{"dp_type": "Project", "free_text": "Biomass Burning"}
[{"awards": null, "bounds_geometry": null, "dataset_titles": "Common-era black carbon deposition and atmospheric modeling for 6 Antarctic ice cores", "datasets": [{"dataset_uid": "601464", "doi": "10.15784/601464", "repository": "USAP-DC", "science_program": null, "title": "Common-era black carbon deposition and atmospheric modeling for 6 Antarctic ice cores", "url": "http://www.usap-dc.org/view/dataset/601464"}], "date_created": "Fri, 16 Jul 2021 00:00:00 GMT", "description": null, "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "Antarctica; Antarctic Peninsula; Biomass Burning; Black Carbon; Dronning Maud Land; East Antarctic Plateau; Ice Core", "locations": "Antarctica; Antarctic Peninsula; Dronning Maud Land; East Antarctic Plateau", "north": null, "nsf_funding_programs": null, "paleo_time": null, "persons": "McConnell, Joseph; Chellman, Nathan", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": null, "uid": null, "west": null}, {"awards": "1644245 Aydin, Murat", "bounds_geometry": null, "dataset_titles": "Ice Core Air Ethane and Acetylene Measurements - South Pole SPC14 Ice Core (SPICEcore project); Ice core ethane measurements, Greenland and Antarctica, 1000-1900 CE.", "datasets": [{"dataset_uid": "002574", "doi": "", "keywords": null, "people": null, "repository": "Arctic Data Center", "science_program": null, "title": "Ice core ethane measurements, Greenland and Antarctica, 1000-1900 CE.", "url": "https://arcticdata.io/catalog/view/doi:10.18739/A2CR5NC1B"}, {"dataset_uid": "601367", "doi": "10.15784/601367", "keywords": "Antarctica; Ethane", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Ice Core Air Ethane and Acetylene Measurements - South Pole SPC14 Ice Core (SPICEcore project)", "url": "https://www.usap-dc.org/view/dataset/601367"}], "date_created": "Tue, 13 Nov 2018 00:00:00 GMT", "description": "Aydin/1644245 This award supports a project to measure ethane in ice core air extracted from the recently drilled intermediate depth South Pole ice core (SPICECORE). Ethane is an abundant hydrocarbon in the atmosphere. The ice core samples that will be used in this analysis will span about 150 years before present to about 55,000 years before present and therefore, ethane emissions linked to human activities are not a subject of this study. The study will focus on quantifying the variability in the natural sources of ethane and the processes that govern its removal from the atmosphere. A long-term ice core ethane record will provide new knowledge on the chemistry of Earth?s atmosphere during time periods when human influence was either much smaller than present day or non-existent. The broader impacts of this work include education and training of students and a contribution to a better understanding of the chemistry of the atmosphere in the past and how it has been impacted by past changes in climate. Natural sources that emit ethane are both geologic (e.g. seeps, vents, mud volcanoes etc.) and pyrogenic (wild fires) which is commonly called biomass burning. Ethane is removed from the atmosphere via oxidation reactions. The ice core ethane measurements have great potential as a proxy for gaseous emissions from biomass burning. This is especially true for time periods preceding the industrial revolution when atmospheric variability of trace gases was largely controlled by natural processes. Another objective of this study is to improve understanding of the causes of atmospheric methane variability apparent which are in the existing ice core records. Methane is a simpler hydrocarbon than ethane and more abundant in the atmosphere. Even though the project does not include any methane measurements; the commonalities between the sources and removal of atmospheric ethane and methane mean that ethane measurements can be used to gain insight into the causes of changes in atmospheric methane levels. The broader impacts of the project include partial support for one Ph.D. student and support for undergraduate researchers at UC Irvine. The PIs group currently has 4 undergraduate researchers. The PI and the graduate students in the UCI ice core laboratory regularly participate in on- and off-campus activities such as laboratory tours and lectures directed towards educating high-school students and science teachers, and the local community at large about the scientific value of polar ice cores as an environmental record of our planet\u0027s past. The results of this research will be disseminated via peer-review publications and will contribute to policy-relevant activities such as the IPCC Climate Assessment. Data resulting from this project will be archived in a national data repository. This award does not have field work in Antarctica.", "east": null, "geometry": null, "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "USAP-DC; NOT APPLICABLE", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "Arctic Data Center", "repositories": "Arctic Data Center; USAP-DC", "science_programs": "SPICEcore", "south": null, "title": "Ethane Measurements in the Intermediate Depth South Pole Ice Core (SPICECORE)", "uid": "p0000762", "west": null}, {"awards": "1246223 Hastings, Meredith", "bounds_geometry": "POINT(-112.1115 -79.481)", "dataset_titles": "WAIS Divide WDC06A Nitrate Isotope Record", "datasets": [{"dataset_uid": "601022", "doi": "10.15784/601022", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Nitrate; WAIS Divide; WAIS Divide Ice Core", "people": "Buffen, Aron; Hastings, Meredith", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide WDC06A Nitrate Isotope