{"dp_type": "Dataset", "free_text": "Nitrous Oxide"}
[{"awards": "1903681 Brook, Edward J.", "bounds_geometry": ["POLYGON((160 -77.6,160.25 -77.6,160.5 -77.6,160.75 -77.6,161 -77.6,161.25 -77.6,161.5 -77.6,161.75 -77.6,162 -77.6,162.25 -77.6,162.5 -77.6,162.5 -77.63,162.5 -77.66,162.5 -77.69,162.5 -77.72,162.5 -77.75,162.5 -77.78,162.5 -77.81,162.5 -77.84,162.5 -77.87,162.5 -77.9,162.25 -77.9,162 -77.9,161.75 -77.9,161.5 -77.9,161.25 -77.9,161 -77.9,160.75 -77.9,160.5 -77.9,160.25 -77.9,160 -77.9,160 -77.87,160 -77.84,160 -77.81,160 -77.78,160 -77.75,160 -77.72,160 -77.69,160 -77.66,160 -77.63,160 -77.6))"], "date_created": "Wed, 26 Jun 2024 00:00:00 GMT", "description": "This data set is a new N2O isotopic data set including site preference isotopic data derived from ice core samples containing air spanning the deglacial N2O rise (16.5-13.2 ka). The data extend through the Younger Dryas cooling interval, when N2O decreased by about 30 ppb (13.2-11.9 ka). The data set also contains N2O isotope records spanning the Heinrich Stadial 4 / Dansgaard-Oeschger 8 (HS4/DO8) transition (39.8-35.8 ka), an example of cyclical millennial-scale N2O variability characteristic of the last ice age. ", "east": 162.5, "geometry": ["POINT(161.25 -77.75)"], "keywords": "Antarctica; Cryosphere; Ice Core; Nitrous Oxide; Taylor Glacier", "locations": "Taylor Glacier; Antarctica; Taylor Glacier", "north": -77.6, "nsf_funding_programs": "Antarctic Earth Sciences", "persons": "Menking, Andy; Brook, Edward J.", "project_titles": null, "projects": null, "repositories": null, "science_programs": null, "south": -77.9, "title": "Final N2O isotopic data including isotopomer ratios for the last deglaciation and Heinrich Stadia 4/Dansgaard Oeschger Event 8", "uid": "601803", "west": 160.0}, {"awards": "1643716 Buizert, Christo", "bounds_geometry": ["POLYGON((-180 -67,-144 -67,-108 -67,-72 -67,-36 -67,0 -67,36 -67,72 -67,108 -67,144 -67,180 -67,180 -69.3,180 -71.6,180 -73.9,180 -76.2,180 -78.5,180 -80.8,180 -83.1,180 -85.4,180 -87.7,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.7,-180 -85.4,-180 -83.1,-180 -80.8,-180 -78.5,-180 -76.2,-180 -73.9,-180 -71.6,-180 -69.3,-180 -67))"], "date_created": "Mon, 22 May 2023 00:00:00 GMT", "description": "We have reconstructed the atmospheric N2O mole fraction and its isotopic composition by combining data from ice cores, firn air, and atmospheric samples. The mole fraction reconstruction extends back to 1000 CE using ice cores, firn air, and atmospheric sampling; and the isotopic reconstruction extends back to 1900 CE using only firn air data. We have incorporated both newly measured and previously published data. We present new data for the mole fraction, d15Nbulk, d18O, and d15NSP values from the Styx (East Antarctica) firn air, and mole fraction from the North Greenland Eemian Ice drilling Project (NEEM) firn air. We have used published records from the Styx and NEEM ice cores, direct atmospheric measurements from the NOAA global sampling network, and firn air data, giving a total of 11 sites for N2O mole fraction, 12 sites for d15Nbulk, 11 sites for d18O, and 8 sites for d15NSP values.\r\n", "east": 180.0, "geometry": ["POINT(0 -89.999)"], "keywords": "Antarctic; Antarctica; Anthropogenic Emission; Atmosphere; Greenhouse Gas; Greenland; Ice Core Data; Nitrification And Denitrification Processes; Nitrous Oxide; Site-Specific 15N Isotopomer; Styx Glacier", "locations": "Antarctic; Greenland; Antarctica; Styx Glacier", "north": -67.0, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Ghosh, Sambit; Toyoda, Sakae ; Buizert, Christo ; Langenfelds, Ray L ; Yoshida, Naohiro ; Joong Kim, Seong; Ahn, Jinho ; Etheridge, David", "project_titles": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability", "projects": [{"proj_uid": "p0010341", "repository": "USAP-DC", "title": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Concentration and isotopic composition of atmospheric N2O over the last century", "uid": "601693", "west": -180.0}, {"awards": "1543537 Priscu, John", "bounds_geometry": ["POINT(-149.50134 -84.640287)"], "date_created": "Wed, 01 Feb 2023 00:00:00 GMT", "description": "This dataset contains water column biogeochemical properties measured on discrete samples collected from Mercer Subglacial Lake by the SALSA project. Data included are: specific conductance; carbonic acid system parameters (total alkalinity, total inorganic carbon, and pH); water stable isotopes (\u03b42H and \u03b418O); dissolved gases (oxygen, methane, nitrous oxide, and hydrogen); dissolved nutrients (ammonium, nitrite and phosphate), major anions (including nitrate) and cations; size-fractionated colloidal and dissolved trace elements); dissolved organic carbon; and microbial cell and virus-like particle counts.", "east": -149.50134, "geometry": ["POINT(-149.50134 -84.640287)"], "keywords": "Antarctica; Carbon; Cell Counts; Geochemistry; Glacier; Glaciers/ice Sheet; Glaciers/Ice Sheet; Mercer Subglacial Lake; Microbes; Nutrients; SALSA; Stable Isotopes; Trace Elements; West Antarctic Ice Sheet", "locations": "Mercer Subglacial Lake; Mercer Subglacial Lake; West Antarctic Ice