[{"awards": "0337933 Cole-Dai, Jihong; 0338363 Thiemens, Mark", "bounds_geometry": null, "dataset_titles": "Major Ion Concentrations in 2004 South Pole Ice Core", "datasets": [{"dataset_uid": "609542", "doi": "10.7265/N5HX19N8", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ion Chromatograph; South Pole", "people": "Cole-Dai, Jihong", "repository": "USAP-DC", "science_program": null, "title": "Major Ion Concentrations in 2004 South Pole Ice Core", "url": "https://www.usap-dc.org/view/dataset/609542"}], "date_created": "Fri, 11 Aug 2006 00:00:00 GMT", "description": "This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Not provided; Ion Chromatograph; Ions; LABORATORY; GROUND-BASED OBSERVATIONS", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Cole-Dai, Jihong", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Investigating Atmospheric Chemistry and Dynamics through Oxygen and Sulfur Isotopes in Volcanic Sulfate from South Pole Ice Cores", "uid": "p0000031", "west": null}, {"awards": "9527373 Dunbar, Nelia; 9615167 Dunbar, Nelia", "bounds_geometry": null, "dataset_titles": "Blue Ice Tephra II - Brimstone Peak; Blue Ice Tephra II - Mt. DeWitt; Tephra in Siple and Taylor Dome Ice Cores; Volcanic Records in the Siple and Taylor Dome Ice Cores", "datasets": [{"dataset_uid": "609126", "doi": "10.7265/N5FQ9TJG", "keywords": "Antarctica; Chemistry:rock; Chemistry:Rock; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome Ice Core; Taylor Dome Ice Core; Tephra; WAIS; WAISCORES", "people": "Zielinski, Gregory; Dunbar, Nelia", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Volcanic Records in the Siple and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/609126"}, {"dataset_uid": "609126", "doi": "10.7265/N5FQ9TJG", "keywords": "Antarctica; Chemistry:rock; Chemistry:Rock; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome Ice Core; Taylor Dome Ice Core; Tephra; WAIS; WAISCORES", "people": "Dunbar, Nelia; Zielinski, Gregory", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Volcanic Records in the Siple and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/609126"}, {"dataset_uid": "609114", "doi": "10.7265/N5MG7MDK", "keywords": "Antarctica; Blue Ice; Brimstone Peak; Chemistry:rock; Chemistry:Rock; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Petrography; Tephra", "people": "Dunbar, Nelia", "repository": "USAP-DC", "science_program": null, "title": "Blue Ice Tephra II - Brimstone Peak", "url": "https://www.usap-dc.org/view/dataset/609114"}, {"dataset_uid": "609110", "doi": "10.7265/N50P0WXF", "keywords": "Antarctica; Backscattered Electron Images; Chemistry:rock; Chemistry:Rock; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Siple Dome; Siple Dome Ice Core; Taylor Dome Ice Core; WAIS", "people": "Dunbar, Nelia", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Tephra in Siple and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/609110"}, {"dataset_uid": "609110", "doi": "10.7265/N50P0WXF", "keywords": "Antarctica; Backscattered Electron Images; Chemistry:rock; Chemistry:Rock; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Siple Dome; Siple Dome Ice Core; Taylor Dome Ice Core; WAIS", "people": "Dunbar, Nelia", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Tephra in Siple and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/609110"}, {"dataset_uid": "609115", "doi": "10.7265/N5GQ6VPV", "keywords": "Antarctica; Blue Ice; Chemistry:rock; Chemistry:Rock; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Mount Dewitt; Petrography; Tephra", "people": "Dunbar, Nelia", "repository": "USAP-DC", "science_program": null, "title": "Blue Ice Tephra II - Mt. DeWitt", "url": "https://www.usap-dc.org/view/dataset/609115"}], "date_created": "Sat, 01 Jun 2002 00:00:00 GMT", "description": "Dunbar/Kyle OPP 9527373 Zielinski OPP 9527824 Abstract The Antarctic ice sheets are ideal places to preserve a record the volcanic ash (tephra) layers and chemical aerosol signatures of volcanic eruptions. This record, which is present both in areas of bare blue ice, as well as in deep ice cores, consists of a combination of local eruptions, as well as eruptions from more distant volcanic sources from which glassy shards can be chemically fingerprinted and related to a source volcano. Field work carried out during the 1994/1995 Antarctic field season in the Allan Hills area of Antarctica, and subsequent microbeam chemical analysis and 40Ar/39Ar dating has shown that tephra layers in deep Antarctic ice preserve a coherent, systematic stratigraphy, and can be successfully mapped, dated, chemically fingerprinted and tied to source volcanoes. The combination of chemical fingerprinting of glass shards, and chemical analysis of volcanic aerosols associated with ash layers will allow establishment of a high-resolution chronology of local and distant volcanism that can help understand patterns of significant explosive volcanisms and atmospheric loading and climactic effects associated with volcanic eruptions. Correlation of individual tephra layers, or sets of layers, in blue ice areas, which have been identified in many places the Transantarctic Mountains, will allow the geometry of ice flow in these areas to be better understood and will provide a useful basis for interpreting ice core records.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ELECTRON MICROPROBES", "is_usap_dc": true, "keywords": "USAP-DC; Siple Coast; Sulfur Dioxide; Siple Dome; Taylor Dome; Chlorine; WAISCORES; Ice Core; Tephra; Geochemistry; Volcanic Deposits; GROUND STATIONS; Brimstone Peak; GROUND-BASED OBSERVATIONS; Magnesium Oxide; Glaciology; Mount Dewitt; Silicon Dioxide; Glass Shards; Ice Sheet; Siple; Nickel Oxide; Potassium Dioxide; Not provided; Manganese Oxide; Volcanic; Snow; Nitrogen; Iron Oxide; Titanium Dioxide; Stratigraphy; Antarctica", "locations": "Antarctica; Siple; Siple Coast; Siple Dome; Taylor Dome; Brimstone Peak; Mount Dewitt", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Dunbar, Nelia; Zielinski, Gregory", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": null, "title": "Collaborative Research: Volcanic Record in Antarctic Ice: Implications for Climatic and Eruptive History and Ice Sheet Dynamics of the South Polar Region", "uid": "p0000065", "west": null}]

