{"dp_type": "Dataset", "free_text": "Firn Air"}
[{"awards": "1643669 Petrenko, Vasilii", "bounds_geometry": ["POLYGON((112 -66,112.2 -66,112.4 -66,112.6 -66,112.8 -66,113 -66,113.2 -66,113.4 -66,113.6 -66,113.8 -66,114 -66,114 -66.1,114 -66.2,114 -66.3,114 -66.4,114 -66.5,114 -66.6,114 -66.7,114 -66.8,114 -66.9,114 -67,113.8 -67,113.6 -67,113.4 -67,113.2 -67,113 -67,112.8 -67,112.6 -67,112.4 -67,112.2 -67,112 -67,112 -66.9,112 -66.8,112 -66.7,112 -66.6,112 -66.5,112 -66.4,112 -66.3,112 -66.2,112 -66.1,112 -66))"], "date_created": "Thu, 24 Oct 2024 00:00:00 GMT", "description": "This is a data set containing measurements of [14CO] in firn air and ice core samples from Law Dome DE08-OH site, Antarctica. The firn air and ice core samples were collected at Law Dome in December 2018 and January 2019. The [14CO] data represent atmospheric values (with the in situ cosmogenic and procedural components removed). [14CO] measurements were conducted as described in Hmiel et al., 2024 (https://doi.org/10.5194/tc-18-3363-2024). The in situ cosmogenic [14CO] contribution was calculated using parameters and model also described in Hmiel et al. (2024). As [14CO] measurements in ice cores are complex, use of the data in a publication requires contacting Vasilii Petrenko (vasilii.petrenko@rochester.edu) to ensure correct understanding of the data. Depending on nature of use of the data, co-authorship may be appropriate. ", "east": 114.0, "geometry": ["POINT(113 -66.5)"], "keywords": "Antarctica; Carbon-14; Cryosphere; Firn Air; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Law Dome; Snow/ice; Snow/Ice", "locations": "Antarctica; Law Dome", "north": -66.0, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Petrenko, Vasilii", "project_titles": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability", "projects": [{"proj_uid": "p0010341", "repository": "USAP-DC", "title": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -67.0, "title": "Law Dome firn air and ice core 14CO concentration", "uid": "601846", "west": 112.0}, {"awards": "1643716 Buizert, Christo", "bounds_geometry": ["POLYGON((-180 -67,-144 -67,-108 -67,-72 -67,-36 -67,0 -67,36 -67,72 -67,108 -67,144 -67,180 -67,180 -69.3,180 -71.6,180 -73.9,180 -76.2,180 -78.5,180 -80.8,180 -83.1,180 -85.4,180 -87.7,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.7,-180 -85.4,-180 -83.1,-180 -80.8,-180 -78.5,-180 -76.2,-180 -73.9,-180 -71.6,-180 -69.3,-180 -67))"], "date_created": "Mon, 22 May 2023 00:00:00 GMT", "description": "We have reconstructed the atmospheric N2O mole fraction and its isotopic composition by combining data from ice cores, firn air, and atmospheric samples. The mole fraction reconstruction extends back to 1000 CE using ice cores, firn air, and atmospheric sampling; and the isotopic reconstruction extends back to 1900 CE using only firn air data. We have incorporated both newly measured and previously published data. We present new data for the mole fraction, d15Nbulk, d18O, and d15NSP values from the Styx (East Antarctica) firn air, and mole fraction from the North Greenland Eemian Ice drilling Project (NEEM) firn air. We have used published records from the Styx and NEEM ice cores, direct atmospheric measurements from the NOAA global sampling network, and firn air data, giving a total of 11 sites for N2O mole fraction, 12 sites for d15Nbulk, 11 sites for d18O, and 8 sites for d15NSP values.\r\n", "east": 180.0, "geometry": ["POINT(0 -89.999)"], "keywords": "Antarctic; Antarctica; Anthropogenic Emission; Atmosphere; Greenhouse Gas; Greenland; Ice Core Data; Nitrification And Denitrification Processes; Nitrous Oxide; Site-Specific 15N Isotopomer; Styx Glacier", "locations": "Antarctic; Greenland; Antarctica; Styx Glacier", "north": -67.0, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Ghosh, Sambit; Toyoda, Sakae ; Buizert, Christo ; Langenfelds, Ray L ; Yoshida, Naohiro ; Joong Kim, Seong; Ahn, Jinho ; Etheridge, David", "project_titles": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability", "projects": [{"proj_uid": "p0010341", "repository": "USAP-DC", "title": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Concentration and isotopic composition of atmospheric N2O over the last century", "uid": "601693", "west": -180.0}, {"awards": "1643664 Severinghaus, Jeffrey", "bounds_geometry": null, "date_created": "Tue, 16 Aug 2022 00:00:00 GMT", "description": "This data set comprises measurements of noble and inert gases in the firn at the DE08-OH site sampled in 2018-2019 near the summit of Law Dome, Antarctica. The data show the expected gravitational enrichment of heavy isotopes with depth, somewhat attenuated