{"dp_type": "Project", "free_text": "SULFUR COMPOUNDS"}
[{"awards": "1341717 Ackley, Stephen; 1341606 Stammerjohn, Sharon; 1341513 Maksym, Edward; 1543483 Sedwick, Peter; 1341725 Guest, Peter", "bounds_geometry": "POLYGON((-180 -55,-177 -55,-174 -55,-171 -55,-168 -55,-165 -55,-162 -55,-159 -55,-156 -55,-153 -55,-150 -55,-150 -57.3,-150 -59.6,-150 -61.9,-150 -64.2,-150 -66.5,-150 -68.8,-150 -71.1,-150 -73.4,-150 -75.7,-150 -78,-153 -78,-156 -78,-159 -78,-162 -78,-165 -78,-168 -78,-171 -78,-174 -78,-177 -78,180 -78,178 -78,176 -78,174 -78,172 -78,170 -78,168 -78,166 -78,164 -78,162 -78,160 -78,160 -75.7,160 -73.4,160 -71.1,160 -68.8,160 -66.5,160 -64.2,160 -61.9,160 -59.6,160 -57.3,160 -55,162 -55,164 -55,166 -55,168 -55,170 -55,172 -55,174 -55,176 -55,178 -55,-180 -55))", "dataset_titles": "ASPeCt Visual Ice Observations on PIPERS Cruise NBP1704 April-June 2017; Expedition data of NBP1704; Impact of Convective Processes and Sea Ice Formation on the Distribution of Iron in the Ross Sea: Closing the Seasonal Cycle; NBP1704 CTD sensor data; NBP1704 Expedition Data; PIPERS Airborne LiDAR Data; PIPERS Meteorology Rawinsonde Data; PIPERS Meteorology Time Series; PIPERS Noble Gases; Sea Ice Layer Cakes, PIPERS 2017; SUMO unmanned aerial system (UAS) atmospheric data", "datasets": [{"dataset_uid": "601609", "doi": "10.15784/601609", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Mass Spectrometer; NBP1704; Noble Gas; Oceans; Ross Sea; R/v Nathaniel B. Palmer", "people": "Loose, Brice", "repository": "USAP-DC", "science_program": null, "title": "PIPERS Noble Gases", "url": "https://www.usap-dc.org/view/dataset/601609"}, {"dataset_uid": "601422", "doi": "10.15784/601422", "keywords": "Antarctica; CTD; CTD Data; NBP1704; Ocean Profile Data; Ross Sea; R/v Nathaniel B. Palmer; Salinity; Temperature", "people": "Stammerjohn, Sharon", "repository": "USAP-DC", "science_program": null, "title": "NBP1704 CTD sensor data", "url": "https://www.usap-dc.org/view/dataset/601422"}, {"dataset_uid": "601183", "doi": "10.15784/601183", "keywords": "Antarctica; Glaciology; Ice Concentration; Ice Thickness; Ice Type; NBP1704; Oceans; Ross Sea; R/v Nathaniel B. Palmer; Sea Ice; Snow Depth; Snow/ice; Snow/Ice; Visual Observations", "people": "Ackley, Stephen", "repository": "USAP-DC", "science_program": null, "title": "ASPeCt Visual Ice Observations on PIPERS Cruise NBP1704 April-June 2017", "url": "https://www.usap-dc.org/view/dataset/601183"}, {"dataset_uid": "601184", "doi": "10.15784/601184 ", "keywords": "Air Temperature; Antarctica; Atmosphere; Meteorology; Near-Surface Air Temperatures; PIPERS; Radiation; Sea Ice Temperatures; Temperature; Weather Station Data; Wind Direction; Wind Speed", "people": "Guest, Peter", "repository": "USAP-DC", "science_program": null, "title": "PIPERS Meteorology Time Series", "url": "https://www.usap-dc.org/view/dataset/601184"}, {"dataset_uid": "601185", "doi": "10.15784/601185 ", "keywords": "Air Temperature; Antarctica; Atmosphere; Atmospheric Surface Winds; Meteorology; NBP1704; PIPERS; Pressure; Radiosonde; Rawinsonde; Relative Humidity; Ross Sea; R/v Nathaniel B. Palmer; Wind Direction; Wind Speed", "people": "Guest, Peter", "repository": "USAP-DC", "science_program": null, "title": "PIPERS Meteorology Rawinsonde Data", "url": "https://www.usap-dc.org/view/dataset/601185"}, {"dataset_uid": "002663", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of NBP1704", "url": "https://www.rvdata.us/search/cruise/NBP1704"}, {"dataset_uid": "601188", "doi": "10.15784/601188", "keywords": "Aerogeophysics; Airborne Laser Altimetry; Antarctica; LIDAR; PIPERS; Ross Sea; Sea Ice", "people": "Bertinato, Christopher; Locke, Caitlin; Bell, Robin; Xie, Hongjie; Dhakal, Tejendra", "repository": "USAP-DC", "science_program": null, "title": "PIPERS Airborne LiDAR Data", "url": "https://www.usap-dc.org/view/dataset/601188"}, {"dataset_uid": "001363", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "NBP1704 Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP1704"}, {"dataset_uid": "601191", "doi": "10.15784/601191", "keywords": "Air