Sheet; Antarctica", "north": -84.640287, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Dore, John; Skidmore, Mark; Hawkings, Jon; Steigmeyer, August; Li, Wei; Barker, Joel; Tranter, Martyn; Priscu, John; Science Team, SALSA", "project_titles": "Collaborative Research: Subglacial Antarctic Lakes Scientific Access (SALSA): Integrated Study of Carbon Cycling in Hydrologically-active Subglacial Environments", "projects": [{"proj_uid": "p0010119", "repository": "USAP-DC", "title": "Collaborative Research: Subglacial Antarctic Lakes Scientific Access (SALSA): Integrated Study of Carbon Cycling in Hydrologically-active Subglacial Environments"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -84.640287, "title": "Water column biogeochemical data from Mercer Subglacial Lake", "uid": "601663", "west": -149.50134}, {"awards": "1903681 Brook, Edward J.", "bounds_geometry": ["POLYGON((161.745 -77.745,161.746 -77.745,161.747 -77.745,161.748 -77.745,161.749 -77.745,161.75 -77.745,161.751 -77.745,161.752 -77.745,161.753 -77.745,161.754 -77.745,161.755 -77.745,161.755 -77.74600000000001,161.755 -77.747,161.755 -77.748,161.755 -77.749,161.755 -77.75,161.755 -77.751,161.755 -77.752,161.755 -77.753,161.755 -77.75399999999999,161.755 -77.755,161.754 -77.755,161.753 -77.755,161.752 -77.755,161.751 -77.755,161.75 -77.755,161.749 -77.755,161.748 -77.755,161.747 -77.755,161.746 -77.755,161.745 -77.755,161.745 -77.75399999999999,161.745 -77.753,161.745 -77.752,161.745 -77.751,161.745 -77.75,161.745 -77.749,161.745 -77.748,161.745 -77.747,161.745 -77.74600000000001,161.745 -77.745))"], "date_created": "Tue, 02 Aug 2022 00:00:00 GMT", "description": "Measurements of the isotopic composition of atmospheric nitrous oxide from samples from the Taylor Glacier, Antarctica, spanning the last deglaciation (21-11 ka) and part of the last glacial period (40 to 36 ka). Data set includes the site preference of 15-N in N2O. A manuscript describing these data is currently in preparation. Data are referenced to in house air standards at OSU which are currently being cross calibrated with other laboratories. ", "east": 161.755, "geometry": ["POINT(161.75 -77.75)"], "keywords": "Antarctica; Nitrous Oxide; Taylor Glacier", "locations": "Taylor Glacier; Antarctica", "north": -77.745, "nsf_funding_programs": "Antarctic Earth Sciences", "persons": "Menking, Andy; Brook, Edward J.", "project_titles": "Deciphering Changes in Atmospheric Nitrous Oxide Concentration During the Last Ice Age Using the Intramolecular Site-Preference of Nitrogen Isotopes", "projects": [{"proj_uid": "p0010465", "repository": "USAP-DC", "title": "Deciphering Changes in Atmospheric Nitrous Oxide Concentration During the Last Ice Age Using the Intramolecular Site-Preference of Nitrogen Isotopes"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.755, "title": "Preliminary nitrous oxide site preference isotopic data for last deglaciation from Taylor Glacier", "uid": "601592", "west": 161.745}, {"awards": "1246148 Severinghaus, Jeffrey; 1245821 Brook, Edward J.; 1245659 Petrenko, Vasilii", "bounds_geometry": null, "date_created": "Mon, 02 Nov 2020 00:00:00 GMT", "description": "Ice core measurements of the concentration and stable isotopic composition of atmospheric nitrous oxide (N2O) 74,000-59,000 years ago constrain marine and terrestrial emissions. The data include two major Dansgaard-Oeschger (D-O) events and the N2O decrease during global cooling at the Marine Isotope Stage (MIS) 5a-4 transition. The N2O increase associated with D-O 19 (~73-71.5 ka) was driven by equal contributions from marine and terrestrial emissions. The N2O decrease during the transition into MIS 4 (~71.5-67.5 ka) was caused by gradual reductions of similar magnitude in both marine and terrestrial sources. A 50 ppb increase in N2O concentration at the end of MIS 4 was caused by gradual increases in marine and terrestrial emissions between ~64-61 ka, followed by an abrupt increase in marine emissions at the onset of D-O 16/17 (59.5 ka). This suggests that the importance of marine versus terrestrial emissions in controlling millennial-scale N2O fluctuations varied in time.", "east": null, "geometry": null, "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Gas Records; Ice Core Records; Marine Isotope Stage 4; MIS 4; Nitrous Oxide; Pleistocene; Taylor Dome Ice Core; Taylor Glacier", "locations": "Taylor Glacier; Taylor Glacier; Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "persons": "Menking, James; Brook, Edward J.; Schilt, Adrian; Shackleton, Sarah; Dyonisius, Michael; Severinghaus, Jeffrey P.; Petrenko, Vasilii", "project_titles": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "projects": [{"proj_uid": "p0000283", "repository": "USAP-DC", "title": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": null, "title": "N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica", "uid": "601398", "west": null}, {"awards": "1443550 Brook, Edward J.", "bounds_geometry": ["POINT(-180 -90)"], "date_created": "Thu, 08 Aug 2019 00:00:00 GMT", "description": "Measurements of CO2, N2O, and the isotopic composition of CO2 from the Holocene section of SPICEcore", "east": -180.0, "geometry": ["POINT(-180 -90)"], "keywords": "Antarctica; Carbon Dioxide; Ice Core Gas Records; Nitrous Oxide; South Pole; SPICEcore", "locations": "South