USAP-DC

{"dp_type": "Project", "free_text": "TRACE GASES/TRACE SPECIES"}

[{"awards": "1745078 Brook, Edward", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ; Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation; Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "datasets": [{"dataset_uid": "601736", "doi": "10.15784/601736", "keywords": "Antarctica; Greenland; Methane; Paleoclimate; West Antarctic Ice Sheet", "people": "Fischer, Hubertus; Blunier, Thomas; Schmitt, Jochen; M\u00fchl, Michaela; Edwards, Jon S.; Lee, James; Martin, Kaden; Buizert, Christo; Rosen, Julia; Brook, Edward; Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane interpolar difference and four-box troposphere model output across the Last Glacial Maximum and Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601736"}, {"dataset_uid": "601683", "doi": "10.15784/601683", "keywords": "Antarctica; Methane; West Antarctic Ice Sheet", "people": "Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Carbon-13 isotopic composition of atmospheric methane across Heinrich Stadials 1 and 5, and Dansgaard Oesgher Event 12, WAIS Divide Ice Core, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601683"}, {"dataset_uid": "601737", "doi": "10.15784/601737", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Ice Core Records; Methane; West Antarctic Ice Sheet", "people": "Lee, James; Edwards, Jon S.; Brook, Edward; Martin, Kaden; Rosen, Julia; Riddell-Young, Benjamin", "repository": "USAP-DC", "science_program": null, "title": "Atmospheric methane across the Last Glacial Maximum and deglaciation from the GISP2, NEEM and WAIS Divide ice cores ", "url": "https://www.usap-dc.org/view/dataset/601737"}], "date_created": "Mon, 01 May 2023 00:00:00 GMT", "description": "This project will develop methods to measure the ratios of carbon-13 to carbon-12, and heavy to light hydrogen in methane in air trapped in ice cores. The ratios of the different forms of carbon and hydrogen are \"fingerprints\" of different sources of this gas in the past--for example wetlands in the tropics versus methane frozen in the sea floor. Once the analysis method is developed, the measurements will be used to examine why methane changed abruptly in the past, both during the last ice age, and during previous warm periods. The data will be used to understand how methane sources like wildfires, methane hydrates, and wetlands respond to climate change. This information is needed to understand future risks of large changes in methane in the atmosphere as Earth warms. \u003cbr/\u003e\u003cbr/\u003eThe project involves two tasks. First, the investigators will build and test a gas extraction system for methane isotopic measurements using continuous flow methods, with the goal of equaling or bettering the precision attained by the few other laboratories that make these measurements. The system will be interfaced with existing mass spectrometers at Oregon State University. The system consists of a vacuum chamber and sequence of traps, purification columns, and furnaces that separate methane from other gases and convert it to carbon dioxide or hydrogen for mass spectrometry. Second, the team will measure the isotopic composition of methane across large changes in concentration associated with two past interglacial periods and during abrupt methane changes of the last ice age. These measurements will be used to understand if the main reason for these concentration changes is climate-driven changes in emissions from wetlands, or whether other sources are involved, for example methane hydrates or wildfires.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "Antarctic Ice Sheet; TRACE GASES/TRACE SPECIES; METHANE", "locations": "Antarctic Ice Sheet", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward", "platforms": null, "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Tracing Past Methane Variations with Stable Isotopes in Antarctic Ice Cores", "uid": "p0010416", "west": -180.0}, {"awards": "1543457 Munro, David; 1543511 Stephens, Britton", "bounds_geometry": "POLYGON((-73 -53,-71.2 -53,-69.4 -53,-67.6 -53,-65.8 -53,-64 -53,-62.2 -53,-60.4 -53,-58.6 -53,-56.8 -53,-55 -53,-55 -54.4,-55 -55.8,-55 -57.2,-55 -58.6,-55 -60,-55 -61.4,-55 -62.8,-55 -64.2,-55 -65.6,-55 -67,-56.8 -67,-58.6 -67,-60.4 -67,-62.2 -67,-64 -67,-65.8 -67,-67.6 -67,-69.4 -67,-71.2 -67,-73 -67,-73 -65.6,-73 -64.2,-73 -62.8,-73 -61.4,-73 -60,-73 -58.6,-73 -57.2,-73 -55.8,-73 -54.4,-73 -53))", "dataset_titles": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the Southern Ocean, Drake Passage and South Atlantic Ocean in 2018, processed by NOAA (NCEI Accession 0184338); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, Drake Passage, South Atlantic Ocean in 2022 (NCEI Accession 0276577); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Atlantic Ocean in 2021 (NCEI Accession 0246983); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean from 2019-02-16 to 2020-02-11 (NCEI Accession 0208838); Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean in 2020 (NCEI Accession 0225445); Underway measurements of pCO2 in the Surface Waters and the Atmosphere During the ARSV Laurence M. Gould 2017 Expeditions processed by NOAA (NCEI Accession 0170337)", "datasets": [{"dataset_uid": "200351", "doi": "https://doi.org/10.25921/z0pk-pv81", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean in 2020 (NCEI Accession 0225445)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200353", "doi": "https://doi.org/10.25921/fq0a-7y11", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, Drake Passage, South Atlantic Ocean in 2022 (NCEI Accession 0276577)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200352", "doi": "https://doi.org/10.25921/f94g-zp40", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Atlantic Ocean in 2021 (NCEI Accession 0246983)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200350", "doi": "https://doi.org/10.25921/3ysc-pm11", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the the Southern Ocean, South Pacific Ocean, Drake Passage and South Atlantic Ocean from 2019-02-16 to 2020-02-11 (NCEI Accession 0208838)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200349", "doi": "https://doi.org/10.25921/b4jn-ef56", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Surface underway measurements of partial pressure of carbon dioxide (pCO2) during the Antarctic Research and Supply Vessel (ARSV) Laurence M. Gould expeditions in the Southern Ocean, Drake Passage and South Atlantic Ocean in 2018, processed by NOAA (NCEI Accession 0184338)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}, {"dataset_uid": "200348", "doi": "https://doi.org/10.7289/v5tq5zt1", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Underway measurements of pCO2 in the Surface Waters and the Atmosphere During the ARSV Laurence M. Gould 2017 Expeditions processed by NOAA (NCEI Accession 0170337)", "url": "https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/LM_gould.html"}], "date_created": "Wed, 22 Feb 2023 00:00:00 GMT", "description": "The Southern Ocean plays a key role in modulating the global carbon cycle, but the size and even the sign of the flux of carbon dioxide between the ocean and atmosphere in this region is still uncertain. This is in part due to the lack of measurements in this remote region of the world ocean. This project continues a multi-year time series of shipboard chemical measurements in the Drake Passage to detect changes in the ocean carbon cycle and to improve the understanding of mechanisms driving natural variability and long-term change in the Southern Ocean. More specifically, this project is a continuation of the collection of underway upper ocean measurements of the surface partial pressure of carbon dioxide during crossings of the Drake Passage by the Antarctic Research and Supply Vessel Laurence M. Gould. This project also includes collection and analysis of discrete samples relevant to ocean carbon cycle studies including macronutrient concentrations, total carbon dioxide concentrations, and the carbon isotopic composition of total carbon dioxide. The Drake Passage data are made readily available to the international science community and serve as both validation and constraints of remotely sensed observations and numerical coupled earth systems models.", "east": -55.0, "geometry": "POINT(-64 -60)", "instruments": null, "is_usap_dc": true, "keywords": "Drake Passage; NUTRIENTS; BIOGEOCHEMICAL CYCLES; DISSOLVED GASES; TRACE GASES/TRACE SPECIES", "locations": "Drake