Temperature; Antarctica; Atmosphere; Meteorology; NBP1704; PIPERS; R/v Nathaniel B. Palmer; Southern Ocean; Temperature Profiles; UAV; Unmanned Aircraft", "people": "Cassano, John", "repository": "USAP-DC", "science_program": null, "title": "SUMO unmanned aerial system (UAS) atmospheric data", "url": "https://www.usap-dc.org/view/dataset/601191"}, {"dataset_uid": "200150", "doi": "", "keywords": null, "people": null, "repository": "BCO-DMO", "science_program": null, "title": "Impact of Convective Processes and Sea Ice Formation on the Distribution of Iron in the Ross Sea: Closing the Seasonal Cycle", "url": "https://www.bco-dmo.org/project/815403"}, {"dataset_uid": "601207", "doi": "10.15784/601207", "keywords": "Antarctica; Digital Elevation Model; Glaciology; Ice; Ice Thickness; Ice Thickness Distribution; LIDAR; NBP1704; PIPERS; Ross Sea; R/v Nathaniel B. Palmer; Sea Ice; Snow; Snow Depth; Surface Elevation", "people": "Maksym, Edward; Jeffrey Mei, M.; Mei, M. Jeffrey", "repository": "USAP-DC", "science_program": null, "title": "Sea Ice Layer Cakes, PIPERS 2017", "url": "https://www.usap-dc.org/view/dataset/601207"}], "date_created": "Mon, 10 Jun 2019 00:00:00 GMT", "description": "Proposal Title: Collaborative Research: Seasonal Sea Ice Production in the Ross Sea, Antarctica (working title changed from submitted title) Institutions: UT-San Antonio; Columbia University; Naval Postgraduate School; Woods Hole Oceanographic Institute; UC@Boulder The one place on Earth consistently showing increases in sea ice area, duration, and concentration is the Ross Sea in Antarctica. Satellite imagery shows about half of the Ross Sea increases are associated with changes in the austral fall, when the new sea ice is forming. The most pronounced changes are also located near polynyas, which are areas of open ocean surrounded by sea ice. To understand the processes driving the sea ice increase, and to determine if the increase in sea ice area is also accompanied by a change in ice thickness, this project will conduct an oceanographic cruise to the polynyas of the Ross Sea in April and May, 2017, which is the austral fall. The team will deploy state of the art research tools including unmanned airborne systems (UASs, commonly called drones), autonomous underwater vehicles (AUVs), and remotely operated underwater vehicles (ROVs). Using these tools and others, the team will study atmospheric, oceanic, and sea ice properties and processes concurrently. A change in sea ice production will necessarily change the ocean water below, which may have significant consequences for global ocean circulation patterns, a topic of international importance. All the involved institutions will be training students, and all share the goal of expanding climate literacy in the US, emphasizing the role high latitudes play in the Earth\u0027s dynamic climate. The main goal of the project is to improve estimates of sea ice production and water mass transformation in the Ross Sea. The team will fully capture the spatial and temporal changes in air-ice-ocean interactions when they are initiated in the austral fall, and then track the changes into the winter and spring using ice buoys, and airborne mapping with the newly commissioned IcePod instrument system, which is deployed on the US Antarctic Program\u0027s LC-130 fleet. The oceanographic cruise will include stations in and outside of both the Terra Nova Bay and Ross Ice Shelf polynyas. Measurements to be made include air-sea boundary layer fluxes of heat, freshwater, and trace gases, radiation, and meteorology in the air; ice formation processes, ice thickness, snow depth, mass balance, and ice drift within the sea ice zone; and temperature, salinity, and momentum in the ocean below. Following collection of the field data, the team will improve both model parameterizations of air-sea-ice interactions and remote sensing algorithms. Model parameterizations are needed to determine if sea-ice production has increased in crucial areas, and if so, why (e.g., stronger winds or fresher oceans). The remote sensing validation will facilitate