{"dp_type": "Project", "free_text": "Nitrate Isotopes"}
[{"awards": "1542723 Alexander, Becky", "bounds_geometry": "POINT(-112.05 -79.28)", "dataset_titles": "WAIS Divide ice core nitrate isotopes", "datasets": [{"dataset_uid": "601456", "doi": "10.15784/601456", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Chemistry; Ice Core Records; Nitrate; Nitrate Isotopes; WAIS Divide Ice Core; West Antarctic Ice Sheet", "people": "Alexander, Becky", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide ice core nitrate isotopes", "url": "https://www.usap-dc.org/view/dataset/601456"}], "date_created": "Mon, 13 Feb 2023 00:00:00 GMT", "description": "The Earth\u0027s atmosphere is a highly oxidizing medium. The abundance of oxidants such as ozone in the atmosphere strongly influences the concentrations of pollutants and greenhouse gases, with implications for human health and welfare. Because oxidants are not preserved in geological archives, knowledge of how oxidants have varied in the past under changing climate conditions is extremely limited. This award will measure a proxy for oxidant concentrations in a West Antarctic ice core over several major climate transitions over the past 50,000 years. These measurements will complement similar measurements from a Greenland ice core, which showed significant changes in atmospheric oxidants over major climate transitions covering this same time period. The addition of measurements from Antarctica will allow researchers to examine if the oxidant changes suggested by the Greenland ice core record are regional or global in scale. Knowledge of how oxidants vary naturally with climate will better inform predictions of the composition of the future atmosphere under a warming climate.\u003cbr/\u003e\u003cbr/\u003eThis award will support measurements of the isotopic composition of nitrate in a West Antarctic ice core as a proxy for oxidant concentrations in the past atmosphere. The nitrogen isotopes of nitrate provide information on the degree of preservation of nitrate in the ice core record, and thus aid in the interpretation of the observed variability in the observed nitrate concentrations and oxygen isotopes in ice core records. By providing information about the spatial scale of oxidant changes over abrupt climate change events during the last glacial period, this project may also improve our understanding of mechanisms driving these abrupt events. Insight from this project will prove valuable for forecasting the response of stratospheric circulation to climate change, which has large implications for climate feedbacks and tropospheric composition. In addition, the information gleaned from this project on the mechanisms and feedbacks during abrupt climate change events will help determine the likelihood of such rapid events occurring in the future, which would have dramatic impacts on humankind. This award will provide training for one graduate and one undergraduate student, and will support the development of a hands-on activity related to rapid climate change to be used at the annual Polar Science Weekend at the Pacific Science Center in Seattle, WA.", "east": -112.05, "geometry": "POINT(-112.05 -79.28)", "instruments": null, "is_usap_dc": true, "keywords": "Nitrate Isotopes; ICE CORE RECORDS; WAIS Divide; LABORATORY", "locations": "WAIS Divide", "north": -79.28, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Alexander, Becky", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -79.28, "title": "Measuring an Ice-core Proxy for Relative Oxidant Abundances over Glacial-interglacial and Rapid Climate changes in a West Antarctic Ice Core", "uid": "p0010403", "west": -112.05}, {"awards": "0538520 Thiemens, Mark; 0538049 Steig, Eric", "bounds_geometry": "POINT(-112.085 -79.5)", "dataset_titles": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core; WAIS Divide sulfate and nitrate isotopes; WAIS ice core isotope data #387, 385 (full data link not provided)", "datasets": [{"dataset_uid": "601007", "doi": "10.15784/601007", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Nitrate; Oxygen Isotope; Sulfate; WAIS Divide; WAIS Divide Ice Core", "people": "Alexander, Becky; Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide sulfate and nitrate isotopes", "url": "https://www.usap-dc.org/view/dataset/601007"}, {"dataset_uid": "609479", "doi": "10.7265/N5BG2KXH", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Thiemens, Mark H.", "repository": "USAP-DC", "science_program": null, "title": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609479"}, {"dataset_uid": "002512", "doi": "", "keywords": null, "people": null, "repository": "Project website", "science_program": null, "title": "WAIS ice core isotope data #387, 385 (full data link not provided)", "url": "http://www.waisdivide.unh.edu/"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "0538520\u003cbr/\u003eThiemens\u003cbr/\u003eThis award supports a project to develop the first complete record of multiple isotope ratios of nitrate and sulfate covering the last ~100,000 years, from the deep ice core planned for the central ice divide of the West Antarctic Ice Sheet (WAIS). The WAIS Divide ice core will be the highest resolution long ice core obtained from Antarctica and we can expect important complementary information to be available, including accurate knowledge of past accumulation rates, temperatures, and compounds such as H2O2, CO and CH4. These compounds play significant roles in global atmospheric chemistry and climate. Especially great potential lies in the use of multiple isotope signatures. The unique mass independent fractionation (MIF) 17O signature of ozone is observed in both nitrate and sulfate, due to the interaction of their precursors with ozone. The development of methods to measure the multiple-isotope composition of small samples of sulfate and nitrate makes continuous high resolution measurements on ice cores feasible for the first time. Recent work has shown that such measurements can be used to determine the hydroxyl radial (OH) and ozone (O3) concentrations in the paleoatmosphere as well as to apportion sulfate and nitrate sources. There is also considerable potential in using these isotope measurements to quantify post depositional changes. In the first two years, continuous measurements from the upper ~100-m of ice at WAIS divide will be obtained, to provide a detailed look at seasonal through centennial scale variability. In the third year, measurements will be made throughout the available depth of the deep core (expected to reach ~500 m at this time). The broader impacts of the project include applications to diverse fields including atmospheric chemistry, glaciology, meteorology, and paleoclimatology. Because nitrate and sulfate are important atmospheric pollutants, the results will also have direct and relevance to global environmental policy. This project will coincide with the International Polar Year (2007-2008), and contributes to goals of the IPY, which include the fostering of interdisciplinary research toward enhanced understanding of atmospheric chemistry and climate in the polar regions.", "east": -112.085, "geometry": "POINT(-112.085 -79.5)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Isotope Ratios; Temperature; Sulfate; West Antarctic; Paleoatmosphere; LABORATORY; Ice Core; Ice Core Data; Mass Independent Fractionation; FIELD SURVEYS; Not provided; Accumulation Rate; Oxygen Isotope; FIELD INVESTIGATION; Ice Core Chemistry; Isotope", "locations": "West Antarctic", "north": -79.5, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Alexander, Becky; Steig, Eric J.; Thiemens, Mark H.