Passage", "north": -53.0, "nsf_funding_programs": "Antarctic Ocean and Atmospheric Sciences; Antarctic Organisms and Ecosystems; Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Munro, David; Sweeney, Colm; Lovenduski, Nicole S; Stephens, Britton", "platforms": null, "repo": "NCEI", "repositories": "NCEI", "science_programs": null, "south": -67.0, "title": "Collaborative Research: Investigating Biogeochemical Fluxes and Linkages To Climate Change With Multi-Scale Observations In The Drake Passage", "uid": "p0010407", "west": -73.0}, {"awards": "1643664 Severinghaus, Jeffrey; 1643669 Petrenko, Vasilii; 1643716 Buizert, Christo", "bounds_geometry": "POLYGON((112 -66,112.2 -66,112.4 -66,112.6 -66,112.8 -66,113 -66,113.2 -66,113.4 -66,113.6 -66,113.8 -66,114 -66,114 -66.1,114 -66.2,114 -66.3,114 -66.4,114 -66.5,114 -66.6,114 -66.7,114 -66.8,114 -66.9,114 -67,113.8 -67,113.6 -67,113.4 -67,113.2 -67,113 -67,112.8 -67,112.6 -67,112.4 -67,112.2 -67,112 -67,112 -66.9,112 -66.8,112 -66.7,112 -66.6,112 -66.5,112 -66.4,112 -66.3,112 -66.2,112 -66.1,112 -66))", "dataset_titles": "Concentration and isotopic composition of atmospheric N2O over the last century; Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2; Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy", "datasets": [{"dataset_uid": "601597", "doi": "10.15784/601597", "keywords": "Antarctica; Ice Core; Law Dome; Noble Gas", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy", "url": "https://www.usap-dc.org/view/dataset/601597"}, {"dataset_uid": "601598", "doi": "10.15784/601598", "keywords": "Antarctica; Firn; Firn Density; Gravitational Settling; Inert Gases; Law Dome", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2", "url": "https://www.usap-dc.org/view/dataset/601598"}, {"dataset_uid": "601693", "doi": "10.15784/601693", "keywords": "Antarctic; Antarctica; Anthropogenic Emission; Atmosphere; Greenhouse Gas; Greenland; Ice Core Data; Nitrification And Denitrification Processes; Nitrous Oxide; Site-Specific 15N Isotopomer; Styx Glacier", "people": "Etheridge, David; Ahn, Jinho ; Joong Kim, Seong; Yoshida, Naohiro ; Langenfelds, Ray L ; Buizert, Christo ; Toyoda, Sakae ; Ghosh, Sambit", "repository": "USAP-DC", "science_program": null, "title": "Concentration and isotopic composition of atmospheric N2O over the last century", "url": "https://www.usap-dc.org/view/dataset/601693"}], "date_created": "Fri, 17 Jun 2022 00:00:00 GMT", "description": "Hydroxyl radicals are responsible for removal of most atmospheric trace gases, including pollutants and important greenhouse gases. They have been called the \"detergent of the atmosphere\". Changes in hydroxyl radical concentration in response to large changes in reactive trace gas emissions, which may happen in the future, are uncertain. This project aims to provide the first estimates of the variability of atmospheric hydroxyl radicals since about 1880 AD when anthropogenic emissions of reactive trace gases were minimal. This will improve understanding of their stability in response to large changes in emissions. The project will also investigate whether ice cores record past changes in Southern Hemisphere westerly winds. These winds are a key component of the global climate system, and have an important influence on ocean circulation and possibly on atmospheric carbon dioxide concentrations. The project team will include three early career scientists, a postdoctoral researcher, and graduate and undergraduate students, working in collaboration with senior scientists and Australian collaborators. \u003cbr/\u003e \u003cbr/\u003eFirn air and shallow ice to a depth of about 233 m will be sampled at the Law Dome high-accumulation coastal site in East Antarctica. Trapped air will be extracted from the ice cores on site immediately after drilling. Carbon-14 of carbon monoxide (14CO) will be analyzed in firn and ice-core air samples. Corrections will be made for the in situ cosmogenic 14CO component in the ice, allowing for the atmospheric 14CO history to be reconstructed. This 14CO history will be interpreted with the aid of a chemistry-transport model to place the first observational constraints on the variability of Southern Hemisphere hydroxyl radical concentration after about 1880 AD. An additional component of the project will analyze Krypton-86 in the firn-air and ice-core samples. These measurements will explore whether ice-core Krypton-86 acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere westerly winds.