change detection over wider areas and verify model predictions over time. Accordingly this project will contribute to the international Southern Ocean Observing System (SOOS) goal of measuring essential climate variables continuously to monitor the state of the ocean and ice cover into the future.", "east": -150.0, "geometry": "POINT(-175 -66.5)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e CTD; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e LIDAR/LASER SOUNDERS \u003e LIDAR; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUOROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e MAGNETIC/MOTION SENSORS \u003e GRAVIMETERS \u003e GRAVIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e RECORDERS/LOGGERS \u003e AWS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e XBT; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e ECHO SOUNDERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e MBES; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e THERMOSALINOGRAPHS", "is_usap_dc": true, "keywords": "OCEAN MIXED LAYER; TRACE ELEMENTS; CARBON DIOXIDE; ATMOSPHERIC RADIATION; ICE GROWTH/MELT; AMD; BOUNDARY LAYER TEMPERATURE; SULFUR COMPOUNDS; NBP1704; HEAT FLUX; ICE DEPTH/THICKNESS; R/V NBP; USA/NSF; BOUNDARY LAYER WINDS; SNOW DEPTH; VERTICAL PROFILES; METHANE; POLYNYAS; CONDUCTIVITY; SEA ICE; Ross Sea; WATER MASSES; TURBULENCE; USAP-DC; Amd/Us", "locations": "Ross Sea", "north": -55.0, "nsf_funding_programs": "Antarctic Integrated System Science; Antarctic Instrumentation and Support; Antarctic Integrated System Science; Antarctic Ocean and Atmospheric Sciences; Antarctic Integrated System Science; Antarctic Integrated System Science", "paleo_time": null, "persons": "Ackley, Stephen; Bell, Robin; Weissling, Blake; Nuss, Wendell; Maksym, Edward; Stammerjohn, Sharon; Cassano, John; Guest, Peter; Sedwick, Peter; Xie, Hongjie", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "USAP-DC", "repositories": "BCO-DMO; R2R; USAP-DC", "science_programs": null, "south": -78.0, "title": "Collaborative Research: Seasonal Sea Ice Production in the Ross Sea, Antarctica", "uid": "p0010032", "west": 160.0}, {"awards": "0944659 Kiene, Ronald; 0944686 Kieber, David", "bounds_geometry": "POLYGON((-180 -68,-177 -68,-174 -68,-171 -68,-168 -68,-165 -68,-162 -68,-159 -68,-156 -68,-153 -68,-150 -68,-150 -69,-150 -70,-150 -71,-150 -72,-150 -73,-150 -74,-150 -75,-150 -76,-150 -77,-150 -78,-153 -78,-156 -78,-159 -78,-162 -78,-165 -78,-168 -78,-171 -78,-174 -78,-177 -78,180 -78,178 -78,176 -78,174 -78,172 -78,170 -78,168 -78,166 -78,164 -78,162 -78,160 -78,160 -77,160 -76,160 -75,160 -74,160 -73,160 -72,160 -71,160 -70,160 -69,160 -68,162 -68,164 -68,166 -68,168 -68,170 -68,172 -68,174 -68,176 -68,178 -68,-180 -68))", "dataset_titles": "Ecophysiology of DMSP and related compounds and their contributions to carbon and sulfur dynamics in Phaeocystis antarctica", "datasets": [{"dataset_uid": "600150", "doi": "10.15784/600150", "keywords": "Antarctica; Biota; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Oceans; Ross Sea", "people": "Kiene, Ronald", "repository": "USAP-DC", "science_program": null, "title": "Ecophysiology of DMSP and related compounds and their contributions to carbon and sulfur dynamics in Phaeocystis antarctica", "url": "https://www.usap-dc.org/view/dataset/600150"}, {"dataset_uid": "600117", "doi": "10.15784/600117", "keywords": "Biota; Ross Sea; Southern Ocean", "people": "Kieber, David John", "repository": "USAP-DC", "science_program": null, "title": "Ecophysiology of DMSP and related compounds and their contributions to carbon and sulfur dynamics in Phaeocystis antarctica", "url": "https://www.usap-dc.org/view/dataset/600117"}], "date_created": "Wed, 16 Dec 2015 00:00:00 GMT", "description": "Spectacular blooms of Phaeocystis antarctica in the Ross Sea, Antarctica are the source of some of the world\u0027s highest concentrations of dimethylsulfoniopropionate (DMSP) and its volatile degradation product, dimethylsulfide (DMS). The flux of DMS from the oceans to the atmosphere in this region and its subsequent gas