USAP-DC

{"dp_type": "Project", "free_text": "Krypton"}

[{"awards": "1744562 Loose, Brice", "bounds_geometry": "POLYGON((-180 -71,-179.9 -71,-179.8 -71,-179.7 -71,-179.6 -71,-179.5 -71,-179.4 -71,-179.3 -71,-179.2 -71,-179.1 -71,-179 -71,-179 -71.7,-179 -72.4,-179 -73.1,-179 -73.8,-179 -74.5,-179 -75.2,-179 -75.9,-179 -76.6,-179 -77.3,-179 -78,-179.1 -78,-179.2 -78,-179.3 -78,-179.4 -78,-179.5 -78,-179.6 -78,-179.7 -78,-179.8 -78,-179.9 -78,180 -78,177.5 -78,175 -78,172.5 -78,170 -78,167.5 -78,165 -78,162.5 -78,160 -78,157.5 -78,155 -78,155 -77.3,155 -76.6,155 -75.9,155 -75.2,155 -74.5,155 -73.8,155 -73.1,155 -72.4,155 -71.7,155 -71,157.5 -71,160 -71,162.5 -71,165 -71,167.5 -71,170 -71,172.5 -71,175 -71,177.5 -71,-180 -71))", "dataset_titles": "Expedition Data of NBP1704; NBP1704 Expedition Data; PIPERS Noble Gases", "datasets": [{"dataset_uid": "200329", "doi": "", "keywords": null, "people": null, "repository": "MGDS", "science_program": null, "title": "Expedition Data of NBP1704", "url": "https://www.marine-geo.org/tools/entry/NBP1704"}, {"dataset_uid": "001363", "doi": "", "keywords": null, "people": null, "repository": "R2R", "science_program": null, "title": "NBP1704 Expedition Data", "url": "https://www.rvdata.us/search/cruise/NBP1704"}, {"dataset_uid": "601609", "doi": "10.15784/601609", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Mass Spectrometer; NBP1704; Noble Gas; Oceans; Ross Sea; R/v Nathaniel B. Palmer", "people": "Loose, Brice", "repository": "USAP-DC", "science_program": null, "title": "PIPERS Noble Gases", "url": "https://www.usap-dc.org/view/dataset/601609"}], "date_created": "Wed, 14 Sep 2022 00:00:00 GMT", "description": "Near the Antarctic coast, polynyas are open-water regions where extreme heat loss in winter causes seawater to become cold, salty, and dense enough to sink into the deep sea. The formation of this dense water has regional and global importance because it influences the ocean current system. Polynya processes are also tied to the amount of sea ice formed, ocean heat lost to atmosphere, and atmospheric CO2 absorbed by the Southern Ocean. Unfortunately, the ocean-atmosphere interactions that influence the deep ocean water properties are difficult to observe directly during the Antarctic winter. This project will combine field measurements and laboratory experiments to investigate whether differences in the concentration of noble gasses (helium, neon, argon, xenon, and krypton) dissolved in ocean waters can be linked to environmental conditions at the time of their formation. If so, noble gas concentrations could provide insight into the mechanisms controlling shelf and bottom-water properties, and be used to reconstruct past climate conditions. Project results will contribute to the Southern Ocean Observing System (SOOS) theme of The Future and Consequences of Carbon Uptake in the Southern Ocean. The project will also train undergraduate and graduate students in environmental monitoring, and earth and ocean sciences methods. \u003cbr/\u003e\u003cbr/\u003eUnderstanding the causal links between Antarctic coastal processes and changes in the deep ocean system requires study of winter polynya processes. The winter period of intense ocean heat loss and sea ice production impacts two important Antarctic water masses: High-Salinity Shelf Water (HSSW), and Antarctic Bottom Water (AABW), which then influence the strength of the ocean solubility pump and meridional overturning circulation. To better characterize how sea ice cover, ocean-atmosphere exchange, brine rejection, and glacial melt influence the physical properties of AABW and HSSW, this project will analyze samples and data collected from two Ross Sea polynyas during the 2017 PIPERS winter cruise. Gas concentrations will be measured in seawater samples collected by a CTD rosette, from an underwater mass-spectrometer, and from a benchtop Membrane Inlet Mass Spectrometer. Noble gas concentrations will reveal the ocean-atmosphere (dis)equilibrium that exists at the time that surface water is transformed into HSSW and AABW, and provide a fingerprint of past conditions. In addition, nitrogen (N2), oxygen (O2), argon, and CO2 concentration will be used to determine the net metabolic balance, and to evaluate the efficacy of N2 as an alternative to O2 as glacial meltwater tracer. Laboratory experiments will determine the gas partitioning ratios during sea ice formation. Findings will be synthesized with PIPERS and related projects, and so provide an integrated view of the role of the wintertime Antarctic coastal system on deep water composition.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": -179.0, "geometry": "POINT(168 -74.5)", "instruments": null, "is_usap_dc": true, "keywords": "Helium Isotopes; R/V NBP; DISSOLVED GASES; POLYNYAS; Ross Sea", "locations": "Ross Sea", "north": -71.0, "nsf_funding_programs": "Antarctic Integrated System Science; Antarctic Ocean and Atmospheric Sciences", "paleo_time": null, "persons": "Loose, Brice", "platforms": "WATER-BASED PLATFORMS \u003e VESSELS \u003e SURFACE \u003e R/V NBP", "repo": "MGDS", "repositories": "MGDS; R2R; USAP-DC", "science_programs": null, "south": -78.0, "title": "Measuring Dissolved Gases to Reveal the Processes that Drive the Solubility Pump and Determine Gas Concentration in Antarctic Bottom Water", "uid": "p0010376", "west": 155.0}, {"awards": "1643664 Severinghaus, Jeffrey; 1643669 Petrenko, Vasilii; 1643716 Buizert, Christo", "bounds_geometry": "POLYGON((112 -66,112.2 -66,112.4 -66,112.6 -66,112.8 -66,113 -66,113.2 -66,113.4 -66,113.6 -66,113.8 -66,114 -66,114 -66.1,114 -66.2,114 -66.3,114 -66.4,114 -66.5,114 -66.6,114 -66.7,114 -66.8,114 -66.9,114 -67,113.8 -67,113.6 -67,113.4 -67,113.2 -67,113 -67,112.8 -67,112.6 -67,112.4 -67,112.2 -67,112 -67,112 -66.9,112 -66.8,112 -66.7,112 -66.6,112 -66.5,112 -66.4,112 -66.3,112 -66.2,112 -66.1,112 -66))", "dataset_titles": "Concentration and isotopic composition of atmospheric N2O over the last century; Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2; Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy", "datasets": [{"dataset_uid": "601597", "doi": "10.15784/601597", "keywords": "Antarctica; Ice Core; Law Dome; Noble Gas", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH site noble gases in ice: testing the 86Krexcess proxy", "url": "https://www.usap-dc.org/view/dataset/601597"}, {"dataset_uid": "601598", "doi": "10.15784/601598", "keywords": "Antarctica; Firn; Firn Density; Gravitational Settling; Inert Gases; Law Dome", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Law Dome DE08-OH firn air 15N, O2/N2, Ar/N2, 18O of O2", "url": "https://www.usap-dc.org/view/dataset/601598"}, {"dataset_uid": "601693", "doi": "10.15784/601693", "keywords": "Antarctic; Antarctica; Anthropogenic Emission; Atmosphere; Greenhouse Gas; Greenland; Ice Core Data; Nitrification And Denitrification Processes; Nitrous Oxide; Site-Specific 15N Isotopomer; Styx Glacier", "people": "Etheridge, David; Ahn, Jinho ; Joong Kim, Seong; Yoshida, Naohiro ; Langenfelds, Ray L ; Buizert, Christo ; Toyoda, Sakae ; Ghosh, Sambit", "repository": "USAP-DC", "science_program": null, "title": "Concentration and isotopic composition of atmospheric N2O over the last century", "url": "https://www.usap-dc.org/view/dataset/601693"}], "date_created": "Fri, 17 Jun 2022 00:00:00 GMT", "description": "Hydroxyl radicals are responsible for removal of most atmospheric trace gases, including pollutants and important greenhouse gases. They have been called the \"detergent of the atmosphere\". Changes in hydroxyl radical concentration in response to large changes in reactive trace gas emissions, which may happen in the future, are uncertain. This project aims to provide the first estimates of the variability of atmospheric hydroxyl radicals since about 1880 AD when anthropogenic emissions of reactive trace gases were minimal. This will improve understanding of their stability in response to large changes in emissions. The project will also investigate whether ice cores record past changes in Southern Hemisphere westerly winds. These winds are a key component of the global climate system, and have an important influence on ocean circulation and possibly on atmospheric carbon dioxide concentrations. The project team will include three early career scientists, a postdoctoral researcher, and graduate and undergraduate students, working in collaboration with senior scientists and Australian collaborators. \u003cbr/\u003e \u003cbr/\u003eFirn air and shallow ice to a depth of about 233 m will be sampled at the Law Dome high-accumulation coastal site in East Antarctica. Trapped air will be extracted from the ice cores on site immediately after drilling. Carbon-14 of carbon monoxide (14CO) will be analyzed in firn and ice-core air samples. Corrections will be made for the in situ cosmogenic 14CO component in the ice, allowing for the atmospheric 14CO history to be reconstructed. This 14CO history will be interpreted with the aid of a chemistry-transport model to place the first observational constraints on the variability of Southern Hemisphere hydroxyl radical concentration after about 1880 AD. An additional component of the project will analyze Krypton-86 in the firn-air and ice-core samples. These measurements will explore whether ice-core Krypton-86 acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere westerly winds.\u003cbr/\u003e\u003cbr/\u003eThis award reflects NSF\u0027s statutory mission and has been deemed worthy of support through evaluation using the Foundation\u0027s intellectual merit and broader impacts review criteria.", "east": 114.0, "geometry": "POINT(113 -66.5)", "instruments": null, "is_usap_dc": true, "keywords": "AMD; TRACE GASES/TRACE SPECIES; Law Dome; Amd/Us; USAP-DC; LABORATORY; ICE CORE AIR BUBBLES; USA/NSF", "locations": "Law Dome", "north": -66.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Murray, Lee T; Buizert, Christo; Petrenko, Vasilii; Murray, Lee T", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -67.0, "title": "Collaborative Research: Reconstructing Carbon-14 of Atmospheric Carbon Monoxide from Law Dome, Antarctica to Constrain Long-Term Hydroxyl Radical Variability", "uid": "p0010341", "west": 112.0}, {"awards": "1543267 Brook, Edward; 1543229 Severinghaus, Jeffrey", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Multi-site ice core Krypton stable isotope ratios; Noble Gas Data from recent ice in Antarctica for 86Kr problem", "datasets": [{"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Mulvaney, Robert; Severinghaus, Jeffrey P.; Buizert, Christo; Pyne, Rebecca L.; Brook, Edward J.; Shackleton, Sarah; Baggenstos, Daniel; Mosley-Thompson, Ellen; Bertler, Nancy; Etheridge, David; Bereiter, Bernhard", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601195", "doi": "10.15784/601195", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Krypton; Noble Gas; Xenon", "people": "Shackleton, Sarah; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": null, "title": "Noble