USAP-DC

{"dp_type": "Project", "free_text": "Photochemistry"}

[{"awards": "0636929 Bales, Roger", "bounds_geometry": null, "dataset_titles": "Measurements of Air and Snow Photochemical Species at WAIS Divide, Antarctica", "datasets": [{"dataset_uid": "609585", "doi": "10.7265/N5GX48HW", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "Bales, Roger", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Measurements of Air and Snow Photochemical Species at WAIS Divide, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609585"}], "date_created": "Thu, 14 Jul 2011 00:00:00 GMT", "description": "This award supports a project to understand how recent changes in atmospheric chemistry, and historical changes as recorded in snow, firn and ice, have affected atmospheric photochemistry over Antarctica. Atmospheric, snow and firn core measurements of selected gas, meteorological and snow physical properties will be made and modeling of snow-atmosphere exchange will be carried out. The intellectual merit of the project is that it will lead to a better an understanding of the atmospheric chemistry in West Antarctica, its bi-directional linkages with the snowpack, and how it responds to regional influences. There are at least four broader impacts of this work. First is education of university students at both the graduate and undergraduate levels. One postdoctoral researcher and one graduate student will carry out much of the work, and a number of undergraduates will be involved. Second, involvement with the WAIS-Divide coring program will be used to help recruit under-represented groups as UC Merced students. As part of UC Merced\u0027s outreach efforts in the San Joaquin Valley, whose students are under-represented in the UC system, the PI and co-PI give short research talks to groups of prospective students, community college and high school educators and other groups. They will develop one such talk highlighting this project. Including high-profile research in these recruiting talks has proven to be an effective way to promote dialog, and interest students in UC Merced. Third, talks such as this also contribute to the scientific literacy of the general public. The PI and grad student will all seek opportunities to share project information with K-14 and community audiences. Fourth, results of the research will be disseminated broadly to the scientific community, and the researchers will seek additional applications for the transfer functions as tools to improve interpretation of ice-cores. This research is highly collaborative, and leverages the expertise and data from a number of other groups.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e CHEMILUMINESCENCE", "is_usap_dc": true, "keywords": "Snow; Atmospheric Chemistry; Not provided; LABORATORY; Antarctica; FIELD SURVEYS; Snow Physical Properties; Meteorology; Wais Divide-project; Firn; Atmosphere Exchange; WAIS Divide; FIELD INVESTIGATION", "locations": "Antarctica; WAIS Divide", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Bales, Roger", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Atmospheric, Snow and Firn Chemistry Studies for Interpretation of WAIS-Divide Cores", "uid": "p0000041", "west": null}, {"awards": "9527255 Mopper, Kenneth", "bounds_geometry": null, "dataset_titles": "Expedition data of LMG9809", "datasets": [{"dataset_uid": "002719", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of LMG9809", "url": "https://www.rvdata.us/search/cruise/LMG9809"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "ACT K. Mopper \u0026 D. Kieber OPP 9527255 \u0026 OPP 9527314 PHOTOCHEMICAL AND OPTICAL PROPERTIES OF ANTARCTIC WATERS IN RESPONSE TO CHANGING UV-B FLUXES The decrease in stratospheric ozone over the Antarctic results in an increase in the UV-B flux in the euphotic zone. The increase leads to cellular damage to aquatic organisms, as documented by photo-inhibition and decreased productivity. Cellular damage can occur either intracellularly, or externally at the cell surface from biomolecular reactions with externally-generated reactive transients. The extent of this extracellular damage will depend on the photochemistry of the seawater surrounding the cell. Until recently, nothing was known about the type of photochemical processes, rates, and steady state concentrations of transients in Antarctic waters. It is proposed that field experiments be performed which will allow the construction of predictive models of photochemical production rates in surface waters and with depth. These studies will involve further quantum yield measurementts, development of a sensitive underwater actinometer system, and use of a new underwater multichannel photometer. The model will allow the prediction of the impact of varying levels of UV-B on the photoproduction and steady state concentration of several key reactive transient species in the upper water column. In addition to this effort, experiments will also be performed to study the photodegradation of dissolved organic matter and to determine whether biologically utilizable substrates that are formed photochemically can enhance secondary productivity in Antarctic waters.