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 114.0, "geometry": "POINT(113 -66.5)", "instruments": null, "is_usap_dc": true, "keywords": "AMD; TRACE GASES/TRACE SPECIES; Law Dome; Amd/Us; USAP-DC; LABORATORY; ICE CORE AIR BUBBLES; USA/NSF", "locations": "Law Dome", "north": -66.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Murray, Lee T; Buizert, Christo; Petrenko, Vasilii; Murray, Lee T", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -67.0, "title": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability", "uid": "p0010341", "west": 112.0}, {"awards": "1443482 Mak, John", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Carbon monoxide mixing ratios and stable isotopic values, SPICE", "datasets": [{"dataset_uid": "601356", "doi": "10.15784/601356", "keywords": "Antarctica; CO; Delta 13C; Delta 18O; South Pole; SPICEcore", "people": "Mak, John", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Carbon monoxide mixing ratios and stable isotopic values, SPICE", "url": "https://www.usap-dc.org/view/dataset/601356"}], "date_created": "Thu, 09 Jul 2020 00:00:00 GMT", "description": "The investigators plan to reconstruct historical variations in the sources of atmospheric carbon monoxide (CO) from measurements of the concentration and stable isotopic abundance of carbon monoxide ([CO], 13CO and C18O) in the South Pole Ice Core, which is being drilled in 2014-2016. The goal is to strategically sample and reconstruct the relative variations in CO source strengths over the past 20,000 years. These will be the first measurements to extend the CO record beyond 650 years before present, back to the last glacial maximum. Both atmospheric chemical processes and variations in CO sources can impact the CO budget, and variations in the CO budget are useful in identifying and quantifying chemistry-climate interactions.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "LABORATORY; TRACE GASES/TRACE SPECIES; FIELD INVESTIGATION; South Pole", "locations": "South Pole", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Mak, John", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Using Stable Isotopes to Constrain the Atmospheric Carbon Monoxide Budget over the Last 20,000 Years", "uid": "p0010117", "west": -180.0}, {"awards": "1907974 Saltzman, Eric", "bounds_geometry": "POLYGON((129.26 -89.86,130.261 -89.86,131.262 -89.86,132.263 -89.86,133.264 -89.86,134.265 -89.86,135.266 -89.86,136.267 -89.86,137.268 -89.86,138.269 -89.86,139.27 -89.86,139.27 -89.861,139.27 -89.862,139.27 -89.863,139.27 -89.864,139.27 -89.865,139.27 -89.866,139.27 -89.867,139.27 -89.868,139.27 -89.869,139.27 -89.87,138.269 -89.87,137.268 -89.87,136.267 -89.87,135.266 -89.87,134.265 -89.87,133.264 -89.87,132.263 -89.87,131.262 -89.87,130.261 -89.87,129.26 -89.87,129.26 -89.869,129.26 -89.868,129.26 -89.867,129.26 -89.866,129.26 -89.865,129.26 -89.864,129.26 -89.863,129.26 -89.862,129.26 -89.861,129.26 -89.86))", "dataset_titles": "H2 in South Pole firn air", "datasets": [{"dataset_uid": "601332", "doi": "10.15784/601332", "keywords": "Antarctica; Firn; Glaciology; Hydrogen; Ice Core Records; Snow/ice; Snow/Ice; South Pole", "people": "Saltzman, Eric", "repository": "USAP-DC", "science_program": null, "title": "H2 in South Pole firn air", "url": "https://www.usap-dc.org/view/dataset/601332"}], "date_created": "Tue, 09 Jun 2020 00:00:00 GMT", "description": "Hydrogen (H2) is one of the most abundant trace gases in the atmosphere, with a mean level of 500 ppb and an atmospheric lifetime of about two years. Hydrogen has an impact on both air quality and climate, due to its role as a precursor for tropospheric ozone and stratospheric water vapor. Projections indicate that a future \"hydrogen economy\" would increase hydrogen emissions. Understanding of the atmospheric hydrogen budget is largely based on a 30-year record of surface air measurements, but there are no long-term records with which to assess either: 1) the influence of climate change on atmospheric hydrogen, or 2) the extent to which humans have impacted the hydrogen budget. Polar ice core