Gas Data from recent ice in Antarctica for 86Kr problem", "url": "https://www.usap-dc.org/view/dataset/601195"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Bertler, Nancy; Etheridge, David; Baggenstos, Daniel; Brook, Edward J.; Severinghaus, Jeffrey P.; Pyne, Rebecca L.; Mulvaney, Robert; Buizert, Christo; Mosley-Thompson, Ellen; Bereiter, Bernhard; Shackleton, Sarah", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}, {"dataset_uid": "601394", "doi": "10.15784/601394", "keywords": "Antarctica; Bruce Plateau; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenland Ice Cap; Ice Core; Ice Core Chemistry; Ice Core Records; James Ross Island; Krypton; Law Dome; Low Dome Ice Core; Roosevelt Island; Siple Dome; Siple Dome Ice Core; South Pole; SPICEcore; WAIS Divide; WAIS Divide Ice Core", "people": "Buizert, Christo; Severinghaus, Jeffrey P.; Shackleton, Sarah; Bertler, Nancy; Brook, Edward J.; Baggenstos, Daniel; Bereiter, Bernhard; Mosley-Thompson, Ellen; Etheridge, David; Pyne, Rebecca L.; Mulvaney, Robert", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Multi-site ice core Krypton stable isotope ratios", "url": "https://www.usap-dc.org/view/dataset/601394"}], "date_created": "Wed, 10 Jul 2019 00:00:00 GMT", "description": "Overview: The funded work investigated whether ice core 86Kr acts as a proxy for barometric pressure variability, and whether this proxy can be used in Antarctic ice cores to infer past movement of the Southern Hemisphere (SH) westerly winds. Pressure variations drive macroscopic air movement in the firn column, which reduces the gravitational isotopic enrichment of slow-diffusing gases (such as Kr). The 86Kr deviation from gravitational equilibrium (denoted D86Kr) thus reflects the magnitude of pressure variations (among other things). Atmospheric reanalysis data suggest that pressure variability over Antarctica is linked to the Southern Annular Mode (SAM) index and the position of the SH westerly winds. Preliminary data from the WAIS Divide ice core show a large excursion in D86Kr during the last deglaciation (20-9 ka before present). In this project the investigators (1) performed high-precision 86Kr analysis on ice core and firn air samples to establish whether D86Kr is linked to pressure variability; (2) Refined the deglacial WAIS Divide record of Kr isotopes; (3) Investigated the role of pressure variability in firn air transport using firn air models with firn microtomography data and Lattice- Boltzmann modeling; and (4) Investigated how barometric pressure variability in Antarctica is linked to the SAM index and the position/strength of the SH westerlies in past and present climates using GCM and reanalysis data. A key finding was that D86Kr in recent ice samples (e.g. last 50 years) from a broad spatial array of sites in Antarctica and Greenland showed a significant correlation with directly measured barometric pressure variability at the ice core site. This strongly supports the hypothesis that 86Kr can be used as a paleo-proxy for storminess.\r\nIntellectual Merit: The SH westerlies are a key component of the global climate system; they are an important control on the global oceanic overturning circulation and possibly on atmospheric CO2 concentrations. Poleward movement of the SH westerlies during the last deglaciation has been hypothesized, yet evidence from proxy and modeling studies remains inconclusive. The funded work could provide valuable new constraints on deglacial movement of the SH westerlies. This record can be compared to high-resolution CO2 data from the same core, allowing us to test hypotheses that link CO2 to the SH westerlies. Climate proxies are at the heart of paleoclimate research. The funded work has apparently led to the discovery of a completely new proxy, opening up exciting new research possibilities and increasing the scientific value of existing ice cores. Once validated, the 86Kr proxy could be applied to other time periods as well, providing a long-term perspective on the movement of the SH westerlies. The funded work has furthermore provided valuable new insights into firn air transport. \r\n\r\nBroader impact: The Southern Ocean is presently an important sink of atmospheric CO2, thereby reducing the warming associated with anthropogenic CO2 emissions. Stratospheric ozone depletion and greenhouse warming have displaced the SH westerlies poleward, with potential consequences for the future magnitude of this oceanic carbon uptake. The funded work may provide a paleo-perspective on past movement of the SH westerlies and its link to atmospheric CO2, which could guide projections of future oceanic CO2 uptake, with strong societal benefits. The awarded funds supported and trained an early-career postdoctoral scholar at OSU, and fostered (international) collaboration. Data from the study will be available to the scientific community and the broad public through recognized data centers. During this project the PI and senior personnel have continued their commitment to public outreach through media interviews and speaking to schools and the public about their work. The PI provides services to the community by chairing the IPICS (International Partnership in Ice Core Sciences) working group and organizing annual PIRE (Partnerships in International Research and Education) workshops.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "USA/NSF; FIRN; ICE CORE RECORDS; USAP-DC; Greenland; Xenon; Noble Gas; Ice Core; Amd/Us; Antarctica; AMD; LABORATORY; Krypton; ATMOSPHERIC PRESSURE", "locations": "Greenland; Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Brook, Edward J.