Record", "url": "https://www.usap-dc.org/view/dataset/601022"}], "date_created": "Tue, 02 May 2017 00:00:00 GMT", "description": "Hastings/1246223 This award supports a project with the aim of distinguishing the sources of nitrate deposition to the West Antarctic Ice Sheet (WAIS) using isotopic ratios snow in archive snow and ice samples. The isotopic composition of nitrate has been shown to contain information about the source of the nitrate (i.e. nitrogen oxides = NOx = NO+NO2) and the oxidation processes that convert NOx to nitrate in the atmosphere prior to deposition. A difficulty in interpreting records in the context of NOx sources is that nitrate can be post-depositionally processed in surface snow, such that the archived record does not reflect the composition of the atmosphere. This intellectual merit of this work specifically aims to investigate variability in the isotopic composition of nitrate in snow and ice from the WAIS in the context of accumulation rate, NOx source emissions, and atmospheric chemistry. These records will be interpreted in the context of our understanding of biospheric (biomass burning, microbial processes in soils), atmospheric (lightning, transport, chemistry), and climate (temperature, accumulation rate) changes over time. A graduate student will be supported as part of this project, and both graduate student and PI will be involved in communicating the utility and results of polar research to elementary school students in the Providence, RI area. The broader impacts of the project also include making efforts to attract more young, female scientists to polar research by establishing a connection between the Earth Science Women\u0027s Network (ESWN), an organization PI Hastings helped to establish, and the Association of Polar Early Career Scientists (APECS). Finally, results of all measurements will be presented at relevant conferences, made available publicly and published in peer-reviewed journals.", "east": -112.1115, "geometry": "POINT(-112.1115 -79.481)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -79.481, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Hastings, Meredith", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.481, "title": "Investigating Source, Chemistry and Climate changes using the Isotopic Composition of Nitrate in Antarctic Snow and Ice", "uid": "p0000399", "west": -112.1115}, {"awards": "1142166 McConnell, Joseph", "bounds_geometry": "POINT(-112.1115 -79.481)", "dataset_titles": "WAIS Divide Ice-Core Aerosol Records from 1300 to 3404 m", "datasets": [{"dataset_uid": "601008", "doi": "10.15784/601008", "keywords": "Aerosol; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "McConnell, Joseph", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Ice-Core Aerosol Records from 1300 to 3404 m", "url": "https://www.usap-dc.org/view/dataset/601008"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "McConnell/1142166 This award supports a project to use unprecedented aerosol and continuous gas (methane, carbon monoxide) measurements of the deepest section of the West Antarctic Ice Sheet (WAIS) Divide ice core to investigate rapid climate changes in Antarctica during the ~60,000 year long Marine Isotope Stage 3 period of the late Pleistocene. These analyses, combined with others, will take advantage of the high snow accumulation of the WAIS Divide ice core to yield the highest time resolution glaciochemical and gas record of any deep Antarctic ice core for this time period. The research will expand already funded discrete gas measurements and extend currently funded continuous aerosol measurements on the WAIS Divide ice core from ~25,000 to ~60,000 years before present, spanning Heinrich events 3 to 6 and Antarctic Isotope Maximum (AIM, corresponding to the Northern Hemisphere Dansgaard-Oeschger) events 3 to 14. With other high resolution Greenland cores and lower resolution Antarctic cores, the combined record will yield new insights into worldwide climate dynamics and abrupt change. The intellectual merit of the work is that it will be used to address the science goals of the WAIS Divide project including the identification of dust and biomass burning tracers such as black carbon and carbon monoxide which reflect mid- and low-latitude climate and atmospheric circulation patterns, and fallout from these sources affects marine and terrestrial biogeochemical cycles. Similarly, sea salt and ocean productivity tracers reflect changes in sea ice extent, marine primary productivity, wind speeds above the ocean, and atmospheric circulation. Volcanic tracers address the relationship between northern, tropical, and southern climates as well as stability of the West Antarctic ice sheet and sea level change. When combined with other gas records from WAIS Divide, the records developed here will transform understanding of mid- and low-latitude drivers of Antarctic, Southern Hemisphere, and global climate rapid changes and the timing of such changes. The broader impacts of the work are that it will enhance infrastructure through expansion of continuous ice core analytical techniques, train students and support collaboration between two U.S. institutions (DRI and OSU). All data will be made available to the scientific community and the public and will include participation the WAIS Divide Outreach Program. Extensive graduate and undergraduate student involvement is planned. Student recruitment will be made from under-represented groups building on a long track record. Broad outreach will be achieved through collaborations with the global and radiative modeling communities, NESTA-related and