phase oxidation generates aerosols that have a strong influence on cloud properties and possibly climate. In the oceans, DMS and DMSP are quantitatively significant components of the carbon, sulfur, and energy flows in marine food webs, especially in the Ross Sea. Despite its central role in carbon and sulfur biogeochemistry in the Ross Sea, surprisingly little is known about the physiological functions of DMSP in P. Antarctica. The research will isolate and characterize DMSP lyases from P. antarctica, with the goal of obtaining amino acid and gene sequence information on these important enzymes. The physiological studies will focus on the effects of varying intensities of photosynthetically active radiation, with and without ultraviolet radiation as these are factors that we have found to be important controls on DMSP and DMS dynamics. The research also will examine the effects of prolonged darkness on the dynamics of DMSP and related compounds in P. antarctica, as survival of this species during the dark Antarctic winter and at sub-euphotic depths appears to be an important part of the Phaeocystis? ecology. A unique aspect of this work is the focus on measurements of intracellular MSA, which if detected, would provide strong evidence for in vivo radical scavenging functions for methyl sulfur compounds. The study will advance understanding of what controls DMSP cycling and ultimately DMS emissions from the Ross Sea and also provide information on what makes P. antarctica so successful in this extreme environment. The research will directly benefit and build on several interrelated ocean-atmosphere programs including the International Surface Ocean Lower Atmosphere Study (SOLAS) program. The PIs will participate in several activities involving K-12 education, High School teacher training, public education and podcasting through the auspices of the Dauphin Island Sea Lab Discovery Hall program and SUNY ESF. Two graduate students will be employed full time, and six undergraduates (2 each summer) will be trained as part of this project.", "east": -150.0, "geometry": "POINT(-175 -73)", "instruments": null, "is_usap_dc": true, "keywords": "Amd/Us; Not provided; Ecophysiology; AMD; USAP-DC; FIELD SURVEYS", "locations": null, "north": -68.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Kiene, Ronald; Kieber, David John", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -78.0, "title": "Collaborative Research: Ecophysiology of DMSP and related compounds and their contributions to carbon and sulfur dynamics in Phaeocystis antarctica", "uid": "p0000085", "west": 160.0}, {"awards": "0939628 Barletta, Robert", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": null, "datasets": null, "date_created": "Thu, 06 Aug 2015 00:00:00 GMT", "description": "Biogenic sulfur compounds, such as dimethyl sulfide (DMS), its precursors dimethyl sulfoniopropionate (DMSP) and dimethyl sulfoxide (DMSO), and its atmospheric oxidation product, methane sulfonic acid (MSA), are important components of the global sulfur cycle that significantly impact global climate. The roles of DMSP and DMSO within the organisms that produce them, as well as their intracellular concentrations, are poorly understood. DMSO has been speculated to play a role in intracellular osmoregulation, cryoprotection and scavenging of reactive oxygen species, but its intracellular concentration in plankton has only been inferred. Quantitative measurement of the concentration of biogenic sulfur compounds in vivo is necessary to more completely understand their biogeochemistry. The principal investigator has developed methods for the quantitative analysis of biogenic sulfur compounds using Raman spectroscopy, which have resulted in the detection of DMSO with a sensitivity of \u003c10 mM - far lower than the current estimates of its intracellular concentrations. The research will extend this technique to DMSP. The direct determination of the intracellular DMSP and DMSO, will allow the proposed roles of these compounds in phytoplankton to be investigated. Lastly, using field-collected cores, measurements