USAP-DC

{"dp_type": "Project", "free_text": "Polycrystalline Ice"}

[{"awards": "2317263 Cross, Andrew", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Mon, 14 Aug 2023 00:00:00 GMT", "description": "The seaward motion of ice sheets and glaciers is primarily controlled by basal sliding below, and internal viscous flow within, ice masses. The latter of these\u2014viscous flow\u2014is dependent on various factors, including temperature, stress, grain size, and the alignment of ice crystals during flow to produce a crystal orientation fabric (COF). Historically, ice flow has been modeled using a constitutive equation, termed \u201cGlen\u2019s law\u201d, that describes ice flow rate as a function of temperature and stress. Glen\u2019s law was constrained under relatively high-stress conditions, and is often attributed to the motion of crystal defects within ice grains. More recently, however, grain boundary sliding (GBS) has been invoked as the rate-controlling process under low-stress, \u201csuperplastic\u201d conditions. The grain boundary sliding hypothesis is contentious because GBS is not thought to produce a COF, whereas geophysical measurements and polar ice cores demonstrate strong COFs in polar ice masses. However, very few COF measurements have been conducted on ice samples subjected to superplastic flow conditions in the laboratory. In this project, the PI primarily seeks to measure the evolution of ice COF across the transition from superplastic to Glen-type creep. Results will be used to interrogate the role of superplastic GBS creep within polar ice masses, and thereby provide constraints on polar ice discharge models.\r\n\r\nPolycrystalline ice samples with grain sizes ranging from 5 \u00b5m to 1000 \u00b5m will be fabricated and deformed in the PI\u2019s laboratory at WHOI, using a 1-atm cryogenic axial-torsion apparatus. Experiments will be conducted at temperatures of \u221230\u00b0C to \u221210\u00b0C, and at a constant uniaxial strain rate of 10-7 s-1. Under these conditions, 5% to 99.99% of strain should be accommodated by superplastic, GBS-limited creep, depending on the sample grain size. The deformed samples will then be imaged using cryogenic electron backscatter diffraction (cryo-EBSD) and high-angular-resolution electron backscatter diffraction (HR-EBSD) to quantify COF, grain size, grain shape, and crystal defect (dislocation) densities, among other microstructural properties. These measurements will be used to decipher the rate-controlling mechanisms operating within different thermomechanical regimes, and resolve a long-standing debate over whether superplastic creep can produce a COF in ice. In addition to the polycrystal experiments, ice bicrystals will be fabricated and deformed to investigate the micromechanical behavior of individual grain boundaries under superplastic conditions. Ultimately, these results will be used to provide a microstructural toolbox for identifying superplastic creep using geophysical (e.g., seismic, radar) and glaciological (e.g., ice core) observations. This project will support one graduate student within the MIT-WHOI Joint Program, one or more undergraduate summer students, and a junior faculty member (the PI). In addition, the PI will host a workshop aimed at bringing together experimentalists, glaciologists, and ice modelers to facilitate cross-disciplinary knowledge sharing and collaborative problem solving.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "United States Of America; Rheology; ROCKS/MINERALS/CRYSTALS; GLACIERS/ICE SHEETS", "locations": "United States Of America", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Cross, Andrew", "platforms": null, "repositories": null, "science_programs": null, "south": null, "title": "Microstructural Evolution during Superplastic Ice Creep", "uid": "p0010430", "west": null}, {"awards": "1851022 Fudge, Tyler; 1851094 Baker, Ian", "bounds_geometry": null, "dataset_titles": "EPICA Dome C Sulfate Data 7-3190m", "datasets": [{"dataset_uid": "601759", "doi": "10.15784/601759", "keywords": "Antarctica", "people": "Severi, Mirko; Fudge, T. J.", "repository": "USAP-DC", "science_program": "COLDEX", "title": "EPICA Dome C Sulfate Data 7-3190m", "url": "https://www.usap-dc.org/view/dataset/601759"}], "date_created": "Mon, 28 Jun 2021 00:00:00 GMT", "description": "An accurate constitutive relationship for ice is fundamental to ice-flow models and ice-core interpretations. While Glen\u2019s flow law describes well the overall deformation of ice when subjected to stress, many details remain poorly constrained. In particular, the