{"dp_type": "Project", "free_text": "Lithium"}
[{"awards": "0087235 Grew, Edward", "bounds_geometry": "POLYGON((42 -64,43.2 -64,44.4 -64,45.6 -64,46.8 -64,48 -64,49.2 -64,50.4 -64,51.6 -64,52.8 -64,54 -64,54 -64.4,54 -64.8,54 -65.2,54 -65.6,54 -66,54 -66.4,54 -66.8,54 -67.2,54 -67.6,54 -68,52.8 -68,51.6 -68,50.4 -68,49.2 -68,48 -68,46.8 -68,45.6 -68,44.4 -68,43.2 -68,42 -68,42 -67.6,42 -67.2,42 -66.8,42 -66.4,42 -66,42 -65.6,42 -65.2,42 -64.8,42 -64.4,42 -64))", "dataset_titles": null, "datasets": null, "date_created": "Mon, 09 Aug 2004 00:00:00 GMT", "description": "0087235\u003cbr/\u003eGrew\u003cbr/\u003e\u003cbr/\u003eThis award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a project to investigate the role of beryllium in lower crustal partial melting events. The formation of granitic liquids by partial melting deep in the Earth\u0027s crust is one of the major topics of research in igneous and metamorphic petrology today. One aspect of this sphere of research is the beginning of the process, specifically, the geochemical interaction between melts and source rocks before the melt has left the source area. One example of anatexis in metamorphic rocks affected by conditions found deep in the Earth\u0027s crust is pegmatite in the Archean ultrahigh temperature granulite-facies Napier Complex of Enderby Land, East Antarctica. Peak conditions for this granulite-facies metamorphism are estimated to have reached nearly 1100 Degrees Celsius and 11 kilobar, that is, conditions in the Earth\u0027s lower crust in Archean time. The proposed research is a study of the Napier Complex pegmatites with an emphasis on the minerals and geochemistry of beryllium. This element, which is estimated to constitute 3 ppm of the Earth\u0027s upper crust, is very rarely found in any significant concentrations in metamorphic rocks subjected to conditions of the Earth\u0027s lower crust. Structural, geochronological, and mineralogical studies will be carried out to test the hypothesis that the beryllium pegmatites resulted from anatexis of their metapelitic host rocks during the ultrahigh-temperature metamorphic event in the late Archean. Host rocks will be analyzed for major and trace elements. Minerals will be analyzed by the electron microprobe for major constituents including fluorine and by the ion microprobe for lithium, beryllium and boron. The analytical data will be used to determine how beryllium and other trace constituents were extracted from host rocks under ultrahigh-temperature conditions and subsequently concentrated in the granitic melt, eventually to crystallize out in a pegmatite as beryllian sapphirine and khmaralite, minerals not found in pegmatites elsewhere. Mineral compositions and assemblages will be used to determine the evolution and conditions of crystallization and recrystallization of the pegmatites and their host rocks during metamorphic episodes following the ultrahigh-temperature event. Monazite will be analyzed for lead, thorium and uranium to date the ages of these events. Because fluorine is instrumental in mobilizing beryllium, an undergraduate student will study the magnesium fluorphosphate wagnerite in the pegmatites in order to estimate fluorine activity in the melt as part of a senior project. The results of the present project will provide important insights on the melting process in general and on the geochemical behavior of beryllium in particular under the high temperatures and low water activities characteristic of the Earth\u0027s lower crust.", "east": 54.0, "geometry": "POINT(48 -66)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ELECTRON MICROPROBES; IN SITU/LABORATORY INSTRUMENTS \u003e PROBES \u003e ION MICROPROBES", "is_usap_dc": false, "keywords": "Metamorphism; Li; Be; Pegmatitic Leucosomes; Partial Melting; Lithium; Granulites; Napier Complex; Boron; Beryllium; Mineralogy; Not provided; Continental Crust", "locations": "Napier Complex", "north": -64.0, "nsf_funding_programs": "Antarctic Earth Sciences", "paleo_time": null, "persons": "Grew, Edward", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -68.0, "title": "Beryllium