will be made of the intracellular sulfur compounds as well as the concentration of molecular anions in the sea ice micro-environment. As an RUI project, successful completion of this work will have a substantial impact on undergraduate education in the Chemistry Department at the University of South Alabama, exposing undergraduates and, particularly, under-represented minorities in the sciences to cutting-edge research. It will provide financial support for their education and allow them to present research in journal articles and at technical meetings. Contacts with scientists in the field of Antarctic research at other institutions will give students the opportunity to interact with researchers in related fields, broadening their experience base.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -60.0, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Barletta, Robert", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -90.0, "title": "RUI: Analysis of Intracellular Biogenic Sulfur Using micro-Raman Spectroscopy", "uid": "p0000403", "west": -180.0}, {"awards": "0338363 Thiemens, Mark; 0337933 Cole-Dai, Jihong", "bounds_geometry": null, "dataset_titles": "Major Ion Concentrations in 2004 South Pole Ice Core", "datasets": [{"dataset_uid": "609542", "doi": "10.7265/N5HX19N8", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Major Ion Concentrations in 2004 South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609542"}], "date_created": "Fri, 11 Aug 2006 00:00:00 GMT", "description": "This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Not provided; Ion Chromatograph; Ions; LABORATORY; GROUND-BASED OBSERVATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Investigating Atmospheric Chemistry and Dynamics through Oxygen and Sulfur Isotopes in Volcanic Sulfate from South Pole Ice Cores", "uid": "p0000031", "west": null}]
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Project Title/Abstract/Map | NSF Award(s) | Date Created | PIs / Scientists | Dataset Links and Repositories | Abstract | Bounds Geometry | Geometry | Selected | Visible | |||
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Collaborative Research: Seasonal Sea Ice Production in the Ross Sea, Antarctica
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1341717 1341606 1341513 1543483 1341725 |
2019-06-10 | Ackley, Stephen; Bell, Robin; Weissling, Blake; Nuss, Wendell; Maksym, Edward; Stammerjohn, Sharon; Cassano, John; Guest, Peter; Sedwick, Peter; Xie, Hongjie | Proposal Title: Collaborative Research: Seasonal Sea Ice Production in the Ross Sea, Antarctica (working title changed from submitted title) Institutions: UT-San Antonio; Columbia University; Naval Postgraduate School; Woods Hole Oceanographic Institute; UC@Boulder The one place on Earth consistently showing increases in sea ice area, duration, and concentration is the Ross Sea in Antarctica. Satellite imagery shows about half of the Ross Sea increases are associated with changes in the austral fall, when the new sea ice is forming. The most pronounced changes are also located near polynyas, which are areas of open ocean surrounded by sea ice. To understand the processes driving the sea ice increase, and to determine if the increase in sea ice area is also accompanied by a change in ice thickness, this project will conduct an oceanographic cruise to the polynyas of the Ross Sea in April and May, 2017, which is the austral fall. The team will deploy state of the art research tools including unmanned airborne systems (UASs, commonly called drones), autonomous underwater vehicles (AUVs), and remotely operated underwater vehicles (ROVs). Using these tools and others, the team will study atmospheric, oceanic, and sea ice properties and processes concurrently. A change in sea ice production will necessarily change the ocean water below, which may have significant consequences for global ocean circulation patterns, a topic of international importance. All the involved institutions will be training students, and all share the goal of expanding climate literacy in the US, emphasizing the