records of hydrogen will advance our understanding of the atmospheric hydrogen cycle and provide a stronger basis for projecting future changes to atmospheric levels of hydrogen and their impacts. \u003cbr/\u003e\u003cbr/\u003eThe research will involve laboratory work to enable the collection and analysis of hydrogen in polar ice cores. Hydrogen is a highly diffusive molecule and, unlike most other atmospheric gases, diffusion of hydrogen in ice is so rapid that ice samples must be stored in impermeable containers immediately upon drilling and recovery. This project will: 1) construct a laboratory system for extracting and analyzing hydrogen in polar ice, 2) develop and test materials and construction designs for vessels to store ice core samples in the field, and 3) test the method on samples of opportunity previously stored in the field. The goal of this project is a proven, cost-effective design for storage flasks to be fabricated for use on future polar ice coring projects. This project will support the dissertation research of a graduate student in the UC Irvine Department of Earth System Science.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 139.27, "geometry": "POINT(134.265 -89.865)", "instruments": null, "is_usap_dc": true, "keywords": "LABORATORY; Firn; TRACE GASES/TRACE SPECIES; South Pole; FIELD INVESTIGATION; USAP-DC", "locations": "South Pole", "north": -89.86, "nsf_funding_programs": "Antarctic Instrumentation and Facilities; Antarctic Glaciology; Antarctic Instrumentation and Support", "paleo_time": null, "persons": "Saltzman, Eric", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -89.87, "title": "EAGER: Feasibility of Reconstructing the Atmospheric History of Molecular Hydrogen from Antarctic Ice", "uid": "p0010106", "west": 129.26}, {"awards": "1443470 Aydin, Murat", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "South Pole ice core (SPC14) discrete methane data; SP19 Gas Chronology; SPC14 carbonyl sulfide, methyl chloride, and methyl bromide measurements from South Pole, Antarctica", "datasets": [{"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kreutz, Karl; Buizert, Christo; Brook, Edward J.; Epifanio, Jenna; Severinghaus, Jeffrey P.; Kennedy, Joshua A.; Ferris, David G.; Kalk, Michael; Hood, Ekaterina; Fudge, T. J.; Osterberg, Erich; Winski, Dominic A.; Steig, Eric J.; Kahle, Emma; Sowers, Todd A.; Edwards, Jon S.; Aydin, Murat", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601270", "doi": "10.15784/601270", "keywords": "Antarctica", "people": "Aydin, Murat", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPC14 carbonyl sulfide, methyl chloride, and methyl bromide measurements from South Pole, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601270"}], "date_created": "Thu, 26 Mar 2020 00:00:00 GMT", "description": "In the past, Earth\u0027s climate underwent dramatic changes that influenced physical, chemical, geological, and biological processes on a global scale. Such changes left an imprint in Earth\u0027s atmosphere, as shown by the variability in abundances of trace gases like carbon dioxide and methane. In return, changes in the atmospheric trace gas composition affected Earth\u0027s climate. Studying compositional variations of the past atmosphere helps us understand the history of interactions between global biogeochemical cycles and Earth?s climate. The most reliable information on past atmospheric composition comes from analysis of air entrapped in polar ice cores. This project aims to generate ice-core records of relatively short-lived, very-low-abundance trace gases to determine the range of past variability in their atmospheric levels and investigate the changes in global biogeochemical cycles that caused this variability. This project measures three such gases: carbonyl sulfide, methyl chloride, and methyl bromide. Changes in carbonyl sulfide can indicate changes in primary productivity and photosynthetic update of carbon dioxide. Changes in methyl chloride and methyl bromide significantly impact natural variability in stratospheric ozone. In addition, the processes that control atmospheric levels of methyl chloride and methyl bromide are shared with those controlling levels of atmospheric methane. The measurements will be made in the new ice core from the South Pole, which is expected to provide a 40,000-year record.