USAP-DC

{"dp_type": "Project", "free_text": "Thermal Fractionation"}

[{"awards": "0538657 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Borehole Temperature Measurement in WDC05A in January 2008 and January 2009; d15N and d18O of air in the WAIS Divide ice core; Low-res d15N and d18O of O2 in the WAIS Divide 06A Deep Core; Ultra-High Resolution LA-ICP-MS Results: DO-21 Rapid Warming Event; WAIS Divide d18Oatm and Siple Dome/WAIS Divide composite and individual delta epsilon LAND", "datasets": [{"dataset_uid": "609635", "doi": "10.7265/N51J97PS", "keywords": "Arctic; Geochemistry; GISP; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate", "people": "Haines, Skylar; Mayewski, Paul A.; Kurbatov, Andrei V.", "repository": "USAP-DC", "science_program": null, "title": "Ultra-High Resolution LA-ICP-MS Results: DO-21 Rapid Warming Event", "url": "https://www.usap-dc.org/view/dataset/609635"}, {"dataset_uid": "601747", "doi": "10.15784/601747", "keywords": "Antarctica; Delta 15N; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Gas Records; Ice Core Records; Isotope; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; WAIS; WAIS Divide", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "d15N and d18O of air in the WAIS Divide ice core", "url": "https://www.usap-dc.org/view/dataset/601747"}, {"dataset_uid": "609637", "doi": "10.7265/N5B27S7S", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Temperature; WAIS Divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.; Orsi, Anais J.", "repository": "USAP-DC", "science_program": null, "title": "Borehole Temperature Measurement in WDC05A in January 2008 and January 2009", "url": "https://www.usap-dc.org/view/dataset/609637"}, {"dataset_uid": "609660", "doi": "10.7265/N5S46PWD", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Low-res d15N and d18O of O2 in the WAIS Divide 06A Deep Core", "url": "https://www.usap-dc.org/view/dataset/609660"}, {"dataset_uid": "601041", "doi": "10.15784/601041", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Gas; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; WAIS Divide Ice Core", "people": "Severinghaus, Jeffrey P.; Seltzer, Alan", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide d18Oatm and Siple Dome/WAIS Divide composite and individual delta epsilon LAND", "url": "https://www.usap-dc.org/view/dataset/601041"}], "date_created": "Thu, 08 Jul 2010 00:00:00 GMT", "description": "0538657\u003cbr/\u003eSeveringhaus\u003cbr/\u003eThis award supports a project to develop high-resolution (20-yr) nitrogen and oxygen isotope records on trapped gases in the WAIS Divide ice core (Antarctica), with a comparison record for chronological purposes in the GISP2 (Greenland) ice core. The main scientific objective is to provide an independent temperature-change record for the past 100,000 years in West Antarctica that is not subject to the uncertainty inherent in ice isotopes (18O and deuterium), the classical paleothermometer. Nitrogen isotopes (Delta 15N) in air bubbles in glacial ice record rapid surface temperature change because of thermal fractionation of air in the porous firn layer, and this isotopic anomaly is recorded in bubbles as the firn becomes ice. Using this gas-based temperature-change record, in combination with methane data as interpolar stratigraphic markers, the proposed work will define the precise relative timing of abrupt warming in Greenland and abrupt cooling at the WAIS Divide site during the millennial-scale climatic oscillations of Marine Isotopic Stage 3 (30-70 kyr BP) and the last glacial termination. The nitrogen isotope record also provides constraints on past firn thickness, which inform temperature and accumulation rate histories from the ice core. A search for possible solar-related cycles will be conducted with the WAIS Divide Holocene (Delta 15N.) Oxygen isotopes of O2 (Delta 18Oatm) are obtained as a byproduct of the (Delta 15N) measurement. The gas-isotopic records will enhance the value of other atmospheric gas measurements in WAIS Divide, which are expected to be of unprecedented quality. The high-resolution (Delta 18Oatm) records will provide chronological control for use by the international ice coring community and for surface glacier ice dating. Education of a graduate student, and training of a staff member in the laboratory, will contribute to the nation\u0027s human resource base. Outreach activities in the context of the International Polar Year will be enhanced. International collaboration is planned with the laboratory of LSCE, University of Paris.