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Collaborative Research: Investigating Atmospheric Chemistry and Dynamics through Oxygen and Sulfur Isotopes in Volcanic Sulfate from South Pole Ice Cores

0337933
0338363

2006-08-11

Cole-Dai, Jihong

Major Ion Concentrations in 2004 South Pole Ice Core

USAP-DC

This award supports a collaborative study between South Dakota State University (SDSU) and University of California, San Diego (UCSD) to investigate the oxygen and sulfur isotope composition of sulfates from a number of large volcanic eruptions in the past 1000 years. The project aims to drill a number of shallow ice cores at South Pole and return them to SDSU and UCSD lab for chemical and isotope analysis. Preliminary results from measurements of isotopes in sulfate samples from several volcanic eruptions in Antarctic snow and ice indicate that isotopic composition of volcanic sulfate contains abundant valuable information on atmospheric chemical and dynamic processes that have not been previously investigated. One tentative conclusion is that mass-independently fractionated sulfur isotopes reveal that atmospheric photolysis of sulfur compounds occurs at longer UV wavelengths than those in the Archean atmosphere, possibly reflecting the atmospheric ozone and/or oxygen concentration. This suggests that isotopic composition of atmospheric sulfate may be used to understand the role of UV radiation in sulfur dioxide conversion in the atmosphere and to track the evolution (i.e., oxygenation) of the atmosphere and the origin of life on Earth. Other major research objectives include understanding what impact massive volcanic eruptions have on the oxidative capacity of the atmosphere, what oxidants and mechanisms are involved in the oxidation or conversion of volcanic sulfur dioxide to sulfate in the stratosphere and what isotopic criteria may be used to differentiate ice core signals of stratospheric eruptions from those of tropospheric eruptions. By providing educational and research opportunities to graduate and undergraduate students at both SDSU and UCSD, the proposed project will promote the integration of research and education and contribute to human resource development in science and engineering. The project will contribute to a proposed REU chemistry site program at SDSU. This collaboration will utilize the complementary strengths of both labs and promote exchange between the two institutions. International collaboration will enhance scientific cooperation between France and US.

Collaborative Research: Volcanic Record in Antarctic Ice: Implications for Climatic and Eruptive History and Ice Sheet Dynamics of the South Polar Region

9527373
9615167

2002-06-01

Dunbar, Nelia; Zielinski, Gregory

Volcanic Records in the Siple and Taylor Dome Ice Cores	USAP-DC
Volcanic Records in the Siple and Taylor Dome Ice Cores	USAP-DC
Blue Ice Tephra II - Brimstone Peak	USAP-DC
Tephra in Siple and Taylor Dome Ice Cores	USAP-DC
Tephra in Siple and Taylor Dome Ice Cores	USAP-DC
Blue Ice Tephra II - Mt. DeWitt	USAP-DC