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": false, "keywords": "R/V LMG", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Mopper, Kenneth", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V LMG", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "Collaborative Research: Photochemical and Optical Properties of Antarctic Waters in Response to Changing UV-B Fluxes", "uid": "p0000870", "west": null}, {"awards": "9221598 Mopper, Kenneth", "bounds_geometry": null, "dataset_titles": "Expedition Data", "datasets": [{"dataset_uid": "002282", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP9306"}], "date_created": "Fri, 19 Jun 2009 00:00:00 GMT", "description": "Decreases in stratospheric ozone over the Antarctic result in an increase in the ultraviolet radiation flux in the euphotic zone of the ocean. This increase may lead to cellular damage in aquatic organisms resulting in photo-inhibition and decreased productivity. Cellular damage can occur either intracellularly, or externally at the cell surface from biomolecular reactions with externally-generated reactive transient species. Extracellular damage will depend to a large degree on the photochemistry of the seawater surrounding the cell. To date, little is known about the photochemistry of the unique Antarctic waters. This project integrates a field and laboratory approach to obtain baseline information regarding the marine photochemistry of the euphotic zone in Antarctica waters as related to changes in ultraviolet radiation levels. In situ photochemical production rates and steady state concentrations of a suite of reactive species and dissolved organic matter degradation products as well as downwelling ultraviolet radiation will be measured. Additionally, flux by in situ chemical actinometry, action spectra for photochemical production of various reactive species and dissolved organic matter degradation products, and fluorescence and absorbance properties of dissolved organic matter will be determined. This information will serve as a basis for understanding and predicting the effects of ultraviolet radiation-induced marine photochemical processes on the productivity and ecology in the euphotic zone of the Antarctic Ocean.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS", "is_usap_dc": false, "keywords": "R/V NBP", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Mopper, Kenneth; Neale, Patrick", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "Photochemistry of Antarctic Waters in Repsonse to Changing Ultraviolet Radiation Fluxes", "uid": "p0000649", "west": null}, {"awards": "9814810 Bales, Roger", "bounds_geometry": "POLYGON((-124 -76,-120 -76,-116 -76,-112 -76,-108 -76,-104 -76,-100 -76,-96 -76,-92 -76,-88 -76,-84 -76,-84 -77.4,-84 -78.8,-84 -80.2,-84 -81.6,-84 -83,-84 -84.4,-84 -85.8,-84 -87.2,-84 -88.6,-84 -90,-88 -90,-92 -90,-96 -90,-100 -90,-104 -90,-108 -90,-112 -90,-116 -90,-120 -90,-124 -90,-124 -88.6,-124 -87.2,-124 -85.8,-124 -84.4,-124 -83,-124 -81.6,-124 -80.2,-124 -78.8,-124 -77.4,-124 -76))", "dataset_titles": "Atmospheric Mixing Ratios of Hydroperoxides above the West Antarctic Ice Sheet; Twenty-Three Century-scale Ice Core Records of Hydrogen Peroxide (H2O2) from West Antarctica", "datasets": [{"dataset_uid": "609394", "doi": "10.7265/N5PZ56RS", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; ITASE; WAIS", "people": "Bales, Roger; Frey, Markus; McConnell, Joseph", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric Mixing Ratios of Hydroperoxides above the West Antarctic Ice Sheet", "url": "https://www.usap-dc.org/view/dataset/609394"}, {"dataset_uid": "609392", "doi": "10.7265/N5TM7826", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS", "people": "McConnell, Joseph; Bales, Roger; Frey, Markus", "repository": "USAP-DC", "science_program": null, "title": "Twenty-Three Century-scale Ice Core Records of Hydrogen Peroxide (H2O2) from West Antarctica", "url": "https://www.usap-dc.org/view/dataset/609392"}], "date_created": "Mon, 01 Jun 2009 00:00:00 GMT", "description": "This award supports a project to improve understanding of atmospheric photochemistry over West Antarctica, as recorded in snow, firn and ice. Atmospheric and firn sampling will be undertaken as part of the U.S. International Trans-Antarctic Scientific Expedition (US ITASE) traverses. Measurements of hydrogen peroxide (H2O2) and formaldehyde (HCHO) will be made on these samples and a recently developed, physically based atmosphere-to-snow transfer model will be used to relate photochemical model estimates of these components to the concentrations of these parameters in the atmosphere and snow. The efficiency of atmosphere-to-snow transfer and the preservation of these components is strongly related to the rate and timing of snow accumulation. This information will be obtained by analyzing the concentration of seasonally dependent species such as hydrogen peroxide, nitric acid and stable isotopes of oxygen. Collection of samples along the US ITASE traverses will allow sampling at a wide variety of locations, reflecting both a number of different depositional environments and covering much of the West Antarctic region.", "east": -84.0, "geometry": "POINT(-104 -83)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUORESCENCE SPECTROSCOPY; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS SENSORS", "is_usap_dc": true, "keywords": "Ice Core; Ice Core Chemistry; FIELD INVESTIGATION; FIELD SURVEYS; Antarctica; West Antarctica; Antarctic; LABORATORY; Ice Core Gas Records; Not provided; Ice Core Data; Polar Firn Air; Hydrogen Peroxide; West Antarctic Ice Sheet; Shallow Firn Air; US ITASE; Antarctic Ice Sheet; Snow Chemistry", "locations": "Antarctica; West Antarctica; Antarctic; Antarctic Ice Sheet; West Antarctic Ice Sheet", "north": -76.