USAP-DC

{"dp_type": "Project", "free_text": "Organic Compounds"}

[{"awards": "1443474 Jenkins, Bethany", "bounds_geometry": null, "dataset_titles": "Expedition data of NBP1608", "datasets": [{"dataset_uid": "002664", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of NBP1608", "url": "https://www.rvdata.us/search/cruise/NBP1608"}], "date_created": "Fri, 29 Dec 2017 00:00:00 GMT", "description": "This project focuses on an important group of photosynthetic algae in the Southern Ocean (SO), diatoms, and the roles associated bacterial communities play in modulating their growth. Diatom growth fuels the SO food web and balances atmospheric carbon dioxide by sequestering the carbon used for growth to the deep ocean on long time scales as cells sink below the surface. The diatom growth is limited by the available iron in the seawater, most of which is not freely available to the diatoms but instead is tightly bound to other compounds. The nature of these compounds and how phytoplankton acquire iron from them is critical to understanding productivity in this region and globally. The investigators will conduct experiments to characterize the relationship between diatoms, their associated bacteria, and iron in open ocean and inshore waters. Experiments will involve supplying nutrients at varying nutrient ratios to natural phytoplankton assemblages to determine how diatoms and their associated bacteria respond to different conditions. This will provide valuable data that can be used by climate and food web modelers and it will help us better understand the relationship between iron, a key nutrient in the ocean, and the organisms at the base of the food web that use iron for photosynthetic growth and carbon uptake. The project will also further the NSF goals of training new generations of scientists and of making scientific discoveries available to the general public. The project supports early career senior investigators and the training of graduate and undergraduate students as well as outreach activities with middle school Girl Scouts in Rhode Island, inner city middle and high school age girls in Virginia, and middle school girls in Florida.\u003cbr/\u003e\u003cbr/\u003eThe project combines trace metal biogeochemistry, phytoplankton cultivation, and molecular biology to address questions regarding the production of iron-binding compounds and the role of diatom-bacterial interactions in this iron-limited region. Iron is an essential micronutrient for marine phytoplankton. Phytoplankton growth in the SO is limited by a lack of sufficient iron, with important consequences for carbon cycling and climate in this high latitude regime. Some of the major outstanding questions in iron biogeochemistry relate to the organic compounds that bind \u003e99.9% of dissolved iron in surface oceans. The investigators\u0027 prior research in this region suggests that production of strong iron-binding compounds in the SO is linked to diatom blooms in waters with high nitrate to iron ratios. The sources of these compounds are unknown but the investigators hypothesize that they may be from bacteria, which are known to produce such compounds for their own use. The project will test three hypotheses concerning the production of these iron-binding compounds, limitations on the biological availability of iron even if present in high concentrations, and the roles of diatom-associated bacteria in these processes. Results from this project will provide fundamental information about the biogeochemical trigger, and biological sources and function, of natural strong iron-binding compound production in the SO, where iron plays a critical role in phytoplankton productivity, carbon cycling, and climate regulation.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e CTD; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUOROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e MAGNETIC/MOTION SENSORS \u003e GRAVIMETERS \u003e GRAVIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e RECORDERS/LOGGERS \u003e AWS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS; EARTH REMOTE SENSING INSTRUMENTS \u003e ACTIVE REMOTE SENSING \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e ECHO SOUNDERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e MBES; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e THERMOSALINOGRAPHS", "is_usap_dc": false, "keywords": "R/V NBP; NBP1608", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Jenkins, Bethany", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "Collaborative Research: Investigating Iron-inding Ligands in Southern Ocean Diatom Communities: The Role of Diatom-Bacteria Associations", "uid": "p0000852", "west": null}, {"awards": "0838970 Foreman, Christine", "bounds_geometry": "POINT(161.667 -77.117)", "dataset_titles": "The Biogeochemical Evolution of Dissolved Organic Matter in a Fluvial System on the Cotton