in Antarctic Ultrahigh-Temperature Granulite-Facies Rocks and its Role in Partial Melting of the Lower Continental Crust", "uid": "p0000370", "west": 42.0}, {"awards": "9977306 Ryan, Jeffrey", "bounds_geometry": "POINT(167.16 -77.5)", "dataset_titles": "B-Be-Li Abundance and Isotope Data: Mt. Erebus-McMurdo Volcanics", "datasets": [{"dataset_uid": "600020", "doi": "", "keywords": "B; Be; Beryllium; Boron; Isotope; Li; Lithium; Mcmurdo Volcanic Group; Mount Erebus", "people": "Ryan, Jeffrey", "repository": "USAP-DC", "science_program": null, "title": "B-Be-Li Abundance and Isotope Data: Mt. Erebus-McMurdo Volcanics", "url": "https://www.usap-dc.org/view/dataset/600020"}], "date_created": "Thu, 19 Jun 2003 00:00:00 GMT", "description": "Subduction zones are the one place on Earth where materials from the surface (water, sediments and crustal rocks) can be carried into our planet\u0027s deep interior. To quantify this process of subduction-zone recycling, we need to understand both the input of sediments and crust to trenches, and all geochemical outputs related to the subduction process. While the chemical outputs represented by magmatism at volcanic arcs and in back-arc settings have been widely studied, little is known about possible subduction-related outfluxes through the shallow forearc, between the arc and the trench. We are attempting to characterize the \"forearc flux\" by examining serpentinites which are rising diapirically through the forearc mantle and crust in the Mariana arc-trench system. Our work will complete efforts begun (with NSF support) several years ago, and will characterize these samples (and the slab-derived fluids which helped to create them) for radiogenic isotopes, lithium and oxygen isotopes, and the \"fluid-mobile\" elements Cs, Rb, U, As, Pb, and Sb. Our work will allow us to characterize both the chemical inventories of species that are released from subducting slabs beneath forearcs, and the magnitude of this flux, for comparison with results for trench inputs (being collected as part of ODP Leg 125), and existing data for arc volcanic outputs in the Mariana system.", "east": 167.16, "geometry": "POINT(167.16 -77.5)", "instruments": null, "is_usap_dc": false, "keywords": "Mount Erebus; Mcmurdo Volcanic Group; Not provided; Crary Mountains", "locations": "Crary Mountains; Mount Erebus", "north": -77.5, "nsf_funding_programs": "Marine Geology and Geophysics", "paleo_time": null, "persons": "Ryan, Jeffrey", "platforms": "Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -77.5, "title": "The Role of the Forearc in Subduction Zone Chemical Cycles: Elemental and Isotopic Signatures of Forearc Serpentinites, ODP Leg 125", "uid": "p0000244", "west": 167.16}]
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| Project Title/Abstract/Map | NSF Award(s) | Date Created | PIs / Scientists | Dataset Links and Repositories | Abstract | Bounds Geometry | Geometry | Selected | Visible | |||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
Beryllium in Antarctic Ultrahigh-Temperature Granulite-Facies Rocks and its Role in Partial Melting of the Lower Continental Crust
|
0087235 |
2004-08-09 | Grew, Edward | No dataset link provided | 0087235<br/>Grew<br/><br/>This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a project to investigate the role of beryllium in lower crustal partial melting events. The formation of granitic liquids by partial melting deep in the Earth's crust is one of the major topics of research in igneous and metamorphic petrology today. One aspect of this sphere of research is the beginning of the process, specifically, the geochemical interaction between melts and source rocks before the melt has left the source area. One example of anatexis in metamorphic rocks affected by conditions found deep in the Earth's crust is pegmatite in the Archean ultrahigh temperature granulite-facies Napier Complex of Enderby Land, East Antarctica. Peak conditions for this granulite-facies metamorphism are estimated to have reached nearly 