other educational outreach efforts, and public lectures. This proposed project does not require field work in the Antarctic.", "east": -112.1115, "geometry": "POINT(-112.1115 -79.481)", "instruments": null, "is_usap_dc": true, "keywords": "Not provided", "locations": null, "north": -79.481, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "McConnell, Joseph", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.481, "title": "Collaborative Research: Investigating Upper Pleistocene Rapid Climate Change using Continuous, Ultra-High-Resolution Aerosol and Gas Measurements in the WAIS Divide Ice Core", "uid": "p0000287", "west": -112.1115}, {"awards": "0838936 Brook, Edward J.; 0839031 Severinghaus, Jeffrey", "bounds_geometry": "POINT(161.75 -77.75)", "dataset_titles": "Measurements of 14C-methane for the Younger Dryas - Preboreal Transition from Taylor Glacier, Antarctica; Measurements of in situ cosmogenic 14C from Taylor Glacier, Antarctica; Taylor Glacier chemistry data and Taylor Dome TD2015 time scale; Taylor Glacier CO2 record; Taylor Glacier Gas Isotope Data", "datasets": [{"dataset_uid": "601029", "doi": "10.15784/601029", "keywords": "Antarctica; Chemistry:rock; Chemistry:Rock; Critical Zone; Geochemistry; Methane; Paleoclimate; Sample/collection Description; Sample/Collection Description; Solid Earth; Taylor Glacier; Transantarctic Mountains; Younger Dryas", "people": "Severinghaus, Jeffrey P.; Petrenko, Vasilii", "repository": "USAP-DC", "science_program": null, "title": "Measurements of 14C-methane for the Younger Dryas - Preboreal Transition from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601029"}, {"dataset_uid": "601103", "doi": "10.15784/601103", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Horizontal Ice Core; Ice Core Records; Taylor Dome; Taylor Dome Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier chemistry data and Taylor Dome TD2015 time scale", "url": "https://www.usap-dc.org/view/dataset/601103"}, {"dataset_uid": "600165", "doi": "10.15784/600165", "keywords": "Antarctica; Cosmogenic; Geochemistry; Ice Core Records; Paleoclimate; Radiocarbon; Taylor Glacier; Transantarctic Mountains", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Measurements of in situ cosmogenic 14C from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/600165"}, {"dataset_uid": "601033", "doi": "10.15784/601033", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciology; Ice Core Records; Isotope; Solid Earth; Taylor Glacier; Transantarctic Mountains", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier Gas Isotope Data", "url": "https://www.usap-dc.org/view/dataset/601033"}, {"dataset_uid": "000158", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Taylor Glacier CO2 record", "url": "ftp://ftp.ncdc.noaa.gov/pub/data/paleo/icecore/antarctica/taylor/taylor2016d13co2.txt"}], "date_created": "Tue, 29 Mar 2016 00:00:00 GMT", "description": "Severinghaus/0839031 \u003cbr/\u003e\u003cbr/\u003eThis award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to develop a precise gas-based chronology for an archive of large-volume samples of the ancient atmosphere, which would enable ultra-trace gas measurements that are currently precluded by sample size limitations of ice cores. The intellectual merit of the proposed work is that it will provide a critical test of the \"clathrate hypothesis\" that methane clathrates contributed to the two abrupt atmospheric methane concentration increases during the last deglaciation 15 and 11 kyr ago. This approach employs large volumes of ice (\u003e1 ton) to measure carbon-14 on past atmospheric methane across the abrupt events. Carbon-14 is an ideal discriminator of fossil sources of methane to the atmosphere, because most methane sources (e.g., wetlands, termites, biomass burning) are rich in carbon-14, whereas clathrates and other fossil sources are devoid of carbon-14. The proposed work is a logical extension to Taylor Glacier, Antarctica, of an approach pioneered at the margin of the Greenland ice sheet over the past 7 years. The Greenland work found higher-than-expected carbon-14 values, likely due in part to contaminants stemming from the high impurity content of Greenland ice and the interaction of the ice with sediments from the glacier bed. The data also pointed to the possibility of a previously unknown process, in-situ cosmogenic production of carbon-14 methane (radiomethane) in the ice matrix. Antarctic ice in Taylor Glacier is orders of magnitude cleaner than the ice at the Greenland site, and is much colder and less stratigraphically disturbed, offering the potential for a clear resolution of this puzzle and a definitive test of the cosmogenic radiomethane hypothesis. Even if cosmogenic radiomethane in ice is found, it still may be possible to reconstruct atmospheric radiomethane with a correction enabled by a detailed understanding of the process, which will be sought by co-measuring carbon-14 in carbon monoxide and carbon dioxide. The broader impacts of the proposed work are that the clathrate test may shed light on the stability of the clathrate reservoir and its potential for climate feedbacks under human-induced warming. Development of Taylor Glacier as a \"horizontal ice core\" would provide a community resource for other researchers. Education of one postdoc, one graduate student, and one undergraduate, would add to human resources. This award has field work in Antarctica.", "east": 161.75, "geometry": "POINT(161.75 -77.75)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "NOT APPLICABLE; Not provided; USAP-DC", "locations": null, "north": -77.75, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Brook, Edward