the participation of both graduate and undergraduate students.", "east": -148.81, "geometry": "POINT(-148.81 -81.65)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Gas Records; Carbonyl Sulfide; Siple Coast; Chloride; Trapped Gases; Snow; Ice Core Chemistry; Chromatography; Siple; GROUND STATIONS; Atmospheric Gases; Ozone Depletion; AWS Siple; Ice Sheet; Ice Core Data; Antarctica; Glaciology; West Antarctica; Atmospheric Chemistry; Ice Core; Stratigraphy; LABORATORY; Methane; Mass Spectrometer; GROUND-BASED OBSERVATIONS; WAISCORES; Msa; Mass Spectrometry; Not provided; Siple Dome; Gas Measurement", "locations": "Antarctica; Siple Coast; Siple Dome; West Antarctica; Siple", "north": -81.65, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Saltzman, Eric; Aydin, Murat; Williams, Margaret; Tatum, Cheryl", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.65, "title": "Methyl chloride and methyl bromide in Antarctic ice cores", "uid": "p0000032", "west": -148.81}, {"awards": "0087380 Alley, Richard", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 01 Jul 2004 00:00:00 GMT", "description": "0087380\u003cbr/\u003eAlley\u003cbr/\u003e\u003cbr/\u003eThis award provides three years of support to use a broad, adaptable, multi-parameter approach, using a range of techniques including artificial neural networks to seek the relations between meteorological conditions and the snow pit and ice core records they produce. Multi-parameter, high resolution, ice core data already in hand or now being collected reflect snow accumulation, atmospheric chemistry, isotopic fractionation, and other processes, often with subannual resolution. The West Antarctic sites from which such data are available will be used as starting points for back-trajectory analyses in reanalysis data products to determine the meteorological conditions feeding the data stream. The artificial neural nets will then be used to look for optimal relations between these meteorological conditions and their products. Previous work has demonstrated the value of reanalysis products in determining snow accumulation, of back trajectory analyses in understanding glaciochemistry, and of artificial neural nets in linking meteorological conditions and their products. Preliminary work shows that neural nets are successful in downscaling from reanalysis products to automatic weather station data in West Antarctica, enabling interpolation of site-specific data to improve understanding of recent changes in West Antarctic climate.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": false, "keywords": "Climate; Not provided; Feed-Forward Artificial Neural Networks; Ff-Anns", "locations": null, "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Reusch, David", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -90.0, "title": "Relating West Antarctic Ice Cores to Climate with Artificial Neural Networks", "uid": "p0000747", "west": -180.0}]

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