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Collaborative research: Kr-86 as a proxy for barometric pressure variability and movement of the SH westerlies during the last\r\ndeglaciation", "uid": "p0010037", "west": -180.0}, {"awards": "1443263 Higgins, John; 1443306 Mayewski, Paul", "bounds_geometry": null, "dataset_titles": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores; Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores; Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores; Greenhouse gas composition in the Allan Hills S27 ice core; Methane concentration in Allan Hills ice cores; Stable isotope composition of the trapped air in the Allan Hills S27 ice core; Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area; Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "datasets": [{"dataset_uid": "601203", "doi": "10.15784/601203", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Chemistry:ice; Chemistry:Ice; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Greenhouse Gas; Ice; Ice Core Data; Ice Core Gas Records; Methane; Snow/ice; Snow/Ice", "people": "Brook, Edward J.; Yan, Yuzhen; Bender, Michael; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Methane concentration in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601203"}, {"dataset_uid": "601512", "doi": "10.15784/601512", "keywords": "Allan Hills; Antarctica; Blue Ice; Ice Core; Ice Core Gas Records; Isotope; Nitrogen; Oxygen", "people": "Higgins, John; Yan, Yuzhen; Bender, Michael", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable isotope composition of the trapped air in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601512"}, {"dataset_uid": "601201", "doi": "10.15784/601201", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Argon; Chemistry:ice; Chemistry:Ice; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Data; Ice Core Gas Records; Krypton; Mass Spectrometer; Noble Gas; Snow/ice; Snow/Ice; Xenon", "people": "Bender, Michael; Higgins, John; Yan, Yuzhen; Ng, Jessica; Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of heavy noble gases in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601201"}, {"dataset_uid": "601483", "doi": "10.15784/601483", "keywords": "Allan Hills; Antarctica; Argon; Ice; Ice Core Data; Ice Core Gas Records; Isotope; Mass Spectrometry; Nitrogen; Oxygen", "people": "Bender, Michael; Yan, Yuzhen; Higgins, John", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Elemental and isotopic composition of nitrogen, oxygen, and argon in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601483"}, {"dataset_uid": "601130", "doi": "10.15784/601130", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Delta Deuterium; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Gas Records; Ice Core Records; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Introne, Douglas; Kurbatov, Andrei V.; Mayewski, Paul A.; Yan, Yuzhen", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the surface samples collected at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601130"}, {"dataset_uid": "601129", "doi": "10.15784/601129", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Blue Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Isotope Data; Oxygen; Snow/ice; Snow/Ice; Stable Water Isotopes; Transantarctic Mountains", "people": "Yan, Yuzhen; Kurbatov, Andrei V.; Introne, Douglas; Mayewski, Paul A.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1502 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601129"}, {"dataset_uid": "601128", "doi": "10.15784/601128", "keywords": "Allan Hills; Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope Record; Mass Spectrometry; Stable Water Isotopes", "people": "Mayewski, Paul A.; Kurbatov, Andrei V.; Yan, Yuzhen; Introne, Douglas", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Stable water isotope data for the AH-1503 ice core drilled at the Allan Hills Blue ice area", "url": "https://www.usap-dc.org/view/dataset/601128"}, {"dataset_uid": "601425", "doi": "10.15784/601425", "keywords": "Allan Hills; Antarctica; Blue Ice; Carbon Dioxide; Ice Core; Methane", "people": "Yan, Yuzhen; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Greenhouse gas composition in the Allan Hills S27 ice core", "url": "https://www.usap-dc.org/view/dataset/601425"}, {"dataset_uid": "601202", "doi": "10.15784/601202", "keywords": "Allan Hills; Allan Hills Project; Antarctica; Carbon Dioxide; Carbon Isotopes; Chemistry:ice; Chemistry:Ice; CO2; Gas Chromatography; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Data; Ice Core Gas Records; Ice Core Records; Mass Spectrometer; Mass Spectrometry; Methane; Snow/ice; Snow/Ice", "people": "Bender, Michael; Yan, Yuzhen; Higgins, John; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Allan Hills", "title": "Carbon dioxide concentration and its stable carbon isotope composition in Allan Hills ice cores", "url": "https://www.usap-dc.org/view/dataset/601202"}], "date_created": "Thu, 18 Oct 2018 00:00:00 GMT", "description": "Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800,000 years. Previous field expeditions to the Allan Hills blue ice area, Antarctica, have recovered ice cores that date to one million years, the oldest ice cores yet recovered from Antarctica. These records have revealed that interglacial CO2 concentrations decreased by 800,000 years ago and