Glacier, Antarctica", "datasets": [{"dataset_uid": "600104", "doi": "10.15784/600104", "keywords": "Antarctica; Biota; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Microbiology", "people": "Foreman, Christine", "repository": "USAP-DC", "science_program": null, "title": "The Biogeochemical Evolution of Dissolved Organic Matter in a Fluvial System on the Cotton Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/600104"}], "date_created": "Fri, 10 Oct 2014 00:00:00 GMT", "description": "Dissolved organic matter (DOM) comprises a significant pool of Earth\u0027s organic carbon that dwarfs the amount present in living aquatic organisms. The properties and reactivity of DOM are not well defined, and the evolution of autochthonous DOM from its precursor materials in freshwater has not been observed. Recent sampling of a supraglacial stream formed on the Cotton Glacier in the Transantarctic Mountains revealed DOM that more closely resembles an assemblage of recognizable precursor organic compounds, based upon its UV-VIS and fluorescence spectra. It is suggested that the DOM from this water evolved over time to resemble materials present in marine and many inland surface waters. The transient nature of the system i.e., it reforms seasonally, also prevents any accumulation of the refractory DOM present in most surface waters. Thus, the Cotton Glacier provides us with a unique environment to study the formation of DOM from precursor materials. An interdisciplinary team will study the biogeochemistry of this progenitor DOM and how microbes modify it. By focusing on the chemical composition of the DOM as it shifts from precursor material to the more humified fractions, the investigators will relate this transition to bioavailability, enzymatic activity, community composition and microbial growth efficiency. This project will support education at all levels, K-12, high school, undergraduate, graduate and post-doc and will increase participation by under-represented groups in science. Towards these goals, the investigators have established relationships with girls\u0027 schools and Native American programs. Additional outreach will be carried out in coordination with PolarTREC, PolarPalooza, and if possible, an Antarctic Artist and Writer.", "east": 161.667, "geometry": "POINT(161.667 -77.117)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -77.117, "nsf_funding_programs": "Antarctic Organisms and Ecosystems", "paleo_time": null, "persons": "Foreman, Christine", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.117, "title": "Collaborative Research: The Biogeochemical Evolution of Dissolved Organic Matter in a Fluvial System on the Cotton Glacier, Antarctica", "uid": "p0000458", "west": 161.667}, {"awards": "0338101 Padman, Laurence", "bounds_geometry": null, "dataset_titles": "Expedition data of NBP0603", "datasets": [{"dataset_uid": "002615", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of NBP0603", "url": "https://www.rvdata.us/search/cruise/NBP0603"}, {"dataset_uid": "002614", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of NBP0603", "url": "https://www.rvdata.us/search/cruise/NBP0603"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "The Larsen Ice Shelf is the third largest ice shelf in Antarctica and has continued a pattern of catastrophic decay since the mid 1990\u0027s. The proposed marine geologic work at the Larsen Ice Shelf builds upon our previous NSF-OPP funding and intends to test the working hypothesis that the Larsen B Ice Shelf system has been a stable component of Antarctica\u0027s glacial system since it formed during rising sea levels 10,000 years BP. This conclusion, if supported by observations from our proposed work, is an important first step in establishing the uniqueness and consequences of rapid regional warming currently taking place across the Peninsula. Our previous work in the Larsen A and B embayments has allowed us to recognize the signature of past ice shelf fluctuations and their impact on the oceanographic and biologic environments. We have also overcome many of the limitations of standard radiocarbon dating in Antarctic marine sequences by using variations in the strength of the earth\u0027s magnetic field for correlation of sediment records and by using specific organic compounds (instead of bulk sediment) for radiocarbon dating. We intend to pursue these analytical advances and extend our sediment core stratigraphy to areas uncovered by the most recent collapse of the Larsen B Ice Shelf and areas immediately adjacent to the Larsen C Ice Shelf. In addition to the core recovery program, we intend to utilize our unique access to the ice shelf front to continue our observations of the snow/ice stratigraphy, oceanographic character, and ocean floor character. Sediment traps will also be deployed in order to measure the input of debris from glaciers that are now surging in response to the ice shelf collapse. This proposal is a multi-institutional, international (USAP, Italy, and Canada) effort that combines the established expertise in a variety of disciplines and integrates the research plan into the educational efforts of primarily undergraduate institutions but including some graduate education. This is a three-year project with field seasons planned with flexibility in order to accommodate schedules for the RVIB L.M. Gould. The Antarctic Peninsula is undergoing greater warming than almost anywhere on Earth, perhaps associated with human-induced greenhouse effects. Our proposed work contributes to understanding of these changes where they are occurring first and with greatest magnitude and impact upon the environment.