\u003cbr/\u003e\u003cbr/\u003eThe primary focus of this project is to develop high-quality trace gas records for the entire Holocene period (the past 11,000 years), with additional, more exploratory measurements from the last glacial period including the period from 29,000-36,000 years ago when there were large changes in atmospheric methane. Due to the cold temperatures of the South Pole ice, the proposed carbonyl sulfide measurements are expected to provide a direct measure of the past atmospheric variability of this gas without the large hydrolysis corrections that are necessary for interpretation of measurements from ice cores in warmer settings. Furthermore, we will test the expectation that contemporaneous measurements from the last glacial period in the deep West Antarctic Ice Sheet Divide ice core will not require hydrolysis loss corrections. With respect to methyl chloride, we aim to verify and improve the existing Holocene atmospheric history from the Taylor Dome ice core in Antarctica. The higher resolution of our measurements compared with those from Taylor Dome will allow us to derive a more statistically significant relationship between methyl chloride and methane. With respect to methyl bromide, we plan to extend the existing 2,000-year database to 11,000 years. Together, the methyl bromide and methyl chloride records will provide strong measurement-based constraints on the natural variability of stratospheric halogens during the Holocene period. In addition, the methyl bromide record will provide insight into the correlation between methyl chloride and methane during the Holocene period due to common sources and sinks.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "NOT APPLICABLE; CARBONYL SULFIDE; HALOCARBONS AND HALOGENS; TRACE GASES/TRACE SPECIES; Antarctic; USAP-DC", "locations": "Antarctic", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Carbonyl Sulfide, Methyl Chloride, and Methyl Bromide Measurements in the New Intermediate-depth South Pole Ice Core", "uid": "p0010089", "west": -180.0}, {"awards": "1341494 Gao, Yuan", "bounds_geometry": "POINT(-64.05 -64.77)", "dataset_titles": "Concentrations and Particle Size Distributions of Aerosol Trace Elements; Particle sizes of aerosol iron", "datasets": [{"dataset_uid": "601257", "doi": "10.15784/601257", "keywords": "Aerosol Concentration; Antarctica; Chemistry:gas; Chemistry:Gas; Iron; Palmer Station; Particle Size", "people": "Gao, Yuan", "repository": "USAP-DC", "science_program": null, "title": "Particle sizes of aerosol iron", "url": "https://www.usap-dc.org/view/dataset/601257"}, {"dataset_uid": "601370", "doi": "10.15784/601370", "keywords": "Antarctica; Antarctic Peninsula; Palmer Station; Trace Elements", "people": "Gao, Yuan", "repository": "USAP-DC", "science_program": null, "title": "Concentrations and Particle Size Distributions of Aerosol Trace Elements", "url": "https://www.usap-dc.org/view/dataset/601370"}], "date_created": "Thu, 20 Feb 2020 00:00:00 GMT", "description": "The research seeks to further quantify the input of atmospheric Fe into the sparsely sampled Southern Ocean (SO), specifically in the vicinity of the West Antarctic Peninsula (WAP) and adjacent continental shelf waters in the Drake Passage. This is typically a high nutrient low chlorophyll region where surface trace metal and primary productivity data are suggestive of Fe limitation. The WAP is characterized by high productivity in the austral summer, and at this time may be in the path of northern dust (aeolian Fe) input or subject to melt influx of elevated Fe accumulated from glacial and present-day sea ice sources.