by the high accumulation rate and a near-surface well-mixed zone (convective zone), and the \"lock-in\" horizon at 68 m depth. As seen at many other sites, the heavy isotope of oxygen 18O is depleted progressively with depth within the lock-in zone due to faster gas permeation of 16O16O relative to 18O16O from compressed air bubbles.", "east": null, "geometry": null, "keywords": "Antarctica; Firn; Firn Density; Gravitational Settling; Inert Gases; Law Dome", "locations": "Law Dome; Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Severinghaus, Jeffrey P.", "project_titles": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability", "projects": [{"proj_uid": "p0010341", "repository": "USAP-DC", "title": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2", "uid": "601598", "west": null}, {"awards": "0440602 Saltzman, Eric; 0338359 Saltzman, Eric", "bounds_geometry": null, "date_created": "Fri, 10 Jul 2020 00:00:00 GMT", "description": "This is a data set of ice core carbonyl sulfide data. Carbonyl sulfide was analyzed in air extracted from the SPRESSO ice core at 106 discrete depths as indicated in the data file. SPRESSO is a shallow, dry-drilled ice core from the South Pole. ", "east": null, "geometry": null, "keywords": "Antarctica; Atmospheric Gases; Gas Measurement; Ice Core; Ice Core Gas Records; Trace Gases", "locations": "Antarctica; Antarctica", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "persons": "Aydin, Murat; Saltzman, Eric", "project_titles": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site; Methyl chloride and methyl bromide in Antarctic ice cores", "projects": [{"proj_uid": "p0000368", "repository": "USAP-DC", "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site"}, {"proj_uid": "p0000032", "repository": "USAP-DC", "title": "Methyl chloride and methyl bromide in Antarctic ice cores"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core", "uid": "601357", "west": null}, {"awards": "1907974 Saltzman, Eric", "bounds_geometry": ["POLYGON((129.26 -89.86,130.261 -89.86,131.262 -89.86,132.263 -89.86,133.264 -89.86,134.265 -89.86,135.266 -89.86,136.267 -89.86,137.268 -89.86,138.269 -89.86,139.27 -89.86,139.27 -89.861,139.27 -89.862,139.27 -89.863,139.27 -89.864,139.27 -89.865,139.27 -89.866,139.27 -89.867,139.27 -89.868,139.27 -89.869,139.27 -89.87,138.269 -89.87,137.268 -89.87,136.267 -89.87,135.266 -89.87,134.265 -89.87,133.264 -89.87,132.263 -89.87,131.262 -89.87,130.261 -89.87,129.26 -89.87,129.26 -89.869,129.26 -89.868,129.26 -89.867,129.26 -89.866,129.26 -89.865,129.26 -89.864,129.26 -89.863,129.26 -89.862,129.26 -89.861,129.26 -89.86))"], "date_created": "Tue, 09 Jun 2020 00:00:00 GMT", "description": "This data set contains measurements of molecular hydrogen (H2) in firn air samples collected at South Pole in 2001.", "east": 139.27, "geometry": ["POINT(134.265 -89.865)"], "keywords": "Antarctica; Firn; Glaciology; Hydrogen; Ice Core Records; Snow/ice; Snow/Ice; South Pole", "locations": "South Pole; Antarctica", "north": -89.86, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Saltzman, Eric", "project_titles": "EAGER: Feasibility of Reconstructing the Atmospheric History of Molecular Hydrogen from Antarctic Ice", "projects": [{"proj_uid": "p0010106", "repository": "USAP-DC", "title": "EAGER: Feasibility of Reconstructing the Atmospheric History of Molecular Hydrogen from Antarctic Ice"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -89.87, "title": "H2 in South Pole firn air", "uid": "601332", "west": 129.26}, {"awards": "0440701 Severinghaus, Jeffrey", "bounds_geometry": ["POINT(-112.125 -79.463)"], "date_created": "Mon, 08 Jun 2015 00:00:00 GMT", "description": "This data set shows the modeled surface temperature reconstruction from an inversion of the 300 m WDC05A borehole at the West Antarctic Divide Ice core site.", "east": -112.125, "geometry": ["POINT(-112.125 -79.463)"], "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS Divide; WAIS Divide Ice Core", "locations": "WAIS Divide; Antarctica", "north": -79.463, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Severinghaus, Jeffrey P.; Orsi, Anais J.", "project_titles": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "projects": [{"proj_uid": "p0000368", "repository": "USAP-DC", "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -79.463, "title": "Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A", "uid": "609638", "west": -112.125}, {"awards": "0739598 Aydin, Murat", "bounds_geometry": ["POINT(112.09 -79.47)", "POINT(-38.3833 72.5833)", "POINT(0 -90)"], "date_created": "Wed, 30 Nov 2011 00:00:00 GMT", "description": "This data set contains ethane, propane, and n-butane measurements in firn air from the South Pole and the West Antarctic Ice Sheet (WAIS) Divide in Antarctica, and from Summit, Greenland. The WAIS Divide and South Pole samples were collected in December to January of of 2005/06 and 2008/09, respectively. The Summit firn was sampled in the summer of 2006. Analyses were conducted on a gas chromatography - mass spectrometry (GC-MS) system at the University of California, Irvine. Measurements and the associated uncertainties are reported as dry air molar mixing ratios in part per trillion (ppt). The reported measurements for each sampling depth represent a mean of multiple measurements on more than one flask in most cases.