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e CAMERAS \u003e CAMERAS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e CTD; IN SITU/LABORATORY INSTRUMENTS \u003e MAGNETIC/MOTION SENSORS \u003e GRAVIMETERS \u003e GRAVIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e PRESSURE/HEIGHT METERS \u003e PRESSURE SENSORS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e SEDIMENT CORERS; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e TURBIDITY METERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e ADCP; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e MSBS", "is_usap_dc": false, "keywords": "R/V NBP", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Padman, Laurence; Domack, Eugene Walter", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "Collaborative Research: Paleohistory of the Larsen Ice Shelf: Phase II", "uid": "p0000827", "west": null}, {"awards": "0338109 Brachfeld, Stefanie", "bounds_geometry": null, "dataset_titles": "Expedition data of NBP0603", "datasets": [{"dataset_uid": "002614", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of NBP0603", "url": "https://www.rvdata.us/search/cruise/NBP0603"}], "date_created": "Tue, 04 May 2010 00:00:00 GMT", "description": "The Larsen Ice Shelf is the third largest ice shelf in Antarctica and has continued a pattern of catastrophic decay since the mid 1990\u0027s. The proposed marine geologic work at the Larsen Ice Shelf builds upon our previous NSF-OPP funding and intends to test the working hypothesis that the Larsen B Ice Shelf system has been a stable component of Antarctica\u0027s glacial system since it formed during rising sea levels 10,000 years BP. This conclusion, if supported by observations from our proposed work, is an important first step in establishing the uniqueness and consequences of rapid regional warming currently taking place across the Peninsula. Our previous work in the Larsen A and B embayments has allowed us to recognize the signature of past ice shelf fluctuations and their impact on the oceanographic and biologic environments. We have also overcome many of the limitations of standard radiocarbon dating in Antarctic marine sequences by using variations in the strength of the earth\u0027s magnetic field for correlation of sediment records and by using specific organic compounds (instead of bulk sediment) for radiocarbon dating. We intend to pursue these analytical advances and extend our sediment core stratigraphy to areas uncovered by the most recent collapse of the Larsen B Ice Shelf and areas immediately adjacent to the Larsen C Ice Shelf. In addition to the core recovery program, we intend to utilize our unique access to the ice shelf front to continue our observations of the snow/ice stratigraphy, oceanographic character, and ocean floor character. Sediment traps will also be deployed in order to measure the input of debris from glaciers that are now surging in response to the ice shelf collapse. This proposal is a multi-institutional, international (USAP, Italy, and Canada) effort that combines the established expertise in a variety of disciplines and integrates the research plan into the educational efforts of primarily undergraduate institutions but including some graduate education. This is a three-year project with field seasons planned with flexibility in order to accommodate schedules for the RVIB L.M. Gould. The Antarctic Peninsula is undergoing greater warming than almost anywhere on Earth, perhaps associated with human-induced greenhouse effects. Our proposed work contributes to understanding of these changes where they are occurring first and with greatest magnitude and impact upon the environment.", "east": null, "geometry": null, "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e CAMERAS \u003e CAMERAS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e CTD; IN SITU/LABORATORY INSTRUMENTS \u003e MAGNETIC/MOTION SENSORS \u003e GRAVIMETERS \u003e GRAVIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e PRESSURE/HEIGHT METERS \u003e PRESSURE SENSORS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e SEDIMENT CORERS; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e TURBIDITY METERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e ADCP; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e MSBS", "is_usap_dc": false, "keywords": "R/V NBP", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Brachfeld, Stefanie; Domack, Eugene Walter", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R", "science_programs": null, "south": null, "title": "Collaborative