that, in the warmer world 1 million years ago, CO2 and Antarctic temperature were linked as during the last 800,000 years. This project will return to the Allan Hills blue ice area to recover additional ice cores that date to 1 million years or older. The climate records developed from the drilled ice cores will provide new insights into the chemical composition of the atmosphere and Antarctic climate during times of comparable or even greater warmth than the present day. Our results will help answer questions about issues associated with anthropogenic change. These include the relationship between temperature change and the mass balance of Antarctic ice; precipitation and aridity variations associated with radiatively forced climate change; and the climate significance of sea ice extent. The project will entrain two graduate students and a postdoctoral scholar, and will conduct outreach including workshops to engage teachers in carbon science and ice cores.\u003cbr/\u003e\u003cbr/\u003eBetween about 2.8-0.9 million years ago, Earth\u0027s climate was characterized by 40,000-year cycles, driven or paced by changes in the tilt of Earth\u0027s spin axis. Much is known about the \"40,000-year\" world from studies of deep-sea sediments, but our understanding of climate change during this period is incomplete because we lack records of Antarctic climate and direct records of atmospheric greenhouse gas concentrations. We propose to address these issues by building on our recent studies of ancient ice from the Main Ice Field, Allan Hills, Antarctica. During previous field seasons we recovered ice extending, discontinuously, from 0.1-1.0 million years old. Ice was dated by measuring the 40Ar/38Ar (Argon) ratio of the trapped gases. Our discovery of million year-old ice demonstrates that there is gas-record-quality ice from the 40,000-year world in the Allan Hills Main Ice Field. We have identified two different sites, each overlying bedrock at ~ 200 m depth, that are attractive targets for coring ice dating to 1 million years and older. This project aims to core the ice at these two sites, re-occupy a previous site with million year-old ice and drill it down to the bedrock, and generate 10-20 short (~10-meter) cores in areas where our previous work and terrestrial meteorite ages suggest ancient surface ice. We plan to date the ice using the 40Ar/38Ar ages of trapped Argon. We also plan to characterize the continuity of our cores by measuring the deuterium and oxygen isotope ratios in the ice, methane, ratios of Oxygen and Argon to Nitrogen in trapped gas, the Nitrogen-15 isotope (d15N) of Nitrogen, and the Oxygen-18 isotope (d18O) of Oxygen. As the ice may be stratigraphically disturbed, these measurements will provide diagnostic properties for assessing the continuity of the ice-core records. Successful retrieval of ice older than one million years will provide the opportunity for follow-up work to measure the CO2 concentration and other properties within the ice to inform on the temperature history of the Allan Hills region, dust sources and source-area aridity, moisture sources, densification conditions, global average ocean temperature, and greenhouse gas concentrations. We will analyze the data in the context of leading hypotheses of the 40,000-year world and the Mid-Pleistocene Transition to the 100,000-year world. We expect to advance understanding of climate dynamics during these periods.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "Amd/Us; AMD; Allan Hills; USA/NSF; FIELD INVESTIGATION; USAP-DC; Ice Core; LABORATORY", "locations": "Allan Hills", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Mayewski, Paul A.; Kurbatov, Andrei V.; Higgins, John; Bender, Michael", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Allan Hills", "south": null, "title": "Collaborative Research: Window into the World with 40,000-year Glacial Cycles from Climate Records in Million Year-old Ice from the Allan Hills Blue Ice Area", "uid": "p0000760", "west": null}, {"awards": "1245821 Brook, Edward; 1245659 Petrenko, Vasilii; 1246148 Severinghaus, Jeffrey", "bounds_geometry": "POINT(162.167 -77.733)", "dataset_titles": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores; Last Interglacial Mean Ocean Temperature; Mean Ocean Temperature in Marine Isotope Stage 4; Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation; N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica; Taylor Glacier CO2 Isotope Data 74-59 kyr; Taylor Glacier Noble Gases - Younger Dryas; The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "datasets": [{"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "601260", "doi": "10.15784/601260", "keywords": "Antarctica; Carbon-14; Cosmogenic; Ice Core; Methane", "people": "Dyonisius, Michael; Petrenko, Vasilii", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601260"}, {"dataset_uid": "601198", "doi": "10.15784/601198", "keywords": "Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; CO2; Dust; Gas; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Mass Spectrometer; Methane; Nitrogen Isotopes; Oxygen Isotope; Paleoclimate; Snow/ice; Snow/Ice; Taylor Dome; Taylor Dome Ice Core", "people": "Severinghaus, Jeffrey P.; Menking, James; Brook, Edward J.; Marcott, Shaun; Barker, Stephen; Shackleton, Sarah; Dyonisius, Michael; Petrenko, Vasilii; McConnell, Joseph; Rhodes, Rachel; Bauska, Thomas; Baggenstos, Daniel", "repository": "USAP-DC", "science_program": null, "title": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/601198"}, {"dataset_uid": "601415", "doi": "10.15784/601415", "keywords": "Antarctica; Glaciology; Ice