\n\nData are available via FTP in Microsoft Excel (.xls) format.", "east": 112.09, "geometry": ["POINT(112.09 -79.47)", "POINT(-38.3833 72.5833)", "POINT(0 -90)"], "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Snow/ice; Snow/Ice; South Pole; WAIS Divide", "locations": "Arctic; WAIS Divide; South Pole; Greenland; Antarctica", "north": 72.5833, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Aydin, Murat; Saltzman, Eric", "project_titles": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air", "projects": [{"proj_uid": "p0000162", "repository": "USAP-DC", "title": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Alkanes in Firn Air Samples, Antarctica and Greenland", "uid": "609504", "west": -38.3833}, {"awards": "0739780 Taylor, Kendrick; 0538578 Brook, Edward J.; 0520523 Brook, Edward J.; 0538538 Sowers, Todd; 0538427 McConnell, Joseph", "bounds_geometry": ["POINT(112.09 -79.47)"], "date_created": "Fri, 27 May 2011 00:00:00 GMT", "description": "This data set provides a high-precision and high-resolution record of atmospheric methane from the West Antarctic Ice Sheet (WAIS) Divide ice core WDC05A, spanning the years 1000 to 1800 C.E. The data include methane (CH4) concentration measurements and ice age chronology. Methane concentration data include mean sample depth, gas age, mean concentration, and concentrations from individual measurements, at a temporal resolution of approximately nine years. Ice chronology data include depth and ice age.\n\nData are available via FTP, in Microsoft Excel (.xlsx) format.", "east": 112.09, "geometry": ["POINT(112.09 -79.47)"], "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "locations": "WAIS Divide; Antarctica", "north": -79.47, "nsf_funding_programs": "Antarctic Glaciology", "persons": "McConnell, Joseph; Brook, Edward J.; Mitchell, Logan E; Sowers, Todd A.; Taylor, Kendrick C.", "project_titles": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "projects": [{"proj_uid": "p0000368", "repository": "USAP-DC", "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.47, "title": "Methane Concentration and Chronology from the WAIS Divide Ice Core (WDC05A)", "uid": "609493", "west": 112.09}, {"awards": "0739491 Sowers, Todd", "bounds_geometry": ["POLYGON((-180 90,-144 90,-108 90,-72 90,-36 90,0 90,36 90,72 90,108 90,144 90,180 90,180 72,180 54,180 36,180 18,180 0,180 -18,180 -36,180 -54,180 -72,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -72,-180 -54,-180 -36,-180 -18,-180 0,-180 18,-180 36,-180 54,-180 72,-180 90))"], "date_created": "Sat, 01 Jan 2011 00:00:00 GMT", "description": "This data set contains depth profiles for delta carbon-13 (\u0026#948;13C) and delta deuterium (\u0026#948;D) of methane (CH\u003csub\u003e4\u003c/sub\u003e) in South Pole firn air. The investigators obtained air samples from two boreholes during December 2008 and January 2009, and subsequently determined isotope ratios at 18 depths. The profiles represent a roughly 100-year history of the isotopic composition of CH\u003csub\u003e4\u003c/sub\u003e at South Pole Station (no depth-age model provided).\n\nData are available via FTP as an ASCII text file (.txt) and a Microsoft Excel file (.xlsx).", "east": 180.0, "geometry": ["POINT(0 -89.999)"], "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Isotope; Paleoclimate; Snow/ice; Snow/Ice; South Pole", "locations": "Antarctica; South Pole", "north": 90.0, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Sowers, Todd A.", "project_titles": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air", "projects": [{"proj_uid": "p0000162", "repository": "USAP-DC", "title": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Methane Isotopes in South Pole Firn Air, 2008", "uid": "609502", "west": -180.0}, {"awards": "0440759 Sowers, Todd", "bounds_geometry": ["POINT(112.09 -79.47)"], "date_created": "Tue, 01 Dec 2009 00:00:00 GMT", "description": "This data set includes methane (CH4) isotope data from the West Antarctic Ice Sheet (WAIS) Divide ice core, WDC05A, in Antarctica. The data include depth, gas age, and the isotopic composition of methane (\u0026#8706;13C and \u0026#8706;D of CH4). The ice core was collected during the 2005-2006 Antarctic field season. The CH4 isotope data was generated in 2008 using wet extraction methodology. Samples span the last 1,000 years, at a resolution of about 15 years. Data for samples above 69 meters were from firn air, and data below 69 meters from ice. The dating of the ice was based on continuous chemical analyses above 69 meters and Electrical Conductivity/Dielectric Property (ECM/DEP) measurements from ice. Dating uncertainty is estimated to be better than five years.