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "Project website; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.5, "title": "Collaborative Research: Multiple-isotope Analysis of Nitrate and Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "uid": "p0000020", "west": -112.085}]
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| Project Title/Abstract/Map | NSF Award(s) | Date Created | PIs / Scientists | Dataset Links and Repositories | Abstract | Bounds Geometry | Geometry | Selected | Visible | |||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
Measuring an Ice-core Proxy for Relative Oxidant Abundances over Glacial-interglacial and Rapid Climate changes in a West Antarctic Ice Core
|
1542723 |
2023-02-13 | Alexander, Becky |
|
The Earth's atmosphere is a highly oxidizing medium. The abundance of oxidants such as ozone in the atmosphere strongly influences the concentrations of pollutants and greenhouse gases, with implications for human health and welfare. Because oxidants are not preserved in geological archives, knowledge of how oxidants have varied in the past under changing climate conditions is extremely limited. This award will measure a proxy for oxidant concentrations in a West Antarctic ice core over several major climate transitions over the past 50,000 years. These measurements will complement similar measurements from a Greenland ice core, which showed significant changes in atmospheric oxidants over major climate transitions covering this same time period. The addition of measurements from Antarctica will allow researchers to examine if the oxidant changes suggested by the Greenland ice core record are regional or global in scale. Knowledge of how oxidants vary naturally with climate will better inform predictions of the composition of the future atmosphere under a warming climate.<br/><br/>This award will support measurements of the isotopic composition of nitrate in a West Antarctic ice core as a proxy for oxidant concentrations in the past atmosphere. The nitrogen isotopes of nitrate provide information on the degree of preservation of nitrate in the ice core record, and thus aid in the interpretation of the observed variability in the observed nitrate concentrations and oxygen isotopes in ice core records. By providing information about the spatial scale of oxidant changes over abrupt climate change events during the last glacial period, this project may also improve our understanding of mechanisms driving these abrupt events. Insight from this project will prove valuable for forecasting the response of stratospheric circulation to climate change, which has large implications for climate feedbacks and tropospheric composition. In addition, the information gleaned from this project on the mechanisms and feedbacks during abrupt climate change events will help determine the likelihood of such rapid events occurring in the future, which would have dramatic impacts on humankind. This award will provide training for one graduate and one undergraduate student, and will support the development of a hands-on activity related to rapid climate change to be used at the annual Polar Science Weekend at the Pacific Science Center in Seattle, WA. | POINT(-112.05 -79.28) | POINT(-112.05 -79.28) | false | false | |||
|
Collaborative Research: Multiple-isotope Analysis of Nitrate and Sulfate in the West Antarctic Ice Sheet Divide Ice Core
|
0538520 0538049 |
2017-04-25 | Alexander, Becky; Steig, Eric J.; Thiemens, Mark H. | 0538520<br/>Thiemens<br/>This award supports a project to develop the first complete record of multiple isotope ratios of nitrate and sulfate covering the last ~100,000 years, from the deep ice core planned for the central ice divide of the West Antarctic Ice Sheet (WAIS). The WAIS Divide ice core will be the highest resolution long ice core obtained from Antarctica and we can expect important complementary information to be available, including accurate knowledge of past accumulation rates, temperatures, and compounds such as H2O2, CO and CH4. These compounds play significant roles in global atmospheric chemistry and climate. Especially great potential lies in the use of multiple isotope signatures. The unique mass independent fractionation (MIF) 17O signature of ozone is observed in both nitrate and sulfate, due to the interaction of their precursors with ozone. The development of methods to measure the multiple-isotope composition of small samples of sulfate and nitrate makes continuous high resolution measurements on ice cores feasible for the first time. Recent work has shown that such measurements can be used to determine the hydroxyl radial (OH) and ozone (O3) concentrations in the paleoatmosphere as well as to apportion sulfate and nitrate sources. There is also considerable potential in using these isotope measurements to quantify post depositional changes. In the first two years, continuous measurements from the upper ~100-m of ice at WAIS divide will be obtained, to provide a detailed look at seasonal through centennial scale variability. In the third year, measurements will be made throughout the available depth of the deep core (expected to reach ~500 m at this time). The broader impacts of the project include applications to diverse fields including atmospheric chemistry, glaciology, meteorology, and paleoclimatology. Because nitrate and sulfate are important atmospheric pollutants, the results will also have direct and relevance to global environmental policy. This project will coincide with the International Polar Year (2007-2008), and contributes to goals of the IPY, which include the fostering of interdisciplinary research toward enhanced understanding of atmospheric chemistry and climate in the polar regions. | POINT(-112.085 -79.5) | POINT(-112.085 -79.5) | false | false |