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Bales, Roger; Frey, Markus; McConnell, Joseph", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Hydrogen Peroxide, Formaldehyde, and Sub-Annual Snow Accumulation in West Antarctica: Participation in West Antarctic Traverse", "uid": "p0000253", "west": -124.0}, {"awards": "0230288 Anastasio, Cort", "bounds_geometry": "POLYGON((123.30014 -75.093445,123.307404 -75.093445,123.314668 -75.093445,123.321932 -75.093445,123.329196 -75.093445,123.33646 -75.093445,123.343724 -75.093445,123.350988 -75.093445,123.358252 -75.093445,123.365516 -75.093445,123.37278 -75.093445,123.37278 -75.0952669,123.37278 -75.0970888,123.37278 -75.0989107,123.37278 -75.1007326,123.37278 -75.1025545,123.37278 -75.1043764,123.37278 -75.1061983,123.37278 -75.1080202,123.37278 -75.1098421,123.37278 -75.111664,123.365516 -75.111664,123.358252 -75.111664,123.350988 -75.111664,123.343724 -75.111664,123.33646 -75.111664,123.329196 -75.111664,123.321932 -75.111664,123.314668 -75.111664,123.307404 -75.111664,123.30014 -75.111664,123.30014 -75.1098421,123.30014 -75.1080202,123.30014 -75.1061983,123.30014 -75.1043764,123.30014 -75.1025545,123.30014 -75.1007326,123.30014 -75.0989107,123.30014 -75.0970888,123.30014 -75.0952669,123.30014 -75.093445))", "dataset_titles": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "datasets": [{"dataset_uid": "609519", "doi": "10.7265/N5MS3QP0", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Dome C Ice Core; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Physical Properties; Snow/ice; Snow/Ice", "people": "Anastasio, Cort; Robles, Tony", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609519"}], "date_created": "Wed, 07 Mar 2007 00:00:00 GMT", "description": "Photochemical reactions in snow can have important effects on the chemistry and composition of the snowpack as well as the overlying atmosphere. For example, recent measurements in the Antarctic and Arctic have revealed that sunlit snow releases a number of important pollutants to the atmosphere. Our ability to understand and model this chemistry is currently limited, in part because we lack fundamental photochemical information for a number of important chemical species in snow. This award supports research that will help fill this gap by characterizing the low-temperature photochemistry of three of these key species: nitrite (NO2-), nitrous acid (HNO2), and hydrogen peroxide (HOOH). We will measure quantum yields for these reactions on ice using a sensitive technique that we recently developed during a study of nitrate (NO3-) photochemistry. In addition to this basic research, we will also measure the rates of formation of hydroxyl radical (OH), nitrogen oxides (NOx), and HOOH in illuminated Antarctic snow samples. These measurements will be important inputs for future models, and will allow us to test whether known species (e.g., NO3-, NO2- and HNO2) are responsible for most of snowpack reactivity (e.g., OH formation). Overall, results from this award will significantly improve our ability to understand snowpack chemistry, and the resulting effects on the atmosphere, both in the Antarctic as well as in the many other regions with permanent or seasonal snow. These results will also strengthen efforts to use ice core records to monitor global change. In addition to these impacts, this award will help train students and a postdoctoral fellow, and results from this work will be integrated into two classes in order to expose students to some of the important issues facing polar regions.", "east": 123.37278, "geometry": "POINT(123.33646 -75.1025545)", "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PHOTOMETERS \u003e SPECTROPHOTOMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e HPLC; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Snow Chemistry; Antarctica; Snowpack Chemistry; Snow Samples; Hydrogen Peroxide; Snow Properties; Pollutants; Chemistry; Light Absorption; Antarctic; Chemical Species; Snow; East Antarctica; Organic Compounds; Photochemistry; LABORATORY", "locations": "Antarctica; East Antarctica; Antarctic", "north": -75.093445, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Anastasio, Cort; Robles, Tony", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Dome C Ice Core", "south": -75.111664, "title": "Laboratory Studies of Photochemistry in Antarctic Snow and Ice", "uid": "p0000175", "west": 123.30014}]

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