\n\nData are available via FTP in Microsoft Excel (.xls) tab delimited format", "east": 112.09, "geometry": ["POINT(112.09 -79.47)"], "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Isotope; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "locations": "Antarctica; WAIS Divide", "north": -79.47, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Sowers, Todd A.", "project_titles": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "projects": [{"proj_uid": "p0000368", "repository": "USAP-DC", "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.47, "title": "Methane Isotopes from the WAIS Divide Ice Core", "uid": "609435", "west": 112.09}, {"awards": "0440602 Saltzman, Eric", "bounds_geometry": ["POINT(112.09 -79.47)"], "date_created": "Thu, 30 Jul 2009 00:00:00 GMT", "description": "This data set contains trace gas measurements of air extracted from ice core samples from the West Antarctic Ice Sheet Divide A core (WAIS-D 05A). The WAIS A core was dry-drilled at the WAIS site during the 2005-2006 Antarctic field season. Data include trace gas species including ethane (C2H6), propane (C3H8), n-butane (n-C4H10), carbonyl sulfide (COS), carbon disulfide (CS2), methyl chloride (CH3Cl), methyl bromide (CH3Br), acetonitrile (CH3CN), and chlorofluorocarbon-12 (CFC-12), for 57 ice core samples. The data are available via FTP in Microsoft Excel (.xls) file format.", "east": 112.09, "geometry": ["POINT(112.09 -79.47)"], "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core", "locations": "WAIS Divide; Antarctica", "north": -79.47, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Saltzman, Eric", "project_titles": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site", "projects": [{"proj_uid": "p0000368", "repository": "USAP-DC", "title": "Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.47, "title": "Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica", "uid": "609412", "west": 112.09}, {"awards": "9526556 Sowers, Todd", "bounds_geometry": ["POINT(-148.3023 -81.403)"], "date_created": "Mon, 09 Jul 2007 00:00:00 GMT", "description": "This data set includes records of the delta carbon-13 (\u0026delta;\u003csup\u003e13\u003c/sup\u003eC) of methane (CH\u003csub\u003e4\u003c/sub\u003e) in firn air from the South Pole and trapped in bubbles in a short ice core from Siple Dome, Antarctica. Using two firn air samples, one from January 1995 and the other from January 2001, investigators reconstructed records of the isotopic composition of paleoatmospheric methane covering the last 2 centuries, from 1820 to 2001. \n\nData are in Microsoft Excel and Microsoft Word formats and are available via FTP.", "east": -148.3023, "geometry": ["POINT(-148.3023 -81.403)"], "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Siple Dome; Snow/ice; Snow/Ice; South Pole", "locations": "South Pole; Antarctica; Siple Dome", "north": -81.403, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Sowers, Todd A.", "project_titles": "Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide", "projects": [{"proj_uid": "p0000611", "repository": "USAP-DC", "title": "Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -81.403, "title": "Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica", "uid": "609310", "west": -148.3023}, {"awards": "9725305 Severinghaus, Jeffrey; 0230260 Bender, Michael; 0230452 Severinghaus, Jeffrey", "bounds_geometry": ["POINT(-148.767 -80.667)", "POINT(0 -90)"], "date_created": "Thu, 17 Aug 2006 00:00:00 GMT", "description": "This data set includes gas ratios in polar firn air: O\u003csub\u003e2\u003c/sub\u003e/N\u003csub\u003e2\u003c/sub\u003e, \u003csup\u003e15\u003c/sup\u003eN/\u003csup\u003e14\u003c/sup\u003eN, \u003csup\u003e40\u003c/sup\u003eAr/N\u003csub\u003e2\u003c/sub\u003e, \u003csup\u003e40\u003c/sup\u003eAr/\u003csup\u003e36\u003c/sup\u003eAr, \u003csup\u003e40\u003c/sup\u003eAr/\u003csup\u003e38\u003c/sup\u003eAr, \u003csup\u003e84\u003c/sup\u003eKr/\u003csup\u003e36\u003c/sup\u003eAr, \u003csup\u003e132\u003c/sup\u003eXe/\u003csup\u003e36\u003c/sup\u003eAr, and \u003csup\u003e22\u003c/sup\u003eNe/\u003csup\u003e36\u003c/sup\u003eAr. Investigators sampled air from the permeable snowpack (firn) layer at two sites: Siple Dome, Antarctica in 1996 and at the South Pole in 2001. They observed and modeled the processes of gravitational settling, thermal fractionation, and preferential exclusion of small gas molecules from closed air bubbles. The purpose of this study was to understand these physical processes, which affect the composition of bubbles trapped in ice. By measuring these gas ratios in the ancient air preserved in bubbles trapped in ice, researchers can determine past atmospheric composition and local temperature changes along with the relative timing and magnitude of such events.\n\nThe data file is available in Microsoft Excel format. The research paper is available in PDF. Data and the research paper are available via FTP.", "east": 0.0, "geometry": ["POINT(-148.767 -80.667)", "POINT(0 -90)"], "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciology; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole", "locations": "South Pole; Siple Dome; Antarctica", "north": -80.667, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Severinghaus, Jeffrey P.; Battle, Mark; Bender, Michael", "project_titles": "Collaborative Research: Trapped Gas Composition and the Chronology of the Vostok Ice Core", "projects": [{"proj_uid": "p0000257", "repository": "USAP-DC", "title": "Collaborative Research: Trapped Gas Composition and the Chronology of the Vostok Ice Core"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -90.0, "title": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001", "uid": "609290", "west": -148.767}, {"awards": "9725918 Brook, Edward J.; 9725305 Severinghaus, Jeffrey", "bounds_geometry": ["POINT(-102 -89.997)", "POINT(-148.767 -81.667)"], "date_created": "Mon, 01 Jan 2001 00:00:00 GMT", "description": "This data set includes d15N, d18O/2, dO2/N2/4, d40Ar/4, d38/Ar/2,\nd84Kr/48, and d132Xe/96 values for air drawn from the top 15 to 50 m\nof firn at the South Pole (summer and winter 1998) and a site at Siple\nDome (summers 1996 and 1998). Data also include related firn\ntemperature measurements.\n\nThe objective of this research was to better understand thermal\nfractionation processes affecting records of atmospheric history from\nfirn and ice core gases. Recent work (e.g., Severinghaus and Brook,\n1999) has exploited trapped air in ice and deep firn as a record of\npast atmospheric composition and climate change. Interpretation of these paleoclimate archives is complicated by artifacts of thermal\ndiffusion, a process in which heavier gases migrate down temperature\ngradients toward colder regions in the firn. Seasonal temperature\nchange at the snow surface creates strong temperature gradients in the\ntop few meters of the firn, which cause isotopic fractionation of firn\ngases. A specific goal of this research is to identify any long-term\neffects of seasonal temperature fluctuations on firn air isotopic\nanomalies.", "east": -102.0, "geometry": ["POINT(-102 -89.997)", "POINT(-148.767 -81.667)"], "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciology; Isotope; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole; Temperature", "locations": "Siple Dome; Antarctica; South Pole", "north": -81.667, "nsf_funding_programs": "Antarctic Glaciology", "persons": "Severinghaus, Jeffrey P.; Battle, Mark; Grachev, Alexi", "project_titles": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change", "projects": [{"proj_uid": "p0000160", "repository": "USAP-DC", "title": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change"}], "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -89.997, "title": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "uid": "609098", "west": -148.767}]
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Dataset Title/Abstract/Map | NSF Award(s) | Date Created | PIs / Scientists | Project Links | Abstract | Bounds Geometry | Geometry | Selected | Visible |
---|---|---|---|---|---|---|---|---|---|
Law Dome firn air and ice core 14CO concentration
|
1643669 |
2024-10-24 | Petrenko, Vasilii |
Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability |
This is a data set containing measurements of [14CO] in firn air and ice core samples from Law Dome DE08-OH site, Antarctica. The firn air and ice core samples were collected at Law Dome in December 2018 and January 2019. The [14CO] data represent atmospheric values (with the in situ cosmogenic and procedural components removed). [14CO] measurements were conducted as described in Hmiel et al., 2024 (https://doi.org/10.5194/tc-18-3363-2024). The in situ cosmogenic [14CO] contribution was calculated using parameters and model also described in Hmiel et al. (2024). As [14CO] measurements in ice cores are complex, use of the data in a publication requires contacting Vasilii Petrenko (vasilii.petrenko@rochester.edu) to ensure correct understanding of the data. Depending on nature of use of the data, co-authorship may be appropriate. | ["POLYGON((112 -66,112.2 -66,112.4 -66,112.6 -66,112.8 -66,113 -66,113.2 -66,113.4 -66,113.6 -66,113.8 -66,114 -66,114 -66.1,114 -66.2,114 -66.3,114 -66.4,114 -66.5,114 -66.6,114 -66.7,114 -66.8,114 -66.9,114 -67,113.8 -67,113.6 -67,113.4 -67,113.2 -67,113 -67,112.8 -67,112.6 -67,112.4 -67,112.2 -67,112 -67,112 -66.9,112 -66.8,112 -66.7,112 -66.6,112 -66.5,112 -66.4,112 -66.3,112 -66.2,112 -66.1,112 -66))"] | ["POINT(113 -66.5)"] | false | false |
Concentration and isotopic composition of atmospheric N2O over the last century
|
1643716 |
2023-05-22 | Ghosh, Sambit; Toyoda, Sakae ; Buizert, Christo ; Langenfelds, Ray L ; Yoshida, Naohiro ; Joong Kim, Seong; Ahn, Jinho ; Etheridge, David |
Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability |
We have reconstructed the atmospheric N2O mole fraction and its isotopic composition by combining data from ice cores, firn air, and atmospheric samples. The mole fraction reconstruction extends back to 1000 CE using ice cores, firn air, and atmospheric sampling; and the isotopic reconstruction extends back to 1900 CE using only firn air data. We have incorporated both newly measured and previously published data. We present new data for the mole fraction, d15Nbulk, d18O, and d15NSP values from the Styx (East Antarctica) firn air, and mole fraction from the North Greenland Eemian Ice drilling Project (NEEM) firn air. We have used published records from the Styx and NEEM ice cores, direct atmospheric measurements from the NOAA global sampling network, and firn air data, giving a total of 11 sites for N2O mole fraction, 12 sites for d15Nbulk, 11 sites for d18O, and 8 sites for d15NSP values. | ["POLYGON((-180 -67,-144 -67,-108 -67,-72 -67,-36 -67,0 -67,36 -67,72 -67,108 -67,144 -67,180 -67,180 -69.3,180 -71.6,180 -73.9,180 -76.2,180 -78.5,180 -80.8,180 -83.1,180 -85.4,180 -87.7,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87.7,-180 -85.4,-180 -83.1,-180 -80.8,-180 -78.5,-180 -76.2,-180 -73.9,-180 -71.6,-180 -69.3,-180 -67))"] | ["POINT(0 -89.999)"] | false | false |
Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2
|
1643664 |
2022-08-16 | Severinghaus, Jeffrey P. |
Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability |
This data set comprises measurements of noble and inert gases in the firn at the DE08-OH site sampled in 2018-2019 near the summit of Law Dome, Antarctica. The data show the expected gravitational enrichment of heavy isotopes with depth, somewhat attenuated by the high accumulation rate and a near-surface well-mixed zone (convective zone), and the "lock-in" horizon at 68 m depth. As seen at many other sites, the heavy isotope of oxygen 18O is depleted progressively with depth within the lock-in zone due to faster gas permeation of 16O16O relative to 18O16O from compressed air bubbles. | [] | [] | false | false |
Ice Core Air Carbonyl Sulfide Measurements - SPRESSO Ice Core
|
0440602 0338359 |
2020-07-10 | Aydin, Murat; Saltzman, Eric |
Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site Methyl chloride and methyl bromide in Antarctic ice cores |
This is a data set of ice core carbonyl sulfide data. Carbonyl sulfide was analyzed in air extracted from the SPRESSO ice core at 106 discrete depths as indicated in the data file. SPRESSO is a shallow, dry-drilled ice core from the South Pole. | [] | [] | false | false |
H2 in South Pole firn air
|
1907974 |
2020-06-09 | Saltzman, Eric |
EAGER: Feasibility of Reconstructing the Atmospheric History of Molecular Hydrogen from Antarctic Ice |
This data set contains measurements of molecular hydrogen (H2) in firn air samples collected at South Pole in 2001. | ["POLYGON((129.26 -89.86,130.261 -89.86,131.262 -89.86,132.263 -89.86,133.264 -89.86,134.265 -89.86,135.266 -89.86,136.267 -89.86,137.268 -89.86,138.269 -89.86,139.27 -89.86,139.27 -89.861,139.27 -89.862,139.27 -89.863,139.27 -89.864,139.27 -89.865,139.27 -89.866,139.27 -89.867,139.27 -89.868,139.27 -89.869,139.27 -89.87,138.269 -89.87,137.268 -89.87,136.267 -89.87,135.266 -89.87,134.265 -89.87,133.264 -89.87,132.263 -89.87,131.262 -89.87,130.261 -89.87,129.26 -89.87,129.26 -89.869,129.26 -89.868,129.26 -89.867,129.26 -89.866,129.26 -89.865,129.26 -89.864,129.26 -89.863,129.26 -89.862,129.26 -89.861,129.26 -89.86))"] | ["POINT(134.265 -89.865)"] | false | false |