Pole; Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Brook, Edward J.", "project_titles": "Controls on Variations in Atmospheric Carbon Dioxide and Nitrous Oxide During the Last 10,000 years", "projects": [{"proj_uid": "p0010043", "repository": "USAP-DC", "title": "Controls on Variations in Atmospheric Carbon Dioxide and Nitrous Oxide During the Last 10,000 years"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "SPICEcore Holocene CO2 and N2O data", "uid": "601197", "west": -180.0}, {"awards": "1245821 Brook, Edward J.", "bounds_geometry": ["POINT(162.167 -77.733)"], "date_created": "Fri, 01 Jan 2016 00:00:00 GMT", "description": "This award supports a project to use the Taylor Glacier, Antarctica, ablation zone to collect ice samples for a range of paleoenvironmental studies. A record of carbon-14 of atmospheric methane (14CH4) will be obtained for the last deglaciation and the Early Holocene, together with a supporting record of CH4 stable isotopes. In-situ cosmogenic 14C content and partitioning of 14C between different species (14CH4, C-14 carbon monoxide (14CO) and C-14 carbon dioxide (14CO2)) will be determined with unprecedented precision in ice from the surface down to ~67 m. Further age-mapping of the ablating ice stratigraphy will take place using a combination of CH4, CO2, and delta 18O of oxygen gas and H2O stable isotopes. High precision, high-resolution records of CO2, delta 13C of CO2, nitrous oxide (N2O) and N2O isotopes will be obtained for the last deglaciation and intervals during the last glacial period. The potential of 14CO2 and Krypton-81 (81Kr) as absolute dating tools for glacial ice will be investigated. The intellectual merit of proposed work includes the fact that the response of natural methane sources to continuing global warming is uncertain, and available evidence is insufficient to rule out the possibility of catastrophic releases from large 14C-depleted reservoirs such as CH4 clathrates and permafrost. The proposed paleoatmospheric 14CH4 record will improve our understanding of the possible magnitude and timing of CH4 release from these reservoirs during a large climatic warming. A thorough understanding of in-situ cosmogenic 14C in glacial ice (production rates by different mechanisms and partitioning between species) is currently lacking. Such an understanding will likely enable the use of in-situ 14CO in ice at accumulation sites as a reliable, uncomplicated tracer of the past cosmic ray flux and possibly past solar activity, as well as the use of 14CO2 at both ice accumulation and ice ablation sites as an absolute dating tool. Significant gaps remain in our understanding of the natural carbon cycle, as well as in its responses to global climate change. The proposed high-resolution, high-precision records of delta 13C of CO2 would provide new information on carbon cycle changes both during times of rising CO2 in a warming climate and falling CO2 in a cooling climate. N2O is an important greenhouse gas that increased by ~30% during the last deglaciation. The causes of this increase are still largely uncertain, and the proposed high-precision record of N2O concentration and isotopes would provide further insights into N2O source changes in a warming world. The broader impacts of proposed work include an improvement in our understanding of the response of these greenhouse gas budgets to global warming and inform societally important model projections of future climate change. The continued age-mapping of Taylor Glacier ablation ice will add value to this high-quality, easily accessible archive of natural environmental variability. Establishing 14CO as a robust new tracer for past cosmic ray flux would inform paleoclimate studies and constitute a valuable contribution to the study of the societally important issue of climate change. The proposed work will contribute to the development of new laboratory and field analytical systems. The data from the study will be made available to the scientific community and the broad public through the NSIDC and NOAA Paleoclimatology data centers. 1 graduate student each will be trained at UR, OSU and SIO, and the work will contribute to the training of a postdoc at OSU. 3 UR undergraduates will be involved in fieldwork and research. The work will support a new, junior UR faculty member, Petrenko. All PIs have a strong history of and commitment to scientific outreach in the forms of media interviews, participation in filming of field projects, as well as speaking to schools and the public about their research, and will continue these activities as part of the proposed work. This award has field work in Antarctica.", "east": 162.167, "geometry": ["POINT(162.167 -77.733)"], "keywords": "Antarctica; Atmosphere; Geochemistry; Ice Core Records; Isotope; Paleoclimate; Taylor Glacier; Transantarctic Mountains", "locations": "Taylor Glacier; Transantarctic Mountains; Antarctica", "north": -77.733, "nsf_funding_programs": null, "persons": "Brook, Edward J.", "project_titles": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "projects": [{"proj_uid": "p0000283", "repository": "USAP-DC", "title": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.733, "title": "The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "uid": "600163", "west": 