J.; Severinghaus, Jeffrey P.", "platforms": "Not provided; OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "NCEI; USAP-DC", "science_programs": null, "south": -77.75, "title": "Collaborative Research: A \"Horizontal Ice Core\" for Large-Volume Samples of the Past Atmosphere, Taylor Glacier, Antarctica", "uid": "p0000099", "west": 161.75}, {"awards": "0739598 Aydin, Murat; 0739491 Sowers, Todd", "bounds_geometry": null, "dataset_titles": "Alkanes in Firn Air Samples, Antarctica and Greenland; Methane Isotopes in South Pole Firn Air, 2008", "datasets": [{"dataset_uid": "609504", "doi": "10.7265/N5X9287C", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Snow/ice; Snow/Ice; South Pole; WAIS Divide", "people": "Aydin, Murat; Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "Alkanes in Firn Air Samples, Antarctica and Greenland", "url": "https://www.usap-dc.org/view/dataset/609504"}, {"dataset_uid": "609502", "doi": "10.7265/N55T3HFP", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Isotope; Paleoclimate; Snow/ice; Snow/Ice; South Pole", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": null, "title": "Methane Isotopes in South Pole Firn Air, 2008", "url": "https://www.usap-dc.org/view/dataset/609502"}], "date_created": "Thu, 18 Aug 2011 00:00:00 GMT", "description": "This award supports a project to make measurements of methane and other trace gases in firn air collected at South Pole, Antarctica. The analyses will include: methane isotopes (delta-13CH4 and delta-DCH4), light non-methane hydrocarbons (ethane, propane, and n-butane), sulfur gases (COS, CS2), and methyl halides (CH3Cl and CH3Br). The atmospheric burdens of these trace gases reflect changes in atmospheric OH, biomass burning, biogenic activity in terrestrial, oceanic, and wetland ecosystems, and industrial/agricultural activity. The goal of this project is to develop atmospheric histories for these trace gases over the last century through examination of depth profiles of these gases in South Pole firn air. The project will involve two phases: 1) a field campaign at South Pole, Antarctica to drill two firn holes and fill a total of ~200 flasks from depths reaching 120 m, 2) analysis of firn air at University of California, Irvine, Penn State University, and several other collaborating laboratories. Atmospheric histories will be inferred from the measurements using a one dimensional advective/diffusive model of firn air transport. This study will provide new information about the recent changes in atmospheric levels of these gases, providing about a 90 year long time series record that connects the earlier surface and firn air measurements to present day. The project will also explore the possibility of in- situ production of light non-methane hydrocarbons in firn air that is relevant to the interpretation of ice core records. The broader impacts of this research are that it has the potential for significant societal impact by improving our understanding of climate change and man\u0027s input to the atmosphere. The results of this work will be disseminated through the peer review process, and will contribute to environmental assessments, such as the Inter-governmental Panel on Climate Change (IPCC) Climate Assessment and the Word Meteorological Organization (WMO) Stratospheric Ozone Assessment. This research will provide educational opportunities for graduate and undergraduate students, and will contribute to a teacher training program for K-12 teachers in minority school districts.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS", "is_usap_dc": true, "keywords": "FIELD INVESTIGATION; Isotope; Firn Air Chemistry; Firn Air Isotope Measurements; Not provided; LABORATORY; South Pole; Firn; Delta 13C; Carbon-13; Mass Spectrometer; Deuterium; Mass Spectrometry; Firn Air Samples; Carbon; Gas Chromatography; Polar Firn Air; GROUND-BASED OBSERVATIONS; Methane; Antarctica; Firn Air Isotopes; Delta Deuterium; FIELD SURVEYS; Firn Air; Chromatography; Methane Isotopes; Carbon Isotopes; Stable Isotopes", "locations": "Antarctica; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat; Saltzman, Eric; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air", "uid": "p0000162", "west": null}, {"awards": "0739780 Taylor, Kendrick", "bounds_geometry": "POINT(-112.117 -79.666)", "dataset_titles": "WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning", "datasets": [{"dataset_uid": "600142", "doi": "10.15784/600142", "keywords": "Antarctica; Atmosphere; Black Carbon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; WAIS Divide; WAIS Divide Ice Core", "people": "Taylor, Kendrick C.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning", "url": "https://www.usap-dc.org/view/dataset/600142"}], "date_created": "Thu, 28 Apr 2011 00:00:00 GMT", "description": "Edwards/0739780\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to develop a 2,000-year high-temporal resolution record of biomass burning from the analysis of black carbon in the WAIS Divide bedrock ice core. Pilot data for the WAIS WD05A core demonstrates that we now have the ability to reconstruct this record with minimal impact on the amount of ice available for other projects. The intellectual merit of this project is that black carbon (BC) aerosols result solely from combustion and play a critical but poorly quantified role in global climate forcing and the carbon cycle. When incorporated into snow and ice, BC increases absorption of solar radiation making seasonal snow packs, mountain glaciers, polar ice sheets, and sea ice much more vulnerable