1100 Degrees Celsius and 11 kilobar, that is, conditions in the Earth's lower crust in Archean time. The proposed research is a study of the Napier Complex pegmatites with an emphasis on the minerals and geochemistry of beryllium. This element, which is estimated to constitute 3 ppm of the Earth's upper crust, is very rarely found in any significant concentrations in metamorphic rocks subjected to conditions of the Earth's lower crust. Structural, geochronological, and mineralogical studies will be carried out to test the hypothesis that the beryllium pegmatites resulted from anatexis of their metapelitic host rocks during the ultrahigh-temperature metamorphic event in the late Archean. Host rocks will be analyzed for major and trace elements. Minerals will be analyzed by the electron microprobe for major constituents including fluorine and by the ion microprobe for lithium, beryllium and boron. The analytical data will be used to determine how beryllium and other trace constituents were extracted from host rocks under ultrahigh-temperature conditions and subsequently concentrated in the granitic melt, eventually to crystallize out in a pegmatite as beryllian sapphirine and khmaralite, minerals not found in pegmatites elsewhere. Mineral compositions and assemblages will be used to determine the evolution and conditions of crystallization and recrystallization of the pegmatites and their host rocks during metamorphic episodes following the ultrahigh-temperature event. Monazite will be analyzed for lead, thorium and uranium to date the ages of these events. Because fluorine is instrumental in mobilizing beryllium, an undergraduate student will study the magnesium fluorphosphate wagnerite in the pegmatites in order to estimate fluorine activity in the melt as part of a senior project. The results of the present project will provide important insights on the melting process in general and on the geochemical behavior of beryllium in particular under the high temperatures and low water activities characteristic of the Earth's lower crust. | POLYGON((42 -64,43.2 -64,44.4 -64,45.6 -64,46.8 -64,48 -64,49.2 -64,50.4 -64,51.6 -64,52.8 -64,54 -64,54 -64.4,54 -64.8,54 -65.2,54 -65.6,54 -66,54 -66.4,54 -66.8,54 -67.2,54 -67.6,54 -68,52.8 -68,51.6 -68,50.4 -68,49.2 -68,48 -68,46.8 -68,45.6 -68,44.4 -68,43.2 -68,42 -68,42 -67.6,42 -67.2,42 -66.8,42 -66.4,42 -66,42 -65.6,42 -65.2,42 -64.8,42 -64.4,42 -64)) | POINT(48 -66) | false | false | |||
|
The Role of the Forearc in Subduction Zone Chemical Cycles: Elemental and Isotopic Signatures of Forearc Serpentinites, ODP Leg 125
|
9977306 |
2003-06-19 | Ryan, Jeffrey |
|
Subduction zones are the one place on Earth where materials from the surface (water, sediments and crustal rocks) can be carried into our planet's deep interior. To quantify this process of subduction-zone recycling, we need to understand both the input of sediments and crust to trenches, and all geochemical outputs related to the subduction process. While the chemical outputs represented by magmatism at volcanic arcs and in back-arc settings have been widely studied, little is known about possible subduction-related outfluxes through the shallow forearc, between the arc and the trench. We are attempting to characterize the "forearc flux" by examining serpentinites which are rising diapirically through the forearc mantle and crust in the Mariana arc-trench system. Our work will complete efforts begun (with NSF support) several years ago, and will characterize these samples (and the slab-derived fluids which helped to create them) for radiogenic isotopes, lithium and oxygen isotopes, and the "fluid-mobile" elements Cs, Rb, U, As, Pb, and Sb. Our work will allow us to characterize both the chemical inventories of species that are released from subducting slabs beneath forearcs, and the magnitude of this flux, for comparison with results for trench inputs (being collected as part of ODP Leg 125), and existing data for arc volcanic outputs in the Mariana system. | POINT(167.16 -77.5) | POINT(167.16 -77.5) | false | false |