162.167}, {"awards": "0739681 Murray, Alison; 0739698 Doran, Peter", "bounds_geometry": ["POINT(161.931 -77.3885)"], "date_created": "Tue, 01 Jan 2013 00:00:00 GMT", "description": "Lake Vida is the largest lake of the McMurdo Dry Valleys, with an approximately 20 m ice cover overlaying a brine of unknown depth with at least 7 times seawater salinity and temperatures below -10 degrees C year-round. Samples of brine collected from ice above the main water body contain 1) the highest nitrous oxide levels of any natural water body on Earth, 2) unusual geochemistry including anomalously high ammonia and iron concentrations, 3) high microbial counts with an unusual proportion (99%) of ultramicrobacteria. The microbial community is unique even compared to other Dry Valley Lakes. The research proposes to enter, for the first time the main brine body below the thick ice of Lake Vida and perform in situ measurements, collect samples of the brine column, and collect sediment cores from the lake bottom for detailed geochemical and microbiological analyses. The results will allow the characterization of present and past life in the lake, assessment of modern and past sedimentary processes, and determination of the lake\u0027s history. The research will be conducted by a multidisciplinary team that will uncover the biogeochemical processes associated with a non-photosynthetic microbial community isolated for a significant period of time. This research will address diversity, adaptive mechanisms and evolutionary processes in the context of the physical evolution of the environment of Lake Vida. Results will be widely disseminated through publications, presentations at national and international meetings, through the Subglacial Antarctic Lake Exploration (SALE) web site and the McMurdo LTER web site. The research will support three graduate students and three undergraduate research assistants. The results will be incorporated into a new undergraduate biogeosciences course at the University of Illinois at Chicago which has an extremely diverse student body, dominated by minorities.", "east": 161.931, "geometry": ["POINT(161.931 -77.3885)"], "keywords": "Antarctica; Biota; Carbon-14; Chemistry:fluid; Chemistry:Fluid; Chemistry:ice; Chemistry:Ice; Dry Valleys; Geochronology; Ice Core Records; Lake Vida; Microbiology", "locations": "Dry Valleys; Lake Vida; Antarctica", "north": -77.3885, "nsf_funding_programs": null, "persons": "Murray, Alison", "project_titles": "Collaborative Research: Geochemistry and Microbiology of the Extreme Aquatic Environment in Lake Vida, East Antarctica", "projects": [{"proj_uid": "p0000485", "repository": "USAP-DC", "title": "Collaborative Research: Geochemistry and Microbiology of the Extreme Aquatic Environment in Lake Vida, East Antarctica"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.3885, "title": "Geochemistry and Microbiology of the Extreme Aquatic Environment in Lake Vida, East Antarctica", "uid": "600080", "west": 161.931}, {"awards": "0230276 Ward, Bess", "bounds_geometry": ["POLYGON((162 -77.2,162.16 -77.2,162.32 -77.2,162.48 -77.2,162.64 -77.2,162.8 -77.2,162.96 -77.2,163.12 -77.2,163.28 -77.2,163.44 -77.2,163.6 -77.2,163.6 -77.26,163.6 -77.32,163.6 -77.38,163.6 -77.44,163.6 -77.5,163.6 -77.56,163.6 -77.62,163.6 -77.68,163.6 -77.74,163.6 -77.8,163.44 -77.8,163.28 -77.8,163.12 -77.8,162.96 -77.8,162.8 -77.8,162.64 -77.8,162.48 -77.8,162.32 -77.8,162.16 -77.8,162 -77.8,162 -77.74,162 -77.68,162 -77.62,162 -77.56,162 -77.5,162 -77.44,162 -77.38,162 -77.32,162 -77.26,162 -77.2))"], "date_created": "Thu, 01 Jan 2009 00:00:00 GMT", "description": "Denitrification is the main process by which fixed nitrogen is lost from ecosystems and the regulation of this process may directly affect primary production and carbon cycling over short and long time scales. Previous investigations of the role of bioactive metals in regulating denitrification in bacteria from permanently ice-covered Lake Bonney in the Taylor Valley of East Antarctica indicated that denitrifying bacteria can be negatively affected by metals such as copper, iron, cadmium, lead, chromium, nickel, silver and zinc; and that there is a distinct difference in denitrifying activity between the east and west lobes of the lake. \n\nLow iron concentrations were found to exacerbate the potential toxicity of the other metals, while silver has the potential to specifically inhibit denitrification because of its ability to interfere with copper binding in redox proteins, such as nitrite reductase and nitrous oxide reductase. High silver concentrations might prevent the functioning of nitrous oxide reductase in the same way that simple copper limitation does, thereby causing the buildup of nitrous oxide and resulting in a nonfunctional nitrogen cycle. Other factors, such as oxygen concentration, are likely also to affect bacterial activity in Lake Bonney.