Surface Temperature Reconstruction from Borehole Temperature Measurement in WDC05A
|
0440701 |
2015-06-08 | Severinghaus, Jeffrey P.; Orsi, Anais J. |
Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site |
This data set shows the modeled surface temperature reconstruction from an inversion of the 300 m WDC05A borehole at the West Antarctic Divide Ice core site. | ["POINT(-112.125 -79.463)"] | ["POINT(-112.125 -79.463)"] | false | false |
Alkanes in Firn Air Samples, Antarctica and Greenland
|
0739598 |
2011-11-30 | Aydin, Murat; Saltzman, Eric |
Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air |
This data set contains ethane, propane, and n-butane measurements in firn air from the South Pole and the West Antarctic Ice Sheet (WAIS) Divide in Antarctica, and from Summit, Greenland. The WAIS Divide and South Pole samples were collected in December to January of of 2005/06 and 2008/09, respectively. The Summit firn was sampled in the summer of 2006. Analyses were conducted on a gas chromatography - mass spectrometry (GC-MS) system at the University of California, Irvine. Measurements and the associated uncertainties are reported as dry air molar mixing ratios in part per trillion (ppt). The reported measurements for each sampling depth represent a mean of multiple measurements on more than one flask in most cases. Data are available via FTP in Microsoft Excel (.xls) format. | ["POINT(112.09 -79.47)", "POINT(-38.3833 72.5833)", "POINT(0 -90)"] | ["POINT(112.09 -79.47)", "POINT(-38.3833 72.5833)", "POINT(0 -90)"] | false | false |
Methane Concentration and Chronology from the WAIS Divide Ice Core (WDC05A)
|
0739780 0538578 0520523 0538538 0538427 |
2011-05-27 | McConnell, Joseph; Brook, Edward J.; Mitchell, Logan E; Sowers, Todd A.; Taylor, Kendrick C. |
Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site |
This data set provides a high-precision and high-resolution record of atmospheric methane from the West Antarctic Ice Sheet (WAIS) Divide ice core WDC05A, spanning the years 1000 to 1800 C.E. The data include methane (CH4) concentration measurements and ice age chronology. Methane concentration data include mean sample depth, gas age, mean concentration, and concentrations from individual measurements, at a temporal resolution of approximately nine years. Ice chronology data include depth and ice age. Data are available via FTP, in Microsoft Excel (.xlsx) format. | ["POINT(112.09 -79.47)"] | ["POINT(112.09 -79.47)"] | false | false |
Methane Isotopes in South Pole Firn Air, 2008
|
0739491 |
2011-01-01 | Sowers, Todd A. |
Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air |
This data set contains depth profiles for delta carbon-13 (δ13C) and delta deuterium (δD) of methane (CH<sub>4</sub>) in South Pole firn air. The investigators obtained air samples from two boreholes during December 2008 and January 2009, and subsequently determined isotope ratios at 18 depths. The profiles represent a roughly 100-year history of the isotopic composition of CH<sub>4</sub> at South Pole Station (no depth-age model provided). Data are available via FTP as an ASCII text file (.txt) and a Microsoft Excel file (.xlsx). | ["POLYGON((-180 90,-144 90,-108 90,-72 90,-36 90,0 90,36 90,72 90,108 90,144 90,180 90,180 72,180 54,180 36,180 18,180 0,180 -18,180 -36,180 -54,180 -72,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -72,-180 -54,-180 -36,-180 -18,-180 0,-180 18,-180 36,-180 54,-180 72,-180 90))"] | ["POINT(0 -89.999)"] | false | false |
Methane Isotopes from the WAIS Divide Ice Core
|
0440759 |
2009-12-01 | Sowers, Todd A. |
Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site |
This data set includes methane (CH4) isotope data from the West Antarctic Ice Sheet (WAIS) Divide ice core, WDC05A, in Antarctica. The data include depth, gas age, and the isotopic composition of methane (∂13C and ∂D of CH4). The ice core was collected during the 2005-2006 Antarctic field season. The CH4 isotope data was generated in 2008 using wet extraction methodology. Samples span the last 1,000 years, at a resolution of about 15 years. Data for samples above 69 meters were from firn air, and data below 69 meters from ice. The dating of the ice was based on continuous chemical analyses above 69 meters and Electrical Conductivity/Dielectric Property (ECM/DEP) measurements from ice. Dating uncertainty is estimated to be better than five years. Data are available via FTP in Microsoft Excel (.xls) tab delimited format | ["POINT(112.09 -79.47)"] | ["POINT(112.09 -79.47)"] | false | false |