Research: Paleohistory of the Larsen Ice Shelf: Phase II", "uid": "p0000826", "west": null}, {"awards": "0338163 Leventer, Amy; 0338220 Ishman, Scott; 0338142 Domack, Eugene", "bounds_geometry": "POLYGON((-63 -62,-62.3 -62,-61.6 -62,-60.9 -62,-60.2 -62,-59.5 -62,-58.8 -62,-58.1 -62,-57.4 -62,-56.7 -62,-56 -62,-56 -62.5,-56 -63,-56 -63.5,-56 -64,-56 -64.5,-56 -65,-56 -65.5,-56 -66,-56 -66.5,-56 -67,-56.7 -67,-57.4 -67,-58.1 -67,-58.8 -67,-59.5 -67,-60.2 -67,-60.9 -67,-61.6 -67,-62.3 -67,-63 -67,-63 -66.5,-63 -66,-63 -65.5,-63 -65,-63 -64.5,-63 -64,-63 -63.5,-63 -63,-63 -62.5,-63 -62))", "dataset_titles": "Expedition Data; Expedition data of LMG0404; NBP0603 - Expedition Data; NBP0603 - Paleohistory of the Larsen Ice Shelf System", "datasets": [{"dataset_uid": "001610", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition Data", "url": "https://www.rvdata.us/search/cruise/LMG0502"}, {"dataset_uid": "600027", "doi": "10.15784/600027", "keywords": "ADCP Acoustic Doppler Current Profiler; Antarctic Peninsula; Biota; Diatom; Electromagnetic Data; Flask Glacier; Foehn Winds; Larsen Ice Shelf; Marine Sediments; NBP0603; Oceans; Physical Ice Properties; R/v Nathaniel B. Palmer; Scar Inlet; Southern Ocean", "people": "Domack, Eugene Walter", "repository": "USAP-DC", "science_program": null, "title": "NBP0603 - Paleohistory of the Larsen Ice Shelf System", "url": "https://www.usap-dc.org/view/dataset/600027"}, {"dataset_uid": "000236", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "NBP0603 - Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP0603"}, {"dataset_uid": "002710", "doi": null, "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "Expedition data of LMG0404", "url": "https://www.rvdata.us/search/cruise/LMG0404"}], "date_created": "Wed, 11 Jun 2008 00:00:00 GMT", "description": "The Larsen Ice Shelf is the third largest ice shelf in Antarctica and has continued a pattern of catastrophic decay since the mid 1990\u0027s. The proposed marine geologic work at the Larsen Ice Shelf builds upon our previous NSF-OPP funding and intends to test the working hypothesis that the Larsen B Ice Shelf system has been a stable component of Antarctica\u0027s glacial system since it formed during rising sea levels 10,000 years BP. This conclusion, if supported by observations from our proposed work, is an important first step in establishing the uniqueness and consequences of rapid regional warming currently taking place across the Peninsula. Our previous work in the Larsen A and B embayments has allowed us to recognize the signature of past ice shelf fluctuations and their impact on the oceanographic and biologic environments. We have also overcome many of the limitations of standard radiocarbon dating in Antarctic marine sequences by using variations in the strength of the earth\u0027s magnetic field for correlation of sediment records and by using specific organic compounds (instead of bulk sediment) for radiocarbon dating. We intend to pursue these analytical advances and extend our sediment core stratigraphy to areas uncovered by the most recent collapse of the Larsen B Ice Shelf and areas immediately adjacent to the Larsen C Ice Shelf. In addition to the core recovery program, we intend to utilize our unique access to the ice shelf front to continue our observations of the snow/ice stratigraphy, oceanographic character, and ocean floor character. Sediment traps will also be deployed in order to measure the input of debris from glaciers that are now surging in response to the ice shelf collapse. This proposal is a multi-institutional, international (USAP, Italy, and Canada) effort that combines the established expertise in a variety of disciplines and integrates the research plan into the educational efforts of primarily undergraduate institutions but including some graduate education. This is a three-year project with field seasons planned with flexibility in order to accommodate schedules for the RVIB L.M. Gould. The Antarctic Peninsula is undergoing greater warming than almost anywhere on Earth, perhaps associated with human-induced greenhouse effects. Our proposed work contributes to understanding of these changes where they are occurring first and with greatest magnitude and impact upon the environment.", "east": -56.0, "geometry": "POINT(-59.5 -64.5)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e CTD; IN SITU/LABORATORY INSTRUMENTS \u003e PRESSURE/HEIGHT METERS \u003e PRESSURE SENSORS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e POSITIONING/NAVIGATION \u003e GPS \u003e GPS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e ADCP; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e CAMERAS \u003e CAMERAS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e CTD; IN SITU/LABORATORY INSTRUMENTS \u003e MAGNETIC/MOTION SENSORS \u003e GRAVIMETERS \u003e GRAVIMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e PRESSURE/HEIGHT METERS \u003e PRESSURE SENSORS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e