\n\nThis project will investigate silver toxicity, general metal toxicity and oxygen concentration to determine their effect on denitrification in the lake by using a suite of \u0027sentinel\u0027 strains of denitrifying bacteria (isolated from the lake) incubated in Lake Bonney water and subjected to various treatments. The physiological responses of these strains to changes in metal and oxygen concentration will be quantified by flow cytometric detection of single cell molecular probes whose sensitivity and interpretation have been optimized for the sentinel strains. Understanding the relationships between metals and denitrification is expected to enhance our understanding of not only Lake Bonney\u0027s unusual nitrogen cycle, but more generally, of the potential role of metals in the regulation of microbial nitrogen transformations. The broader impacts of this work include not only a better understanding of regional biogeochemistry and global perspectives on these processes; but also the training of graduate students and a substantial outreach effort for school children.", "east": 163.6, "geometry": ["POINT(162.8 -77.5)"], "keywords": "Antarctica; Biota; CTD Data; Dry Valleys; Lake Bonney; Lake Vanda; Microbiology; Taylor Valley", "locations": "Dry Valleys; Lake Bonney; Lake Vanda; Taylor Valley; Antarctica", "north": -77.2, "nsf_funding_programs": null, "persons": "Ward, Bess", "project_titles": "Collaborative Research: What Limits Denitrification and Bacterial Growth in Lake Bonney, Taylor Valley, Antarctica?", "projects": [{"proj_uid": "p0000223", "repository": "USAP-DC", "title": "Collaborative Research: What Limits Denitrification and Bacterial Growth in Lake Bonney, Taylor Valley, Antarctica?"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.8, "title": "What Limits Denitrification and Bacterial Growth in Lake Bonney, Taylor Valley, Antarctica?", "uid": "600033", "west": 162.0}, {"awards": "9526556 Sowers, Todd", "bounds_geometry": ["POINT(-148.3023 -81.403)"], "date_created": "Mon, 09 Jul 2007 00:00:00 GMT", "description": "This data set includes records of the delta carbon-13 (\u0026delta;\u003csup\u003e13\u003c/sup\u003eC) of methane (CH\u003csub\u003e4\u003c/sub\u003e) in firn air from the South Pole and trapped in bubbles in a short ice core from Siple Dome, Antarctica. Using two firn air samples, one from January 1995 and the other from January 2001, investigators reconstructed records of the isotopic composition of paleoatmospheric methane covering the last 2 centuries, from 1820 to 2001. \n\nData are in Microsoft Excel and Microsoft Word formats and are available via FTP.", "east": -148.3023, "geometry": ["POINT(-148.3023 -81.403)"], "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Siple Dome; Snow/ice; Snow/Ice; South Pole", "locations": "Siple Dome; South Pole; Antarctica", "north": -81.403, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Sowers, Todd A.", "project_titles": "Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide", "projects": [{"proj_uid": "p0000611", "repository": "USAP-DC", "title": "Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.403, "title": "Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica", "uid": "609310", "west": -148.3023}]
X
X
Help on the Results MapX
This window can be dragged by its header, and can be resized from the bottom right corner.
Clicking the Layers button - the blue square in the top left of the Results Map - will display a list of map layers you can add or remove
from the currently displayed map view.
The Results Map and the Results Table
- The Results Map displays the centroids of the geographic bounds of all the results returned by the search.
- Results that are displayed in the current map view will be highlighted in blue and brought to the top of the Results Table.
- As the map is panned or zoomed, the highlighted rows in the table will update.
- If you click on a centroid on the map, it will turn yellow and display a popup with details for that project/dataset - including a link to the landing page. The bounds for the project(s)/dataset(s) selected will be displayed in red. The selected result(s) will be highlighted in red and brought to the top of the table.
- The default table sorting order is: Selected, Visible, Date (descending), but this can be changed by clicking on column headers in the table.
- Selecting Show on Map for an individual row will both display the geographic bounds for that result on a mini map, and also display the bounds and highlight the centroid on the Results Map.
- Clicking the 'Show boundaries' checkbox at the top of the Results Map will display all the bounds for the filtered results.
Defining a search area on the Results Map
- If you click on the Rectangle or Polygon icons in the top right of the Results Map, you can define a search area which will be added to any other search criteria already selected.
- After you have drawn a polygon, you can edit it using the Edit Geometry dropdown in the search form at the top.
- Clicking Clear in the map will clear any drawn polygon.
- Clicking Search in the map, or Search on the form will have the same effect.
- The returned results will be any projects/datasets with bounds that intersect the polygon.
- Use the Exclude project/datasets checkbox to exclude any projects/datasets that cover the whole Antarctic region.
Viewing map layers on the Results Map
To sort the table of search results, click the header of the column you wish to search by. To sort by multiple columns, hold down the shift key whilst selecting the sort columns in order.