to climate warming. BC emissions in the Southern Hemisphere are dominated by biomass burning in the tropical regions of Southern Africa, South America and South Asia. Biomass burning, which results from both climate and human activities, alters the atmospheric composition of greenhouse gases, aerosols and perturbs key biogeochemical cycles. A long-term record of biomass burning is needed to aid in the interpretation of ice core gas composition and will provide important information regarding human impacts on the environment and climate before instrumental records. The broader impacts of the project are that it represents a paradigm shift in our ability to reconstruct the history of fire from ice core records and to understand its impact on atmospheric chemistry and climate over millennial time scales. This type of data is especially needed to drive global circulation model simulations of black carbon aerosols, which have been found to be an important component of global warming and which may be perturbing the hydrologic cycle. The project will also employ undergraduate students and is committed to attracting underrepresented groups to the physical sciences. The project?s outreach component will be conducted as part of the WAIS project outreach program and will reach a wide audience.", "east": -112.117, "geometry": "POINT(-112.117 -79.666)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core Chemistry; Not provided; Gas Record; Ice Core; Gas Measurement; Ice Core Gas Composition; Antarctica; LABORATORY; Bedrock Ice Core; Ice Core Gas Records; Wais Project; Greenhouse Gas; Atmospheric Chemistry; FIELD INVESTIGATION; Black Carbon; Biomass Burning; WAIS Divide; FIELD SURVEYS; West Antarctica; Methane", "locations": "Antarctica; West Antarctica; WAIS Divide", "north": -79.666, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.; McConnell, Joseph; Mitchell, Logan E; Sowers, Todd A.; Taylor, Kendrick C.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.666, "title": "WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning", "uid": "p0000022", "west": -112.117}, {"awards": "9526556 Sowers, Todd", "bounds_geometry": "POINT(-148.3023 -81.403)", "dataset_titles": "Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica", "datasets": [{"dataset_uid": "609310", "doi": "10.7265/N5ST7MR2", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Siple Dome; Snow/ice; Snow/Ice; South Pole", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica", "url": "https://www.usap-dc.org/view/dataset/609310"}], "date_created": "Mon, 09 Jul 2007 00:00:00 GMT", "description": "This award is for support for a program to reconstruct records of the isotopic composition of paleoatmospheric methane and nitrous oxide covering the last 200,000 years. High resolution measurements of the carbon-13 isotopic composition of methane from shallow ice cores will help to determine the relative contributions of biogenic (wetlands, rice fields and ruminants) and abiogenic (biomass burning and natural gas) methane emissions which have caused the concentrations of this gas to increase at an exponential rate during the anthropogenic period. Isotopic data on methane and nitrous oxide over glacial/interglacial timescales will help determine the underlying cause of the large concentration variations that are known to occur. This project will make use of a new generation mass spectrometer which is capable of generating precise isotopic information on nanomolar quantities of methane and nitrous oxide, which means that samples can be 1000 times smaller than those needed for a standard isotope ratio instrument. The primary objective of the work is to further our understanding of the biogeochemical cycles of these two greenhouse gases throughout the anthropogenic period as well as over glacial interglacial timescales.", "east": -148.3023, "geometry": "POINT(-148.3023 -81.403)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Ice Core; Firn Air Isotope Measurements; Ice Core Chemistry; Firn Isotopes; Stable Isotopes; Methane; Carbon; Paleoclimate; LABORATORY; Siple Dome; Antarctica; Ice Core Data; Firn Air Isotopes; Antarctic Ice Sheet", "locations": "Antarctica; Antarctic Ice Sheet; Siple Dome", "north": -81.403, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Sowers, Todd A.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.403, "title": "Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide", "uid": "p0000611", "west": -148.3023}]
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Project Title/Abstract/Map | NSF Award(s) | Date Created | PIs / Scientists | Dataset Links and Repositories | Abstract | Bounds Geometry | Geometry | Selected | Visible | |||||
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None
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None | 2021-07-16 | McConnell, Joseph; Chellman, Nathan |
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None | None | None | false | false | |||||
Ethane Measurements in the Intermediate Depth South Pole Ice Core (SPICECORE)
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1644245 |
2018-11-13 | Aydin, Murat |
|