Core Data; Ice Core Records; Paleoclimate; Paleotemperature; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": null, "title": "Mean Ocean Temperature in Marine Isotope Stage 4", "url": "https://www.usap-dc.org/view/dataset/601415"}, {"dataset_uid": "601600", "doi": "10.15784/601600", "keywords": "Antarctica; Taylor Glacier", "people": "Severinghaus, Jeffrey P.; Menking, Andy; Petrenko, Vasilii; Dyonisius, Michael; Barker, Stephen; Brook, Edward J.; Buffen, Aron; Bauska, Thomas; Shackleton, Sarah; Menking, James", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier CO2 Isotope Data 74-59 kyr", "url": "https://www.usap-dc.org/view/dataset/601600"}, {"dataset_uid": "601176", "doi": "10.15784/601176", "keywords": "Antarctica; CO2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; Noble Gas; Noble Gas Isotopes; Snow/ice; Snow/Ice; Taylor Glacier; Younger Dryas", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Taylor Glacier Noble Gases - Younger Dryas", "url": "https://www.usap-dc.org/view/dataset/601176"}, {"dataset_uid": "601398", "doi": "10.15784/601398", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Gas Records; Ice Core Records; Marine Isotope Stage 4; MIS 4; Nitrous Oxide; Pleistocene; Taylor Dome Ice Core; Taylor Glacier", "people": "Schilt, Adrian; Menking, James; Shackleton, Sarah; Severinghaus, Jeffrey P.; Dyonisius, Michael; Brook, Edward J.; Petrenko, Vasilii", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601398"}, {"dataset_uid": "600163", "doi": "10.15784/600163", "keywords": "Antarctica; Atmosphere; Geochemistry; Ice Core Records; Isotope; Paleoclimate; Taylor Glacier; Transantarctic Mountains", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "url": "https://www.usap-dc.org/view/dataset/600163"}, {"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "This award supports a project to use the Taylor Glacier, Antarctica, ablation zone to collect ice samples for a range of paleoenvironmental studies. A record of carbon-14 of atmospheric methane (14CH4) will be obtained for the last deglaciation and the Early Holocene, together with a supporting record of CH4 stable isotopes. In-situ cosmogenic 14C content and partitioning of 14C between different species (14CH4, C-14 carbon monoxide (14CO) and C-14 carbon dioxide (14CO2)) will be determined with unprecedented precision in ice from the surface down to ~67 m. Further age-mapping of the ablating ice stratigraphy will take place using a combination of CH4, CO2, \u0026#948;18O of oxygen gas and H2O stable isotopes. High precision, high-resolution records of CO2, \u0026#948;13C of CO2, nitrous oxide (N2O) and N2O isotopes will be obtained for the last deglaciation and intervals during the last glacial period. The potential of 14CO2 and Krypton-81 (81Kr) as absolute dating tools for glacial ice will be investigated. The intellectual merit of proposed work includes the fact that the response of natural methane sources to continuing global warming is uncertain, and available evidence is insufficient to rule out the possibility of catastrophic releases from large 14C-depleted reservoirs such as CH4 clathrates and permafrost. The proposed paleoatmospheric 14CH4 record will improve our understanding of the possible magnitude and timing of CH4 release from these reservoirs during a large climatic warming. A thorough understanding of in-situ cosmogenic 14C in glacial ice (production rates by different mechanisms and partitioning between species) is currently lacking. Such an understanding will likely enable the use of in-situ 14CO in ice at accumulation sites as a reliable, uncomplicated tracer of the past cosmic ray flux and possibly past solar activity, as well as the use of 14CO2 at both ice accumulation and ice ablation sites as an absolute dating tool. Significant gaps remain in our understanding of the natural carbon cycle, as well as in its responses to global climate change. The proposed high-resolution, high-precision records of \u0026#948;13C of CO2 would provide new information on carbon cycle changes both during times of rising CO2 in a warming climate and falling CO2 in a cooling climate. N2O is an important greenhouse gas that increased by ~30% during the last deglaciation. The causes of this increase are still largely uncertain, and the proposed high-precision record of N2O concentration and isotopes would provide further insights into N2O source changes in a warming world. The broader impacts of proposed work include an improvement in our understanding of the response of these greenhouse gas budgets to global warming and inform societally important model projections of future climate change. The continued age-mapping of Taylor Glacier ablation ice will add value to this high-quality, easily accessible archive of natural environmental variability. Establishing 14CO as a robust new tracer for past cosmic ray flux would inform paleoclimate studies and constitute a valuable contribution to the study of the societally important issue of climate change. The proposed work will contribute to the development of new laboratory and field analytical systems. The data from the study will be made available to the scientific community and the broad public through the NSIDC and NOAA Paleoclimatology data centers. 