Dataset Title/Abstract/Map | NSF Award(s) | Date Created | PIs / Scientists | Project Links | Abstract | Bounds Geometry | Geometry | Selected | Visible |
---|---|---|---|---|---|---|---|---|---|
Final N2O isotopic data including isotopomer ratios for the last deglaciation and Heinrich Stadia 4/Dansgaard Oeschger Event 8
|
1903681 |
2024-06-26 | Menking, Andy; Brook, Edward J. | No project link provided | This data set is a new N2O isotopic data set including site preference isotopic data derived from ice core samples containing air spanning the deglacial N2O rise (16.5-13.2 ka). The data extend through the Younger Dryas cooling interval, when N2O decreased by about 30 ppb (13.2-11.9 ka). The data set also contains N2O isotope records spanning the Heinrich Stadial 4 / Dansgaard-Oeschger 8 (HS4/DO8) transition (39.8-35.8 ka), an example of cyclical millennial-scale N2O variability characteristic of the last ice age. | ["POLYGON((160 -77.6,160.25 -77.6,160.5 -77.6,160.75 -77.6,161 -77.6,161.25 -77.6,161.5 -77.6,161.75 -77.6,162 -77.6,162.25 -77.6,162.5 -77.6,162.5 -77.63,162.5 -77.66,162.5 -77.69,162.5 -77.72,162.5 -77.75,162.5 -77.78,162.5 -77.81,162.5 -77.84,162.5 -77.87,162.5 -77.9,162.25 -77.9,162 -77.9,161.75 -77.9,161.5 -77.9,161.25 -77.9,161 -77.9,160.75 -77.9,160.5 -77.9,160.25 -77.9,160 -77.9,160 -77.87,160 -77.84,160 -77.81,160 -77.78,160 -77.75,160 -77.72,160 -77.69,160 -77.66,160 -77.63,160 -77.6))"] | ["POINT(161.25 -77.75)"] | false | false |
Concentration and isotopic composition of atmospheric N2O over the last century
|
1643716 |
2023-05-22 | Ghosh, Sambit; Toyoda, Sakae ; Buizert, Christo ; Langenfelds, Ray L ; Yoshida, Naohiro ; Joong Kim, Seong; Ahn, Jinho ; Etheridge, David |
Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability |
We have reconstructed the atmospheric N2O mole fraction and its isotopic composition by combining data from ice cores, firn air, and atmospheric samples. The mole fraction reconstruction extends back to 1000 CE using ice cores, firn air, and atmospheric sampling; and the isotopic reconstruction extends back to 1900 CE using only firn air data. We have incorporated both newly measured and previously published data. We present new data for the mole fraction, d15Nbulk, d18O, and d15NSP values from the Styx (East Antarctica) firn air, and mole fraction from the North Greenland Eemian Ice drilling Project (NEEM) firn air. We have used published records from the Styx and NEEM ice cores, direct atmospheric measurements from the NOAA global sampling network, and firn air data, giving a total of 11 sites for N2O mole fraction, 12 sites for d15Nbulk, 11 sites for d18O, and 8 sites for d15NSP values. | ["POLYGON((-180 -67,-144 -67,-108 -67,-72 -67,-36 -67,0 -67,36 -67,72 -67,108 -67,144 -67,180 -67,180 -69.3,180 -71.6,180 -73.9,180 -76.2,180 -78.5,180 -80.8,180 -83.1,180 -85.4,180 -87.7,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.7,-180 -85.4,-180 -83.1,-180 -80.8,-180 -78.5,-180 -76.2,-180 -73.9,-180 -71.6,-180 -69.3,-180 -67))"] | ["POINT(0 -89.999)"] | false | false |
Water column biogeochemical data from Mercer Subglacial Lake
|
1543537 |
2023-02-01 | Dore, John; Skidmore, Mark; Hawkings, Jon; Steigmeyer, August; Li, Wei; Barker, Joel; Tranter, Martyn; Priscu, John; Science Team, SALSA |
Collaborative Research: Subglacial Antarctic Lakes Scientific Access (SALSA): Integrated Study of Carbon Cycling in Hydrologically-active Subglacial Environments |
This dataset contains water column biogeochemical properties measured on discrete samples collected from Mercer Subglacial Lake by the SALSA project. Data included are: specific conductance; carbonic acid system parameters (total alkalinity, total inorganic carbon, and pH); water stable isotopes (δ2H and δ18O); dissolved gases (oxygen, methane, nitrous oxide, and hydrogen); dissolved nutrients (ammonium, nitrite and phosphate), major anions (including nitrate) and cations; size-fractionated colloidal and dissolved trace elements); dissolved organic carbon; and microbial cell and virus-like particle counts. | ["POINT(-149.50134 -84.640287)"] | ["POINT(-149.50134 -84.640287)"] | false | false |
Preliminary nitrous oxide site preference isotopic data for last deglaciation from Taylor Glacier
|
1903681 |
2022-08-02 | Menking, Andy; Brook, Edward J. |
Deciphering Changes in Atmospheric Nitrous Oxide Concentration During the Last Ice Age Using the Intramolecular Site-Preference of Nitrogen Isotopes |
Measurements of the isotopic composition of atmospheric nitrous oxide from samples from the Taylor Glacier, Antarctica, spanning the last deglaciation (21-11 ka) and part of the last glacial period (40 to 36 ka). Data set includes the site preference of 15-N in N2O. A manuscript describing these data is currently in preparation. Data are referenced to in house air standards at OSU which are currently being cross calibrated with other laboratories. | ["POLYGON((161.745 -77.745,161.746 -77.745,161.747 -77.745,161.748 -77.745,161.749 -77.745,161.75 -77.745,161.751 -77.745,161.752 -77.745,161.753 -77.745,161.754 -77.745,161.755 -77.745,161.755 -77.74600000000001,161.755 -77.747,161.755 -77.748,161.755 -77.749,161.755 -77.75,161.755 -77.751,161.755 -77.752,161.755 -77.753,161.755 -77.75399999999999,161.755 -77.755,161.754 -77.755,161.753 -77.755,161.752 -77.755,161.751 -77.755,161.75 -77.755,161.749 -77.755,161.748 -77.755,161.747 -77.755,161.746 -77.755,161.745 -77.755,161.745 -77.75399999999999,161.745 -77.753,161.745 -77.752,161.745 -77.751,161.745 -77.75,161.745 -77.749,161.745 -77.748,161.745 -77.747,161.745 -77.74600000000001,161.745 -77.745))"] | ["POINT(161.75 -77.75)"] | false | false |
N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica
|
1246148 1245821 1245659 |
2020-11-02 | Menking, James; Brook, Edward J.; Schilt, Adrian; Shackleton, Sarah; Dyonisius, Michael; Severinghaus, Jeffrey P.; Petrenko, Vasilii |
Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive |
Ice core measurements of the concentration and stable isotopic composition of atmospheric nitrous oxide (N2O) 74,000-59,000 years ago constrain marine and terrestrial emissions. The data include two major Dansgaard-Oeschger (D-O) events and the N2O decrease during global cooling at the Marine Isotope Stage (MIS) 5a-4 transition. The N2O increase associated with D-O 19 (~73-71.5 ka) was driven by equal contributions from marine and terrestrial emissions. The N2O decrease during the transition into MIS 4 (~71.5-67.5 ka) was caused by gradual reductions of similar magnitude in both marine and terrestrial sources. A 50 ppb increase in N2O concentration at the end of MIS 4 was caused by gradual increases in marine and terrestrial emissions between ~64-61 ka, followed by an abrupt increase in marine emissions at the onset of D-O 16/17 (59.5 ka). This suggests that the importance of marine versus terrestrial emissions in controlling millennial-scale N2O fluctuations varied in time. | [] | [] | false | false |
SPICEcore Holocene CO2 and N2O data
|
1443550 |
2019-08-08 | Brook, Edward J. |
Controls on Variations in Atmospheric Carbon Dioxide and Nitrous Oxide During the Last 10,000 years |
Measurements of CO2, N2O, and the isotopic composition of CO2 from the Holocene section of SPICEcore | ["POINT(-180 -90)"] | ["POINT(-180 -90)"] | false | false |
The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive
|
1245821 |
2016-01-01 | Brook, Edward J. |
Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive |
This award supports a project to use the Taylor Glacier, Antarctica, ablation zone to collect ice samples for a range of paleoenvironmental studies. A record of carbon-14 of atmospheric methane (14CH4) will be obtained for the last deglaciation and the Early Holocene, together with a supporting record of CH4 stable isotopes. In-situ cosmogenic 14C content and partitioning of 14C between different species (14CH4, C-14 carbon monoxide (14CO) and C-14 carbon dioxide (14CO2)) will be determined with unprecedented precision in ice from the surface down to ~67 m. Further age-mapping of the ablating ice stratigraphy will take place using a combination of CH4, CO2, and delta 18O of oxygen gas and H2O stable isotopes. High precision, high-resolution records of CO2, delta 13C of CO2, nitrous oxide (N2O) and N2O isotopes will be obtained for the last deglaciation and intervals during the last glacial period. The potential of 14CO2 and Krypton-81 (81Kr) as absolute dating tools for glacial ice will be investigated. The intellectual merit of proposed work includes the fact that the response of natural methane sources to continuing global warming is uncertain, and available evidence is insufficient to rule out the possibility of catastrophic releases from large 14C-depleted reservoirs such as CH4 clathrates and permafrost. The proposed paleoatmospheric 14CH4 record will improve our understanding of the possible magnitude and timing of CH4 release from these reservoirs during a large climatic warming. A thorough understanding of in-situ cosmogenic 14C in glacial ice (production rates by different mechanisms and partitioning between species) is currently lacking. Such an understanding will likely enable the use of in-situ 14CO in ice at accumulation sites as a reliable, uncomplicated tracer of the past cosmic ray flux and possibly past solar activity, as well as the use of 14CO2 at both ice accumulation and ice ablation sites as an absolute dating tool. Significant gaps remain in our understanding of the natural carbon cycle, as well as in its responses to global climate change. The proposed high-resolution, high-precision records of delta 13C of CO2 would provide new information on carbon cycle changes both during times of rising CO2 in a warming climate and falling CO2 in a cooling climate. N2O is an important greenhouse gas that increased by ~30% during the last deglaciation. The causes of this increase are still largely uncertain, and the proposed high-precision record of N2O concentration and isotopes would provide further insights into N2O source changes in a warming world. The broader impacts of proposed work include an improvement in our understanding of the response of these greenhouse gas budgets to global warming and inform societally important model projections of future climate change. The continued age-mapping of Taylor Glacier ablation ice will add value to this high-quality, easily accessible archive of natural environmental variability. Establishing 14CO as a robust new tracer for past cosmic ray flux would inform paleoclimate studies and constitute a valuable contribution to the study of the societally important issue of climate change. The proposed work will contribute to the development of new laboratory and field analytical systems. The data from the study will be made available to the scientific community and the broad public through the NSIDC and NOAA Paleoclimatology data centers. 1 graduate student each will be trained at UR, OSU and SIO, and the work will contribute to the training of a postdoc at OSU. 3 UR undergraduates will be involved in fieldwork and research. The work will support a new, junior UR faculty member, Petrenko. All PIs have a strong history of and commitment to scientific outreach in the forms of media interviews, participation in filming of field projects, as well as speaking to schools and the public about their research, and will continue these activities as part of the proposed work. This award has field work in Antarctica. | ["POINT(162.167 -77.733)"] | ["POINT(162.167 -77.733)"] | false | false |
Geochemistry and Microbiology of the Extreme Aquatic Environment in Lake Vida, East Antarctica
|
0739681 0739698 |
2013-01-01 | Murray, Alison |
Collaborative Research: Geochemistry and Microbiology of the Extreme Aquatic Environment in Lake Vida, East Antarctica |