Aydin/1644245 This award supports a project to measure ethane in ice core air extracted from the recently drilled intermediate depth South Pole ice core (SPICECORE). Ethane is an abundant hydrocarbon in the atmosphere. The ice core samples that will be used in this analysis will span about 150 years before present to about 55,000 years before present and therefore, ethane emissions linked to human activities are not a subject of this study. The study will focus on quantifying the variability in the natural sources of ethane and the processes that govern its removal from the atmosphere. A long-term ice core ethane record will provide new knowledge on the chemistry of Earth?s atmosphere during time periods when human influence was either much smaller than present day or non-existent. The broader impacts of this work include education and training of students and a contribution to a better understanding of the chemistry of the atmosphere in the past and how it has been impacted by past changes in climate. Natural sources that emit ethane are both geologic (e.g. seeps, vents, mud volcanoes etc.) and pyrogenic (wild fires) which is commonly called biomass burning. Ethane is removed from the atmosphere via oxidation reactions. The ice core ethane measurements have great potential as a proxy for gaseous emissions from biomass burning. This is especially true for time periods preceding the industrial revolution when atmospheric variability of trace gases was largely controlled by natural processes. Another objective of this study is to improve understanding of the causes of atmospheric methane variability apparent which are in the existing ice core records. Methane is a simpler hydrocarbon than ethane and more abundant in the atmosphere. Even though the project does not include any methane measurements; the commonalities between the sources and removal of atmospheric ethane and methane mean that ethane measurements can be used to gain insight into the causes of changes in atmospheric methane levels. The broader impacts of the project include partial support for one Ph.D. student and support for undergraduate researchers at UC Irvine. The PIs group currently has 4 undergraduate researchers. The PI and the graduate students in the UCI ice core laboratory regularly participate in on- and off-campus activities such as laboratory tours and lectures directed towards educating high-school students and science teachers, and the local community at large about the scientific value of polar ice cores as an environmental record of our planet's past. The results of this research will be disseminated via peer-review publications and will contribute to policy-relevant activities such as the IPCC Climate Assessment. Data resulting from this project will be archived in a national data repository. This award does not have field work in Antarctica. | None | None | false | false | |||||
Investigating Source, Chemistry and Climate changes using the Isotopic Composition of Nitrate in Antarctic Snow and Ice
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1246223 |
2017-05-02 | Hastings, Meredith |
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Hastings/1246223 This award supports a project with the aim of distinguishing the sources of nitrate deposition to the West Antarctic Ice Sheet (WAIS) using isotopic ratios snow in archive snow and ice samples. The isotopic composition of nitrate has been shown to contain information about the source of the nitrate (i.e. nitrogen oxides = NOx = NO+NO2) and the oxidation processes that convert NOx to nitrate in the atmosphere prior to deposition. A difficulty in interpreting records in the context of NOx sources is that nitrate can be post-depositionally processed in surface snow, such that the archived record does not reflect the composition of the atmosphere. This intellectual merit of this work specifically aims to investigate variability in the isotopic composition of nitrate in snow and ice from the WAIS in the context of accumulation rate, NOx source emissions, and atmospheric chemistry. These records will be interpreted in the context of our understanding of biospheric (biomass burning, microbial processes in soils), atmospheric (lightning, transport, chemistry), and climate (temperature, accumulation rate) changes over time. A graduate student will be supported as part of this project, and both graduate student and PI will be involved in communicating the utility and results of polar research to elementary school students in the Providence, RI area. The broader impacts of the project also include making efforts to attract more young, female scientists to polar research by establishing a connection between the Earth Science Women's Network (ESWN), an organization PI Hastings helped to establish, and the Association of Polar Early Career Scientists (APECS). Finally, results of all measurements will be presented at relevant conferences, made available publicly and published in peer-reviewed journals. | POINT(-112.1115 -79.481) | POINT(-112.1115 -79.481) | false | false | |||||
Collaborative Research: Investigating Upper Pleistocene Rapid Climate Change using Continuous, Ultra-High-Resolution Aerosol and Gas Measurements in the WAIS Divide Ice Core
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1142166 |
2017-04-25 | McConnell, Joseph |