\u003cbr/\u003e\u003cbr/\u003ePrimary scientific questions are: (1) to what extent does atmospheric Fe contribute to nutrient cycles and ecosystem dynamics in the SO? (2) How is warming climate occurring in the WAP affecting the aerosol composition of the maritime atmosphere. The primary productivity of the Southern Ocean is key to understanding oceanic uptake of anthropogenic greenhouse gases such as carbon dioxide.", "east": -64.05, "geometry": "POINT(-64.05 -64.77)", "instruments": null, "is_usap_dc": true, "keywords": "Aerosol Concentration; TRACE GASES/TRACE SPECIES; Particle Size; Palmer Station; FIELD INVESTIGATION; Trace Elements; Iron; AEROSOL OPTICAL DEPTH/THICKNESS; USAP-DC", "locations": "Palmer Station", "north": -64.77, "nsf_funding_programs": "Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Gao, Yuan", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -64.77, "title": "Quantifying Atmospheric Iron Properties over West Antarctic Peninsula", "uid": "p0010082", "west": -64.05}, {"awards": "1443550 Brook, Edward", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Polar Ice Cores 3,000 Year Nitrous Oxide d15N and d18O Data; SPICEcore Holocene CO2 and N2O data", "datasets": [{"dataset_uid": "601197", "doi": "10.15784/601197", "keywords": "Antarctica; Carbon Dioxide; Ice Core Gas Records; Nitrous Oxide; South Pole; SPICEcore", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPICEcore Holocene CO2 and N2O data", "url": "https://www.usap-dc.org/view/dataset/601197"}, {"dataset_uid": "200055", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Polar Ice Cores 3,000 Year Nitrous Oxide d15N and d18O Data", "url": "https://www.ncdc.noaa.gov/paleo-search/study/25530"}], "date_created": "Tue, 06 Aug 2019 00:00:00 GMT", "description": "The temperature of the earth is controlled, in part, by heat trapping gases that include carbon dioxide, methane, and nitrous oxide. Despite their importance to climate, direct measurements of these gases in the atmosphere are limited to the last 50 years at best. Air trapped in ice cores extends those data back hundreds of millennia, and measurements of greenhouse gases in ice cores underpin much of our understanding of global chemical cycles relevant to modern climate change. Existing records vary in quality and detail. The proposed work fills gaps in our knowledge of nitrous oxide and carbon dioxide over the last 10,000 years. New measurements from an ice core from the South Pole will be used to determine what role changes in ocean and land based processes played in controlling these gases, which decreased during the first 2,000 years of this time period, then gradually increased toward the present. The work will address a major controversy over whether early human activities could have impacted the atmosphere, and provide data to improve mathematical models of the land-ocean-atmosphere system that predict how future climate change will impact the composition of the atmosphere and climate. \u003cbr/\u003e\u003cbr/\u003eFor nitrous oxide the work will improve on existing concentration records It will also develop measurement of the isotopomers of nitrous oxide and explore their utility for understanding aspects of the Holocene nitrous oxide budget. The primary goal is to determine if marine and/or terrestrial emissions of nitrous oxide change in response to changes in Holocene climate. A new Holocene isotopic record for carbon dioxide (stable carbon and oxygen isotopes), will improve the precision of existing records by a factor 5 and increase the temporal resolution. These data will be used to evaluate controversial hypotheses about why carbon dioxide concentrations changed in the Holocene and provide insight into millennial scale processes in the carbon cycle, which are not resolved by current isotopic data. A graduate student and post doc will receive advanced training during and the student and principle investigator will conduct outreach efforts targeted at local middle school students. The proposed work will also contribute to teaching efforts by the PI and to public lectures on climate and climate change. The results will be disseminated through publications, data archive, and the OSU Ice Core Lab web site. New analytical methods of wide utility will also be developed and documented.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Antarctica; ICE CORE RECORDS; CARBON DIOXIDE; NOT APPLICABLE; USAP-DC; TRACE GASES/TRACE SPECIES; NITROUS OXIDE", "locations": "Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Brook, Edward J.", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "NCEI; USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Controls on Variations in Atmospheric Carbon Dioxide and Nitrous Oxide During the Last 10,000 years", "uid": "p0010043", "west": -180.0}]

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