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e LA-ICP-MS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Borehole Temperature; LABORATORY; Depth; Not provided; GROUND-BASED OBSERVATIONS; Wais Divide-project; Ice Core; WAIS Divide", "locations": "WAIS Divide", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Haines, Skylar; Mayewski, Paul A.; Orsi, Anais J.; Kurbatov, Andrei V.; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Nitrogen and Oxygen Gas Isotopes in the WAIS Divide Ice Core as Constraints on Chronology, Temperature, and Accumulation Rate", "uid": "p0000036", "west": null}, {"awards": "0230448 Severinghaus, Jeffrey; 0230260 Bender, Michael", "bounds_geometry": "POLYGON((-75.34 86.6,-68.742 86.6,-62.144 86.6,-55.546 86.6,-48.948 86.6,-42.35 86.6,-35.752 86.6,-29.154 86.6,-22.556 86.6,-15.958 86.6,-9.36 86.6,-9.36 83.618,-9.36 80.636,-9.36 77.654,-9.36 74.672,-9.36 71.69,-9.36 68.708,-9.36 65.726,-9.36 62.744,-9.36 59.762,-9.36 56.78,-15.958 56.78,-22.556 56.78,-29.154 56.78,-35.752 56.78,-42.35 56.78,-48.948 56.78,-55.546 56.78,-62.144 56.78,-68.742 56.78,-75.34 56.78,-75.34 59.762,-75.34 62.744,-75.34 65.726,-75.34 68.708,-75.34 71.69,-75.34 74.672,-75.34 77.654,-75.34 80.636,-75.34 83.618,-75.34 86.6))", "dataset_titles": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001; Trapped Gas Composition and Chronology of the Vostok Ice Core", "datasets": [{"dataset_uid": "609311", "doi": "10.7265/N5P26W12", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Lake Vostok; Paleoclimate; Vostok; Vostok Ice Core", "people": "Bender, Michael; Suwa, Makoto", "repository": "USAP-DC", "science_program": null, "title": "Trapped Gas Composition and Chronology of the Vostok Ice Core", "url": "https://www.usap-dc.org/view/dataset/609311"}, {"dataset_uid": "609290", "doi": "10.7265/N5FJ2DQC", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciology; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole", "people": "Bender, Michael; Battle, Mark; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Inert Gas and Oxygen Observations from Siple Dome, 1996, and the South Pole, 2001", "url": "https://www.usap-dc.org/view/dataset/609290"}], "date_created": "Wed, 18 Jan 2006 00:00:00 GMT", "description": "High latitude deep ice cores contain fundamental records of polar temperatures, atmospheric dust loads (and continental aridity), greenhouse gas concentrations, the status of the biosphere, and other essential properties of past environments. An accurate chronology for these records is needed if their significance is to be fully realized. The dating challenge has stimulated efforts at orbital tuning. In this approach, one varies a timescale, within allowable limits, to optimize the match between a paleoenvironmental property and a curve of insolation through time. The ideal property would vary with time due to direct insolation forcing. It would be unaffected by complex climate feedbacks and teleconnections, and it would give a clean record with high signal/noise ratio. It is argued strongly that the O2/N2 ratio of ice core trapped gases is such a property, and evidence is presented that this property, whose atmospheric ratio is nearly constant, is tied to local summertime insolation. This award will support a project to analyze the O2/N2 ratios at 1 kyr intervals from ~ 115-400 ka in the Vostok ice core. Ancillary measurements will be made of Ar/N2, and Ne/N2 and heavy noble gas ratios, in order to understand bubble close-off fractionation and its manifestation in the Vostok trapped gas record. O2/N2 variations will be matched with summertime insolation at Vostok to achieve a high-accuracy chronology for the Vostok core. The Vostok and other correlatable climate records will then be reexamined to improve our understanding of the dynamics of Pleistocene climate change.", "east": 106.8, "geometry": "POINT(106.8 -72.4667)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Paleoclimate; Siple Dome; Ice Age; Shallow Firn Air; Firn Air Isotope Measurements; Polar Firn Air; Ice Sample Gas Integrity; Oxygen Isotope; Noble Gas; Ice Core Gas Records; Atmospheric Gases; Trapped Gases; Not provided; LABORATORY; Vostok; Firn Air Isotopes; Thermal Fractionation; Ice Core Chemistry; Trapped Air Bubbles; Ice Core; Antarctica; South Pole; Ice Core Data; GROUND-BASED OBSERVATIONS; Gas Age; Firn Isotopes", "locations": "Antarctica; Vostok; Siple Dome; South Pole", "north": -72.4667, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Bender, Michael; Suwa, Makoto; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": -72.4667, "title": "Collaborative Research: Trapped Gas Composition and the Chronology of the Vostok Ice Core", "uid": "p0000257", "west": 106.8}, {"awards": "9725305 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "datasets": [{"dataset_uid": "609098", "doi": "10.7265/N51N7Z2P", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciology; Isotope; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole; Temperature", "people": "Grachev, Alexi; Battle, Mark; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "url": "https://www.usap-dc.org/view/dataset/609098"}], "date_created": "Mon, 01 Jan 2001 00:00:00 GMT", "description": "9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Isotopic History; GROUND STATIONS; Thermal Diffusion; Firn Temperature Measurements; Not provided; Oxygen Isotope; Trapped Air Bubbles; Shallow Firn Air; Firn Air Isotope Measurements; Seasonal Temperature Gradients; Mass Spectrometry; GROUND-BASED OBSERVATIONS; Thermal Fractionation; Polar Firn Air; Isotopic Anomalies; Xenon; Atmospheric Gases; Argon Isotopes; Siple Dome; Krypton; Nitrogen Isotopes; Seasonal Temperature Changes; Antarctica; Ice Core Gas Records; Firn Air Isotopes; Mass Spectrometer; South Pole; Firn Isotopes; Borehole", "locations": "Antarctica; Siple Dome; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change", "uid": "p0000160", "west": null}]

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