effect of impurities on the strain rate both directly and through the development of ice fabric is not well understood. Variations in impurity concentrations are associated with variations in deformation rates as observed in both Greenland and Antarctica. The impact of uncertainties on the deformation of ice is most acutely observed in the interpretation of ice cores where the inference of past accumulation rate depends on the cumulative vertical thinning. Thus, many ice-core climate reconstructions, such as the gas-age ice-age difference, surface temperature histories, and aerosol fluxes, are also affected. Given the complexities of the possible impacts of sulfuric acid on the flow of ice and the interaction between these impacts, it seems almost impossible to examine an ice core and understand the impacts of impurities on the microstructural evolution and creep behavior. Our research seeks to understand the effects of sulfuric acid at concentrations applicable to polar ice sheets and relate these results to the flow of polar ice both through experiments and through modeling. Our results have shown that the presence of sulfuric acid in the grain boundaries of polar ice increases its strength in shear, while sulfuric acid in the whole matrix of polar ice reduces its strength. We have also found that sulfuric acid causes an initial increase in average grain sizes and then a subsequent decrease, a trend that differs from the continuous increase in average grain sizes observed in freshwater ice. We are also determining the role of stress state, i.e. simple compression versus shear, on the microstructural evolution and how sulfuric acid impacts this.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": true, "keywords": "AMD; Polycrystalline Ice; LABORATORY; Epica Dome C; SNOW/ICE; USA/NSF; USAP-DC; Ice Core; Amd/Us", "locations": "Epica Dome C", "north": null, "nsf_funding_programs": "Antarctic Science and Technology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Fudge, T. J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: The Impact of Impurities and Stress State on Polycrystalline Ice Deformation", "uid": "p0010211", "west": null}, {"awards": "1141411 Baker, Ian", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Laboratory Experiments with H2SO4-Doped Ice; The Effects of Soluble Impurities on the Flow and Fabric of Polycrystalline Ice", "datasets": [{"dataset_uid": "601081", "doi": "10.15784/601081", "keywords": null, "people": "Hammonds, Kevin", "repository": "USAP-DC", "science_program": null, "title": "Laboratory Experiments with H2SO4-Doped Ice", "url": "https://www.usap-dc.org/view/dataset/601081"}, {"dataset_uid": "600380", "doi": "10.15784/600380", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Physical Properties; Snow", "people": "Baker, Ian", "repository": "USAP-DC", "science_program": null, "title": "The Effects of Soluble Impurities on the Flow and Fabric of Polycrystalline Ice", "url": "https://www.usap-dc.org/view/dataset/600380"}], "date_created": "Fri, 09 Oct 2020 00:00:00 GMT", "description": "This award supports a project to undertake a systematic examination of the effects of soluble impurities, particularly sulfuric acid, on the creep of polycrystalline ice as function of temperature, strain rate and impurity concentration. The working hypothesis is that soluble impurities will increase the flow rate of polycrystalline ice compared to high-purity ice, that this effect will be temperature dependent and that the impurities by affecting the re-crystallization and grain growth will change the fabric of the ice. Both H2SO4-doped and high-purity poly-crystalline ice will be produced by freezing sheets of ice, breaking them up, sieving the ice particles and then sintering them in a mold into fine-grained cylindrical specimens with at least ten grains across their diameter. The resulting microstructures (dislocation structure, grain size and shape, grain boundary character and micro-structural location of the acid) will be characterized using a variety of techniques including: optical microscopy, scanning electron microscopy, including secondary electron imaging, electron backscattered patterns, energy dispersive X-ray spectroscopy, electron channeling contrast imaging, and X-ray topography. The creep of both the H2SO4-doped and the high-purity polycrystalline ice will be undertaken at a range of temperatures and stresses. The ice?s response to the creep deformation (grain boundary sliding, dislocation motion, re-crystallization, grain boundary migration, impurity redistribution) will be studied using