Gases in Firn Air and Shallow Ice at the WAIS Drilling Site, Antarctica
|
0440602 |
2009-07-30 | Saltzman, Eric |
Collaborative Research: Gases in Firn Air and Shallow Ice at the Proposed WAIS Divide Drilling Site |
This data set contains trace gas measurements of air extracted from ice core samples from the West Antarctic Ice Sheet Divide A core (WAIS-D 05A). The WAIS A core was dry-drilled at the WAIS site during the 2005-2006 Antarctic field season. Data include trace gas species including ethane (C2H6), propane (C3H8), n-butane (n-C4H10), carbonyl sulfide (COS), carbon disulfide (CS2), methyl chloride (CH3Cl), methyl bromide (CH3Br), acetonitrile (CH3CN), and chlorofluorocarbon-12 (CFC-12), for 57 ice core samples. The data are available via FTP in Microsoft Excel (.xls) file format. | ["POINT(112.09 -79.47)"] | ["POINT(112.09 -79.47)"] | false | false |
Carbon-13 Isotopic Composition of Atmospheric Methane in Firn Air, South Pole and Siple Dome, Antarctica
|
9526556 |
2007-07-09 | Sowers, Todd A. |
Constructing Paleoatmospheric Records of the Isotopic Composition of Methane and Nitrous Oxide |
This data set includes records of the delta carbon-13 (δ<sup>13</sup>C) of methane (CH<sub>4</sub>) in firn air from the South Pole and trapped in bubbles in a short ice core from Siple Dome, Antarctica. Using two firn air samples, one from January 1995 and the other from January 2001, investigators reconstructed records of the isotopic composition of paleoatmospheric methane covering the last 2 centuries, from 1820 to 2001. Data are in Microsoft Excel and Microsoft Word formats and are available via FTP. | ["POINT(-148.3023 -81.403)"] | ["POINT(-148.3023 -81.403)"] | false | false |
Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001
|
9725305 0230260 0230452 |
2006-08-17 | Severinghaus, Jeffrey P.; Battle, Mark; Bender, Michael |
Collaborative Research: Trapped Gas Composition and the Chronology of the Vostok Ice Core |
This data set includes gas ratios in polar firn air: O<sub>2</sub>/N<sub>2</sub>, <sup>15</sup>N/<sup>14</sup>N, <sup>40</sup>Ar/N<sub>2</sub>, <sup>40</sup>Ar/<sup>36</sup>Ar, <sup>40</sup>Ar/<sup>38</sup>Ar, <sup>84</sup>Kr/<sup>36</sup>Ar, <sup>132</sup>Xe/<sup>36</sup>Ar, and <sup>22</sup>Ne/<sup>36</sup>Ar. Investigators sampled air from the permeable snowpack (firn) layer at two sites: Siple Dome, Antarctica in 1996 and at the South Pole in 2001. They observed and modeled the processes of gravitational settling, thermal fractionation, and preferential exclusion of small gas molecules from closed air bubbles. The purpose of this study was to understand these physical processes, which affect the composition of bubbles trapped in ice. By measuring these gas ratios in the ancient air preserved in bubbles trapped in ice, researchers can determine past atmospheric composition and local temperature changes along with the relative timing and magnitude of such events. The data file is available in Microsoft Excel format. The research paper is available in PDF. Data and the research paper are available via FTP. | ["POINT(-148.767 -80.667)", "POINT(0 -90)"] | ["POINT(-148.767 -80.667)", "POINT(0 -90)"] | false | false |
Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole
|
9725918 9725305 |
2001-01-01 | Severinghaus, Jeffrey P.; Battle, Mark; Grachev, Alexi |
Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change |
This data set includes d15N, d18O/2, dO2/N2/4, d40Ar/4, d38/Ar/2, d84Kr/48, and d132Xe/96 values for air drawn from the top 15 to 50 m of firn at the South Pole (summer and winter 1998) and a site at Siple Dome (summers 1996 and 1998). Data also include related firn temperature measurements. The objective of this research was to better understand thermal fractionation processes affecting records of atmospheric history from firn and ice core gases. Recent work (e.g., Severinghaus and Brook, 1999) has exploited trapped air in ice and deep firn as a record of past atmospheric composition and climate change. Interpretation of these paleoclimate archives is complicated by artifacts of thermal diffusion, a process in which heavier gases migrate down temperature gradients toward colder regions in the firn. Seasonal temperature change at the snow surface creates strong temperature gradients in the top few meters of the firn, which cause isotopic fractionation of firn gases. A specific goal of this research is to identify any long-term effects of seasonal temperature fluctuations on firn air isotopic anomalies. | ["POINT(-102 -89.997)", "POINT(-148.767 -81.667)"] | ["POINT(-102 -89.997)", "POINT(-148.767 -81.667)"] | false | false |