Lake Vida is the largest lake of the McMurdo Dry Valleys, with an approximately 20 m ice cover overlaying a brine of unknown depth with at least 7 times seawater salinity and temperatures below -10 degrees C year-round. Samples of brine collected from ice above the main water body contain 1) the highest nitrous oxide levels of any natural water body on Earth, 2) unusual geochemistry including anomalously high ammonia and iron concentrations, 3) high microbial counts with an unusual proportion (99%) of ultramicrobacteria. The microbial community is unique even compared to other Dry Valley Lakes. The research proposes to enter, for the first time the main brine body below the thick ice of Lake Vida and perform in situ measurements, collect samples of the brine column, and collect sediment cores from the lake bottom for detailed geochemical and microbiological analyses. The results will allow the characterization of present and past life in the lake, assessment of modern and past sedimentary processes, and determination of the lake's history. The research will be conducted by a multidisciplinary team that will uncover the biogeochemical processes associated with a non-photosynthetic microbial community isolated for a significant period of time. This research will address diversity, adaptive mechanisms and evolutionary processes in the context of the physical evolution of the environment of Lake Vida. Results will be widely disseminated through publications, presentations at national and international meetings, through the Subglacial Antarctic Lake Exploration (SALE) web site and the McMurdo LTER web site. The research will support three graduate students and three undergraduate research assistants. The results will be incorporated into a new undergraduate biogeosciences course at the University of Illinois at Chicago which has an extremely diverse student body, dominated by minorities. | ["POINT(161.931 -77.3885)"] | ["POINT(161.931 -77.3885)"] | false | false |
What Limits Denitrification and Bacterial Growth in Lake Bonney, Taylor Valley, Antarctica?
|
0230276 |
2009-01-01 | Ward, Bess |
Collaborative Research: What Limits Denitrification and Bacterial Growth in Lake Bonney, Taylor Valley, Antarctica? |
Denitrification is the main process by which fixed nitrogen is lost from ecosystems and the regulation of this process may directly affect primary production and carbon cycling over short and long time scales. Previous investigations of the role of bioactive metals in regulating denitrification in bacteria from permanently ice-covered Lake Bonney in the Taylor Valley of East Antarctica indicated that denitrifying bacteria can be negatively affected by metals such as copper, iron, cadmium, lead, chromium, nickel, silver and zinc; and that there is a distinct difference in denitrifying activity between the east and west lobes of the lake. Low iron concentrations were found to exacerbate the potential toxicity of the other metals, while silver has the potential to specifically inhibit denitrification because of its ability to interfere with copper binding in redox proteins, such as nitrite reductase and nitrous oxide reductase. High silver concentrations might prevent the functioning of nitrous oxide reductase in the same way that simple copper limitation does, thereby causing the buildup of nitrous oxide and resulting in a nonfunctional nitrogen cycle. Other factors, such as oxygen concentration, are likely also to affect bacterial activity in Lake Bonney. This project will investigate silver toxicity, general metal toxicity and oxygen concentration to determine their effect on denitrification in the lake by using a suite of 'sentinel' strains of denitrifying bacteria (isolated from the lake) incubated in Lake Bonney water and subjected to various treatments. The physiological responses of these strains to changes in metal and oxygen concentration will be quantified by flow cytometric detection of single cell molecular probes whose sensitivity and interpretation have been optimized for the sentinel strains. Understanding the relationships between metals and denitrification is expected to enhance our understanding of not only Lake Bonney's unusual nitrogen cycle, but more generally, of the potential role of metals in the regulation of microbial nitrogen transformations. The broader impacts of this work include not only a better understanding of regional biogeochemistry and global perspectives on these processes; but also the training of graduate students and a substantial outreach effort for school children. | ["POLYGON((162 -77.2,162.16 -77.2,162.32 -77.2,162.48 -77.2,162.64 -77.2,162.8 -77.2,162.96 -77.2,163.12 -77.2,163.28 -77.2,163.44 -77.2,163.6 -77.2,163.6 -77.26,163.6 -77.32,163.6 -77.38,163.6 -77.44,163.6 -77.5,163.6 -77.56,163.6 -77.62,163.6 -77.68,163.6 -77.74,163.6 -77.8,163.44 -77.8,163.28 -77.8,163.12 -77.8,162.96 -77.8,162.8 -77.8,162.64 -77.8,162.48 -77.8,162.32 -77.8,162.16 -77.8,162 -77.8,162 -77.74,162 -77.68,162 -77.62,162 -77.56,162 -77.5,162 -77.44,162 -77.38,162 -77.32,162 -77.26,162 -77.2))"] | ["POINT(162.8 -77.5)"] | false | false |
Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica
|
9526556 |
2007-07-09 | Sowers, Todd A. |
Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide |
This data set includes records of the delta carbon-13 (δ<sup>13</sup>C) of methane (CH<sub>4</sub>) in firn air from the South Pole and trapped in bubbles in a short ice core from Siple Dome, Antarctica. Using two firn air samples, one from January 1995 and the other from January 2001, investigators reconstructed records of the isotopic composition of paleoatmospheric methane covering the last 2 centuries, from 1820 to 2001. Data are in Microsoft Excel and Microsoft Word formats and are available via FTP. | ["POINT(-148.3023 -81.403)"] | ["POINT(-148.3023 -81.403)"] | false | false |