a combination of methods. The creep behavior will be modeled and related to the microstructure. Of particular interest is how impurities affect the activation energy for creep. The intellectual merit of the work is that it will lead to a better understanding of glacier ice and will enable glaciologists to model the influence of impurities on the flow and fabric development in polycrystalline ice. The broader impacts of the project include the knowledge that will be gained of the effects of impurities on the flow of ice which will allow paleoclimatologists to better interpret ice core data and will allow scientists developing predictive models to better address the flow of ice sheets under various climate change scenarios. The project will also lead to the education and training of a Ph.D. student, several undergraduates and some high school students. Results from the research will be published in refereed journals. Several undergraduates, typically two per year, will also perform the work. Dartmouth aggressively courts minority students at all degree levels, and we will seek women or minority group undergraduates for this project. The undergraduates will be supported by Dartmouth?s nationally-honored Women In Science Project or by REU funding. The undergraduates? research will integrate closely with the Ph.D. student?s studies. Hanover High School students will also be involved in the project and develop an educational kit to introduce students to the properties of ice. Results from the research will be published in refereed journals and presented at conferences.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "USA/NSF; USAP-DC; SNOW/ICE; Amd/Us; LABORATORY; Antarctica; AMD", "locations": "Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "The Effects of Soluble Impurities on the Flow and Fabric of Polycrystalline Ice", "uid": "p0010133", "west": -180.0}, {"awards": "9980379 Baker, Ian", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Mon, 15 Feb 2010 00:00:00 GMT", "description": "This award is for support for three years of funding to study the effects of impurities on the flow of poly-\u003cbr/\u003ecrystalline ice. It has been known for thirty years that both hydrofluoric acid (HF) and hydrochloric acid (HCl) dramatically decrease the strength of ice and recent work by the author\u0027s group has shown that sulfuric acid (H2SO4) produces a similar reduction in strength. However, these data are for single crystals at strain rates and stresses that far exceed those found in glaciers and ice sheets, and often at concentrations that far exceed those in natural ice. Therefore, it is not known how impurities found in nature affect the flow of polycrystalline ice at slow strain rates. In this research, the effects of nitric acid and sulfuric acid (which are naturally occurring impurities in ice) on the microstructure (dislocation structure, grain boundary structure and location of the acids) and creep of polycrystalline ice (at a range of temperatures and stresses) will be determined. The ice\u0027s response to creep deformation will be studied using a combination of x-ray topography, optical microscopy and scanning electron microscopy. X-ray microanalysis in an environmental scanning electron microscope will be used to study the location of impurities. The structure and creep behavior of the acid-doped ice will be compared with those of both high-purity laboratory-grown ice and ice from Byrd Station, Antarctica. The end-result of this project will be to elucidate the effects of naturally-occurring acid impurities on the mechanical properties of polycrystalline ice under conditions relevant to the deformation of glaciers and ice sheets, including and understanding of how impurities affect the underlying deformation mechanisms.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e ION CHROMATOGRAPHS; EARTH REMOTE SENSING INSTRUMENTS \u003e PASSIVE REMOTE SENSING \u003e PHOTON/OPTICAL DETECTORS \u003e PARTICLE DETECTORS; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e SCANNING ELECTRON MICROSCOPES", "is_usap_dc": true, "keywords": "Ice Core Data; Ice Core; Microstructure; Ice Sheet; Ice Core Chemistry; Antarctic Ice Sheet; LABORATORY", "locations": "Antarctic Ice Sheet", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Baker, Ian; Obbard, Rachel", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repositories": null, "science_programs": null, "south": null, "title": "The Effects of Impurities on the Flow of Polycrystalline Ice", "uid": "p0000015", "west": null}]

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