role high latitudes play in the Earth's dynamic climate. The main goal of the project is to improve estimates of sea ice production and water mass transformation in the Ross Sea. The team will fully capture the spatial and temporal changes in air-ice-ocean interactions when they are initiated in the austral fall, and then track the changes into the winter and spring using ice buoys, and airborne mapping with the newly commissioned IcePod instrument system, which is deployed on the US Antarctic Program's LC-130 fleet. The oceanographic cruise will include stations in and outside of both the Terra Nova Bay and Ross Ice Shelf polynyas. Measurements to be made include air-sea boundary layer fluxes of heat, freshwater, and trace gases, radiation, and meteorology in the air; ice formation processes, ice thickness, snow depth, mass balance, and ice drift within the sea ice zone; and temperature, salinity, and momentum in the ocean below. Following collection of the field data, the team will improve both model parameterizations of air-sea-ice interactions and remote sensing algorithms. Model parameterizations are needed to determine if sea-ice production has increased in crucial areas, and if so, why (e.g., stronger winds or fresher oceans). The remote sensing validation will facilitate change detection over wider areas and verify model predictions over time. Accordingly this project will contribute to the international Southern Ocean Observing System (SOOS) goal of measuring essential climate variables continuously to monitor the state of the ocean and ice cover into the future. | POLYGON((-180 -55,-177 -55,-174 -55,-171 -55,-168 -55,-165 -55,-162 -55,-159 -55,-156 -55,-153 -55,-150 -55,-150 -57.3,-150 -59.6,-150 -61.9,-150 -64.2,-150 -66.5,-150 -68.8,-150 -71.1,-150 -73.4,-150 -75.7,-150 -78,-153 -78,-156 -78,-159 -78,-162 -78,-165 -78,-168 -78,-171 -78,-174 -78,-177 -78,180 -78,178 -78,176 -78,174 -78,172 -78,170 -78,168 -78,166 -78,164 -78,162 -78,160 -78,160 -75.7,160 -73.4,160 -71.1,160 -68.8,160 -66.5,160 -64.2,160 -61.9,160 -59.6,160 -57.3,160 -55,162 -55,164 -55,166 -55,168 -55,170 -55,172 -55,174 -55,176 -55,178 -55,-180 -55)) | POINT(-175 -66.5) | false | false | ||||
Collaborative Research: Ecophysiology of DMSP and related compounds and their contributions to carbon and sulfur dynamics in Phaeocystis antarctica
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0944659 0944686 |
2015-12-16 | Kiene, Ronald; Kieber, David John | Spectacular blooms of Phaeocystis antarctica in the Ross Sea, Antarctica are the source of some of the world's highest concentrations of dimethylsulfoniopropionate (DMSP) and its volatile degradation product, dimethylsulfide (DMS). The flux of DMS from the oceans to the atmosphere in this region and its subsequent gas phase oxidation generates aerosols that have a strong influence on cloud properties and possibly climate. In the oceans, DMS and DMSP are quantitatively significant components of the carbon, sulfur, and energy flows in marine food webs, especially in the Ross Sea. Despite its central role in carbon and sulfur biogeochemistry in the Ross Sea, surprisingly little is known about the physiological functions of DMSP in P. Antarctica. The research will isolate and characterize DMSP lyases from P. antarctica, with the goal of obtaining amino acid and gene sequence information on these important enzymes. The physiological studies will focus on the effects of varying intensities of photosynthetically active radiation, with and without ultraviolet radiation as these are factors that we have found to be important controls on DMSP and DMS dynamics. The research also will examine the effects of prolonged darkness on the dynamics of DMSP and related compounds in P. antarctica, as survival of this species during the dark Antarctic winter and at sub-euphotic depths appears to be an important part of the Phaeocystis? ecology. A unique aspect of this work is the focus on measurements of intracellular MSA, which if detected, would provide strong evidence for in vivo radical scavenging functions for methyl sulfur