1 graduate student each will be trained at UR, OSU and SIO, and the work will contribute to the training of a postdoc at OSU. 3 UR undergraduates will be involved in fieldwork and research. The work will support a new, junior UR faculty member, Petrenko. All PIs have a strong history of and commitment to scientific outreach in the forms of media interviews, participation in filming of field projects, as well as speaking to schools and the public about their research, and will continue these activities as part of the proposed work. This award has field work in Antarctica.", "east": 162.167, "geometry": "POINT(162.167 -77.733)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Not provided; USAP-DC; FIELD INVESTIGATION; Stratigraphy; FIELD SURVEYS; Antarctica; Paleoenvironment; Methane; Ice Core; Carbon Dioxide; FIXED OBSERVATION STATIONS; Stable Isotopes; Ablation Zone; Taylor Glacier; Nitrous Oxide; USA/NSF; LABORATORY; AMD; Cosmogenic; Amd/Us", "locations": "Taylor Glacier; Antarctica", "north": -77.733, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Brook, Edward J.; Severinghaus, Jeffrey P.; PETRENKO, VASILLI", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e FIXED OBSERVATION STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.733, "title": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "uid": "p0000283", "west": 162.167}, {"awards": "0944343 Severinghaus, Jeffrey", "bounds_geometry": "POINT(-112.05 -79.28)", "dataset_titles": null, "datasets": null, "date_created": "Fri, 15 Aug 2014 00:00:00 GMT", "description": "Severinghaus/0944343\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to develop both a record of past local temperature change at the WAIS Divide site, and past mean ocean temperature using solubility effects on atmospheric krypton and xenon. The two sets of products share some of the same measurements, because the local temperature is necessary to make corrections to krypton and xenon, and thus synergistically support each other. Further scientific synergy is obtained by the fact that the mean ocean temperature is constrained to vary rather slowly, on a 1000-yr timescale, due to the mixing time of the deep ocean. Thus rapid changes are not expected, and can be used to flag methodological problems if they appear in the krypton and xenon records. The mean ocean temperature record produced will have a temporal resolution of 500 years, and will cover the entire 3400 m length of the core. This record will be used to test hypotheses regarding the cause of atmospheric carbon dioxide (CO2) variations, including the notion that deep ocean stratification via a cold salty stagnant layer caused atmospheric CO2 drawdown during the last glacial period. The local surface temperature record that results will synergistically combine with independent borehole thermometry and water isotope records to produce a uniquely precise and accurate temperature history for Antarctica, on a par with the Greenland temperature histories. This history will be used to test hypotheses that the ?bipolar seesaw? is forced from the North Atlantic Ocean, which makes a specific prediction that the timing of Antarctic cooling should slightly lag abrupt Greenland warming. The WAIS Divide ice core is expected to be the premier atmospheric gas record of the past 100,000 years for the foreseeable future, and as such, making this set of high precision noble gas measurements adds value to the other gas records because they all share a common timescale and affect each other in terms of physical processes such as gravitational fractionation. Broader impact of the proposed work: The clarification of timing of atmospheric CO2 and Antarctic surface temperature, along with deep ocean temperature, will aid in efforts to understand the feedbacks among CO2, temperature, and ocean circulation. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. A deeper understanding of the mechanism of deglaciation, and the role of atmospheric CO2, will go a long way towards clarifying a topic that has become quite confused in the public mind in the public debate over climate change. Elucidating the role of the bipolar seesaw in ending glaciations and triggering CO2 increases may also provide an important warning that this represents a potential positive feedback, not currently considered by IPCC. Education of one graduate student, and training of one technician, will add to the nation?s human resource base. Outreach activities will be enhanced and will to continue to entrain young people in discovery, and excitement will enhance the training of the next generation of scientists and educators.", "east": -112.05, "geometry": "POINT(-112.05 -79.28)", "instruments": null, "is_usap_dc": false, "keywords": "Noble Gas; FIELD INVESTIGATION; Climate; Xenon; FIELD SURVEYS; Ice Core; Antarctica; Krypton; LABORATORY", "locations": "Antarctica", "north": -79.28, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repositories": null, "science_programs": null, "south": -79.28, "title": "Noble Gases in the WAIS Divide Ice Core as Indicators of Local and Mean-ocean Temperature", "uid": "p0000430", "west": -112.05}, {"awards": "0538630 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": null, "datasets": null, "date_created": "Wed, 01 Apr 2009 00:00:00 GMT", "description": "0538630\u003cbr/\u003eSeveringhaus\u003cbr/\u003eThis award supports a project to produce the first record of Kr/N2 in the paleo-atmosphere as measured in air bubbles trapped in ice cores. These measurements may be indicative of past variations in mean ocean temperature. Knowing the mean ocean temperature in the past will give