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McConnell/1142166 This award supports a project to use unprecedented aerosol and continuous gas (methane, carbon monoxide) measurements of the deepest section of the West Antarctic Ice Sheet (WAIS) Divide ice core to investigate rapid climate changes in Antarctica during the ~60,000 year long Marine Isotope Stage 3 period of the late Pleistocene. These analyses, combined with others, will take advantage of the high snow accumulation of the WAIS Divide ice core to yield the highest time resolution glaciochemical and gas record of any deep Antarctic ice core for this time period. The research will expand already funded discrete gas measurements and extend currently funded continuous aerosol measurements on the WAIS Divide ice core from ~25,000 to ~60,000 years before present, spanning Heinrich events 3 to 6 and Antarctic Isotope Maximum (AIM, corresponding to the Northern Hemisphere Dansgaard-Oeschger) events 3 to 14. With other high resolution Greenland cores and lower resolution Antarctic cores, the combined record will yield new insights into worldwide climate dynamics and abrupt change. The intellectual merit of the work is that it will be used to address the science goals of the WAIS Divide project including the identification of dust and biomass burning tracers such as black carbon and carbon monoxide which reflect mid- and low-latitude climate and atmospheric circulation patterns, and fallout from these sources affects marine and terrestrial biogeochemical cycles. Similarly, sea salt and ocean productivity tracers reflect changes in sea ice extent, marine primary productivity, wind speeds above the ocean, and atmospheric circulation. Volcanic tracers address the relationship between northern, tropical, and southern climates as well as stability of the West Antarctic ice sheet and sea level change. When combined with other gas records from WAIS Divide, the records developed here will transform understanding of mid- and low-latitude drivers of Antarctic, Southern Hemisphere, and global climate rapid changes and the timing of such changes. The broader impacts of the work are that it will enhance infrastructure through expansion of continuous ice core analytical techniques, train students and support collaboration between two U.S. institutions (DRI and OSU). All data will be made available to the scientific community and the public and will include participation the WAIS Divide Outreach Program. Extensive graduate and undergraduate student involvement is planned. Student recruitment will be made from under-represented groups building on a long track record. Broad outreach will be achieved through collaborations with the global and radiative modeling communities, NESTA-related and other educational outreach efforts, and public lectures. This proposed project does not require field work in the Antarctic. | POINT(-112.1115 -79.481) | POINT(-112.1115 -79.481) | false | false | |||||
Collaborative Research: A "Horizontal Ice Core" for Large-Volume Samples of the Past Atmosphere, Taylor Glacier, Antarctica
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0838936 0839031 |
2016-03-29 | Brook, Edward J.; Severinghaus, Jeffrey P. | Severinghaus/0839031 <br/><br/>This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).<br/><br/>This award supports a project to develop a precise gas-based chronology for an archive of large-volume samples of the ancient atmosphere, which would enable ultra-trace gas measurements that are currently precluded by sample size limitations of ice cores. The intellectual merit of the proposed work is that it will provide a critical test of the "clathrate hypothesis" that methane clathrates contributed to the two abrupt atmospheric methane concentration increases during the last deglaciation 15 and 11 kyr ago. This approach employs large volumes of ice (>1 ton) to measure carbon-14 on past atmospheric methane across the abrupt events. Carbon-14 is an ideal discriminator of fossil sources of methane to the atmosphere, because most methane sources (e.g., wetlands, termites, biomass burning) are rich in carbon-14, whereas clathrates and other fossil sources are devoid of carbon-14. The proposed work is a logical extension to Taylor Glacier, Antarctica, of an approach pioneered at the margin of the Greenland ice sheet over the past 7 years. The Greenland work found higher-than-expected carbon-14 values, likely due in part to contaminants stemming from the high impurity content of Greenland ice and the interaction of the ice with sediments from the glacier bed. The data also pointed to the possibility of a previously unknown process, in-situ cosmogenic production of carbon-14 methane (radiomethane) in the ice matrix. Antarctic ice in Taylor Glacier is orders of magnitude cleaner than the ice at the Greenland site, and is much colder and less stratigraphically disturbed, offering the potential for a clear resolution of this puzzle and a definitive test of the cosmogenic radiomethane hypothesis. Even if cosmogenic radiomethane in ice is found, it still may be possible to reconstruct atmospheric radiomethane with a correction enabled by a detailed understanding of the process, which will be sought by co-measuring carbon-14 in carbon monoxide and carbon dioxide. The broader impacts of the proposed work are that the clathrate test may shed light on the stability of the clathrate reservoir and its potential for climate feedbacks under human-induced warming. Development of Taylor Glacier as a "horizontal ice core" would provide a community resource for other researchers. Education of one postdoc, one graduate student, and one undergraduate, would add to human resources. This award has field work in Antarctica. | POINT(161.75 -77.75) | POINT(161.75 -77.75) | false | false | ||||||
Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air
|
0739598 0739491 |
2011-08-18 | Aydin, Murat; Saltzman, Eric; Sowers, Todd A. |
|