SEDIMENT CORERS; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e TURBIDITY METERS; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e ADCP; IN SITU/LABORATORY INSTRUMENTS \u003e PROFILERS/SOUNDERS \u003e ACOUSTIC SOUNDERS \u003e MSBS", "is_usap_dc": true, "keywords": "R/V LMG; R/V NBP; Not provided", "locations": null, "north": -62.0, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences; Antarctic Earth Sciences", "paleo_time": null, "persons": "Ishman, Scott; Leventer, Amy; Domack, Eugene Walter", "platforms": "Not provided; WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V LMG; WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "R2R", "repositories": "R2R; USAP-DC", "science_programs": null, "south": -67.0, "title": "Collaborative Research: Paleohistory of the Larsen Ice Shelf System: Phase II", "uid": "p0000215", "west": -63.0}, {"awards": "0230288 Anastasio, Cort", "bounds_geometry": "POLYGON((123.30014 -75.093445,123.307404 -75.093445,123.314668 -75.093445,123.321932 -75.093445,123.329196 -75.093445,123.33646 -75.093445,123.343724 -75.093445,123.350988 -75.093445,123.358252 -75.093445,123.365516 -75.093445,123.37278 -75.093445,123.37278 -75.0952669,123.37278 -75.0970888,123.37278 -75.0989107,123.37278 -75.1007326,123.37278 -75.1025545,123.37278 -75.1043764,123.37278 -75.1061983,123.37278 -75.1080202,123.37278 -75.1098421,123.37278 -75.111664,123.365516 -75.111664,123.358252 -75.111664,123.350988 -75.111664,123.343724 -75.111664,123.33646 -75.111664,123.329196 -75.111664,123.321932 -75.111664,123.314668 -75.111664,123.307404 -75.111664,123.30014 -75.111664,123.30014 -75.1098421,123.30014 -75.1080202,123.30014 -75.1061983,123.30014 -75.1043764,123.30014 -75.1025545,123.30014 -75.1007326,123.30014 -75.0989107,123.30014 -75.0970888,123.30014 -75.0952669,123.30014 -75.093445))", "dataset_titles": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "datasets": [{"dataset_uid": "609519", "doi": "10.7265/N5MS3QP0", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Dome C Ice Core; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Physical Properties; Snow/ice; Snow/Ice", "people": "Anastasio, Cort; Robles, Tony", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609519"}], "date_created": "Wed, 07 Mar 2007 00:00:00 GMT", "description": "Photochemical reactions in snow can have important effects on the chemistry and composition of the snowpack as well as the overlying atmosphere. For example, recent measurements in the Antarctic and Arctic have revealed that sunlit snow releases a number of important pollutants to the atmosphere. Our ability to understand and model this chemistry is currently limited, in part because we lack fundamental photochemical information for a number of important chemical species in snow. This award supports research that will help fill this gap by characterizing the low-temperature photochemistry of three of these key species: nitrite (NO2-), nitrous acid (HNO2), and hydrogen peroxide (HOOH). We will measure quantum yields for these reactions on ice using a sensitive technique that we recently developed during a study of nitrate (NO3-) photochemistry. In addition to this basic research, we will also measure the rates of formation of hydroxyl radical (OH), nitrogen oxides (NOx), and HOOH in illuminated Antarctic snow samples. These measurements will be important inputs for future models, and will allow us to test whether known species (e.g., NO3-, NO2- and HNO2) are responsible for most of snowpack reactivity (e.g., OH formation). Overall, results from this award will significantly improve our ability to understand snowpack chemistry, and the resulting effects on the atmosphere, both in the Antarctic as well as in the many other regions with permanent or seasonal snow. These results will also strengthen efforts to use ice core records to monitor global change. In addition to these impacts, this award will help train students and a postdoctoral fellow, and results from this work will be integrated into two classes in order to expose students to some of the important issues facing polar regions.", "east": 123.37278, "geometry": "POINT(123.33646 -75.1025545)", "instruments": "EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PHOTOMETERS \u003e SPECTROPHOTOMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e HPLC; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Snow Chemistry; Antarctica; Snowpack Chemistry; Snow Samples; Hydrogen Peroxide; Snow Properties; Pollutants; Chemistry; Light Absorption; Antarctic; Chemical Species; Snow; East Antarctica; Organic Compounds; Photochemistry; LABORATORY", "locations": "Antarctica; East Antarctica; Antarctic", "north": -75.093445, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Anastasio, Cort; Robles, Tony", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Dome C Ice Core", "south": -75.111664, "title": "Laboratory Studies of Photochemistry in Antarctic Snow and Ice", "uid": "p0000175", "west": 123.30014}]

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