insight into past variations in deep ocean temperature, which remain poorly understood. Deep ocean temperature variations are important for understanding the mechanisms of climate change. Krypton is highly soluble in water, and its solubility varies with temperature, with higher solubilities at colder water temperatures. A colder ocean during the last glacial period would therefore hold more krypton than today\u0027s ocean. Because the total amount of krypton in the ocean-atmosphere system is constant, the increase in the krypton inventory in the glacial ocean should cause a resultant decrease in the atmospheric inventory of krypton. The primary goal of this work is to develop the use of Kr/N2 as an indicator of paleo-oceanic mean temperature. This will involve improving the analytical technique for the Kr/N2 measurement itself, and measuring the Kr/N2 in air bubbles in ice from the last glacial maximum (LGM) and the late Holocene in the Vostok and GISP2 ice cores. This provides an estimate of LGM mean ocean temperature change, and allows for a comparison between previous estimates of deep ocean temperature during the LGM. The Vostok ice core is ideal for this purpose because of the absence of melt layers, which compromise the krypton and xenon signal. Another goal is to improve precision on the Xe/N2 measurement, which could serve as a second, independent proxy of ocean temperature change. A mean ocean temperature time series during this transition may help to explain these observations. Additionally, the proposed work will measure the Kr/N2 from marine isotope stage (MIS) 3 in the GISP2 ice core. Knowing the past ocean temperature during MIS 3 will help to constrain sea level estimates during this time period. The broader impacts of the proposed work: are that it will provide the first estimate of the extent and timing of mean ocean temperature change in the past. This will help to constrain previously proposed mechanisms of climate change involving large changes in deep ocean temperature. This project will also support the education of a graduate student. The PI gives interviews and talks to the media and public about climate change, and the work will enhance these outreach activities. Finally, the work will occur during the International Polar Year (IPY), and will underscore the unique importance of the polar regions for understanding the global atmosphere and ocean system.", "east": null, "geometry": null, "instruments": null, "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": null, "title": "Paleoatmospheric Krypton and Xenon Abundances from Trapped Air in Polar Ice as Indicators of Past Mean Ocean Temperature", "uid": "p0000553", "west": null}, {"awards": "9725305 Severinghaus, Jeffrey", "bounds_geometry": null, "dataset_titles": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "datasets": [{"dataset_uid": "609098", "doi": "10.7265/N51N7Z2P", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciology; Isotope; Paleoclimate; Siple Dome; Snow/ice; Snow/Ice; South Pole; Temperature", "people": "Severinghaus, Jeffrey P.; Grachev, Alexi; Battle, Mark", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Firn Air Isotope and Temperature Measurements from Siple Dome and South Pole", "url": "https://www.usap-dc.org/view/dataset/609098"}], "date_created": "Mon, 01 Jan 2001 00:00:00 GMT", "description": "9725305 Severinghaus This award supports a project to develop and apply a new technique for quantifying temperature changes in the past based on the thermodynamic principle of thermal diffusion, in which gas mixtures in a temperature gradient become fractionated. Air in polar firn is fractionated by temperature gradients induced by abrupt climate change, and a record of this air is preserved in bubbles in the ice. The magnitude of the abrupt temperature change, the precise relative timing, and an estimate of the absolute temperature change can be determined. By providing a gas-phase stratigraphic marker of temperature change, the phasing of methane (with decadal precision) and hence widespread climate change (relative to local polar temperature changes) can be determined (across five abrupt warming events during the last glacial period).", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SAMPLERS \u003e BOTTLES/FLASKS/JARS \u003e FLASKS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e TEMPERATURE/HUMIDITY SENSORS \u003e THERMISTORS \u003e THERMISTORS", "is_usap_dc": true, "keywords": "Isotopic History; GROUND STATIONS; Thermal Diffusion; Firn Temperature Measurements; Not provided; Oxygen Isotope; Trapped Air Bubbles; Shallow Firn Air; Firn Air Isotope Measurements; Seasonal Temperature Gradients; Mass Spectrometry; GROUND-BASED OBSERVATIONS; Thermal Fractionation; Polar Firn Air; Isotopic Anomalies; Xenon; Atmospheric Gases; Argon Isotopes; Siple Dome; Krypton; Nitrogen Isotopes; Seasonal Temperature Changes; Antarctica; Ice Core Gas Records; Firn Air Isotopes; Mass Spectrometer; South Pole; Firn Isotopes; Borehole", "locations": "Antarctica; Siple Dome; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Battle, Mark; Grachev, Alexi; Severinghaus, Jeffrey P.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND STATIONS; Not provided", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Siple Dome Ice Core", "south": null, "title": "Thermal Fractionation of Firn Air and the Ice Core Record of Abrupt Interstadial Climate Change", "uid": "p0000160", "west": null}]

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