This award supports a project to make measurements of methane and other trace gases in firn air collected at South Pole, Antarctica. The analyses will include: methane isotopes (delta-13CH4 and delta-DCH4), light non-methane hydrocarbons (ethane, propane, and n-butane), sulfur gases (COS, CS2), and methyl halides (CH3Cl and CH3Br). The atmospheric burdens of these trace gases reflect changes in atmospheric OH, biomass burning, biogenic activity in terrestrial, oceanic, and wetland ecosystems, and industrial/agricultural activity. The goal of this project is to develop atmospheric histories for these trace gases over the last century through examination of depth profiles of these gases in South Pole firn air. The project will involve two phases: 1) a field campaign at South Pole, Antarctica to drill two firn holes and fill a total of ~200 flasks from depths reaching 120 m, 2) analysis of firn air at University of California, Irvine, Penn State University, and several other collaborating laboratories. Atmospheric histories will be inferred from the measurements using a one dimensional advective/diffusive model of firn air transport. This study will provide new information about the recent changes in atmospheric levels of these gases, providing about a 90 year long time series record that connects the earlier surface and firn air measurements to present day. The project will also explore the possibility of in- situ production of light non-methane hydrocarbons in firn air that is relevant to the interpretation of ice core records. The broader impacts of this research are that it has the potential for significant societal impact by improving our understanding of climate change and man's input to the atmosphere. The results of this work will be disseminated through the peer review process, and will contribute to environmental assessments, such as the Inter-governmental Panel on Climate Change (IPCC) Climate Assessment and the Word Meteorological Organization (WMO) Stratospheric Ozone Assessment. This research will provide educational opportunities for graduate and undergraduate students, and will contribute to a teacher training program for K-12 teachers in minority school districts. | None | None | false | false | |||||
WAIS DIVIDE - High Temporal Resolution Black Carbon Record of Southern Hemisphere Biomass Burning
|
0739780 |
2011-04-28 | Brook, Edward J.; McConnell, Joseph; Mitchell, Logan E; Sowers, Todd A.; Taylor, Kendrick C. |
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Edwards/0739780<br/><br/>This award supports a project to develop a 2,000-year high-temporal resolution record of biomass burning from the analysis of black carbon in the WAIS Divide bedrock ice core. Pilot data for the WAIS WD05A core demonstrates that we now have the ability to reconstruct this record with minimal impact on the amount of ice available for other projects. The intellectual merit of this project is that black carbon (BC) aerosols result solely from combustion and play a critical but poorly quantified role in global climate forcing and the carbon cycle. When incorporated into snow and ice, BC increases absorption of solar radiation making seasonal snow packs, mountain glaciers, polar ice sheets, and sea ice much more vulnerable to climate warming. BC emissions in the Southern Hemisphere are dominated by biomass burning in the tropical regions of Southern Africa, South America and South Asia. Biomass burning, which results from both climate and human activities, alters the atmospheric composition of greenhouse gases, aerosols and perturbs key biogeochemical cycles. A long-term record of biomass burning is needed to aid in the interpretation of ice core gas composition and will provide important information regarding human impacts on the environment and climate before instrumental records. The broader impacts of the project are that it represents a paradigm shift in our ability to reconstruct the history of fire from ice core records and to understand its impact on atmospheric chemistry and climate over millennial time scales. This type of data is especially needed to drive global circulation model simulations of black carbon aerosols, which have been found to be an important component of global warming and which may be perturbing the hydrologic cycle. The project will also employ undergraduate students and is committed to attracting underrepresented groups to the physical sciences. The project?s outreach component will be conducted as part of the WAIS project outreach program and will reach a wide audience. | POINT(-112.117 -79.666) | POINT(-112.117 -79.666) | false | false | |||||
Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide
|
9526556 |
2007-07-09 | Sowers, Todd A. |
|
This award is for support for a program to reconstruct records of the isotopic composition of paleoatmospheric methane and nitrous oxide covering the last 200,000 years. High resolution measurements of the carbon-13 isotopic composition of methane from shallow ice cores will help to determine the relative contributions of biogenic (wetlands, rice fields and ruminants) and abiogenic (biomass burning and natural gas) methane emissions which have caused the concentrations of this gas to increase at an exponential rate during the anthropogenic period. Isotopic data on methane and nitrous oxide over glacial/interglacial timescales will help determine the underlying cause of the large concentration variations that are known to occur. This project will make use of a new generation mass spectrometer which is capable of generating precise isotopic information on nanomolar quantities of methane and nitrous oxide, which means that samples can be 1000 times smaller than those needed for a standard isotope ratio instrument. The primary objective of the work is to further our understanding of the biogeochemical cycles of these two greenhouse gases throughout the anthropogenic period as well as over glacial interglacial timescales. | POINT(-148.3023 -81.403) | POINT(-148.3023 -81.403) | false | false |