compounds. The study will advance understanding of what controls DMSP cycling and ultimately DMS emissions from the Ross Sea and also provide information on what makes P. antarctica so successful in this extreme environment. The research will directly benefit and build on several interrelated ocean-atmosphere programs including the International Surface Ocean Lower Atmosphere Study (SOLAS) program. The PIs will participate in several activities involving K-12 education, High School teacher training, public education and podcasting through the auspices of the Dauphin Island Sea Lab Discovery Hall program and SUNY ESF. Two graduate students will be employed full time, and six undergraduates (2 each summer) will be trained as part of this project. | POLYGON((-180 -68,-177 -68,-174 -68,-171 -68,-168 -68,-165 -68,-162 -68,-159 -68,-156 -68,-153 -68,-150 -68,-150 -69,-150 -70,-150 -71,-150 -72,-150 -73,-150 -74,-150 -75,-150 -76,-150 -77,-150 -78,-153 -78,-156 -78,-159 -78,-162 -78,-165 -78,-168 -78,-171 -78,-174 -78,-177 -78,180 -78,178 -78,176 -78,174 -78,172 -78,170 -78,168 -78,166 -78,164 -78,162 -78,160 -78,160 -77,160 -76,160 -75,160 -74,160 -73,160 -72,160 -71,160 -70,160 -69,160 -68,162 -68,164 -68,166 -68,168 -68,170 -68,172 -68,174 -68,176 -68,178 -68,-180 -68)) | POINT(-175 -73) | false | false | ||||
RUI: Analysis of Intracellular Biogenic Sulfur Using micro-Raman Spectroscopy
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0939628 |
2015-08-06 | Barletta, Robert | No dataset link provided | Biogenic sulfur compounds, such as dimethyl sulfide (DMS), its precursors dimethyl sulfoniopropionate (DMSP) and dimethyl sulfoxide (DMSO), and its atmospheric oxidation product, methane sulfonic acid (MSA), are important components of the global sulfur cycle that significantly impact global climate. The roles of DMSP and DMSO within the organisms that produce them, as well as their intracellular concentrations, are poorly understood. DMSO has been speculated to play a role in intracellular osmoregulation, cryoprotection and scavenging of reactive oxygen species, but its intracellular concentration in plankton has only been inferred. Quantitative measurement of the concentration of biogenic sulfur compounds in vivo is necessary to more completely understand their biogeochemistry. The principal investigator has developed methods for the quantitative analysis of biogenic sulfur compounds using Raman spectroscopy, which have resulted in the detection of DMSO with a sensitivity of <10 mM - far lower than the current estimates of its intracellular concentrations. The research will extend this technique to DMSP. The direct determination of the intracellular DMSP and DMSO, will allow the proposed roles of these compounds in phytoplankton to be investigated. Lastly, using field-collected cores, measurements will be made of the intracellular sulfur compounds as well as the concentration of molecular anions in the sea ice micro-environment. As an RUI project, successful completion of this work will have a substantial impact on undergraduate education in the Chemistry Department at the University of South Alabama, exposing undergraduates and, particularly, under-represented minorities in the sciences to cutting-edge research. It will provide financial support for their education and allow them to present research in journal articles and at technical meetings. Contacts with scientists in the field of Antarctic research at other institutions will give students the opportunity to interact with researchers in related fields, broadening their experience base. | POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60)) | POINT(0 -89.999) | false | false | |||
Collaborative Research: Investigating Atmospheric Chemistry and Dynamics through Oxygen and Sulfur Isotopes in Volcanic Sulfate from South Pole Ice Cores
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0338363 0337933 |
2006-08-11 | Cole-Dai, Jihong |
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This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US. | None | None | false | false |